CN109705851A - A kind of organic matter makees the light emitting composition of filler - Google Patents

A kind of organic matter makees the light emitting composition of filler Download PDF

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Publication number
CN109705851A
CN109705851A CN201711010383.0A CN201711010383A CN109705851A CN 109705851 A CN109705851 A CN 109705851A CN 201711010383 A CN201711010383 A CN 201711010383A CN 109705851 A CN109705851 A CN 109705851A
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bis
oxalate
filler
oxalates
content
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Pending
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CN201711010383.0A
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Chinese (zh)
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何晓华
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Individual
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Individual
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Abstract

A kind of organic matter makees the light emitting composition of filler, it is made of " the oxalate component " comprising oxalate and " activator component " comprising oxidant and fluorescer, solvent and filler, wherein oxalic acid ester content is 1%-30%, the content of oxidant is 1%-40%, the content of fluorescer is 0.01%-1%, the content of solvent is 0.3%-30%, and the content of filler is 15%-90%.Of the invention to be advantageous in that: 1, the type, quantity and stability of impurity are easy to control, so that the chemiluminescence reaction of composition be made to be controlled;2, when using the filler containing organic filler, bigger light-emitting area or luminous volume can be obtained;3, the active principle of all chemiluminescence reactions can come into full contact with reaction, so that light output be made to maximize.

Description

A kind of organic matter makees the light emitting composition of filler
Invention field
The present invention relates to the solid background skills that filler is made in chemical luminous composite field more particularly to a kind of organic matter Art:
Oxalate-oxidant-dyestuff chemistry luminescence system composition is familiar and utilizes.Such as in United States Patent (USP) Oxidation chemistry light emitting composition described in 3816326,4313843 and 5122306.They are all liquid and typically have There are 50mPas or smaller viscosity, a container is needed to contain for using.Which limits its application ranges.When need into When the illumination of row area or mark, the influence of container itself will receive.
Chinese patent application 200610130440.4 describes a kind of solid chemistry luminescent composition, it can be with when using Using or not application container, the region that simply can be uniformly disseminated to needs carries out area illumination or mark, and is easy to clear It removes, does not cause or result only in seldom contamination.
Summary of the invention
The purpose of the present invention is to provide a kind of solid chemistry luminescent compositions for making filler with organic matter, it has Excellent chemiluminescence performance.
Technical solution of the present invention: a kind of organic matter makees the solid chemistry luminescent composition of filler, it is by including grass " the oxalate component " of acid esters and " activator component " comprising oxidant and fluorescer, solvent and filler are constituted, wherein Oxalate content in chemical luminous composite is 1%-30%, and content of the oxidant in chemical luminous composite is 1%- 40%, content of the fluorescer in chemical luminous composite is 0.01%-1%, solvent containing in chemical luminous composite Amount is 0.3%-30%, and content of the filler in chemical luminous composite is 15%-90%, it is characterised in that used fills out Fill the mixture that agent is organic filler or organic filler and inorganic filler.
Above-mentioned described activator component includes oxidant, one or more kinds of solvent, filler and/or fluorescence Agent, chelating agent, catalyst;It can contain or not contain the thickener of water in activator component.
Above-mentioned described oxalate component can be single oxalate, is also possible to oxalate and fluorescer and/or urges The mixture of agent;Oxalate or oxalate and fluorescer and/or catalyst be can be with the mixture of filler, mixed herein Close the other solvents and/or non-water hickener that can be added or be added without in object in addition to water.
Oxalate in above-mentioned described oxalate component include bis- (2,4,5- tri- chloro- penta oxygen phenyl of 6- carbonyl) oxalates, Bis- (2,4,5- trichlorophenyl) oxalates, bis- (2,4, the 5- tri- bromo- own oxygen phenyl of 6- carbonyl) oxalates, bis- (2 ,-nitrobenzophenone) grass Acid esters, bis- (2,4- dinitrophenyl) oxalates, bis- (2,6- bis- chloro-4 nitrophenyl) oxalates, bis- (2,4,6- trichloro-benzenes Base) oxalate, bis- (3- trifluoromethyl -4- nitrobenzophenone) oxalates, bis- (1,2- dimethyl -4,6- dinitrophenyl) oxalic acid Ester, bis- (2,4- dichlorophenyl) oxalates, bis- (2,4- dinitrophenyl) oxalates, bis- (2,5- dinitrophenyl) oxalates, Bis- (2- formyl -4- nitrobenzophenone) oxalates, bis- (five chlorophenyl) oxalates, bis- (1,2- dihydro-2-oxo -1- pyridyl groups) Glyoxal, bis- (2,4- dinitro -6- aminomethyl phenyl) oxalates;The oxalate preferably includes bis- (2,4,5- tri- chloro- 6- carbonyls Penta oxygen phenyl) oxalate (referred to as " CPPO ") or bis- (2,4,5- trichlorophenyl) oxalates (referred to as " TCPO ").
Of the invention to be advantageous in that: the solid chemistry luminescent composition has used the filler containing organic matter, with Know that solid chemistry luminescent composition is compared using inorganic filler: 1, since the organic filler of selection be synthesis chemical products, Compared with inorganic natural minerals, type, quantity and the stability of impurity are easy to control, to make the chemiluminescence of composition Reaction is controlled;2, the density of inorganic filler is in 2g/cm3-4g/cm3, and the density of organic filler is in 1g/cm3 Hereinafter, therefore bigger light-emitting area or luminous volume can be obtained when using the filler containing organic filler;3, Organic filler does not have deep layer adsorption function, and the active principle of all chemiluminescence reactions is to attach on filler surface, This active principle for allowing for all chemiluminescence reactions can come into full contact with reaction, so that light output be made to maximize.
Specific embodiment
Embodiment 1
1 embodiment of table, 1 ingredient lists
9.10% CPPO of component content oxalate component polypropylenes powder 9.10% 9,10- tolans base anthracene 0.36% 7.28% activator component polypropylene powder of repefral, 54.60% urea peroxide, 9.10% sodium salicylate 1.36% water 9.10% amounts to 100%
By CPPO, 9,10- tolans base anthracene and phthalic acid two is added listed by table 1 into organic filler polypropylene powder Methyl esters, being uniformly mixed is " oxalate component ".
Water, urea peroxide and sodium salicylate are added into organic filler polypropylene powder, being uniformly mixed is " activator Component ".
Above-mentioned " oxalate component " is mixed together " activator component ", Green Chemistry is generated and shines.
Embodiment 2
2 embodiment of table, 2 ingredient lists
8.45% aluminium oxide of component content oxalate component polyethylene powder, 25.34% CPPO 2.54% 1,8- bis- is chloro- 9,10- 0.08% repefral of tolans base anthracene, 1.69% activator component polyethylene powder 50.68% 4.22% disodium ethylene diamine tetraacetate of urea peroxide 5.91% sodium salicylate, 0.84% water, 0.08% xanthan gum 0.17% amounts to 100%
By inorganic filler aluminium oxide and various additives CPPO, 1,8- is added listed by table 2 into organic filler polyethylene powder Two chloro- 9,10- tolans base anthracenes and repefral, being uniformly mixed is " oxalate component ".
Water, urea peroxide, disodium ethylene diamine tetraacetate, sodium salicylate and Huang are added into organic filler polyethylene powder Virgin rubber, being uniformly mixed is " activator component ".
Above-mentioned " oxalate component " is mixed together " activator component ", yellow chemiluminescence is generated.

