TW201124196A - Organic waste gas purification system and method capable of preventing from surface condensation and agglomeration of the absorption material. - Google Patents

Organic waste gas purification system and method capable of preventing from surface condensation and agglomeration of the absorption material. Download PDF

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TW201124196A
TW201124196A TW100105347A TW100105347A TW201124196A TW 201124196 A TW201124196 A TW 201124196A TW 100105347 A TW100105347 A TW 100105347A TW 100105347 A TW100105347 A TW 100105347A TW 201124196 A TW201124196 A TW 201124196A
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organic waste
waste gas
tower
desorption
agglomeration
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TW100105347A
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TWI377088B (en
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feng-tang Zhang
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Jg Environmental Tech Co Ltd
feng-tang Zhang
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  • Treating Waste Gases (AREA)
  • Separation Of Gases By Adsorption (AREA)

Abstract

The invention relates to a kind of organic waste gas purification system capable of preventing from surface condensation and agglomeration of the absorption material, which includes: an absorption tower, which is divided internally into a plurality of layers via porous boards, so that the dropping absorption material from the top end forms a floating layer on the porous board and drops down into the storage tank along layers of the mouths; a desorption tower, the absorption material dropping from the top end drops again into the desorption heating portion via the overflow portion so that the desorption gas is guided into the bottom to contact with the absorption material, therefore, the absorbed organic gas in the absorption material is shed, then the absorption material that is shed is cooled in the cooling portion and drops into the storage tank portion; a delivery device, the absorption material dropping into the absorption storage tank portion is delivered to top end of the desorption tower, but the absorption material dropping into the desorption storage tank portion is delivered to top end of the absorption tower; and a absorption material pre-heating device, which is disposed on the top of the desorption heating portion of the desorption tower. Thereby, it has the effect of preventing from surface condensation and agglomeration of the absorption material in the desorption tower.

