TW201219295A - Carbon nanotubes film supporting structure and method for using the same - Google Patents

Carbon nanotubes film supporting structure and method for using the same Download PDF

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TW201219295A
TW201219295A TW99137722A TW99137722A TW201219295A TW 201219295 A TW201219295 A TW 201219295A TW 99137722 A TW99137722 A TW 99137722A TW 99137722 A TW99137722 A TW 99137722A TW 201219295 A TW201219295 A TW 201219295A
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carbon nanotube
nanotube film
bearing
bearing structure
carbon
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TW99137722A
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TWI444325B (en
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yu-quan Wang
Chen Feng
Li Qian
Liang Liu
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Beijing Funate Innovation Tech
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Abstract

The present invention relates to a carbon nanotubes film supporting structure. The carbon nanotubes film supporting structure includes a substrate and a plurality of raised structures. The substrate includes a surface, and a carbon nanotubes film supporting area is defined on the surface of the substrate. The plurality of raised structures are located in the carbon nanotubes film supporting area. The carbon nanotubes film supporting structure is used to support a carbon nanotubes film structure, and the carbon nanotubes film structure can be peeled off completely after contact with carbon nanotubes film supporting structure. The present invention also relates to a methed for using the carbon nanotubes film supporting structure.

Description

201219295 六、發明說明: 【發明所屬之技術領域】 [0001] 本發明涉及一種奈米碳管膜承載結構及其使用方法。 [先前技術3 [0002] 奈米碳管係一種由石墨烯片卷成的中空管狀物,其具有 優異的力學、熱學及電學性質。奈米碳管應用領域非常 廣闊,例如,它可用於製作場效應電晶體、原子力顯微 鏡針尖、場發射電子槍、奈米模板等等。惟,目前基本 上都係在微觀尺度下應用奈米碳管,操作較困難β所以201219295 VI. Description of the Invention: [Technical Field of the Invention] [0001] The present invention relates to a carbon nanotube film bearing structure and a method of using the same. [Prior Art 3 [0002] A carbon nanotube is a hollow tubular body rolled from a graphene sheet, which has excellent mechanical, thermal and electrical properties. Nano carbon nanotubes are used in a wide range of applications, for example, for field effect transistors, atomic force microscopy needle tips, field emission electron guns, nano templates, and more. However, at present, it is basically applied to the carbon nanotubes at the microscopic scale, and the operation is difficult.

[0003][0003]

,將奈米碳管組裝成宏觀尺度的結構對於奈米碳管的宏 觀應用具有重要意義。 ―: , 先前的奈米碳管宏觀結構主要有奈米碳管膜,惟,奈米 碳管膜等奈米破管*觀結構的比表面賴Α,其宏觀上 表現出很強的黏性’一旦接觸到其他物體便會黏住並 很難分開’所以給保存和轉移奈米碳管宏觀結構帶來較 大的困難’從而了奈米碳管膜等奈米碳管 在宏觀領域的進一步應用。 且 結構 【發明内容】 [0004] 有鑒於此, 實為必要。 提供—種奈料管料餘似其使用方法 [0005] 099137722 -“碜管骐承栽結構,用 構,且該奈来碳管 、承載—奈米碳管膜狀結 觸後可以完整地從科;奈米碳㈣承載結構接 該奈米碳^承 =S承細構脫離,其中, 構,所述基底具有基底以及複數個凸起結 、’一表面,所述I办 表單編號A010】 在展的表面具有一齐米 第3頁/共28頁 不〆、 0992065766-0 201219295 碳管膜承載區域,所述複數個凸起結構設置在所述基底 表面的奈米碳管膜承載區域,從而使得將一奈米碳管膜 狀結構設置於所述奈米碳管膜承載區域中的複數個凸起 結構時,所述奈米碳管膜狀結構與所述複數個凸起結構 形成點接觸或線接觸,所述奈米碳管膜狀結構與所述奈 米碳管膜承載結構的有效接觸面積小於等於所述奈米碳 管膜狀結構本身面積的20°/〇。 [0006] 一種奈米碳管膜承載結構的使用方法,其包括:提供至 少一奈米碳管膜承載結構,所述奈米碳管膜承載結構包 括一基底及複數個凸起結構,所述基底具有一表面,該 表面具有一奈米碳管膜承載區域,所述複數個凸起結構 設置於所述基底表面的奈米碳管膜承載區域;提供一奈 米碳管膜狀結構;以及將所述奈米碳管膜狀結構直接設 置於所述奈米碳管膜承載結構中的複數個凸起結構,所 述奈米碳管膜狀結構與所述複數個凸起結構形成點接觸 或線接觸,所述奈米碳管膜狀結構與所述奈米碳管膜承 載結構的有效接觸面積小於所述奈米碳管膜狀結構本身 面積的20%。 [0007] 相較先前技術,所述的奈米碳管膜承載結構具有結構簡 單等特點,該奈米碳管膜承載結構通過在一基底的表面 設置複數個凸起結構,使得將一奈米碳管膜狀結構設置 於所述奈米碳管膜承載結構表面時,該奈米碳管膜狀結 構的大部分結構通過所述凸起結構懸空設置,從而大大 地減少了所述奈米碳管膜狀結構與所述奈米碳管膜承載 結構的有效接觸面積,進而降低了所述奈米碳管膜狀結 099137722 表單編號A0101 第4頁/共28頁 0992065766-0 201219295 [0008] [0009] Ο [0010] ο 099137722 構與所述奈米碳管膜承載結構之間的凡得瓦力’最後實 現奈米碳管膜狀結構的保存和轉移。 所述奈米碳管膜承載結構的使用方法’通過將一奈米石灰 管膜直接承載於一 奈米碳管膜承載結構的奈米破管膜承 載區域,從而實現奈米碳管膜狀結構的保存和轉移該 方法簡單易行。 【實施方式】 下面將結合附圖及具體實施例,對本發明作進步的詳 細說明。 請參閱圖1,本發明第一實施例提供一種奈冰碳管膜承栽 結構100,該奈米碳管膜承栽結構100用於承載或保護— 奈米碳管膜狀結構,且該奈米碳管膜狀結構與所述奈米 碳管獏承載結構100接觸後可完整地從所述奈米碳管膜承 載結構100剝離。該奈米碳管膜承載結構1〇〇包括·一基 底110以及複數個凸起結構116,其中,所_基底110具 有一表面112,該表面112上設置有一奈米碳管膜承載區 域114。所述複數個凸起結構Π6設置於所述奈米碳管膜 承载區域114。所述複數個凸起結構U6用於承載一奈米 碳管骐狀結構《可以理解,將一奈米碳管膜狀結構設置 於所述奈米碳管膜承載區域114上的複數個凸起結構116 時’該奈米碳管膜狀結構與所述複數個凸起結構116形成 點接觸或線接觸,從而使所述奈米碳營臈狀結構與所述 奈米碳管膜承載結構100的有效接觸面積小於所述奈米碳 管膜狀結構本身面積的20% ’該奈米碳管膜狀結構可以完 整地從該奈米碳管膜承載結構100的表面112剝離。 表單編號Α0101 第5頁/共28頁 0992065766-0 201219295 [0011] 所述基底110為具有一定強度的薄片狀結構,其形狀、尺 寸可依據實際需求設計。該基底110的材料可選自硬性或 具有一定強度的柔性材料。具體地,該基底110的材料選 自金屬、金屬氧化物、陶究、樹脂等材料。該基底11 0具 有一表面112。所述表面112可以為平面、曲面或其他不 規則面。 [0012] 所述奈米碳管膜承載區域114可以為所述基底110的整個 表面112或者部分表面112。所述複數個凸起結構116相 互間隔地設置於所述奈米碳管膜承載區域114。該複數個 凸起結構116的材料選自金屬氧化物、金屬及無機鹽等材 料。所述複數個凸起結構116可以通過化學方法或物理方 法形成於所述基底110的表面112。該複數個凸起結構 11 6可以為點狀凸起結構、線狀凸起結構或點狀凸起結構 與線狀凸起結構的組合等結構。所述點狀凸起結構的形 狀為球形、橢球形或其他不規則形狀,由於該點狀凸起 結構的體積較小,可以近似的看作為球形。所述線狀凸 起結構的橫截面可以係三角形、方形、矩形、梯形或其 他形狀。優選地,所述基底110的表面112形成有複數個 均勻分佈且間隔設置的點狀凸起結構,該點狀凸起結構 的形狀為球形,其直徑可以為1微米〜1毫米,相鄰的點 狀凸起結構之間的間距為10微米〜10毫米。此外,所述 複數個凸起結構11 6亦可以採用其他不同結構的組合。可 以理解,將一奈米碳管膜狀結構設置於所述奈米碳管膜 承載區域114上的複數個凸起結構116時,該奈米碳管膜 狀結構與所述複數個凸起結構11 6形成點接觸或線接觸, 099137722 表單編號A0IO1 第6頁/共28頁 0992065766-0 201219295 從而使所述奈米碳管膜狀結構與所述奈米碳管膜承載結 構100的有效接觸面積小於所述奈米碳管膜狀結構本身面 積的20%。優選地,所述奈米破管膜狀結構與所述奈米後 管膜承載結構100的有效接觸面積小於等於所述奈米碳管 膜狀結構本身面積的10%。可以理解,所述複數個凸起結 構116亦可以與所述基底11〇可以一體成型。 [0013] Ο 本實施例中,所述奈米碳管膜承載結構10〇為一邊長為 10cm的方形100#砂紙。該100#砂紙表面形成有複數個岣 勻分佈且間隔設置的點狀必起結構,相鄰的點狀凸起結 構的距離約為2 ο α微米。所述點狀凸起結構的直徑約為 - 仏,》 15〇微米。可以理解,所述奈米破管膜承載結構1 〇〇亦可 以係其他塑號的砂紙,如5㈣〜2⑽〇#的欢紙。 [0014] Ο 請參閱圖2,本發明第二實施例提供一種奢米碳管骐承栽 結構200,該奈米碳管膜承載結構200用於承載或保護一 奈米碳管膜狀結構,且該奈米碳管膜狀結構與所述奈米 碳管膜承載、结構2〇〇接觸後可完整地從該奈米碳管膜承栽 結構200剝離。所述奈米碳管膜承載結構200包括:—基 底210以及複數個凸起結構216 ’其中’所述基底2!〇具 有一表面212 ’該表面212上設置有一奈米碳管膜承載區 域214。所述複數個凸起結構216設置於所述奈米碳管膜 承載區域214。所述複數個凸起結構216用於承載一奈米 碳管膜狀結構°可以理解’將一奈米碳管膜狀結構設置 於所述奈米碳管膜承載區域214上的複數個凸起結構216 時,該奈米碳管膜狀結構與所述複數個凸起結構216形成 點接觸或線接觸,從而使所述奈米碳管膜狀結構與所述 099137722 表單编號Α0101 第7頁/共28頁 0992065766-0 201219295 奈来碳管膜承栽結構2 00的有效接觸面積小於所述奈米碳 管膜狀結構本身面積的2 〇%,該奈米破管膜狀結構可以完 整地從該奈米碳管膜承載結構200的表面212剝離。 [0015] 本實施例中,所述基底21〇為具有一定強度的金屬薄片。 所述奈米碳管膜承載區域214為所述金屬薄片的部分表面 °所述奈米碳管膜承載區域214包括複數個線狀凸起結構 216。該複數個線狀凸起結構216均勻分佈且相互平行間 隔設置。該複數個線狀凸起結構216可以通過化學方法或 物理方法形成於所述基底210的表面212。該複數個線狀 凸起結構216的横截面為三角形。該複數個線狀凸起結構 216橫截面的寬度可以為1微米〜1〇〇微米,相鄰的複數個 線狀凸起結構216之間的距離為10微米〜i毫米。所述複 數個線狀凸起結構216的高度可以為1微來〜1毫米。此外 ’形成在所述基底210的表面212的複數個線狀凸起結構 216可以相互交叉設置或採;:用其他不同結構的組合。