US20090227166A1 - Thermal-adhesive bicomponent fiber and method for producing it - Google Patents
Thermal-adhesive bicomponent fiber and method for producing it Download PDFInfo
- Publication number
- US20090227166A1 US20090227166A1 US12/300,428 US30042807A US2009227166A1 US 20090227166 A1 US20090227166 A1 US 20090227166A1 US 30042807 A US30042807 A US 30042807A US 2009227166 A1 US2009227166 A1 US 2009227166A1
- Authority
- US
- United States
- Prior art keywords
- thermal
- adhesive
- fiber
- resin component
- bicomponent fiber
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Abandoned
Links
- 239000000835 fiber Substances 0.000 title claims abstract description 180
- 239000000853 adhesive Substances 0.000 title claims abstract description 84
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 10
- 239000004745 nonwoven fabric Substances 0.000 claims abstract description 64
- 239000004840 adhesive resin Substances 0.000 claims abstract description 42
- 229920006223 adhesive resin Polymers 0.000 claims abstract description 42
- 229920005989 resin Polymers 0.000 claims abstract description 36
- 239000011347 resin Substances 0.000 claims abstract description 36
- 229920000139 polyethylene terephthalate Polymers 0.000 claims abstract description 32
- 239000005020 polyethylene terephthalate Substances 0.000 claims abstract description 32
- 238000002844 melting Methods 0.000 claims abstract description 24
- 230000008018 melting Effects 0.000 claims abstract description 24
- -1 polyethylene terephthalate Polymers 0.000 claims abstract description 23
- 229920005992 thermoplastic resin Polymers 0.000 claims abstract description 13
- 239000000306 component Substances 0.000 claims description 84
- 238000009987 spinning Methods 0.000 claims description 28
- 239000008358 core component Substances 0.000 claims description 19
- 230000002040 relaxant effect Effects 0.000 claims description 15
- 238000010622 cold drawing Methods 0.000 claims description 10
- 230000009477 glass transition Effects 0.000 claims description 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 10
- 229920001634 Copolyester Polymers 0.000 claims description 6
- 229920005672 polyolefin resin Polymers 0.000 claims description 4
- 230000001070 adhesive effect Effects 0.000 abstract description 6
- 238000000034 method Methods 0.000 description 41
- 239000013078 crystal Substances 0.000 description 8
- 229920000642 polymer Polymers 0.000 description 7
- 239000002826 coolant Substances 0.000 description 6
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 5
- 238000007334 copolymerization reaction Methods 0.000 description 5
- WERYXYBDKMZEQL-UHFFFAOYSA-N butane-1,4-diol Chemical compound OCCCCO WERYXYBDKMZEQL-UHFFFAOYSA-N 0.000 description 4
- 239000004744 fabric Substances 0.000 description 4
- 229920001903 high density polyethylene Polymers 0.000 description 4
- 239000004700 high-density polyethylene Substances 0.000 description 4
- QQVIHTHCMHWDBS-UHFFFAOYSA-N isophthalic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-N 0.000 description 4
- 239000004743 Polypropylene Substances 0.000 description 3
- 238000009960 carding Methods 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- 229920006038 crystalline resin Polymers 0.000 description 3
- 238000002425 crystallisation Methods 0.000 description 3
- 230000008025 crystallization Effects 0.000 description 3
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 238000010438 heat treatment Methods 0.000 description 3
- 239000000155 melt Substances 0.000 description 3
- 229920001169 thermoplastic Polymers 0.000 description 3
- 239000004416 thermosoftening plastic Substances 0.000 description 3
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 2
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 description 2
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 2
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 2
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- 125000004432 carbon atom Chemical group C* 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 230000001276 controlling effect Effects 0.000 description 2
- 230000007423 decrease Effects 0.000 description 2
- GWTCIAGIKURVBJ-UHFFFAOYSA-L dipotassium;dodecyl phosphate Chemical compound [K+].[K+].CCCCCCCCCCCCOP([O-])([O-])=O GWTCIAGIKURVBJ-UHFFFAOYSA-L 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 238000004049 embossing Methods 0.000 description 2
- 150000002148 esters Chemical class 0.000 description 2
- 238000011835 investigation Methods 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 239000003960 organic solvent Substances 0.000 description 2
- 229920000728 polyester Polymers 0.000 description 2
- 229920001155 polypropylene Polymers 0.000 description 2
- 229920001296 polysiloxane Polymers 0.000 description 2
- 229940033623 potassium lauryl phosphate Drugs 0.000 description 2
- 238000003825 pressing Methods 0.000 description 2
- YPFDHNVEDLHUCE-UHFFFAOYSA-N propane-1,3-diol Chemical compound OCCCO YPFDHNVEDLHUCE-UHFFFAOYSA-N 0.000 description 2
- CXMXRPHRNRROMY-UHFFFAOYSA-N sebacic acid Chemical compound OC(=O)CCCCCCCCC(O)=O CXMXRPHRNRROMY-UHFFFAOYSA-N 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 2
- LDHQCZJRKDOVOX-UHFFFAOYSA-N trans-crotonic acid Natural products CC=CC(O)=O LDHQCZJRKDOVOX-UHFFFAOYSA-N 0.000 description 2
- NIDNOXCRFUCAKQ-RNGGSSJXSA-N (1r,2r,3s,4s)-bicyclo[2.2.1]hept-5-ene-2,3-dicarboxylic acid Chemical compound C1[C@@H]2C=C[C@H]1[C@H](C(=O)O)[C@@H]2C(O)=O NIDNOXCRFUCAKQ-RNGGSSJXSA-N 0.000 description 1
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- JAHNSTQSQJOJLO-UHFFFAOYSA-N 2-(3-fluorophenyl)-1h-imidazole Chemical compound FC1=CC=CC(C=2NC=CN=2)=C1 JAHNSTQSQJOJLO-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- ISPYQTSUDJAMAB-UHFFFAOYSA-N 2-chlorophenol Chemical compound OC1=CC=CC=C1Cl ISPYQTSUDJAMAB-UHFFFAOYSA-N 0.000 description 1
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical group OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 239000002202 Polyethylene glycol Substances 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000008065 acid anhydrides Chemical class 0.000 description 1
- 239000001361 adipic acid Substances 0.000 description 1
- 235000011037 adipic acid Nutrition 0.000 description 1
- 238000010420 art technique Methods 0.000 description 1
- 239000012298 atmosphere Substances 0.000 description 1
- 238000005452 bending Methods 0.000 description 1
- 239000004305 biphenyl Substances 0.000 description 1
- 235000010290 biphenyl Nutrition 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- HNEGQIOMVPPMNR-IHWYPQMZSA-N citraconic acid Chemical compound OC(=O)C(/C)=C\C(O)=O HNEGQIOMVPPMNR-IHWYPQMZSA-N 0.000 description 1