Description

201124196 六、發明說明: 【發明所屬之技術領域】 本發月係有關-種預防吸附材表面凝結與結塊之有機 廢氣淨化系統及方法’尤指—種於進行脫附程序之前增加 一將吸附材預熱或/及將有機廢氣預熱之預熱程序之設計 者。 【先前技術】 按,利用高孔隙率、高比表面積之吸附材,藉由吸附 作用去除揮發性有機氣體(Vo丨at i丨e 〇rgan i c c〇rap〇unds, VOCs)之吸附淨化技術,如第一圖所示之流體化浮動床淨 化系統,乃為一種常見之有機廢氣淨化系統,其以廢氣風 機(14)自有機廢氣入口(13)送入吸附塔的底部’而有 機廢氣藉氣流分散板(12)分散後,乃與由上落下的吸附材 (30)接觸,即可成為淨化氣體並從塔頂之淨化氣體出口(15) 排放;其中,吸附塔(10)的内部以多孔板(11)分隔成數層, 吸附材(30)由吸附塔(1〇)的頂端落下,而在多孔板〇1)的 上方形成浮動層’並沿著多孔板(11) 一層一層的開口側落 下,當吸附材(30)與含有有機廢氣接觸時,將廢氣中的有 機氣體吸附於吸附材(3 0)的孔洞内,廢氣即變成淨化氣體 排放;然而,吸附飽和的吸附材(3〇)落至吸附塔(1〇)底部 的貯槽(16)後,藉輸送裝置(20)送至後續之脫附塔(4〇)頂 端’進行脫附再生工作後送回吸附塔(1〇)之頂端。 然後’待再生之吸附材(30)乃在脫附塔(40)慢慢往下 流動’該脫附塔(40)包括有:溢流部(41 )、脫附加熱部 201124196 (43) 、冷卻部(44)以及一貯槽部(45);於是,自頂端落下 之吸附材(30)經溢流部(41)再落至脫附加熱部(43),而由 底部導入脫附氣體與吸附材(3〇)接觸,將吸附材(3〇)中所 吸附之有機氣體脫附’脫附出來的高濃度有機氣體被導引 至冷凝塔(50)冷凝回收’脫附後之吸附材則於冷卻部 (44) 冷卻後落至貯槽部(45)。 再按,尚可能於該溢流部(41)與該脫附加熱部(43)之 間s又置有脫附氣體純化部(4 2 )’而導引冷凝後之低溫脫附 氣體於此純化(吸附殘餘之有機氣體)後,再循環回到該脫 _ 附塔()底部;因此,剛由該脫附加熱部(43)所脫附出來 的有機氣體,在該脫附加熱部(43)頂緣處就會接觸到準備 進行純化之低溫脫附氣體,高濃度有機氣體乃極易凝結, 進一步致使吸附材(30)結塊堵塞,而影響吸附材(3〇)流動 輸送順暢’造成氣流集中而破壞脫附之均勻性,致使脫附 塔(40)内氣流超過流體化速度(Fluidized Velocity),甚 至超過流體化吹出速度(Terminal Fluidized Velocity)而 衍生吹碳現象,進而可能產生脫附不完全、空塔與相關部 • 件堵塞情形。 此外’縱使未於该溢流部(41)與該脫附加熱部(4 3 )之 間設置有脫附氣體純化部(42);倘若,由該脫附加熱部(;43) 所脫附出來的有機氣體濃度越高,則其達凝結(蒸氣相變化 為液相之冷凝現象;Condensing)的飽和溫度亦越高,同樣 容易造成上述之吸附材表面凝結而進一步結塊問題;然 而’在天候寒冷之操作環境中,亦可能有吸附材表面凝結 而進一步結塊之問題。 201124196 【發明内容】 本發明之主要目的,係欲解決先前技術之脫附塔脫附 加熱部會有高濃度有機氣體凝結與吸附材結塊之問題,而 具有預防吸附材表面凝結與結塊之功效。 本發明之另一目的,則具有預防脫附不完全、空塔與 相關部件堵塞情形。 為達上述功效,本發明之預防吸附材表面凝結與結塊 之有機廢氣淨化系統第一實施例之結構特徵,係包括有: 鲁 一吸附塔,底部设置有機廢氣入口,頂部設置淨化氣 體出口,内部以多孔板分隔成數層,讓由頂端落下之吸附 材在多孔板上方形成浮動層,並沿著多孔板一層一層的開 口側落至貯槽,而將廢氣中的有機氣體吸附於吸附材的孔 洞内; 一脫附塔,讓自頂端落下之吸附材經溢流部再落至脫 附加熱部’而由底部導入脫附氣體與吸附材接觸,將吸附 材中所吸附之有機氣體脫附,脫附出來的高濃度有機氣體 φ 被導引至冷凝塔冷凝回收,脫附後之吸附材則於冷卻部冷 卻後落至貯槽部; 一輸送裝置,將落至該吸附塔貯槽之吸附材輸送至該 脫附塔頂端,且將落至該脫附塔貯槽部之吸附材輸送至該 吸附塔頂端;以及 一吸附材預熱裝置,設置於該脫附塔之脫附加熱部上 游者。 此外’進一步於該吸附塔之有機廢氣入口上游端設置 201124196 一有機廢氣預熱裝置。另,進一步於該有機廢氣預熱裝置 之上游端設置一預冷凝裝置。又,進一步令該吸附材預熱 裝置之熱源與該冷凝塔或/及該預冷凝裝置之冷源藉由熱 泵予以連結。再者,進一步令該有機廢氣預熱裝置之熱源 與該冷凝塔或/及該預冷凝裝置之冷源藉由熱泵予以連結。 