可以 理解’將一奈米碳管膜狀結構設置於所述奈米碳管膜承 載區域214上的複數傭凸起結;^216時,該奈米碳管膜狀 結構與所述複數個凸起結構216形成線接觸,從而使所述 奈米碳管膜狀結構與所述奈米碳管膜承載結構2 〇 〇的有效 接觸面積小於所述奈米碳管膜狀結構本身面積的2〇%。優 選地,所述奈米碳管膜狀結構與所述奈米碳管臈承載結 構200的有效接觸面積小於等於所述奈米碳管膜狀結構本 身面積的10%。 請參閱圖3,本發明還進一步提供一種使用所述奈米碳管 膜承載結構100承載和保存奈米碳管膜狀結構的方法,該 099137722 表單編號A0I01 第8頁/共28頁 0992065766-0 [0016] 201219295 G [0017] 〇 [0018] [0019] [0020] 方法主要包括以下步驟:(S101)提供至少一奈米碳管 膳承載結構,所述奈米碳管膜承栽結構包括一基底及複 數個凸起詰構,所述基底具有—表面,該表面具有一奈 米碳管膜承載區域,所述複數個凸起結構設置於所述基 底表面的奈米碳管膜承載區域;(S102)提供一奈米碳 管膜狀結構;以及(S103)將所述奈米碳管膜狀結構直 接設置於所述奈米碳管膜承載結構的複數個凸起結構, 所述奈米破管膜狀結構與所述複數個凸起結構形成點接 觸或線接觸,所述奈米破管膜狀結構與所述奈米碳管臈 承載結構的有效接觸面積小於所述奈米碳管膜狀結構本 身面積的20%。 ' 少驟S101,提供至少一奈米碳管膜承載結構,所述奈米 破管膜承載結構包括一基底及複數個凸起結構,所述基 底具有一表面’該表面具有一奈米碳管膜承載區域,所 述複數個凸起結構設置於所述基底表面的奈米碳管膜承 載區域。 所述奈米破管膜承載結構為本發明第一實施例所提供的 奈米碳管膜承載結構100。可以理解,所述奈米碳管膜承 載結構亦可以為本發明第二實施例所提供的奈米碳管媒 承載結構200或其他結構。 步驟S102,提供一奈米碳管膜狀結構。 提供一奈米碳管膜狀結構120,所述奈米碳管膜狀結構 120包括至少一個奈米碳管膜。該奈米碳管膜可以係奈米 碳管拉膜、奈米碳管絮化膜或奈米碳管碾壓膜等。 099137722 表單編號A0101 第9頁/共28頁 0992065766-0 201219295 [0021] 請參見圖4,所述奈米碳管拉膜為從一奈米碳管陣列中直 接拉取獲得的整體結構。該奈米碳管拉膜係由複數個奈 米碳管組成的自支撐結構。所述自支撐結構係指該奈米 碳管拉膜可無需基底支撐,自支撐存在。所述複數個奈 米碳管基本沿同一方向擇優取向延伸。所述擇優取向係 指在奈米碳管拉膜中大多數奈米碳管的整體延伸方向基 本朝同一方向。而且,所述大多數奈米碳管的整體延伸 方向基本平行於所述奈米碳管拉膜的表面。進一步地, 所述奈米碳管拉膜中多數奈米碳管係通過凡得瓦力首尾 相連並且基本沿同一方向延伸。所述奈米碳管拉膜及其 製備方法請參見2007年2月12日申請的,2010年7月11日 公告的,公告號為TW 13271 77的台灣發明專利申請公開 說明書。 [0022] 請參見圖5,所述奈米碳管碾壓膜包括均勻分佈的奈米碳 管,該奈米破管無序,沿同一方向或不同方向擇優取向 排列。優選地,所述奈米碳管碾壓膜中的奈米碳管基本 沿同一方向延伸且平行於該奈米碳管碾壓膜的表面。所 述奈米碳管碾壓膜中的奈米碳管相互交疊。所述奈米碳 管碾壓膜中奈米碳管之間通過凡得瓦力相互吸引,緊密 結合,使得該奈米碳管碾壓膜具有很好的柔韌性,可以 彎曲折疊成任意形狀而不破裂。所述奈米碳管碾壓膜及 其製備方法請參見2009年1月1曰公開的,公開號為 TW200 90 0348的台灣發明專利申請公開說明書。 [0023] 請參見圖6,所述奈米碳管絮化膜包括相互纏繞的奈米碳 管。該奈米碳管之間通過凡得瓦力相互吸引、纏繞,形 099137722 表單編號A0101 第10頁/共28頁 0992065766-0 201219295 [0024] 成網絡狀結構。所述奈米碳管絮化膜各向同性。所述奈 米碳管絮化膜中的奈米碳管為均勻分佈,無規則排列。 所述奈米碳管絮化膜及其製備方法請參見2008年11月16 日公開的,公開號為TW200844041的台灣發明專利申請 公開說明書。 本實施例中,所述奈米碳管膜狀結構120包為一奈米碳管 拉膜,該奈米碳管拉膜為從一奈米碳管陣列中直接拉取 獲得,其製備方法具體包括以下步驟: Ο 陳Η 首先,提供一形成於一生長基底的奈米碳管陣列,該陣 列為超順排的奈米碳管陣列。 [0026] ❹ 所述超順排的奈米碳管陣列採用化學氣相沉積法製備, 該超順排奈米碳管陣列的製備方法可參見台灣專利公告 第TW 1303239號。該超順排的奈米碳管陣列為複數個彼 此平行且垂直於生長基底生長的奈米碳管形成的純奈米 碳管陣列。通過控制生長條件,該超順排的奈米碳管陣 列中基本不含有雜質,如無定型碳或殘留的催化劑金屬 顆粒等,適於從中拉取奈米碳管膜。本發明實施例提供 的奈米碳管陣列為多壁奈米碳管陣列。所述奈米碳管的 直徑為0.5〜50奈米,長度為50奈米〜5毫米。本實施例中 ,奈米碳管的長度優選為100微米〜900微米。 [0027] 其次,採用一拉伸工具從所述奈米碳管陣列中拉取奈米 碳管獲得一奈米碳管膜,其具體包括以下步驟:(a)從 所述超順排奈米碳管陣列中選定一個或具有一定寬度的 複數個奈米碳管,本實施例優選為採用具有一定寬度的 099137722 表單編號A0101 第11頁/共28頁 0992065766-0 201219295 膠帶接觸奈米碳管陣列以選定一個或具有一定寬度的複 數個奈米碳管;(b)以一定速度拉伸該選定的奈米碳管 ,從而形成首尾相連的複數個奈米碳管片段,進而形成 一連續的奈米碳管拉膜。該拉取方向沿基本垂直於奈米 碳管陣列的生長方向。 [0028] 在上述拉伸過程中,該複數個奈米碳管片段在拉力作用 下沿拉伸方向逐漸剝離生長基底的同時,由於該複數個 奈米碳管片段之間凡得瓦力的作用,該選定的複數個奈 米碳管片段分別與其他奈米碳管片段首尾相連地連續地 被拉出,從而形成一連續、均勻且具有一定寬度的奈米 碳管拉膜。所述奈米碳管拉膜中的奈米碳管包括單壁奈 米碳管、雙壁奈米碳管及多壁奈米碳管中的一種或多種 。該奈米碳管拉膜具有較大的比表面積,故該奈米碳管 拉膜宏觀上表現出較大的黏性。 [0029] 步驟S103,將所述奈米碳管膜狀結構直接設置於所述奈 米碳管膜承載結構的複數個凸起結構,所述奈米碳管膜 狀結構與所述複數個凸起結構形成點接觸或線接觸,所 述奈米碳管膜狀結構與所述奈米碳管膜承載結構的有效 接觸面積小於所述奈米碳管膜狀結構本身面積的20%。 [0030] 請參照圖7及圖8,將所述奈米碳管膜狀結構120設置於所 述奈米碳管膜承載結構100的複數個凸起結構116,該奈 米碳管膜狀結構120通過所述奈米碳管膜承載區域114中 的複數個凸起結構116部分懸空設置。 [0031] 可以理解,由於所述基底110表面112具有均勻分佈且間 099137722 表單編號A0101 第12頁/共28頁 0992065766-0 201219295 隔設置的複數個凸起結構116,因此,將所述奈米碳管膜 狀結構120設置在所述複數個凸起結構116時,該奈米碳 管膜狀結構120與所述複數個凸起結構116形成點接觸或 線接觸’從而使該条米碳營膜狀結構120與所述奈米碳管 膜承載結構100的有效接觸面積小於所述奈米碳管膜狀結 構120本身面積的20%,從而降低該奈米碳管膜狀結構 120與該奈米碳管膜承栽結構i⑽之_凡得瓦力,使該 奈米碳管膜狀結構120與該奈米碳管膜承栽結構剛之間 的凡得瓦力小於所述奈米碳管膜狀結構12〇中複數個奈米 〇 碳管之間凡得瓦力。爾此,將所迷奈米碳管膜狀結構120 設置於所述奈米碳管膜承栽結構j⑽時,由於所述奈米碳 管膜狀結構120與所述奈米後管膜承载結構i〇〇之間的凡 得瓦力小於所述奈米碳管膜狀結構12〇中複數個奈米碳管 之間的凡得瓦力,從而使該奈米碳管膜狀結構12〇可以容 易地從所述奈米碳管膜承栽結構10〇剝離,而不至於破壞 該奈米碳管膜狀結構120的形_構?旋而實現了該奈 米碳管膜狀結構120的保存和轉移。 〇 [0032] 本實施例中,將一奈米碳管拉膜設置於一 100#砂紙的表 面時,該奈米碳管拉膜的大部分結構通過所述100#砂纸 表面的複數個凸起結構懸空設置,該奈米碳管拉膜與所 述100#砂紙表面的複數個凸起結構形成點接觸,從而使 所述奈米碳管拉膜與所述100#砂紙的有效接觸面積小於 所述奈米碳管拉膜本身面積的20%,進而降低該奈米碳管 拉膜與該100#砂紙的表面之間的凡得瓦力’使該奈米碳 管拉膜與該100#砂紙的表面之間的凡得瓦力小於所述奈 099137722 表單編號A0101 第13頁/共28頁 0992065766-0 201219295 米碳管拉膜中複數個奈米碳管之間的凡得瓦力。因此, 將所述奈米碳管拉膜設置於所述100#砂紙的表面時,由 於所述奈米碳管拉膜與所述100#砂紙的表面之間的凡得 瓦力小於所述奈米碳管拉膜中複數個奈米碳管之間的凡 得瓦力,從而使該奈米碳管拉膜可以容易地從所述100# 砂紙的表面剝離,而不至於破壞該奈米碳管拉膜的形態 和結構,從而實現了該奈米碳管拉膜的保存和轉移。 [0033] 可以理解,當所述奈米碳管膜狀結構包括複數個奈米碳 管膜時,該複數個奈米碳管膜可以層疊設置或並排設置 於所述奈米碳管膜承載區域。具體地,將所述奈米碳管 膜設置於所述奈米碳管膜承載區域後,可以進一步將另 一奈米碳管膜覆蓋至先前的奈米碳管膜表面,如此反復 多次,在該奈米碳管膜承載區域上鋪設複數個奈米碳管 膜。此外,當所述奈米碳管膜承載區域具有較大的面積 時,將所述奈米碳管膜沿一個方向設置於所述奈米碳管 膜承載區域後,還可以將另一奈米碳管膜並排設置於所 述奈米碳管膜承載區域沒有鋪設奈米碳管膜的區域。可 以理解,該步驟為可選步驟。 [0034] 此外,將所述奈米碳管膜狀結構直接設置於所述奈米碳 管膜承載結構的奈米碳管膜承載區域後,可以進一步將 另一奈米碳管膜承載結構覆蓋在所述奈米碳管膜狀結構 的表面,並使所述另一奈米碳管膜承載結構中的奈米碳 管膜承載區域與所述奈米碳管膜狀結構相接觸,形成一 兩邊為奈米碳管膜承載結構,中間為奈米碳管膜的夾心 結構。在所述夾心結構中,所述奈米碳管膜狀結構挾持 099137722 表單編號A0101 第14頁/共28頁 0992065766-0 201219295 於兩個奈米碳管膜承栽結構的中間,使奈米碳營膜狀結 構位於兩個奈米碳管膳承載結構具有凸起結構的表面之 間,並分別與兩個奈米碳管膜承載結構具有凸起結構的 表面接觸,使所述奈米奴管膜狀結構可以更牢固地被固 定,從而使該奈米碳管膜狀結構可以更為容易的保存和 轉移。此外,該夾心結構還可以使所述奈米碳管骐狀結 構不受到破壞,以及具有防塵等作用。 [0035] Ο 本發明實施例提供的奈米碳管膜承載結構具有結構簡單 、成本較低等特點。該奈米碳管膜承載結構通過在一基 底的表面設置複數傭凸起結構’使得將一奈米碳管膜狀 結構設置於所述奈米碳管膜承載結構表面時’該奈米碳 管膜狀結構與所述凸起結構形成點接觸或線接觸,從而 大大地減少了所述奈米碳管膜狀結構與所述奈米碳管膜 承載結構的有效接觸面積,進而降低了所述奈米碳管犋 狀結構與所述奈米碳管膜承載結構之間的卞得瓦力,最 後實現奈米碳管膜狀結構的保存和轉移。 ❹ [_] 本發明實施例所述奈米碳管膜承載結構的使用方法,通 過將-奈米破管膜狀結構直接承載於—奈米碳管膜承栽 結構的複數個凸起結構,從而實現奈*碳管膜狀結構的 保存和轉移,該方法簡單易行。此外,將另一奈米碳管 膜承載結構覆蓋在所述承載於一奈米礙管媒承載結構中 的奈米碳管膜狀結構的表面,形成一兩側為奈米碳管臈 承載結構中間為奈米碳管膜狀结構的夹心結構。所述奈 米碳管膜狀結才冓狹躲兩個奈米破管膜承載結構的中間 ,使該奈来碳管麟結構更牢固地被固定。此外,該夾 099137722 表單編號Α0101 第15頁/共28頁 0992065766-0 201219295 心結構還可以使所述奈米碳管膜狀結構不受到外界作用 力的破壞’還具有防塵等作用。 [0037]综上所述,本發明確已符合發明專利之要件,遂依法提 出專利帽。惟’以上所述者僅為本發明之較佳實施例 ,自不能以此限制本案之申請專圍。舉凡習知本案 技藝之人純依本發明之精神所作之等效修飾或變化, 皆應涵蓋於以下申請專利範圍内。 【圖式簡單說明】 闕@1為本發明第-實施綱提供㈣米碳㈣承載結構 的示意圖。 _]圖2為本發明第二實劇所提供的奈Μ管膜承载結構 的示意圖。 [_圖3冑應用本發明實施例提供的奈米碳管膜承載結構承 載奈米碳官膜狀結構的流程圖。 [0041] 圖4為應用本發明實施例提併的奈米碳管膜承載結構承 載的奈米碳管拉膜的SEM照片《 [0042] 圖5為應用本發明實施例提供的奈米碳管膜承載結構承The assembly of nano-carbon tubes into a macro-scale structure is of great significance for the macroscopic application of carbon nanotubes. ―: , The macrostructure of the previous carbon nanotubes mainly consists of carbon nanotube membranes. However, the nanotubes and other nanotubes have a strong viscosity on the macroscopic surface. 