- 229940018557 citraconic acid Drugs 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 230000006835 compression Effects 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- LDHQCZJRKDOVOX-NSCUHMNNSA-N crotonic acid Chemical compound C\C=C\C(O)=O LDHQCZJRKDOVOX-NSCUHMNNSA-N 0.000 description 1
- 150000002009 diols Chemical class 0.000 description 1
- PBOFFNYRKURMFP-UHFFFAOYSA-L dipotassium;5-sulfobenzene-1,3-dicarboxylate Chemical compound [K+].[K+].OS(=O)(=O)C1=CC(C([O-])=O)=CC(C([O-])=O)=C1 PBOFFNYRKURMFP-UHFFFAOYSA-L 0.000 description 1
- 229920006240 drawn fiber Polymers 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 238000012681 fiber drawing Methods 0.000 description 1
- 239000001530 fumaric acid Substances 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 230000020169 heat generation Effects 0.000 description 1
- XXMIOPMDWAUFGU-UHFFFAOYSA-N hexane-1,6-diol Chemical compound OCCCCCCO XXMIOPMDWAUFGU-UHFFFAOYSA-N 0.000 description 1
- 239000012510 hollow fiber Substances 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- 230000002401 inhibitory effect Effects 0.000 description 1
- 230000002452 interceptive effect Effects 0.000 description 1
- 230000001788 irregular Effects 0.000 description 1
- LDHQCZJRKDOVOX-IHWYPQMZSA-N isocrotonic acid Chemical compound C\C=C/C(O)=O LDHQCZJRKDOVOX-IHWYPQMZSA-N 0.000 description 1
- 229920000092 linear low density polyethylene Polymers 0.000 description 1
- 239000004707 linear low-density polyethylene Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 229920001684 low density polyethylene Polymers 0.000 description 1
- 239000004702 low-density polyethylene Substances 0.000 description 1
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 1
- 239000011976 maleic acid Substances 0.000 description 1
- 238000002074 melt spinning Methods 0.000 description 1
- HNEGQIOMVPPMNR-NSCUHMNNSA-N mesaconic acid Chemical compound OC(=O)C(/C)=C/C(O)=O HNEGQIOMVPPMNR-NSCUHMNNSA-N 0.000 description 1
- OJURWUUOVGOHJZ-UHFFFAOYSA-N methyl 2-[(2-acetyloxyphenyl)methyl-[2-[(2-acetyloxyphenyl)methyl-(2-methoxy-2-oxoethyl)amino]ethyl]amino]acetate Chemical compound C=1C=CC=C(OC(C)=O)C=1CN(CC(=O)OC)CCN(CC(=O)OC)CC1=CC=CC=C1OC(C)=O OJURWUUOVGOHJZ-UHFFFAOYSA-N 0.000 description 1
- LVHBHZANLOWSRM-UHFFFAOYSA-N methylenebutanedioic acid Natural products OC(=O)CC(=C)C(O)=O LVHBHZANLOWSRM-UHFFFAOYSA-N 0.000 description 1
- HNEGQIOMVPPMNR-UHFFFAOYSA-N methylfumaric acid Natural products OC(=O)C(C)=CC(O)=O HNEGQIOMVPPMNR-UHFFFAOYSA-N 0.000 description 1
- RXOHFPCZGPKIRD-UHFFFAOYSA-N naphthalene-2,6-dicarboxylic acid Chemical compound C1=C(C(O)=O)C=CC2=CC(C(=O)O)=CC=C21 RXOHFPCZGPKIRD-UHFFFAOYSA-N 0.000 description 1
- YCWSUKQGVSGXJO-NTUHNPAUSA-N nifuroxazide Chemical group C1=CC(O)=CC=C1C(=O)N\N=C\C1=CC=C([N+]([O-])=O)O1 YCWSUKQGVSGXJO-NTUHNPAUSA-N 0.000 description 1
- JCXJVPUVTGWSNB-UHFFFAOYSA-N nitrogen dioxide Inorganic materials O=[N]=O JCXJVPUVTGWSNB-UHFFFAOYSA-N 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 239000008188 pellet Substances 0.000 description 1
- YWAKXRMUMFPDSH-UHFFFAOYSA-N pentene Chemical compound CCCC=C YWAKXRMUMFPDSH-UHFFFAOYSA-N 0.000 description 1
- 230000002093 peripheral effect Effects 0.000 description 1
- ZUOUZKKEUPVFJK-UHFFFAOYSA-N phenylbenzene Natural products C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 229920002959 polymer blend Polymers 0.000 description 1
- 229920000098 polyolefin Polymers 0.000 description 1
- 238000007712 rapid solidification Methods 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 238000005096 rolling process Methods 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- YXTFRJVQOWZDPP-UHFFFAOYSA-M sodium;3,5-dicarboxybenzenesulfonate Chemical compound [Na+].OC(=O)C1=CC(C(O)=O)=CC(S([O-])(=O)=O)=C1 YXTFRJVQOWZDPP-UHFFFAOYSA-M 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 230000008961 swelling Effects 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F8/00—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof
- D01F8/04—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers
- D01F8/14—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers with at least one polyester as constituent
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01D—MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
- D01D5/00—Formation of filaments, threads, or the like
- D01D5/28—Formation of filaments, threads, or the like while mixing different spinning solutions or melts during the spinning operation; Spinnerette packs therefor
- D01D5/30—Conjugate filaments; Spinnerette packs therefor
- D01D5/34—Core-skin structure; Spinnerette packs therefor
-
- D—TEXTILES; PAPER
- D02—YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
- D02J—FINISHING OR DRESSING OF FILAMENTS, YARNS, THREADS, CORDS, ROPES OR THE LIKE
- D02J1/00—Modifying the structure or properties resulting from a particular structure; Modifying, retaining, or restoring the physical form or cross-sectional shape, e.g. by use of dies or squeeze rollers
- D02J1/22—Stretching or tensioning, shrinking or relaxing, e.g. by use of overfeed and underfeed apparatus, or preventing stretch
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
- D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
- D04H1/54—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by welding together the fibres, e.g. by partially melting or dissolving
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
- D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
- D04H1/54—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by welding together the fibres, e.g. by partially melting or dissolving
- D04H1/541—Composite fibres, e.g. sheath-core, sea-island or side-by-side; Mixed fibres
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2913—Rod, strand, filament or fiber
- Y10T428/2929—Bicomponent, conjugate, composite or collateral fibers or filaments [i.e., coextruded sheath-core or side-by-side type]
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
- Y10T442/60—Nonwoven fabric [i.e., nonwoven strand or fiber material]
- Y10T442/637—Including strand or fiber material which is a monofilament composed of two or more polymeric materials in physically distinct relationship [e.g., sheath-core, side-by-side, islands-in-sea, fibrils-in-matrix, etc.] or composed of physical blend of chemically different polymeric materials or a physical blend of a polymeric material and a filler material
- Y10T442/641—Sheath-core multicomponent strand or fiber material
Definitions
- the present invention relates to a self-extensible thermal-adhesive bicomponent fiber, which has a low modulus and is self-extensible in thermal adhesion and which has a soft feel when formed into a thermal-adhesive nonwoven fabric, and to a method for producing it.
