TW405047B

TW405047B - Radiation sensitive composition for color filter

Info

Publication number: TW405047B
Application number: TW088110116A
Authority: TW
Inventors: Masaaki Miyamichi; Hiroaki Nemoto; Shigeru Abe; Tomohiro Udaka; Shirou Takahashi
Original assignee: Jsr Corp
Priority date: 1998-06-24
Filing date: 1999-06-16
Publication date: 2000-09-11
Also published as: JP3870555B2; KR20000006371A; KR100415041B1; JP2000009919A

Abstract

This invention is to provide a radiation sensitive composition for color filters capable of forming color filters having high reliability and having excellent transparency to radiation, contrast, etc. This composition contains (A) coloring agents of >=0.9 in the refining degree calculated by the equation: the refining degree = Y/X, (B) a photo-polymerization initiator, (C) a poly-functional monomer and (D) an alkali soluble resin, (where, X is a voltage holding rate at a measurement temperature of 60 DEG C and frame period 500 microseconds of a liquid crystal display element filled with nematic type liquid crystals; Y is the voltage holding rate at the measurement temperature of 60 DEG C and frame period 500 microseconds of the liquid crystal display element filled with the contaminated liquid crystal prepared by mixing 5 wt% coloring agents with the same nematic type liquid crystals in place of the nematic type liquid crystals, then removing a solid content).

Description

405047 五、發明說明（1 ) 【發明之技術領域】本發明係有關一種濾色器用感放射線組成物之發明。更詳細的說’係有關一種製造用於彩色液晶顯示裝置、彩色攝像管元件等之透過型或反射型濾色器時所使用之濾色器用感放射線組成物的發明。【冃前之技術】一般用於彩色液晶顯示裝置、彩色攝像管元件之濾色器，係將放射線介著光罩對感光性樹脂之塗膜進行照射（以下稱「曝光」）後，使曝光之部份硬化以進行顯像處理 ’其後，在去除塗膜中未曝光之部份（未曝光部）以形成圖型的同時，可使用染色之方法（染色法）或，分散有著色劑之組成物依前記方法形成塗膜，並依曝光及顯像處理等光蝕刻方法予以製得。此些濾色器之著色劑除紅、綠及藍三原色外’特別是在彩色攝像管時，可以再配合腈、洋紅及黃色等補色方式進行。經濟部智慧財產局員工消費合作社印製但’ 一般用於彩色液晶顯示裝置、彩色攝像管元件之濾色器’其玻璃等透明基板之表面上，係受有2種以上不同色調之畫素，其中直線狀畫素係以平行或交叉之方式配列’方形畫素係以縱橫之方式配列，且畫素尺寸係具有數十/zm至數百//m之細微程度。在製造配置有一定形狀之細微畫素的濾色器時，目前已知之方法係將感光樹脂塗布於基板上，並對所形成之塗膜介著光罩使放射線照射部硬化，其後經顯像處理並去除 -4- >(請先閱讀背面之注意事項再填寫本頁) 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） A7 4Q5〇47_b7 五、發明說明$ ) 塗膜中未曝光之部份，再使用染色之染色法或，溶有著色劑（染料或顏料）之組成物，依前記方法形成塗膜、曝光及顯像處理使其圖型化之光鈾刻方法等。又，彩色液晶顯示裝置一般爲便於液晶驅動，多以氧化銦或氧化錫所成之透明電極以蒸鍍或濺射方式形成於濾色器上，並再於其上方形成使液晶具有一定方向定向之定向膜，且爲製得具高性能之透明電極及定向膜時，一般需要2 0 0 °C以上，更佳爲2 5 0 °C以上之高溫。依前記方法所製得之濾色器中，對有使用染料之濾色器而言，因其對放射線具有較高透明度，且耐熱性並不充分，故透明電極與定向膜必須在2 0 0 °C以下之溫度下形成，因此要如何確保透明電極與定向膜之性能將形成另一種問題。又，對有使用染料之濾色器而言，會產生耐光性不佳，且不適合室外使用之缺點。因此，目前多將染料以具有優良耐熱性、耐光性之顏料取代，使目前所製造之瀘色器幾乎是使用有機顏料。但是，一般用於濾色器之有機顏料等著色劑，在大多情形下皆混有不純物質，且因畫素陣列中所含之著色劑中的不純物質會逐漸滲漏（bleed )於液晶中而污染該液晶’ 進而使液晶顯示元件之功能逐漸損壞，而造成產品信用上之問題。此外，近年來就反應濾色器之高品質化及用途之擴大性上，濾色器在對放射線之透明性、彩度與’照度之平衡、顯示上之對比等多被要求應具有更高度之性能’但實際上此些性能多受到著色劑中不純物質產生之不良影響本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） (請先閱讀背面之注意事項再填寫本頁) 裝-------—訂·！ -線，經濟部智慧財產局員工消費合作社印製 -5- A7 B7 405047 【發明所可以解決之問題】本發明係鑒於以上問題所提出之結果。因此，本發明之目的以提供一種具有高度可信度，且可形成一種對放射線具有透明性、對比等優良透過型或反射型濾色器的濾色器用感放射線組成物。本發明之其他目的及優點將於以下說明中敘述。【解決問題之方法】依本發明之內容，本發明之目的及優點係以含有 (A )下式（1 ) 精製度=Y/X …（1 ) 其中，X爲注入有向列型液晶之液晶顯示元件於測定溫度6 Ot、及火焰週期5 0 0微秒下之電壓保持率，Y爲將前記所注入之向列型液晶以同型液晶混以5 重量％著色劑並去除固體成分所製得之由污染液晶取代所得之液晶顯示元件，於測定溫度6 0 °C、及火焰週期500微秒下之電壓保持率；又，「火焰週期」係指脈衝之間隔；所示之精製度爲0.9以上之著色劑、 (請先閱讀背面之注意事項再填寫本頁) 裝 ----— II 訂·！— I-線- 經濟部智慧財產局員工消費合作社印製本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） -6- 經濟部智慧財產局員工消費合作社印製五、發明說明0 ) (B )光聚合起始劑、 (C )多官能性單體、及 (D )鹼可溶性樹脂所得之濾色器用放射線性組成物爲特徵之方式以達成。以下，將對本發明作更詳細之說明。 (A )成分本發明中之（A )成分，係由前記式（1 )計算所得之精製度（以下簡稱「精製度」）爲0 . 9以上之著色劑所形成。此著色劑在滿足前記精製度下，於色調上並沒有特限定，且有機著色劑或無機著色劑皆可使用。前記有機著色劑例如染料、有機顔料、天然色素等，又前記無機著色劑例如，除無機顏料以外，稱爲體質顏料之無機鹽等亦可以使用，本發明之著色劑中，以發色性高、且耐熱性高之著色劑，特別是耐熱分解性較高之著色劑爲佳，可使用一般之有機著色劑’特別是有機顏料爲更佳〇前記有機顏料之具體例，例如彩色手冊（C.I.;The Society of Dyers and Colourists公司發行。以下相同）中編號所示之下示內容’ C. I ·碧格曼黃—83、 c. I ·碧格曼黃—11〇、 ^紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） --------------裝--------訂---------線（- (請先閱讀背面之注意事項再填寫本頁) 405047 A7 _B7 五、發明說明6 ) 經濟部智慧財產局員工消費合作社印製405047 V. Description of the Invention (1) [Technical Field of the Invention] The present invention relates to a radiation-sensitive composition for a color filter. More specifically, it relates to the invention of a radiation-sensitive composition for a color filter used in the production of a transmissive or reflective color filter for a color liquid crystal display device, a color camera tube element, and the like. [Previous technology] Generally used as a color filter for color liquid crystal display devices and color image pickup tube elements, the coating film of photosensitive resin is irradiated with radiation through a photomask (hereinafter referred to as "exposure") and then exposed. The part is hardened for development processing. 'Then, the unexposed part (unexposed part) in the coating film is removed to form a pattern, and a dyeing method (dyeing method) or a colorant may be dispersed. The composition is formed into a coating film according to the foregoing method, and is prepared by a photo-etching method such as exposure and development processing. In addition to the three primary colors of red, green and blue, the coloring agents of these color filters, especially when used in color video tubes, can be supplemented with nitrile, magenta, and yellow complementary colors. Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs, but 'Generally used as a color filter for color liquid crystal display devices and color camera tube elements' on the surface of glass and other transparent substrates, there are more than two different color pixels. Among them, linear pixels are arranged in parallel or intersecting manner, and square pixels are arranged in a horizontal and vertical manner, and the pixel size is as fine as several tens / zm to several hundreds // m. When manufacturing a color filter equipped with fine pixels of a certain shape, a currently known method is to apply a photosensitive resin to a substrate, and harden the radiation irradiated portion through a photomask formed by a coating film, and then display the Image processing and removal -4- > (Please read the precautions on the back before filling this page) This paper size is applicable to China National Standard (CNS) A4 specification (210 X 297 mm) A7 4Q5〇47_b7 V. Description of the invention $ ) The unexposed part of the coating film, then use the dyeing method or the composition with the colorant (dye or pigment) dissolved, and form the coating film according to the method described above, and expose and pattern the light to pattern it. Uranium carving method and so on. In addition, in order to facilitate liquid crystal driving, a color liquid crystal display device generally uses transparent electrodes made of indium oxide or tin oxide to be formed on a color filter by evaporation or sputtering, and is formed on the color filter so that the liquid crystal has a certain orientation. Orientation film, and in order to obtain transparent electrodes and orientation films with high performance, generally higher than 200 ° C, more preferably higher than 250 ° C. Among the color filters prepared according to the foregoing method, for color filters with dyes, because they have high transparency to radiation and inadequate heat resistance, the transparent electrode and the alignment film must be at 200 It is formed at a temperature below ° C, so how to ensure the performance of the transparent electrode and the alignment film will form another problem. In addition, color filters using dyes have disadvantages that they have poor light resistance and are not suitable for outdoor use. Therefore, most of the dyes have been replaced with pigments with excellent heat resistance and light resistance at present, so that the organic pigments are almost used in the chromers currently manufactured. However, in most cases, colorants such as organic pigments used in color filters are mixed with impurities, and the impurities in the coloring agent contained in the pixel array will gradually leak (bleed) into the liquid crystal. Pollution of the liquid crystal 'causes the function of the liquid crystal display element to be gradually damaged, which causes problems in product credit. In addition, in recent years, in terms of the high quality of the reaction color filter and the expansion of its use, color filters are required to have a higher degree of transparency to radiation, balance of chroma and 'illumination, and contrast on the display. Performance ', but in fact these properties are mostly affected by the impure substances in the colorant. The paper size applies the Chinese National Standard (CNS) A4 specification (210 X 297 mm) (Please read the precautions on the back before filling in this Page) Install --------- Order! -Line, printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs -5- A7 B7 405047 [Problems Solved by the Invention] The present invention is a result of the above-mentioned problems. Therefore, an object of the present invention is to provide a radiation-sensitive composition for a color filter having high reliability and capable of forming a transmissive or reflective color filter having excellent transparency and contrast to radiation. Other objects and advantages of the present invention will be described in the following description. [Method for solving the problem] According to the content of the present invention, the object and advantages of the present invention are to contain (A) the following formula (1) refined system = Y / X… (1), where X is a type of nematic liquid crystal injection The voltage retention rate of the liquid crystal display element at a measurement temperature of 6 Ot and a flame period of 500 microseconds. Y is a mixture of the nematic liquid crystal injected by the foregoing method with the same type of liquid crystal and a 5 wt% colorant, and the solid content is removed. The liquid crystal display element obtained by replacing the contaminated liquid crystal with the voltage retention rate at a measurement temperature of 60 ° C and a flame period of 500 microseconds; and the "flame period" refers to the interval between pulses; the precise system shown is Colorants above 0.9, (Please read the precautions on the back before filling out this page) Installation -------- Order II! — I-Line-Printed by the Consumers 'Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs This paper is printed in accordance with the Chinese National Standard (CNS) A4 (210 X 297 mm) -6-Printed by the Consumers' Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs Explanation 0) (B) a photopolymerization initiator, (C) a polyfunctional monomer, and (D) an alkali-soluble resin, which is obtained by a method characterized by a radiation composition for a color filter. Hereinafter, the present invention will be described in more detail. (A) Component The component (A) in the present invention is formed by a coloring agent whose refined system (hereinafter referred to as "refined system") calculated by the foregoing formula (1) is 0.9 or more. This colorant is not limited in hue under the prescriptive system, and both organic and inorganic colorants can be used. The aforementioned organic colorants such as dyes, organic pigments, natural pigments, etc., and the aforementioned inorganic colorants such as inorganic salts other than inorganic pigments, which are called constitution pigments, can also be used. The coloring agent of the present invention has high color development properties. Colorants with high heat resistance, especially those with high thermal decomposition resistance, can be used with general organic colorants', especially organic pigments are better. Specific examples of organic pigments, such as the color manual (CI Issued by The Society of Dyers and Colourists. Same below) The contents shown below are shown in the numbers below. 'C. I. Bigman Yellow-83, c. I. Bigman Yellow-110, ^ Paper size applies to China National Standard (CNS) A4 Specification (210 X 297 mm) -------------- Installation -------- Order --------- Line (- (Please read the notes on the back before filling out this page) 405047 A7 _B7 V. Description of Invention 6) Printed by the Consumer Cooperative of Intellectual Property Bureau of the Ministry of Economic Affairs