'Once it touches other objects, it sticks and is difficult to separate', so it brings great difficulties in preserving and transferring the macrostructure of carbon nanotubes. Thus, nanocarbon tubes such as carbon nanotube membranes are further developed in the macroscopic field. application. And Structure [Summary of the Invention] [0004] In view of this, it is really necessary. Providing a kind of inlaid tube material like its use method [0005] 099137722 - "碜管骐承承结构, the structure, and the carbon nanotube, bearing-nano carbon tube film-like junction can be completely from The nano carbon (four) load-bearing structure is connected to the nano-carbon support, and the base has a base and a plurality of raised knots, a surface, the I form form number A010. The surface of the exhibition has a carbon nanotube film bearing region of a surface of the substrate, and a plurality of convex structures are disposed on the surface of the carbon nanotube film bearing region of the substrate surface, thereby When the carbon nanotube film structure is disposed on the plurality of convex structures in the carbon nanotube film bearing region, the carbon nanotube film structure forms a point contact with the plurality of convex structures Or the line contact, the effective contact area of the carbon nanotube film structure and the carbon nanotube film bearing structure is less than or equal to 20°/〇 of the area of the carbon nanotube film structure itself. Method of using a carbon nanotube membrane carrying structure, comprising: providing a carbon nanotube film bearing structure, the carbon nanotube film bearing structure comprising a substrate and a plurality of convex structures, the substrate having a surface having a carbon nanotube film bearing region, a plurality of raised structures disposed on the carbon nanotube film bearing region on the surface of the substrate; providing a carbon nanotube film structure; and directly placing the carbon nanotube film structure on the carbon nanotube a plurality of raised structures in the film-bearing structure, the carbon nanotube film-like structure forming point contact or line contact with the plurality of raised structures, the carbon nanotube film structure and the nano carbon The effective contact area of the tubular membrane supporting structure is less than 20% of the area of the carbon nanotube membrane structure itself. [0007] Compared with the prior art, the carbon nanotube membrane supporting structure has the characteristics of simple structure, etc. The carbon nanotube film bearing structure is formed by providing a plurality of convex structures on the surface of a substrate such that a carbon nanotube film structure is disposed on the surface of the carbon nanotube film bearing structure, the carbon nanotube film is formed Most of the structure of the structure The raised structure is suspended, thereby greatly reducing the effective contact area of the carbon nanotube film structure and the carbon nanotube film bearing structure, thereby reducing the carbon nanotube film structure 099137722 Form No. A0101 Page 4 / Total 28 Page 0992065766-0 201219295 [0008] [0009] [0010] ο 099137722 constituting the van der Waals between the carbon nanotube film carrying structure 'final realization of nanocarbon Preservation and transfer of the tubular membrane structure. The method of using the carbon nanotube membrane supporting structure is carried out by directly carrying a nanometer lime membrane film on the nano-tube membrane bearing area of a carbon nanotube membrane supporting structure. Therefore, the method for storing and transferring the carbon nanotube film structure is simple and easy. [Embodiment] Hereinafter, the present invention will be described in detail with reference to the accompanying drawings and specific embodiments. Referring to FIG. 1 , a first embodiment of the present invention provides a carbon nanotube film bearing structure 100 for carrying or protecting a carbon nanotube film structure, and the nano tube. The carbon nanotube film-like structure is completely peeled off from the carbon nanotube film-bearing structure 100 after being in contact with the carbon nanotube-supporting structure 100. The carbon nanotube film carrying structure 1 includes a substrate 110 and a plurality of raised structures 116, wherein the substrate 110 has a surface 112 on which a carbon nanotube film bearing region 114 is disposed. The plurality of raised structures Π6 are disposed in the carbon nanotube film bearing region 114. The plurality of raised structures U6 are used to carry a carbon nanotube-shaped structure. It is understood that a plurality of protrusions are disposed on the carbon nanotube film bearing region 114. The structure 116 is 'the carbon nanotube film structure is in point contact or line contact with the plurality of raised structures 116, so that the nano carbon camping structure and the carbon nanotube film bearing structure 100 The effective contact area is less than 20% of the area of the carbon nanotube film structure itself. The carbon nanotube film structure can be completely peeled off from the surface 112 of the carbon nanotube film bearing structure 100. Form No. 1010101 Page 5 of 28 0992065766-0 201219295 [0011] The substrate 110 is a sheet-like structure having a certain strength, and its shape and size can be designed according to actual needs. The material of the substrate 110 may be selected from a rigid material having a hardness or a certain strength. Specifically, the material of the substrate 110 is selected from the group consisting of metals, metal oxides, ceramics, resins, and the like. The substrate 110 has a surface 112. The surface 112 can be a flat surface, a curved surface, or other irregular surface. [0012] The carbon nanotube film bearing region 114 may be the entire surface 112 or a portion of the surface 112 of the substrate 110. The plurality of raised structures 116 are disposed at intervals in the carbon nanotube film bearing region 114. The material of the plurality of raised structures 116 is selected from the group consisting of metal oxides, metals, and inorganic salts. The plurality of raised structures 116 may be formed on the surface 112 of the substrate 110 by chemical or physical methods. The plurality of raised structures 11 6 may be a point-like convex structure, a linear convex structure or a combination of a dot-like convex structure and a linear convex structure. The shape of the point-like convex structure is a spherical shape, an ellipsoidal shape or other irregular shape, and since the volume of the point-like convex structure is small, it can be approximated as a spherical shape. The cross section of the linear projection structure may be triangular, square, rectangular, trapezoidal or the like. Preferably, the