- a thermal-adhesive bicomponent fiber such as typically a core/sheath thermal-adhesive bicomponent fiber that comprises a thermal-adhesive resin component as the sheath and a fiber-forming resin component as the core is used as a nonwoven fabric by forming a fiber web according to a carding method, an air-laid method or a wet sheet-making method and then melting the thermal-adhesive resin component through hot air drier treatment or hot roll treatment to thereby form fiber-fiber bonding to give a nonwoven fabric.
- this does not use an adhesive comprising an organic solvent, and its advantage is that the amount of a harmful substance such as an organic solvent to be released from it is small.
- it since its other advantages of high producibility and cost reduction are great, it has been widely used as fiber structures such as fiber cushions (hard cotton) and bed mats, and as nonwoven fabrics.
- thermal-adhesive nonwoven fabric typically for sanitary materials such as paper diapers and sanitary napkins is required to have softness and drapability like a fabric and have a suitable, non-paperlike bulkiness, since the nonwoven fabric may be kept in direct contact with users' skin.
- thermoly adhering a web obtained from thermal-adhesive fibers there is known a heat-roll method comprising thermally pressing and softening a part of the web by the use of an embossing roll and melt-sealing it.
- the nonwoven fabric may be readily folded at the boundary between the heat-sealed region and the non-heat-sealed region, and the obtained nonwoven fabric may have excellent drapability.
- the fibers in the heat-sealed region are pressed and flattened, the heat-sealed part may become hard and may lose the bulkiness of nonwoven fabric, and therefore the obtained nonwoven fabric may have a paperlike feel.
- an air-through method that comprises applying a hot air jet to the whole of a web to thereby soften or melt the intersections of the fibers.
- the applied hot air runs through the web while the bulkiness of the web is left as such in some degree, and therefore the obtained nonwoven fabric is bulky, not having a partly hardened region, and the touch of its surface is smooth.
- the nonwoven fabric when the nonwoven fabric is folded, it may have irregular folds and may lose drapability.
- Patent Reference 1 For solving the problems, a method is disclosed in Patent Reference 1. Specifically, according to a high-speed spinning method, the orientation index of a thermal-adhesive resin component is made to be at most 25% and the orientation index of a fiber-forming resin component is made to be at least 40%, thereby giving a thermal-adhesive bicomponent fiber having a strong adhering point strength, melt-fusible at a lower temperature and having a small degree of thermal shrinkage.
- the disclosed technique comprises adhering a blended web of the thermal-adhesive bicomponent fibers and non-thermal-adhesive fibers according to an air-through method, thereby producing a nonwoven fabric having drapability and bulkiness and having a sufficient nonwoven fabric strength.
- non-thermal-adhesive fibers are mixed to produce a nonwoven fabric, but in this case, since the number of the adhering intersections in the nonwoven fabric decreases, the nonwoven fabric strength may lower. Accordingly, the nonwoven fabric strength and the soft feel could not always be on a sufficient level.
- thermal-adhesive bicomponent fiber in which the core component is a fiber-forming resin component and the core component is polyethylene terephthalate (hereinafter referred to as PET), is not disclosed in Patent Reference 1.
- PET polyethylene terephthalate
- the melting point of the core component in the fiber may be sufficiently higher than the melting point of the sheath component therein, as compared with a thermal-adhesive bicomponent fiber in which the core component is polypropylene (hereinafter referred to as PP), and therefore, the thermal-adhesive strength of the obtained nonwoven fabric may be further improved.
- PP thermal-adhesive bicomponent fiber in which the core component is polypropylene
- the bicomponent fiber in which the core component is PET is relatively highly rigid, it has a potential to give a nonwoven fabric having higher bulkiness.
- the bicomponent fibers undrawn at a low draw ratio or the undrawn bicomponent fibers described in Patent Reference 1 are formed into nonwoven fabrics, the thermal shrinkage of the fabrics is still large since the orientation crystallinity of the core component of the bicomponent fibers used is insufficient.
- the invention has been made under the background of the above-mentioned prior art techniques, and its object is to provide a low-modulus, self-extensible thermal-adhesive bicomponent fiber comprising polyethylene terephthalate as the fiber-forming resin component thereof and capable of producing a nonwoven fabric or a fiber structure that has a high adhesive strength and is bulky and well drapable.
