US2519858A - Electrodeposition of nickel and nickel alloys - Google Patents

Electrodeposition of nickel and nickel alloys Download PDF

Info

Publication number: US2519858A
Authority: US; United States
Prior art keywords: nickel; ozs; bath; grams; cobalt
Prior art date: 1944-09-29
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired - Lifetime

Application number

US619904A

Other languages

English (en)

Inventor

Spiro Peter

Wohlgemuth Fritz

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Individual

Original Assignee

Individual

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1944-09-29

Filing date

1945-10-02

Publication date

1950-08-22

1945-10-02 Application filed by Individual filed Critical Individual

1950-08-22 Application granted granted Critical

1950-08-22 Publication of US2519858A publication Critical patent/US2519858A/en

1967-08-22 Anticipated expiration legal-status Critical

Status Expired - Lifetime legal-status Critical Current

Links

238000004070 electrodeposition Methods 0.000 title claims description 9
PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical group [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 title description 44
229910052759 nickel Inorganic materials 0.000 title description 22
229910000990 Ni alloy Inorganic materials 0.000 title description 11
FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 claims description 14
PUZPDOWCWNUUKD-UHFFFAOYSA-M sodium fluoride Chemical compound [F-].[Na+] PUZPDOWCWNUUKD-UHFFFAOYSA-M 0.000 claims description 14
239000000243 solution Substances 0.000 claims description 13
RHZZVWTVJHZKAH-UHFFFAOYSA-K trisodium;naphthalene-1,2,3-trisulfonate Chemical compound [Na+].[Na+].[Na+].C1=CC=C2C(S([O-])(=O)=O)=C(S([O-])(=O)=O)C(S(=O)(=O)[O-])=CC2=C1 RHZZVWTVJHZKAH-UHFFFAOYSA-K 0.000 claims description 12
DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical class C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 claims description 8
229910000531 Co alloy Inorganic materials 0.000 claims description 7
QXZUUHYBWMWJHK-UHFFFAOYSA-N [Co].[Ni] Chemical group [Co].[Ni] QXZUUHYBWMWJHK-UHFFFAOYSA-N 0.000 claims description 7
239000007864 aqueous solution Substances 0.000 claims description 7
KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 claims description 7
239000004327 boric acid Substances 0.000 claims description 7
LGQLOGILCSXPEA-UHFFFAOYSA-L nickel sulfate Chemical compound [Ni+2].[O-]S([O-])(=O)=O LGQLOGILCSXPEA-UHFFFAOYSA-L 0.000 claims description 7
239000011780 sodium chloride Substances 0.000 claims description 7
235000013024 sodium fluoride Nutrition 0.000 claims description 7
239000011775 sodium fluoride Substances 0.000 claims description 7
239000000615 nonconductor Substances 0.000 claims description 5
238000005323 electroforming Methods 0.000 claims description 4
QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 claims 1
229910021653 sulphate ion Inorganic materials 0.000 claims 1
238000000576 coating method Methods 0.000 description 10
238000007747 plating Methods 0.000 description 10
239000000080 wetting agent Substances 0.000 description 10
238000007792 addition Methods 0.000 description 9
229910017052 cobalt Inorganic materials 0.000 description 8
239000010941 cobalt Substances 0.000 description 8
GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 8
238000000151 deposition Methods 0.000 description 8
KRHYYFGTRYWZRS-UHFFFAOYSA-M Fluoride anion Chemical compound [F-] KRHYYFGTRYWZRS-UHFFFAOYSA-M 0.000 description 7
238000000034 method Methods 0.000 description 7
239000004848 polyfunctional curative Substances 0.000 description 7
239000011248 coating agent Substances 0.000 description 6
KTVIXTQDYHMGHF-UHFFFAOYSA-L cobalt(2+) sulfate Chemical compound [Co+2].[O-]S([O-])(=O)=O KTVIXTQDYHMGHF-UHFFFAOYSA-L 0.000 description 6
239000004020 conductor Substances 0.000 description 5
229910052751 metal Inorganic materials 0.000 description 5
239000002184 metal Substances 0.000 description 5
239000003795 chemical substances by application Substances 0.000 description 4
239000003792 electrolyte Substances 0.000 description 4
