TW201831654A - Chemiluminescent body and chemiluminescent system, breakable container for chemiluminescent body, and oxidation solution for chemiluminescent body - Google Patents

Abstract

The purpose of the present invention is to provide a chemiluminescent body such that reduction and such of the luminescent properties of fluorescent material due to precipitation is suppressed and such that luminescent properties including light emission brightness and light emission time are excellent. The present invention provides a chemiluminescent body (10) which mixes a first composition (1) and a second composition (2) to emit light, wherein the first composition (1) is a composition comprising oxalates, and the second composition (2) is a composition comprising a hydrogen peroxide, a solvent for an oxidation solution, a catalyst, and a fluorescent material. This chemiluminescent body (10) may be configured to comprise a breakable inner container (1) and a chemiluminescent body container (4) that contains the breakable inner container (3) therein, wherein the first composition (1) is contained in the breakable inner container (3), and the second composition (2) is contained between the breakable inner container (3) and the chemiluminescent body container(4).

Description

化學發光體及化學發光系統、以及化學發光體用破壞性容器、化學發光用氧化液Chemiluminescence body and chemiluminescence system, destructive container for chemiluminescence body, oxidation liquid for chemiluminescence

[0001] 本發明有關化學發光體及化學發光系統、以及化學發光體用破壞性容器、化學發光用氧化液。[0001] The present invention relates to a chemiluminescent body and a chemiluminescent system, a destructive container for a chemiluminescent body, and an oxidizing liquid for chemiluminescence.

[0002] 迄今，利用化學發光之製品已有眾多上市，一般係藉由將含有草酸酯類及螢光物質(螢光色素)之溶液(螢光液)、含有氧化劑(主要為過氧化氫)及觸媒成分(尤其水楊酸鹽)之溶液(氧化液)混合，而於任意時機引起化學發光，並供於目的而進行。 　　[0003] 而且，螢光液及氧化液係以調節內容物濃度，使兩液中之反應種均一混合並反應之方式，使用溶劑作成黏度比較低之溶液狀。例如，專利文獻1中揭示之螢光液中，作為溶劑係使用鄰苯二甲酸酯類、苯甲酸酯類等之芳香族系溶劑。 　　[0004] 另一方面，由於該等溶劑本身對於化學發光之發光本身之助益認為有限制，故專利文獻2中揭示化學發光組成物，其係設為將草酸酯以固體狀態存在之組成物。 [先前技術文獻] [專利文獻] 　　[0005] 　　[專利文獻1] 日本特開2002-138278號公報 　　[專利文獻2] 日本專利第4726237號公報[0002] So far, many products using chemiluminescence have been on the market. Generally, solutions (fluorescent liquids) containing oxalates and fluorescent substances (fluorescent pigments) and oxidants (mainly hydrogen peroxide) are used. It is mixed with a solution (oxidizing liquid) of a catalyst component (especially salicylate), and chemiluminescence is caused at any timing, and it is provided for the purpose. [0003] In addition, the fluorescent liquid and the oxidizing liquid are used to adjust the content concentration so that the reaction species in the two liquids are uniformly mixed and reacted, and the solvent is used to make a solution with a relatively low viscosity. For example, in the fluorescent liquid disclosed in Patent Document 1, aromatic solvents such as phthalates and benzoates are used as the solvent. [0004] On the other hand, since the solvents themselves are considered to have a limitation on the benefits of chemiluminescence, the chemiluminescence composition disclosed in Patent Document 2 is a composition in which the oxalate is present in a solid state. Thing. [Prior Art Document] [Patent Document] [0005] [Patent Document 1] Japanese Patent Laid-Open No. 2002-138278 [Patent Document 2] Japanese Patent No. 4726237

[發明欲解決之課題] 　　[0006] 化學發光體係藉由在觸媒存在下使草酸酯類與過氧化氫反應而發生之氧化物激發螢光物質(螢光色素)而發光。因此，未使用時，必須將草酸酯類與過氧化氫分開。因此，該分離設計時，一般設計為稱為「螢光液」與「氧化液」。亦即，「螢光液」係以使草酸酯類與螢光物質與溶劑一起混合者為基本組成物。該螢光液中之草酸酯類濃度於設計為一般螢光液時大約為5~30質量%左右。 　　[0007] 另一方面，「氧化液」係以過氧化氫與氧化液用之溶劑與觸媒混合者為基本組成物。此係因為過氧化氫本身反應性高，故與直接參與化學發光之其他成分分離認為越佳。 　　[0008] 基於此等設計而考慮各成分濃度之變更時，必然地，螢光液自其螢光液組成實現減低溶劑濃度。例如，如專利文獻2所揭示，藉由提高草酸酯(草酸酯類)之濃度，而可減低作為化學發光體全體之溶劑濃度，故可期待增加亮度、長時間持續發光時間之發光性能之高功能化。近幾年來，如實現發光之長時間化般之組成的發光體製品係僅以黃色等之一部分為主流。然而，大多數發光色基於以下理由而無法實現。亦即，降低溶劑濃度，提高螢光物質濃度時，螢光液(或螢光液組成物)中之螢光物質易析出。析出之固形螢光物質幾乎無助於發光，關於溶解度低之螢光物質，由於與氧化液溶劑接觸後亦容易變不溶，故無法滿足本來之初期發光性能。 　　[0009] 該狀況下，本發明之課題在於提供能實現此等化學發光之發光性能之高功能化，且安定之發光亮度、發光時間優異之化學發光體及化學發光系統、及該等所使用之破壞性容器或氧化液等。 [用以解決課題之手段] 　　[0010] 本發明人等為解決上述課題而重複積極研究之結果，發現下述發明與上述目的一致，因而完成本發明。 　　[0011] 亦即，本發明有關以下之發明。 　　＜1＞一種化學發光體，其係藉由將第一組成物與第二組成物混合而發光之化學發光體，前述第一組成物係含有草酸酯類之組成物，前述第二組成物係含有過氧化氫、氧化液用溶劑及螢光物質之組成物。 　　＜2＞如前述＜1＞之化學發光體，其具有破壞性內側容器與內包前述破壞性內側容器之化學發光體用容器，前述第一組成物或前述第二組成物之任一者內含於破壞性內側容器中，另一組成物內含於前述破壞性內側容器與前述化學發光體用容器之間。 　　＜3＞如前述＜2＞之化學發光體，其中內含於前述破壞性內側容器之組成物為第一組成物。 　　＜4＞如前述＜1＞~＜3＞中任一項之化學發光體，其中前述第一組成物中之草酸酯類濃度為50質量%以上。 　　＜5＞如前述＜1＞~＜4＞中任一項之化學發光體，其中前述第二組成物中含有之螢光物質係苝系螢光物質及/或萘醯亞胺系螢光物質。 　　＜6＞如前述＜1＞~＜5＞中任一項之化學發光體，其中前述第一組成物為固體狀。 　　＜7＞一種破壞性容器，其係封入有第一組成物之化學發光體用破壞性容器，且其係用於藉由使封入於破壞性容器中之第一組成物與內包前述破壞性容器之化學發光體用容器內之與前述第一組成物分離封入之第二組成物混合而發光之化學發光體， 　　前述第一組成物係含有50質量%以上草酸酯類之組成物。 　　＜8＞一種氧化液，其係藉由與含有草酸酯類之組成物混合而產生化學發光之氧化液，且係含有過氧化氫水、氧化液用溶劑及螢光物質之組成物。 　　＜9＞一種化學發光系統，其係藉由使第一組成物與第二組成物混合而發光之化學發光系統，前述第一組成物係含有草酸酯類之組成物，前述第二組成物係含有過氧化氫、氧化液用溶劑及螢光物質之組成物。 [發明效果] 　　[0012] 依據本發明，提供安定且發光亮度、發光時間優異之化學發光體及化學發光系統、以及其所使用之組成物及安瓿瓶。[Problems to be Solved by the Invention] 0006 [0006] A chemiluminescence system emits light by exciting a fluorescent substance (fluorescent pigment) by an oxide generated by a reaction between oxalates and hydrogen peroxide in the presence of a catalyst. Therefore, when not in use, oxalates must be separated from hydrogen peroxide. Therefore, this separation design is generally called "fluorescent liquid" and "oxidizing liquid". That is, the "fluorescent liquid" is a basic composition in which an oxalate is mixed with a fluorescent substance and a solvent. The oxalate concentration in this fluorescent liquid is about 5-30% by mass when designed as a general fluorescent liquid. [0007] On the other hand, the "oxidizing solution" is based on a mixture of hydrogen peroxide and a solvent for a oxidizing solution and a catalyst. This is because hydrogen peroxide itself is highly reactive, so it is considered to be better to be separated from other components directly involved in chemiluminescence. [0008] When considering the changes in the concentration of each component based on these designs, it is inevitable that the fluorescent liquid can reduce the solvent concentration from its fluorescent liquid composition. For example, as disclosed in Patent Document 2, by increasing the concentration of oxalate (oxalate), the concentration of the solvent as a whole chemiluminescence can be reduced. Therefore, it is expected that the luminous performance can be increased by increasing the brightness and continuing the light emission time for a long time. Highly functional. In recent years, the luminous body products with a composition such as the long-term emission of light are mainly mainstreamed in yellow. However, most luminescent colors cannot be achieved for the following reasons. That is, when the concentration of the solvent is decreased and the concentration of the fluorescent substance is increased, the fluorescent substance in the fluorescent liquid (or the fluorescent liquid composition) is liable to precipitate. The precipitated solid fluorescent substance hardly contributes to light emission. As for the fluorescent substance with low solubility, it is easy to become insoluble after contact with the oxidizing liquid solvent, so it cannot satisfy the original initial luminous performance. [0009] Under these circumstances, the object of the present invention is to provide a chemiluminescence system and a chemiluminescence system capable of realizing high luminescence performance of such chemiluminescence, and having stable luminescence brightness and luminescence time, and use thereof. Destructive container or oxidizing liquid. [Means for Solving the Problems] [0010] As a result of repeated active researches by the present inventors to solve the above-mentioned problems, it was found that the following inventions are consistent with the above-mentioned objects, and thus completed the present invention. [0011] That is, the present invention relates to the following inventions. <1> A chemiluminescent substance that emits light by mixing a first composition with a second composition, wherein the first composition contains a composition of oxalates, and the second composition contains A composition containing hydrogen peroxide, a solvent for an oxidizing solution, and a fluorescent substance. <2> The chemiluminescence body according to the above <1>, which has a destructive inner container and a container for a chemiluminescent body that contains the destructive inner container, in either the first composition or the second composition The composition is contained in a destructive inner container, and another composition is contained between the destructive inner container and the chemiluminescent container. <3> The chemiluminescence body according to the aforementioned <2>, wherein the composition contained in the aforementioned destructive inner container is the first composition. <4> The chemiluminescence body according to any one of <1> to <3>, wherein the oxalate concentration in the first composition is 50% by mass or more. <5> The chemiluminescent substance according to any one of <1> to <4>, wherein the fluorescent substance contained in the second composition is a fluorene-based fluorescent substance and / or a naphthaleneimine-based fluorescent substance. . <6> The chemiluminescence body according to any one of <1> to <5>, wherein the first composition is solid. <7> A destructive container which is a destructive container for a chemiluminescence body in which a first composition is enclosed, and which is used for encapsulating the first composition enclosed in a destructive container with the aforementioned destructive property The chemiluminescence body of the container is a chemiluminescence body which is mixed with the second composition separated and sealed in the first composition to emit light. The first composition is a composition containing 50% by mass or more of oxalate. <8> An oxidizing liquid, which is an oxidizing liquid that generates chemiluminescence by mixing with a composition containing oxalates, and is a composition containing hydrogen peroxide water, a solvent for an oxidizing liquid, and a fluorescent substance. <9> A chemiluminescence system, which is a chemiluminescence system that emits light by mixing a first composition with a second composition, the first composition contains a composition of oxalates, and the second composition A composition containing hydrogen peroxide, a solvent for an oxidizing solution, and a fluorescent substance. [Effects of the Invention] [0012] According to the present invention, a chemiluminescence system and a chemiluminescence system which are stable and have excellent light emission brightness and light emission time, and a composition and an ampoule used therefor are provided.