另者,本發明之預防吸附材表面凝結與結塊之有機廢 氣淨化系統第二實施例之結構特徵,係包括有: 一吸附塔,底部設置有機廢氣入口,頂部設置淨化氣 φ 體出口,内部以多孔板分隔成數層,讓由頂端落下之吸附 材在多孔板上方形成浮動層,並沿著多孔板一層一層的開 口側落至貯槽’而將廢氣中的有機氣體吸附於吸附材的孔 洞内; 一脫附塔,讓自頂端落下之吸附材經溢流部再落至脫 附加熱部,而由底部導入脫附氣體與吸附材接觸,將吸附 材中所吸附之有機氣體脫附,脫附出來的高濃度有機氣體 被導引至冷凝塔冷凝回收,脫附後之吸附材則於冷卻後落 Φ 至貯槽部; 一輸送裝置,將落至該吸附塔貯槽之吸附材輸送至該 脫附塔頂端’且將落至該脫附塔貯槽部之吸附材輸送至該 吸附塔頂端;以及 一有機廢氣預熱裝置,設置於該吸附塔之有機廢氣入 口上游端者。 接著’進一步於該有機廢氣預熱裝置之上游端設置一 預冷凝裝置。又,進一步令該有機廢氣預熱裝置之熱源與 201124196 該冷凝塔或/及該預冷凝裝置之冷源藉由熱栗予以連結。 然而,本發明之有機廢氣淨化系統預防吸附材表面凝 結與結塊之方法’係於進行脫附程序之前增加一預熱程序 者。其中’該預熱程序係將吸附材預熱或/及將有機廢氣 預熱。 【實施方式】 首先,請參閱第二圖所示,本發明預防吸附材表面凝 結與結塊之有機廢氣淨化系統之第一實施例係包括有: • 一吸附塔(10),底部設置有機廢氣入口(13),頂部設 置淨化氣體出口(15),内部以多孔板(11)分隔成數層,讓 由頂端落下之吸附材(30)在多孔板(11)上方形成浮動層, 並沿著多孔板(11)一層一層的開口側落至貯槽(16),而將 廢氣中的有機氣體吸附於吸附材(30)的孔洞内; 一脫附塔(40),讓自頂端落下之吸附材(30)經溢流部 (41)再落至脫附加熱部(43),而由底部導入脫附氣體與吸 附材(30)接觸’將吸附材(3〇)中所吸附之有機氣體脫附, • 脫附出來的有機氣體被導引至冷凝塔(50)冷凝回收,脫附 後之吸附材(30)則於冷卻部(44)冷卻後落至貯槽部(45); 一輸送裝置(20),將落至該吸附塔(10)貯槽(16)之吸 附材(30)輸送至該脫附塔(4〇)頂端,且將落至該脫附塔(4〇) 貯槽部(45)之吸附材(30)輸送至該吸附塔(10)頂端;以及 一吸附材預熱裝置(60),設置於該脫附塔(40)之脫附 加熱部(43)上游者。 接著,請再參閱第三圖所示,本發明預防吸附材表面 201124196 凝結與結塊之有機廢氣淨化系統之第二實施例係包括有: 一吸附塔(10),底部設置有機廢氣入口(13),頂部設 置淨化氣體出口(15),内部以多孔板(11)分隔成數層,讓 由頂端落下之吸附材(30)在多孔板(11)上方形成浮動層, 並沿著多孔板(11) 一層一層的開口側落至貯槽(16 ),而將 廢氣中的有機氣體吸附於吸附材(30)的孔洞内; 一脫附塔(40),讓自頂端落下之吸附材(30)經溢流部 (41)再落至脫附加熱部(43),而由底部導入脫附氣體與吸 附材(30)接觸,將吸附材(30)中所吸附之有機氣體脫附, 脫附出來的有機氣體被導引至冷凝塔(50)冷凝回收,脫附 後之吸附材(30)則於冷卻部(44)冷卻後落至貯槽部(45); 一輸送裝置(20),將落至該吸附塔(10)貯槽(16)之吸 附材(30)輸送至該脫附塔(40)頂端,且將落至該脫附塔(40) 貯槽部(45)之吸附材(30)輸送至該吸附塔(10)頂端;以及 一有機廢氣預熱裝置(70),設置於該吸附塔(1〇)之有 機廢氣入口(13)上游端者。 再者,該吸附材預熱裝置(60)與該有機廢氣預熱裝置 (70)可同時設置。此外,進一步於該有機廢氣預熱裝置(7〇) 之上游端設置一預冷凝裝置(80),可進一步針對較高沸點 的有機氣體予以預先冷凝回收,以降低進入該吸附塔(1〇) 之有機廢氨的濃度。又,進一步令該吸附材預熱裝置(6〇) 或/及該有機廢氣預熱裝置(7〇)之熱源與該冷凝塔(5〇)或/ 及該預冷凝裝置(80)之冷源藉由熱泵(90)予以連結。 基於如是之構成,若進入該吸附塔(10)之有機廢氣風 201124196 量為 350NCMM (包括有 200ppmv 之 DMF、500ppmv 之 T0L 與 500ppmv之MEK),而進入該脫附塔(40)之脫附氣體循環風 量為90Nm3/hr,該脫附塔(40)之脫附濃縮倍率則為233倍 (350*60/90);因此,自該脫附加熱部(43)脫附出來的DMF 濃度為200*233ppmv(飽和溫度約為63.5°C)、T0L濃度為 500*233ppmv(飽和溫度約為49.2°C)與MEK濃度為 500*233ppmv(飽和溫度約為23. 5°C );若吸附材(30)的溫度 低於上述各成份之飽和溫度,將致使該成份於該吸附材(30) 的表面產生凝結現象。 • 是以,利用該吸附材預熱裝置(60)對即將進入該脫附 加熱部(43)之吸附材(30)加熱(可控制在約略65°C ;也就是 說必須大於上述DMF的飽和溫度63. 5°C以上方可預防DMF 凝結),即可避免脫附出來的高濃度有機氣體(以上述實施 例來說,尤其是DMF)遇到低溫之吸附材(30)而凝結,乃具 有預防吸附材表面凝結與結塊之功效。