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------装------— —訂----I--線， (請先閲讀背面之注意事項再填寫本頁) 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） -8- 經濟部智慧財產局員Η消費合作社印製 _ 鄕 047 ；__ 五、發明說明（b ) C.I.碧格曼藍—15:6; C . I .碧格曼綠一 7、 c . I .碧格曼綠一 3 6 ; c . I ·碧格曼黑1 、 C · I .碧格曼黑7。又，前記無機著色劑例如氧化鈦、硫酸鋇、碳酸鈣、鋅華、硫酸鉛、黃鉛、氧化鐵紅（紅色氧化鐵（I I I ) )、鎘紅、淺藍、深藍、氧化鉻綠、鈷綠、琥珀、鈦黑、合成鐵黑、碳黑等等。本發明中，著色劑可使用下記（a )〜（e )方式精製’而達前記之精製度。以下，將對著色劑之精製法作更詳細之說明。 (a )再結晶法再結晶法係選擇一種可以溶解之著色劑，及不會與著色劑產生反應之適當溶媒，再將含有此一著色劑置入溶媒中於加溫下使其溶解至飽和溶液後予以冷卻，再使著色劑結晶之一種精製方法。此一再結晶法所使用之溶媒，依著色劑之不同而有所不同。例如使用C . I ·碧格曼綠—7、C · I .碧格曼綠一 3 6等銅鈦菁系綠色顏料進行精製時，以使用濃硫酸、氯磺酸等爲佳。此時，爲使精製之顏料得以完全溶解，故溶媒之使用量一般以對顏料爲5倍重量份以上，更佳爲 1 0倍重量份以上爲宜。又，有關顏料之分解溫度，因溫本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公髮） -9 - (請先閱讀背面之注意事項再填寫本頁) 裝 — —II訂---------線 A7 __405047__b7 五、發明說明C ) 度過高會有造成顏料分解之疑慮，過低則造成冷卻前後之溶解度差變小，故不易製得充分量之精製顏料，一般爲 20〜500 °C，較佳爲30〜250 °C之範圍。又，顏料之溶解時間若過短時則所得顏料之精製度不易達到〇 . 9以上，過長時則顏料則有分解之疑慮，故較佳爲5 秒〜5小時，更佳爲3 0秒〜2小時。於此條件下使顏料再結晶、過濾後即可得精製之顏料。 (ύ )再沉澱法再沉澱法係選擇一種可以溶解之著色劑，再將著色劑溶解於不會與著色劑產生反應之適當溶媒，再於此一溶液中添加添加弱溶媒，再使著色劑結晶析出之一種精製方法〇此再沉澱法所使用之溶媒，依著色劑之種類而有所不同，例如使用C . I .碧格曼綠_ 7、c . I ·碧格曼綠 - 3 6等銅鈦菁系綠色顏料進行精製時，以使用濃硫酸、氯磺酸等爲佳。此時，爲使精製之顏料得以完全溶解，故溶媒之使用量一般以對顏料爲5倍重量份以上，更佳爲 1 ◦倍重量份以上爲宜。又，有關顏料之分解溫度，因溫度過高會有造成顏料分解之疑慮，過低則造成冷卻前後之溶解度差變小，而不易製得充分量之精製顏料，一般爲常溫〜500 °C，更佳爲常溫〜250 °C之範圍。又，顔料之溶解時間若過短時則所得顏料之精製度不易達到0 . 9 以上，過長時則顏料則有分解之疑慮，故較佳爲5秒〜5 (請先閱讀背面之注意事項再填寫本頁) ------I I 訂·！！！，經濟部智慧財產局員工消費合作社印製本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） -10- ___405047_B7___ 五、發明說明) (請先閱讀背面之注意事項再填寫本頁) 小時’更佳爲3 0秒〜2小時。又，弱溶媒例如以使用純水、甲醇、乙醇、氫氧化鈉水溶液、氫氧化鉀水溶液等爲佳。其用量一般以對顔料爲1 〇倍重量份以上，更佳爲 1 5倍重量份以上，最佳爲2 0倍重量份以上爲宜。將顏料溶液添加入純水後，將顏料析出，並將所得結晶過濾後即可得精製之顏料。 (c )溶媒洗淨法溶媒洗淨法，係選擇一種可分散著色劑、不與著色劑反應’且具有適當揮發性之適當溶媒以洗淨著色劑之方法。此溶媒洗淨法所使用之溶媒，只要在洗淨中可以留存大量之著色劑，即使會造成著色劑產生些微溶解之溶媒亦可使用。前記有機溶媒例如，乙二醇一甲基醚、乙二醇一乙基醚、乙二醇——η —丙基醚、乙二醇——η_ 丁基醚等乙二醇一烷基醚類；乙二醇一甲基醚乙酸酯、乙二醇一乙基醚乙酸酯等乙二_一烷基醚乙酸酯類；經濟部智慧財產局員工消費合作社印製二乙二醇一甲基醚、二乙二醇一乙基醚、二乙二醇一一 η —丙基醚、二乙二醇——η - 丁基醚、三乙二醇一甲基醚、三乙二醇一乙基醚等聚乙二醇一烷基醚類；丙二醇一甲基醚、丙二醇一乙基醚、丙二醇——η -丙基酸、丙二醇一_ η -丁基酸等丙二醇一院基醚類；二丙二醇一甲基醚、二丙二醇一乙基醚、二丙二醇一 -11 - 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） 405047 A7 B7 五、發明說明0 ) 一 η -丙基醚、二丙二醇一一 η —丁基醚、三丙二醇一甲基醚、三丙乙二醇一乙基醚等聚丙二醇一烷基醚類；丙二醇一甲基醚乙酸酯、丙二醇一乙基醚乙酸酯等丙二醇一烷基醚乙酸酯類；二***、乙基一 i 一丙醚、二一 i _丙醚、二乙二醇二甲基醚、二乙二醇甲基***、二乙二醇二乙基醚、四氫呋喃、1，4 一二噁烷等其他醚類；丙酮、甲基乙基酮、甲基一 i — 丁酮、環己酮、2 -戊酮、3 -戊酮、二丙酮醇等酮類； 2 -羥基丙酸甲酯、2 -羥基丙酸乙酯等乳酸烷酯類 > 2 -羥基一 2 -甲基丙酸乙酯、3 —羥基丙酸甲酯、 3 —甲氧基丙酸乙酯、3 —乙氧基丙酸甲酯、3 —乙氧基丙酸乙酯、乙氧基醋酸乙酯、丙氧基醋酸乙酯、2 —羥基一 3 _甲基丁酸甲酯、3_甲基—3 —甲氧基丁酸酯、3 一甲基一3—甲氧基丙酸酯、乙酸乙酯、乙酸n_丁酯、乙酸i 一丁酯、蟻酸η —戊酯、乙酸i _戊酯、丙酸η -丁酯、丁酸乙酯、丁酸i -丙酯、丁酸η — 丁酯、丙酮酸甲酯、丙酮酸乙酯、丙酮酸η —丙酯、乙醯乙酸甲酯、乙醯乙酸乙酯、2 —羰基丁酸酯、二甲基碳酸酯等其他酯類， Ν —甲基吡硌烷酮、Ν，Ν_二甲基甲醯胺、乙醯胺、Ν，Ν -二甲基乙醯胺等醯胺類；甲醇、乙醇、i —丙醇、乙二醇、二乙二醇、丙三醇 -------------裝------II 訂---------線 (請先閱讀背面之注意事項再填寫本頁) 經濟部智慧財產局員工消費合作社印製本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） -12- 405047 A7 B7_ 五、發明說明（10 ) 等醇類；，(請先閱讀背面之注意事項再填寫本頁) 二甲基硕、乙腈、吡啶等其他高極性溶媒； η —戊烷、η —己烷、η -庚烷、環己烷等脂肪族烴類；甲苯、二甲苯等芳香族烴類；二氯甲烷、氯仿、四氯化碳、1，1一二氯乙烷、1 ’ 2~二氯乙烷、1，1，1—三氯乙烷、1，1，2- 三氯乙烷、六氯苯等鹵化烴類；等等。此些溶媒，可以單獨或2種以上混合使用。又，前記溶媒中可再倂用例如，苄基乙基醚、二己基醚、丙酮基丙酮、異佛爾酮、己酸、辛酸、1一辛醇、1 一壬醇、苄基醇、醋酸苄酯、安息香酸乙酯、草酸二酯、馬來酸二酯、r—丁內酯、碳酸乙烯、碳酸丙烯、乙二醇一苯基醚乙酸酯等高沸點溶媒。上述高沸點溶媒，可單獨使用或2種以上混合使用皆可〇經濟部智慧財產局員工消費合作社印製又’前記酸性水溶液所使用之酸，可爲有機酸或無機酸。前記有機酸，例如醋酸、丙酸、丁酸、戊酸、三甲基乙酸、己酸、二乙基醋酸、庚酸、癸酸等脂肪族一羧酸類 » 草酸、丙二酸、琥珀酸、戊二酸、己二酸、庚二酸、辛二酸、壬二酸、癸二酸、巴西二酸、甲基丙二酸、乙基 13· 本紙張尺度適用中國國家標準（CNS)A4規格（21〇 X 297公爱） A7 405047 --------B7__ 五、發明說明（11 ) 丙二酸、二甲基丙二酸、甲基琥珀酸、四甲基琥珀酸、1 ’ 4 —環己二羧酸、衣康酸、檬康酸、馬來酸、富馬酸、中康酸等脂肪族二羧酸類；三胺基甲酸、烏頭酸、卡彭酸等脂肪族三羧酸；安息香酸、甲苯酸、枯茗酸、二甲基苯酸、三甲基苯酸等芳香族一羧酸類；鄰苯二甲酸、間苯二甲酸、對苯二甲酸、等芳香族二羧酸類；偏苯三酸、均苯三酸、偏苯四酸、均苯四酸等3價以上之芳香族聚羧酸類；乙醇酸、乳酸、（2 -氧代丁酸、甘油酸、羥基丙二酸 '蘋果酸、酒石酸、枸椽酸、水楊酸、P —氧代安息香酸 '二羥基苯甲酸、苦杏酸、托品酸、香豆酸、二羥基肉桂酸等氧代羧酸類；及苯基醋酸、氫化阿托酸、氫化肉桂酸、苯基琥珀酸、阿托酸、肉桂酸、肉桂乙酸等等。前記無機酸例如，硫酸、硝酸、碳酸、氯酸、過氯酸等等。此時，硫酸水溶液可使用濃硫酸、熱濃硫酸、稀硫酸等。此些酸，可以單獨使用或2種以上混合使用。前記無機鹼性水溶液所使用之鹼，可使用無機鹼或有機鹼。前記無機鹼例如，氫氧化鈉、氫氧化鉀、碳酸鈉、碳酸鉀、碳酸氫鈉、難酸氫鉀、氫氧化鈣、氫氧化鋇等。 ---!Ί!-^ 裝！1 訂·!1 I 線， (請先閱讀背面之注意事項再填寫本頁) 經濟部智慧財產局員工消費合作社印製本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） -14- 405047 經濟部智慧財產局員工消費合作社印製五、發明說明（12 ) 前記有機鹼，例如乙醇二乙基胺乙醇、2 —（二一 -一 1 一丙基胺基 ) 乙醇、醇 3 ― 二甲基胺基 ― 1 一丙醇 2 二甲基胺基 ― 1 ― 丙醇 Λ 4 ― 二甲基胺基 ― 2 ― 丁醇、 3 ― 二甲基胺基 ~ 2 丁醇、 5 ― 二甲基胺基 ― 2 一戊醇、 4 ― 二甲基胺基 — 2 ― 丁醇等院醇胺類 — 甲基胺、二甲基胺 > 、一乙基胺 > 二乙基胺二單 ― Π ― 丙基胺 ― η — — i 一丙基胺單 ― η ― 丁類 0 此鹼性化合物可以單可 0 此些溶媒中 > 就洗淨力除純水以外 7 有機溶媒以 —. 曱基乙酸酯 ' 四氫呋喃甲基碳酸酯 > N 一甲基吡硌 Λ ~~· 甲基硕、甲醇乙醇則例如r 一丁內酯等爲佳。胺、2 —二甲基胺乙醇、2 — η —丙基胺基）乙醇、2 -（ 2-（二一η_丁基丙基）乙丙醇、3 —二乙基胺基一 1一 —丙醇、2 —二乙基胺基一 1 2—丁醇'4一二乙基胺基— 一 2 —丁醇、3 —二乙基胺基基一2 —戊醇、5 —二乙基胺胺基—2 — 丁醇、4 —二乙基 j 三甲基胺、四甲基銨氫氧化物乙基胺、四乙基銨氫氧化物、丙基胺、單一i一丙基胺、二基胺、二一η-丁基胺等烷胺獨一種或2種以上混合使用皆及與著色劑之親和力觀點而言使用丙二醇一甲基醚、丙二醇丙酮、環己酮、二丙酮醇、二烷酮、Ν，Ν—二甲基甲醯胺 i 一丙醇、η —己烷、甲苯、四氯化碳等爲佳，高沸點溶劑 — — ΙΊΙ — ———— — — — 1.裝·1 — 11 訂-! !線， .(請先閱讀背面之注意事項再填寫本頁> 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） -15- 經濟部智慧財產局員工消費合作社印製 405047 五、發明說明（13 ) 又，酸性水溶液以1重量％之草酸水溶液、1重量％之鄰苯二甲酸、1重量％之枸椽酸水溶液、濃硫酸、熱濃硫酸、稀硫酸等爲佳。又，鹼性水溶液例如氫氧化鈉、氫氧化鉀等無機鹼之水溶液；乙醇胺、2 —二甲基胺基乙醇、三乙基胺、四甲基銨氫氧化物等有機鹼性水溶液爲佳。使用前記溶媒所進行之洗淨步驟例如， (c - 1 )將著色劑與溶媒之混合物使用狄若爾攪拌器、均化攪拌器、均化器、進料攪拌器、3軸、2軸、輾粒輥等混合裝置，以1分鐘〜7 0小時，較佳爲混合5分鐘〜2 4小時，更佳爲1 0分鐘〜6小時後，經過濾、傾析等步驟而將溶媒分離後再進行乾燥之分散洗淨步驟； (c _ 2 )、將著色劑與溶媒之混合物置入超音波分散均化器、超音波洗淨機等超音波混合裝置內’使用1〜 3 0 0KHz、較佳爲2〜ΙΟΟΚΗζ周波數之超音波，進行3 0秒〜1 0小時，較佳爲1分鐘〜5小時之處理，經過濾、傾析等步驟而將溶媒分離後再進行乾燥之超音波洗淨步驟； (c - 3 )、將著色劑與溶媒之混合物置入附有攪拌翼之攪拌機內，使用50〜1 5000 r pm、較佳爲 1 00〜2000 r pm之迴轉數，進行5分鐘〜1 ◦小時，較佳爲1 0分鐘〜5小時之攪拌，經過濾、傾析等步驟而將溶媒分離後再進行乾燥之攪拌洗淨步驟等。又，前記（c 一 1)〜（c — 3)之步驟’可以個別實施或可任意組合2個以上步驟之方式實施。本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） -16 - I I J I I I I I I I 裝·1·1訂----------^-1 (請先閱讀背面之注意事項再填寫本頁) 經濟部智慧財產局員工消費合作社印製 405047 a7 _________B7_ 五、發明說明（14 ) 依此溶媒洗淨法可製得精製之著色劑。 (d )昇華法昇華法，即是將著色劑於常壓或減壓下進行加熱使其昇華之方式進行精製之方法。使著色劑昇華之加熱溫度，一般依著色劑之種類或壓力有所變化，例如使用C · I .碧格曼綠一 7、C . I . 碧格曼綠- 3 6等銅鈦菁系綠色顏料進行精製時，於常壓下，一般以200〜800 °C，較佳爲300〜600 °C 爲宜。依此昇華法可製得精製之著色劑。 (e )真空加熱法真空加熱法，一般係將著色劑置入耐壓容器中，並於真空下以加熱方式精製之方法。真空加熱法之加熱溫度，依著色劑種類之不同而有所不同，溫度過高會造成著色劑昇華，過低則會使不純物之去除有所困難性，故，一般爲2 0 t 〇 r r以下，較佳爲 1 0 t 〇 r r以下之範圍爲宜。依此真空加熱法可製得精製之著色劑。本發明中，前記（a )〜（e )之各精製法，可以實施1次或反覆實施2次以上。前記（a )〜（e )之各精製法中之較佳組合例如， (a )再結晶法與（c )溶媒洗淨法之組合（再結晶本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） -17- (請先閱讀背面之注意事項再填寫本頁> 裝 —1—訂— — — — — I -線-- 405047 A7 B7 五、發明說明（15 ) •溶媒洗淨法）、 (b )再沉澱法與（c )溶媒洗淨法之組合（再沉澱 •溶媒洗淨法）、 (c )溶媒洗淨法與（e )真空加熱法之組合（溶媒洗淨•溶媒洗淨法）、或 (c )溶媒洗淨法中，以替換2次以上溶媒之方式進行洗淨之組合（複數溶媒洗淨法）等。本發明中，精製所得之著色劑之精製度爲〇 . 9以上 ’更佳爲0·93以上。此時，若使用精製度低於〇.9 以下之著色劑時’，會降低液晶顯示元件之電壓保持率、燒烤、定向不良，且會造成通電後之顯示狀態或光透過性不佳，故爲不佳之條件。本發明中，精製之著色劑可單獨使用或以2種以上組合之方式使用。又，本發明中，依各種情形之不同，可將未精製之著色劑與精製之著色劑，在2著色劑之混合物之精製度爲〇 . 9以上之條件下倂用。前記未精製之著色劑於色調上並未有特別限定’且可使用有機著色劑或無機著色劑。未精製之著色劑中，有機著色劑例如染料、有機顏料、天然色素等，又，前記無機著色劑例如除無機顏料以外，一般稱爲體質顏料之無機鹽等亦屬之。又’本發明中未精製之著色劑，以發色性高’且具高耐熱性之著色劑，特別是具有高度耐熱分解性之著色劑爲佳’一般以使用有機著色劑，又以使用有機顏料爲最佳。 --,! ·! —訂！--線， •(請先閲讀背面之注意事項再填寫本頁) 經濟部智慧財產局員工消費合作社印製 ^紙張尺度適用中_豕標準(CNS)A4規格（210 X 297公釐） 18 A7 405047 _________B7 __ 五、發明說明（16 ) 未精製之有機顔料及無機顏料之具體例如，精製著色劑中所例示之前記有機顏料及無機顏料等化合物。此些未精製之顏料，可單獨使用或亦可以將2種以上混合使用。本發明中之著色劑，依所希望目的之不同，而可與分散劑共同使用。此些分散劑例如，陽離子系、陰離子系、非離子系、兩性、聚矽氧烷系、氟系等界面活性劑。前記界面活性劑，例如聚氧乙烯月桂醚、聚氧乙烯硬脂醚、聚氧乙烯油醚等聚氧乙烯烷醚類；聚氧以烯辛苯醚、聚氧乙烯壬苯醚等聚氧乙烯烷苯醚類；聚乙二醇二月桂酸酯、聚乙醇二硬脂酸酯等聚乙二醇二酯類：山梨糖醇軒脂防酸酯類；脂肪酸聚酯類；3級胺變性聚尿烷類；聚乙烯亞胺類以外，例如以下商品名之K P (信越化學工業公司製）、保力氟（共榮油脂化學工業公司製）、冶氟托浦 (托科製造公司製）、美加法克（大日本油墨公司製）、氟羅來特（住友3 Μ公司製）、朝日卡得、沙福隆（以上，旭硝子公司製）等等。此些界面活性劑可單獨使用或將2種以上化合物混合使用。劑面活性劑之使用量’以對著色劑1 0 0重量份而言，一般爲5 0重量份以下’較佳爲〇〜4 0重量份。 (Β )成分本紙張尺度適用中國國家標準(CNS)A4規格（210 X 297公釐）「19- ~~— ---J — II--I I--i ! ! I 訂-I I I ! ·線- •(請先閱讀背面之注意事項再填寫本頁) 經濟部智慧財產局員工消費合作社印製 405047 五、發明說明耖）本發明中所稱（B )成分，爲一種可在可視光、紫外線 '遠紫外線、電子線、X線等放射線之曝光下，使後述 (C )成分開始聚合而產生活性種之光聚合起始劑所構成------ Installation -------- --Order ---- I-- line, (Please read the precautions on the back before filling this page) This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) -8- Printed by the Consumer Property Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs _ 鄕 047; __ V. Description of the invention (b) CI Bigman Blue—15: 6; C. I. Bigman Green -7, c. I. Biggman Green 1-6; c. I. Biggman Black 1, C. I. Biggman Black 7. In addition, the foregoing inorganic colorants include titanium oxide, barium sulfate, calcium carbonate, zinc bloom, lead sulfate, yellow lead, iron oxide red (red iron oxide (III)), cadmium red, light blue, dark blue, chrome oxide green, and cobalt. Green, amber, titanium black, synthetic iron black, carbon black, etc. In the present invention, the coloring agent can be refined using the following methods (a) to (e) to achieve the refining system described above. Hereinafter, a method for purifying a colorant will be described in more detail. (a) Recrystallization method The recrystallization method selects a dissolving coloring agent and an appropriate solvent that will not react with the coloring agent. The coloring agent containing this coloring agent is placed in the solvent and dissolved to saturation under heating. A refining method in which the solution is cooled and the colorant is crystallized. The solvent used in this recrystallization method varies depending on the colorant. For example, when using copper-titanium-cyanine-based green pigments such as C.I. Biggman Green-7 and C.I. Biggman Green-36 for purification, it is preferable to use concentrated sulfuric acid and chlorosulfonic acid. At this time, in order to completely dissolve the refined pigment, the amount of solvent used is generally 5 times by weight or more, and more preferably 10 times by weight or more. In addition, as for the decomposition temperature of the pigment, the paper size of this paper applies the Chinese National Standard (CNS) A4 specification (210 X 297). -9-(Please read the precautions on the back before filling this page) --------- Line A7 __405047__b7 V. Description of the invention C) If the degree is too high, there will be doubts about pigment decomposition. If the degree is too low, the difference in solubility before and after cooling will become smaller, so it is not easy to obtain a sufficient amount of refined pigment. It is generally in the range of 20 ~ 500 ° C, preferably 30 ~ 250 ° C. In addition, if the dissolution time of the pigment is too short, the refined system of the obtained pigment may not easily reach 0.9 or more, and if it is too long, the pigment may be decomposed, so it is preferably 5 seconds to 5 hours, and more preferably 30 seconds. ~2 hours. Under these conditions, the pigment is recrystallized and filtered to obtain a refined pigment. (ύ) Re-precipitation method The re-precipitation method is to choose a coloring agent that can be dissolved, and then dissolve the coloring agent in an appropriate solvent that does not react with the coloring agent. Then add a weak solvent to this solution, and then make the coloring agent. A refining method for crystallization. The solvent used in this reprecipitation method varies depending on the type of colorant. For example, C.I.Bigman Green_7, c.I.Bigman Green-3 6 When the copper-titanium-cyanide-based green pigment is refined, it is preferable to use concentrated sulfuric acid, chlorosulfonic acid, or the like. At this time, in order to completely dissolve the refined pigment, the amount of solvent used is generally 5 times by weight or more, and more preferably 1 time by weight or more. In addition, the decomposition temperature of pigments may cause the pigment to be decomposed because the temperature is too high. If the temperature is too low, the solubility difference before and after cooling will be small, and it is not easy to obtain a sufficient amount of refined pigments. Generally, the normal temperature is ~ 500 ° C. More preferably, it is in the range of normal temperature to 250 ° C. In addition, if the dissolution time of the pigment is too short, the refined system of the obtained pigment may not easily reach 0.9 or more, and if it is too long, the pigment may be decomposed, so it is preferably 5 seconds to 5 (please read the precautions on the back first) (Fill in this page again) ------ II Order! !! !! The paper size printed by the Employees' Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs applies the Chinese National Standard (CNS) A4 specification (210 X 297 mm) -10- ___405047_B7___ V. Description of the invention) (Please read the precautions on the back before filling in this (Page) Hour 'is more preferably 30 seconds to 2 hours. The weak solvent is preferably, for example, pure water, methanol, ethanol, an aqueous solution of sodium hydroxide, or an aqueous solution of potassium hydroxide. The amount is generally 10 times by weight or more, preferably 15 times by weight or more, and most preferably 20 times by weight or more for the pigment. After adding the pigment solution to pure water, the pigment is precipitated, and the obtained crystal is filtered to obtain a refined pigment. (c) Solvent washing method The solvent washing method is a method for selecting a dispersing colorant, which does not react with the coloring agent, and has a suitable volatility, and a suitable solvent to wash the colorant. The solvent used in this solvent cleaning method can be used as long as a large amount of the coloring agent can be kept in the cleaning, even if the coloring agent is slightly dissolved. The aforementioned organic solvents include, for example, ethylene glycol monomethyl ether, ethylene glycol monoethyl ether, ethylene glycol-η-propyl ether, and ethylene glycol-η-butyl ether. ; Ethylene glycol monomethyl ether acetate, ethylene glycol monoethyl ether acetate, etc .; ethylene glycol monoethyl ether acetate printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs Ether, diethylene glycol monoethyl ether, diethylene glycol mono-n-propyl ether, diethylene glycol-n-butyl ether, triethylene glycol monomethyl ether, triethylene glycol-1 Polyethylene glycol monoalkyl ethers such as ethyl ether; propylene glycol monomethyl ether, propylene glycol monoethyl ether, propylene glycol——η-propyl acid, propylene glycol mono-η-butyl acid, etc. ; Dipropylene glycol monomethyl ether, dipropylene glycol monoethyl ether, dipropylene glycol 1-11-This paper size applies to China National Standard (CNS) A4 specifications (210 X 297 mm) 405047 A7 B7 V. Description of the invention 0) 1 Polypropylene glycol monoalkyl ethers such as η-propyl ether, dipropylene glycol mono-η-butyl ether, tripropylene glycol monomethyl ether, and tripropylene glycol monoethyl ether Propylene glycol monoalkyl ether acetates such as propylene glycol monomethyl ether acetate, propylene glycol monoethyl ether acetate, etc .; diethyl ether, ethyl i-propyl ether, di-i-propyl ether, diethylene glycol Dimethyl ether, diethylene glycol methyl ether, diethylene glycol diethyl ether, tetrahydrofuran, 1,4-dioxane and other ethers; acetone, methyl ethyl ketone, methyl 1-butane Ketones such as ketones, cyclohexanone, 2-pentanone, 3-pentanone, and diacetone alcohol; alkyl lactates such as methyl 2-hydroxypropionate and ethyl 2-hydroxypropionate > 2-hydroxyl-2 -Ethyl methyl propionate, methyl 3-hydroxypropionate, ethyl 3-methoxypropionate, methyl 3-ethoxypropionate, ethyl 3-ethoxypropionate, ethoxyacetic acid Ethyl acetate, ethyl propoxyacetate, methyl 2-hydroxy-3-methylbutanoate, 3-methyl-3-methoxybutyrate, 3-methyl-3-methoxypropionate , Ethyl acetate, n-butyl acetate, i-butyl acetate, i-amyl formate, i-amyl acetate, n-butyl propionate, ethyl butyrate, i-propyl butyrate, butyric acid η — butyl ester, methyl pyruvate, ethyl pyruvate Pyruvic acid η-propyl ester, acetic acid methyl acetate, acetic acid ethyl acetate, 2-carbonyl butyrate, dimethyl carbonate and other esters, Ν-methylpyridone, Ν, Ν_ 二Methylamine, methylamine, N, N-dimethylacetamide and other amines; methanol, ethanol, i-propanol, ethylene glycol, diethylene glycol, glycerol ---- --------- install ------ II order --------- line (please read the precautions on the back before filling this page) The paper size of the paper is applicable to Chinese National Standard (CNS) A4 (210 X 297 mm) -12- 405047 A7 B7_ V. Description of the invention (10) and other alcohols; (Please read the precautions on the back before filling this page ) Other high-polarity solvents such as dimethyl master, acetonitrile, pyridine, etc .; η-pentane, η-hexane, η-heptane, cyclohexane and other aliphatic hydrocarbons; aromatic hydrocarbons such as toluene and xylene; Methyl chloride, chloroform, carbon tetrachloride, 1,1-dichloroethane, 1 '2-dichloroethane, 1,1,1-trichloroethane, 1,1,2-trichloroethane, Halogenated hydrocarbons such as hexachlorobenzene; etc. These solvents may be used alone or in combination of two or more. In the foregoing solvent, for example, benzylethyl ether, dihexyl ether, acetone, isophorone, hexanoic acid, caprylic acid, 1-octanol, 1-nonanol, benzyl alcohol, and acetic acid can be reused. High-boiling solvents such as benzyl ester, ethyl benzoate, diester oxalate, diester maleate, r-butyrolactone, ethylene carbonate, propylene carbonate, and ethylene glycol monophenyl ether acetate. The above-mentioned high-boiling-point solvents can be used alone or in combination of two or more. ○ Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs. The acid used in the above-mentioned acidic aqueous solution can be organic or inorganic. Organic acids such as acetic acid, propionic acid, butyric acid, valeric acid, trimethylacetic acid, hexanoic acid, diethylacetic acid, heptanoic acid, capric acid and other aliphatic monocarboxylic acids »oxalic acid, malonic acid, succinic acid, Glutaric acid, adipic acid, pimelic acid, suberic acid, azelaic acid, sebacic acid, azelaic acid, methylmalonic acid, ethyl 13. This paper size applies to China National Standard (CNS) A4 (21〇X 297 public love) A7 405047 -------- B7__ 5. Description of the invention (11) Malonic acid, dimethylmalonic acid, methylsuccinic acid, tetramethylsuccinic acid, 1 ' 4 —aliphatic dicarboxylic acids such as cyclohexanedicarboxylic acid, itaconic acid, citraconic acid, maleic acid, fumaric acid, and mesaconic acid; aliphatic tricarboxylic acids such as triaminocarboxylic acid, aconitic acid, and carpenic acid Acids; aromatic monocarboxylic acids such as benzoic acid, toluic acid, humic acid, dimethylbenzoic acid, and trimethylbenzoic acid; phthalic acid, isophthalic acid, terephthalic acid, and other aromatic dicarboxylic acids Acids; trimellitic acid, trimellitic acid, trimellitic acid, pyromellitic acid and other three polyvalent aromatic polycarboxylic acids; glycolic acid, lactic acid, (2-oxobutanoic acid , Glyceric acid, hydroxymalonic acid 'malic acid, tartaric acid, citric acid, salicylic acid, P-oxobenzoic acid' dihydroxybenzoic acid, picric acid, tropic acid, coumaric acid, dihydroxycinnamic acid And other oxocarboxylic acids; and phenylacetic acid, hydrogenated atropic acid, hydrogenated cinnamic acid, phenylsuccinic acid, atropic acid, cinnamic acid, cinnamic acid, etc. The foregoing inorganic acids are, for example, sulfuric acid, nitric acid, carbonic acid, chloric acid , Perchloric acid, etc. At this time, sulfuric acid aqueous solution can use concentrated sulfuric acid, hot concentrated sulfuric acid, dilute sulfuric acid, etc. These acids can be used alone or in combination of two or more. The alkali used in the above-mentioned inorganic alkaline aqueous solution can be Use an inorganic or organic base. The previous inorganic bases are, for example, sodium hydroxide, potassium hydroxide, sodium carbonate, potassium carbonate, sodium bicarbonate, potassium hydrogen refractory, calcium hydroxide, barium hydroxide, etc. ---! Ί! -^ Install! 1 order · 1 I line, (Please read the notes on the back before filling out this page) Printed by the Intellectual Property Bureau Staff Consumer Cooperatives of the Ministry of Economy This paper is printed in accordance with China National Standard (CNS) A4 (210 X 297 mm) -14- 405047 Ministry of Economic Affairs Printed by the Consumers' Cooperative of the Property Bureau V. Description of the invention (12) Preface organic bases, such as ethanol diethylamine ethanol, 2- (di-1-1 propylamino) ethanol, alcohol 3--dimethylamino ― 1 monopropanol 2 dimethylamino group ― 1 ― propanol Λ 4 ― dimethylamino group ― 2 ― butanol, 3 ― dimethylamino group ~ 2 butanol, 5 ― dimethylamino group ― 2 monopentyl alcohol, 4-dimethylamino group-2-butanol, and other alcohol amines-methylamine, dimethylamine >, monoethylamine > diethylamine dimono-Π-propyl Amine — η — — i monopropylamine mono- η — butyls 0 This basic compound can be mono- or 0 in these solvents > The cleaning power is in addition to pure water 7 organic solvents with-. Esters' tetrahydrofuran methyl carbonate > N-methylpyridine Λ ~~ · methyl ethyl alcohol, methanol ethanol is preferably r-butyrolactone and the like. Amine, 2-dimethylamine ethanol, 2-η-propylamino) ethanol, 2- (2- (di-η-butylpropyl) ethylenepropanol, 3-diethylamino-1-11 —Propanol, 2-diethylamino- 1 2-butanol'4—diethylamino——2-butanol, 3-diethylamino—2—pentanol, 5-diethyl Aminoamine amino-2-butanol, 4-diethylj trimethylamine, tetramethylammonium hydroxide ethylamine, tetraethylammonium hydroxide, propylamine, single i-propylamine One or two or more alkylamines such as diamine, di-n-butylamine, and di-n-butylamine are used in combination with propylene glycol monomethyl ether, propylene glycol acetone, cyclohexanone, diacetone alcohol from the viewpoint of affinity with the coloring agent , Dioxanone, Ν, Ν-dimethylformamide, i-propanol, η-hexane, toluene, carbon tetrachloride, etc. are preferred, high-boiling-point solvents — ΙΊΙ — ———— — — — 1 .Packing · 1 — 11 order-!! Line,. (Please read the notes on the back before filling out this page> This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) -15- Economy Intellectual Property Office Printed by employee consumer cooperatives 405047 V. Description of the invention (13) In addition, the acidic aqueous solution is 1% by weight aqueous oxalic acid solution, 1% by weight phthalic acid, 1% by weight citric acid solution, concentrated sulfuric acid, hot concentrated sulfuric acid, Dilute sulfuric acid is preferred. Also, alkaline aqueous solutions such as aqueous solutions of inorganic bases such as sodium hydroxide and potassium hydroxide; organic solvents such as ethanolamine, 2-dimethylaminoethanol, triethylamine, and tetramethylammonium hydroxide. An alkaline aqueous solution is preferred. The washing step performed before using the solvent is, for example, (c-1) using a mixture of a colorant and a solvent using a Dior mixer, a homogenizer, a homogenizer, a feed mixer, Mixing devices such as 3-axis, 2-axis, granulation rollers, etc., for 1 minute to 70 hours, preferably for 5 minutes to 24 hours, more preferably for 10 minutes to 6 hours, after filtration, decantation and other steps After the solvent is separated, the dispersion and washing step of drying is performed; (c _ 2). The mixture of the colorant and the solvent is placed in an ultrasonic mixing device such as an ultrasonic dispersing homogenizer and an ultrasonic washing machine. ~ 3 0 0KHz, preferably 2 ~ ΙΟΟΚΗζ The ultrasonic wave of wave number is processed for 30 seconds to 10 hours, preferably 1 minute to 5 hours. After the solvent is separated by filtration, decantation and other steps, the ultrasonic washing step is dried; (c -3). Put the mixture of colorant and solvent into a mixer equipped with a stirring blade, and use the number of revolutions of 50 ~ 1 5000 r pm, preferably 100 ~ 2000 r pm, for 5 minutes ~ 1 ◦ hours, It is preferably stirring for 10 minutes to 5 hours, a stirring and washing step for separating the solvent after filtration, decantation, and other steps, and the like. Also, the steps of (c-1) to (c-3) 'Can be implemented individually or in any combination of two or more steps. This paper size applies to China National Standard (CNS) A4 specifications (210 X 297 mm) -16-IIJIIIIIII Packing · 1 · 1 Order ------------ ^-1 (Please read the precautions on the back first (Fill in this page again) Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 405047 a7 _________B7_ V. Description of the invention (14) A refined coloring agent can be prepared according to this solvent washing method. (d) Sublimation method The sublimation method is a method of purifying a colorant by sublimating it by heating it under normal pressure or reduced pressure. The heating temperature used to sublimate the colorant generally varies depending on the type or pressure of the colorant, such as the use of copper titanium green such as C · I. Bigman Green-7, C. I. Bigman Green-3 6 When the pigment is refined, it is generally 200 to 800 ° C, preferably 300 to 600 ° C, under normal pressure. According to this sublimation method, a refined coloring agent can be obtained. (e) Vacuum heating method The vacuum heating method is generally a method in which a colorant is placed in a pressure-resistant container and is purified by heating under vacuum. The heating temperature of the vacuum heating method varies according to the type of colorant. Too high a temperature will cause the colorant to sublimate, and too low a temperature will make it difficult to remove impurities. Therefore, it is generally below 20 t 〇rr It is preferable that the range is 10 t rr or less. According to this vacuum heating method, a refined coloring agent can be obtained. In the present invention, each of the refining methods (a) to (e) may be performed once or repeatedly. The preferred combinations of the refining methods (a) to (e) in the foregoing (e.g., the combination of (a) recrystallization method and (c) solvent cleaning method (recrystallization) The paper size applies to Chinese National Standard (CNS) A4 specifications (210 X 297 mm) -17- (Please read the precautions on the back before filling in this page > Pack — 1 — Order — — — — — I-Line-405047 A7 B7 V. Description of Invention (15) • Solvent washing method), (b) Combination of reprecipitation method and (c) Solvent washing method (reprecipitation · solvent washing method), (c) Combination of solvent washing method and (e) Vacuum heating method (solvent (Washing / solvent washing method), or (c) a solvent washing method, a combination of cleaning by replacing two or more solvents (multiple solvent washing method), etc. In the present invention, the obtained coloring agent is refined The fineness system is 0.9 or more, and more preferably 0.93 or more. At this time, if a coloring agent with a fineness system below 0.9 is used, the voltage retention rate, grilling, and poor orientation of the liquid crystal display element will be reduced. , And will cause poor display state or light transmission after power-on, so it is a poor condition. Refined colorants can be used alone or in a combination of two or more types. In the present invention, depending on the situation, unrefined colorants and refined colorants can be refined in a mixture of 2 colorants. It is used under the conditions of 0.9 or more. The unrefined coloring agent is not particularly limited in hue, and organic colorants or inorganic colorants can be used. Among the unrefined coloring agents, organic colorants such as dyes , Organic pigments, natural pigments, etc. In addition to the foregoing inorganic colorants, for example, in addition to inorganic pigments, inorganic salts generally referred to as constitutional pigments, etc. are also included. Also, the "unrefined colorant in the present invention has high color development" And high heat-resistant coloring agents, especially those with high thermal decomposition resistance are better 'Generally, the use of organic colorants, and the use of organic pigments is the best.-,! ·! —Order!-Line , • (Please read the precautions on the back before filling out this page) Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs ^ Paper size applicable _ 豕 Standard (CNS) A4 (210 X 297 mm) 18 A7 405047 _________B7 __ 5. Description of the invention (16) Specific examples of unrefined organic pigments and inorganic pigments, such as the compounds of organic pigments and inorganic pigments exemplified in the refined colorants. These unrefined pigments can be used alone or can be used. Two or more kinds are mixed and used. The coloring agent in the present invention may be used together with a dispersant depending on the intended purpose. Such dispersants are, for example, cationic, anionic, nonionic, amphoteric, polysiloxane Surfactants such as alkane and fluorine series. The surfactants mentioned above, such as polyoxyethylene lauryl ether, polyoxyethylene stearyl ether, polyoxyethylene oleyl ether and other polyoxyethylene alkyl ethers; polyoxyethylene octyl ether, Polyoxyethylene alkylene ethers such as polyoxyethylene nonyl ether; polyethylene glycol diesters such as polyethylene glycol dilaurate, polyethylene glycol distearate: sorbitol hexamine esters; Fatty acid polyesters; Grade 3 amine denatured polyurethanes; other than polyethyleneimines, such as KP (manufactured by Shin-Etsu Chemical Industry Co., Ltd.), Polyfluoro (manufactured by Kyoei Oil Chemical Industry Co., Ltd.), and fluorine metal Top ( (Manufactured by Toko Manufacturing Co., Ltd.), Mecfaq (manufactured by Dainippon Ink Co., Ltd.), fllorite (manufactured by Sumitomo 3M Co., Ltd.), Asahi Card, Safulon (above, manufactured by Asahi Glass Co., Ltd.), etc. These surfactants can be used alone or in combination of two or more compounds. The amount of the surface active agent used is generally 50 to 50 parts by weight based on 100 parts by weight of the colorant, and preferably 0 to 40 parts by weight. (Β) Composition The size of this paper applies the Chinese National Standard (CNS) A4 specification (210 X 297 mm) "19- ~~---- J — II--I I--i!! I Order-III! · Line-• (Please read the notes on the back before filling out this page) Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs, printed by 405047 5. Description of the Invention 耖) The component (B) in the present invention is a kind of visible light, Under the exposure of ultraviolet rays, far ultraviolet rays, electron rays, X-rays, and the like, the photopolymerization initiator that starts polymerization of the component (C) to be described later and generates active species