[0014] 以下詳細說明本發明之實施形態，但以下記載之構成要件的說明係本發明實施態樣之一例(代表例)，本發明只要不變更其要旨，則不限定於以下內容。又，本說明書中使用「~」表現時，係作為包含其前後數值之表現使用。 　　[0015] 本發明有關化學發光體，其係藉由將第一組成物與第二組成物混合而發光之化學發光體，前述第一組成物係含有草酸酯類之組成物，前述第二組成物係含有過氧化氫、氧化液用溶劑、觸媒及螢光物質之組成物。 　　藉由成為此等化學發光體，以於化學發光體內混合組成物而產生安定發光。更具體而言，彎折化學發光體，進行敲打等而破壞化學發光體用容器內之破壞性內側容器，於化學發光體用容器內混合化學發光體用組成物時，第一組成物中之草酸酯濃度高，可防止螢光物質之析出，故發光亮度高，可使發光時間長時間化。 　　[0016] 又，本發明有關化學發光系統，其係藉由使第一組成物與第二組成物混合而發光之化學發光系統，前述第一組成物係含有草酸酯類之組成物，前述第二組成物係含有過氧化氫、氧化液用溶劑、觸媒及螢光物質之組成物。 　　作為此等化學發光系統，欲產生化學發光時，使第一組成物及第二組成物反應。此時，第一組成物中之草酸酯類濃度高，藉由於第二組成物中含有螢光物質，可防止於第一組成物中析出，故產生安定發光。 　　[0017] 本發明人等對變更螢光液(螢光組成物)之組成，於液中殘留螢光物質之固體，或將螢光組成物作成粉末狀，作為化學發光體予以混合時，產生不易混合之塊(所謂麵團狀)之原因進行檢討。其結果，發現螢光組成物中所含之螢光物質析出的影響較大。因此，檢討將該螢光物質混合於一般認為不安定而避免的氧化液側的組成物中。 　　[0018] 圖1係顯示本發明有關之代表化學發光體之構造的圖。本發明可設為圖1(a)所示之化學發光體10的實施形態。該實施形態係有關具有封入於破壞性內側容器3之第一組成物1與於內包破壞性內側容器3的化學發光體用容器4內而與第一組成物1分離封入之第二組成物2之化學發光體10。該化學發光體10於使用時，藉由於化學發光體用容器4內使破壞性內側容器3破壞，使第一組成物1與第二組成物2混合，進行化學發光。 　　[0019] 基於該圖1(a)所示之化學發光體10之態樣，作為第一組成物1，以粉末狀單獨封入草酸酯(CIPO)，作為第二組成物2，使用氧化液用溶劑(DMP及t-BuOH之混合溶劑)、過氧化氫、觸媒(SS)及螢光物質(Lumogen(註冊商標) F Red)之混合物而製造。彎折該化學發光體，使破壞性內側容器3破壞，藉由輕振，未見到螢光物質析出，且迅速混合產生安定發光。 　　[0020] 且，本發明可設為圖1(b)所示之化學發光體11之實施形態。該實施形態係有關具有封入於破壞性內側容器3之第二組成物2與於內包破壞性內側容器3的化學發光體用容器4內而與第二組成物2分離封入之第一組成物1之化學發光體11。該化學發光體11係將化學發光體10中之第一組成物與第二組成物變更內容之形態者。該化學發光體11與化學發光體10同樣，於使用時，藉由於化學發光體用容器4內使破壞性內側容器3破壞，使第一組成物1與第二組成物2混合，進行化學發光。 　　[0021] 又，本發明可設為圖2所示之化學發光系統之實施形態。該實施形態中，首先準備於圖2(a)不織布5中含浸第一組成物6者。此時，第一組成物可為實質上僅由草酸酯類所成之構成，或實質上僅由草酸酯類與溶劑等之構成，故成為無色且不易視認第一組成物如何配置之狀態(圖2(a)中以虛線表示之部分)。 　　此處，如圖2(b)所示，第二組成物7自容器71接觸於不織布5上。如此，藉由接觸，使含浸於不織布5之第一組成物6與第二組成物7反應，產生化學發光部100。如此，本發明之化學發光系統於非接觸(混合)狀態，以隱藏無色之第一組成物之如文字形態配置，使用時產生化學發光，可成為化學發光系統。 　　[0022] [第一組成物] 　　本發明所用之第一組成物係含有草酸酯類之組成物。若為此組成物，由於含有草酸酯類，故與詳情如後述之第二組成物混合時，產生化學發光。 　　[0023] 本發明所用之第一組成物含有有助於其化學發光之作為主要成分的草酸酯類。此處使用之草酸酯類可適當地使用可使含有其之第一組成物與第二組成物混合時開始化學發光者。作為具體之草酸酯類舉例為例如雙(2,4,5-三氯-6-碳丁氧基苯基)草酸酯、雙(2,4,5-三氯-6-碳戊氧基苯基)草酸酯等。 　　[0024] 本發明所用之第一組成物較好含有比通常螢光液更高濃度之草酸酯類。藉由作成此等構成，可進行化學發光時之發光特性改善。草酸酯類之濃度越高，基本上化學發光之發光特性更被改善。 　　[0025] 該第一組成物因以高濃度含有草酸酯類，而第一組成物成為固體狀或膏狀、漿料狀之組成物。又，以往之技術思想係於草酸酯類濃度低時，為含有大量其他溶劑之設計，作成螢光物質之析出不易發生之以往的螢光液組成者，係不考慮過氧化氫對螢光物質之影響而易於設計。 　　[0026] 由於草酸酯類濃度越高，越易改善發光特性，故第一組成物中之草酸酯類濃度較好為50質量%以上，更好為80質量%以上，又更好為90質量%以上。草酸酯類濃度為80質量%以上時，實質上其性狀可作為相當於草酸酯單獨者予以處理之方面亦優異。又，本發明中第一組成物可實質上為草酸酯類單獨，亦可作為包含草酸酯類單獨之情況之概念，表現為第一組成物。 　　[0027] 本發明所用之前述第一組成物較好為固體狀。本發明所用之第一組成物除草酸酯類以外，亦可採用作為後述之任意成分而添加者且常溫亦為固體狀者，將第一組成物全體作成如粉狀體或粒體之固體狀混合物。尤其，藉由設為粉狀體或粒體，於化學發光時，認為液狀之第二組成物容易侵入該粉狀體或粒體之間隙，而可提高混合性，使發光特性良好。 　　[0028] 且，該第一組成物一般大多封入於化學發光體內側之破壞性內側容器內。該破壞性內側容器由於根據化學發光體大小而成為極細徑，故第一組成物較好為易於封入其內般之流動性較高的粉狀體或粒體。 　　[0029] 本發明之第一組成物實質上亦可為草酸酯類單獨，但亦可混合其他成分。例如，於第二組成物側含有之較佳觸媒亦可含於第一組成物側。藉由於第一組成物側亦含有觸媒，而更安定地產生化學發光反應。且，亦可含有與第二組成物之混合性或析出的影響較少的螢光物質。例如蒽系螢光物質由於溶解性高不易產生析出，故亦可使用於第一組成物側。作為此等螢光物質，更具體而言，舉例有已某程度實用化之黃色螢光物質之1-氯-9,10-雙(苯基乙炔基)蒽(2-Et-BPEA)。且除此之外，亦可適當含有抗氧化劑或安定化劑、溶劑等。 　　[0030] 本發明所用之第一組成物可設為以如前述之草酸酯類為主之固體狀設計。另一方面，以漿料狀等設計時，亦可含有溶劑，作為溶劑一般係單獨或混合使用乙醯基檸檬酸三丁酯(ATBC)、苯甲酸苄酯(BeB)、二丙二醇二甲醚(DMM)等。 　　[0031] 另一方面，本發明所用之第一組成物較好減少於第一組成物之溶液中溶解性低的成分。作為此等成分之典型者，舉例為螢光物質，其中苝系螢光物質或萘醯亞胺系螢光物質等含於溶劑少流動性低之第一組成物中時不易產生析出，易使化學發光特性降低。因此，第一組成物中之苝系螢光物質及萘醯亞胺系螢光物質之含量較好為0.5質量%以下，更好為0.2質量%以下，又更好為0.1質量%以下。該等含量，特佳為不使用作為組成物之原料，而不含(0質量%)。 　　[0032] 以本發明之化學發光體所用之第一組成物為內容之破壞性內側容器係於化學發光體之化學發光用容器內，僅其破壞性內側容器優先破壞，於化學發光體用容器內，使經內含之第一組成物分散之容器。舉例為例如，玻璃或樹脂製之安瓿瓶狀者，或鋁製或PP製之袋狀者等之構成。 　　[0033] 本發明係化學發光體用破壞性容器，其係封入有第一組成物之化學發光體用破壞性容器，且其係用於藉由使封入於破壞性容器中之第一組成物與內包前述破壞性容器之化學發光體用容器內之與前述第一組成物分離封入之第二組成物混合而發光之化學發光體，前述第一組成物係含有50質量%以上草酸酯類之組成物。 　　[0034] 該化學發光體用破壞性容器可成為相當於含有前述第一組成物之破壞性內側容器之構成。該化學發光體用破壞性容器係用以藉由與第二組成物反應而以作為化學發光體之優異混合性混合之發揮優異發光特性。且，該化學發光體用破壞性容器由於係內包於作為化學發光體全體之化學發光體用容器，故大多為比較小且其徑亦為小徑之細長筒狀安瓿瓶。 　　[0035] 此等安瓿瓶中，亦有因封入其中之組成物之流動性而難以封入之情況，有難以對每次改變組成物之組成而進行之封入條件調整之情況。然而，本發明之安瓿瓶設計時，成為其內容物之第一組成物不含有支配性決定化學發光顏色之螢光物質，亦可做成可作為化學發光體而廣泛共通使用之標準化安瓿瓶。該安瓿瓶中，亦可含有對發光特性之顏色調整時之影響較少，且即使實質上為粉體或漿料狀，與氧化液之混合性亦不易降低之黃色螢光物質(例如1-氯-9,10-雙(苯基乙炔基)蒽(2-Et-BPEA))。 　　[0036] [第二組成物] 　　本發明所用之第二組成物係含有過氧化氫、氧化液用溶劑及螢光物質之組成物。作為此等第二組成物，可調製液狀組成物而使用，作為化學發光體使用時以與前述第一組成物之優異混合性混合產生安定之化學發光。其原因係藉由於第二組成物側含有螢光物質，而不易發生起因於固體或漿料狀等之第一組成物與氧化液之混合性或溶解性問題的問題。 　　[0037] 本發明所用之第二組成物含有過氧化氫。第二組成物係以氧化劑的過氧化氫為必須成分，且為了調整該過氧化氫濃度、提高與第一組成物之相溶性(混合性)，進而提高為了提高發光效率而添加之水楊酸鹽等之溶解度而含有溶劑。作為第二組成物中之過氧化氫濃度標準，為1~10質量%左右。 　　[0038] 本發明所用之第二組成物含有氧化液用溶劑。作為本發明之氧化液所含之溶劑之具體例較好包含使用檸檬酸酯類、苯二甲酸酯類、苯甲酸酯類、苯偏三酸酯類、己二酸酯類、癸二酸酯類、杜鵑花酸酯類、甘油酯類、內酯類、二醇類、烷基二醇醚類等之有機系溶劑的溶劑。該等溶劑中，基於安全性之觀點，較好使用引火點為60℃以上者作為主要溶劑，且作為全體之引火點為70℃以上。又，溶劑之選擇中，所謂主要溶劑係指以可達成引火點成為本發明之目的溫度之方式調整摻合量時，基於引火點高則摻合比例較多而設計時成為中心之溶劑。且，溶劑亦可為主要溶劑單獨的溶劑。第二組成物中之氧化液用溶劑之量成為第二組成物含有之過氧化氫或觸媒、螢光物質等之其他成分的其餘部分。 　　[0039] 本發明所用之第一組成物及第二組成物之至少一者中，較好含有觸媒。該觸媒較好含於使用溶劑之第二組成物中。另一方面，觸媒亦可僅含於第一組成物中。又，於兩組成物中含有時，如一部分前述而有助於更快速發光或安定發光。通常，期望含有少量(通常對於氧化液為0.1mmol/L至10mmol/L)之例如水楊酸鋰、水楊酸銨、水楊酸鈉、水楊酸四烷銨鹽等之水楊酸及其衍生物作為作為觸媒成分。 　　[0040] 本發明所用之第二組成物含有螢光物質。藉由使該螢光物質含於使用溶劑之第二組成物側，而不會發生提高第一組成物中之草酸酯濃度且如以往含有螢光物質時所發生之混合性問題。因此，第一組成物與第二組成物快速混合，可於化學發光體內安定獲得草酸酯、過氧化氫、觸媒、螢光物質之化學發光所必須之成分成為適當存在狀態的反應場所。藉此，獲得初期發光強度或發光時間提高之效果。第二組成物中之螢光物質濃度標準為0.01~5質量%左右，係根據顏色、強度、時間等之發光性能或混合性等而設定。其濃度基於溶解性(防止析出等)之觀點，使用複數螢光物質時，作為以其合計量之濃度標準，較好為上述範圍。前述螢光物質之濃度下限，為了提高發光時之發色性更好設為0.05質量%以上。前述螢光物質之濃度上限，即使過量混合螢光物質亦有發色性等飽和之情況，相對地提高有助於化學發光之成分濃度，且易發生螢光物質析出等，故更好為2質量%以下。 　　[0041] 作為螢光物質若於300~1200nm具有發光光譜且於氧化液溶劑中亦至少部分可溶之螢光化合物則未特別限制。作為該等螢光化合物，例示有蒽、取代蒽、苯并蒽、菲、取代菲、并四苯、取代并四苯、并五苯、取代并五苯、苝、取代苝、蒽酮紫(violanthrone)、取代蒽酮紫、萘醯亞胺、取代萘醯亞胺等之具有縮合環之共軛多環芳香族化合物。作為上述化合物之取代基，只要不妨礙發光反應則未特別限制，可例示苯基、低級烷基、氯基、溴基、氰基、烷氧基、苯基萘基等。該等中，於以草酸酯類為主成分之第一組成物中含有苝、取代苝等之苝系螢光物質、或萘醯亞胺、取代萘醯亞胺等之萘醯亞胺系螢光物質時，容易產生析出，亦成為發光特性不安定之原因。因此，本發明中，第二組成物中含有之螢光物質較好為苝系螢光物質及/或萘醯亞胺系螢光物質。該等苝系螢光物質及萘醯亞胺系螢光物質的螢光物質基於在第二組成物中長時間安定之觀點亦較佳。 　　[0042] 作為前述螢光物質之具體例者，例示有2-氯-9,10-雙(4-甲基乙炔基)蒽、9,10-雙(苯基乙炔基)蒽、1-甲氧基-9,10-雙(苯基乙炔基)蒽、1,5-二氯-9,10-雙(苯基乙炔基)蒽、1,8-二氯-9,10-雙(苯基乙炔基)蒽、單氯及二氯取代之9,10-雙(苯基乙炔基)蒽、5,12-雙(苯基乙炔基)四并苯、9,10-二苯基蒽、16,17-二己氧基蒽酮紫、2-甲基-9,10-雙(苯基乙炔基)蒽、9,10-雙(4-甲氧基苯基)-2-氯蒽、9,10-雙(4-乙氧基苯基)-2-氯蒽、5,12-雙(苯基乙炔基)五并苯、5,6,11,12-四苯基并五苯(紅螢烯(rubrene))、苝及該等之混合物。 　　[0043] 本發明之第二組成物中含有之螢光物質較好為苝系螢光物質。所謂苝系螢光物質為具有苝或取代苝之骨架之螢光物質。所謂苝係下述式(1)表示之構造，苝系螢光物質具有該構造作為骨架。此等苝系螢光物質尤其含於所謂氧化液之第二組成物中時，亦長時間安定且長期保存性亦優異。 　　[0044][0045] 該等苝系螢光物質中，特佳為苝二羧醯亞胺系螢光物質。作為該苝二羧醯亞胺系螢光物質之具體製品舉例有例如LUMOGEN RED(發出紅色之苝二羧醯亞胺系螢光劑，BASF公司，商品名)、LUMOGEN YELLOW(發出黃色之苝二羧醯亞胺系螢光劑，BASF公司，商品名)、LUMOGEN ORANGE(發出橙色之苝二羧醯亞胺系螢光劑，BASF公司，商品名)。 　　[0046] 本發明之第二組成物中含有之螢光物質較好為萘醯亞胺系螢光物質。作為萘醯亞胺系螢光物質使用之化合物係具有萘醯亞胺骨架之化合物，係使用可作為化學發光中之螢光物質使用者。萘醯亞胺骨架亦可具有取代基。萘醯亞胺骨架以下述式(2)表示。 　　[0047][0048] 上述式中之氮原子可與例如氫原子；可具有如氧原子、氮原子、硫原子之雜原子之烴基鍵結者。烴基與上述同義。作為具有萘醯亞胺骨架之化合物之市售品舉例為例如LUMOGEN F Violet 570(BASF公司製)。 　　[0049] 本發明所用之第二組成物中，在不損及本發明目的之範圍內亦可含有其他成分。例如為了使第二組成物中之過氧化氫等於保存時安定而可添加抗氧化劑。 　　[0050] 本發明可為含有過氧化氫、氧化液用溶劑、觸媒與螢光物質之組成物的氧化液，其係用於藉由使封入於破壞性內側容器中之第一組成物與內包前述破壞性內側容器之化學發光體用容器內之與前述第一組成物分離封入之第二組成物混合而發光之化學發光體的氧化液。該氧化液相當於前述本發明所用之第二組成物。 　　[0051] 該氧化液係被封入破壞性內側容器之外部等而利用。且藉由變更該氧化液之螢光物質，易改變作為化學發光體之顏色。且，如前述於破壞性內側容器所用之安瓿瓶為小徑而不易填充內容物，另一方面填充有該氧化液之化學發光體用容器以更廣徑設計，故易進行液的填充。再者，與該氧化液組合使用時，安瓿瓶側之設計亦可設為標準化且作為既定者而製造，僅藉由變更氧化液之螢光物質顏色即可效率良好地製造顯示任意發色之化學發光體。 　　[0052] 作為本發明所用之化學發光體用容器，可採用作為化學發光體使用之任意形狀。且，根據該化學發光體之用途，適當調整顏色、大小、發光強度・時間等與內包之破壞性內側容器等之組合。例如可作為釣具用之小型化學發光體或發光棒狀之演唱會光棒、或警示燈、緊急燈。又，亦可作為採用遮罩狀之容器而發光之會場用發光體，亦可作為星形或心型等之玩具形狀。 　　[0053] 本發明之化學發光系統係使第一組成物或第二組成物於任意場所接觸並反應者。因此，可設成第一組成物與第二組成物之化學發光用套組。又，本發明亦可為化學發光方法，其係藉由使第一組成物與第二組成物混合而發光之化學發光方法，前述第一組成物係含有草酸酯類之組成物，前述第二組成物係含有過氧化氫、氧化液用溶劑及螢光物質之組成物。 　　[0054] 如前述實施形態所示，例如亦可預先配置(含浸)一組成物後，另外接觸另一組成物，而發生其形狀或含浸狀態的文字、圖形等之發光。此由於本發明之化學發光系統有關之第一組成物中顯示著色之螢光物質含量極微量且可為實質上不含之構成，故將預先配置之組成物設為第一組成物時，第二組成物接觸前可為無色。且，由於使用時其為無色且配置有第一組成物之場所發光，故可如隱藏文字般加以利用。 　　[0055] 或，作為本發明之化學發光系統之一例，為典禮等之演出用，可預先於任意容器中容納一組成物，使用時自開口部等添加另一組成物而發光。此時，亦可以如相當於隱藏文字般之構成而發光，可以不同顏色設定各組成物而將該等混合，作為新的顏色予以發光者。 　　[0056] 又，此等化學發光系統中，亦可預先減低第一組成物之草酸酯類之濃度。具體而言，草酸酯類之濃度可設為3質量%以上。且，作為隱藏文字用，由於第一組成物中之螢光物質越無著色越佳，故而減低其含量，而較好設為0.1質量%以下，更好為0.05質量%以下。此時，螢光物質之含量下限係不使用作為原料而為0質量%。 　　[0057] 或者，考慮保存時分離之各組成物狀態，鑒於第二組成物的氧化液中之安定性，可於第二組成物中含有苝系螢光物質及/或萘醯亞胺系螢光物質，於第一組成物中預先含有其他先前例示之螢光物質。藉由該設計，對應於螢光物質種類，對第一組成物與第二組成物分別施以著色，於使用時亦可演出發出該等混合而成之顏色。 [實施例] 　　[0058] 以下，藉由實施例更詳細說明本發明，但本發明只要不變更其要旨，則不限定於以下實施例。 　　[0059] [評價項目] [亮度] 　　使用“亮度計LS-100(Close Up Lens No.122)”(Konica Minolta)測定亮度。 　　[HPLC] 　　使用下述裝置進行HPLC試驗。 　　・HPLC吸光檢測器：“SPD-10A vp”(島津製作所) 　　・HPLC送液單元：“LC-10AT” (島津製作所) 　　・管柱烘箱：“CTO-10A” (島津製作所) 　　・數據處理裝置：“Chromato Pack C-R6A” (島津製作所) 　　[0060] [試驗用試藥等] 　　DMP：鄰苯二甲酸二甲酯 　　t-BuOH：第三丁醇(tert-Butanol)(東京化成工業股份有限公司) 　　ATBC：乙醯基檸檬酸三丁酯(東京化成工業股份有限公司) 　　BeB：苯甲酸苄酯(東京化成工業股份有限公司) 　　H₂ O₂ ：過氧化氫(過氧化氫水(和光純藥工業)經脫水處理後使用) 　　SS：水楊酸鈉(關東化學股份有限公司) 　　CIPO：雙(2,4,5-三氯-6-異戊氧基羰基苯基)草酸酯(東京化成工業股份有限公司) 　　CPPO：雙[2,4,5-三氯-6-(戊氧基羰基)苯基]草酸酯(東京化成工業股份有限公司) 　　[0061] [實施例1] 　　[0062] 為了明確出於成為第二組成物之氧化液中加入色素(螢光物質)之情況，與於成為第一組成物之粉末中加入色素(螢光物質)之情況的發光差異，而進行發光特性比較。 　　[0063] 螢光物質(a)：使用以下述式(3)表示之苝系螢光物質。又，後述之試驗方法中，各試驗中有助於發光亮度之成分的量係總量為相同，故各氧化液中與粉末中之螢光物質量調製為同量。 　　[0064][0065] [試驗方法1. 第一組成物(粉末)側含有螢光物質之實驗(粉末中)] 　　(1)調製氧化液(組成概要：DMP 81.6質量%，t-BuOH 13.4質量%，H₂ O₂ 5質量%，SS 0.04質量%)。 　　(2)量取CIPO 9.85g與螢光物質(a) 0.15g，使用研缽混合。 　　(3)於4mL之樣本管瓶內量入(1)之混合粉末0.14g。 　　(4)將(1)之氧化液0.43mL加入(3)之樣本管瓶中予以發光。 　　(5)以均質機(25M手攪拌機+215A型微均質機)攪拌10秒(於容器底面攪拌使粉末於氧化液中擴散)。 　　(6)以攪拌結束時為基準的0點(初始)，於每下述特定測定時間，自採樣瓶容器上部測定發光亮度。 　　測定時間：30秒、1分鐘、5分鐘、15分鐘 　　[0066] [試驗方法2. 