surface 112 of the substrate 110 is formed with a plurality of uniformly distributed and spaced apart dot-like convex structures, the shape of which is spherical and may be 1 micrometer to 1 mm in diameter, adjacent to each other. The spacing between the dot-like raised structures is from 10 micrometers to 10 millimeters. In addition, the plurality of raised structures 116 may also be combined with other different structures. It can be understood that when a carbon nanotube film structure is disposed on the plurality of convex structures 116 on the carbon nanotube film bearing region 114, the carbon nanotube film structure and the plurality of convex structures 11 6 forming a point contact or a line contact, 099137722 Form No. A0IO1 Page 6 / Total 28 page 0992065766-0 201219295 Thereby an effective contact area of the carbon nanotube film structure with the carbon nanotube film support structure 100 It is less than 20% of the area of the carbon nanotube film structure itself. Preferably, the effective contact area of the nano-tube-membrane structure with the nano-backed film-bearing structure 100 is less than or equal to 10% of the area of the carbon nanotube film-like structure itself. It will be understood that the plurality of raised structures 116 may also be integrally formed with the substrate 11A. [0013] In the present embodiment, the carbon nanotube film bearing structure 10 is a square 100# sandpaper having a side length of 10 cm. The surface of the 100# sandpaper is formed with a plurality of point-like structures which are evenly distributed and spaced apart, and the distance between the adjacent point-like convex structures is about 2 ο α μm. The diameter of the point-like convex structure is about - 仏," 15 〇 micron. It can be understood that the nano tube-breaking membrane bearing structure 1 can also be made of other plastic sandpaper, such as 5 (four) ~ 2 (10) 〇 #. [0014] Referring to FIG. 2, a second embodiment of the present invention provides a luxury rice carbon nanotube-supporting structure 200 for carrying or protecting a carbon nanotube film structure. And the carbon nanotube film structure can be completely peeled off from the carbon nanotube film bearing structure 200 after being in contact with the carbon nanotube film bearing and the structure 2〇〇. The carbon nanotube film carrying structure 200 comprises: a substrate 210 and a plurality of raised structures 216 'where the substrate 2 has a surface 212 ′. The surface 212 is provided with a carbon nanotube film bearing region 214 . The plurality of raised structures 216 are disposed in the carbon nanotube film bearing region 214. The plurality of raised structures 216 are used to carry a carbon nanotube film structure. It can be understood that a plurality of protrusions are disposed on the carbon nanotube film bearing region 214. In the structure 216, the carbon nanotube film structure forms a point contact or line contact with the plurality of raised structures 216, thereby making the carbon nanotube film structure and the 099137722 form number Α0101 page 7 / Total 28 pages 0992065766-0 201219295 The effective contact area of the carbon nanotube membrane bearing structure 200 is less than 2% of the area of the membrane structure of the carbon nanotube, and the nano-membrane structure can be intact. The surface 212 of the carbon nanotube film support structure 200 is peeled off. [0015] In this embodiment, the substrate 21 is a metal foil having a certain strength. The carbon nanotube film bearing region 214 is a portion of the surface of the foil. The carbon nanotube film bearing region 214 includes a plurality of linear projection structures 216. The plurality of linear projection structures 216 are evenly distributed and spaced apart from each other. The plurality of linear raised structures 216 can be formed on the surface 212 of the substrate 210 by chemical or physical methods. The plurality of linear raised structures 216 are triangular in cross section. The plurality of linear protrusion structures 216 may have a cross section width of 1 micrometer to 1 inch, and a distance between adjacent plurality of linear protrusion structures 216 of 10 micrometers to 1 millimeter. The plurality of linear protrusion structures 216 may have a height of 1 micrometer to 1 millimeter. Further, a plurality of linear protrusion structures 216 formed on the surface 212 of the substrate 210 may be disposed or intersected with each other; using a combination of other different structures. It can be understood that 'the carbon nanotube film structure is disposed on the carbon nanotube film bearing region 214 at the plurality of bulging protrusions; 216, the carbon nanotube film structure and the plurality of convex portions The structure 216 forms a line contact such that the effective contact area of the carbon nanotube film structure with the carbon nanotube film bearing structure 2 小于 is smaller than the area of the carbon nanotube film structure itself. %. Preferably, the effective contact area of the carbon nanotube film structure with the carbon nanotube support structure 200 is less than or equal to 10% of the area of the carbon nanotube film structure itself. Referring to FIG. 3, the present invention still further provides a method for carrying and preserving a film structure of a carbon nanotube film using the carbon nanotube film bearing structure 100. The 099137722 Form No. A0I01 Page 8 of 28 0992065766-0 [0016] 201219295 G [0017] [0020] The method mainly comprises the following steps: (S101) providing at least one nanocarbon tube load bearing structure, the carbon nanotube film bearing structure comprises a a substrate and a plurality of convex structures, the substrate having a surface having a carbon nanotube film bearing region, wherein the plurality of convex structures are disposed on a carbon nanotube film bearing region of the surface of the substrate; (S102) providing a carbon nanotube film-like structure; and (S103) providing the carbon nanotube film structure directly to the plurality of convex structures of the carbon nanotube film bearing structure, the nano The broken membrane-like structure forms a point contact or a line contact with the plurality of convex structures, and the effective contact area of the nano-tube-membrane structure and the carbon nanotube-supporting structure is smaller than the carbon nanotubes The membrane structure itself is 20% of the area. 