此光聚合起始劑，例如至少具有1種以下式（式C 3 )或式（4 )爲主要骨架之聯二咪唑以外，This photopolymerization initiator, for example, has at least one of the following formula (Formula C 3) or Formula (4) having a main skeleton other than biimidazole,

)γ\ -Ν Ν (2) (3) (請先閱讀背面之注意事項再填寫本頁> Η ⑷ 經濟部智慧財產局員工消費合作社印製其他如苯偶因系化合物、酮苯酚系化合物、二苯甲酮系化合物、α -二酮系化合物、多核苯酮系化合物、氧雜蒽酮系化合物、重氮系化合物、三嗪系化合物等等。其中又以聯二咪唑爲最佳。前記聯二咪唑系化合物之具體例如，2，2，~雙（2 —氯苯基）一4，4，，5，5’一四（4 一乙氧羰基苯基）一 1 ’ 2’ —聯二咪唑、2，2,一雙（2 —溴苯基）一 4， 4’’ 5，5’一四（4 一乙氧羰基苯基）一1，2,一聯二本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） -20- 經濟部智慧財產局員工消費合作社印製 A7 405047 B7 五、發明說明（18 ) 咪唑、2，2’一雙（2，4 —二氯苯基）一4 , 4，，5， 5’一四苯基一 1，2，—聯二咪唑、2，2,一雙（2，4 ，6 —三氯苯基）一4，4，，5，5’一四苯基一 1，2，一聯二咪唑、2，2’ —雙（2，4 一二溴苯基）一4，4 ’ 5，5’一四苯基—1 ，2’一聯二咪唑及2，2’一雙（ 2，4，6 —三溴苯基）一4，4’，5，5，一四（4 —乙氧羰基苯基）一 1，2 ’ 一聯二咪唑等等。前記聯二咪唑系化合物，對溶劑具有優良溶解性、不會產生未溶解物、析出物等異物，此外感度極高，故可使用較低能量之曝光即可使硬化反應充分進行，此外對比亦較高，而不會使未曝光部份產生硬化反應。因此，曝光後之塗膜上，可以明確地區分對顯影液爲不溶性之硬化部份，與對顯影液具有高度溶解性之未硬化部份，且可以形成不會產生圖型缺落、損壞或底割（under cut )現象之優良濾色器。其他例如前記苯偶因系化合物，例如苯偶因、苯偶因甲基醚、苯偶因乙基醚、苯偶因i 一丙基醚、苯偶因i -丁基醚、甲基- 2 —苯偶因苯甲酸酯等。酮苯酚系化合物例如2，2 -二甲氧基—2 —苯基酮苯酚、2 -羥基一 2 -甲基一 1 一苯基丙烷一 1 一酮、1 一（4 —i 一丙基苯基）一 2 —羥基—2 —甲基丙烷一 1 —酮、4— (2 -羥基乙氧基）苯基—（2 —羥基一 2 -丙基）酮、2，2 -二甲氧基酮苯酚、2，2 —二乙氧基酮苯酚、2 -甲基一（4 一甲基硫苯基）一 2 —嗎啉基一 1—丙烷—1 一酮、2 —苄基一 2 —二甲基胺基一（4 一本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） -21 - — In----—III! - I II---—訂· I I II I---*5^ , (請先閲讀背面之注意事項再填寫本頁) 405047 五、發明說明（19 ) 嗎啉苯基）丁烷一 1 一酮、1 一羥基環己苯基酮、4 -迭氮基酮苯酚、4 -迭氮基亞苄基酮苯酚等。前記二苯甲酮系化合物例如，二苯甲酮、4，4’一雙 (二甲基胺基）二苯甲酮、 4，4’一雙（二乙基胺基）二苯甲酮、3 ，3 ’一二甲基一4一甲氧基二苯甲酮等。前記α -二酮系化合物例如，乙醯、苯醯、甲基苯醯甲酯等。前記多核苯酮系化合物例如，蒽醌' 2 -乙基蒽醌、 2 — t -丁基蒽醌、1 ，4 一萘醌等。前記氧雜蒽酮系化合物例如，氧雜蒽酮、硫基氧雜蒽酮、2，4 一二乙基氧雜蒽酮、2 -氯硫基氧雜蒽酮等等〇前記重氮系化合物例如，4 一重氮基二苯基胺、4 — 重氮基一 4’一甲氧基苯基胺、4 一重氮基—3 —甲氧基二苯基胺等等。前記三嗓系化合物例如，2 -（ 2 ’ 一呋喃亞乙基）一 4，6 -雙（三氯甲基）一 s—三嗪、 2 —（3’，4’一二甲基苯乙烯基）一4，6 -雙（三氯甲基）一 s —二嗪、2— (4’一甲氧基蔡基）一 4 ’ 6 一雙（三氯甲基）一 s —三嗪、2 - (2’一溴基一 4’ —甲基苯基）—4，6 -雙（三氯甲基）—s—三嗪、2—( 2’一硫苯基亞乙基）一4，6 —雙（三氯甲基）一 s —三嗪等。 (請先閱讀背面之注意事項再填寫本頁) 裝— II訂_! !線- 經濟部智慧財產局員工消費合作社印製本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） -22- 經濟部智慧財產局員工消費合作社印製 405047 A7 一 B7 五、發明說明Co ) 又’除前記以外之光聚合起始劑’例如可使用4 -迭氮基苯甲醛、嵌二萘、雙（2，6 —二甲氧基苯醯基）一 2，4，4 一三甲基戊基磷氧化物、N —苯基硫吖啶酮、三苯基吡喃鑰全氯鹽等等。本發明中，光聚合起始劑可單獨使用或將2種以上混合使用皆可。本發明中，光聚合起始劑之使用量，對（C)成分 100重量份而言，一般爲0.01〜200重量份，較佳爲1〜120重量份，最佳爲1〜50重量份。此時，光聚合起始劑之使用量若低於0 . 0 1重量份時，曝光所產生之硬化程度並不充分，會有產生圖型缺落、損壞或底割（under cut)現象之疑慮，又，超過2 0 0重量份時，對於所形成之圖型而言，在顯像時極容易由基板上脫落，或會對形成圖型以外之部份產生污染、或生成殘留物等。此外，本發明中，前記光聚合起始劑可與增感劑、硬化促進劑、高分子光交聯·增感劑等合倂使用。前記增感劑，例如4 一二乙胺基苯乙酮、4 ~二甲胺基苯丙酮、乙基一 4 一二甲胺基苯甲酸酯、2 —乙己基一 1 ，4 —二甲胺基苯甲酸酯、2，5 -雙（4，一二乙胺基苯亞甲基）環己酮、7 -二乙胺基一3 —（4 一二乙胺基苯甲醯基）香豆素、4 -（二乙胺基）苯丙烯醯苯等。此些增感劑，可以單獨使用或將2種以上混合使用皆可。又，前記硬化促進劑例如，2 -氫硫基苯駢咪唑、2 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） -23- Γ-------!~ 裝--------訂---------線' (請先10讀背面之注意事項再填寫本頁) 405047 Α7 --Β7 五、發明說明幻） (請先閱讀背面之注意事項再填寫本頁) 一氫硫基苯駢噻唑、2 —氫硫基苯駢噁唑、2，5 -二氫硫基一 1 ，3，4一噻唑、2 —氫硫基一 4，6_二甲胺基嘧啶等連鎖移動劑等等。此些硬化促進劑’可以單獨使用或將2種以上混合使用皆可。又’前記高分子光交聯·增感劑，例如爲一種以可因曝光而使交聯劑及/或增感劑產生作用之官能基爲主鏈及 /或支鏈之高分子化合物。其例如4 -迭氮基苯甲醛與聚乙Μ醇之縮合物、4 -迭氮基苯甲醛與酚醛樹酯之縮合物 ' 4 -丙烯醯苯基肉桂醯酯之寡聚物或共聚物、1，4 一聚丁二烯、1 ’ 2 -聚丁二烯等。此些高分子光交聯·增感劑，可以單獨使用或將2種以上混合使用皆可。本發明中，增感劑、硬化促進劑及高分子光交聯•增感劑之合計使用量，對光聚合起始劑1 〇〇重量份而言，一般爲3 0 0重量份以下，較佳爲5〜2 0 0重量份，更佳爲1 0〜1 0 0重量份。經濟部智慧財產局員工消費合作社印製本發明中，光聚合起始劑，例如使用聯二咪唑系化合物Μ二苯甲酮系化合物及/或噻唑系硬化促進劑之組合時，所形成之畫素於顯像時不易由基板脫落，且具有高畫素強度及感度，故爲較佳之選擇。本發明中，光聚合起始劑之聯二咪唑系化合物若與其他成分倂用時，其他成分之使用量以對全體光聚合起始劑爲3 0重量％以下爲佳。 -24- 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） 405047 A7 B7_ 五、發明說明紅）本發明中，最佳之光聚合起始劑若以其所構成之組成份作一說明時，例如下述所示內容。 2，2,一雙（2 —氯苯基）一4，4’，5，5’一四 (4 一乙氧羰基苯基）一1，2’一聯二咪唑/4，4’一雙 (二乙胺基）二苯甲酮、 2，2’一雙（2 —氯苯基）一4，4’，5，5,一四 (4 —乙氧羰基苯基）一1，2’一聯二咪唑/ 4，4’_雙 (二乙胺基）二苯甲酮/2 -苄基一 2 —二甲胺基一 1 — (4 一嗎啉苯基）丁烷一 1 一酮、 2，2’一雙（2 —氯苯基）一 4，4’，5，5’ —四 (4 一乙氧羰基苯基）一1，2’一聯二咪唑/4，4’一雙 (二乙胺基）二苯甲酮/1一羥基環己苯基酮、 2，2’一雙（2 — 氯苯基）一4，4’，5，5’ —四 (4 一乙氧羰基苯基）—1，2’一聯二咪唑/ 4，4 雙 (二甲胺基）二苯甲酮/1一羥基環己苯基酮/2-氫硫基苯駢噻唑、 2，2’一雙（2，4 —二氯苯基）一4，4，，5， 5’一四苯基一 1 ，2’ —聯二咪唑/ 4，4’一雙（二乙胺基）二苯甲酮、 2，2’一雙（2，4 —二氯苯基）一4，4’，5， 5’一四苯基—1 ，2’一聯二咪唑/ 4，4’ —雙（二乙胺基：^二苯甲酮/ 2 —苄基一 2 —二甲胺基一1 一（4 一嗎啉苯基）丁烷一1一酮、 2，2’ —雙（2，4 —二氯苯基）—4，4’，5， ------------I I i!!11---------線' (請先閱讀背面之注意事項再填寫本頁) 經濟部智慧財產局員工消費合作社印製本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） -25- 405047 A7 B7 五、發明說明鉍）基）四苯基一 1 ’ 2’一聯二咪唑/ 4，4’一雙（二乙胺二苯甲酮/2 —苄基一 2 —二甲胺基一 1— (4 一嗎啉苯基）丁烷一1一酮/2-氫硫基苯駢噻唑、 2 雙（2，4 一二溴 4 ，4， 5’~四苯基一1 ’ 2’ —聯二咪唑/ 4 ’ 4,一雙（二乙胺基）二苯甲酮/2 —苄基一 2 —二甲胺基一1— (4 —嗎啉苯基）丁烷一1一酮、 2 ’ 2’ —雙（2，4 一二溴苯基）一4，41，5， 5’一四苯基一1 ，2，一聯二咪唑/ 4，4’一雙（二乙胺基）二苯甲酮/1一羥基環己苯基酮、 2，2’一雙（2 ’ 4 ’ 6 —三氯苯基）—4，4’， 5 ’ 5’一四苯基—1，2’ —聯二咪唑/ 4，4，—雙（二苯甲酮/ 1 -羥基環己苯基酮/2〜氫硫基苯 (請先閱讀背面之注意事項再填寫本頁) 駢噻唑裝·--— — — — —訂！---線經濟部智慧財產局員工消費合作社印製 (C )成分本發明之（C )成分，係由分子內含有2個以上具有聚合性之乙烯性不飽和性鍵結之多官能性單體所構成。此些多官能性單體，例如乙二醇、丙二醇等烷二醇之二（甲基）丙烯酸酯類；聚乙二醇、聚丙二醇等聚烷二醇之二（甲基）丙烯酸酯類；丙三醇、三羥甲基丙烷、季戊四醇、二季戊四醇、琥珀酸變性季戊四醇等3價以上之多價醇之聚（甲基）丙烯酸酯類；聚酯、環氧樹脂、尿烷樹脂、醇酸樹脂、聚矽氧烷樹脂、螺烷樹脂等低（甲基）丙本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） -26- 405047 A7 B7 五、發明說明如）烯酸酯類；二末端羥基聚一 1，3- 丁二烯、二末端羥基聚異戊二烯、二末端羥基聚己內酯等二末端羥基化聚合物之二（甲基）丙烯酸酯類或、反（2 —（甲基）丙烯醯基氧乙基）磷酸酯等。此些多官能性單體中，以3價以上醇的聚（甲基）丙烯酸酯類爲佳，具體而言，例如三羥甲基丙烷三丙烯酸酯、三羥甲基丙烷三甲基丙烯酸酯、季戊四醇基三丙烯酸酯、季戊四醇基三甲基丙烯酸酯、季戊四醇基四丙烯酸酯、季戊四醇基四甲基丙烯酸酯、二季戊四醇基五丙烯酸酯、二季戊四醇基五甲基丙烯酸酯、二季戊四醇基六丙烯酸酯、二季戊四醇基六甲基丙烯酸酯、琥珀酸變性季戊四醇基三丙烯酸酯等，以具有高畫素強度、優良之畫素表面平滑度、且不易污染畫素形成之部份以外之區域、或產生殘留物等，故爲較佳之選擇。本發明之多官能性單體，可單獨使用或將2種以上混合使用。本發明之多官能性單體之使用量，對於後述之（D ) 成分1 0 0重量份，一般爲5〜5 0 0重量份，更佳爲 2 0〜3 0 0重量份。此時，多官能性單體之使用量若未達5重量份時，會有畫素強度或畫素表面平滑性不佳之傾向，又，若超過5 0 0重量份時，例如會有鹼顯像性降低，且會污染畫素形成之部份以外之區域、或產生殘留物等傾向。本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） 111 J 11 —Ί 11 In 裝.！11· —---- _線， -(請先閱讀背面之注意事項再填寫本頁) 經濟部智慧財產局員工消費合作社印製 -27- 經濟部智慧財產局員工消費合作社印製 __ 405047 五、發明說明紅 (D )成分本發明之使用，且只要液爲可溶性下溶性樹脂例如脂。鹼可溶性 1個以上羧基基之不飽和單前記含羧含有羧基之不和單體（以下混合物之共聚 d)」）爲佳酸；馬來酸、、檬康酸、無 )類；3價以 A7 B7 (D)成分’對（A)成分而言作爲膠粘劑是封於製造濾色器之顯像處理步驟之驗顯像 ’即可選擇適當的驗可溶性樹脂。此些驗可 ’羧基、苯酚性羥基等含有酸性官能基之樹樹脂中，含羧基之鹼可溶性樹脂例如，含有之乙烯性不飽和單體（以下，簡稱爲「含羧體」）之（共）聚合物等。基之不飽和單體之（共）聚合物，特別是以飽和單體與可與其他產生共聚之乙烯性不飽 ’簡稱爲「其他不飽和單體」）所成之單體合物（以下，簡稱爲「含羧基之共聚合物（前記含羧基之不飽和單體，例如（甲基）丙烯酸、巴豆酸、α -氯丙烯酸、乙基丙烯酸、桂皮酸等不飽和一羧無水馬來酸、富馬酸、衣康酸、無水衣康酸水檬康酸、中康酸等不飽和二羧酸（無水物上之不飽和多價竣酸（無水物）類；琥珀酸單（2 -（甲基）丙烯氧基乙酯）、苯二酸單 (2-（甲基）丙烯氧基乙酯）等2價以上之多價羧酸之單（甲基）丙烯氧基烷酯類； ω -羧基一聚己內醯胺一等二末端 (請先閱讀背面之注意事項再填寫本頁) 裝！ —訂- 111 — !-線 ' ί . 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） -28- 經濟部智慧財產局員工消費合作社印製 405047 五、發明說明泛6 ) 殘基聚合物之一（甲基）丙烯酸酯類等。此些含羧基之不飽和單體，可單獨或將2種以上混合使用。又前記之其他不飽和聚合物，例如，苯乙烯、α -甲基苯乙烯、〇 —乙烯基甲苯、m_乙烯基甲苯、Ρ —乙稀基田苯、〇一氯基苯乙嫌、m —氯基苯乙稀、P —氯基苯乙稀、〇 —甲氧基苯乙稀、m —甲氧基苯乙嫌、P —甲氧基苯乙烯、茚、〇 —乙烯基苄甲基醚、m —乙烯基苄甲基醚、P -乙烯基苄甲基醚、〇 —乙烯基苄甘油醚、m -乙烯基苄甘油醚、p -乙烯基苄甘油醚等芳香族乙烯化合物〇甲基丙烯酸酯、甲基甲基丙烯酸酯、乙基丙烯酸酯、乙基甲基丙烯酸酯、η -丙基丙烯酸酯、η -丙基甲基丙烯酸酯、i -丙基丙烯酸酯、i 一丙基甲基丙烯酸酯、i 一丁基丙烯酸酯、1 一丁基甲基丙烯酸酯、sec —丁基丙_酸酯' s e c - 丁基甲基丙烯酸酯、t 一丁基丙烯酸酯、t 一丁基甲基丙烯酸酯、2 —羥乙基丙烯酸酯、2 -羥乙基甲基丙烯酸酯、2 -羥丙基丙烯酸酯、2 -羥丙基甲基丙烯酸酯、3 -羥丙基丙烯酸酯、3 -羥丙基甲基丙烯酸酯、2 -羥丁基丙烯酸酯、2 -羥丁基甲基丙烯酸酯、：3 -羥丁基丙烯酸酯、3 -羥丁基甲基丙烯酸酯、4-羥丁基丙烯酸酯、4 -羥丁基甲基丙烯酸酯、戊基丙烯酸酯、戊基甲基丙烯酸酯、苄基丙烯酸酯、苄基甲基丙烯酸酯、環己基丙烯酸酯、環己基甲基丙烯酸酯、苯基丙烯酸本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） -29- ------—.1 -------- I I I 訂.！ I ! -售 >(請先閱讀背面之注意事項再填寫本頁) 405047 五、發明說明泛7 ) 酯' 苯基甲基丙烯酸酯、2 -甲氧乙基丙烯酸酯、2 -甲氧乙基甲基丙烯酸酯、2 -苯氧乙基丙烯酸酯、2 —苯氧乙基甲基丙烯酸酯、甲氧二乙二醇基丙烯酸酯、甲氧二乙二醇基甲基丙烯酸酯、甲氧丙三醇基丙烯酸酯、甲氧丙三醇基甲基丙烯酸酯、甲氧基二丙二醇基丙烯酸酯、甲氧基二丙二醇基甲基丙烯酸酯、異冰片基丙烯酸酯、異冰片基甲基丙烯酸酯、二環戊二烯基丙烯酸酯、二環戊二烯基甲基丙烯酸酯、2 -羥基一 3 -苯氧丙基丙烯酸酯、2 —羥基- 3 -苯氧丙基甲基丙烯酸酯、甘油基一丙烯酸酯、甘油基一甲基丙烯酸酯等不飽和羧酸酯類； 2 -胺乙基（甲基）丙烯酸酯、2 —二甲基胺乙基（甲基）丙烯酸酯、2 -胺丙基（甲基）丙烯酸酯、2 —二甲基胺丙基（甲基）丙烯酸酯、3 -胺丙基（甲基）丙烯酸酯、3 -二甲基胺丙基（甲基）丙烯酸酯等不飽和羧酸胺烷基酯類；經濟部智慧財產局員工消費合作杜印製環丙氧基（甲基）丙烯酸酯等不飽和羧酸環丙酯類；乙酸乙酯、丙酸乙酯、丁酸乙酯、安息酸乙酯等羧酸乙酯類；乙烯基甲基醚、乙烯基乙基醚、烯丙基甘油醚、甲代烯丙基甘油醚等不飽和醚類； (甲基）丙烯醯胺、α -氯基丙烯醯胺、氰化亞乙烯基等氰化乙烯化合物；馬來醯胺、Ν -環己基馬來醯胺、Ν -苯基馬來醯胺等不飽和醯胺類； -30- -(請先閱讀背面之注意事項再填寫本頁) 本紙張尺度適用令國國家標準（CNS)A4規格（210 X 297公釐） A7 405047 B7 五、發明說明細） 1，3 - 丁二烯、異戊二烯、氯戊二烯等脂肪族共價二烯類；聚苯乙烯、聚甲基（甲基）丙烯酸酯、聚η -丁基（甲基）丙烯酸酯、聚矽氧烷等聚合物分子鏈之末端具有單 (甲基）丙烯醯酸基之巨大單體類等等。此些其他不飽和單體，可以單獨使用或將2種以上混合使用皆可。含羧基之共聚合物（d)例如爲由（1)(甲基）丙烯酸與，（2)苯乙烯、甲基（甲基）丙烯酸、2 —羥乙基（甲基）丙烯酸、苄基（甲基）丙烯酸、苯基（甲基）丙烯酸、N-苯基馬來醯胺、聚苯乙烯巨大單體及聚甲基甲基丙烯酸巨大單體群中選出之至少一種所形成之共聚合物〇其中較佳的含羧基之共聚合物（d )之具體例如，丙烯酸/苄基丙烯酸酯共聚合物、丙烯酸/苯乙烯/甲基丙烯酸酯共聚合物、丙烯酸/苯乙烯/苄基丙烯酸酯共聚合物、丙烯酸/甲基丙烯酸酯/聚苯乙烯巨大單體共聚合物、丙烯酸/甲基丙烯酸酯/聚甲基甲基丙烯酸酯巨大單體共聚合物、丙烯酸/苄基丙烯酸酯/聚苯乙烯巨大單體共聚合物丙烯酸/苄基丙烯酸酯/聚甲基甲基丙烯酸酯巨大單本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） (請先閱讀背面之注意事項再填寫本頁)) γ \ -Ν Ν (2) (3) (Please read the notes on the back before filling out this page> Η ⑷ Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs, other benzoin-based compounds, ketophenol-based compounds , Benzophenone-based compound, α-diketone-based compound, polynuclear benzophenone-based compound, xanthone-based compound, diazonium-based compound, triazine-based compound, etc. Among them, biimidazole is the best. Specific examples of the aforementioned biimidazole-based compounds include 2,2, ~ bis (2-chlorophenyl) -4,4,5,5'-tetrakis (4-ethoxycarbonylphenyl)-1 '2' — Bis-imidazole, 2, 2, bis (2-bromophenyl)-4, 4 '' 5, 5 '-tetra (4-ethoxycarbonylphenyl)-1, 2, and 2 China National Standard (CNS) A4 Specification (210 X 297 mm) -20- Printed by Employee Consumer Cooperative of Intellectual Property Bureau of the Ministry of Economic Affairs A7 405047 B7 V. Description of Invention (18) Imidazole, 2, 2 'one pair (2, 4 —Dichlorophenyl) -1,4,4,5,5′-tetraphenyl-1,2,2-biimidazole, 2,2,1bis (2,4,6-trichlorophenyl) -1 4,4,5,5'-tetraphenyl-1,2, dibiimidazole, 2,2'-bis (2,4-dibromophenyl) -4,4'5,5'-four Phenyl-1,2'-bibiimidazole and 2,2'-bis (2,4,6-tribromophenyl) -4,4 ', 5,5, tetrakis (4-ethoxycarbonylphenyl) ) 1,2 'one diimidazole, etc. The former diimidazole compound has excellent solubility in solvents, does not produce foreign matter such as undissolved matter, precipitates, etc. In addition, its sensitivity is very high, so it can use lower energy The exposure can make the hardening reaction fully proceed, and the contrast is also high, and it will not cause the hardening reaction of the unexposed parts. Therefore, the hardened part that is insoluble to the developer can be clearly distinguished on the coating film after exposure. And unhardened parts that have high solubility in the developer, and can form excellent color filters that do not cause pattern loss, damage, or under cut. Other examples include the aforementioned benzoin compounds, For example, Benzoin, Benzoin methyl ether, Benzoin ethyl ether, Benzoin i-propyl ether, Benzoin i-butyl ether, A -2-Benzoin benzoate, etc. Ketophenol compounds such as 2,2-dimethoxy-2-phenylketophenol, 2-hydroxy-1 -methyl-1, 1-phenylpropane-1 Monoketone, 1- (4-i-propylphenyl), 2-hydroxy-2, 2-methylpropane, 1-one, 4- (2-hydroxyethoxy) phenyl- (2-hydroxy-1, 2- (Propyl) ketone, 2,2-dimethoxyketonephenol, 2,2-diethoxyketonephenol, 2-methyl- (4-methylthiophenyl)-2-morpholinyl- 1- Propane—1 ketone, 2—benzyl—2—dimethylamino— (4—This paper size applies to China National Standard (CNS) A4 specifications (210 X 297 mm) -21-— In ---- —III!-I II ---— Order II II I --- * 5 ^, (Please read the notes on the back before filling out this page) 405047 V. Description of the invention (19) Morpholinephenyl) Butane 1-one ketone, 1-hydroxycyclohexanone ketone, 4-azidoketone phenol, 4-azidobenzylidene ketone, and the like. The foregoing benzophenone-based compounds are, for example, benzophenone, 4,4'-bis (dimethylamino) benzophenone, 4,4'-bis (diethylamino) benzophenone, 3,3'-dimethyl-4 4-methoxybenzophenone and the like. The aforementioned α-diketone compounds are, for example, acetamidine, phenylamidine, methylphenylammonium methyl ester and the like. The foregoing polynuclear benzophenone-based compound is, for example, anthraquinone '2-ethylanthraquinone, 2-t-butylanthraquinone, 1,4-naphthoquinone, and the like. Former xanthones, for example, xanthones, thioxanthone, 2,4-diethylxanthone, 2-chlorothioxanthone, etc. For example, 4-diazodiphenylamine, 4-diazo-4'-methoxyphenylamine, 4-diazo-3-methoxydiphenylamine, and the like. For example, three-line compounds such as 2- (2'-furanethylene) -4,6-bis (trichloromethyl) -s-triazine, 2- (3 ', 4'-dimethylstyrene) Group) -4,6-bis (trichloromethyl) -s-diazine, 2- (4'-methoxyzekiyl) -4'6-bis (trichloromethyl) -s-triazine, 2-(2'-bromo-4'-methylphenyl) -4,6-bis (trichloromethyl) -s-triazine, 2- (2'-thiophenylethylene) -4 , 6-bis (trichloromethyl) -s-triazine and the like. (Please read the precautions on the back before filling out this page) Packing — Order II !! Line-Printed by the Employees' Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs This paper is printed in accordance with China National Standard (CNS) A4 (210 X 297 mm) ) -22- Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 405047 A7-B7 V. Description of the invention Co) For 'photopolymerization initiators other than the previous note', for example, 4-azidebenzaldehyde, perylene , Bis (2,6-dimethoxyphenylfluorenyl) -2,4,4-trimethylpentyl phosphorus oxide, N-phenylthioacridone, triphenylpyranyl perchlorate, etc. Wait. In the present invention, the photopolymerization initiator may be used alone or in combination of two or more kinds. In the present invention, the amount of the photopolymerization initiator used is generally 0.01 to 200 parts by weight, more preferably 1 to 120 parts by weight, and most preferably 1 to 50 parts by weight for 100 parts by weight of the component (C). At this time, if the photopolymerization initiator is used in an amount of less than 0.01 parts by weight, the degree of hardening due to exposure is insufficient, and pattern defects, damage, or under cut may occur. If it exceeds 200 parts by weight, the formed pattern may easily fall off from the substrate during development, or it may cause contamination or residues on the parts other than the formed pattern. . In the present invention, the aforementioned photopolymerization initiator may be used in combination with a sensitizer, a hardening accelerator, a polymer photocrosslinking / sensitizing agent, and the like. Former sensitizers, such as 4-diethylaminoacetophenone, 4-dimethylaminophenylacetone, ethyl-4-dimethylaminobenzoate, 2-ethylhexyl-1, 4-dimethyl Aminobenzoate, 2,5-bis (4,1-diethylaminobenzylidene) cyclohexanone, 7-diethylamino-3- (4-diethylaminobenzyl) Coumarin, 4- (diethylamino) phenylpropene, benzene, etc. These sensitizers may be used alone or in combination of two or more. In addition, the aforementioned hardening accelerators are, for example, 2-hydrothiobenzimidazole, and 2 paper sizes are applicable to China National Standard (CNS) A4 (210 X 297 mm) -23- Γ -------! ~ Install -------- order --------- line '(please read the precautions on the back 10 before filling in this page) 405047 Α7 --Β7 V. Invention Description) (Please read first Note on the back page, please fill in this page again) Monohydrothiobenzoxazole, 2-hydrothiobenzoxazole, 2,5-dihydrothio-1, 3,4-thiazole, 2-hydrothio 4,6_ dimethylaminopyrimidine and other chain moving agents and so on. These hardening accelerators' may be used alone or in combination of two or more. The "preliminary polymer photocrosslinking and sensitizer" is, for example, a polymer compound having a main chain and / or a branched chain with a functional group capable of acting on the crosslinker and / or sensitizer due to exposure. It is, for example, a condensate of 4-azidobenzaldehyde and polyethylene glycol, a condensate of 4-azidebenzaldehyde and phenolic resin, an oligomer or copolymer of 4-propenylphenylphenylcinnamate, 1,4 polybutadiene, 1 '2-polybutadiene and the like. These polymer photocrosslinkers and sensitizers can be used alone or in combination of two or more kinds. In the present invention, the total amount of the sensitizer, the hardening accelerator, and the polymer photocrosslinking / sensitizing agent is generally 300 parts by weight or less for 100 parts by weight of the photopolymerization initiator. It is preferably 5 to 200 parts by weight, and more preferably 10 to 100 parts by weight. Printed by the Consumers' Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs of the present invention when the photopolymerization initiator, for example, a combination of a biimidazole-based compound M benzophenone-based compound and / or a thiazole-based hardening accelerator, is drawn. It is not easy to fall off from the substrate during development, and has high pixel intensity and sensitivity, so it is a better choice. In the present invention, if the biimidazole compound of the photopolymerization initiator is used in combination with other components, the amount of other components used is preferably 30% by weight or less with respect to the entire photopolymerization initiator. -24- This paper size is in accordance with Chinese National Standard (CNS) A4 (210 X 297 mm) 405047 A7 B7_ V. Description of the invention Red) In the present invention, if the best photopolymerization initiator is composed of its composition When one copy is explained, for example, the contents shown below. 2,2,1-bis (2-chlorophenyl) -4,4 ', 5,5'-tetra (4-ethoxycarbonylphenyl) -1,2,1-dibiimazole / 4,4'-double (Diethylamino) benzophenone, 2,2'-bis (2-chlorophenyl) -4,4 ', 5,5, tetrakis (4-ethoxycarbonylphenyl) -1,2,' Dibiazole / 4,4'_bis (diethylamino) benzophenone / 2 -benzyl-2 -dimethylamino-1-(4 monomorpholinephenyl) butane-1 monoketone , 2,2'-bis (2-chlorophenyl) -4,4 ', 5,5'-tetra (4-ethoxycarbonylphenyl) -1,2,1'-biimidazole / 4,4'- Bis (diethylamino) benzophenone / 1-hydroxycyclohexanone, 2,2'-bis (2-chlorophenyl) -4,4 ', 5,5'-tetra (4-ethyl Oxycarbonylphenyl) -1,2'-biimidazole / 4,4 bis (dimethylamino) benzophenone / 1 monohydroxycyclohexylphenyl ketone / 2-hydrothiobenzophenthiazole, 2, 2'-bis (2,4-dichlorophenyl) -4,4,5,5'-tetraphenyl-1,2'-biimidazole / 4,4'-bis (diethylamino) Benzophenone, 2,2'-bis (2,4-dichlorobenzene ) -4,4 ', 5,5'-tetraphenyl-1,2'-biimidazole / 4,4'-bis (diethylamino: ^ benzophenone / 2-benzyl-2-- Dimethylamino-1 1- (4-morpholinophenyl) butane-1 1-ketone, 2,2'-bis (2,4-dichlorophenyl) -4,4 ', 5, ---- -------- II i !! 11 --------- line '(Please read the notes on the back before filling out this page) The paper size printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs Applicable to China National Standard (CNS) A4 (210 X 297 mm) -25- 405047 A7 B7 V. Description of the invention Bismuth) Base) Tetraphenyl-1 '2'-biimidazole / 4, 4'-double ( Diethylamine benzophenone / 2-benzyl-1 2-dimethylamino-1 1- (4-morpholinephenyl) butane-1 1-ketone / 2-hydrothiobenzophenthiazole, 2 bis (2 , 4-dibromo 4,4,5 '~ tetraphenyl-1' 2'-biimidazole / 4 '4, one bis (diethylamino) benzophenone / 2-benzyl-1 2-di Methylamino- 1- (4-morpholinylphenyl) butane-1, one, 2 '2'-bis (2,4-dibromophenyl) -4,41,5,5'-tetraphenyl 1,2,1'-diimidazole / 4,4'-bis (diethylamino) benzophenone / 1-hydroxycyclohexanone, 2,2'-bis (2'4'6-trichloro Phenyl) -4,4 ', 5'5'-tetraphenyl-1,2'-biimidazole / 4,4, -bis (benzophenone / 1-hydroxycyclohexanone ketone / 2 ~ Hydrogenthiobenzene (please read the precautions on the back before filling out this page) 骈 Thiazole Pack · ———— — — — — Order! --- Printed (C) component by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs. The (C) component of the present invention is a multifunctional monomer containing two or more polymerizable ethylenically unsaturated bonds in the molecule. Body composition. Such multifunctional monomers, for example, di (meth) acrylates of alkanediols such as ethylene glycol and propylene glycol; poly (meth) acrylates of polyalkanediols such as polyethylene glycol and polypropylene glycol; Poly (meth) acrylates such as glycerol, trimethylolpropane, pentaerythritol, dipentaerythritol, succinic acid modified pentaerythritol, and other polyvalent polyvalent alcohols; polyester, epoxy resin, urethane resin, alkyd Resins, polysiloxane resins, spirane resins and other low (meth) acrylic paper sizes are applicable to Chinese National Standard (CNS) A4 specifications (210 X 297 mm) -26- 405047 A7 B7 V. Description of the invention Acid esters; di (meth) acrylates of di-terminal hydroxylated polymers such as di-terminal hydroxy poly-1,3-butadiene, di-terminal hydroxy polyisoprene, di-terminal hydroxy polycaprolactone, or , Trans (2- (meth) acrylfluorenyloxyethyl) phosphate, etc. Among these polyfunctional monomers, poly (meth) acrylates of trivalent or higher alcohols are preferred, and specific examples thereof include trimethylolpropane triacrylate and trimethylolpropane trimethacrylate. , Pentaerythritol triacrylate, pentaerythritol trimethacrylate, pentaerythritol tetraacrylate, pentaerythritol tetramethacrylate, dipentaerythritol pentaacrylate, dipentaerythritol pentamethacrylate, dipentaerythritol hexaacrylate Esters, dipentaerythritol hexamethacrylate, succinic acid modified pentaerythritol triacrylate, etc., in areas other than the portion with high pixel strength, excellent surface smoothness of the pixel, and not easily contaminated by the pixel, or Residues and the like are preferred. The polyfunctional monomer of the present invention may be used alone or in combination of two or more. The amount of the polyfunctional monomer of the present invention is generally from 5 to 500 parts by weight, and more preferably from 20 to 300 parts by weight, with respect to 100 parts by weight of the component (D) described later. At this time, if the amount of the polyfunctional monomer is less than 5 parts by weight, the pixel strength or the surface smoothness of the pixel tends to be poor, and if it exceeds 5,000 parts by weight, for example, there is an alkali effect. The image quality is lowered, and areas other than the pixel-forming portion are contaminated, or residues are generated. This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) 111 J 11 —Ί 11 In Packing.! 11 · —---- _line,-(Please read the notes on the back before filling out this page) Printed by the Employees 'Cooperatives of the Intellectual Property Bureau of the Ministry of Economics-27- Printed by the Employees' Cooperatives of the Intellectual Property Bureau of the Ministry of Economics __ 405047 V. Description of the Invention The red (D) component is used in the present invention, as long as the liquid is a soluble insoluble resin such as a lipid. Alkali-soluble unsaturated mono- and unsaturated mono- and mono-carboxyl-containing carboxyl-containing dicarboxylic monomers (copolymerization of the following mixtures d) ") are preferred acids; maleic acid, citraconic acid, and none); A7 B7 (D) component 'For the component (A), as an adhesive, it is sealed in the development process of the color filter manufacturing process, and an appropriate soluble resin can be selected. In these tests, among resins containing acidic functional groups such as carboxyl groups and phenolic hydroxyl groups, alkali-soluble resins containing carboxyl groups, such as ethylenically unsaturated monomers (hereinafter, referred to as "carboxylate-containing bodies") ) Polymers, etc. (Co) polymers based on unsaturated monomers, especially monomeric compounds (hereinafter referred to as "other unsaturated monomers") made of saturated monomers and copolymerizable ethylenic unsaturated " , Abbreviated as "Copolymers containing carboxyl groups (the unsaturated monomers containing carboxyl groups previously, such as (meth) acrylic acid, crotonic acid, α-chloroacrylic acid, ethyl acrylic acid, cinnamic acid and other unsaturated monocarboxylic anhydrous maleic acid Unsaturated dicarboxylic acids such as fumaric acid, itaconic acid, itaconic acid, citric acid, and mesaconic acid (unsaturated polyvalent acids (anhydrous) on anhydrous substances); succinic acid mono (2- (Meth) acryloxyethyl esters), mono (meth) acryloxyalkyl esters of polyvalent carboxylic acids, such as poly (2- (meth) acryloxyethyl) phthalate; ω-carboxyl-polycaprolactam first-class second terminal (please read the precautions on the back before filling this page) Pack! —Order-111 —!-Thread 'ί. This paper size applies Chinese National Standard (CNS) A4 Specifications (210 X 297 mm) -28- Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economy 405047 V. Invention Explanation Pan 6) One of the residue polymers (meth) acrylates, etc. These carboxyl-containing unsaturated monomers can be used alone or as a mixture of two or more. Other unsaturated polymers mentioned above, for example, Styrene, α-methylstyrene, 0-vinyltoluene, m-vinyltoluene, P-ethylene-based benzene, 0-chlorophenylethyl, m-chlorophenylethyl, P-chloro Styrene, 0-methoxystyrene, m-methoxystyrene, P-methoxystyrene, indene, 0-vinyl benzyl methyl ether, m-vinyl benzyl methyl ether, Aromatic vinyl compounds such as P-vinyl benzyl methyl ether, 0-vinyl benzyl glyceryl ether, m-vinyl benzyl glyceryl ether, p-vinyl benzyl glyceryl ether, methacrylate, methmethacrylate, Ethyl acrylate, ethyl methacrylate, η-propyl acrylate, η-propyl methacrylate, i-propyl acrylate, i-propyl methacrylate, i-butyl acrylate , 1-butyl methacrylate, sec —butyl propionate 'sec-butyl methacrylate, t-butyl Acrylate, t-butyl methacrylate, 2-hydroxyethyl acrylate, 2-hydroxyethyl methacrylate, 2-hydroxypropyl acrylate, 2-hydroxypropyl methacrylate, 3-hydroxypropyl Acrylate, 3-hydroxypropyl methacrylate, 2-hydroxybutyl acrylate, 2-hydroxybutyl methacrylate, 3-hydroxybutyl acrylate, 3-hydroxybutyl methacrylate, 4-hydroxy Butyl acrylate, 4-hydroxybutyl methacrylate, pentyl acrylate, pentyl methacrylate, benzyl acrylate, benzyl methacrylate, cyclohexyl acrylate, cyclohexyl methacrylate, benzene The size of acrylic paper is applicable to Chinese National Standard (CNS) A4 (210 X 297 mm) -29- ----------. 1 -------- Order III! I! -Sale> (Please read the notes on the back before filling out this page) 405047 V. Description of the invention Pan 7) Ester 'phenyl methacrylate, 2-methoxyethyl acrylate, 2-methoxyethyl Methyl methacrylate, 2-phenoxyethyl acrylate, 2-phenoxyethyl methacrylate, methoxydiethylene glycol acrylate, methoxydiethylene glycol methacrylate, methoxy Glyceryl acrylate, methoxyglycerol methacrylate, methoxydipropylene glycol acrylate, methoxydipropylene glycol methacrylate, isobornyl acrylate, isobornyl methacrylic acid Ester, dicyclopentadienyl acrylate, dicyclopentadienyl methacrylate, 2-hydroxy-3 -phenoxypropyl acrylate, 2-hydroxy-3 -phenoxypropyl methacrylate, Unsaturated carboxylic acid esters such as glyceryl monoacrylate and glyceryl monomethacrylate; 2-aminoethyl (meth) acrylate, 2-dimethylaminoethyl (meth) acrylate, 2- Aminopropyl (meth) acrylate, 2-dimethylaminopropyl (meth) acrylate, 3-amine Unsaturated carboxylic acid amine alkyl esters such as propyl (meth) acrylate, 3-dimethylaminopropyl (meth) acrylate, etc .; Consumer cooperation with the Intellectual Property Bureau of the Ministry of Economic Affairs, Du printed cyclopropoxy ( Cyclopropyl esters of unsaturated carboxylic acids, such as methyl acrylate; ethyl carboxylates, such as ethyl acetate, ethyl propionate, ethyl butyrate, ethyl benzoate; vinyl methyl ether, vinyl ethyl Unsaturated ethers such as ether, allyl glyceryl ether, methallyl glyceryl ether; (meth) acrylamide, α-chloroacrylamide, vinylidene cyanide compounds, etc .; Malay Unsaturated ammonium amines such as amidine, N-cyclohexylmaleimide, and N-phenylmaleimide; -30--(Please read the precautions on the back before filling this page) National Standard (CNS) A4 specification (210 X 297 mm) A7 405047 B7 V. Detailed description of the invention) 1,3-Butadiene, isoprene, chloroprene and other aliphatic covalent diene; Poly Polymer molecular chains such as styrene, polymeth (meth) acrylate, poly-n-butyl (meth) acrylate, polysiloxane End has a great monomers mono (meth) Bing Xixi of acid groups and the like. These other unsaturated monomers may be used alone or in combination of two or more. The carboxyl group-containing copolymer (d) includes, for example, (1) (meth) acrylic acid and (2) styrene, meth (meth) acrylic acid, 2-hydroxyethyl (meth) acrylic acid, and benzyl ( Copolymer formed from at least one selected from the group consisting of meth) acrylic acid, phenyl (meth) acrylic acid, N-phenylmaleimide, polystyrene macromonomer, and polymethmethacrylic macromonomer group 〇 Among the specific examples of preferred carboxyl-containing copolymers (d), acrylic acid / benzyl acrylate copolymer, acrylic acid / styrene / methacrylate copolymer, acrylic acid / styrene / benzyl acrylate Copolymer, acrylic / methacrylate / polystyrene macromonomer copolymer, acrylic / methacrylate / polymethmethacrylate macromonomer copolymer, acrylic / benzylacrylate / poly Copolymer of styrenic macromonomer acrylic / benzyl acrylate / polymethyl methacrylate monolithic paper size applicable to China National Standard (CNS) A4 (210 X 297 mm) (Please read the note on the back first (Fill in this page again)