第二組成物(氧化液)側含有螢光物質之實驗(氧化液中)] 　　(1)調製氧化液(組成概要：DMP 81.6質量%，t-BuOH 13.4質量%，H₂ O₂ 5質量%，SS 0.04質量%)。 　　(2)量取(1)之氧化液100g，於其中添加螢光物質0.5g (0.5質量%)，於常溫攪拌溶解。 　　(3)於4ml樣本管瓶中量取CIPO粉末0.14g。 　　(4)於(3)之樣本管瓶中添加(2)之已加入螢光物質之氧化液0.43ml使其發光。 　　(5)以均質機攪拌10秒(於容器底面攪拌使粉末於氧化液中擴散)。 　　(6)以攪拌結束時為基準的0點(初始)，於每下述特定測定時間，自採樣瓶容器上部測定發光亮度。 　　測定時間：30秒、1分鐘、5分鐘、15分鐘 　　[0067] 「實驗結果」亮度測定 　　圖3及表1中，分別顯示於粉末中與氧化液中分別含有螢光物質(a)時之發光亮度曲線、每時間之發光亮度。又，於各條件各進行2次試驗。 　　[0068][0069] 於粉末中(第一組成物)中含有螢光物質時，與於氧化液中(第二組成物)中含有螢光物質時，直至1分鐘後之初期發光產生差異，開始發光初期之亮度有差異。於粉末側添加螢光物質時，由於螢光物質之溶解性低而析出，故即使混合，於粉末與氧化液混合而成之液中亦立即不溶解分散，認為使初期發光變差。 　　[0070] [實施例2] 　　針對氧化液組成物中之螢光物質安定性進行試驗。 　　[0071] [螢光物質] 　　[0072] [苝系螢光物質] 　　・“Lumogen F Red 305”：1,6,7,12-四苯氧基-N,N’-雙(2,6-二異丙基苯基)苝二碳醯亞胺 　　・“Lumogen F Yellow 083”：4,10-二氰基-3,9-苝二羧酸二異丁酯 　　・“Lumogen F Orange 240”：2,9-雙(2,6-二異丙基苯基)-1,2,3,8,9,10-六氫蒽并[2,1,9-def:6,5,10-d’e’f’]二異喹啉-1,3,8,10-四酮 　　[0073] [萘醯亞胺系螢光物質] 　　・“Lumogen F Violet 570” 　　[0074] [蒽系螢光物質] [黃色色素] 　　・“1-ClBPEA”：1-氯-9,10-雙(苯基乙炔基)蒽 　　・“1,8-dClBPEA”：1,8-二氯-9,10-雙(苯基乙炔基)蒽 [綠色色素] 　　・“2-EtBPEA”：2-乙基-9,10-雙(苯基乙炔基)蒽 [藍色色素] 　　・“2-ClBMPA”：2-氯-9,10-雙(4-甲氧基苯基)蒽 　　・“DPA”：9,10-二苯基蒽 　　[0075] [并四苯系螢光物質] [橙色色素] 　　・“BPEN”：5,12-雙(苯基乙炔基)并四苯 　　・“紅螢烯”：5,6,11,12-四苯基并四苯 　　[0076] [實驗操作] 1. 試驗試料之準備 　　(1)調製氧化液(組成概要：DMP 81.6質量%，t-BuOH 13.4質量%，H₂ O₂ 5質量%，SS 0.04質量%)。 　　(2)量取前述(1)之氧化液100g，於其中添加螢光物質0.15g(0.15質量%)，於常溫攪拌溶解。 　　(3)將前述(2)之氧化液小分地分裝於旋蓋管中，於恆溫庫60℃中進行加速處理試驗。 　　(4)於恆溫庫60℃中進行加速處理試驗者，於1週後取出。 　　(5)針對加速處理試驗前與加速處理試驗後之試料，關於殘留螢光物質(色素)析出者，使用超音波洗淨機完全溶解後進行測定。 　　[0077] 2. HPLC測定 　　(1)藉以下條件，藉由HPLC測定之試驗評價於前述試驗試料之準備步驟中準備之氧化液中之螢光物質安定性。 　　測定條件： 　　稀釋操作：於試料10μL中添加4mL乙腈 　　檢測波長：254nm 　　移動相：乙腈100%，管柱烘箱：40℃ 　　流速：0.7mL/min，注入量：5μL，檢測時間：20分鐘 　　[0078] 3. 亮度測定 　　(1)於含草酸酯之組成物的空白液(溶質：CPPO，溶劑：ATBC、BeB) 2.0mL加入採樣瓶容器中。 　　(2)量取1.0mL之含各螢光物質之氧化液，添加於前述(1)，開始發光。 　　(3)以均質機攪拌10秒。 　　(4)攪拌結束時設為0秒，測定發光亮度。 　　[0079] [實驗結果] [實驗結果1. HPLC測定] 　　藉由前述實驗操作，進行HPLC試驗時之各螢光物質波峰之數據測定結果示於表2。表2(螢光物質波峰之數據(面積比))中，進行加速處理試驗之前者表示為「加速前」，進行加速處理試驗1週後者表示為「加速1週後」，進行加速處理試驗2週後者表示為「加速2週後」。又，「1週後之殘存量」、「2週後之殘存量」均係將加速前作為100%進行比較者。 　　[0080][0081] 作為HPLC試驗結果，於苝系、萘醯亞胺系螢光物質於加速處理試驗前後未見到太大劣化。於其他螢光物質，於BPEN、紅螢烯大幅劣化(HPLC試驗結果，由於未確認到明顯波峰，故於表中記載為「無」)，其他螢光物質之波峰值亦降低。 　　[0082] [實驗結果2. 發光亮度之測定結果] 　　使用含有各螢光物質之氧化液的亮度測定結果示於下表。又，以下表中，加速處理試驗之前表示為「加速前」，進行加速處理試驗1週後表示為「加速1w」(亮度測定溫度22℃)，進行加速處理試驗2週後表示為「加速2w」(亮度測定溫度23℃)。又，「加速1w後之亮度」係將加速前設為100%者。表中之發光亮度之數值單位為「cd/m² 」。 　　[0083] Lumogen F Red之試驗結果示於表3(1週)、表4(2週)。 　　[0084][0085][0086] Lumogen F Yellow 083之試驗結果示於表5(1週)、表6(2週)。 　　[0087][0088][0089] Lumogen F Orange 240之試驗結果示於表7(1週)、表8(2週)。 　　[0090][0091][0092] Lumogen F Violet 570之試驗結果示於表9(1週)、表10(2週)。 　　[0093][0094][0095] 1-ClBPEA之試驗結果示於表11(1週)、表12(2週)。 　　[0096][0097][0098] 1,8-dClBPEA之試驗結果示於表13(1週)、表14(2週)。 　　[0099][0100][0101] 2-EtBPEA之試驗結果示於表15(1週)、表16(2週)。 　　[0102][0103][0104] 2-ClBMPA之試驗結果示於表17(1週)、表18(2週)。 　　[0105][0106][0107] DPA之試驗結果示於表19(1週)、表20(2週)。 　　[0108][0109][0110] BPEN之試驗結果示於表21(1週)、表22(2週)。 　　[0111][0112][0113] 紅螢烯之試驗結果示於表23(1週)、表24(2週)。 　　[0114][0115][0116] 亮度測定之實驗結果，任一化學發光體，於加速試驗前之初期發光的發光亮度，並無產生析出問題等，而發光。另一方面，加速試驗後見到其安定性較差。 　　苝系及萘醯亞胺系螢光物質，於加速試驗前後，其發光亮度並未見到太大劣化。使用其他螢光物質之氧化液，與使用苝系及萘醯亞胺系螢光物質者比較時，見到劣化且發光亮度降低。尤其於1,8-dClBPEA、BPEN、紅螢烯，於發光時顏色變淡至以目視即可了解變化之程度。 [產業上之可利用性] 　　[0117] 依據本發明，提供安定且發光亮度、發光時間優異之化學發光體及化學發光系統。例如該化學發光體可利用於如演唱會光棒等之會場用、釣具用之發光體、防災用簡易光、標誌燈、警示燈之各種用途而於產業上有用。[0014] The embodiments of the present invention will be described in detail below. However, the description of the constituent elements described below is an example (representative example) of the embodiment of the present invention, and the present invention is not limited to the following as long as the gist is not changed. In addition, when the expression "~" is used in this specification, it is used as the expression including the numerical value before and after that. [0015] The present invention relates to a chemiluminescent substance, which is a chemiluminescent substance that emits light by mixing a first composition with a second composition, the first composition is a composition containing oxalates, and the second composition is The composition is a composition containing hydrogen peroxide, a solvent for an oxidizing solution, a catalyst, and a fluorescent substance. By becoming such a chemiluminescent substance, the composition is mixed in the chemiluminescent substance to generate stable luminescence. More specifically, when the chemiluminescence body is bent and knocked to destroy the destructive inner container in the chemiluminescence container, when the composition for chemiluminescence is mixed in the chemiluminescence container, the The high concentration of oxalate can prevent the precipitation of fluorescent substances, so the luminous brightness is high, and the luminous time can be prolonged. [0016] The present invention relates to a chemiluminescence system, which is a chemiluminescence system that emits light by mixing a first composition with a second composition. The first composition is a composition containing oxalates. The second composition is a composition containing hydrogen peroxide, a solvent for an oxidizing solution, a catalyst, and a fluorescent substance. In these chemiluminescence systems, when chemiluminescence is to be generated, the first composition and the second composition are reacted. At this time, the concentration of oxalates in the first composition is high, and since the second composition contains a fluorescent substance, it can be prevented from precipitating in the first composition, so that stable light emission occurs. [0017] When the inventors changed the composition of the fluorescent liquid (fluorescent composition), the solid of the fluorescent substance remained in the liquid, or the fluorescent composition was powdered and mixed as a chemiluminescent substance. The reason for the difficult to mix (so-called dough) is reviewed. As a result, it was found that the influence of the precipitation of the fluorescent substance contained in the fluorescent composition is large. Therefore, this fluorescent substance was mixed with the composition on the oxidation liquid side which is generally considered unstable and avoided. [0018] FIG. 1 is a diagram showing a structure of a representative chemiluminescent body according to the present invention. The present invention can be an embodiment of the chemiluminescence body 10 shown in FIG. 1 (a). This embodiment relates to the first composition 1 enclosed in the destructive inner container 3 and the second composition separated from the first composition 1 in the container 4 for chemiluminescence which encloses the destructive inner container 3. 2 的 化学 光 体 10。 2 of the chemiluminescent body 10. When the chemiluminescence body 10 is used, the destructive inner container 3 is destroyed in the chemiluminescence container 4, so that the first composition 1 and the second composition 2 are mixed to perform chemiluminescence. [0019] Based on the state of the chemiluminescence body 10 shown in FIG. 1 (a), as the first composition 1, oxalate (CIPO) is individually sealed in powder form, and as the second composition 2, an oxidizing solution is used. It is produced from a mixture of a solvent (a mixed solvent of DMP and t-BuOH), hydrogen peroxide, a catalyst (SS), and a fluorescent substance (Lumogen (registered trademark) F Red). This chemiluminescence body was bent, and the destructive inner container 3 was destroyed. No light emission was observed by light vibration, and the mixture was rapidly mixed to generate stable luminescence. [0020] In addition, the present invention may be an embodiment of the chemiluminescent body 11 shown in FIG. 1 (b). This embodiment relates to the second composition 2 which is enclosed in the destructive inner container 3 and the first composition which is separated from the second composition 2 in the container 4 for chemiluminescence which encloses the destructive inner container 3. 1 的 化学 光 体 11。 