'Small S101, providing at least one carbon nanotube film bearing structure, the nano tube breaking film bearing structure comprising a substrate and a plurality of convex structures, the substrate having a surface having a carbon nanotube The film bearing region, the plurality of convex structures are disposed on a carbon nanotube film bearing region of the surface of the substrate. The nano tube-breaking film carrying structure is the carbon nanotube film bearing structure 100 provided by the first embodiment of the present invention. It will be understood that the carbon nanotube film bearing structure may also be the carbon nanotube medium carrying structure 200 or other structure provided by the second embodiment of the present invention. Step S102, providing a carbon nanotube film structure. A carbon nanotube film structure 120 is provided, the carbon nanotube film structure 120 comprising at least one carbon nanotube film. The carbon nanotube film can be a carbon nanotube film, a carbon nanotube film or a carbon nanotube film. 099137722 Form No. A0101 Page 9 of 28 0992065766-0 201219295 [0021] Referring to FIG. 4, the carbon nanotube film is a unitary structure obtained by directly drawing from a carbon nanotube array. The carbon nanotube film is a self-supporting structure composed of a plurality of carbon nanotubes. The self-supporting structure means that the carbon nanotube film can be self-supported without substrate support. The plurality of carbon nanotubes extend in a preferred orientation along substantially the same direction. The preferred orientation means that the overall extension direction of most of the carbon nanotubes in the carbon nanotube film is substantially in the same direction. Moreover, the overall direction of extension of the majority of the carbon nanotubes is substantially parallel to the surface of the carbon nanotube film. Further, most of the carbon nanotubes in the carbon nanotube film are connected end to end by van der Waals and extend substantially in the same direction. The carbon nanotube film and the preparation method thereof are described in the Taiwan invention patent application publication specification of the TW 13271 77 filed on Feb. 12, 2010, which is hereby incorporated by reference. [0022] Referring to FIG. 5, the carbon nanotube rolled film comprises uniformly distributed carbon nanotubes, which are disorderly arranged in a preferred orientation in the same direction or in different directions. Preferably, the carbon nanotubes in the carbon nanotube rolled film extend substantially in the same direction and are parallel to the surface of the carbon nanotube rolled film. The carbon nanotubes in the carbon nanotube rolled film overlap each other. The carbon nanotubes in the carbon nanotube film are attracted to each other by van der Waals force, and the carbon nanotubes have good flexibility and can be bent and folded into any shape. Does not break. The carbon nanotube rolled film and the preparation method thereof are disclosed in the Taiwan Patent Application Publication No. TW200 90 0348, which is published on Jan. 1, 2009. [0023] Referring to FIG. 6, the carbon nanotube flocculation membrane comprises intertwined carbon nanotubes. The carbon nanotubes are mutually attracted and entangled by van der Waals force. Form 099137722 Form No. A0101 Page 10 of 28 0992065766-0 201219295 [0024] A network structure. The carbon nanotube flocculation membrane is isotropic. The carbon nanotubes in the carbon nanotube flocculation membrane are uniformly distributed and arranged irregularly. The carbon nanotube flocculation film and the preparation method thereof are described in the Taiwan Patent Application Publication No. TW200844041, which is published on Nov. 16, 2008. In this embodiment, the carbon nanotube film structure 120 is a carbon nanotube film, and the carbon nanotube film is directly drawn from a carbon nanotube array, and the preparation method thereof is specific. The following steps are included: Ο Chen Wei First, an array of carbon nanotubes formed on a growth substrate is provided, which is an array of super-aligned carbon nanotubes. [0026] The super-aligned carbon nanotube array is prepared by chemical vapor deposition, and the preparation method of the super-sequential carbon nanotube array can be referred to Taiwan Patent Publication No. TW 1303239. The super-aligned carbon nanotube array is a plurality of pure carbon nanotube arrays formed of carbon nanotubes that are parallel to each other and grown perpendicular to the growth substrate. By controlling the growth conditions, the super-aligned carbon nanotube array contains substantially no impurities, such as amorphous carbon or residual catalyst metal particles, and is suitable for pulling a carbon nanotube film therefrom. The carbon nanotube array provided by the embodiment of the present invention is a multi-walled carbon nanotube array. The carbon nanotubes have a diameter of 0.5 to 50 nm and a length of 50 nm to 5 mm. In this embodiment, the length of the carbon nanotubes is preferably from 100 μm to 900 μm. [0027] Next, a carbon nanotube film is obtained by pulling a carbon nanotube from the carbon nanotube array by using a stretching tool, which specifically includes the following steps: (a) from the super-shunned nano tube One of the carbon tube arrays is selected or a plurality of carbon nanotubes having a certain width. In this embodiment, it is preferred to use 099137722 having a certain width. Form No. A0101 Page 11 / Total 28 Page 0992065766-0 201219295 Tape Contact Nanotube Array Selecting one or a plurality of carbon nanotubes having a certain width; (b) stretching the selected carbon nanotubes at a certain speed to form a plurality of carbon nanotube segments connected end to end, thereby forming a continuous nai The carbon tube is pulled. The pull direction is substantially perpendicular to the growth direction of the carbon nanotube array. [0028] During the above stretching process, the plurality of carbon nanotube segments