- the present inventors have assiduously investigated for the purpose of solving the above-mentioned problems, and as a result, have invented a low-modulus, self-extensible thermal-adhesive bicomponent fiber that comprises PET as the fiber-forming resin component thereof and satisfies high adhesive strength, sufficient bulkiness and drapability, using a crystalline thermoplastic resin having a lower melting point than PET by at least 20° C., as the thermal-adhesive resin component of the fiber, and cold-drawing an undrawn yarn of the fiber taken out at a spinning speed of not higher than 1300 m/min, by from 1.05 times to 1.30 times under no heat or with cooling in a coolant, followed by relaxing and thermally shrinking it at a temperature higher by at least 10° C. than both the glass transition point of the thermal-adhesive resin component and the glass transition point of the fiber-forming resin component.
- a self-extensible thermal-adhesive bicomponent fiber that comprises a fiber-forming resin component and a thermal-adhesive resin component and is characterized in that the fiber-forming resin component comprises polyethylene terephthalate (PET), that the thermal-adhesive resin component comprises a crystalline thermoplastic resin having a melting point lower by at least 20° C. than that of the fiber-forming resin component, and that its breaking elongation is from 130 to 600%, its 100% elongation tensile strength is from 0.3 to 1.0 cN/dtex and its 12° C. dry heat shrinkage is smaller than ⁇ 1.0%.
- PET polyethylene terephthalate
- the above-mentioned problems can be solved by the invention of a method for producing the thermal-adhesive bicomponent fiber, which comprises cold-drawing an undrawn yarn of a bicomponent fiber taken out at a spinning speed of not higher than 1300 m/min, by from 1.05 to 1.30 times, and then relaxing and thermally shrinking it at a temperature higher by at least 10° C. than both the glass transition point of the thermal-adhesive resin component and the glass transition point of the fiber-forming resin component.
- a nonwoven fabric formed of the low-modulus, self-extensible thermal-adhesive bicomponent fiber of the invention can have a soft feel based on the low-modulus characteristic and the self-extensibility of the thermal-adhesive bicomponent fiber itself.
- the nonwoven fabric may have a high adhesive strength intrinsic to a thermal-adhesive nonwoven fabric formed of only thermal-adhesive bicomponent fibers.
- the invention is a bicomponent fiber comprising a fiber-forming resin component and a thermal-adhesive resin component. More precisely, the invention is a low-modulus, self-extensible thermal-adhesive bicomponent fiber that comprises PET as the fiber-forming resin component thereof and a crystalline thermoplastic resin having a melting point lower by at least 20° C. than that of PET as the thermal-adhesive resin component thereof.
- the melting point difference between PET and the thermal-adhesive resin component is less than 20° C., then it is unfavorable since the fiber-forming resin component may also melt in a step of melting and adhering the thermal-adhesive resin component and since a nonwoven fabric or a fiber structure having a high adhesive strength could not be produced.
- the melting point difference range is from 20 to 180° C.
- the bicomponent fiber may be produced by obtaining an undrawn yarn of the fiber at a spinning speed of from 100 to 1300 m/min, then cold-drawing it by from 1.05 to 1.30 times, and further relaxing and thermally shrinking it at a temperature higher by at least 10° C. than both the glass transition point (hereinafter this is referred to as Tg) of PET and Tg of the thermoplastic crystalline resin constituting the thermal-adhesive resin component and lower by at least 10° C. than the melting point of the thermal-adhesive resin component, preferably at a temperature higher by at least 20° C. than Tg of the two and lower by at least 20° C.
- Tg glass transition point
- the temperature higher than both Tg of PET and Tg of the thermoplastic crystalline resin of the thermal-adhesive resin component is, in many cases, a temperature higher than Tg (about 70° C.) of PET. Accordingly, it is desirable that the relaxing and thermal-shrinking treatment is effected at a temperature not lower than 80° C., more preferably not lower than 90° C. Even more preferably, the temperature is not lower than 100° C.
- the relaxing and thermal-shrinking treatment may be attained in hot air or in hot water. This is because, in the invention, the melting point of the crystalline thermoplastic resin that constitutes the thermal-adhesive resin component is lower by at least 20° C.
- Tg of the thermoplastic crystalline resin constituting the thermal-adhesive resin component is mostly lower than Tg of PET.
- the relaxing and thermal-shrinking treatment may be attained according to a method of leading a drawn tow to pass through hot air under no tension at all, or according to a method of overfeeding it in hot air at from 0.5 to 0.85 times under no tension given thereto.
- the low-drawn fiber may form crystals having a crystal axis inclined in random directions from the fiber axis direction, while shrunk in the fiber axis direction by the residual strain therein. Further, when the fiber is heated, then the crystal size of the crystals constituting it increases, and therefore when the crystals existing near to each other are kept in contact with each other, the crystal size may further increase. Accordingly, there may occur a phenomenon that the fiber would seemingly extend. This phenomenon is referred to as self-extension, and the bicomponent fiber of the invention exhibit the self-extensibility.
- the self-extension degree of the fiber increases when the draw ratio is higher than 1.00 time, and the self-extension degree thereof reaches a maximum level when the draw ratio is 1.20 times.
- the fiber For expressing the self-extensibility of the fiber, it may be a key point how the orientation of the crystals constituting the fiber could be kept random relative to the fiber axis before the crystals grow thick, and for it, therefore, the fiber may well be greatly shrunk before its crystallization. Accordingly, in a step of drawing it, when the fiber is cold-drawn by from 1.05 to 1.30 times at a drawing temperature further lower than the drawing temperature in hot drawing treatment to be effected by the use of hot water, steam or a plate heater, then the residual strain in the amorphous part of the fiber may be increased with inhibiting the orientation crystallization by the drawing, and therefore this is favorable for obtaining the bicomponent fiber of the invention.
- Cold-drawing as referred to herein includes not only drawing at room temperature but also drawing in an atmosphere positively cooled to a temperature lower than room temperature. Concretely, it includes a method of drawing under no heat at room temperature, or in a coolant cooled to a temperature lower than room temperature. More concretely, a method of cold-drawing in air or drawing in a cold water bath is preferred.
- the coolant includes not only air and water mentioned above, but also vapors such as rare gas, nitrogen or carbon dioxide inert to the fiber-forming resin component and the thermal-adhesive resin component that form the bicomponent fiber of the invention without swelling or dissolving them, as well as other liquids such as various oils not dissolving PET and the thermal-adhesive resin component; and the coolant may be suitably selected from them.