238000004519 manufacturing process Methods 0.000 description 4
125000000913 palmityl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 4
229910052793 cadmium Inorganic materials 0.000 description 3
BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium atom Chemical compound [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 description 3
230000008021 deposition Effects 0.000 description 3
BXWNKGSJHAJOGX-UHFFFAOYSA-N hexadecan-1-ol Chemical class CCCCCCCCCCCCCCCCO BXWNKGSJHAJOGX-UHFFFAOYSA-N 0.000 description 3
-1 oleyl alcohols Chemical class 0.000 description 3
CXKCTMHTOKXKQT-UHFFFAOYSA-N cadmium oxide Inorganic materials [Cd]=O CXKCTMHTOKXKQT-UHFFFAOYSA-N 0.000 description 2
CFEAAQFZALKQPA-UHFFFAOYSA-N cadmium(2+);oxygen(2-) Chemical compound [O-2].[Cd+2] CFEAAQFZALKQPA-UHFFFAOYSA-N 0.000 description 2
230000000694 effects Effects 0.000 description 2
150000002739 metals Chemical class 0.000 description 2
125000001117 oleyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])/C([H])=C([H])\C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
230000003647 oxidation Effects 0.000 description 2
238000007254 oxidation reaction Methods 0.000 description 2
ALSTYHKOOCGGFT-KTKRTIGZSA-N (9Z)-octadecen-1-ol Chemical class CCCCCCCC\C=C/CCCCCCCCO ALSTYHKOOCGGFT-KTKRTIGZSA-N 0.000 description 1
VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
BDAGIHXWWSANSR-UHFFFAOYSA-M Formate Chemical compound [O-]C=O BDAGIHXWWSANSR-UHFFFAOYSA-M 0.000 description 1
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
238000005299 abrasion Methods 0.000 description 1
229910045601 alloy Inorganic materials 0.000 description 1
239000000956 alloy Substances 0.000 description 1
239000004411 aluminium Substances 0.000 description 1
229910052782 aluminium Inorganic materials 0.000 description 1
XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
238000000137 annealing Methods 0.000 description 1
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
230000015572 biosynthetic process Effects 0.000 description 1
229960000541 cetyl alcohol Drugs 0.000 description 1
ZGDWHDKHJKZZIQ-UHFFFAOYSA-N cobalt nickel Chemical group [Co].[Ni].[Ni].[Ni] ZGDWHDKHJKZZIQ-UHFFFAOYSA-N 0.000 description 1
239000000356 contaminant Substances 0.000 description 1
238000000354 decomposition reaction Methods 0.000 description 1
238000004512 die casting Methods 0.000 description 1
239000012153 distilled water Substances 0.000 description 1
239000002659 electrodeposit Substances 0.000 description 1
238000009713 electroplating Methods 0.000 description 1
230000008030 elimination Effects 0.000 description 1
238000003379 elimination reaction Methods 0.000 description 1
239000001257 hydrogen Substances 0.000 description 1
229910052739 hydrogen Inorganic materials 0.000 description 1
239000000463 material Substances 0.000 description 1
235000012054 meals Nutrition 0.000 description 1
URXNVXOMQQCBHS-UHFFFAOYSA-N naphthalene;sodium Chemical compound [Na].C1=CC=CC2=CC=CC=C21 URXNVXOMQQCBHS-UHFFFAOYSA-N 0.000 description 1
239000001301 oxygen Substances 0.000 description 1
229910052760 oxygen Inorganic materials 0.000 description 1
230000000704 physical effect Effects 0.000 description 1
239000012286 potassium permanganate Substances 0.000 description 1
150000003839 salts Chemical class 0.000 description 1
239000000126 substance Substances 0.000 description 1
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
238000009736 wetting Methods 0.000 description 1
229910052725 zinc Inorganic materials 0.000 description 1
239000011701 zinc Substances 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D3/00—Electroplating: Baths therefor
- C25D3/02—Electroplating: Baths therefor from solutions
- C25D3/56—Electroplating: Baths therefor from solutions of alloys
- C25D3/562—Electroplating: Baths therefor from solutions of alloys containing more than 50% by weight of iron or nickel or cobalt
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D3/00—Electroplating: Baths therefor
- C25D3/02—Electroplating: Baths therefor from solutions
- C25D3/12—Electroplating: Baths therefor from solutions of nickel or cobalt

