US1575627A - Electrode for use in the electrolytic evolution of gases - Google Patents

Electrode for use in the electrolytic evolution of gases Download PDF

Info

Publication number
US1575627A
US1575627A US755083A US75508324A US1575627A US 1575627 A US1575627 A US 1575627A US 755083 A US755083 A US 755083A US 75508324 A US75508324 A US 75508324A US 1575627 A US1575627 A US 1575627A
Authority
US
United States
Prior art keywords
gases
electrode
electrodes
gas
block
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
US755083A
Inventor
Heinze Ernst
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Bayer AG
Original Assignee
Farbenfabriken Vorm Friedr Bayer and Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Farbenfabriken Vorm Friedr Bayer and Co filed Critical Farbenfabriken Vorm Friedr Bayer and Co
Priority to US755083A priority Critical patent/US1575627A/en
Application granted granted Critical
Publication of US1575627A publication Critical patent/US1575627A/en
Priority to FR654417D priority patent/FR654417A/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Images

Classifications

    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25BELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B11/00Electrodes; Manufacture thereof not otherwise provided for
    • C25B11/02Electrodes; Manufacture thereof not otherwise provided for characterised by shape or form
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25BELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B11/00Electrodes; Manufacture thereof not otherwise provided for
    • C25B11/02Electrodes; Manufacture thereof not otherwise provided for characterised by shape or form
    • C25B11/03Electrodes; Manufacture thereof not otherwise provided for characterised by shape or form perforated or foraminous

Definitions

  • This invention relates to an electrode for use in the electrolytic evolution of gases.
  • an electrode is provided with internal borings. or passages leading to the underside thereof, which serve to collect and lead olf any gas set free on the'underside of the electrode. ,y
  • Figure 1 is a longitudinal section
  • Figure 2 a transverse section
  • Figure 3 a plan of an electrolytic cell.
  • Figure 4 shows a modification.
  • a is one electrode consisting of a block of graphite, for example, b a trough and c the other electrode, while el 'indicates the level of the electrolyte.
  • the block a is a series of passages e which receive the gas evolved at the underside of the block; the gas collects in a communicating passage f and passes away through a pipe g.v 4
  • each passage e may be replaced by a number of .borings.
  • the block is formed of a number of separate portions h threaded on a web z' clamped together.
  • Electrodes in accordance with this invention are differentiated from those of known construction in that the side wall and cover of the cell are formed by the electrode, while another and very important advantage in practice is that when the gas evolved is eX- plosive, there is no 'danger of explosion.
  • I claim 1 In an electrolytic cell for production of gases, a pair of electrodes in gas-tight spaced relation, one of said electrodes having within the same a ber and passages'leading thereto from the space .between the electrodes.
  • a pair of electrodes in gas-tight spaced gas collecting chamrelation one of said electrodes having within the same a number of passages leading l from the space between the electrodes and a cross passage connecting said gas passages and providing a collectingw chamber.
  • a pair of electrodes one above the other, in gas-tight spaced relation, the upper of said electrodes having wlthin the same la number of upwardly directed pas sages leading from the space between the electrodes, a collecting chamber' to whichv the upper ends of said passages are connected and means passing through the other.
  • a lower electrode and an upper electrode in gas-tight spaced relation said upper electrode comprising a block forming A"a cap surmounting said lower electrode and having within the same ⁇ passages leading from the space collecting the gas produced.
  • a lower electrode and an upper electrode in gas-tight spaced relation said upper electrode comprising a cap surmounting said lower electrode and having within the same a gas collecting chamber and passages leading thereto from the space between the electrodes.
  • a lower electrode and an upper electrode in gas-tight spaced relation said upper electrode comprising a graphitic block forming a cap surmounting said lower electrode and having within the same lpassages leading from the space between the e ectroes for collecting the gas produced.
  • An electrolytic cell for production of gases comprising a lower electrode, a support an upper electrode carried 'by said support tion to said lower electrode, said upper elecbetween the electrodes for trode comprising a cap surmounting saidl 'production of gases comprising a plain block y35 lower electrode and having within the same passages leading from the space between the electrodes for collecting the gas produced.
  • a pair of electrodes in gas-tight spaced relation, one of said electrodes comprising a ⁇ Unlock composed of assembled elements, each of said elements having a reduced portion registering-with a similar'reduced portion in an adjacent element to provide passages leading from the space between the electrodes, and each of said elements having ⁇ also a ⁇ cross passage registering with the cross passage of an adjacent element to provide a gas collecting chamber at the ends of the first named passages remote from the space between the electrodes.
  • An electrode for use in the electrolytic production of gases comprising a plain block of a substance having several borings andl passages extending through the block serving to collect the gas produced at the under side of the block and suitable pipes tolead olf the collected gases.
  • An electrode for use in the electrolytic production of gases comprising a plain block of carbon having several borings and passages extending through the' block serving to collect the gas produced at the under side of the block and suitable pipes to lead 'oil the collected gases.
  • An electrode for use in the electrolytic of graphite having several borings and passages extending through the block serving to collect the gas produced at the under side of the block and suitable pipes to lead off the collected gases.
  • An electrode for use in the electrolytic production of gases comprising a plain block of a substanceymade up of a number 0i' sepi arate portions having several borings and passages extending through the block serving to collecty the gas produced at the under 'side of the block and suitable pipes to lead off the collected gases.
  • An electrode for use in the electrolytic production of gases comprising a plain block of carbon made up of a number of se arate portions, having several borings an passageso extending through the block serving to collect the gas produced at the under side ofthe block and suitable pipes to lead oi 'the collected gases.
  • An electrode for use in the electrolytic production of gases comprising a plain block of graphite made up of a number of separate portion-s, having several borings and passages extending through the block serving to collect the gas produced at the under side of the block and suitable pipes to lead ofi' the collected gases.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Electrodes For Compound Or Non-Metal Manufacture (AREA)