- the temperature of the coolant in cold-drawing may be from 0 to 30° C., preferably from 10 to 25° C.
- the draw ratio must fall within a range of from 1.05 to 1.30 times.
- the 100% elongation tensile strength of the bicomponent fiber could be at most 1.0 cN/dtex but the self-extension degree thereof is less than 1.0% and the fiber could not attain the object of the invention.
- the draw ratio is more than 1.30 times, then the 100% elongation tensile strength is more than 1.0 cN/dtex.
- a thermal-adhesive nonwoven fabric is formed of a web of completely, 100-percentage the thermal-adhesive bicomponent fibers of the type, then the nonwoven fabric could not have the excellent drapability that is the object of the invention.
- the drawing temperature is preferably lower; and when cold water is used as the coolant, then the drawing temperature is more preferably from 0° C. to 25° C.
- the drawing operation at such a low temperature greatly contributes to increasing the thermal shrinkage of the obtained bicomponent fiber, since the crystallization of the fiber owing to orientation and heat generation may be prevented by removing the heat generated by the bicomponent fiber during drawing.
- the 100% elongation tensile strength of the bicomponent fiber of the invention must be from 0.3 to 1.0 cN/dtex.
- the spinning speed must be at most 1300 m/min, preferably at most 1200 m/min, even more preferably from 100 to 1100 m/min.
- the spinning speed is higher than 1300 m/min, then the orientation of the undrawn yarn may increase but the effect of expressing a high self-extension degree through low-drawing treatment, which is a characteristic of the bicomponent fiber of the invention, may decrease.
- the low-modulus, self-extensible thermal-adhesive bicomponent fiber of the invention may be in any form of a side-by-side laminated bicomponent fiber of a fiber-forming resin component and a thermal-adhesive resin component, or a core-sheath bicomponent fiber where the core component is a fiber-forming resin component and the sheath component is a thermal-adhesive resin component.
- a core-sheath bicomponent fiber where the core component is a fiber-forming resin component and the sheath component is a thermal-adhesive resin component, since the thermal-adhesive resin component may be disposed in all directions vertical to the fiber axis direction of the fiber.
- the core-sheath bicomponent fiber includes a concentric core-sheath bicomponent fiber and an eccentric core-sheath bicomponent fiber.
- thermoplastic resin For the thermal-adhesive resin component, a crystalline thermoplastic resin must be selected. When an amorphous thermoplastic resin is selected for it, then the molecular chains oriented during spinning may be disoriented while melted and therefore the fiber may thereby greatly shrink.
- Preferred examples of the crystalline thermoplastic resin are polyolefin resin and crystalline copolyester.
- the polyolefin resin examples include crystalline polyolefin resins such as crystalline polypropylene, high-density polyethylene, middle-density polyethylene, low-density polyethylene, linear low-density polyethylene.
- the crystalline thermoplastic resin to constitute the thermal-adhesive resin component may be a copolyolefin prepared through copolymerization of the above-mentioned polyolefin with at least one unsaturated compound selected from ethylene, propylene, butene-1, pentene-1, or acrylic acid, methacrylic acid, maleic acid, fumaric acid, itaconic acid, crotonic acid, isocrotonic acid, mesaconic acid, citraconic acid or himic acid or their esters or acid anhydrides.
- Preferred examples of the crystalline copolyester for the thermal-adhesive resin component are mentioned below.
- Preferred for it are copolyesters prepared through copolymerization of an alkylene terephthalate with any of substituted or sulfonic acid group-having aromatic dicarboxylic acids such as isophthalic acid, naphthalene-2,6-dicarboxylic acid, sodium 5-sulfoisophthalate or potassium 5-sulfoisophthalate, aliphatic dicarboxylic acids such as adipic acid or sebacic acid, alicyclic dicarboxylic acids such as 1,4-cyclohexamethylene-dicarboxylic acid, ⁇ -hydroxyalkylcarboxylic acid, aliphatic diols such as polyethylene glycol or polytetramethylene glycol, or alicyclic diols such as cyclohexamethylene-1,4-dimethanol, so that the formed copolyester may have an intended
- the alkylene terephthalate may be a polyester obtained starting from 1 to 3 combinations selected from terephthalic acid or its ester-forming derivatives as the essential dicarboxylic acid component, and ethylene glycol, diethylene glycol, trimethylene glycol, tetramethylene glycol, hexamethylene glycol or their derivatives as the essential diol component.
- the ester-forming derivative includes lower dialkyl esters having from 1 to 6 carbon atoms, and a lower diaryl esters having from 6 to 10 carbon atoms.
- the ester-forming derivative is are dimethyl ester or diphenyl ester.
- the copolymerization ratio of these components is variously regulated, depending on the copolymerization components, so that the formed copolymer may have a desired melting point. Preferably, it is from 5 to 50 mol %.
- the thermal-adhesive resin component may be a polymer blend of at least two crystalline thermoplastic resins having a melting point lower than that of PET by at least 20° C., and it may contain an amorphous thermoplastic resin and a crystalline thermoplastic resin of which the melting point difference between PET is less than 20° C. within a range not greatly interfering with the adhesiveness and the low thermal shrinkability of the fiber.
- the breaking elongation of the low-modulus, self-extensible thermal-adhesive bicomponent fiber of the invention must be within a range of from 130 to 600%, preferably from 170 to 450%.
- the breaking elongation of the bicomponent fiber of the invention is less than 130%, then the orientation of the thermal-adhesive resin component is too high and the adhesiveness of the fiber may be poor and therefore the nonwoven fabric strength lowers.
- the breaking elongation of the bicomponent fiber of the invention is more than 600%, then the strength of the bicomponent fiber is substantially too low and the strength of the thermal-adhesive nonwoven fabric could not be increased.
- the breaking elongation of the bicomponent fiber For controlling the breaking elongation of the bicomponent fiber to fall within a range of from 130 to 600%, herein employable is a method of suitably selecting the nozzle orifice diameter through which the polymer is spun out and the spinning speed, though varying depending the type of the polymers to be combined and on the melt viscosity thereof. Above all, the method of suitably selecting the spinning speed is more effective. Further in the invention, in order that the breaking elongation is controlled to fall within the above-mentioned range, it is desirable that the spinning speed is controlled within a range of from 100 to 1300 m/min, though depending on the type of the polymers and the combination thereof. When the spinning speed is higher, then the breaking elongation maybe smaller; and when the spinning speed is lower, then the breaking elongation may be higher.
