TW371305B - Process for preparing polymers of monovinylidene aromatic monomers - Google Patents

Process for preparing polymers of monovinylidene aromatic monomers

Info

Publication number
TW371305B
TW371305B TW084109815A TW84109815A TW371305B TW 371305 B TW371305 B TW 371305B TW 084109815 A TW084109815 A TW 084109815A TW 84109815 A TW84109815 A TW 84109815A TW 371305 B TW371305 B TW 371305B
Authority
TW
Taiwan
Prior art keywords
hydrocarbyl
aromatic monomers
monovinylidene aromatic
hydrocarbyloxy
polymers
Prior art date
Application number
TW084109815A
Other languages
English (en)
Inventor
Peter N Nickias
Thomas H Newman
Karen K Borodychuk
Original Assignee
Idemitsu Kosan Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Idemitsu Kosan Co filed Critical Idemitsu Kosan Co
Application granted granted Critical
Publication of TW371305B publication Critical patent/TW371305B/zh

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F12/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
    • C08F12/02—Monomers containing only one unsaturated aliphatic radical
    • C08F12/04—Monomers containing only one unsaturated aliphatic radical containing one ring
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F17/00—Metallocenes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
TW084109815A 1994-10-03 1995-09-19 Process for preparing polymers of monovinylidene aromatic monomers TW371305B (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US08/316,748 US5536797A (en) 1994-10-03 1994-10-03 Syndiotactic prochiral olefin polymerization process

Publications (1)

Publication Number Publication Date
TW371305B true TW371305B (en) 1999-10-01

Family

ID=23230493

Family Applications (1)

Application Number Title Priority Date Filing Date
TW084109815A TW371305B (en) 1994-10-03 1995-09-19 Process for preparing polymers of monovinylidene aromatic monomers

Country Status (11)

Country Link
US (1) US5536797A (zh)
EP (1) EP0784639B1 (zh)
JP (1) JPH10506932A (zh)
KR (1) KR100357358B1 (zh)
CN (1) CN1082057C (zh)
BR (1) BR9509493A (zh)
CA (1) CA2200956A1 (zh)
DE (1) DE69507626T2 (zh)
MX (1) MX9702453A (zh)
TW (1) TW371305B (zh)
WO (1) WO1996010592A1 (zh)

Families Citing this family (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5670680A (en) * 1996-04-26 1997-09-23 The Dow Chemical Company Method for producing octahydrofluorenyl metal complexes
US6100352A (en) * 1996-05-29 2000-08-08 Idemitsu Kosan Co., Ltd. Process for producing polymer
KR20010042509A (ko) 1998-04-07 2001-05-25 그래햄 이. 테일러 개선된 신디오택틱 비닐리덴 방향족 중합체의 중합방법
US6232415B1 (en) * 1999-03-31 2001-05-15 Phillips Petroleum Company Process to produce a monovinylaromatic/ monoolefin polymer and said monovinylaromatic/monoolefin polymer
US6232414B1 (en) * 1999-03-31 2001-05-15 Phillips Petroleum Company Process to make a monovinylaromatic polymer and said monovinylaromatic polymer
DE60217675T2 (de) * 2001-06-29 2007-10-11 E.I. Du Pont De Nemours And Co., Wilmington Hydroxylierung von beta-dicarbonyl mit zirkonium katalysatoren
WO2004108775A1 (en) * 2003-06-05 2004-12-16 Dow Global Technologies Inc. Activated multinuclear transition metal catalyst compositions
ES2638913T3 (es) * 2009-08-31 2017-10-24 Dow Global Technologies Llc Catalizador y procedimiento para polimerizar una olefina y poliolefina preparada mediante el mismo
CN111902439B (zh) 2018-03-30 2023-06-23 陶氏环球技术有限责任公司 双核烯烃聚合活化剂
SG11202008656PA (en) * 2018-03-30 2020-10-29 Dow Global Technologies Llc Olefin polymerization activators
KR20200138272A (ko) 2018-03-30 2020-12-09 다우 글로벌 테크놀로지스 엘엘씨 올레핀 중합 활성화제
US11787880B2 (en) 2018-03-30 2023-10-17 Dow Global Technologies Llc Highly soluble alkyl substituted carbenium borate as co-catalysts for olefin polymerizations