-------—訂 -------' I 經濟部智慧財產局員工消費合作社印製 -31 - 經濟部智慧財產局員工消費合作社印製 A7 405047 B7 五、發明說明（29 ) 體共聚合物、丙烯酸/苄基甲基丙烯酸酯共聚合物、丙烯酸/苯乙烯/甲基甲基丙烯酸酯共聚合物、丙烯酸/苯乙烯/苄基甲基丙烯酸酯共聚合物、丙烯酸/甲基甲基丙烯酸酯/聚苯乙烯巨大單體共聚合物、丙烯酸/甲基甲基丙烯酸酯/聚甲基曱基丙烯酸酯巨大單體共聚合物、丙烯酸/苄基甲基丙烯酸酯/聚苯乙烯巨大單體共聚合物、丙烯酸/苄基甲基丙烯酸酯/聚甲基甲基丙烯酸酯巨大單體共聚合物、丙烯酸/2 —羥乙基甲基丙烯酸酯/苯乙烯/苄基甲基丙烯酸酯/聚苯乙烯巨大單體共聚合物、丙烯酸/2 —羥乙基甲基丙烯酸酯/苄基甲基丙烯酸酯/聚甲基甲基丙烯酸酯巨大單體共聚合物等丙烯酸共聚合物類；甲基丙烯酸/苄基丙烯酸酯共聚合物、甲基丙烯酸/苯乙烯/甲基丙烯酸酯共聚合物、甲基丙烯酸/苯乙烯/苄基丙烯酸酯共聚合物、甲基丙烯酸/甲基丙烯酸酯/聚苯乙烯巨大單體共聚合物、甲基丙烯酸/甲基丙烯酸酯/聚甲基甲基丙烯酸酯巨大單體共聚合物、本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） -32- 1!1 丨 ΙΊ — 丨 — — — 丨 111111 訂— — — — — — —I -< (請先閱讀背面之注意事項再填寫本頁) 405047 A7 B7 五、發明說明如）甲基丙烯酸/苄基丙烯酸酯/聚苯乙烯巨大單體共聚合物、甲基丙烯酸/苄基丙烯酸酯/聚甲基甲基丙烯酸酯巨 '大單體共聚合物、甲基丙烯酸/苄基甲基丙烯酸酯共聚合物、甲基丙烯酸/苯乙烯/甲基甲基丙烯酸酯共聚合物、甲基丙烯酸/苯乙烯/苄基甲基丙烯酸酯共聚合物、甲基丙烯酸/甲基甲基丙烯酸酯/聚苯乙烯巨大單體共聚合物、甲基丙烯酸/甲基甲基丙烯酸酯/聚甲基甲基丙烯酸酯巨大單體共聚合物、甲基丙烯酸/苄基甲基丙烯酸酯/聚苯乙烯巨大單體共聚合物、甲基丙烯酸/苄基甲基丙烯酸酯/聚甲基甲基丙烯酸酯巨大單體共聚合物、甲基丙烯酸/2 -羥乙基甲基丙烯酸酯/苯乙烯/苄基甲基丙烯酸酯/聚苯乙烯巨大單體共聚合物、甲基丙烯酸/2 —羥乙基甲基丙烯酸酯/苄基甲基丙烯酸酯/聚甲基甲基丙烯酸酯巨大單體共聚合物、甲基丙嫌酸/苯乙嫌/爷基甲基丙嫌酸酯/N -苯基馬來醯胺共聚合物、甲基丙烯酸/苯乙烯/苯基甲基丙烯酸酯/N -苯基馬來醯胺共聚合物、甲基丙烯酸/苯乙烯/卡基甲基丙烯酸酯/N -苯基 - _ < -nll^illlln — — — — — — II ^ ·11!11! ^ ί 4 ，(請先閱讀背面之注意事項再填寫本頁) 經濟部智慧財產局員工消費合作社印製本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） -33- A7 405047 _____Β7 _ 五、發明說明h ) 馬來醯胺/聚苯乙烯巨大單體共聚合物、甲基丙烯酸/苯乙烯/苄基甲基丙烯酸酯/N -苯基馬來醯胺/聚甲基甲基丙烯酸巨大單體共聚合物、甲基丙烯酸/苯乙烯/苯基甲基丙烯酸酯/N -苯基馬來醯胺/聚苯乙烯巨大單體共聚合物、甲基丙烯酸/苯乙烯/苯基甲基丙烯酸酯/N -苯基馬來醯胺/聚甲基甲基丙烯酸巨大單體共聚合物、甲基丙烯酸/苯乙烯/2 -羥乙基甲基丙烯酸酯/苄基甲基丙烯酸酯/N-苯基馬來醯胺/聚苯乙烯巨大單體共聚合物、甲基丙烯酸/苯乙烯/2 -羥乙基甲基丙烯酸酯/苄基甲基丙烯酸酯/N-苯基馬來醯胺/聚甲基甲基丙烯酸酯巨大單體共聚合物、甲基丙烯酸/苯乙烯/ 2 -羥乙基甲基丙烯酸酯/苯基甲基丙烯酸酯/N -苯基馬來醯胺/聚苯乙烯巨大單體共聚合物、甲基丙烯酸/苯乙烯/2 -羥乙基甲丙烯酸酯/苯基甲基丙烯酸酯/N —苯基馬來醯胺/聚甲基甲基丙烯酸酯巨大單體共聚合物、甲基丙烯酸/苯乙烯/2 -羥乙基甲丙烯酸酯/苄基甲基丙烯酸酯/N -苯基馬來醯胺/聚苯乙烯巨大單體共聚合物、甲基丙烯酸/苯乙烯/ 2 —羥乙基甲丙烯酸酯/苄基甲基丙烯酸酯/N -苯基馬來醯胺/聚甲基甲基丙烯酸酯 ' - 1 * illlllMIIIU - I I I I I I I ^ >111111! ^ I i * (請先間讀背面之注意事項再填寫本頁) 經濟部智慧財產局員工消費合作社印製本紙張尺度適用中國國家標準（CNS)A4規格mo X 297公釐） -34- 405047 A7 __B7 五、發明說明幻）巨大單體共聚合物、 -(請先閱讀背面之注意事項再填寫本頁) (甲基）丙烯酸/琥珀酸一〔2 —（甲基）丙烯氧基乙酯〕/苯乙烯/苄基（甲基）丙烯酸酯/N —苯基馬來醯胺共聚合物、 (甲基）丙烯酸/琥珀酸一〔2_ (甲基）丙烯氧基乙酯〕/苯乙烯/烯丙基（甲基）丙烯酸酯/N —苯基馬來醯胺共聚合物、 (甲基）丙烯酸/苯乙烯/苄基（甲基）丙烯酸酯/ 丙三醇一（甲基）丙烯酸酯/N-苯基馬來醯胺共聚合物 (甲基）丙烯酸/ω-羧基聚己內醯胺一（甲基）丙烯酸酯/苯乙烯/苄基（甲基）丙烯酸酯/丙三醇一（甲基）丙烯酸酯/Ν-苯基馬來醯胺共聚合物等甲基興酸共聚合物等。經濟部智慧財產局員工消費合作社印製此些含羧基之共聚合物（d )中，特別是以甲基丙烯酸/苄基甲基丙烯酸酯共聚合物、甲基丙烯酸/苯乙烯/ 甲基甲基丙烯酸酯共聚合物、甲基丙烯酸/苯乙烯/苄基甲基丙烯酸酯共聚合物、甲基丙烯酸/甲基甲基丙烯酸酯 /劇本乙烯巨大單體共聚合物、甲基丙烯酸/甲基甲基丙烯酸酯/聚甲基甲基丙烯酸酯巨大單體共聚合物'甲基丙烯酸/苄基甲基丙烯酸酯/聚苯乙烯巨大單體共聚合物、甲基丙烯酸/苄基甲基丙烯酸酯/聚甲基甲基丙烯酸酯巨大單體共聚合物、甲基丙烯酸/2 —羥乙基甲基丙烯酸酯 /苄基甲基丙烯酸酯/聚苯乙烯巨大單體共聚合物、甲基 -35- 本紙張尺度適用中國國家標準（CNS)A4規格（2〗0 X 297公釐） 40504*7 A7 __ B7 __ 五、發明說明紅）丙烯酸/2 —羥乙基甲基丙烯酸酯/苄基甲基丙烯酸酯/ 聚甲基甲基丙烯酸酯巨大單體共聚合物、甲基丙烯酸/苯乙烯/苄基甲基丙烯酸酯/N-苯基馬來醯胺共聚合物、 _甲基丙烯酸/苯乙烯/苯基甲基丙烯酸酯/N—苯基馬來醯胺共聚合物、甲基丙烯酸/苯乙烯/苄基甲基丙烯酸酯 /N -苯基馬來醯胺/聚苯乙烯巨大單體共聚合物、甲基丙烯酸/苯乙烯/苄基甲基丙烯酸酯/N -苯基馬來醯胺 /聚甲基甲基丙烯酸酯巨大單體共聚合物、甲基丙烯酸/ 苯乙烯/苯基甲基丙烯酸酯/N -苯基馬來醯胺/聚苯乙烯巨大單體共聚合物、甲基丙烯酸/苯乙烯/苯基甲基丙烯酸酯/N-苯基馬來醯胺/聚甲基甲基丙烯酸酯巨大單體共聚合物、甲基丙烯酸/苯乙烯/2 —羥乙基甲基丙烯酸酯/苄基甲基丙烯酸酯/N-苯基馬來醯胺/聚苯乙烯巨大單體共聚合物、甲基丙烯酸/苯乙烯/2 —羥乙基甲基丙烯酸酯/苄基甲基丙烯酸酯/N -苯基馬來醯胺/聚甲基甲基丙烯酸酯巨大單體共聚合物、甲基丙烯酸/苯乙烯/2 -羥乙基甲基丙烯酸酯/苯基甲基丙烯酸酯/N — 苯基馬來醯胺/聚苯乙烯巨大單體共聚合物、甲基丙烯酸 /苯乙烯/2 -羥乙基甲基丙烯酸酯/苯基甲基丙烯酸酯 /N-苯基馬來醯胺/聚甲基甲基丙烯酸酯巨大單體共聚合物等爲佳。含羧基之共聚合物（d )中含羧基之不飽和單體共聚合比例，一般爲5〜5 0重量％，較佳爲1 0〜4 0重量 % 。此時，含羧基之不飽和單體之共聚比例低於5重量％本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） - . ' η . — II ΙΊ--^-------^---I----^' — — — 1 —---^ ·(請先閱讀背面之注意事項再填寫本頁) 經濟部智慧財產局員工消費合作杜印製 -36- 經濟部智慧財產局員工消費合作社印製 4050^ 五、發明說明（34 ) 時’所得之感放射線性組成物對鹼顯像液之溶解性有降低之傾向，又，超過5 0重量％時，在以鹼性顯像液顯像時 ’所形成之畫素具有容易由基板脫落，或畫素表面容易產生膜粗造化等傾向。特別是含有特定聚合比例之含羧基之不飽和單體的含羧基之共聚合物（d )，以其對鹼顯像液具有優良溶解性 ’故將該共聚合物作爲膠粘劑使用之感放射線組成物，於鹼顯像液顯像後所殘存之未溶解物量極低，因此不會污染畫素形成之部位以外之基板上，因而不易產生膜殘留等現象’此外’使用該組成物所製得之畫素，不會過度溶解於鹼顯像液中，因此對基板而言，爲一具有優良密著性、且不會有由基板脫落之疑慮。含羧基之共聚合物（d)使用凝膠滲透色層分析法（ G P C ;溶出溶媒：四氫呋喃）測定所得的聚乙烯換算之重量平均分子量（以下，簡稱「重量平均分子量」），較佳爲3，000〜300，〇〇〇，更佳爲5，000〜 1 0 0，0 0 0 ° 又，含苯酚性羥基之鹼可溶性樹脂，例如含苯酚性羥基之乙烯基芳香族（共）聚合物、酚醛淸漆樹脂等。前記含苯酚性羥基之乙烯基芳香族化合物，例如，0 一翔基本乙煉、m —經基苯乙稀、p —翔基苯乙嫌、〇 — 羥基一α-甲基苯乙烯、m—羥基一α—甲基苯乙烯'p 一羥基一甲基苯乙烯等。此些含苯酚性羥基之乙烯基芳香族化合物可單獨或將本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） »111,.--—Ί—! - ---- - -- 訂 i! ·線 ί ' -(請先閱讀背面之注意事項再填寫本頁) 經濟部智慧財產局員工消費合作社印製 A7 ΛΩ5047_B7 五、發明說明（35 ) 2種以上混合使用。前記含苯酚性羥基之乙烯基芳香族化合物，依各種情形之不同，可與1種以上之其他可共聚合之乙烯性不飽和 '單體（例如以含羧基之共聚合體（d)爲例示之前記其他不飽和單體）共聚。含苯酚性羥基之乙烯基芳香族化合物之（共）聚合物之重量平均分子量，較佳爲1，0 0 0〜150，〇〇〇 ’更佳爲3，000〜〜100，000。又前記用於酚醛淸漆樹脂使用之苯酚類，例如，0 -甲酚、m —甲酚、P —甲酚、2 ，3 —二甲苯酚、2，4 一二甲苯酚、2，5 —二甲苯酚、3，4 一二甲苯酚、3 ，5 -二甲苯酚、2，3，5 —三甲基苯酚、3，4，5 一三甲基苯酚等。醛類例如甲醛、乙醛、三噁烷、仲甲醛、苯甲醛、乙醛、丙醛、苯乙醛、乙二醛、戊二醛、對苯二甲醛、間苯二甲醛等。此些苯酚類及醛類，各自可以單獨使用或將2種以上混合使用。酚醛淸漆樹脂之重量平均分子量，較佳爲1，00 0 〜150，000，更佳爲 1，500 〜〜80 ’ 0〇〇〇本發明中，鹼可溶性樹脂可單獨或將2種以上混合使用。本發明之鹼可溶性樹脂之使用量，對成分（A) 100重量份而言，一般爲10〜1 ’ 000重量份，較本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） -38- Ί — —1!---> ^---I I ! $ ! ! I I A I < -(請先閱讀背面之注意事項再填寫本頁) 經濟部智慧財產局員工消費合作社印製 405047 五、發明說明（36 ) 佳爲2 〇〜5 0 0重量份。此時，若鹼可溶性樹脂之使用量低於1 0重量份時，例如，會有使鹼顯像性降低，或對 β素形成部位以外之區域的基板產生污染或膜殘留物之疑慮’又，超過1，0 0 0重量份時，會使相對性著色濃度降低，且不易達到薄膜所需之目的之色濃度。添加劑本發明之濾色器用感放射線組成物，必要時可添加各種添加劑。前記添加劑可爲一種可改善感放射線組成物之鹼顯像液的溶解性，且可抑制顯像後所殘存之未溶解物的有機酸 0 此一有機酸，以分子量在1，0 0 0以下，且爲脂肪族羧酸或含苯基之羧酸爲佳。前記脂肪酸之具體例如蟻酸、醋酸、丙酸、丁酸、戊酸、三甲基乙酸、己酸、二乙基醋酸、庚酸、癸酸等脂肪族一羧酸類；草酸、丙二酸、琥珀酸、戊二酸、己二酸、庚二酸、辛二酸、壬二酸、癸二酸、巴西二酸、甲基丙二酸、乙基丙二酸、二甲基丙二酸、甲基琥珀酸、四甲基琥珀酸、環己二羧酸、1 ，4 一環己二羧酸、衣康酸、檬康酸、馬來酸、富馬酸、中康酸等脂肪族二羧酸類；三胺基甲酸、烏頭酸、卡彭酸等三羧酸類；又，前記含苯基之羧酸，例如羧基與苯基直接鍵結之本纸張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） . - -lllfl·----— In ---- 11 訂· 11! I — - ' 二請先閱讀背面之注意事項再填寫本頁) 經濟部智慧財產局員工消費合作社印製 A7 --465047_SZ___ 五、發明說明心）芳香族羧酸類或，羧基介由碳鏈與苯基鍵結之羧酸等等，其具體例如，安息香酸、甲苯酸、枯茗酸、二甲基苯酸、三甲基苯酸等芳香族一羧酸類；鄰苯二甲酸、間苯二甲酸、對苯二甲酸、等芳香族二羧酸類；偏苯三酸、均苯三酸、偏苯四酸、均苯四酸等3價以上之芳香族聚羧酸類或，苯基醋酸、氫化阿托酸、氫化肉桂酸、苦杏仁酸、苯基號拍酸、阿托酸、肉桂酸 '肉桂乙酸、香豆酸、二經基肉桂酸等等。此些有機酸中，以丙二酸、己二酸、衣康酸' 檬康酸、富馬酸、中康酸、鄰苯二甲酸等脂肪族二羧酸類及芳香族二羧酸類，以其之鹼溶解性，對溶媒之溶解性，及可防止基板在形成畫素以外部份產生污染或產生膜殘留物等觀點而言，爲一較佳之選擇。前記有機酸，可以單獨或將2種以上混合使用。有機酸之使用量，以對感放射線性組成物全體而言，一般爲1 0重量％以下，較佳爲〇〇〇 1〜1 〇重量％ ’更佳爲〇 . 〇 1〜1重量％。此時，有機酸之使用量若超過1 0重量％時，會有使所形成畫素對基板之密著性降低之傾向。又’有機酸以外之添加劑，例如，銅鈦菁系衍生物等藍色顏料或黃色顏料衍生物等之分散助劑；本紙張尺度適用中國國家標準（CNSXA4規格（210 X 297公髮） -40- ' . - « . ----·---1-------Μ--------^---------線- '(請先閱讀背面之注意事項再填寫本頁) 40504^ A7 B7 五、發明說明（38 ) 坡璃、鋁等塡充劑；聚乙二醇、聚乙二醇一烷基醚、聚（氟烷基丙烯酸酯 1 (請先閱讀背面之注意事項再填寫本頁) )等高分子化合物；非離子系、陽離子系、陰離子系等界面活性劑；乙烯基三烷氧基矽烷、乙烯基三乙氧基矽烷、乙烯基三（2—甲氧乙氧基）矽烷、N—(2—胺乙基）一3— 胺丙基甲基甲氧基矽烷、N —（2 —胺乙基）—3 —胺丙基三甲氧基矽烷、3 -胺丙基三乙氧基矽烷、3 -環氧丙氧基丙基三甲氧基矽烷、3 -環氧丙氧基丙基甲基二甲氧基矽烷、2 -（3，4 一乙氧基環己基）乙基三甲氧基矽烷、3 -氯丙基甲基二甲氧基矽烷、3 —氯丙基三甲氧基矽烷、3 -甲基丙烯醯丙基三甲氧基矽烷、3 -硫氫基丙基三甲氧基矽烷等密著促進劑； 2，2 -硫基雙（4 一甲基一6— t —丁基苯酚）、 2 ’ 6 -二一 t 一丁基苯酚等氧化防止劑；經濟部智慧財產局員工消費合作社印製 2-（3—t—丁基一 5 —甲基—2 -羥苯基）—5 -氯基苯軿***、烷氧基二苯甲酮等紫外線吸收劑；聚丙烯酸鈉等凝聚防止劑； 2 -胺基乙醇、3 -胺基一 1_丙醇、5 -胺基一 1 一戊醇、3 —胺基一1，2 —丙二醇、2 —胺基—1，3 一丙一醇、4 一胺基一 1 ’ 2 — 丁二醇、〇 -胺基苯酣、 m -胺基苯酚、p -胺基苯酚等有基胺化合物等等。溶劑 -41 - 本紙張尺度適用令國國家標準（CNS)A4規格（210 X 297公釐） A7 __405047 五、發明說明如）其他例如本發明之濾色器用感放射線組成物，可再添加溶劑。-------— Order ------- 'I Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs -31-Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs A7 405047 B7 V. Description of Invention (29 ) Bulk copolymer, acrylic acid / benzyl methacrylate copolymer, acrylic acid / styrene / methmethacrylate copolymer, acrylic acid / styrene / benzyl methacrylate copolymer, acrylic acid / Methyl methacrylate / polystyrene macromonomer copolymer, acrylic acid / methmethacrylate / polymethylfluorenyl acrylate macromonomer copolymer, acrylic acid / benzyl methacrylate / poly Styrene macromonomer copolymer, acrylic acid / benzyl methacrylate / polymethmethacrylate macromonomer copolymer, acrylic acid / 2-hydroxyethyl methacrylate / styrene / benzyl methyl Acrylic acid copolymers such as methacrylic acid ester / polystyrene macromonomer copolymer, acrylic acid / 2-hydroxyethyl methacrylate / benzyl methacrylate / polymethmethacrylate macromonomer copolymer, etc. Species; methacrylic acid / benzyl acrylic acid Copolymer, methacrylic acid / styrene / methacrylate copolymer, methacrylic acid / styrene / benzyl acrylate copolymer, methacrylic acid / methacrylate / polystyrene macromonomer copolymer Polymer, methacrylic acid / methacrylic acid ester / polymethmethacrylic acid macromonomer copolymer, this paper size is applicable to Chinese National Standard (CNS) A4 specification (210 X 297 mm) -32- 1! 1 丨 ΙΊ — 丨 — — — 丨 111111 Order — — — — — — — — (Please read the notes on the back before filling out this page) 405047 A7 B7 V. Description of the invention eg) Methacrylic acid / benzyl Acrylate / polystyrene macromonomer copolymer, methacrylic acid / benzyl acrylate / polymethmethacrylate macromonomer copolymer, methacrylic acid / benzyl methacrylate copolymer Polymer, methacrylic acid / styrene / methmethacrylate copolymer, methacrylic acid / styrene / benzyl methacrylate copolymer, methacrylic acid / methmethacrylate / polystyrene Huge monomer copolymer, A Acrylic / methmethacrylate / polymethmethacrylate macromonomer copolymer, methacrylic acid / benzyl methacrylate / polystyrene macromonomer copolymer, methacrylic acid / benzyl Methacrylate / polymethmethacrylate macromonomer copolymer, methacrylate / 2-hydroxyethylmethacrylate / styrene / benzyl methacrylate / polystyrene macromonomer copolymer Polymer, methacrylic acid / 2-hydroxyethyl methacrylate / benzyl methacrylate / polymethmethacrylate macromonomer co-polymer, methacrylic acid / phenethyl ether / preyl Methacrylic acid / N-phenylmaleimide copolymer, methacrylic acid / styrene / phenylmethacrylate / N-phenylmaleimide copolymer, methacrylic acid / benzene Ethylene / Carboxymethacrylate / N-phenyl- _ < -nll ^ illlln — — — — — — II ^ · 11! 11! ^ Ί 4, (Please read the notes on the back before filling this page ) Printed by the Consumers' Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs, the paper size is applicable to the Chinese National Standard (CNS) A4 (210 X 29 7 mm) -33- A7 405047 _____B7 _ V. Description of the invention h) Maleamamine / polystyrene macromonomer copolymer, methacrylic acid / styrene / benzyl methacrylate / N-phenyl Maleamidine / polymethacrylic acid macromonomer copolymer, methacrylic acid / styrene / phenylmethacrylate / N-phenylmaleamide / polystyrene macromonomer copolymer , Methacrylic acid / styrene / phenylmethacrylate / N-phenylmaleamide / polymethmethacrylic macromonomer copolymer, methacrylic acid / styrene / 2-hydroxyethyl methyl Acrylate / benzyl methacrylate / N-phenylmaleamide / polystyrene macromonomer copolymer, methacrylic acid / styrene / 2-hydroxyethyl methacrylate / benzyl methyl Acrylate / N-phenylmaleamide / polymethmethacrylate macromonomer copolymer, methacrylic acid / styrene / 2-hydroxyethyl methacrylate / phenyl methacrylate / N-phenylmaleimide / polystyrene macromonomer copolymer, methacrylic acid / styrene / 2-hydroxyethylmethacrylate / phenylmethylpropane Enoate / N-phenylmaleamide / polymethmethacrylate macromonomer copolymer, methacrylic acid / styrene / 2-hydroxyethylmethacrylate / benzyl methacrylate / N-phenylmaleimide / polystyrene macromonomer copolymer, methacrylic acid / styrene / 2-hydroxyethylmethacrylate / benzylmethacrylate / N-phenylmaleimide / Polymethylmethacrylate '-1 * illlllMIIIU-IIIIIII ^ > 111111! ^ I i * (Please read the precautions on the back before filling out this page) Printed on paper by the Intellectual Property Bureau Employees Consumer Cooperatives The scale is applicable to the Chinese National Standard (CNS) A4 specification mo X 297 mm) -34- 405047 A7 __B7 V. Invention Description Magic) Huge monomer copolymer,-(Please read the precautions on the back before filling this page) ( (Meth) acrylic acid / succinic acid mono [2- (meth) acryloxyethyl] / styrene / benzyl (meth) acrylate / N-phenylmaleimide copolymer, (meth) Acrylic acid / succinic acid mono- [2- (meth) acryloxyethyl] / styrene / allyl (meth) acrylate / N — Phenylmaleimide copolymer, (meth) acrylic acid / styrene / benzyl (meth) acrylate / glycerol mono (meth) acrylate / N-phenylmaleimide copolymer (Meth) acrylic acid / ω-carboxy polycaprolactam mono (meth) acrylate / styrene / benzyl (meth) acrylate / glycerol mono (meth) acrylate / N-phenyl horse Methyl acid copolymers, such as beryllamine copolymers. Among these carboxyl-containing copolymers (d) printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs, especially methacrylic acid / benzyl methacrylate copolymers, methacrylic acid / styrene / methyl methyl Acrylate copolymer, methacrylic acid / styrene / benzyl methacrylate copolymer, methacrylic acid / methmethacrylate / script ethylene macromonomer copolymer, methacrylic acid / methyl Methacrylate / polymethmethacrylate macromonomer copolymer 'methacrylic acid / benzyl methacrylate / polystyrene macromonomer copolymer, methacrylic acid / benzyl methacrylate / Polymethmethacrylate macromonomer copolymer, methacrylic acid / 2-hydroxyethyl methacrylate / benzyl methacrylate / polystyrene macromonomer copolymer, methyl-35 -This paper size is in accordance with China National Standard (CNS) A4 specification (2〗 0 X 297 mm) 40504 * 7 A7 __ B7 __ 5. Description of the invention red) Acrylic acid 2 —Hydroxyethyl methacrylate / benzyl methyl ester Methacrylate / polymethmethacrylate huge Polymer, methacrylic acid / styrene / benzyl methacrylate / N-phenylmaleimide copolymer, _methacrylic acid / styrene / phenylmethacrylate / N-phenyl Maleimide copolymer, methacrylic acid / styrene / benzyl methacrylate / N-phenylmaleimide / polystyrene macromonomer copolymer, methacrylic acid / styrene / benzyl Methacrylate / N-phenylmaleimide / polymethmethacrylate macromonomer copolymer, methacrylic acid / styrene / phenylmethacrylate / N-phenylmaleimide / Polystyrene macromonomer copolymer, methacrylic acid / styrene / phenylmethacrylate / N-phenylmaleamide / polymethmethacrylate macromonomer copolymer, methyl Acrylic / styrene / 2-hydroxyethyl methacrylate / benzyl methacrylate / N-phenylmaleimide / polystyrene macromonomer copolymer, methacrylic acid / styrene / 2 — Hydroxyethyl methacrylate / benzyl methacrylate / N-phenylmaleamide / polymethmethacrylate macromonomer copolymer, methyl propylene Acid / styrene / 2-hydroxyethyl methacrylate / phenylmethacrylate / N — phenylmaleimide / polystyrene macromonomer copolymer, methacrylic acid / styrene / 2- Hydroxyethyl methacrylate / phenyl methacrylate / N-phenylmaleamide / polymethmethacrylate macromonomer copolymer is preferred. The copolymerization ratio of carboxyl group-containing unsaturated monomers in the carboxyl group-containing copolymer (d) is generally 5 to 50% by weight, and preferably 10 to 40% by weight. At this time, the copolymerization ratio of the carboxyl group-containing unsaturated monomer is less than 5% by weight. The paper size applies to the Chinese National Standard (CNS) A4 (210 X 297 mm)-. 'Η. — II ΙΊ-^- ----- ^ --- I ---- ^ '— — — 1 —--- ^ · (Please read the notes on the back before filling out this page) Printed by the Intellectual Property Bureau of the Ministry of Economic Affairs for consumer cooperation -36- Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs 4050 ^ V. Description of the invention (34) The 'radiated radiation-sensitive composition' tends to reduce the solubility of the alkali imaging solution, and more than 50 weight %, When formed in an alkaline developing solution, the formed pixels tend to fall off the substrate, or the surface of the pixels tends to be roughened. In particular, a carboxyl-containing copolymer (d) containing a carboxyl-containing unsaturated monomer having a specific polymerization ratio has excellent solubility in an alkali imaging solution. Therefore, this copolymer is used as an adhesive for a radiation-sensitive composition. The amount of undissolved matter remaining after the development of the alkali developing solution is extremely low, so it will not contaminate the substrate other than the part where the pixels are formed, so it is not easy to produce phenomena such as film residue. Since the pixels are not excessively dissolved in the alkali developing solution, the substrate is excellent in adhesion and there is no doubt that the substrate will fall off from the substrate. The weight average molecular weight of polyethylene (hereinafter referred to as "weight average molecular weight") measured by gel permeation chromatography (GPC; dissolution solvent: tetrahydrofuran) using a carboxyl-containing copolymer (d), preferably 3 10,000 to 300,000, more preferably 5,000 to 10,000, 0 ° Also, alkali-soluble resins containing phenolic hydroxyl groups, such as vinyl aromatic (co) polymers containing phenolic hydroxyl groups , Phenolic resin, etc. Foreword Vinyl aromatic compounds containing phenolic hydroxyl groups, for example, 0 Yixiang basic acetic acid refining, m — via styrene, p — Xiang phenyl styrene, 0 — hydroxy — α-methylstyrene, m — Hydroxy-α-methylstyrene'p-hydroxy-methylstyrene and the like. These vinyl aromatic compounds containing phenolic hydroxyl groups can be used individually or in accordance with the Chinese National Standard (CNS) A4 (210 X 297 mm) for this paper size »111, .---- Ί—!----- --Order i! · Line ί '-(Please read the precautions on the back before filling out this page) Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs A7 ΛΩ5047_B7 V. Description of Invention (35) Use more than 2 types. The vinyl aromatic compound containing a phenolic hydroxyl group may be copolymerized with more than one kind of other copolymerizable ethylenically unsaturated monomers (for example, the carboxyl-containing copolymer (d) is exemplified in each case). The other unsaturated monomers mentioned above are copolymerized. The weight average molecular weight of the (co) polymer of the phenolic hydroxyl-containing vinyl aromatic compound is preferably 1,000 to 150, 000 ', more preferably 3,000 to 100,000. The phenols used in the phenolic lacquer resin are also mentioned in the foregoing, for example, 0-cresol, m-cresol, P-cresol, 2,3-xylenol, 2,4-xylenol, 2,5- Xylenol, 3,4-xylenol, 3,5-xylenol, 2,3,5-trimethylphenol, 3,4,5-trimethylphenol, and the like. Examples of the aldehydes include formaldehyde, acetaldehyde, trioxane, paraformaldehyde, benzaldehyde, acetaldehyde, propionaldehyde, phenylacetaldehyde, glyoxal, glutaraldehyde, terephthalaldehyde, and isophthalaldehyde. These phenols and aldehydes can be used alone or in combination of two or more kinds. The weight average molecular weight of the phenolic lacquer resin is preferably 1,000 to 150,000, and more preferably 1,500 to 80'000. In the present invention, the alkali-soluble resin may be used alone or as a mixture of two or more kinds. use. The amount of the alkali-soluble resin used in the present invention is generally 10 to 1'000 parts by weight for 100 parts by weight of the component (A). Compared with the paper size, the Chinese National Standard (CNS) A4 specification (210 X 297 mm) is applicable. ) -38- Ί — —1! --- > ^ --- II! $!! IIAI <-(Please read the precautions on the back before filling out this page) Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs 405047 Fifth, the description of the invention (36) is preferably 200 to 500 parts by weight. At this time, if the amount of the alkali-soluble resin used is less than 10 parts by weight, for example, there may be a concern that the alkali developability may be reduced, or the substrates in areas other than the beta element-forming site may be contaminated or have film residues. When it exceeds 1, 000 parts by weight, the relative coloring density will be reduced, and it will be difficult to achieve the color density required for the film. Additives The radiation-sensitive composition for a color filter of the present invention may contain various additives as necessary. The aforementioned additive can be an organic acid that can improve the solubility of the alkali imaging solution of the radiation-sensitive composition and can suppress the undissolved matter remaining after the imaging. 0 This organic acid has a molecular weight of 1,000 or less. It is preferably an aliphatic carboxylic acid or a phenyl-containing carboxylic acid. Specific examples of the aforementioned fatty acids include formic acids such as formic acid, acetic acid, propionic acid, butyric acid, valeric acid, trimethylacetic acid, hexanoic acid, diethylacetic acid, heptanoic acid, and capric acid; oxalic acid, malonic acid, and amber Acid, glutaric acid, adipic acid, pimelic acid, suberic acid, azelaic acid, sebacic acid, azelaic acid, methylmalonic acid, ethylmalonic acid, dimethylmalonic acid, formic acid Aliphatic dicarboxylic acids such as methylsuccinic acid, tetramethylsuccinic acid, cyclohexanedicarboxylic acid, 1,4-monocyclohexanedicarboxylic acid, itaconic acid, citraconic acid, maleic acid, fumaric acid, mesaconic acid, etc. ; Tricarboxylic acids such as triaminocarboxylic acid, aconitic acid, and carpenic acid; In addition, the paper-containing carboxylic acids, such as the carboxyl group and phenyl group, are directly bound to the Chinese paper standard (CNS) A4 ( 210 X 297 mm).--Lllfl · ----— In ---- 11 Order · 11! I —-'Second, please read the precautions on the back before filling out this page) Staff Consumption of Intellectual Property Bureau, Ministry of Economic Affairs Printed by the cooperative A7 --465047_SZ ___ 5. Inventive Notes) Aromatic carboxylic acids or carboxylic acids with a carboxyl group bonded to a phenyl group via a carbon chain, etc. For example, aromatic monocarboxylic acids such as benzoic acid, toluic acid, humic acid, dimethylbenzoic acid, and trimethylbenzoic acid; phthalic acid, isophthalic acid, terephthalic acid, and other aromatic dicarboxylic acids Carboxylic acids; aromatic polycarboxylic acids of three or more valences such as trimellitic acid, trimesic acid, trimellitic acid, pyromellitic acid or the like, phenylacetic acid, hydrogenated atoric acid, hydrogenated cinnamic acid, bitter almond acid , Phenyl acid, atropic acid, cinnamic acid 'cinnamic acid, coumaric acid, diacid cinnamic acid and the like. Among these organic acids, aliphatic dicarboxylic acids such as malonic acid, adipic acid, itaconic acid, citraconic acid, fumaric acid, mesaconic acid, phthalic acid, and aromatic dicarboxylic acids, and It is a better choice from the viewpoint of alkali solubility, solubility of the solvent, and prevention of pollution or film residue on the substrate outside the pixel formation. The organic acid described above can be used alone or as a mixture of two or more. The amount of the organic acid used is generally 10% by weight or less for the entire radiation-sensitive composition, preferably 0.001 to 10% by weight, and more preferably 0.001 to 1% by weight. At this time, if the amount of the organic acid used exceeds 10% by weight, the adhesion of the formed pixels to the substrate tends to decrease. Additives other than organic acids, such as dispersion aids for blue pigments or yellow pigment derivatives such as copper-titanium cyanine derivatives; This paper size applies to Chinese national standards (CNSXA4 specification (210 X 297)) -40 -'.-«. ---- · --- 1 ------- Μ -------- ^ --------- line-' (Please read the Please note this page, please fill in this page) 40504 ^ A7 B7 V. Description of the invention (38) Slope, aluminum and other fillers; Polyethylene glycol, polyethylene glycol monoalkyl ether, poly (fluoroalkyl acrylate 1 ( Please read the precautions on the back before filling in this page) and other polymer compounds; non-ionic, cationic, anionic surfactants; vinyltrialkoxysilane, vinyltriethoxysilane, vinyl Tris (2-methoxyethoxy) silane, N- (2-aminoethyl) -3-aminopropylmethylmethoxysilane, N- (2-aminoethyl) -3-aminopropyltrimethyl Oxysilane, 3-aminopropyltriethoxysilane, 3-glycidoxypropyltrimethoxysilane, 3-glycidoxypropylmethyldimethoxysilane, 2- (3 , 4 monoethoxycyclohexyl) ethyl Trimethoxysilane, 3-chloropropylmethyldimethoxysilane, 3-chloropropyltrimethoxysilane, 3-methacrylamidopropyltrimethoxysilane, 3-thiohydropropylpropyltrimethoxy Adhesion promoters such as silanes; 2,2-thiobis (4-methyl-6-t-butylphenol), 2'6-di-t-butylphenol and other oxidation inhibitors; intellectual property of the Ministry of Economic Affairs UV-absorbing agents printed by the Bureau ’s Consumer Cooperatives, such as 2- (3-t-butyl-1,5-methyl-2-hydroxyphenyl) -5-chlorochlorobenzotriazole, and alkoxybenzophenone; Aggregation inhibitors such as sodium acrylate; 2-aminoethanol, 3-amino-1-propanol, 5-amino- 1-pentanol, 3-amino-1,2-propanediol, 2-amino-1 , 3 monopropanol, 4 monoamino 1 ′ 2-butanediol, 0-aminophenylhydrazone, m-aminophenol, p-aminophenol and other amine compounds, etc. Solvent -41- The paper size is applicable to the national standard (CNS) A4 specification (210 X 297 mm) A7 __405047 5. Description of the invention such as) Other radiation-sensitive composition for color filters of the present invention, for example, may be added with a solvent .