- the low-modulus, self-extensible thermal-adhesive bicomponent fiber of the invention is characterized in that its 120° C. dry heat shrinkage is smaller than ⁇ 1.0%. Not specifically defined, the lowermost limit of the dry heat shrinkage may be ⁇ 20.0% or so.
- the bicomponent fibers therein may self-extend before thermal adhesion, thereby further increasing the thickness thereof in the thickness direction and, in addition, the low-modulus fibers may be oriented in the thickness direction of the nonwoven fabric, and therefore, when the compression in the thickness direction thereof is taken into consideration, then the nonwoven fabric may have a soft feel, and when it is used as the surface component of sanitary materials, then the pressing feel to users' skin in the vertical direction of the fabric may be reduced and further the drapability of the fabric may be bettered.
- the thermal-adhesive bicomponent fiber of the invention preferably has a concentric core/sheath cross section or an eccentric core/sheath cross section.
- the bicomponent fiber When the bicomponent fiber has a side-by-side cross section and when it is formed into a web, then the web may crimp three-dimensionally and may be thereby greatly shrunk. In such a case, in addition, the web adhesion strength may be small and the effect of the invention may be reduced in some degree.
- the bicomponent fiber may be a solid fiber or a hollow fiber.
- a round cross section may have a modified cross section, for example, an oval cross section, a multi-leaved cross section such as a 3-to 8-leaved cross section, or a multi-angular cross section such as 3- to 8-angular cross section.
- the multi-leaved cross section is meant to indicate a cross-sectional profile that has plural protruding leaves extending from the center part toward the outer peripheral direction.
- the fineness of the thermal-adhesive bicomponent fiber of the invention may be selected depending on the object of the fiber. Not specifically limited, it may be generally from 0.01 to 500 dtex or so. By controlling the diameter of the orifice through which resin is jetted out in spinning, the fiber fineness range may be attained.
- the ratio of the fiber-forming resin component and the thermal-adhesive resin component may be selected in accordance with the necessary strength, bulkiness or thermal shrinkage of the intended nonwoven fabric or fiber structure.
- the ratio by weight of the fiber-forming resin component to the thermal-adhesive resin component is from 10/90 to 90/10 or so.
- the fiber may be in any form of multifilament, monofilament, staple fiber, chop or tow, depending on the use and the object thereof.
- the fiber is preferably crimped to a suitable degree in order to make the fiber have good card-through runnability.
- the thermal-adhesive bicomponent fiber of the invention is especially effective for improving the drapability the nonwoven fabric having a random fiber structure. Accordingly, the self-extensible thermal-adhesive bicomponent fibers of the invention may be formed into a nonwoven fabric by themselves.
- any other fibers may be mixed with any other fibers to produce a nonwoven fabric.
- employable is any of a carding method, an air-laid method or a wet sheet-making method, in which the fibers are formed into a web, and then predetermined heat is applied thereto in a hot air drier or by an embossing roll, thereby thermally adhering the fibers together to give a soft thermal-adhesive nonwoven fabric of good drapability having a cantilever value of at most 10 cm.
- the intrinsic viscosity of the polyester was determined as follows: A predetermined amount of the polymer was weighed, then dissolved in o-chlorophenol to have a concentration of 0.012 g/ml, and its viscosity was determined at 35° C. according to an ordinary method.
- the melt flow rate was determined according to JIS K-7210, Condition 4 (temperature 190° C., load 21.18 N). Briefly, polymer pellets before melt spinning were sampled, and the melt flow rate of the sample was measured.
- the melting point and the glass transition point of the polymer were measured, using TA Instrument Japan's Thermal Analyst 2200, at a heating rate of 20° C./min.
- the fineness of the bicomponent fiber was measured according to the method described in JIS L-1015:2005, 8.5.1A Method.
- the breaking tensile strength, the breaking elongation and the 100% elongation tensile strength of the bicomponent fiber were measured according to the method described in JIS L-1015:2005, 8.7.1 Method.
- the breaking tensile strength, the breaking elongation and the 100% elongation tensile strength of the bicomponent fiber of the invention may vary; and therefore, when the breaking tensile strength, the breaking elongation and the 100% elongation tensile strength of the fiber are measured as a single yarn thereof, then the number of the points of the sample to be analyzed must increase.
- the number of the points for measurement is preferably at least 50.
- the number of the points for measurement was 50, and the data of all those points were averaged to give a mean value for the intended physical data.
- the breaking tensile strength and the breaking elongation the tensile strength at a point of 100% elongation in the load-stress curve is read, and this is the 100% elongation tensile strength value.
- the number of crimps and the percentage of crimps of the bicomponent fiber were determined according to the method described in JIS L-1015:2005, 8.12.1 and 8.12.2 Methods.
- the 120° C. dry heat shrinkage of the bicomponent fiber was measured according to JIS L-1015:2005, 8.15 b), at 120° C.
- the bicomponent fiber web area shrinkage was determined according to the following method: A card web having a basis weight of 30 g/m 2 was produced, comprising 100% thermal-adhesive bicomponent staple fibers cut to have a fiber length of 51 mm; and the web was cut into a 25 cm ⁇ 25 cm piece. Next, the thus-cut web was heat-treated, as left in a hot air drier (Satake Chemical Machinery's hot air circulating constant-temperature drier: 41-S4) kept at 150° C., for 2 minutes, thereby thermally adhering the bicomponent fibers together. After thus adhered, the length and the width dimension of the web were measured, and these were multiplied to compute the area A 1 . According to the following formula, the area shrinkage was obtained.
- a hot air drier Shitake Chemical Machinery's hot air circulating constant-temperature drier: 41-S4
- the cantilever value was measured according to the following method: On a horizontal bed having a surface smooth and having a 45-degree inclined surface at its one end, the sample test piece is put along the bed. Next, one end of the test piece is accurately registered to one end of the horizontal bed on its inclined side (joint part of the 45-degree inclined surface and the horizontal bed), and the position of the other end of the test piece is measured as the length thereof from one end of the 45-degree inclined surface of the bed. Since the length of the test piece is 25 cm, this should be 25 cm.