Description

March 9 1926.
E. HEINZE 'ELECTRODE FOR USE 1N THE ELEcTRoLYTIc EVOLUTION or' GASES Filed Dec. 10 1924 I l I ll l Il l IIIIIIIIIIIIIIUHHHU n I l l I IIIIIIIMII Patented Mar. 9, 1926.
UNITED .STATES PATENT OFFICE.
ERNs'i` HEINZE, oE LEVERKUSEN, NEAR coLoeNE, GERMANY, AssIGNoR rro FARBEN- EABRIKEN VORM. ERIEDR. BAYER AND oo., 0E LEVERKUSEN, NEAR COLOGNE-0N- THE-REINE, GERMANY.
ELECTRODE FOR USE IN THE ELEGTEOLYTIC EVOLUTION OF GASES.
Application led December 10, 1924. Serial No. 755,083.
To all 'whom t may concern:
l Be it known that I, ERNST HEINZE, a citizen of Germany, residing at Leverkusen, near Cologne, in the State of lPrussia, Germany, have invented new and useful Improvements in Electrodes for Use in the Electrolytic Evolution of Gases, of which the following is a specification.
This invention relates to an electrode for use in the electrolytic evolution of gases.
According to this invention an electrode is provided with internal borings. or passages leading to the underside thereof, which serve to collect and lead olf any gas set free on the'underside of the electrode. ,y
The invention is illustrated in the accompanying diagrammatic figures of the draw# ing, of which Figure 1 is a longitudinal section, Figure 2 a transverse section and Figure 3 a plan of an electrolytic cell. Figure 4 shows a modification.
Referring to Figures 1 to 8, a is one electrode consisting of a block of graphite, for example, b a trough and c the other electrode, while el 'indicates the level of the electrolyte.
In the block a is a series of passages e which receive the gas evolved at the underside of the block; the gas collects in a communicating passage f and passes away through a pipe g.v 4
The shape and arrangement of the borings or passages may vary, for example each passage e may be replaced by a number of .borings.
Referringto Figure 4, the block is formed of a number of separate portions h threaded on a web z' clamped together.
Electrodes in accordance with this invention are differentiated from those of known construction in that the side wall and cover of the cell are formed by the electrode, while another and very important advantage in practice is that when the gas evolved is eX- plosive, there is no 'danger of explosion.
I claim 1. In an electrolytic cell for production of gases, a pair of electrodes in gas-tight spaced relation, one of said electrodes having within the same a ber and passages'leading thereto from the space .between the electrodes.
2. In an electrolytic cell for production of gases, a pair of electrodes in gas-tight spaced gas collecting chamrelation, one of said electrodes having within the same a number of passages leading l from the space between the electrodes and a cross passage connecting said gas passages and providing a collectingw chamber.
3. In an electrolytic cell for production of gases, a pair of'electrodes, one above the other, in gas-tight spaced relation, the upper of said electrodes having within the same a gas collecting chamber and passages leading thereto from the space between the electrodes. e
v4. In an velectrolytic cell for production of gases, a pair of electrodes, one above the other, in gas-tight spaced relation, the upper of said electrodes having wlthin the same la number of upwardly directed pas sages leading from the space between the electrodes, a collecting chamber' to whichv the upper ends of said passages are connected and means passing through the other.
electrode for permitting withdrawal of the gas at a point beneath the cell.
5. In an electrolytic cell for production o-f gases, a lower electrode and an upper electrode in gas-tight spaced relation, said upper electrode comprising a block forming A"a cap surmounting said lower electrode and having within the same `passages leading from the space collecting the gas produced.
6.- In an electrolytic -cell for production of gases, a lower electrode and an upper electrode in gas-tight spaced relation, said upper electrode comprising a cap surmounting said lower electrode and having within the same a gas collecting chamber and passages leading thereto from the space between the electrodes.