前記溶劑’只要可以溶解或分散於前記（A ) 、( B )、（c)及（D)成分或，所期望添加之前記添加劑中 ’且不會與此些成分反應、具有適度揮發性之物質時，即可以適當選擇使用。此些溶劑例如乙二醇一甲基醚、乙二醇一乙基醚、乙二醇——η — 丙基醚、乙二醇一一 η — 丁基醚等乙二醇一烷基醚類；乙二醇一甲基醚乙酸酯、乙二醇一乙基醚乙酸酯等乙二醇一烷基醚乙酸酯類；二乙二醇一甲基醚、二乙二醇一乙基醚、二乙二醇一 —η —丙基醚、二乙二醇--η - 丁基醚、三乙二醇一甲基醚、三乙二醇一乙基醚等聚乙二醇一烷基醚類；丙二醇一甲基醚、丙二醇一乙基醚、丙二醇——η - 丙基醚、丙二醇--η - 丁基醚等丙二醇一烷基醚類；二丙二醇一甲基醚、二丙二醇一乙基醚 '二丙二醇一一 η -丙基醚、二丙二醇--η - 丁基醚、三丙二醇一甲基醚、三丙乙二醇一乙基醚等聚丙二醇一烷基醚類；丙二醇一甲基醚乙酸酯、丙二醇一乙基醚乙酸酯等丙二醇一烷基醚乙酸酯類；二乙二醇二甲基醚、二乙二醇甲基乙基醚、二乙二醇二乙基醚、四氫呋喃等其他醚類；甲基乙基酮、環己酮、2 -戊酮、3 —戊酮等酮類； -------^--------^--------- ，(請先閱讀背面之注意事項再填寫本頁) 經濟部智慧財產局員工消費合作社印製本紙張尺度適用中國國家標準<CNS)A4規格（210 X 297公釐） -42- 甲類； A7 -—40SS047_B7_____ 五、發明說明釦） 2 -羥基丙酸甲酯、2 -羥基丙酸乙酯等乳酸烷酯類 > 2 —羥基_2 —甲基丙酸乙酯、3 —羥基丙酸甲酯、 3〜甲氧基丙酸乙酯、3 —乙氧基丙酸甲酯、3 —乙氧基汚酸乙酯、乙氧基醋酸乙酯、羥基醋酸乙酯、2 -羥基-3〜甲基丁酸甲酯、3 —甲基—3 —甲氧基丁酸酯、3 — 甲基—甲氧基丙酸酯、乙酸乙酯、乙酸η —丁酯、乙酸i ~ 丁酯、犠酸η -戊酯、乙酸i 一戊酯、丙酸η — 丁酯、丁酸乙酯、丁酸i 一丙酯、丁酸η -丁酯、丙酮酸甲酯、丙酮酸乙酯、丙酮酸η —丙酯、乙醯乙酸甲酯、乙醯乙酸乙酯、2 —羰基丁酸酯等其他酯類；甲苯 Ν —甲基吡硌烷酮、Ν，Ν —二甲基甲醯胺、Ν，Ν 此些溶劑，可以單獨或2種以上混合使用。又’此些溶劑中可再倂用例如，苄基乙基醚、二己基醚、丙酮基丙酮、異佛爾酮、己酸、辛酸、1—辛醇、1 -壬醇、苄基醇、醋酸苄酯、安息香酸乙酯、草酸二酯、馬來酸二酯、r 一丁內酯、碳酸乙烯、碳酸丙烯、乙二醇一苯基醚乙酸酯等高沸點溶劑。上述高沸點溶劑，可單獨使用或2種以上混合使用皆可° 此些溶劑中’就溶解性、顏料分散性、塗布性等觀點而言’以使用乙二醇一甲基醚乙酸酯、丙二醇一甲基醚、本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） !·7 — I ------1 ^« — — — — — 1 — I i 、(請先閱讀背面之注意事項再填寫本頁) 經濟部智慧財產局員工消費合作社印製 -43- 經濟部智慧財產局員工消費合作社印製五、發明說明（n ) 丙二醇一甲基醚乙酸酯、丙二醇一乙基醚乙酸酯、二乙二醇二甲基醚、二乙二醇甲基乙基醚、環己嗣、2 —戊酮、 3 -戊酮、2 —羥基丙酸乙酯、3 —甲基一3 —甲氧基丁基丙酸酯、3_甲氧基丙酸乙酯、3—乙氧基丙酸甲酯、 3—乙氧基丙酸乙酯、乙酸η—丁酯、乙酸i一丁酯、犠酸η -戊酯、乙酸i 一戊酯、丙酸η -丁酯、丁酸乙酯、丁酸i 一丙酯、丁酸η -丁酯、丙酮酸乙酯等爲佳。高沸點溶劑則例如r -丁內酯等爲佳。本發明中溶劑之使用量，對（D )成分1 〇〇重量份一般爲100〜10000重量份，更佳爲500〜 5 0 ◦ 0重量份。濾色器之製作方法以下’將對使用本發明之濾色器用感放射線組成物以製造透過型濾色器及反射型濾色器之方法作一說明。首先’於基板上製作一可區隔透明基板上形成畫素圖型部位之遮光層，此基板上，例如塗布分散有綠色之（A )成分的組成物後，經預烘烤將溶劑蒸發，以形成塗膜。其次將此塗膜介光罩曝光後，使用鹼顯像液進行顯像處理 ’將塗膜中未曝光部份予以溶解去除，較佳時可再進行後烘烤’而將著色之畫素固定於特定之圖型上以形成畫素陣列。其後，必要時可使用分散有其他色（例如，紅色或藍色）之（A )成分之各組成物，依上記相同之方法，對各本紙張尺度適用中國國家標準（CNS)A4規格（210x297公i ) ~ I - ♦ · — — — — —•'ίιί -裝 _!1 訂-!1線 I J 二請先閱讀背面之注意事項再填寫本頁) -44 - 經濟部智慧財產局員工消費合作社印製 A7 -- 4ft 3 Μ。__B7 五、發明說明k ) 組成物進行塗布、烘烤、曝光及顯像處理，並較佳時可進行後烘烤處理，於同一基板上依序形成各色之畫素陣列，而製得濾色器。 ' 製作濾色器之時所使用之透明基板，例如可爲玻璃、矽，聚碳酸酯、聚酯、芳香族聚醯胺、聚醯胺亞胺、聚亞胺等。此些透明基板，依各期望之不同，可進行矽偶合劑等藥品處理，或電漿處理、離子電鍍處理、濺射處理、氣相反應法、真空蒸鍍法等適當之前處理。將本發明之濾色器用感放射線組成物塗布於透明基板時，可採用旋轉塗布、流延塗布、滾筒塗布等適當之塗布法進行。塗布之厚度，依乾燥後之膜厚度而言’ 一般爲 0.1〜10ym，較佳爲0.2〜1.5仁m。製作濾色器時所使用之放射線，可爲可視光 '紫外線、遠紫外線、電子線、X線等，其中以波長1 9 0〜 4 5 0 n m範圍之放射線爲佳。放射線之照射能量較佳爲 1 〜1，000mJ/cm2。又，前記鹼顯像液，例如以使用碳酸鈉、碳酸氫鈉、氫氧化鈉、氫氧化鉀、四甲基銨氫氧化物、膽鹼、1，8 一二迭氮二環_〔5 . 4 .◦〕— 7 -十一烷烯、1 ’ 5 一、二迭氮二環〔4 ‘ 3 . 0〕一 5_壬院稀等水丨谷液爲佳。前記鹼顯像液，可再添加適量之例如甲醇、乙醇等水溶性有機溶劑或界面活性劑。又，鹼顯像後一般會再經過本紙張尺度適用中國國家標準（CNS)A4規格mo X 297公f ) _ 45 -~' 』 * · V . ----^---1-------裝--------訂---------線I J ，(請先閱讀背面之注意事項再填寫本頁) A7 A7 B7 _ ΛΠΓ%047 五、發明說明) 水洗處理。鹼顯像法一般可使用噴灑顯像法、噴霧顯像法、浸泡 (d i p )顯像法、攪拌顯像法等方法，顯像之條件以常溫下5〜3 0 0秒爲佳。依此方式所製得之透過型濾色器及反射型濾色器，除特別適用於彩色攝像管元件以外，對於彩色液晶顯示裝置、彩色感應器等亦極爲有用。發明之實施形態以下，將列舉實施例對本發明之實施形態做更具體之說明。但，本發明並不受此些實施例之任何限制。其中有關污染液晶之製造方法、液晶顯示元件之製作方法及各種評估方法之內容，皆記載如以下說明內容。污染液晶之製作方法於由氟基聯苯之衍生物所製得之向列型液晶（商品名 :ZLI—5081 ，美樂日本公司製）l〇g上，加入精製之著色劑或未精製之著色劑0 . 5g，於室溫下攪拌 1小時使其混合後，在使其於1 1 〇 °C之烤箱中經1小時之熱處理，使著色劑中之不純物由液晶中移出，其後將固形成份過濾，以製得污染液晶。液晶顯示元件之製作方法 (1 )於形成有圖型透明導電膜之基板的一側面上’ 本紙張尺度適用中國國家標準（CNS)A4規格（210 x 297公釐） - > - ^ -----'· — 1!! -裝 — II 訂·！！線 J 乂請先閱讀背面之注意事項再填寫本頁) 經濟部智慧財產局員工消費合作社印製 -46- 405047 a? _ Β7 五、發明說明Q ) 將市售之主動矩陣用液晶定向劑使用旋轉機塗布於其上，經1 8 0 °C、1小時之乾燥，製得膜厚8 Ο Ο A之塗膜。 (請先閱讀背面之注意事項再填寫本頁) (2 )其次，於基板上之塗膜表面，使用具有包覆人 ’造絲布帛滾筒之摩擦機械進行摩擦處理，以形成液晶定向膜。此時之摩擦條件爲滾筒迴轉數4 0 0 r pm，絨毛壓入長度0 . 4 m m。 (3 )製作2片具有此一液晶定向膜之基板，於各基板之外緣部分，使用柵網印刷方式塗布含有直徑1 8 // m 鋁球之環氧樹脂粘著劑後，以與各液晶定向膜摩擦方向相反之方向，將2片基板以隔有間隙方式對向放置，並將各基板外緣部分以相鄰接方式壓粘，並使用粘著劑使其硬化〇 (4 )其次，於各基板之內表面與粘著劑之硬化層所形成之胞隙內，將污染之液晶或未混合著色劑之向列型液晶「Z L I — 5 0 8 1」注入其中，並將注入孔封閉而製經濟部智慧財產局員工消費合作社印製得液晶晶圓。其後，於液晶之外表面將偏光板以其偏光方向與形成於基板單側上之液晶定向膜之摩擦方向相同之方式貼合於其上，而製得液晶顯示元件。評估方法液晶顯示元件之電壓保持率於保持在6 0 °C恆溫槽之液晶顯示元件中，施加6 X 1 0 — 5秒之5 V電壓後，解除施加之電壓後使用「 V H R - 1」（商品名，東洋科技公司製）測定0 . 5秒 -47- 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐）第88110116號專利申諝栗文說明書修正頁 A7 民國89年4月修正五、發明說明（45 ) 後之電壓保持率。液晶顯示元件之燒結、定向不佳等發生之情形使用下記基準進行評估：〇：未發生燒結、定向不佳等情形 X :發生燒結、定向不佳等情形液晶顯示元件經通電後之顯示狀態製作液晶顯示元件時，於塗布液晶 ’使用實施例1〜6或比較例1及2所之方法形成膜厚2.0"m之濾色器，布液晶定向劑後，使用未混有著色劑之 Z L I - 5 0 8 1」，依前記液晶顯示作附有濾色器之液晶顯示元件。其次，置入保持於1 0 〇°C之恆溫槽內，使用月後’使用肉眼及偏光顯微鏡觀察通電之顯示狀態（有無顯示）並依下記標〇：無顯示斑點 1 -X :有顯示斑點定向劑前之基板上得之顏料，依下記並於此濾色器上塗向列型液晶^ 元件之製作方法製將此液晶顯示元件 5V電壓通電1個後之液晶顯示元件準進行評估》 — — — — — — —— — — — — — —— — — — — II ^ · —ί ---I-- (請先閱讀背面之注意事項再^本頁) 經濟部智慧財產局員工消費合作社印製，濾色器之製作方法將各顔料100重量份、（B)成分之2，2 —雙 2 _氯苯基）4，4 ' l四苯基一 1，2聯咪唑1 0重量份與4，4，-雙（二乙胺基）二苯甲酮1 0重量份 C )成分之二季戊四醇基五丙烯酸酯4 0重量份本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） -48- A7 405047 B7____ 五 '發明說明k ) 、（D)成分之甲基丙烯酸/苄基甲基丙烯酸酯/聚苯乙稀巨大單體共聚合物（共聚合重量比=2 5/6 5/1 〇 ’重量平均分子量=55，〇〇〇) 50重量份、有機酸 '之丙二酸5重量份、及作爲溶劑之乙二醇一乙基醚乙酸酯 8 0 0重量份混合，以製作感放射線性組成物。其次，於表面具有防止鈉離子溶出之二氧化矽膜（ S i 02)之鈉玻璃製透明基板之表面上，設置一可區隔畫素圖型部份之遮光層後，使用旋轉塗布機將前記感放射線性組成物塗布於其上，於9 0 °C下經2分鐘之預烘烤，得膜厚2 . 之塗膜。其後將基板冷卻後，使用高壓水銀燈，介著光罩對塗膜施以包含波長365nm、405nm、及436nm 之1 0 〇m J/cm2之紫外線曝光處理。其次，將基板浸泡於2 5 °C、含0 · 1重量％之四甲基銨氫氧化物水溶液中1分鐘以進行顯像處理，以超純水洗淨、風乾後，其後再經1 8 0 °C、3 0分鐘之後烘烤後，而製得具有各邊爲2 0 //mx 2 0 畫素圖型之畫素陣列之濾色器。液晶顯不兀件之光透過性將依前記方法製得之附有漉色器之液晶顯不兀件通以 2 4小時之5 V電壓，再將未混有著色劑之向列型液晶（ Z L I - 5 0 8 1 )依前記方法製作相同之附有濾色器之液晶顯示元件，比較其在通過波長5 5 0 nm時之光透過率之差値，並依下記基準評估。本纸張尺度適用中國國家標準（CNS)A4規格（210 x 297公釐） ^-'----I I II I----訂· I-------I J 、(請先閱讀背面之注意事項再填寫本頁) 經濟部智慧財產局員工消費合作社印製 4050471 修正 i§\ η.The prescriptive solvent 'as long as it can be dissolved or dispersed in the prescriptive components (A), (B), (c), and (D) or in the preliminarily added additive' and does not react with these components and has moderate volatility. Substances can be appropriately selected and used. Such solvents are, for example, ethylene glycol monomethyl ether, ethylene glycol monoethyl ether, ethylene glycol-η-propyl ether, ethylene glycol-η-butyl ether, and the like. ; Ethylene glycol monoalkyl ether acetates such as ethylene glycol monomethyl ether acetate, ethylene glycol monoethyl ether acetate; diethylene glycol monomethyl ether, diethylene glycol monoethyl ether Ether, diethylene glycol mono-η-propyl ether, diethylene glycol --η-butyl ether, triethylene glycol monomethyl ether, triethylene glycol monoethyl ether, and other polyethylene glycol monoalkanes Propyl ethers; propylene glycol monomethyl ether, propylene glycol monoethyl ether, propylene glycol-η-propyl ether, propylene glycol-η-butyl ether and other propylene glycol monoalkyl ethers; dipropylene glycol monomethyl ether, dipropylene glycol Polyethylene glycol monoalkyl ethers such as monoethyl ether 'dipropylene glycol-n-propyl ether, dipropylene glycol-n-butyl ether, tripropylene glycol monomethyl ether, and tripropylene glycol monoethyl ether; Propylene glycol monoalkyl ether acetates such as propylene glycol monomethyl ether acetate, propylene glycol monoethyl ether acetate; diethylene glycol dimethyl ether, diethylene glycol methyl ethyl ether, diethylene glycol two Ethers such as methyl ether, tetrahydrofuran; ketones such as methyl ethyl ketone, cyclohexanone, 2-pentanone, 3-pentanone; ------- ^ -------- ^- --------, (Please read the notes on the back before filling out this page) Printed by the Intellectual Property Bureau Staff Consumer Cooperatives of the Ministry of Economic Affairs This paper is printed in accordance with Chinese National Standards < CNS) A4 (210 X 297) %) -42- Class A; A7 --40SS047_B7 _____ V. Description of the invention) 2-Hydroxypropanoic acid methyl ester, 2-hydroxypropanoic acid ethyl lactate and other alkyl esters > 2 -hydroxy_2 -methylpropionic acid Ethyl ester, methyl 3-hydroxypropionate, ethyl 3 to methoxypropionate, methyl 3-ethoxypropionate, ethyl 3-ethoxyfoulate, ethyl ethoxyacetate, glycolic acid Ethyl ester, 2-hydroxy-3 to methyl butyrate, 3-methyl-3-methoxybutyrate, 3-methyl-methoxypropionate, ethyl acetate, eta-butyl acetate Ester, i-butyl acetate, n-pentyl acetate, i-pentyl acetate, n-butyl propionate, ethyl butyrate, i-propyl butyrate, n-butyl butyrate, methylpyruvate Ester, ethyl pyruvate, η-propyl pyruvate, ethyl acetoacetate Methyl ester, ethyl acetoacetate, 2-carbonyl butyrate and other esters; toluene N—methylpyrrolidone, Ν, Ν—dimethylformamide, Ν, Ν These solvents can They can be used alone or in combination. In these solvents, for example, benzylethyl ether, dihexyl ether, acetone, isophorone, hexanoic acid, octanoic acid, 1-octanol, 1-nonanol, benzyl alcohol, High-boiling solvents such as benzyl acetate, ethyl benzoate, diester oxalate, diester maleate, r-butyrolactone, ethylene carbonate, propylene carbonate, and ethylene glycol monophenyl ether acetate. The above-mentioned high-boiling-point solvents may be used singly or in combination of two or more. Among these solvents, ethylene glycol monomethyl ether acetate is used from the viewpoints of solubility, pigment dispersibility, and coatability. Propylene glycol monomethyl ether, this paper size is applicable to China National Standard (CNS) A4 specification (210 X 297 mm)! · 7 — I ------ 1 ^ «— — — — — 1 — I i, ( Please read the notes on the back before filling out this page) Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs-43- Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 5. Description of the Invention (n) Propylene glycol monomethyl ether acetate , Propylene glycol monoethyl ether acetate, diethylene glycol dimethyl ether, diethylene glycol methyl ethyl ether, cyclohexane, 2-pentanone, 3-pentanone, ethyl 2-hydroxypropionate , 3-methyl-3-methoxybutylpropionate, ethyl 3-methoxypropionate, methyl 3-ethoxypropionate, ethyl 3-ethoxypropionate, acetic acid η- Butyl ester, i-butyl acetate, n-pentyl acetate, i-pentyl acetate, n-butyl propionate, ethyl butyrate, i-propyl butyrate, n-butyrate Butyl ester and ethyl pyruvate are preferred. High boiling point solvents such as r-butyrolactone are preferred. The amount of the solvent used in the present invention is generally 100 to 10,000 parts by weight with respect to the (D) component of 100 to 10,000 parts by weight, and more preferably 500 to 50 ◦ 0 parts by weight. Manufacturing method of color filter Hereinafter, a method of manufacturing a transmissive color filter and a reflective color filter by using the radiation-sensitive composition for a color filter of the present invention will be described. First, a light-shielding layer is formed on the substrate, which can separate the pixel pattern on the transparent substrate. For example, the substrate is coated with a composition in which the green (A) component is dispersed, and the solvent is evaporated by pre-baking. To form a coating film. Secondly, after exposing this coating film to the photomask, use an alkali developing solution to carry out a development process to "dissolve and remove the unexposed part of the coating film, and if necessary, perform post-baking" to fix the colored pixels. A pixel array is formed on a specific pattern. Thereafter, if necessary, each component in which (A) component of other colors (for example, red or blue) is dispersed can be used. According to the same method described above, the Chinese National Standard (CNS) A4 specification ( 210x297 公 i) ~ I-♦ · — — — — — • '_ιι-equipment_! 1 order-! 1 line IJ Second, please read the notes on the back before filling out this page) -44-Employees of Intellectual Property Bureau, Ministry of Economic Affairs Consumer Cooperative printed A7-4ft 3M. __B7 V. Description of the invention k) The composition is subjected to coating, baking, exposure, and development processing, and preferably post-baking processing, and sequentially forming pixel arrays of various colors on the same substrate to obtain a color filter. Device. '' The transparent substrate used when making the color filter may be glass, silicon, polycarbonate, polyester, aromatic polyimide, polyimide, polyimide, or the like. These transparent substrates may be subjected to chemical treatments such as silicon coupling agents, plasma treatments, ion plating treatments, sputtering treatments, gas phase reaction methods, and vacuum evaporation methods, as appropriate, depending on the expectations. When applying the radiation-sensitive composition for a color filter of the present invention to a transparent substrate, it can be performed by a suitable coating method such as spin coating, cast coating, or roll coating. The thickness of the coating is generally 0.1 to 10 μm, preferably 0.2 to 1.5 μm, in terms of the film thickness after drying. The radiation used in making the color filter can be visible light 'ultraviolet rays, extreme ultraviolet rays, electron rays, X-rays, etc. Among them, radiation rays having a wavelength of 190 to 450 nm are preferred. The irradiation energy of the radiation is preferably 1 to 1,000 mJ / cm2. In addition, the aforementioned alkali developing solution is, for example, sodium carbonate, sodium bicarbonate, sodium hydroxide, potassium hydroxide, tetramethylammonium hydroxide, choline, 1,8-diazidebicyclo_ [5. 4 .◦]-7-undecane, 1 '5 mono, diazide bicyclo [4' 3. 0]-5_ Renyuan dilute and other water 丨 valley liquid is preferred. The alkali developing solution may be added with an appropriate amount of a water-soluble organic solvent such as methanol or ethanol or a surfactant. In addition, after alkali development, it will generally pass through this paper standard and apply Chinese National Standard (CNS) A4 specification mo X 297 male f) _ 45-~ '』* · V. ---- ^ --- 1 --- ---- Install -------- Order --------- Line IJ, (Please read the precautions on the back before filling this page) A7 A7 B7 _ ΛΠΓ% 047 V. Description of the invention ) Washed with water. Alkali imaging method can generally use spray imaging method, spray imaging method, dip imaging method, stirring imaging method and other methods. The imaging conditions are preferably 5 to 300 seconds at room temperature. The transmissive and reflective color filters produced in this way are particularly useful for color liquid crystal display devices, color sensors, and the like, in addition to being particularly suitable for color camera tube elements. Embodiments of the Invention Hereinafter, embodiments of the present invention will be described in more detail with examples. However, the present invention is not limited in any way by these examples. The contents of the manufacturing method of contaminated liquid crystals, the manufacturing method of liquid crystal display elements, and various evaluation methods are described below. Method for producing contaminated liquid crystals On a 10 g of nematic liquid crystal (trade name: ZLI-5081, manufactured by Merlot Japan Co., Ltd.) made from a derivative of fluorobiphenyl, a refined coloring agent or unrefined liquid crystal is added. 0.5g of the colorant was stirred at room temperature for 1 hour and mixed, and then heat-treated in an oven at 110 ° C for 1 hour to remove impurities in the colorant from the liquid crystal, and thereafter The solid component was filtered to obtain a contaminated liquid crystal. Manufacturing method of liquid crystal display element (1) on one side of a substrate on which a patterned transparent conductive film is formed 'This paper size applies to China National Standard (CNS) A4 (210 x 297 mm)->-^- --- '· — 1 !!-equipment — II order! !! Line J 乂 Please read the notes on the back before filling out this page) Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs -46- 405047 a? _ Β7 V. Description of the Invention Q) Use of commercially available active matrix liquid crystal alignment agent It was coated on a rotary machine and dried at 180 ° C for 1 hour to obtain a coating film with a thickness of 8 〇 A. (Please read the precautions on the back before filling this page) (2) Secondly, the surface of the coating film on the substrate is rubbed with a friction machine with a man-made silk cloth roller to form a liquid crystal alignment film. The friction conditions at this time were the number of drum revolutions of 400 r pm and the fluff pressing length of 0.4 m m. (3) Two substrates with this liquid crystal alignment film are produced, and the outer edge of each substrate is coated with an epoxy adhesive containing an aluminum ball with a diameter of 1 8 // m by a screen printing method. The orientation direction of the liquid crystal alignment film is opposite to that of the two substrates. The two substrates are placed facing each other with a gap therebetween, and the outer edge portions of the substrates are pressed and adhered adjacently, and then hardened with an adhesive. (4) Second In the interstices formed by the inner surface of each substrate and the hardened layer of the adhesive, a contaminated liquid crystal or a nematic liquid crystal "ZLI — 5 0 8 1" without a colorant is injected thereinto, and the injection holes are injected The liquid crystal wafers were printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs. Thereafter, a polarizing plate was bonded to the outer surface of the liquid crystal in such a manner that the polarizing direction thereof was the same as the rubbing direction of the liquid crystal alignment film formed on one side of the substrate, thereby producing a liquid crystal display element. Evaluation method The voltage retention rate of the liquid crystal display element is applied to a liquid crystal display element held at a constant temperature bath of 60 ° C. After applying a voltage of 5 V for 6 X 1 0 to 5 seconds, use "VHR-1" ( Trade name, manufactured by Toyo Technology Co., Ltd.) Measurement 0.5 seconds -47- This paper size is applicable to Chinese National Standard (CNS) A4 (210 X 297 mm) Patent No. 88110116 Patent Application Specification Revision Sheet A7 Republic of China 89 In April, the voltage retention rate after the invention description (45) was amended. The occurrence of sintering and poor orientation of the liquid crystal display element is evaluated using the following criteria: 〇: No sintering, poor orientation, etc. X: Sintering, poor orientation, etc. Production of the display state of the liquid crystal display element after power-on When applying a liquid crystal display element, use the method of Examples 1 to 6 or Comparative Examples 1 and 2 to form a color filter with a thickness of 2.0 " m and apply a liquid crystal aligning agent. Then use ZLI without colorants. -5 0 8 1 ", according to the previous LCD display as a liquid crystal display element with color filters. Secondly, put it in a constant temperature bath maintained at 100 ° C. After using it, use a naked eye and a polarizing microscope to observe the display state of the current (with or without display) and mark it as follows: 0: no display spots 1 -X: display spots The pigment obtained on the substrate in front of the aligning agent is prepared in accordance with the method described below and coated with nematic liquid crystals on this color filter. The liquid crystal display element after the 5V voltage is applied to the liquid crystal display element is evaluated. — — — — — — — — — — — — — — — — — — II ^ · —ί --- I-- (Please read the notes on the back before ^ this page) The method of making and color filters is to make 100 parts by weight of each pigment, (2) 2,2-bis-2-chlorophenyl), 4, 4 'l tetraphenyl-1,2 biimidazole, and 10 parts by weight. 4,4, -bis (diethylamino) benzophenone 10 parts by weight of C) dipentaerythritol pentaacrylate as a component of 40 parts by weight This paper applies Chinese National Standard (CNS) A4 specifications (210 X 297) Mm) -48- A7 405047 B7____ Five 'invention description k), (D) ingredients Methacrylic acid / benzyl methacrylate / polystyrene macromonomer copolymer (copolymerization weight ratio = 2 5/6 5/1 〇 ′ weight average molecular weight = 55,000,000) 50 parts by weight, 5 parts by weight of malonic acid of the organic acid and 800 parts by weight of ethylene glycol monoethyl ether acetate as a solvent were mixed to prepare a radiation-sensitive composition. Secondly, on the surface of a transparent glass substrate made of sodium glass with a silicon dioxide film (S 02) that prevents the dissolution of sodium ions on the surface, a light-shielding layer that can separate the pixel pattern part is set, and then a spin coater is used to The prescriptive radiation-sensitive composition was coated thereon, and pre-baked at 90 ° C for 2 minutes to obtain a coating film having a thickness of 2. Thereafter, the substrate was cooled, and then the coating film was subjected to an ultraviolet exposure treatment including 100 m J / cm2 at a wavelength of 365 nm, 405 nm, and 436 nm through a photomask using a high-pressure mercury lamp. Next, the substrate was immersed in an aqueous solution of tetramethylammonium hydroxide containing 0.1% by weight at 25 ° C for 1 minute to carry out development processing, washed with ultrapure water, air-dried, and then subjected to 1 After baking at 80 ° C for 30 minutes, a color filter having a pixel array with a pixel pattern of 20 / mx 2 0 on each side was prepared. The light transmittance of the liquid crystal display element will be obtained by applying the 5 V voltage for 24 hours to the liquid crystal display element with the color filter produced according to the previous method, and then the nematic liquid crystal without colorant ( ZLI-5 0 8 1) The same liquid crystal display element with a color filter was fabricated according to the method described above, and the difference in light transmittance at the wavelength of 50 nm was compared, and evaluated according to the following benchmark. This paper size is applicable to China National Standard (CNS) A4 (210 x 297 mm) ^ -'---- II II I ---- Order · I ------- IJ 、 (Please read first (Notes on the back, please fill out this page) Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economy 4050471 Amendment i§ \ η.