Definitions

the present invention relates to the electrodeposition of nickel and nickel alloys upon metals and non-conductors and has for its primary object to provide an improved electrolyte which is applicable with advantage to various forms of nickel plating by electro-deposition and is particularly suitable for use in producing the thick, hard and abrasion resistant coatings of nickel and nickel alloys required in eiectro-forming work; such as for example the production of the surfaces of pressure moulds by electro-deposition.
a nickel plating bath of the fluoride type posesses very good throwing power while plating a deposit with low stresses and we propose to use a bath of this kind in preference to other known types of nickel baths such as the Watts, Double salt, Formate and All Chloride types, as a basis for the invention hereinafter described.
wetting agents to avoid pitting in electro-plating is generally known but most of the known wetting agents increase the internal stresses of the electro-deposited coatings considerably. Moreover, they are known to decompose when submitted to the usual plating conditions, 1. e. when influenced by higher temperature, oxygen, development of hydrogen and associated factors and the products of the decomposition increase the stress still further, while the wetting qualities are at the same time lost.
the wetting agent as sold under the trade name Claytavon WM and formed of sulphonated cetyl and oleyl alcohols of which 40-70% is oleyl, and the rest cetyl alcohol serves well for this pur ose.
the hardness of the alloy deposited from the above bath is approximately 550 Vickers. This hardness of the electro-deposit shows relative stability even at temperatures between 300 and 500 C., i. e. at temperatures used in the production of zinc and aluminium pressure die-castings.
the addition of the two organic agents to the fluoride bath containing cobalt ensures hardness, stability at temperatures above 300 C., and the internal stresses, which are usually increased by wetting agents, can be substantially eliminated. An excessive cobalt deposition in the first plating period is prevented, and it is thus possible to build up a deposit of a relatively uniform nickel cobalt alloy.
the nickel electro-formed from the electrolyte of this invention is unusually stable in its hardness, even under the influence of relatively high temperatures and is not embrittled by submission to temperatures up to 300 C., a certain embrittlement sets in above 300 C., which may be mechanically disadvantageous.
cadmium to the electrolyte in concentrations such as l in 30,000 this embrittlement is prevented, while the cadmium addition leads to a gradual increase in ductility with the subjection of the metal to increasingly high temperatures, without.
the physical properties of the nickel referred to are not those ruling when the nickel is subjected to the temperatures mentioned but refers to properties of the nickel at room temperature, after having been heated to certain temperatures.
An electrolytic bath for the electrodeposition of nickel cobalt alloys upon non-conductors for electro-forming pressure molds consisting essentially in aqueous solution of 33-50 ozs. nickel sulphate, 1 to 3 on. cobalt sulphate, 4 to 6 ozs. boric acid, 1 to 2 on. sodium fluoride, V to 2 ozs. sodium chloride, 4 to 20 grams of 1-3-6 sodium naphthalene trisulphonate and 4 to 12 grams of sulphonated aliphatic alcohol per gallon of solution.
An elec'rolytic bath for the electron deposition of cobalt-nickel alloys upon metals and nonconductors in the production of pressure molds consisting essentially in aqueous solution for each gallon thereof 33 to ozs. of nickel sulphate, 4-6 ozs. of boric acid, 1 to 2 ozs. of sodium fluoride, 1 to 3 ozs. of cobalt sulphate, M4 to 2 ozs.
a process for producing the surface of a pressure mould of nickel cobalt alloy which consists of providing on a master of non-conducting material shaped in accordance with the articles to be moulded, a conducting surface, depositing nickel alloy on said conducting surface in an electrolytic bath consisting essentially in each gallon of aqueous solution of 33 to 50 ozs. of nickel sulphate, 4 to 6 ozs. of boric acid, 1 to 2 ozs. of sodium fluoride, l to 3 075. of cobalt sulphate, to 2 ozs.
a process for producing the surface of a pressure mould of nickel cobalt alloy which consists of providing on a master of non-conducting material shaped in accordance with the articles to be moulded, a conducting surface, depositing nickel alloy on said conducting surface in an electrolytic bath consisting essentially in each gallon of aqueous solution of 33 to 50 ozs. of nickel sulphate, 4 to 6 ozs. of boric acid, 1 to 2% ozs. of sodium fluoride, 1 to 3% ozs. of cobalt sulphate,
a process for producing the surface of a pressure mould of nickel cobalt alloy which consists of providing on a master of non-conducting material shaped in accordancewith the articles to be moulded, a conducting surface, depositing nickel alloy on said conducting surface in an electrolytic bath consisting essentially in each gallon of aqueous solution of 33 to 50 ozs. of nickel sulphate, 4 to 6 ozs. of boric acid, 1 to 2 ozs. of sodium fluoride, 1 to 3 /2 ozs. of cobalt sulphate, A, to 2 ozs.