7. In an electrolytic cell for lproduction of gases, a lower electrode and an upper electrode in gas-tight spaced relation, said upper electrode comprising a graphitic block forming a cap surmounting said lower electrode and having within the same lpassages leading from the space between the e ectroes for collecting the gas produced.
8. An electrolytic cell for production of gases comprising a lower electrode, a support an upper electrode carried 'by said support tion to said lower electrode, said upper elecbetween the electrodes for trode comprising a cap surmounting saidl 'production of gases comprising a plain block y35 lower electrode and having within the same passages leading from the space between the electrodes for collecting the gas produced.
9. In an electrolytic cell for production of gases, a pair of electrodes in gas-tight spaced relation, one of said electrodes comprising a `Unlock composed of assembled elements, each of said elements having a reduced portion registering-with a similar'reduced portion in an adjacent element to provide passages leading from the space between the electrodes, and each of said elements having `also a\ cross passage registering with the cross passage of an adjacent element to provide a gas collecting chamber at the ends of the first named passages remote from the space between the electrodes.
10. An electrode for use in the electrolytic production of gases comprising a plain block of a substance having several borings andl passages extending through the block serving to collect the gas produced at the under side of the block and suitable pipes tolead olf the collected gases.
11. An electrode for use in the electrolytic production of gases comprising a plain block of carbon having several borings and passages extending through the' block serving to collect the gas produced at the under side of the block and suitable pipes to lead 'oil the collected gases.
12. An electrode for use in the electrolytic of graphite having several borings and passages extending through the block serving to collect the gas produced at the under side of the block and suitable pipes to lead off the collected gases.
13. An electrode for use in the electrolytic production of gases comprising a plain block of a substanceymade up of a number 0i' sepi arate portions having several borings and passages extending through the block serving to collecty the gas produced at the under 'side of the block and suitable pipes to lead off the collected gases.
14.k An electrode for use in the electrolytic production of gases comprising a plain block of carbon made up of a number of se arate portions, having several borings an passageso extending through the block serving to collect the gas produced at the under side ofthe block and suitable pipes to lead oi 'the collected gases.
15. An electrode for use in the electrolytic production of gases comprising a plain block of graphite made up of a number of separate portion-s, having several borings and passages extending through the block serving to collect the gas produced at the under side of the block and suitable pipes to lead ofi' the collected gases.
In testimony whereof I have hereunto set my hand.
ER-N ST HEINZE.
US755083A 1924-12-10 1924-12-10 Electrode for use in the electrolytic evolution of gases Expired - Lifetime US1575627A (en)

Priority Applications (2)

Application Number Priority Date Filing Date Title
US755083A US1575627A (en) 1924-12-10 1924-12-10 Electrode for use in the electrolytic evolution of gases
FR654417D FR654417A (en) 1924-12-10 1928-05-18 Amalgam tank for electrolysis of alkali and alkaline earth chlorides

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US755083A US1575627A (en) 1924-12-10 1924-12-10 Electrode for use in the electrolytic evolution of gases

Publications (1)

Publication Number Publication Date
US1575627A true US1575627A (en) 1926-03-09

Family

ID=25037660

Family Applications (1)