f\\^· Α7 R7 經濟部智慧財產局員工消費合作社印製五、發明說明（47 ) 〇：差爲5 %以下 X :差爲5 %以上實施例實施例1 於常溫下，將1 OKg之N-甲基吡咯烷酮加入1 Kg之c.I.碧格曼綠一7中，使用翼長4英吋之狄若爾攪拌器（愛梅克公司製）以迴轉數爲6 5 0 r pm攪拌 3 0分鐘後放置一晚。其次，使用傾析法去除不必要之溶媒後，洗淨殘渣、再與1 〇Kg之N —甲基吡咯烷酮混合 ’反覆進行與前記相同之洗淨、放置及傾析法等共3次，其後經乾燥、精製而製得顏料。所得顔料之精製度爲 0.98° 使用混有此顏料之向列型液晶「Z L I — 508 1」所製得之液晶顯示元件，其電壓保持率、燒結、定向不佳等之發生情形、通電後之顯示狀態極光透過性等內容如表 1所示。實施例2 於常溫下，將1 〇Kg之二甲基碾加入1 Kg之C . I .碧格曼黃一 1 3 9中，使用翼長4英吋之狄若爾攪拌器（愛梅克公司製）以迴轉數爲6 5 0 r pm攪拌3 0分鐘後，使用不鏽鋼濾網過濾，再以1OKg二甲基碣洗淨 2次，其後經乾燥、精製而製得顏料。所得顏料之精製度本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） -50- -----1-----------------—------線 (請先閲讀背面之注意事項再填鸾本頁)f \\ ^ · Α7 R7 Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 5. Description of the invention (47) 〇: Difference is less than 5% X: Difference is more than 5% Example Example 1 At normal temperature, 1 OKg N-methylpyrrolidone was added to 1 Kg of cI Bigman Green-7, using a 4-inch Dior mixer (manufactured by Aimeco) with a revolution of 6 5 0 r pm and stirring 3 0 Leave overnight after minutes. Secondly, after removing unnecessary solvent by decantation, the residue was washed and mixed with 10 Kg of N-methylpyrrolidone to repeat the same washing, standing and decantation methods as the previous three times. The pigment is obtained by drying and refining. The refined system of the obtained pigment is 0.98 °. The liquid crystal display element produced by using the nematic liquid crystal "ZLI — 508 1" mixed with the pigment, the occurrence of voltage retention, sintering, poor orientation, etc. The display state of the aurora transmittance is shown in Table 1. Example 2 At normal temperature, 10 Kg of dimethyl mill was added to 1 Kg of C.I.Bigman Yellow-1 319, using a 4-inch Dyrol mixer (Aimec (Manufactured by the company) After stirring for 30 minutes at a rotation number of 650 r pm, it was filtered using a stainless steel filter, and then washed twice with 1OKg dimethylsulfonium, and then dried and refined to obtain a pigment. The refined system of the obtained pigment The paper size is applicable to the Chinese National Standard (CNS) A4 specification (210 X 297 mm) -50- ----- 1 ----------------- —------ Line (Please read the notes on the back before filling this page)