Landscapes

Chemical & Material Sciences (AREA)
Engineering & Computer Science (AREA)
Chemical Kinetics & Catalysis (AREA)
Electrochemistry (AREA)
Materials Engineering (AREA)
Metallurgy (AREA)
Organic Chemistry (AREA)
Electroplating And Plating Baths Therefor (AREA)
Paints Or Removers (AREA)
Pyrrole Compounds (AREA)
Secondary Cells (AREA)

US619904A 1944-09-29 1945-10-02 Electrodeposition of nickel and nickel alloys Expired - Lifetime US2519858A (en)

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
GB18720/44A GB584977A (en)	1944-09-29	1944-09-29	Improvements in or relating to the electro-deposition of nickel and nickel alloys

Publications (1)

Publication Number	Publication Date
US2519858A true US2519858A (en)	1950-08-22

Family

ID=10117250

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
US619904A Expired - Lifetime US2519858A (en)	1944-09-29	1945-10-02	Electrodeposition of nickel and nickel alloys

Country Status (4)

Country	Link
US (1)	US2519858A (de)
DE (1)	DE804278C (de)
FR (1)	FR944048A (de)
GB (1)	GB584977A (de)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
DE956903C (de) *	1952-04-22	1957-01-24	Ncr Co	Verfahren zum elektrolytischen UEberzieen eines nichtmagnetischen Metalls mit einer Nickel-Kobalt-Legierung
US2802779A (en) *	1953-12-10	1957-08-13	Vickers Ltd Sa	Electrodeposition of nickel and nickel alloys
US3274079A (en) *	1962-07-19	1966-09-20	M & T Chemicals Inc	Bath and process for the electrodeposition of nickel and nickel-cobalt alloys

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
BE526094A (de) *	1953-09-19

Citations (11)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US998085A (en) *	1909-02-23	1911-07-18	Frank Iorns Gibbs	Method of producing metallic vessels by electrodeposition.
GB438412A (en) *	1935-02-14	1935-11-15	Harshaw Chem Corp	Improvements relating to the electro-deposition of nickel
US2119304A (en) *	1935-08-01	1938-05-31	Eaton Detroit Metal Company	Electroplating
US2125229A (en) *	1936-04-14	1938-07-26	Harshaw Chem Corp	Electrodeposition of metals
US2147415A (en) *	1937-05-11	1939-02-14	Eastman Kodak Co	Electroplating
US2191813A (en) *	1939-12-01	1940-02-27	Udylite Corp	Electrodeposition of nickel from an acid bath
US2198267A (en) *	1939-12-14	1940-04-23	Harshaw Chem Corp	Electrodeposition of metals
US2228991A (en) *	1936-01-20	1941-01-14	Seymour Mfg Co	Production of bright nickel deposit
US2238861A (en) *	1938-07-06	1941-04-15	Harshaw Chem Corp	Electrodeposition of metals
US2313756A (en) *	1939-03-01	1943-03-16	Dow Chemical Co	Method of electroplating magnesium
US2315802A (en) *	1940-04-20	1943-04-06	Harshaw Chem Corp	Nickel plating

1944
- 1944-09-29 GB GB18720/44A patent/GB584977A/en not_active Expired
1945
- 1945-10-02 US US619904A patent/US2519858A/en not_active Expired - Lifetime
- 1945-10-22 FR FR944048D patent/FR944048A/fr not_active Expired
1948
- 1948-11-13 DE DEP459A patent/DE804278C/de not_active Expired