Claims (4)

1. the light emitting composition that a kind of organic matter makees filler, which is characterized in that it is by " the oxalate group comprising oxalate Point " and " activator component " comprising oxidant and fluorescer, solvent and filler constitute, wherein oxalate is sent out in chemistry Content is 1%-30% in light composition, and content of the oxidant in chemical luminous composite is 1%-40%, and fluorescer exists Content in chemical luminous composite is 0.01%-1%, and content of the solvent in chemical luminous composite is 0.3%-30%, Content of the filler in chemical luminous composite is 15%-90%, it is characterised in that filler used is organic filler Or the mixture of organic filler and inorganic filler.
2. above-mentioned described a kind of light emitting composition for making filler with organic matter according to claim 1, feature exist In activator component includes oxidant, one or more kinds of solvent, filler and/or fluorescer, chelating agent, catalysis Agent;It can contain or not contain the thickener of water in activator component.
3. above-mentioned described a kind of light emitting composition for making filler with organic matter according to claim 1, feature exist In above-mentioned described oxalate component can be single oxalate, be also possible to oxalate and fluorescer and/or catalyst Mixture;Oxalate or oxalate and fluorescer and/or catalyst be can be with the mixture of filler, in this mixture In can be added or be added without other solvents and/or non-water hickener in addition to water.
4. above-mentioned described a kind of light emitting composition for making filler with organic matter according to claim 1, feature exist In, the oxalate in above-mentioned described oxalate component include bis- (2,4,5- tri- chloro- penta oxygen phenyl of 6- carbonyl) oxalates, it is bis- (2, 4,5- trichlorophenyls) oxalate, bis- (2,4, the 5- tri- bromo- own oxygen phenyl of 6- carbonyl) oxalates, bis- (2 ,-nitrobenzophenone) oxalates, Bis- (2,4- dinitrophenyl) oxalates, bis- (2,6- bis- chloro-4 nitrophenyl) oxalates, bis- (2,4,6- trichlorophenyls) grass It is acid esters, bis- (3- trifluoromethyl -4- nitrobenzophenone) oxalates, bis- (1,2- dimethyl -4,6- dinitrophenyl) oxalates, double (2,4- dichlorophenyl) oxalate, bis- (2,4- dinitrophenyl) oxalates, bis- (2,5- dinitrophenyl) oxalates, bis- (2- Formyl -4- nitrobenzophenone) oxalate, bis- (five chlorophenyl) oxalates, bis- (1,2- dihydro-2-oxo -1- pyridyl group) second two Aldehyde, bis- (2,4- dinitro -6- aminomethyl phenyl) oxalates;The oxalate preferably includes bis- (2,4,5- tri- chloro- penta oxygen of 6- carbonyl Phenyl) oxalate (referred to as " CPPO ") or bis- (2,4,5- trichlorophenyl) oxalates (referred to as " TCPO ").
CN201711010383.0A 2017-10-26 2017-10-26 A kind of organic matter makees the light emitting composition of filler Pending CN109705851A (en)

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CN201711010383.0A CN109705851A (en) 2017-10-26 2017-10-26 A kind of organic matter makees the light emitting composition of filler

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201711010383.0A CN109705851A (en) 2017-10-26 2017-10-26 A kind of organic matter makees the light emitting composition of filler

Publications (1)

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CN109705851A true CN109705851A (en) 2019-05-03

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