五、發明說明（48 ) 爲〇 * 9 6 〇 (請先閱讀背面之注意事項再續mr本頁) 使用混有此顏料之向列型液晶「ZL I — 5 08 1」所製得之液晶顯示元件，其電壓保持率、燒結、定向不佳等之發生情形、通電後之顯示狀態極光透過性等內容如表 1所示》實施例3 於常溫下，將lKg之C· I .碧格曼綠一7溶解於 5 〇 K g濃硫酸中，所得溶液再添加入5 0 0 K g之純水中’使顏料再沉澱。所得顏料之精製度爲0 . 9 4。使用混有此顏料之向列型液晶「ZL I — 5081」所製得之液晶顯示元件，其電壓保持率、燒結、定向不佳等之發生情形、通電後之顯示狀態極光透過性等內容如表 1所示。實施例4 , 經濟部智慧財產局員工消費合作社印制声於100°C下，將lKg之C. I .碧格曼綠一 7溶解於5 0 K'g濃硫酸中，其後冷卻至2 0°C，使顏料再沉澱。所得顏料之精製度爲0 . 94。使用混有此顔料之向列型液晶「ZL I — 508 1」所製得之液晶顯示元件，其電壓保持率、燒結、定向不佳等之發生情形、通電後之顯示狀態極光透過性等內容如表 1所示。 -51 - 本纸張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） A7 B7 經濟部智慧財產局員工消费合作社印製實施例6 於常溫下，將1 1 0 K g濃硫酸中，混合物，將其於1 0 之1 0 0 °c之熱濃硫混合液冷卻至2 0 °C 濾，並以1 0 K g之、再結晶法所得之顏使用混有此顏料所製得之液晶顯示元等之發生情形、通電 1所示。 40504*7 9 : 本p”- 丨 _充 ' ' 五、發明說明（49 ) 實施例5 於200°C之真空下，將lKg之C. I .碧格曼綠一 7加熱，所得顏料之精製度爲0 . 9 4。使用混有此顏料之向列型液晶「Z L I — 5 0 8 1」所製得之液晶顯示元件，其電壓保持率、燒結、定向不佳等之發生情形、通電後之顯示狀態極光透過性等容如表 1所示。V. Description of the invention (48) is 〇 * 9 6 〇 (Please read the precautions on the back before continuing on this page) The liquid crystal produced by using the nematic liquid crystal "ZL I — 5 08 1" mixed with this pigment The display element, its voltage retention, sintering, poor orientation, etc., and the display state of the aurora transmittance after power-on are shown in Table 1. "Example 3 At normal temperature, 1Kg of C · I. Mangreen-7 was dissolved in 50K g of concentrated sulfuric acid, and the resulting solution was added to 500 Kg of pure water to reprecipitate the pigment. The fineness of the obtained pigment was 0.94. The liquid crystal display element produced by using the nematic liquid crystal "ZL I-5081" mixed with this pigment, the voltage retention rate, sintering, poor orientation, etc., the display state of the aurora after transmission, etc. Table 1 shows. Example 4: The consumer cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs printed the sound at 100 ° C, dissolving 1 kg of C.I.Bigman Green-7 in 50 K'g of concentrated sulfuric acid, and then cooled to 2 0 ° C, re-precipitate the pigment. The fineness of the obtained pigment was 0.94. The liquid crystal display element produced by using the nematic liquid crystal "ZL I — 508 1" mixed with this pigment, its voltage retention, sintering, poor orientation, etc., the display state of the aurora after transmission, etc. As shown in Table 1. -51-This paper size is in accordance with Chinese National Standard (CNS) A4 (210 X 297 mm) A7 B7 Printed by the Consumers ’Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs Example 6 At room temperature, 1 1 0 g g concentrated sulfuric acid Medium, the mixture, cooled in a hot concentrated sulfur mixture at 10 to 100 ° C to 20 ° C and filtered, and the color obtained by recrystallization method at 10 Kg is used to mix the pigment The occurrence of the obtained liquid crystal display element, etc., is shown in Figure 1. 40504 * 7 9: This p "-丨 _ charge '' V. Description of the Invention (49) Example 5 Under 200 ° C vacuum, lKg of C. I. Biggman Green-7 was heated to obtain the pigment The precision system is 0.94. The liquid crystal display element produced by using the nematic liquid crystal "ZLI — 5 0 8 1" mixed with this pigment, its voltage retention, sintering, poor orientation, etc., and current The following display state of the aurora transmittance is shown in Table 1.

Kg之C. I .碧格曼綠—7溶解於使成部份顔料溶解且部份顏料分散之 0 °C下攪拌1小時後，再添加5 K g 酸後攪拌1小時，並洗淨之。其後將，使溶解之顏料再結晶後，將顔料過純水洗淨2次後乾燥。依此溶媒洗淨料的精製度爲0 . 94。之向列型液晶「Z L I — 5 0 8 1」件，其電壓保持率、燒結、定向不佳後之顯示狀態極光透過性等內容如表實施例7 除將C . I .碧格曼綠一 7變更爲C . I ·碧格曼綠 - 3 6以外，其他皆依實施例6相同之步驟將顔料精製》 -------------裝--------訂jj------線 <請先閱讀背面之注意事項再$本頁) 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） -52- 广 ψ~ Ml 玉 B7 A7 广 ψ~ Ml 玉 B7 A7 經濟部智慧財產局員工消费合作社印製五、發明說明（50 ) 所得之顏料的精製度爲0 . 9 7。使用混有此顏料之向列型液晶「ZL I _5 08 1」所製得之液晶顯示元件，其電壓保持率、燒結、定向不佳等之發生情形、通電後之顯示狀態極光透過性等內容如$ 1所示》表實施例 1 2 3 4 5 6 7 液晶顯示件之評估 •電壓保持率 95 90 95 95 95 97 97 •燒結、定向不〇〇〇〇〇〇〇佳之發生情形 •通電後之顯示〇〇〇〇〇〇〇狀態 •光透過性〇〇〇〇〇〇〇參考例1 使用未混有著色劑之向列型液晶「z L I — 5 Ο 8 1 」所製得之液晶顯示元件，其電壓保持率、燒結、定向不佳等之發生情形、通電ii之顯示狀態極光透過性等內容如表2所示。比較例1 計算未精製之C.I.碧格曼綠_7之精製度得知爲 --------------裝--------訂· ' , ί锖先閱讀背面之注意事項再？；：本頁) 本紙張尺度.適用中國國家標準（CNS)A4規格（210 X 297公釐） -63- 7 4 ο 5 ο 4Kg of C.I.Bigman Green-7 is dissolved at 0 ° C for 1 hour after dissolving part of the pigments and dispersing part of the pigments. After adding 5 Kg of acid, it is stirred for 1 hour and washed. . After that, the dissolved pigment was recrystallized, and the pigment was washed twice with pure water and then dried. Based on this, the fineness of the solvent was 0.94. For the nematic liquid crystal "ZLI — 5 0 8 1", the voltage retention rate, sintering, and display state of the aurora after poor orientation are shown in Table 7 except that C.I.Bigman Green One 7 is changed to C.I. Bigman Green-3, except 6, the pigment is refined according to the same procedure as in Example 6 "------------- Packing ------- -Order jj ------ line < Please read the precautions on the back before you page this page) This paper size is applicable to China National Standard (CNS) A4 (210 X 297 mm) -52- Canton ψ ~ Ml Jade B7 A7 Guang ψ ~ Ml Jade B7 A7 Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 5. The fine pigment system obtained from the invention description (50) is 0.97. The liquid crystal display element produced by using the nematic liquid crystal "ZL I _5 08 1" mixed with this pigment, its voltage retention, sintering, poor orientation, etc., the display state of the aurora after transmission, etc. As shown in $ 1 "Table Example 1 2 3 4 5 6 7 Evaluation of the liquid crystal display device • Voltage retention rate 95 90 95 95 95 97 97 • Occurrence of sintering and orientation not better than 200000.00 • After power-on The display is in the state of light-transmissive, and the light-transmissiveness is shown in Reference Example 1. A liquid crystal display prepared by using a nematic liquid crystal "z LI-5 0 8 1" without a colorant. Table 2 shows the voltage holding rate, sintering, poor orientation, etc. of the device, and the display state of the aurora under power-on II. Comparative Example 1 The calculation of the refined system of the unrefined CI Bigman Green _7 was found to be ---------------------- order, ί 锖先Read the notes on the back again? ;: This page) The paper size. Applicable to China National Standard (CNS) A4 (210 X 297 mm) -63- 7 4 ο 5 ο 4

A7g ----- Trr 1-u-A7g ----- Trr 1-u-

Di 五、發明說萌—作丁〇 . 7 4 ’使用此顏料之液晶顯示元件，其電壓保持率、燒結、定向不佳等之發生情形、通電後之顯示狀態極光透過性等內容如表2所示。比較例2 計算未精製之C. I .碧格曼黃-139之笼製度得知爲0 . 7 0，使用此顏料之液晶顯示元件，其電壓保持率、燒結、定向不佳等之發生情形、通電後之顯示狀態極光透過性等內容如表2所示。比較例1 計算未精製之C · I .碧格曼綠—3 6之精製度得知爲〇 . 7 0，使用此顏料之液晶顯示元件，其電壓保持率、燒結、定向不佳等之發生情形、通電後之顯示狀態極光透過性等內容如表2所示。 !!11_ ^^ i I (請先W讀背面之注意事項再填货表頁) 訂· 線· 經濟部智慧財產局員工消費合作社印製 -54- 本紙張尺度適用中國國家標準（CNS)A4規格（210x297公釐） 405041 一^^^ 44* 本η/尸曰 Α7 Β7 經濟部智慧財產局員工消費合作社印製Di V. The invention is adorable-as Ding 0.74 'The liquid crystal display element using this pigment, its voltage retention rate, sintering, poor orientation, etc., the display state of the aurora after transmission, etc. are shown in Table 2. As shown. Comparative Example 2 Calculating the unrefined C. I. Begman Yellow-139 cage system was found to be 0.70. The liquid crystal display element using this pigment had voltage retention, sintering, and poor orientation. 2. The display state of the aurora transmittance after power-on is shown in Table 2. Comparative Example 1 The unrefined C · I. Begman Green-3 was calculated to be 0.70. The liquid crystal display element using this pigment had voltage retention, sintering, and poor orientation. The situation, the display state of the aurora after power-on, etc. are shown in Table 2. !! 11_ ^^ i I (please read the precautions on the back before filling the form sheet) Order · Thread · Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs -54- This paper size applies to China National Standard (CNS) A4 Specifications (210x297 mm) 405041 1 ^^^ 44 * This η / dead body A7 Β7 Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs

五、發明說兩(52 _ Z 參考例比較例 1 1 2 3 $晶顯示件之評估 •電壓保持率 9 8 7 2 6 8 7 0 •燒結、定向不〇 X X 佳之發生情形 •通電後之顯示〇 X X X 狀態 _ •光透過性 — X X X 1 0重量份與4，份' (C )成分之 (D )成分之甲基巨大單體共聚合物重量平均分子量= 檬康酸5重量份、 8 0 0重量份混合其次，於表面實施例8 將依實施例1精製之顏料與未精製之C . I .碧格曼黃—8 3以7 5/2 5 (重量比）所得之混合物（精製度〇 · 96) 100重量份、（Β)成分之2，2 -雙（2 —氯苯基）4，4'，5，.5'—四苯基一1，2'—聯咪唑 4'一雙（二乙胺基）二苯甲酮1 〇重量二季戊四醇基五丙烯酸酯4 0重量份、丙烯酸/苄基甲基丙烯酸酯/聚苯乙烯 (共聚合重量比=2 5/6 5/1 0， 55，000) 50重量份、有機酸之及作爲溶劑之乙二_ —乙基醚乙酸酯，以製作感放射線性組成物。具有防止鈉離子溶出之二氧化矽膜（ — II----------裝--------訂--Vi,------線 <請先閱讀背面之注意事項再本頁) 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公爱） 55- 40¾㈣伶正五、發明說明炉~~ 振器（東京電色公司製TC — 1800Μ)，以C光源、 2度視野下測定C I Ε表色系中之Υ値，得知Υ = 5 5。又，此畫素陣列之對比値爲3 6 0之低數値。本發明之濾色器用感放射線組成物在作爲濾色器使用時，可顯著地降低以畫素陣列中所包含的著色劑中之不純物爲起因之液晶污染，故作爲液晶顯示件時可顯Β出優良之電壓保持率及通電後之顯示狀態，且不會發生燒結、定向不佳等情形，因而具有高度之可信賴性，此外，亦可製得對放射線具有優良透明性及較高對比之透過型或反射型之滤色器。 n a^i n n I n I - , (請t閱讀背面之注意事項再填f:本頁) ά· 經濟部智慧財產局員工消費合作社印製本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐）Fifth, the invention is two (52 _ Z Reference example Comparative example 1 1 2 3 Evaluation of crystal display parts • Voltage retention rate 9 8 7 2 6 8 7 0 • Sintering and poor orientation XX Good occurrences • Display after power on 〇XXX State _ • Light Transmittance — XXX 1 0 parts by weight and 4, parts of (C) component (D) component of methyl megamonomer copolymer weight average molecular weight = 5 parts by weight of citraconic acid, 8 0 0 parts by weight are mixed, followed by Example 8 on the surface. The pigment refined according to Example 1 and the unrefined C.I.Bigman Yellow-8 are a mixture of 7 5/2 5 (weight ratio) (refining system) 0.96) 100 parts by weight of (B) 2,2-bis (2-chlorophenyl) 4,4 ', 5, .5'-tetraphenyl-1,2'-biimidazole 4'- Bis (diethylamino) benzophenone 1 0 weight dipentaerythritol pentaacrylate 40 weight parts, acrylic acid / benzyl methacrylate / polystyrene (copolymerization weight ratio = 2 5/6 5/1 0,55,000) 50 parts by weight of organic acid and ethylene diethyl ether acetate as a solvent to produce a radiation-sensitive composition. Sodium ion dissolving silicon dioxide film (— II ---------- install -------- order--Vi, ------ line < Please read the note on the back first (Notes on this page) This paper size is in accordance with Chinese National Standard (CNS) A4 (210 X 297 public love) 55- 40 ¾ 伶正正 5. Invention Description Furnace ~~ Vibrator (TC-1800 made by Tokyo Denshoku Corporation) The light source in the CI EI color system was measured under a C light source and a 2 degree field of view, and it was found that Υ = 5 5. In addition, the contrast ratio 此 of this pixel array is a low number of 3 6 0. The color filter feel of the present invention When the radiation composition is used as a color filter, the liquid crystal pollution caused by the impurities in the coloring agent contained in the pixel array can be significantly reduced. Therefore, when used as a liquid crystal display device, it can show excellent voltage retention and The display state after power-on, without sintering or poor orientation, so it has a high degree of reliability. In addition, it can also produce transmission or reflection filters with excellent transparency and high contrast to radiation. Na ^ inn I n I-, (Please read the notes on the back and fill in f: this page) ά Member of Intellectual Property Bureau, Ministry of Economic Affairs Consumer cooperatives printout paper scale applicable Chinese National Standard (CNS) A4 size (210 X 297 mm)

Claims

六、申請專利範圍 A A8 B8 C8 D8 第881 101 16號專利申請案中文申請專利範圍修正本民國8 9年4月修正 1 . 一種濾色器用放射線性組成物，其特徵係包含著色劑，此著色劑爲下式（1 ) 精製度=Y / X 經濟部智慧財產局員工消費合作社印製其中，溫度6 ，Y爲重量％代所得週期5 係指脈所示之精製 (B )光聚量份 (C )多官 10 (D )鹼可量份所構成。 2 .如 X爲注入有向列型 0 t、及火焰週期將前記所注入之向著色劑並去除固體之液晶顯示元件， 0 0微秒下之電壓衝之間隔；度爲0 . 9以上之合起始劑、其含量爲0 . 0 1〜2 0 能性單體、其含量 0重量份爲5〜5 溶性樹脂、其含量爲10〜100重 …（1 ) 液晶之液晶顯示元件於測定 5 0 0微秒下之電壓保持率列型液晶以同型液晶混以5 成分所製得之由污染液晶取於測定溫度6 0 °C、及火焰保持率；又，「火焰週期」著色劑、爲對著色劑（A) 10 ◦重 0重量份，爲對鹼可溶性樹脂（D ) 0 0重量份；及，爲對著色劑（A ) 1 0 0重量份，申請專利範圍第1項之感放射線性組成物，其本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） -------：-----I! ^ in---—訂---------線 I * 乂請先閱讀背面之注意事項再填寫本頁) A8 B8 _μ 六、申請專利範圍中精製度0 . 9以上之著色劑（Α)係由再結晶法、再沉澱法、溶媒洗淨法、昇華法及真空加熱法群中所選出之至少一種精製法所製得。 3 .如申請專利範圍第1項之感放射線性組成物，其中精製度0 . 9以上之著色劑（A)具有0 . 9 3以上之精製度。 4 .如申請專利範圍第1項之感放射線性組成物，其中光聚合起始劑（B )係由聯二咪唑系化合物、苯偶因系化合物、酮苯酚系化合物、二苯甲酮系化合物、α -二酮系化合物、多核苯酮系化合物、氧雜蒽酮系化合物、重氮系化合物及三嗪系化合物群中所選出之至少一種化合物。 5 .如申請專利範圍第1項之感放射線性組成物，其中光聚合起始劑（Β)對多官能性單體（C) 100重量份係含有0·01〜200重量份。 6 ·如申請專利範圍第1項之感放射線性組成物’ 其中多官能性單體（C )之分子內係含有2個以上具有聚合性之乙烯性不飽和性鍵結。經濟部智慧財產局員工消費合作社印製 7 .如申請專利範圍第1項之感放射線性組成物，其中多官能性單體（C )對鹼可涪性樹脂（D ) 1 〇 0重量份係含有5〜5 0 0重量份。 8 .如申請專利範圍第1項之感放射線性組成物，其中鹼可溶性樹脂（D )係爲含羧基之鹼可溶性樹脂或含苯酚性羥基之鹼可溶性樹脂。 9 ·如申請專利範圍第1項之感放射線性組成物，其 -2- 乂請先閱讀背面之注意事項再填寫本頁) 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） A8 B8 C8 D8 405047 六、申請專利範圍中鹼可溶性樹脂（D )對精製度0 . 9以上之著色劑 )100重量份係含有10〜1，〇〇 ◦重量份。 A .'(請先閱讀背面之注意事項再填寫本頁) 訂---------線| 經濟部智慧財產局員工消費合作社印製 -3 - 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐）第88110116號專利申諝栗文說明書修正頁 A7 民國89年4月修正五、發明說明（45 ) 後之電壓保持率。液晶顯示元件之燒結、定向不佳等發生之情形使用下記基準進行評估：〇：未發生燒結、定向不佳等情形 X :發生燒結、定向不佳等情形液晶顯示元件經通電後之顯示狀態製作液晶顯示元件時，於塗布液晶 ’使用實施例1〜6或比較例1及2所之方法形成膜厚2.0"m之濾色器，布液晶定向劑後，使用未混有著色劑之 Z L I - 5 0 8 1」，依前記液晶顯示作附有濾色器之液晶顯示元件。其次，置入保持於1 0 〇°C之恆溫槽內，使用月後’使用肉眼及偏光顯微鏡觀察通電之顯示狀態（有無顯示）並依下記標〇：無顯示斑點 1 -X :有顯示斑點定向劑前之基板上得之顏料，依下記並於此濾色器上塗向列型液晶^ 元件之製作方法製將此液晶顯示元件 5V電壓通電1個後之液晶顯示元件準進行評估》 — — — — — — —— — — — — — —— — — — — II ^ · —ί ---I-- (請先閱讀背面之注意事項再^本頁) 經濟部智慧財產局員工消費合作社印製，濾色器之製作方法將各顔料100重量份、（B)成分之2，2 —雙 2 _氯苯基）4，4 ' l四苯基一 1，2聯咪唑1 0重量份與4，4，-雙（二乙胺基）二苯甲酮1 0重量份 C )成分之二季戊四醇基五丙烯酸酯4 0重量份本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） -48- 4050471 修正 i§\ η.Six, the scope of patent application A A8 B8 C8 D8 patent application No. 881 101 16 Chinese patent application scope amendment April 1989 Amendment 1. A radioactive composition for color filters, which is characterized by containing a colorant, this The coloring agent is the following formula (1) Refined system = Y / X Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs, where temperature is 6 and Y is the weight% generation period 5 is the refined (B) photoconcentration shown in the vein Serving (C) Multi-Den 10 (D) Alkali can be quantified. 2. For example, if X is a nematic type 0 t and a flame cycle, the liquid crystal display element in which the above-mentioned injected colorant is removed and the solid is removed, the interval between the voltage impulses at 0 microseconds; the degree is 0.9 or more. Combined with initiator, its content is 0.01 to 2 0, functional monomer, its content is 0 to 5 parts by weight, soluble resin, its content is 10 to 100 weight ... (1) liquid crystal display element of liquid crystal is measured Voltage retention rate at 500 microseconds. Liquid crystals made from homogeneous liquid crystals mixed with 5 components are taken from polluted liquid crystals at a measurement temperature of 60 ° C and the flame retention rate. Also, the "flame cycle" colorant, For colorant (A) 10 ◦ 0 parts by weight, for alkali-soluble resin (D) 0 0 parts by weight; and, for colorant (A) 100 parts by weight, the feeling of applying for the first item of the patent scope Radial composition, the paper size of this paper applies Chinese National Standard (CNS) A4 specification (210 X 297 mm) -------: ----- I! ^ In ----- order --- ------ Line I * 乂 Please read the notes on the back before filling in this page) A8 B8 _μ VI. The patents in the scope of patent application 0.9 or above Agents ([alpha]) by the Department of recrystallization method, reprecipitation method, a solvent washing method, a sublimation method and a vacuum heating process in the selected group at least one purification method matter prepared. 3. If the radiation-sensitive composition of item 1 of the scope of patent application, the coloring agent (A) with a precision of 0.9 or more has a precision of 0.93 or more. 4. The radiation-sensitive composition according to item 1 of the patent application scope, wherein the photopolymerization initiator (B) is composed of a biimidazole-based compound, a benzoin-based compound, a ketophenol-based compound, and a benzophenone-based compound At least one selected from the group consisting of α-diketone compounds, polynuclear benzophenone compounds, xanthones, diazo compounds, and triazine compounds. 5. The radiation-sensitive composition according to item 1 of the patent application range, wherein the photopolymerization initiator (B) contains 0.01 to 200 parts by weight of 100 parts by weight of the polyfunctional monomer (C). 6 · The radiation-sensitive composition according to item 1 of the patent application range, wherein the polyfunctional monomer (C) contains two or more ethylenically unsaturated bonds having a polymerizability in the molecule. Printed by the Consumers ’Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs. 7. The radiation-sensitive composition as described in the first patent application scope, where the polyfunctional monomer (C) is alkali-resistant resin (D). Contains 5 to 500 parts by weight. 8. The radiation-sensitive composition according to item 1 of the patent application range, wherein the alkali-soluble resin (D) is an alkali-soluble resin containing a carboxyl group or an alkali-soluble resin containing a phenolic hydroxyl group. 9 · If the radiation-sensitive composition in the first scope of the patent application, its -2- 乂 Please read the precautions on the back before filling out this page) This paper size applies to China National Standard (CNS) A4 (210 X 297) (Centi) A8 B8 C8 D8 405047 VI. Alkali-soluble resin (D) in the scope of the patent application (coloring agent of 0.9 or more in the fine system) 100 parts by weight contains 10 to 1,000,000. A. '(Please read the notes on the back before filling out this page) Order --------- line | Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs-3-This paper size applies to Chinese national standards (CNS ) Specification A4 (210 X 297 mm) Patent Application No. 88110116 Amendment to the Li Wen Specification Revised Page A7 Rev. April 89, Republic of China V. Voltage retention after the invention description (45). The occurrence of sintering and poor orientation of the liquid crystal display element is evaluated using the following criteria: 〇: No sintering, poor orientation, etc. X: Sintering, poor orientation, etc. Production of the display state of the liquid crystal display element after power-on When applying a liquid crystal display element, use the method of Examples 1 to 6 or Comparative Examples 1 and 2 to form a color filter with a thickness of 2.0 " m and apply a liquid crystal aligning agent. Then use ZLI without colorants. -5 0 8 1 ", according to the previous LCD display as a liquid crystal display element with color filters. Secondly, put it in a constant temperature bath maintained at 100 ° C. After using it, use a naked eye and a polarizing microscope to observe the display state of the current (with or without display) and mark it as follows: 0: no display spots 1 -X: display spots The pigment obtained on the substrate in front of the aligning agent is prepared in accordance with the method described below and coated with nematic liquid crystals on this color filter. The liquid crystal display element after the 5V voltage is applied to the liquid crystal display element is evaluated. — — — — — — — — — — — — — — — — — — II ^ · —ί --- I-- (Please read the notes on the back before ^ this page) The method of making and color filters is to make 100 parts by weight of each pigment, (2) 2,2-bis-2-chlorophenyl), 4, 4 'l tetraphenyl-1,2 biimidazole, and 10 parts by weight. 4,4, -bis (diethylamino) benzophenone 10 parts by weight of C) dipentaerythritol pentaacrylate as a component of 40 parts by weight This paper applies Chinese National Standard (CNS) A4 specifications (210 X 297) Mm) -48- 4050471 correction i§ \ η.