1 of the chemiluminescent body 11. The chemiluminescence body 11 is obtained by changing the content of the first composition and the second composition in the chemiluminescence body 10. The chemiluminescence body 11 is the same as the chemiluminescence body 10. When the chemiluminescence body 10 is used, the destructive inner container 3 is destroyed, and the first composition 1 and the second composition 2 are mixed to perform chemiluminescence. . [0021] In addition, the present invention may be an embodiment of the chemiluminescence system shown in FIG. 2. In this embodiment, first, the first composition 6 is impregnated into the nonwoven fabric 5 of FIG. 2 (a). In this case, the first composition may be composed of only oxalates, or may be composed of only oxalates and solvents, so that it is colorless and it is difficult to see how the first composition is arranged ( (A part indicated by a dotted line in FIG. 2 (a)). Here, as shown in FIG. 2 (b), the second composition 7 comes into contact with the nonwoven fabric 5 from the container 71. In this way, the first composition 6 impregnated with the non-woven fabric 5 and the second composition 7 are reacted by contact to generate the chemiluminescent part 100. In this way, the chemiluminescence system of the present invention is arranged in a non-contact (mixed) state in a text-like form that hides the colorless first composition, and generates chemiluminescence when used, which can become a chemiluminescence system. [First Composition] The first composition used in the present invention is a composition containing oxalates. If this composition contains oxalates, chemiluminescence is generated when it is mixed with the second composition described in detail later. [0023] The first composition used in the present invention contains oxalates as a main component that contribute to its chemiluminescence. The oxalates used herein can be appropriately used so that the first composition containing the oxalates can start chemiluminescence when mixed with the second composition. Specific examples of the oxalates are, for example, bis (2,4,5-trichloro-6-carbonbutoxyphenyl) oxalate, bis (2,4,5-trichloro-6-carbamyloxy) Phenyl) oxalate and the like. [0024] The first composition used in the present invention preferably contains oxalates at a higher concentration than ordinary fluorescent liquids. With such a configuration, it is possible to improve the light emission characteristics when performing chemiluminescence. The higher the concentration of oxalates, the more substantially the chemiluminescence light emission characteristics are improved. [0025] Since the first composition contains oxalates at a high concentration, the first composition becomes a solid, paste-like, or slurry-like composition. In addition, the conventional technical idea is that when the concentration of oxalates is low, it is designed to contain a large amount of other solvents, and the conventional fluorescent liquid composition that does not easily cause the precipitation of fluorescent substances does not consider hydrogen peroxide to the fluorescent substances. Effect and easy to design. [0026] Since the higher the concentration of oxalates, the easier it is to improve the light-emitting characteristics, the concentration of oxalates in the first composition is preferably 50% by mass or more, more preferably 80% by mass or more, and more preferably 90% by mass %the above. When the oxalate concentration is 80% by mass or more, its properties can be substantially treated as equivalent to oxalate alone. In addition, in the present invention, the first composition may be substantially oxalate alone, or may be expressed as the first composition as a concept including a case where oxalate alone is included. [0027] The aforementioned first composition used in the present invention is preferably solid. In addition to oxalates, the first composition used in the present invention can also be added as an optional component described below and also solid at normal temperature, and the first composition can be made into a solid state such as powder or granules. mixture. In particular, when the powder or granule is used, it is considered that the liquid second composition easily penetrates into the gap between the powder or granule during chemiluminescence, so that the mixing property can be improved and the light emitting characteristics can be improved. [0028] Generally, the first composition is usually enclosed in a destructive inner container inside the chemiluminescent body. Since the destructive inner container has an extremely small diameter in accordance with the size of the chemiluminescent substance, the first composition is preferably a powder or granule having a high fluidity, which is easy to be enclosed therein. [0029] The first composition of the present invention may be oxalates alone, but other components may also be mixed. For example, a preferred catalyst contained on the second composition side may also be contained on the first composition side. Since the first composition side also contains a catalyst, a chemiluminescence reaction is generated more stably. In addition, it may contain a fluorescent substance having little miscibility or precipitation with the second composition. For example, anthracene-based fluorescent substances are difficult to precipitate due to their high solubility, so they can also be used on the first composition side. Examples of such fluorescent substances include, more specifically, 1-chloro-9,10-bis (phenylethynyl) anthracene (2-Et-BPEA), which is a yellow fluorescent substance that has been put into practical use to some extent. In addition, it may contain antioxidants, stabilizers, solvents, and the like as appropriate. [0030] The first composition used in the present invention may be a solid-state design mainly based on the above-mentioned oxalates. On the other hand, when designing in the form of a paste, etc., a solvent may be contained. Generally, the solvent is trimethyl ethyl citrate (ATBC), benzyl benzoate (BeB), or dipropylene glycol dimethyl ether. (DMM), etc. [0031] On the other hand, the first composition used in the present invention is preferably reduced in a component having a low solubility in a solution of the first composition. As typical examples of these components, fluorescent substances are mentioned. Among them, fluorene-based fluorescent substances or naphthaleneimine-based fluorescent substances are not easily precipitated when they are contained in the first composition with low solvent and low fluidity, and are easy to cause. The chemiluminescence characteristics are reduced. Therefore, the content of the fluorene-based fluorescent substance and the naphthaleneimine-based fluorescent substance in the first composition is preferably 0.5% by mass or less, more preferably 0.2% by mass or less, and still more preferably 0.1% by mass or less. These contents are particularly preferably not used as a raw material of the composition, and are not contained (0% by mass). [0032] The destructive inner container with the first composition used in the chemiluminescent body of the present invention as the content is contained in the chemiluminescent container of the chemiluminescent body, and only the destructive inner container is preferentially destroyed, and the container for the chemiluminescent body is preferentially destroyed. A container for dispersing the first composition contained therein. Examples of the structure include glass- or resin-made ampoules, aluminum or PP bags, and the like. [0033] The present invention is a destructive container for a chemiluminescent body, which is a destructive container for a chemiluminescent body in which a first composition is enclosed, and is used for the first composition enclosed in a destructive container. A chemiluminescence substance mixed with a chemiluminescent substance in a destructive container and a second composition separated and sealed from the first composition to emit light. The first composition contains 50% by mass or more of oxalates. Of the composition. [0034] The destructive container for a chemiluminescence body can have a structure equivalent to a destructive inner container containing the aforementioned first composition. The destructive container for a chemiluminescent body is used to exhibit excellent light emitting characteristics by reacting with the second composition and mixing with the excellent mixing property as a chemiluminescent body. In addition, since the destructive container for chemiluminescence is a container for chemiluminescence which is the entire chemiluminescence body, it is often a slim cylindrical ampoule having a relatively small diameter and a small diameter. [0035] In these ampoules, there are cases where it is difficult to seal because of the fluidity of the composition enclosed therein, and it is difficult to adjust the sealing conditions for each change in the composition of the composition. However, when the ampoule of the present invention is designed, the first composition that becomes its content does not contain a fluorescent substance that predominates and determines the color of chemiluminescence, and it can also be a standardized ampoule that can be widely used as a chemiluminescent substance. The ampoule may also contain a yellow fluorescent substance (e.g. 1- Chloro-9,10-bis (phenylethynyl) anthracene (2-Et-BPEA)). [Second Composition] The second composition used in the present invention is a composition containing hydrogen peroxide, a solvent for an oxidizing solution, and a fluorescent substance. As the second composition, a liquid composition can be prepared and used, and when used as a chemiluminescent substance, stable chemiluminescence is produced by mixing with the excellent mixing property of the first composition. The