gradually peel off the growth substrate in the stretching direction under the action of tension, and the effect of the vanadium force between the plurality of carbon nanotube segments The selected plurality of carbon nanotube segments are continuously pulled out end to end with the other carbon nanotube segments, thereby forming a continuous, uniform and a certain width of the carbon nanotube film. The carbon nanotubes in the carbon nanotube film include one or more of a single-walled carbon nanotube, a double-walled carbon nanotube, and a multi-walled carbon nanotube. The carbon nanotube film has a large specific surface area, so that the carbon nanotube film exhibits a large viscosity on a macroscopic basis. [0029] Step S103, the film structure of the carbon nanotubes is directly disposed on a plurality of convex structures of the carbon nanotube film bearing structure, the carbon nanotube film structure and the plurality of convex structures The structure forms a point contact or a line contact, and the effective contact area of the carbon nanotube film structure with the carbon nanotube film bearing structure is less than 20% of the area of the carbon nanotube film structure itself. [0030] Referring to FIG. 7 and FIG. 8, the carbon nanotube film structure 120 is disposed on the plurality of convex structures 116 of the carbon nanotube film supporting structure 100, and the carbon nanotube film structure is formed. 120 is partially suspended by the plurality of raised structures 116 in the carbon nanotube film bearing region 114. [0031] It can be understood that since the surface 112 of the substrate 110 has a uniform distribution and a plurality of raised structures 116 are provided in the form of a number of 099137722, the form number A0101, the second page, the total number of the raised structures 116, When the carbon tube film structure 120 is disposed on the plurality of protrusion structures 116, the carbon nanotube film structure 120 forms a point contact or a line contact with the plurality of protrusion structures 116, thereby making the strip carbon camp The effective contact area of the film structure 120 with the carbon nanotube film support structure 100 is less than 20% of the area of the carbon nanotube film structure 120 itself, thereby reducing the carbon nanotube film structure 120 and the nai The carbon nanotube film bearing structure i (10) _ van der Waals force, so that the van der Waals force between the carbon nanotube film structure 120 and the carbon nanotube film bearing structure is smaller than the carbon nanotube film In the structure 12, there are a number of nano-carbon tubes between the carbon nanotubes. Here, when the carbon nanotube film structure 120 is disposed on the carbon nanotube film bearing structure j (10), the carbon nanotube film structure 120 and the nano back film bearing structure are The van der Waals force between the 〇〇 小于 is smaller than the van der Waals force between the plurality of carbon nanotubes in the 12 carbon nanotube film structure, so that the carbon nanotube film structure can be 12 〇 The carbon nanotube film-like structure 120 is easily preserved by easily peeling off the carbon nanotube film-bearing structure 10〇 without destroying the shape of the carbon nanotube film-like structure 120. And transfer. [0032] In this embodiment, when a carbon nanotube film is placed on the surface of a 100# sandpaper, most of the structure of the carbon nanotube film passes through a plurality of protrusions on the surface of the 100# sandpaper. The structure is suspended, and the carbon nanotube film is in point contact with the plurality of convex structures on the surface of the 100# sandpaper, so that the effective contact area of the carbon nanotube film and the 100# sandpaper is smaller than 20% of the area of the carbon nanotube film itself, thereby reducing the van der Waals between the carbon nanotube film and the surface of the 100# sandpaper, so that the carbon nanotube film is pulled with the 100# sandpaper The van der Waals force between the surfaces is less than that of the Nai 099137722 Form No. A0101 Page 13 / Total 28 Page 0992065766-0 201219295 The carbon tube is pulled between the plurality of carbon tubes in the van der Waals. Therefore, when the carbon nanotube film is disposed on the surface of the 100# sandpaper, the van der Waals force between the carbon nanotube film and the surface of the 100# sandpaper is smaller than the The carbon nanotubes pull the van der Waals force between the plurality of carbon nanotubes, so that the carbon nanotube film can be easily peeled off from the surface of the 100# sandpaper without destroying the nanocarbon The shape and structure of the tube is pulled to realize the preservation and transfer of the carbon nanotube film. [0033] It can be understood that when the carbon nanotube film structure includes a plurality of carbon nanotube films, the plurality of carbon nanotube films may be stacked or arranged side by side in the carbon nanotube film bearing region. . Specifically, after the carbon nanotube film is disposed on the carbon nanotube film bearing region, another carbon nanotube film may be further covered to the surface of the previous carbon nanotube film, and thus repeated, A plurality of carbon nanotube films are laid on the carbon nanotube film bearing region. In addition, when the carbon nanotube film bearing region has a large area, after the carbon nanotube film is disposed in one direction on the carbon nanotube film bearing region, another nanometer can be further The carbon tube membranes are arranged side by side in a region where the carbon nanotube film bearing region is not laid with a carbon nanotube film. It can be understood that this step is an optional step. [0034] In addition, after the carbon nanotube film structure is directly disposed on the carbon nanotube film bearing region of the carbon nanotube film bearing structure, another carbon nanotube film bearing structure may be further covered. Forming a carbon nanotube film bearing region in the other carbon nanotube film bearing structure on the surface of the carbon nanotube film structure and contacting the carbon nanotube film structure to form a The carbon nanotube