五、發明說明（48 ) 爲〇 * 9 6 〇 (請先閱讀背面之注意事項再續mr本頁) 使用混有此顏料之向列型液晶「ZL I — 5 08 1」所製得之液晶顯示元件，其電壓保持率、燒結、定向不佳等之發生情形、通電後之顯示狀態極光透過性等內容如表 1所示》實施例3 於常溫下，將lKg之C· I .碧格曼綠一7溶解於 5 〇 K g濃硫酸中，所得溶液再添加入5 0 0 K g之純水中’使顏料再沉澱。所得顏料之精製度爲0 . 9 4。使用混有此顏料之向列型液晶「ZL I — 5081」所製得之液晶顯示元件，其電壓保持率、燒結、定向不佳等之發生情形、通電後之顯示狀態極光透過性等內容如表 1所示。實施例4 , 經濟部智慧財產局員工消費合作社印制声於100°C下，將lKg之C. I .碧格曼綠一 7溶解於5 0 K'g濃硫酸中，其後冷卻至2 0°C，使顏料再沉澱。所得顏料之精製度爲0 . 94。使用混有此顔料之向列型液晶「ZL I — 508 1」所製得之液晶顯示元件，其電壓保持率、燒結、定向不佳等之發生情形、通電後之顯示狀態極光透過性等內容如表 1所示。 -51 - 本纸張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） A7 B7 經濟部智慧財產局員工消费合作社印製實施例6 於常溫下，將1 1 0 K g濃硫酸中，混合物，將其於1 0 之1 0 0 °c之熱濃硫混合液冷卻至2 0 °C 濾，並以1 0 K g之、再結晶法所得之顏使用混有此顏料所製得之液晶顯示元等之發生情形、通電 1所示。 40504*7 9 : 本p”- 丨 _充 ' ' 五、發明說明（49 ) 實施例5 於200°C之真空下，將lKg之C. I .碧格曼綠一 7加熱，所得顏料之精製度爲0 . 9 4。使用混有此顏料之向列型液晶「Z L I — 5 0 8 1」所製得之液晶顯示元件，其電壓保持率、燒結、定向不佳等之發生情形、通電後之顯示狀態極光透過性等容如表 1所示。 Kg之C. I .碧格曼綠—7溶解於使成部份顔料溶解且部份顏料分散之 0 °C下攪拌1小時後，再添加5 K g 酸後攪拌1小時，並洗淨之。其後將，使溶解之顏料再結晶後，將顔料過純水洗淨2次後乾燥。依此溶媒洗淨料的精製度爲0 . 94。之向列型液晶「Z L I — 5 0 8 1」件，其電壓保持率、燒結、定向不佳後之顯示狀態極光透過性等內容如表實施例7 除將C . I .碧格曼綠一 7變更爲C . I ·碧格曼綠 - 3 6以外，其他皆依實施例6相同之步驟將顔料精製》 -------------裝--------訂jj------線 <請先閱讀背面之注意事項再$本頁) 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） -52- 广 ψ~ Ml 玉 B7 A7 广 ψ~ Ml 玉 B7 A7 經濟部智慧財產局員工消费合作社印製五、發明說明（50 ) 所得之顏料的精製度爲0 . 9 7。使用混有此顏料之向列型液晶「ZL I _5 08 1」所製得之液晶顯示元件，其電壓保持率、燒結、定向不佳等之發生情形、通電後之顯示狀態極光透過性等內容如$ 1所示》表實施例 1 2 3 4 5 6 7 液晶顯示件之評估 •電壓保持率 95 90 95 95 95 97 97 •燒結、定向不〇〇〇〇〇〇〇佳之發生情形 •通電後之顯示〇〇〇〇〇〇〇狀態 •光透過性〇〇〇〇〇〇〇參考例1 使用未混有著色劑之向列型液晶「z L I — 5 Ο 8 1 」所製得之液晶顯示元件，其電壓保持率、燒結、定向不佳等之發生情形、通電ii之顯示狀態極光透過性等內容如表2所示。比較例1 計算未精製之C.I.碧格曼綠_7之精製度得知爲 --------------裝--------訂· ' , ί锖先閱讀背面之注意事項再？；：本頁) 本紙張尺度.適用中國國家標準（CNS)A4規格（210 X 297公釐） -63- 7 4 ο 5 ο 4V. Description of the invention (48) is 〇 * 9 6 〇 (Please read the precautions on the back before continuing on this page) The liquid crystal produced by using the nematic liquid crystal "ZL I — 5 08 1" mixed with this pigment The display element, its voltage retention, sintering, poor orientation, etc., and the display state of the aurora transmittance after power-on are shown in Table 1. "Example 3 At normal temperature, 1Kg of C · I. Bige Mangreen-7 was dissolved in 50K g of concentrated sulfuric acid, and the resulting solution was added to 500 Kg of pure water to reprecipitate the pigment. The fineness of the obtained pigment was 0.94. The liquid crystal display element produced by using the nematic liquid crystal "ZL I-5081" mixed with this pigment, the voltage retention rate, sintering, poor orientation, etc., the display state of the aurora after transmission, etc. Table 1 shows. Example 4: The consumer cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs printed the sound at 100 ° C, dissolving 1 kg of C.I.Bigman Green-7 in 50 K'g of concentrated sulfuric acid, and then cooled to 2 0 ° C, re-precipitate the pigment. The fineness of the obtained pigment was 0.94. The liquid crystal display element produced by using the nematic liquid crystal "ZL I — 508 1" mixed with this pigment, its voltage retention, sintering, poor orientation, etc., the display state of the aurora after transmission, etc. As shown in Table 1. -51-This paper size is in accordance with Chinese National Standard (CNS) A4 (210 X 297 mm) A7 B7 Printed by the Consumers ’Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs Example 6 At room temperature, 1 1 0 g g concentrated sulfuric acid Medium, the mixture, cooled in a hot concentrated sulfur mixture at 10 to 100 ° C to 20 ° C and filtered, and the color obtained by recrystallization method at 10 Kg is used to mix the pigment The occurrence of the obtained liquid crystal display element, etc., is shown in Figure 1. 40504 * 7 9: This p "-丨 _ charge '' V. Description of the Invention (49) Example 5 Under 200 ° C vacuum, lKg of C. I. Biggman Green-7 was heated to obtain the pigment The precision system is 0.94. The liquid crystal display element produced by using the nematic liquid crystal "ZLI — 5 0 8 1" mixed with this pigment, its voltage retention, sintering, poor orientation, etc., and current The following display state of the aurora transmittance is shown in Table 1. Kg of C.I.Bigman Green-7 is dissolved at 0 ° C for 1 hour after dissolving part of the pigments and dispersing part of the pigments. After adding 5 Kg of acid, it is stirred for 1 hour and washed. . After that, the dissolved pigment was recrystallized, and the pigment was washed twice with pure water and then dried. Based on this, the fineness of the solvent was 0.94. For the nematic liquid crystal "ZLI — 5 0 8 1", the voltage retention rate, sintering, and display state of the aurora after poor orientation are shown in Table 7 except that C.I.Bigman Green One 7 is changed to C.I. Bigman Green-3, except 6, the pigment is refined according to the same procedure as in Example 6 "------------- Packing ------- -Order jj ------ line < Please read the precautions on the back before you page this page) This paper size is applicable to China National Standard (CNS) A4 (210 X 297 mm) -52- Canton ψ ~ Ml Jade B7 A7 Guang ψ ~ Ml Jade B7 A7 Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 5. The fine pigment system obtained from the invention description (50) is 0.97. The liquid crystal display element produced by using the nematic liquid crystal "ZL I _5 08 1" mixed with this pigment, its voltage retention, sintering, poor orientation, etc., the display state of the aurora after transmission, etc. As shown in $ 1 "Table Example 1 2 3 4 5 6 7 Evaluation of the liquid crystal display device • Voltage retention rate 95 90 95 95 95 97 97 • Occurrence of sintering and orientation not better than 200000.00 • After power-on The display is in the state of light-transmissive, and the light-transmissiveness is shown in Reference Example 1. A liquid crystal display prepared by using a nematic liquid crystal "z LI-5 0 8 1" without a colorant. Table 2 shows the voltage holding rate, sintering, poor orientation, etc. of the device, and the display state of the aurora under power-on II. Comparative Example 1 The calculation of the refined system of the unrefined CI Bigman Green _7 was found to be ---------------------- order, ί 锖先Read the notes on the back again? ;: This page) The paper size. Applicable to China National Standard (CNS) A4 (210 X 297 mm) -63- 7 4 ο 5 ο 4

A7g ----- Trr 1-u- Di 五、發明說萌—作丁〇 . 7 4 ’使用此顏料之液晶顯示元件，其電壓保持率、燒結、定向不佳等之發生情形、通電後之顯示狀態極光透過性等內容如表2所示。比較例2 計算未精製之C. I .碧格曼黃-139之笼製度得知爲0 . 7 0，使用此顏料之液晶顯示元件，其電壓保持率、燒結、定向不佳等之發生情形、通電後之顯示狀態極光透過性等內容如表2所示。比較例1 計算未精製之C · I .碧格曼綠—3 6之精製度得知爲〇 . 7 0，使用此顏料之液晶顯示元件，其電壓保持率、燒結、定向不佳等之發生情形、通電後之顯示狀態極光透過性等內容如表2所示。 !!11_ ^^ i I (請先W讀背面之注意事項再填货表頁) 訂· 線· 經濟部智慧財產局員工消費合作社印製 -54- 本紙張尺度適用中國國家標準（CNS)A4規格（210x297公釐） 405041 一^^^ 44* 本η/尸曰 Α7 Β7 經濟部智慧財產局員工消費合作社印製五、發明說兩(52 _ Z 參考例比較例 1 1 2 3 $晶顯示件之評估 •電壓保持率 9 8 7 2 6 8 7 0 •燒結、定向不〇 X X 佳之發生情形 •通電後之顯示〇 X X X 狀態 _ •光透過性 — X X X 1 0重量份與4，份' (C )成分之 (D )成分之甲基巨大單體共聚合物重量平均分子量= 檬康酸5重量份、 8 0 0重量份混合其次，於表面實施例8 將依實施例1精製之顏料與未精製之C . I .碧格曼黃—8 3以7 5/2 5 (重量比）所得之混合物（精製度〇 · 96) 100重量份、（Β)成分之2，2 -雙（2 —氯苯基）4，4'，5，.5'—四苯基一1，2'—聯咪唑 4'一雙（二乙胺基）二苯甲酮1 〇重量二季戊四醇基五丙烯酸酯4 0重量份、丙烯酸/苄基甲基丙烯酸酯/聚苯乙烯 (共聚合重量比=2 5/6 5/1 0， 55，000) 50重量份、有機酸之及作爲溶劑之乙二_ —乙基醚乙酸酯，以製作感放射線性組成物。具有防止鈉離子溶出之二氧化矽膜（ — II----------裝--------訂--Vi,------線 <請先閱讀背面之注意事項再本頁) 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公爱） 55- 40¾㈣伶正五、發明說明炉~~ 振器（東京電色公司製TC — 1800Μ)，以C光源、 2度視野下測定C I Ε表色系中之Υ値，得知Υ = 5 5。又，此畫素陣列之對比値爲3 6 0之低數値。本發明之濾色器用感放射線組成物在作爲濾色器使用時，可顯著地降低以畫素陣列中所包含的著色劑中之不純物爲起因之液晶污染，故作爲液晶顯示件時可顯Β出優良之電壓保持率及通電後之顯示狀態，且不會發生燒結、定向不佳等情形，因而具有高度之可信賴性，此外，亦可製得對放射線具有優良透明性及較高對比之透過型或反射型之滤色器。 n a^i n n I n I - , (請t閱讀背面之注意事項再填f:本頁) ά· 經濟部智慧財產局員工消費合作社印製本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐）六、申請專利範圍 A A8 B8 C8 D8 第881 101 16號專利申請案中文申請專利範圍修正本民國8 9年4月修正 1 . 一種濾色器用放射線性組成物，其特徵係包含著色劑，此著色劑爲下式（1 ) 精製度=Y / X 經濟部智慧財產局員工消費合作社印製其中，溫度6 ，Y爲重量％代所得週期5 係指脈所示之精製 (B )光聚量份 (C )多官 10 (D )鹼可量份所構成。 2 .如 X爲注入有向列型 0 t、及火焰週期將前記所注入之向著色劑並去除固體之液晶顯示元件， 0 0微秒下之電壓衝之間隔；度爲0 . 9以上之合起始劑、其含量爲0 . 0 1〜2 0 能性單體、其含量 0重量份爲5〜5 溶性樹脂、其含量爲10〜100重 …（1 ) 液晶之液晶顯示元件於測定 5 0 0微秒下之電壓保持率列型液晶以同型液晶混以5 成分所製得之由污染液晶取於測定溫度6 0 °C、及火焰保持率；又，「火焰週期」著色劑、爲對著色劑（A) 10 ◦重 0重量份，爲對鹼可溶性樹脂（D ) 0 0重量份；及，爲對著色劑（A ) 1 0 0重量份，申請專利範圍第1項之感放射線性組成物，其本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） -------：-----I! ^ in---—訂---------線 I * 乂請先閱讀背面之注意事項再填寫本頁) A8 B8 _μ 六、申請專利範圍中精製度0 . 9以上之著色劑（Α)係由再結晶法、再沉澱法、溶媒洗淨法、昇華法及真空加熱法群中所選出之至少一種精製法所製得。 3 .如申請專利範圍第1項之感放射線性組成物，其中精製度0 . 9以上之著色劑（A)具有0 . 9 3以上之精製度。 4 .如申請專利範圍第1項之感放射線性組成物，其中光聚合起始劑（B )係由聯二咪唑系化合物、苯偶因系化合物、酮苯酚系化合物、二苯甲酮系化合物、α -二酮系化合物、多核苯酮系化合物、氧雜蒽酮系化合物、重氮系化合物及三嗪系化合物群中所選出之至少一種化合物。 5 .如申請專利範圍第1項之感放射線性組成物，其中光聚合起始劑（Β)對多官能性單體（C) 100重量份係含有0·01〜200重量份。 6 ·如申請專利範圍第1項之感放射線性組成物’ 其中多官能性單體（C )之分子內係含有2個以上具有聚合性之乙烯性不飽和性鍵結。經濟部智慧財產局員工消費合作社印製 7 .如申請專利範圍第1項之感放射線性組成物，其中多官能性單體（C )對鹼可涪性樹脂（D ) 1 〇 0重量份係含有5〜5 0 0重量份。 8 .如申請專利範圍第1項之感放射線性組成物，其中鹼可溶性樹脂（D )係爲含羧基之鹼可溶性樹脂或含苯酚性羥基之鹼可溶性樹脂。 9 ·如申請專利範圍第1項之感放射線性組成物，其 -2- 乂請先閱讀背面之注意事項再填寫本頁) 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） A8 B8 C8 D8 405047 六、申請專利範圍中鹼可溶性樹脂（D )對精製度0 . 9以上之著色劑 )100重量份係含有10〜1，〇〇 ◦重量份。 A .'(請先閱讀背面之注意事項再填寫本頁) 訂---------線| 經濟部智慧財產局員工消費合作社印製 -3 - 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐）A7g ----- Trr 1-u- Di V. Inventor Moe-Ding 0.74 'The liquid crystal display element using this pigment, its voltage retention, sintering, poor orientation, etc., after power-on The display state of the aurora transmittance and other contents are shown in Table 2. Comparative Example 2 Calculating the unrefined C. I. Begman Yellow-139 cage system was found to be 0.70. The liquid crystal display element using this pigment had voltage retention, sintering, and poor orientation. 2. The display state of the aurora transmittance after power-on is shown in Table 2. Comparative Example 1 The unrefined C · I. Begman Green-3 was calculated to be 0.70. The liquid crystal display element using this pigment had voltage retention, sintering, and poor orientation. The situation, the display state of the aurora after power-on, etc. are shown in Table 2. !! 11_ ^^ i I (please read the precautions on the back before filling the form sheet) Order · Thread · Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs -54- This paper size applies to China National Standard (CNS) A4 Specifications (210x297 mm) 405041 1 ^^^ 44 * This η / dead body A7 Β7 Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs Five, Inventions Two (52 _ Z Reference example Comparative example 1 1 2 3 $ 晶展示Evaluation of the components • Voltage retention rate 9 8 7 2 6 8 7 0 • Poor sintering and poor orientation. XX • Occurrence after power-on. XXX Status _ • Light Transmittance — XXX 1 0 parts by weight and 4, parts' ( C) The weight average molecular weight of the methyl megamonomer copolymer of the component (D) = 5 parts by weight of citraconic acid and 800 parts by weight of the second component. On the surface of Example 8, the pigment purified according to Example 1 and Unrefined C.I.Bigman Yellow-8 3 at a ratio of 7 5/2 5 (weight ratio) (refined system 0.96) 100 parts by weight, (B) component 2, 2-double (2 —Chlorophenyl) 4,4 ', 5, .5'-tetraphenyl-1,2'-biimidazole 4'-1 (Diethylamino) benzophenone 10 weight parts dipentaerythritol pentaacrylate 40 parts by weight, acrylic acid / benzyl methacrylate / polystyrene (copolymerization weight ratio = 2 5/6 5/1 0 , 55,000) 50 parts by weight of organic acid and ethylene diethyl ether acetate as a solvent to produce a radiation-sensitive composition. Silicon dioxide film (— II-- -------- Installation -------- Order --Vi, ------ line < Please read the precautions on the back before this page) This paper size applies Chinese national standards ( CNS) A4 specification (210 X 297 public love) 55- 40¾㈣正正 5. Inventive furnace ~~ Vibrator (TC-1800M manufactured by Tokyo Denshoku Co., Ltd.), measuring CI EI color system with C light source and 2 degree field of view It is found that Υ = 5 5. In addition, the contrast ratio 此 of this pixel array is a low number of 3 6 0. The radiation-sensitive composition for color filters of the present invention can be used significantly as a color filter. In order to reduce the liquid crystal pollution caused by the impurities in the toner contained in the pixel array, it can show excellent voltage retention and current when used as a liquid crystal display. The subsequent display state, without sintering or poor orientation, has a high degree of reliability. In addition, it can also produce transmissive or reflective color filters with excellent transparency and high contrast to radiation. Device. na ^ inn I n I-, (Please read the notes on the back and fill in f: this page) ά · Printed by the Employees' Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs This paper is printed in accordance with Chinese National Standard (CNS) A4 (210 X 297 mm) 6. Scope of patent application A A8 B8 C8 D8 Patent Application No. 881 101 16 Chinese Patent Application Amendment The Republic of China 8 April 2009 Amendment 1. A radioactive composition for color filters, the characteristics of which include Colorant, the colorant is the following formula (1) Refining system = Y / X Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs, where temperature is 6 and Y is the weight%. Generation period 5 is the refinement shown in the vein (B ) Photopolymerization (C) Polyguan 10 (D) Alkali content. 2. For example, if X is a nematic type 0 t and a flame cycle, the liquid crystal display element in which the above-mentioned injected colorant is removed and the solid is removed, the interval between the voltage impulses at 0 microseconds; the degree is 0.9 or more. Combined with initiator, its content is 0.01 to 2 0, functional monomer, its content is 0 to 5 parts by weight, soluble resin, its content is 10 to 100 weight ... (1) liquid crystal display element of liquid crystal is measured Voltage retention rate at 500 microseconds. Liquid crystals made from homogeneous liquid crystals mixed with 5 components are taken from polluted liquid crystals at a measurement temperature of 60 ° C and the flame retention rate. Also, the "flame cycle" colorant, For colorant (A) 10 ◦ 0 parts by weight, for alkali-soluble resin (D) 0 0 parts by weight; and, for colorant (A) 100 parts by weight, the feeling of applying for the first item of the patent scope Radial composition, the paper size of this paper applies Chinese National Standard (CNS) A4 specification (210 X 297 mm) -------: ----- I! ^ In ----- order --- ------ Line I * 乂 Please read the notes on the back before filling in this page) A8 B8 _μ VI. The patents in the scope of patent application 0.9 or above Agents ([alpha]) by the Department of recrystallization method, reprecipitation method, a solvent washing method, a sublimation method and a vacuum heating process in the selected group at least one purification method matter prepared. 3. If the radiation-sensitive composition of item 1 of the scope of patent application, the coloring agent (A) with a precision of 0.9 or more has a precision of 0.93 or more. 4. The radiation-sensitive composition according to item 1 of the patent application scope, wherein the photopolymerization initiator (B) is composed of a biimidazole-based compound, a benzoin-based compound, a ketophenol-based compound, and a benzophenone-based compound. At least one selected from the group consisting of α-diketone compounds, polynuclear benzophenone compounds, xanthones, diazo compounds, and triazine compounds. 5. The radiation-sensitive composition according to item 1 of the patent application range, wherein the photopolymerization initiator (B) contains 0.01 to 200 parts by weight of 100 parts by weight of the polyfunctional monomer (C). 6 · The radiation-sensitive composition according to item 1 of the patent application range, wherein the polyfunctional monomer (C) contains two or more ethylenically unsaturated bonds having a polymerizability in the molecule. Printed by the Consumers ’Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs. 7. The radiation-sensitive composition as described in the first patent application scope, where the polyfunctional monomer (C) is alkali-resistant resin (D). Contains 5 to 500 parts by weight. 8. The radiation-sensitive composition according to item 1 of the patent application range, wherein the alkali-soluble resin (D) is an alkali-soluble resin containing a carboxyl group or an alkali-soluble resin containing a phenolic hydroxyl group. 9 · If the radiation-sensitive composition in the first scope of the patent application, its -2- 乂 Please read the precautions on the back before filling out this page) This paper size applies to China National Standard (CNS) A4 (210 X 297) (Centi) A8 B8 C8 D8 405047 VI. Alkali-soluble resin (D) in the scope of the patent application (coloring agent of 0.9 or more in the fine system) 100 parts by weight contains 10 to 1,000,000. A. '(Please read the notes on the back before filling out this page) Order --------- line | Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs-3-This paper size applies to Chinese national standards (CNS ) A4 size (210 X 297 mm)