reason for this is that since the second composition side contains a fluorescent substance, it is not easy to cause problems caused by the miscibility or solubility of the first composition and the oxidizing solution, such as solid or slurry. [0037] The second composition used in the present invention contains hydrogen peroxide. The second composition contains oxidant hydrogen peroxide as an essential component, and in order to adjust the hydrogen peroxide concentration, improve the compatibility (miscibility) with the first composition, and further improve the salicylic acid added to improve the luminous efficiency. Soluble salts and other solvents. The hydrogen peroxide concentration standard in the second composition is about 1 to 10% by mass. [0038] The second composition used in the present invention contains a solvent for an oxidizing solution. Specific examples of the solvent contained in the oxidizing solution of the present invention include the use of citrates, phthalates, benzoates, trimellits, adipates, and sebacates. Solvents based on organic solvents such as azaleas, azaleas, glycerides, lactones, glycols, and alkyl glycol ethers. Among these solvents, from the viewpoint of safety, it is preferable to use the ignition point of 60 ° C or higher as the main solvent, and the ignition point of the whole is 70 ° C or higher. In addition, in the selection of the solvent, the so-called main solvent refers to a solvent that becomes the center when designing the blending amount when the blending amount is adjusted so that the ignition point becomes the temperature of the purpose of the present invention. In addition, the solvent may be a solvent alone. The amount of the solvent for the oxidizing liquid in the second composition becomes the remainder of other components such as hydrogen peroxide, catalyst, fluorescent substance and the like contained in the second composition. [0039] At least one of the first composition and the second composition used in the present invention preferably contains a catalyst. The catalyst is preferably contained in the second composition using a solvent. On the other hand, the catalyst may be contained only in the first composition. In addition, when contained in both compositions, as described above in part, it contributes to faster light emission or stable light emission. In general, it is desirable to contain a small amount (usually 0.1 mmol / L to 10 mmol / L for an oxidizing solution) of salicylic acid such as lithium salicylate, ammonium salicylate, sodium salicylate, tetraalkylammonium salicylate, and the like Its derivative is used as a catalyst component. [0040] The second composition used in the present invention contains a fluorescent substance. By including the fluorescent substance on the second composition side using the solvent, the problem of miscibility that occurs when the concentration of the oxalate in the first composition is increased and conventionally when the fluorescent substance is contained does not occur. Therefore, the first composition and the second composition are rapidly mixed, and the components necessary for chemiluminescence of oxalate, hydrogen peroxide, catalyst, and fluorescent substance can be stably obtained in the chemiluminescence body and become a reaction place in a proper state. Thereby, the effect of improving the initial light emission intensity or light emission time is obtained. The concentration standard of the fluorescent substance in the second composition is about 0.01 to 5% by mass, and it is set according to the luminous performance or mixing property of color, intensity, time, and the like. The concentration is based on solubility (prevention prevention, etc.). When a plurality of fluorescent substances are used, the concentration range based on the total amount is preferably in the above range. The lower limit of the concentration of the fluorescent substance is more preferably 0.05% by mass or more in order to improve the color development property during light emission. The upper limit of the concentration of the fluorescent substance may be saturated even if the fluorescent substance is excessively mixed, and the concentration of the components that contribute to chemiluminescence is relatively increased, and the precipitation of the fluorescent substance is prone to occur, so it is more preferably 2 Mass% or less. [0041] If the fluorescent substance has a luminescence spectrum at 300 to 1200 nm and is at least partially soluble in an oxidizing solution solvent, the fluorescent compound is not particularly limited. Examples of such fluorescent compounds include anthracene, substituted anthracene, benzoanthracene, phenanthrene, substituted phenanthrene, tetracene, substituted tetracene, pentacene, substituted pentacene, pyrene, substituted pyrene, and anthrone purple ( conjugated polycyclic aromatic compounds having condensed rings such as violanthrone), substituted anthrone violet, naphtholimine, and substituted naphtholimine. The substituent of the compound is not particularly limited as long as it does not inhibit the light-emitting reaction, and examples thereof include phenyl, lower alkyl, chloro, bromo, cyano, alkoxy, and phenylnaphthyl. Among these, the first composition containing fluorene, substituted fluorene and the like is a fluorene-based fluorescent substance containing fluorene, substituted fluorene, or the naphthylimine-based fluorinated fluorene, etc. In the case of a light substance, precipitation tends to occur, which also causes the unstable emission characteristics. Therefore, in the present invention, the fluorescent substance contained in the second composition is preferably a fluorene-based fluorescent substance and / or a naphthaleneimine-based fluorescent substance. These fluorene-based fluorescent substances and naphthaleneimine-based fluorescent substances are also preferred from the viewpoint of being stable for a long time in the second composition. [0042] Specific examples of the fluorescent substance include 2-chloro-9,10-bis (4-methylethynyl) anthracene, 9,10-bis (phenylethynyl) anthracene, and 1-methyl Oxy-9,10-bis (phenylethynyl) anthracene, 1,5-dichloro-9,10-bis (phenylethynyl) anthracene, 1,8-dichloro-9,10-bis (benzene Ethynyl) anthracene, monochloro and dichloro substituted 9,10-bis (phenylethynyl) anthracene, 5,12-bis (phenylethynyl) tetraacene, 9,10-diphenylanthracene, 16,17-dihexyloxyanthrone violet, 2-methyl-9,10-bis (phenylethynyl) anthracene, 9,10-bis (4-methoxyphenyl) -2-chloroanthracene, 9,10-bis (4-ethoxyphenyl) -2-chloroanthracene, 5,12-bis (phenylethynyl) pentacene, 5,6,11,12-tetraphenylpentacene ( Rubrene), pyrene and mixtures thereof. [0043] The fluorescent substance contained in the second composition of the present invention is preferably a fluorene-based fluorescent substance. The so-called fluorene-based fluorescent substance is a fluorescent substance having a skeleton of tritium or substituted for tritium. The actinide is a structure represented by the following formula (1), and the actinide fluorescent substance has the structure as a skeleton. When these fluorene-based fluorescent substances are contained in a second composition called an oxidizing liquid, they are stable for a long time and have excellent long-term storage stability. [0044] [0045] Among these fluorene-based fluorescent substances, particularly preferred is fluorene-dicarboxyfluorene-based fluorinated substances. Examples of specific products of the fluorene dicarboxyfluorene-based fluorescent substance include, for example, LUMOGEN RED (fluorene-based dicarboxylic acid fluorinated fluorescent agent, BASF Corporation, trade name), and LUMOGEN YELLOW (light-emitting fluorene) Carboximidate-based fluorescent agent, BASF Corporation, trade name), LUMOGEN ORANGE (orange dicarboxycarbamide-based fluorescent agent, BASF Corporation, trade name). [0046] The fluorescent substance contained in the second composition of the present invention is preferably a naphthaleneimine-based fluorescent substance. The compound used as a naphthaleneimine-based fluorescent substance is a compound having a naphthaleneimine skeleton, and is used as a user of a fluorescent substance in chemiluminescence. The naphthalene imine skeleton may have a substituent. The naphthalene imine skeleton is represented by the following formula (2). [0047] [0048] The nitrogen atom in the above formula may be, for example, a hydrogen atom; a hydrocarbon group bonded with a hetero atom such as an oxygen atom, a nitrogen atom, and a sulfur atom. Hydrocarbyl is synonymous with the above. An example of a commercially available compound having a naphthalene imine skeleton is, for example, LUMOGEN F Violet 570 (manufactured by BASF). [0049] The second composition used in the present invention may