Family Cites Families (19)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5153157A (en) * 1987-01-30 1992-10-06 Exxon Chemical Patents Inc. Catalyst system of enhanced productivity
PL276385A1 (en) * 1987-01-30 1989-07-24 Exxon Chemical Patents Inc Method for polymerization of olefines,diolefins and acetylene unsaturated compounds
US5241025A (en) * 1987-01-30 1993-08-31 Exxon Chemical Patents Inc. Catalyst system of enhanced productivity
US5045517A (en) * 1987-06-17 1991-09-03 The Dow Chemical Company Catalyst and process for preparation of syndiotactic polystyrene
US5026798A (en) * 1989-09-13 1991-06-25 Exxon Chemical Patents Inc. Process for producing crystalline poly-α-olefins with a monocyclopentadienyl transition metal catalyst system
US5064802A (en) * 1989-09-14 1991-11-12 The Dow Chemical Company Metal complex compounds
US5066741A (en) * 1990-03-22 1991-11-19 The Dow Chemical Company Process for preparation of syndiotactic vinyl aromatic polymers
JP2545006B2 (ja) * 1990-07-03 1996-10-16 ザ ダウ ケミカル カンパニー 付加重合触媒
US5252677A (en) * 1990-11-20 1993-10-12 Mitsubishi Petrochemical Company Limited Functionalized olefin polymers
US5206197A (en) * 1991-03-04 1993-04-27 The Dow Chemical Company Catalyst composition for preparation of syndiotactic vinyl aromatic polymers
US5721185A (en) * 1991-06-24 1998-02-24 The Dow Chemical Company Homogeneous olefin polymerization catalyst by abstraction with lewis acids
US5886117A (en) * 1991-08-05 1999-03-23 The Dow Chemical Company Process using borane derived catalysts for preparation of syndiotactic vinyl aromatic polymers
US5374696A (en) * 1992-03-26 1994-12-20 The Dow Chemical Company Addition polymerization process using stabilized reduced metal catalysts
US5296433A (en) * 1992-04-14 1994-03-22 Minnesota Mining And Manufacturing Company Tris(pentafluorophenyl)borane complexes and catalysts derived therefrom
US5350723A (en) * 1992-05-15 1994-09-27 The Dow Chemical Company Process for preparation of monocyclopentadienyl metal complex compounds and method of use
WO1994000500A1 (en) * 1992-06-26 1994-01-06 Exxon Chemical Patents Inc. Solution phase polymerization process utilizing metallocene catalyst with production of olefin polymers
EP0598543B1 (en) * 1992-11-10 1997-01-15 Mitsubishi Chemical Corporation Method for producing Alpha-olefin polymers
DE69416801T2 (de) * 1993-12-27 1999-07-08 Idemitsu Kosan Co Verfahren zur Herstellung eines Stryrolpolymer
EP0675139B1 (en) * 1994-03-31 1998-10-14 Idemitsu Kosan Co., Ltd. Process for producing styrenic polymer

Also Published As

Publication number Publication date
BR9509493A (pt) 1997-10-14
CA2200956A1 (en) 1996-04-11
KR100357358B1 (ko) 2003-01-24
DE69507626T2 (de) 1999-09-30
CN1159813A (zh) 1997-09-17
WO1996010592A1 (en) 1996-04-11
US5536797A (en) 1996-07-16
MX9702453A (es) 1997-06-28
JPH10506932A (ja) 1998-07-07
DE69507626D1 (de) 1999-03-11
CN1082057C (zh) 2002-04-03
EP0784639B1 (en) 1999-01-27
EP0784639A1 (en) 1997-07-23
KR970706319A (ko) 1997-11-03

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