membrane bearing structure on both sides and the sandwich structure of the carbon nanotube membrane in the middle. In the sandwich structure, the carbon nanotube film structure holds 099137722 Form No. A0101 Page 14 / 28 Page 0992065766-0 201219295 In the middle of two carbon nanotube film bearing structures, the nano carbon is made The membranous structure is located between the surfaces of the two nanocarbon tube-bearing structures having a convex structure, and is in contact with the surfaces of the two carbon nanotube film-bearing structures having convex structures, respectively, so that the nanotubes are The film structure can be more firmly fixed, so that the carbon nanotube film structure can be more easily preserved and transferred. Further, the sandwich structure can also prevent the braided structure of the carbon nanotube from being damaged, and has a function of dustproofing or the like. [0035] The carbon nanotube film carrying structure provided by the embodiment of the invention has the characteristics of simple structure, low cost and the like. The carbon nanotube film bearing structure is configured by placing a plurality of bulge structures on a surface of the substrate such that a carbon nanotube film structure is disposed on the surface of the carbon nanotube film bearing structure. The film-like structure forms a point contact or line contact with the convex structure, thereby greatly reducing the effective contact area of the carbon nanotube film structure and the carbon nanotube film bearing structure, thereby reducing the The carbon nanotubes between the carbon nanotube-shaped structure and the carbon nanotube film-bearing structure finally realize the preservation and transfer of the film structure of the carbon nanotubes. ❹ [_] The method for using the carbon nanotube film bearing structure according to the embodiment of the present invention, by directly carrying the film structure of the nano tube breaking film on the plurality of convex structures of the carbon nanotube film bearing structure, Thereby, the preservation and transfer of the film structure of the carbon nanotubes are realized, and the method is simple and easy. In addition, another carbon nanotube film bearing structure is covered on the surface of the carbon nanotube film-like structure carried in the nano-tube-damage medium-bearing structure to form a carbon nanotube-bearing structure on both sides. In the middle is a sandwich structure of a carbon nanotube film structure. The carbon nanotube film-like knot is narrowed to the middle of the two nano-damage film-bearing structures, so that the Nylon carbon tube structure is more firmly fixed. In addition, the clip 099137722 Form No. Α0101 Page 15 of 28 0992065766-0 201219295 The core structure can also prevent the membrane structure of the carbon nanotube from being damaged by external forces. [0037] In summary, the present invention has indeed met the requirements of the invention patent, and the patent cap is proposed according to law. However, the above description is only a preferred embodiment of the present invention, and it is not possible to limit the application scope of the present invention. Equivalent modifications or variations made by those skilled in the art in light of the spirit of the invention are intended to be included within the scope of the following claims. [Simple description of the drawing] 阙@1 is a schematic diagram of the (four) meter carbon (four) bearing structure provided for the first embodiment of the present invention. Fig. 2 is a schematic view showing the bearing structure of the naphthalene film provided by the second actual drama of the present invention. [Fig. 3] A flow chart of applying a carbon nanotube film-bearing structure provided by an embodiment of the present invention to a nano-carbon film structure. 4 is a SEM photograph of a carbon nanotube film carried by a carbon nanotube film carrying structure according to an embodiment of the present invention. [0042] FIG. 5 is a carbon nanotube provided by an embodiment of the present invention. Membrane bearing structure

載的奈米碳管碾壓膜的SEM照片。 DSEM photograph of the loaded carbon nanotube film. D

[0043] 圖6為應用本發明實施提供的奈米碳管祺承載結 的奈米碳管絮化膜的SEM照片。 [0044] 圖7為應用本發明實施例提供的奈 載一奈米碳管膜狀結構的示意圖。 米碳管膜承載結構承 [0045] 圖8為應用本發明實施例提供的奈 099137722 表單編號A0101 第16頁/共28頁 米璀營膜承載結構承 201219295 載一奈米碳管膜狀結構的侧視圖。 【主要元件符號說明】 [0046] 奈米碳管膜承載結構: 100 ,200 [0047] 基底:110,210 [0048] 表面:112,212 [0049] 奈来碳管膜承載區域: 114 ,214 [0050] 凸起結構:116,216 [0051] 奈米碳管膜狀結構:120 〇 099137722 表單編號A0101 第17頁/共28頁 0992065766-06 is a SEM photograph of a carbon nanotube flocculating membrane of a carbon nanotube-supported junction provided by the practice of the present invention. 7 is a schematic view showing a film-like structure of a nanotube with a carbon nanotube provided by an embodiment of the present invention. Rice carbon nanotube film bearing structure [0045] FIG. 8 is a view showing the application of the embodiment of the present invention to the 099137722 form number A0101 page 16 / 28 page rice glutinous film bearing structure bearing 201219295 carrying a carbon nanotube film structure Side view. [Main component symbol description] [0046] Nano carbon nanotube film bearing structure: 100,200 [0047] Substrate: 110, 210 [0048] Surface: 112, 212 [0049] Naibel carbon film bearing area: 114, 214 [0050] Raised structure: 116, 216 [0051] Carbon nanotube film structure: 120 〇 099137722 Form No. A0101 Page 17 / 28 pages 0992065766-0

Claims (1)