contain other ingredients within a range that does not impair the object of the present invention. For example, an antioxidant may be added in order to make the hydrogen peroxide in the second composition stable during storage. [0050] The present invention may be an oxidizing liquid containing a composition of hydrogen peroxide, a solvent for an oxidizing liquid, a catalyst, and a fluorescent substance, which is used for the first composition enclosed in a destructive inner container and An oxidizing solution for a chemiluminescence substance that contains the destructive inner container and a luminous chemiluminescence substance that is mixed with the second composition separated and sealed in the first composition. This oxidation solution corresponds to the second composition used in the present invention. [0051] This oxidizing solution is used enclosed in the outside of a destructive inner container or the like. And by changing the fluorescent substance of the oxidizing liquid, it is easy to change the color as a chemiluminescent body. In addition, as the ampule used in the destructive inner container described above has a small diameter and is not easy to fill the contents, on the other hand, the container for the chemiluminescence body filled with the oxidizing liquid has a wider diameter design, so the liquid filling is easy. In addition, when used in combination with this oxidizing liquid, the design of the ampoule side can be standardized and manufactured as a predetermined one. Only by changing the color of the fluorescent substance of the oxidizing liquid, it is possible to efficiently produce a display with arbitrary color development. Chemiluminescence. [0052] As the container for a chemiluminescent substance used in the present invention, any shape used as a chemiluminescent substance can be adopted. In addition, the combination of color, size, luminous intensity, time, etc. with the destructive inner container and the like is appropriately adjusted according to the use of the chemiluminescent substance. For example, it can be used as a small chemiluminescent body for fishing tackle or a concert light stick in the shape of a light stick, or a warning light or an emergency light. In addition, it can also be used as a luminous body for a venue that emits light using a mask-shaped container, and can also be a star-shaped or heart-shaped toy. [0053] The chemiluminescence system of the present invention is a person who makes the first composition or the second composition contact and react at any place. Therefore, a chemiluminescence kit of the first composition and the second composition can be provided. The present invention may also be a chemiluminescence method, which is a chemiluminescence method that emits light by mixing a first composition with a second composition. The first composition is a composition containing oxalates, and the second The composition is a composition containing hydrogen peroxide, a solvent for an oxidizing solution, and a fluorescent substance. [0054] As shown in the foregoing embodiment, for example, after arranging (impregnating) one composition in advance, and then touching another composition, light emission of characters, graphics, etc. in its shape or impregnation state may occur. This is because the content of the colored fluorescent substance in the first composition related to the chemiluminescence system of the present invention is extremely small and can be substantially free of the composition. Therefore, when the pre-configured composition is set as the first composition, the first The two components may be colorless before contact. In addition, since it is colorless and emits light in a place where the first composition is arranged during use, it can be used like a hidden character. [0055] Alternatively, as an example of the chemiluminescence system of the present invention, for performances such as ceremonies, a composition may be stored in an arbitrary container in advance, and another composition may be added from an opening or the like to emit light during use. At this time, it may emit light as a structure equivalent to a hidden character, and each composition may be set in different colors, and these may be mixed to emit light as a new color. [0056] In these chemiluminescence systems, the concentration of oxalates of the first composition can also be reduced in advance. Specifically, the concentration of the oxalates can be 3% by mass or more. In addition, for the use of hidden characters, the fluorescent substance in the first composition is more colorless, so the content thereof is reduced, and it is preferably set to 0.1% by mass or less, and more preferably 0.05% by mass or less. At this time, the lower limit of the content of the fluorescent substance is 0% by mass without using as a raw material. [0057] Alternatively, considering the state of each composition separated during storage, in view of the stability in the oxidizing solution of the second composition, the second composition may contain a fluorene-based fluorescent substance and / or a naphthaleneimine-based fluorescent substance. The light substance contains other previously exemplified fluorescent substances in the first composition. With this design, the first composition and the second composition are colored separately according to the type of fluorescent substance, and these mixed colors can also be produced during the use. EXAMPLES [0058] Hereinafter, the present invention will be described in more detail by way of examples. However, the present invention is not limited to the following examples as long as the gist of the present invention is not changed. [Evaluation Items] [Brightness] The brightness was measured using a "luminance meter LS-100 (Close Up Lens No. 122)" (Konica Minolta). [HPLC] The following apparatus was used for the HPLC test.・ HPLC absorbance detector: "SPD-10A vp" (Shimadzu Corporation) ・ HPLC liquid delivery unit: "LC-10AT" (Shimadzu Corporation) ・ Column oven: "CTO-10A" (Shimadzu Corporation) ・ Data processing device: "Chromato Pack C-R6A" (Shimadzu Corporation) [0060] [Test reagents for testing] DMP: dimethyl phthalate t-BuOH: tert-Butanol (Tokyo Chemical Industry Co., Ltd.) ) ATBC: Tributyl citrate (Tokyo Chemical Industry Co., Ltd.) BeB: Benzyl benzoate (Tokyo Chemical Industry Co., Ltd.) H ₂ O ₂ : Hydrogen peroxide (hydrogen peroxide water (Wako Pure Chemical Industries, Ltd.) Industry) Use after dehydration treatment) SS: Sodium salicylate (Kanto Chemical Co., Ltd.) CIPO: Bis (2,4,5-trichloro-6-isopentoxycarbonylphenyl) oxalate (Tokyo Kasei Industrial Co., Ltd.) CPPO: bis [2,4,5-trichloro-6- (pentoxycarbonyl) phenyl] oxalate (Tokyo Chemical Industry Co., Ltd.) [0061] [Example 1] [0062 ] In order to make it clear that the pigment (fluorescent substance) is added to the oxidizing solution that becomes the second composition, it becomes the first composition When the pigment (fluorescent substance) is added to the powder, the light emission characteristics are compared, and the light emission characteristics are compared. [0063] Fluorescent Substance (a): A perylene fluorescent substance represented by the following formula (3) is used. In the test methods described below, the amounts of the components contributing to the luminous brightness in each test are the same, so the mass of the fluorescent substance in each of the oxidation liquids and the powder is adjusted to the same amount. [0064] [Test method 1. Experiment (in powder) containing fluorescent substance on first composition (powder) side] (1) Preparation of oxidation solution (composition summary: DMP 81.6% by mass, t-BuOH 13.4% by mass, H ₂ O ₂ 5 mass%, SS 0.04 mass%). (2) Measure 9.85 g of CIPO and 0.15 g of fluorescent substance (a) and mix using a mortar. (3) Measure 0.14 g of the mixed powder of (1) into a 4 mL sample vial. (4) Add 0.43 mL of the oxidation solution of (1) to the sample vial of (3) to emit light. (5) Stir with a homogenizer (25M hand blender + 215A type micro homogenizer) for 10 seconds (stir on the bottom of the container to diffuse the powder in the oxidizing solution). (6) The luminous brightness is measured from the upper part of the sampling bottle container at a specific measurement time described below at 0 (initial) at the end of stirring. Measurement time: 30 seconds, 1 minute, 5 minutes, 15 minutes [0066] [Test method 2. Experiment of containing a fluorescent substance on the side of the second composition (oxidizing solution) (oxidizing solution)] (1) Prepare the oxidation solution ( Composition summary: DMP 81.6 mass%, t-BuOH 13.4 mass%, H ₂ O ₂ 5 mass%, SS 0.04 mass%). (2) Measure 100 g of the oxidation solution of (1), add 0.5 g (0.5% by mass) of a fluorescent substance, and stir to dissolve at room temperature. (3) Measure 0.14 