- test piece is gradually slid in the inclined direction according to a suitable method, and when the center point of one end of the test piece has reached the same surface as the inclined surface, then the position of the other end is measured as the length from one end of the 45-degree inclined surface.
- This value is referred to as A.
- the difference between 25 cm and A is the cantilever value of the sample. 5 sample pieces are thus analyzed on both their surface and back, and the mean value of the obtained data indicates the cantilever value of the test sample. Test samples having a larger cantilever value are harder, and their drapability are worse; and those having a smaller cantilever value are softer, and their drapability are better.
- core component fiber-forming resin component
- sheath component thermal-adhesive resin component
- HDPE high-density polyethylene
- the undrawn yarn was cold-drawn by 1.20 times, and then the cold-drawn yarn was dipped in an aqueous solution of an oily agent of potassium lauryl phosphate/polyoxyethylene-modified silicone of 80 wt. %/20 wt. %. Then, using a staffing box-equipped forced crimper, this was mechanically crimped at 11 crimps/25 mm.
- the crimped yarn was subjected to relaxing and thermal shrinkage treatment and drying treatment with hot air at 110° C., higher by 40° C. than the glass transition point of the core component, under no tension, and then cut into pieces having a fiber length of 51 mm.
- the single yarn fineness of the thus-obtained thermal-adhesive bicomponent fiber was 6.4 dtex, the breaking tensile strength thereof was 0.76 cN/dtex, the breaking elongation thereof was 442%, the 100% elongation tensile strength thereof was 0.37 cN/dtex, and the 120° C. dry heat shrinkage thereof was ⁇ 2.6%.
- the web area shrinkage of the web of 100% the thermal-adhesive bicomponent fibers was ⁇ 7.5%, the nonwoven fabric strength thereof was 15.1 kg/g, and the cantilever value thereof was 8.50 cm.
- a bicomponent fiber was produced under the same condition as in Example 1, for which, however, the undrawn yarn obtained in Example 1 was drawn by 2.5 times in hot water at 70° C., and then further drawn by 1.2 times in hot water at 90° C.
- the single yarn fineness of the thus-obtained thermal-adhesive bicomponent fiber was 2.6 dtex, the breaking tensile strength thereof was 2.49 cN/dtex, the breaking elongation thereof was 37.1%, and the 120° C. dry heat shrinkage thereof was 2.5 W. Since the elongation of the thermal-adhesive bicomponent fiber was less than 100%, the 100% elongation tensile strength thereof could not be measured.
- the web area shrinkage of the web of 100% the thermal-adhesive bicomponent fibers was 5%, the nonwoven fabric strength thereof was 20.5 kg/g, and the cantilever value thereof was 12.90 cm.
- a bicomponent fiber was produced under the same condition as in Example 1, for which, however, the undrawn yarn was not drawn.
- the single yarn fineness of the thus-obtained thermal-adhesive bicomponent fiber was 6.47 dtex, the breaking tensile strength thereof was 0.60 cN/dtex, the breaking elongation thereof was 460.3%, the 100% elongation tensile strength thereof was 0.37 cN/dtex, and the 120° C. dry heat shrinkage thereof was ⁇ 0.7%.
- the web area shrinkage of the web of 100% the thermal-adhesive bicomponent fibers was ⁇ 1.45%, the nonwoven fabric strength thereof was 14.5 kg/g, and the cantilever value thereof was 7.90 cm.
- a bicomponent fiber was produced under the same condition as in Example 1, for which, however, the draw ratio in cold drawing was 1.1 times.
- the single yarn fineness of the thus-obtained thermal-adhesive bicomponent fiber was 6.41 dtex, the breaking tensile strength thereof was 0.65 cN/dtex, the breaking elongation thereof was 424.1%, the 100% elongation tensile strength thereof was 0.41 cN/dtex, and the 120° C. dry heat shrinkage thereof was ⁇ 1.9%.
- the web area shrinkage of the web of 100% the thermal-adhesive bicomponent fibers was ⁇ 5.6%, the nonwoven fabric strength thereof was 16.5 kg/g, and the cantilever value thereof was 8.10 cm.
- a bicomponent fiber was produced under the same condition as in Example 1, for which, however, the draw ratio in cold drawing was 1.30 times.
- the single yarn fineness of the thus-obtained thermal-adhesive bicomponent fiber was 6.22 dtex, the breaking tensile strength thereof was 0.72 cN/dtex, the breaking elongation thereof was 381.8%, the 100% elongation tensile strength thereof was 0.46 cN/dtex, and the 120° C. dry heat shrinkage thereof was ⁇ 2.0%.
- the web area shrinkage of the web of 100% the thermal-adhesive bicomponent fibers was ⁇ 6.1%, the nonwoven fabric strength thereof was 17.1 kg/g, and the cantilever value thereof was 8.90 cm.
- a bicomponent fiber was produced under the same condition as in Example 1, for which, however, the draw ratio in cold drawing was 1.4 times.
- the single yarn fineness of the thus-obtained thermal-adhesive bicomponent fiber was 6.14 dtex, the breaking tensile strength thereof was 0.75 cN/dtex, the breaking elongation thereof was 346.8%, the 100% elongation tensile strength thereof was 0.53 cN/dtex, and the 120° C. dry heat shrinkage thereof was ⁇ 0.6%.
- the web area shrinkage of the web of 100% the thermal-adhesive bicomponent fibers was ⁇ 1.8%, the nonwoven fabric strength thereof was 18.4 kg/g, and the cantilever value thereof was 10.1 cm.
- a bicomponent fiber was produced under the same condition as in Example 1, for which, however, the undrawn yarn was cold-drawn while cooled in a water bath having a controlled temperature of 20° C.
- the single yarn fineness of the thus-obtained thermal-adhesive bicomponent fiber was 6.52 dtex, the breaking tensile strength thereof was 0.65 cN/dtex, the breaking elongation thereof was 459.3%, the 100% elongation tensile strength thereof was 0.39 cN/dtex, and the 120° C. dry heat shrinkage thereof was ⁇ 3.2%.