201219295 七、申請專利範圍: 1 . 一種奈米碳管膜承載結構,用於承載一奈米碳管膜狀結構 ,且該奈米碳管膜狀結構與該奈米碳管膜承載結構接觸後 可以完整地從該奈米碳管膜承載結構脫離,其改良在於, 該奈米碳管膜承載結構包括:一基底以及複數個凸起結構 ,其中,所述基底具有一表面,所述基底的表面具有一奈 米碳管膜承載區域,所述複數個凸起結構設置在所述基底 表面的奈米碳管膜承載區域,從而使得將一奈米碳管膜狀 結構設置於所述奈米碳管膜承載區域上的複數個凸起結構 時,所述奈米碳管膜狀結構與所述複數個凸起結構形成點 接觸或線接觸,所述奈米碳管膜狀結構與所述奈米碳管膜 承載結構的有效接觸面積小於等於所述奈米碳管膜狀結構 本身面積的20%。 2.如申請專利範圍第1項所述的奈米碳管膜承載結構,其中 ,所述基底的表面為平面或曲面。 3 .如申請專利範圍第1項所述的奈米碳管膜承載結構,其中 ,所述奈米碳管膜狀結構與所述奈米碳管膜承載結構的有 效接觸面積小於等於所述奈米碳管膜狀結構本身面積的 10% ° 4 .如申請專利範圍第1項所述的奈米碳管膜承載結構,其中 ,所述凸起結構為複數個均勻分佈且間隔設置的點狀凸起 結構,該點狀凸起結構的直徑為1微米至1毫米,相鄰的凸 起結構的間距為10微米至10毫米。 5 .如申請專利範圍第1項所述的奈米碳管膜承載結構,其中 ,所述凸起結構為複數個相互平行且間隔設置的線狀凸起 099137722 表單編號A0101 第18頁/共28頁 0992065766-0 201219295 結構’ 6玄線狀凸起結構的寬度為1微米至100微米,相鄰 的線狀凸起結構的間距為10微米至1毫米。 如申晴專利範圍第1項所述的奈米碳管膜承載結構,其中 ,所述凸起結構與所述基底-體成型。 、 .如申请專利範圍第1項所述的奈米碳管膜承載結構,其中 ’所述凸起結構的材料選自金屬、金屬氧化物及無機鹽類 Ο A 8 Ο 9 ❹ 10 11 . 099137722 .如申请專利範圍第1項所述的奈米碳管膜承載結構,其中 ’所述奈米碳管膜承栽結構選自50#至2GGG#的砂紙。 .:種奈米碳管膜承___方法,其包括以下步驟: 提供至少-奈求碳管膜承載結構,所述奈米崎管膜承栽結 構包括-基底及複數個凸起結構,所述基底具有—表面、。 該表面具有-奈米碳管膜承載區域,所述複數個凸起結構 設置於所述基底表面的奈米碳管膜承載區域;提供一奈米 碳管膜狀結構;以及將所述奈米碳管膜狀結構直接設= 所述奈米碳管膜承載結構的複數個凸起結德,所述奈米碳 管膜狀結構與所述複數個凸起結構形成點接觸或線I觸, 所述奈米碳管膜狀結構與所述奈米碳管膜承載結構的有效 接觸面積小於所述奈米碳管膜狀結構本身面積的2〇%。 .如申請專利範圍第9項所述的奈米碳管膜承載結構的0使用 方法,其令,所述奈米碳管膜狀結構通過所述複數個凸起 結構部分懸空設置° 如申請專利範圍第9項所述的奈米碳管膜承載結構的使用 方法’其中’所述奈米碳管臈狀結構包括至少—奈米碳管 膜,該奈米碳管膜包括複數個奈米碳管,所述複數個夺米 礙管通過凡得瓦力首尾相連並^沿同—方向擇優取向^申 表單編號A0101 第19頁/共28頁 0992065766-0 201219295 12 .如申請專利範圍第11項所述的奈米碳管膜承載結構的使用 方法,其中,所述奈米碳管膜為由複數個奈米碳管組成的 一自支撐結構。 13 .如申請專利範圍第11項所述的奈米碳管膜承載結構的使用 方法,其中,所述奈米碳管膜為從一奈米碳_管陣列中拉取 獲得的一個整體結構。 14 .如申請專利範圍第9項所述的奈米碳管膜承載結構的使用 方法,其中,將所述奈米碳管膜狀結構直接設置於所述奈 米碳管膜承載結構的奈米碳管膜承載區域後,進一步包括 :將另一奈米碳管膜承載結構覆蓋於所述奈米碳管膜狀結 構表面,使奈米碳管膜狀結構位於兩個奈米碳管膜承載結 構具有凸起結構的表面之間。 099137722 表單編號A0101 第20頁/共28頁 0992065766-0201219295 VII. Patent application scope: 1. A carbon nanotube film bearing structure for carrying a carbon nanotube film structure, and the carbon nanotube film structure is in contact with the carbon nanotube film bearing structure The nano carbon tube film carrying structure may be completely detached, the improvement being that the carbon nanotube film bearing structure comprises: a substrate and a plurality of convex structures, wherein the substrate has a surface, the substrate The surface has a carbon nanotube film bearing region, and the plurality of convex structures are disposed on the carbon nanotube film bearing region of the substrate surface, so that a carbon nanotube film structure is disposed on the nanometer The carbon nanotube film-like structure forms a point contact or line contact with the plurality of convex structures when the plurality of convex structures on the carbon nanotube film bearing region, the carbon nanotube film structure and the The effective contact area of the carbon nanotube film bearing structure is less than or equal to 20% of the area of the carbon nanotube film structure itself. 2. The carbon nanotube film-bearing structure according to claim 1, wherein the surface of the substrate is a flat surface or a curved surface. 3. The carbon nanotube film bearing structure according to claim 1, wherein the effective contact area of the carbon nanotube film structure and the carbon nanotube film bearing structure is less than or equal to the nai The carbon nanotube film-bearing structure according to the first aspect of the invention, wherein the convex structure is a plurality of uniformly distributed and spaced dots. The raised structure has a diameter of 1 micrometer to 1 millimeter and an adjacent convex structure having a pitch of 10 micrometers to 10 millimeters. 5. The carbon nanotube film-bearing structure according to claim 1, wherein the convex structure is a plurality of linear protrusions which are parallel to each other and spaced apart. 099137722 Form No. A0101 Page 18 of 28 Page 0992065766-0 201219295 Structure '6 Mysterious raised structures have a width of 1 micron to 100 microns, and adjacent linear raised structures have a pitch of 10 microns to 1 mm. The carbon nanotube film bearing structure according to claim 1, wherein the convex structure is formed with the base body. The carbon nanotube film-bearing structure according to claim 1, wherein the material of the convex structure is selected from the group consisting of metals, metal oxides and inorganic salts Ο A 8 Ο 9 ❹ 10 11 . 099137722 The carbon nanotube film bearing structure according to claim 1, wherein the carbon nanotube film bearing structure is selected from the group consisting of 50# to 2GGG# sandpaper. a method for seeding a carbon nanotube membrane ___, comprising the steps of: providing at least a carbon nanotube membrane bearing structure, wherein the nanosoil tubular membrane bearing structure comprises a substrate and a plurality of convex structures, The substrate has a surface. The surface has a carbon nanotube film bearing region, the plurality of convex structures are disposed on a carbon nanotube film bearing region of the substrate surface; providing a carbon nanotube film structure; and the nano The carbon tube film structure is directly set to a plurality of convex knots of the carbon nanotube film bearing structure, and the carbon nanotube film structure forms a point contact or a line I contact with the plurality of convex structures. The effective contact area of the carbon nanotube film structure with the carbon nanotube film bearing structure is less than 2% of the area of the carbon nanotube film structure itself. The method for using the carbon nanotube film-bearing structure according to claim 9 , wherein the carbon nanotube film structure is suspended by the plurality of convex structures. The method for using a carbon nanotube film-bearing structure according to Item 9 wherein the carbon nanotube-shaped structure comprises at least a carbon nanotube film, the carbon nanotube film comprising a plurality of nanocarbons In the tube, the plurality of obscured pipes are connected end to end by van der Waals and are preferred along the same direction. Form No. A0101 Page 19 / 28 pages 0992065766-0 201219295 12 . The method for using a carbon nanotube film bearing structure, wherein the carbon nanotube film is a self-supporting structure composed of a plurality of carbon nanotubes. 13. The method of using a carbon nanotube film-bearing structure according to claim 11, wherein the carbon nanotube film is a unitary structure obtained by pulling from a nanocarbon-tube array. 14. The method of using a carbon nanotube film-bearing structure according to claim 9, wherein the carbon nanotube film-like structure is directly disposed on the nano-carbon nanotube film-bearing structure of the nanometer After the carbon nanotube film bearing region, the method further comprises: covering another carbon nanotube film bearing structure on the surface of the carbon nanotube film structure, so that the carbon nanotube film structure is located on the two carbon nanotube film bearing The structure has a surface between the raised structures. 099137722 Form No. A0101 Page 20 of 28 0992065766-0
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