g of CIPO powder in a 4 ml sample vial. (4) Add 0.43 ml of the oxidation solution of (2) to which the fluorescent substance has been added to the sample vial of (3) to make it glow. (5) Stir for 10 seconds with a homogenizer (stir on the bottom surface of the container to diffuse the powder in the oxidizing solution). (6) The luminous brightness is measured from the upper part of the sampling bottle container at a specific measurement time described below at 0 (initial) at the end of stirring. Measurement time: 30 seconds, 1 minute, 5 minutes, 15 minutes [0067] "Experimental Results" Brightness measurement Figure 3 and Table 1 show the luminescence when the fluorescent substance (a) is contained in the powder and the oxidation solution, respectively. Brightness curve, luminous brightness per time. The test was performed twice under each condition. [0068] [0069] When the fluorescent substance is contained in the powder (the first composition), and when the fluorescent substance is contained in the oxidizing solution (the second composition), a difference occurs in the initial luminescence after 1 minute, and the initial luminescence is started. There is a difference in brightness. When a fluorescent substance is added on the powder side, the fluorescent substance is precipitated because of its low solubility. Therefore, even if mixed, the solution is not dissolved and dispersed immediately in the liquid in which the powder and the oxidizing solution are mixed, and the initial luminescence is considered to be deteriorated. [Example 2] The stability of the fluorescent substance in the oxidizing liquid composition was tested. [Fluorescent Substance] [0072] [Linium Fluorescent Substance] • "Lumogen F Red 305": 1,6,7,12-tetraphenoxy-N, N'-bis (2,6- Diisopropylphenyl) fluorene dicarbamide · "Lumogen F Yellow 083": 4,10-dicyano-3,9-fluorene dicarboxylic acid diisobutyl ester · "Lumogen F Orange 240": 2 , 9-bis (2,6-diisopropylphenyl) -1,2,3,8,9,10-hexahydroanthracene [2,1,9-def: 6,5,10-d 'e'f'] Diisoquinoline-1,3,8,10-tetraketone [0073] [Napthalene imine-based fluorescent substance] ・ "Lumogen F Violet 570" [0074] [Anthracene-based fluorescent substance] [Yellow pigment] ・ "1-ClBPEA": 1-chloro-9,10-bis (phenylethynyl) anthracene ・ "1,8-dClBPEA": 1,8-dichloro-9,10-bis (benzene Ethynyl) anthracene [green pigment] ・ "2-EtBPEA": 2-ethyl-9,10-bis (phenylethynyl) anthracene [blue pigment] ・ "2-ClBMPA": 2-chloro-9 , 10-bis (4-methoxyphenyl) anthracene ・ "DPA": 9,10-diphenylanthracene [0075] [Tetraphenylbenzene fluorescent substance] [Orange pigment] ・ "BPEN": 5, 12-bis (phenylethynyl) tetrabenzo · "erythrofluorene": 5,6,11,12-tetraphenyltetrabenzo [0076] [Experimental operation] 1. Preparation of test sample (1) Preparation Oxidizing solution Summary into: DMP 81.6 mass%, t-BuOH 13.4 mass%, H ₂ O ₂ 5 mass%, SS 0.04% by mass). (2) Measure 100 g of the oxidation solution (1), add 0.15 g (0.15 mass%) of a fluorescent substance, and stir to dissolve at room temperature. (3) The oxidizing solution of the above (2) is divided into small portions into a screw cap tube, and an accelerated treatment test is performed at 60 ° C in a thermostatic chamber. (4) An accelerated treatment tester was performed at 60 ° C in a thermostatic chamber, and was taken out one week later. (5) Regarding the samples before and after the accelerated treatment test, those who have left out the fluorescent substance (pigment) have been completely dissolved using an ultrasonic cleaner and then measured. [0077] 2. HPLC measurement (1) The stability of the fluorescent substance in the oxidizing solution prepared in the preparation step of the aforementioned test sample was evaluated by the HPLC measurement test under the following conditions. Measurement conditions: Dilution operation: Add 4 mL of acetonitrile to 10 μL of sample. Detection wavelength: 254 nm. Mobile phase: 100% acetonitrile. Column oven: 40 ° C. Flow rate: 0.7 mL / min. Injection volume: 5 μL. Detection time: 20 minutes. [0078] 3. Brightness measurement (1) 2.0 mL of a blank solution (solute: CPPO, solvent: ATBC, BeB) in a composition containing oxalate was added to a sampling bottle container. (2) Measure 1.0 mL of the oxidation solution containing each fluorescent substance, add it to the above (1), and start emitting light. (3) Stir with a homogenizer for 10 seconds. (4) Set to 0 seconds at the end of the stirring, and measure the light emission brightness. [Experimental Results] [Experimental Results 1. HPLC Measurement] Table 2 shows the measurement results of the peak data of each fluorescent substance when the HPLC test was performed by the aforementioned experimental operation. In Table 2 (data of fluorescent substance peaks (area ratio)), the former was expressed as "before acceleration", and the accelerated treatment test was performed for 1 week, and the latter was expressed as "after 1 week acceleration," and the accelerated treatment test 2 The latter was expressed as "after 2 weeks of acceleration." In addition, "residual amount after 1 week" and "residual amount after 2 weeks" are compared with 100% before acceleration. [0080] [0081] As a result of the HPLC test, the fluorene-based and naphthaleneimine-based fluorescent substances did not show much deterioration before and after the accelerated treatment test. For other fluorescent substances, the degradation of BPEN and rubrene is significant (the result of the HPLC test, because no obvious peak is confirmed, so it is described as "none" in the table), and the peak value of other fluorescent substances is also reduced. [Experimental Results 2. Measurement Results of Luminous Brightness] The results of the brightness measurement using an oxidizing solution containing each fluorescent substance are shown in the following table. In the following table, before the acceleration treatment test, it is indicated as "before acceleration", after the acceleration treatment test is performed for 1 week, it is expressed as "acceleration 1w" (brightness measurement temperature 22 ° C), and after the acceleration treatment test is performed for 2 weeks, it is expressed as "acceleration 2w". "(Brightness measurement temperature 23 ° C). The "brightness after acceleration for 1w" is set to 100% before acceleration. The numerical unit of the luminous brightness in the table is "cd / m ² ". [0083] The test results of Lumogen F Red are shown in Table 3 (1 week) and Table 4 (2 weeks). [0084] [0085] [0086] The test results of Lumogen F Yellow 083 are shown in Table 5 (1 week) and Table 6 (2 weeks). [0087] [0088] The test results of Lumogen F Orange 240 are shown in Table 7 (1 week) and Table 8 (2 weeks). [0090] [0091] [0092] The test results of Lumogen F Violet 570 are shown in Table 9 (1 week) and Table 10 (2 weeks). [0093] [0094] [0095] The test results of 1-ClBPEA are shown in Table 11 (1 week) and Table 12 (2 weeks). [0096] [0097] [0098] The test results of 1,8-dClBPEA are shown in Table 13 (1 week) and Table 14 (2 weeks). [0099] [0100] [0101] The test results of 2-EtBPEA are shown in Table 15 (1 week) and Table 16 (2 weeks). [0102] [0103] [0104] The test results of 2-ClBMPA are shown in Table 17 (1 week) and Table 18 (2 weeks). [0105] [0106] [0107] The test results of DPA are shown in Table 19 (1 week) and Table 20 (2 weeks). [0108] [0109] [0110] The test results of BPEN are shown in Table 21 (1 week) and Table 22 (2 weeks). [0111] [0112] [0113] The test results of rubrene are shown in Table 23 (1 week) and Table 24 (2 weeks). [0114] [0115] [0116] As a result of the measurement of the brightness, any chemiluminescence substance emits light at an initial light emission brightness before the accelerated test without causing precipitation problems or the like. On the other hand, the stability was seen to be poor after the accelerated test. The actinic and naphthaleneimine fluorescent substances did not show much deterioration in luminous brightness before and after the accelerated test. In comparison with those using fluorene-based and naphthaleneimine-based fluorescent materials, the oxidation solution using other fluorescent materials was deteriorated and the luminous brightness was decreased. Especially for 1,8-dClBPEA, BPEN, and rubrene, the color becomes lighter when light is emitted to the extent that the change can be understood visually. [Industrial Applicability] [0117] According to the present invention, a chemiluminescence body and a chemiluminescence system that are stable and have excellent light emission brightness and light emission time are provided. For example, the chemiluminescence body can be used in various applications such as a concert light stick, a luminous body for fishing tackle, a simple light for disaster prevention, a sign light, and a warning light, and is industrially useful.