Application Number Title Priority Date Filing Date
US755083A Expired - Lifetime US1575627A (en) 1924-12-10 1924-12-10 Electrode for use in the electrolytic evolution of gases

Country Status (2)

Country Link
US (1) US1575627A (en)
FR (1) FR654417A (en)

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2473290A (en) * 1944-10-21 1949-06-14 George E Millard Apparatus for plating journals of crankshafts
US2500949A (en) * 1945-11-01 1950-03-21 Donald W Kent Top for electrolytic cells of the tank type
US2503337A (en) * 1941-08-27 1950-04-11 Ici Ltd Electrolytic cells of the liquid electrode type
US2550231A (en) * 1946-03-11 1951-04-24 Solvay Cells for the electrolysis of alkali salt solutions
US2786810A (en) * 1952-09-09 1957-03-26 Dominion Tar & Chemical Co Anodes and cover of electrolytic cells
US3405051A (en) * 1964-10-27 1968-10-08 Huron Nassau Ltd Electrolytic cell container
US3535223A (en) * 1963-05-06 1970-10-20 Avesta Jernerks Ab Electrolysers,particularly for chlorine-gas production
US3663380A (en) * 1970-03-02 1972-05-16 Phillips Petroleum Co Electrodes for electrolytic conversion
US3855104A (en) * 1972-03-21 1974-12-17 Oronzio De Nora Impianti PROCESS AND APPARATUS FOR THE ELECTROLYSIS OF HCl CONTAINING SOLUTIONS WITH GRAPHITE ELECTRODES WHICH KEEP THE CHLORINE AND HYDROGEN GASES SEPARATE

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2503337A (en) * 1941-08-27 1950-04-11 Ici Ltd Electrolytic cells of the liquid electrode type
US2473290A (en) * 1944-10-21 1949-06-14 George E Millard Apparatus for plating journals of crankshafts
US2500949A (en) * 1945-11-01 1950-03-21 Donald W Kent Top for electrolytic cells of the tank type
US2550231A (en) * 1946-03-11 1951-04-24 Solvay Cells for the electrolysis of alkali salt solutions
US2786810A (en) * 1952-09-09 1957-03-26 Dominion Tar & Chemical Co Anodes and cover of electrolytic cells
US3535223A (en) * 1963-05-06 1970-10-20 Avesta Jernerks Ab Electrolysers,particularly for chlorine-gas production
US3405051A (en) * 1964-10-27 1968-10-08 Huron Nassau Ltd Electrolytic cell container
US3663380A (en) * 1970-03-02 1972-05-16 Phillips Petroleum Co Electrodes for electrolytic conversion
US3855104A (en) * 1972-03-21 1974-12-17 Oronzio De Nora Impianti PROCESS AND APPARATUS FOR THE ELECTROLYSIS OF HCl CONTAINING SOLUTIONS WITH GRAPHITE ELECTRODES WHICH KEEP THE CHLORINE AND HYDROGEN GASES SEPARATE

Also Published As

Publication number Publication date
FR654417A (en) 1929-04-04

Similar Documents

Publication Publication Date Title
US1575627A (en) Electrode for use in the electrolytic evolution of gases
CN104297274B (en) in-situ XRD reaction chamber for testing electrochemical reaction process
MD3660G2 (en) Electrolyzer for hydrogen electrolytic obtaining
US2194443A (en) Anode for electrolytic cells
US2691628A (en) Electrode structures
GB282688A (en) Electrolytic apparatus
US1513890A (en) Electric furnace of the resistor type
US1212229A (en) Apparatus for the production of oxygen and hydrogen gases.
US3673076A (en) Filter press fluorine cell with carbon connectors
US1476251A (en) Electrolytic cell
US1471641A (en) Electrolytic gas cell
US870985A (en) Carbon electrode for galvanic elements.
US1346849A (en) Electrolytic cell
GB191114050A (en) Primary Electric Batteries.
US1658315A (en) Battery
GB191118733A (en) Electrodes for Electrical Furnaces.
US1159021A (en) Storage battery.
US1360542A (en) levin
US644538A (en) Voltaic cell.
US2500949A (en) Top for electrolytic cells of the tank type
US1454531A (en) Instrument for measuring the height of liquids
GB307934A (en) An electrolyser with collecting block
SU22115A1 (en) Galvanic cell
GB337389A (en)
US2684393A (en) Furnace for the electrothermic production of carbon disulfide