Patent Citations (11)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US998085A (en) *	1909-02-23	1911-07-18	Frank Iorns Gibbs	Method of producing metallic vessels by electrodeposition.
GB438412A (en) *	1935-02-14	1935-11-15	Harshaw Chem Corp	Improvements relating to the electro-deposition of nickel
US2119304A (en) *	1935-08-01	1938-05-31	Eaton Detroit Metal Company	Electroplating
US2228991A (en) *	1936-01-20	1941-01-14	Seymour Mfg Co	Production of bright nickel deposit
US2125229A (en) *	1936-04-14	1938-07-26	Harshaw Chem Corp	Electrodeposition of metals
US2147415A (en) *	1937-05-11	1939-02-14	Eastman Kodak Co	Electroplating
US2238861A (en) *	1938-07-06	1941-04-15	Harshaw Chem Corp	Electrodeposition of metals
US2313756A (en) *	1939-03-01	1943-03-16	Dow Chemical Co	Method of electroplating magnesium
US2191813A (en) *	1939-12-01	1940-02-27	Udylite Corp	Electrodeposition of nickel from an acid bath
US2198267A (en) *	1939-12-14	1940-04-23	Harshaw Chem Corp	Electrodeposition of metals
US2315802A (en) *	1940-04-20	1943-04-06	Harshaw Chem Corp	Nickel plating

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
DE956903C (de) *	1952-04-22	1957-01-24	Ncr Co	Verfahren zum elektrolytischen UEberzieen eines nichtmagnetischen Metalls mit einer Nickel-Kobalt-Legierung
US2802779A (en) *	1953-12-10	1957-08-13	Vickers Ltd Sa	Electrodeposition of nickel and nickel alloys
US3274079A (en) *	1962-07-19	1966-09-20	M & T Chemicals Inc	Bath and process for the electrodeposition of nickel and nickel-cobalt alloys

Also Published As

Publication number	Publication date
GB584977A (en)	1947-01-28
DE804278C (de)	1951-04-19
FR944048A (fr)	1949-03-24

Publication	Publication Date	Title
US4765871A (en)	1988-08-23	Zinc-nickel electroplated article and method for producing the same
US2285548A (en)	1942-06-09	Process for electrodepositing an adherent coating of copper on chromium-contanining alloys of iron and/or nickel
US2693444A (en)	1954-11-02	Electrodeposition of chromium and alloys thereof
US3920468A (en)	1975-11-18	Electrodeposition of films of particles on cathodes
US2176668A (en)	1939-10-17	Silver plating process
US2950233A (en)	1960-08-23	Production of hard surfaces on base metals
US2457059A (en)	1948-12-21	Method for bonding a nickel electrodeposit to a nickel surface
US2519858A (en)	1950-08-22	Electrodeposition of nickel and nickel alloys
US2805192A (en)	1957-09-03	Plated refractory metals
US2511395A (en)	1950-06-13	Process for the electrodeposition of tin alloys
US2430750A (en)	1947-11-11	Method of electroplating to produce fissure network chromium plating
US3207679A (en)	1965-09-21	Method for electroplating on titanium
US3421986A (en)	1969-01-14	Method of electroplating a bright adherent chromium coating onto cast-iron
US3687824A (en)	1972-08-29	Electrodeposition of films of particles on cathodes
US3093556A (en)	1963-06-11	Electro-depositing stainless steel coatings on metal surfaces
US2409983A (en)	1946-10-22	Electrodeposition of indium
US2327676A (en)	1943-08-24	Plating process
US3920527A (en)	1975-11-18	Self-regulating plating bath and method for electrodepositing chromium
US2221562A (en)	1940-11-12	Electroplating
US2437612A (en)	1948-03-09	Process for electrolytically zinc plating magnesium and magnesium base alloys
US2307551A (en)	1943-01-05	Method of producing a white, platinumlike color chromium plate and the product thereof and bath therefor
US2921888A (en)	1960-01-19	Electroplating titanium ano titanium alloys
US2078869A (en)	1937-04-27	Electroplating process
US3442776A (en)	1969-05-06	Electrolyte and process for the electrodeposition of cadmium
US3374154A (en)	1968-03-19	Electroforming and electrodeposition of stress-free nickel from the sulfamate bath

US2519858A - Electrodeposition of nickel and nickel alloys - Google Patents

Info

Links

Classifications

Definitions

Landscapes

Applications Claiming Priority (1)

Publications (1)

Family

ID=10117250

Family Applications (1)

Country Status (4)

Cited By (3)

Families Citing this family (1)

Citations (11)

Patent Citations (11)

Cited By (3)

Also Published As

Similar Documents