[0118][0118]

1、6‧‧‧第一組成物1. 6‧‧‧ first composition

2、7‧‧‧第二組成物2, 7‧‧‧ second composition

3‧‧‧破壞性內側容器3‧‧‧ Destructive inner container

4‧‧‧化學發光體用容器4‧‧‧Chemical luminous container

5‧‧‧不織布5‧‧‧ non-woven

71‧‧‧容器71‧‧‧container

10、11‧‧‧化學發光體10, 11‧‧‧ chemiluminescence

100‧‧‧化學發光部100‧‧‧ Chemiluminescence Department

[0013] 　　圖1係顯示本發明之化學發光體之實施形態的圖，(a)係本發明之化學發光體之第一實施形態，(b)係第二實施形態。 　　圖2係顯示本發明之化學發光系統之實施形態的圖，(a)係反應前之第一組成物之配置圖，(b)係顯示與第二組成物接觸並發光之狀態圖。 　　圖3係顯示本發明實施例1之發光亮度評價結果之圖表。[0013] FIG. 1 is a diagram showing an embodiment of the chemiluminescent body of the present invention, (a) is a first embodiment of the chemiluminescent body of the present invention, and (b) is a second embodiment. FIG. 2 is a diagram showing an embodiment of the chemiluminescence system of the present invention, (a) is a layout diagram of a first composition before the reaction, and (b) is a diagram showing a state in contact with the second composition and emitting light. FIG. 3 is a graph showing the results of light emission luminance evaluation in Example 1 of the present invention.

Claims (9)

一種化學發光體，其係藉由將第一組成物與第二組成物混合而發光之化學發光體， 　　前述第一組成物係含有草酸酯類之組成物， 　　前述第二組成物係含有過氧化氫、氧化液用溶劑及螢光物質之組成物。A chemiluminescent substance that emits light by mixing a first composition with a second composition. The first composition is a composition containing oxalates. The second composition is a peroxide. Composition of solvent for hydrogen, oxidizing liquid and fluorescent substance. 如請求項1之化學發光體，其具有破壞性內側容器與內包前述破壞性內側容器之化學發光體用容器， 　　前述第一組成物或前述第二組成物之任一者內含於破壞性內側容器中，另一組成物內含於前述破壞性內側容器與前述化學發光體用容器之間。For example, the chemiluminescence body of claim 1, which has a destructive inner container and a container for chemiluminescence that includes the aforementioned destructive inner container, either one of the aforementioned first composition or the aforementioned second composition is contained in destructive In the inner container, another composition is contained between the destructive inner container and the chemiluminescent container. 如請求項2之化學發光體，其中內含於前述破壞性內側容器之組成物為第一組成物。For example, the chemiluminescent substance of claim 2, wherein the composition contained in the aforementioned destructive inner container is the first composition. 如請求項1~3中任一項之化學發光體，其中前述第一組成物中之草酸酯類濃度為50質量%以上。The chemiluminescent substance according to any one of claims 1 to 3, wherein the concentration of the oxalate in the first composition is 50% by mass or more. 如請求項1~4中任一項之化學發光體，其中前述第二組成物中含有之螢光物質係苝系螢光物質及/或萘醯亞胺系螢光物質。The chemiluminescent substance according to any one of claims 1 to 4, wherein the fluorescent substance contained in the second composition is a fluorene-based fluorescent substance and / or a naphthaleneimine-based fluorescent substance. 如請求項1~5中任一項之化學發光體，其中前述第一組成物為固體狀。The chemiluminescence body according to any one of claims 1 to 5, wherein the first composition is solid. 一種化學發光體用破壞性容器，其係封入有第一組成物之化學發光體用破壞性容器，且其係用於藉由使封入於破壞性容器中之第一組成物與內包前述破壞性容器之化學發光體用容器內之與前述第一組成物分離封入之第二組成物混合而發光之化學發光體， 　　前述第一組成物係含有50質量%以上草酸酯類之組成物。A destructive container for a chemiluminescent body is a destructive container for a chemiluminescent body in which a first composition is enclosed, and is used for enclosing the first composition enclosed in the destructive container with the aforementioned damage The chemiluminescence body of a chemical container is a chemiluminescence body which is mixed with the second composition separated and sealed in the first composition and emits light. The first composition is a composition containing 50% by mass or more of oxalate. 一種化學發光用氧化液，其係藉由與含有草酸酯類之組成物混合而產生化學發光之氧化液， 　　且係含有過氧化氫水、氧化液用溶劑及螢光物質之組成物。An oxidation solution for chemiluminescence is an oxidation solution that generates chemiluminescence by mixing with a composition containing oxalates, and is a composition containing hydrogen peroxide water, a solvent for an oxidation solution, and a fluorescent substance. 一種化學發光系統，其係藉由使第一組成物與第二組成物混合而發光之化學發光系統， 　　前述第一組成物係含有草酸酯類之組成物， 　　前述第二組成物係含有過氧化氫、氧化液用溶劑及螢光物質之組成物。A chemiluminescence system is a chemiluminescence system that emits light by mixing a first composition with a second composition. The first composition is a composition containing oxalates. The second composition is a peroxide composition. Composition of solvent for hydrogen, oxidizing liquid and fluorescent substance.