- the web area shrinkage of the web of 100% the thermal-adhesive bicomponent fibers was ⁇ 9.5%, the nonwoven fabric strength thereof was 15.3 kg/g, and the cantilever value thereof was 8.13 cm.
- a bicomponent fiber was produced under the same condition as in Example 1, for which, however, the yarn was subjected to relaxing and thermal shrinking treatment and heat treatment in a hot water bath at 95° C. with overfeeding it at 0.7 times, but thereafter it was not dried with hot air.
- the single yarn fineness of the thus-obtained thermal-adhesive bicomponent fiber was 6.58 dtex, the breaking tensile strength thereof was 0.68 cN/dtex, the breaking elongation thereof was 443.3%, the 100% elongation tensile strength thereof was 0.41 cN/dtex, and the 120° C. dry heat shrinkage thereof was ⁇ 3.9%.
- the web area shrinkage of the web of 100% the thermal-adhesive bicomponent fibers was ⁇ 11.4%
- the nonwoven fabric strength thereof was 14.9 kg/g
- the cantilever value thereof was 8.90 cm.
- the core component fiber-forming resin component
- PET polyethylene terephthalate
- sheath component thermal-adhesive resin component
- crystalline copolyester polyethylene terephthalate prepared through copolymerization with 20 mol % of isophthalic acid and 50 mol % of tetramethylene glycol
- the web area shrinkage of the web of 100% the thermal-adhesive bicomponent fibers (however, the thermal-adhering temperature was changed to 180° C.) was ⁇ 11.2%, the nonwoven fabric strength thereof was 12.3 kg/g, and the cantilever value thereof was 8.30 cm.
- the low-modulus, self-extensible thermal-adhesive bicomponent fiber of the invention comprises PET as the fiber-forming resin component, and since the spinning speed in producing it is low, fiber breakage frequency during spinning is extremely low. Further, when the bicomponent fiber is used in producing a nonwoven fabric, then the produced nonwoven fabric is bulky and has high adhesiveness, high drapability and good feel.
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PCT/JP2007/060084 WO2007132905A1 (ja) | 2006-05-12 | 2007-05-10 | 熱接着性複合繊維及びその製造方法 |
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-
2006
- 2006-05-12 JP JP2006133794A patent/JP4820211B2/ja not_active Expired - Fee Related
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2007
- 2007-05-10 RU RU2008148973A patent/RU2440447C2/ru not_active IP Right Cessation
- 2007-05-10 KR KR1020087029803A patent/KR101357446B1/ko not_active IP Right Cessation
- 2007-05-10 DE DE200760006180 patent/DE602007006180D1/de active Active
- 2007-05-10 AT AT07743519T patent/ATE466122T1/de not_active IP Right Cessation
- 2007-05-10 EP EP20070743519 patent/EP2022877B1/en not_active Not-in-force
- 2007-05-10 WO PCT/JP2007/060084 patent/WO2007132905A1/ja active Application Filing
- 2007-05-10 CN CN200780017154XA patent/CN101443491B/zh not_active Expired - Fee Related
- 2007-05-10 US US12/300,428 patent/US20090227166A1/en not_active Abandoned
- 2007-05-11 TW TW96116869A patent/TWI410540B/zh not_active IP Right Cessation
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2008
- 2008-10-29 MY MYPI20084316A patent/MY151200A/en unknown
-
2009
- 2009-06-04 HK HK09105039A patent/HK1127376A1/xx not_active IP Right Cessation
- 2009-08-13 HK HK09107464A patent/HK1129431A1/xx not_active IP Right Cessation
Cited By (10)
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US20150020435A1 (en) * | 2008-10-14 | 2015-01-22 | Y.G.K Co., Ltd. | Fishing line comprising integrated composite yarn comprising short fiber |
US9756839B2 (en) * | 2008-10-14 | 2017-09-12 | Y.G.K. Co., Ltd. | Fishing line comprising integrated composite yarn comprising short fiber |
WO2013181309A2 (en) * | 2012-05-31 | 2013-12-05 | Wm. T. Burnett Ip, Llc | Nonwoven composite fabric and panel made therefrom |
WO2013181309A3 (en) * | 2012-05-31 | 2014-03-06 | Wm. T. Burnett Ip, Llc | Nonwoven composite fabric and panel made therefrom |
US9689097B2 (en) | 2012-05-31 | 2017-06-27 | Wm. T. Burnett Ip, Llc | Nonwoven composite fabric and panel made therefrom |
US9504767B2 (en) | 2012-09-28 | 2016-11-29 | Unicharm Corporation | Absorbent article |
US9724249B2 (en) | 2012-09-28 | 2017-08-08 | Unicharm Corporation | Absorbent article |
US10058808B2 (en) | 2012-10-22 | 2018-08-28 | Cummins Filtration Ip, Inc. | Composite filter media utilizing bicomponent fibers |
US10391434B2 (en) | 2012-10-22 | 2019-08-27 | Cummins Filtration Ip, Inc. | Composite filter media utilizing bicomponent fibers |
JP2017008431A (ja) * | 2015-06-19 | 2017-01-12 | Tmtマシナリー株式会社 | 紡糸引取装置 |
Also Published As
Publication number | Publication date |
---|---|
MY151200A (en) | 2014-04-30 |
JP4820211B2 (ja) | 2011-11-24 |
RU2008148973A (ru) | 2010-06-20 |
CN101443491A (zh) | 2009-05-27 |
JP2007303035A (ja) | 2007-11-22 |
EP2022877B1 (en) | 2010-04-28 |
WO2007132905A1 (ja) | 2007-11-22 |
HK1129431A1 (en) | 2009-11-27 |
TWI410540B (zh) | 2013-10-01 |
EP2022877A1 (en) | 2009-02-11 |
KR101357446B1 (ko) | 2014-02-03 |
KR20090010229A (ko) | 2009-01-29 |
TW200809022A (en) | 2008-02-16 |
EP2022877A4 (en) | 2009-05-13 |
ATE466122T1 (de) | 2010-05-15 |
HK1127376A1 (en) | 2009-09-25 |
CN101443491B (zh) | 2011-11-16 |
DE602007006180D1 (de) | 2010-06-10 |
RU2440447C2 (ru) | 2012-01-20 |
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