再者,若無前述因 脫附濃縮倍率高而脫附出高濃度有機氣體之情事,但有設 置脫附氣體純化部(42)於該溢流部(41)與該脫附加熱部 φ (43)之間,亦可利用該吸附材預熱裝置(60)對即將進入該 脫附加熱部(43)之吸附材(30)加熱,避免脫附出來的有機 氣體遇到低溫之吸附材(30)而凝結,遂具有預防吸附材表 面凝結與結塊之功效。然而,若是在天候寒冷之操作環境 中進行有機氣體之淨化工作,可利用該吸附材預熱裝置(60) 對即將進入該脫附加熱部(43)之吸附材(30)加熱,避免脫 附出來的有機氣體遇到低溫之吸附材(30)而凝結;或是利 用該有機廢氣預熱裝置(70)對即將進入該吸附塔(10)之有 201124196 機廢氣加熱,致使輸送至該脫附塔(40)之吸附材(30)升 溫,避免脫附出來的有機氣體遇到低溫之吸附材(30)而凝 結,皆具有預防吸附材表面凝結與結塊之功效;並具有預 防脫附不完全、空塔與相關部件堵塞情形。 綜上所述’本發明所揭示之技術手段,確具「新穎性」、 進步性」及「可供產業利用」等發明專利要件,祈請鈞 局惠賜專利,以勵發明,無任德感。 惟’上述所揭露之圖式、說明,僅為本發明之較佳實 _ ’大凡熟悉此項技藝人士’依本案精神料所作之修 • ㈣等效變化,仍應包括本案申請專利範圍内。 201124196 【圖式簡單說明】 第一圖係習知有機廢氣淨化系統之結構說明圖。 第二圖係本發明第一實施例之結構說明圖。 第三圖係本發明第二實施例之結構說明圖。201124196 VI. Description of the invention: [Technical field to which the invention pertains] The present invention relates to an organic exhaust gas purification system and method for preventing condensation and agglomeration on the surface of an adsorbent material, in particular, adding an adsorption before the desorption procedure is performed. The designer of the preheating or/and preheating process to preheat the organic waste gas. [Prior Art] According to the adsorption and purification technology of volatile organic gases (Vo丨at i丨e 〇rgan icc〇rap〇unds, VOCs) by high-porosity, high specific surface area adsorption materials, such as The fluidized floating bed purification system shown in the first figure is a common organic waste gas purification system, which is sent from the organic waste gas inlet (13) to the bottom of the adsorption tower by the exhaust gas fan (14) and the organic exhaust gas is dispersed by the gas flow. After the plate (12) is dispersed, it is contacted with the adsorbing material (30) dropped from above, and can be purified gas and discharged from the purification gas outlet (15) at the top of the column; wherein the inside of the adsorption tower (10) is a perforated plate (11) Separated into several layers, the adsorbent material (30) is dropped from the tip end of the adsorption tower (1〇), and a floating layer ' is formed above the perforated plate crucible 1) and falls down along the open side of the perforated plate (11) When the adsorbent material (30) is in contact with the organic exhaust gas, the organic gas in the exhaust gas is adsorbed into the pores of the adsorbent material (30), and the exhaust gas becomes a purge gas discharge; however, the adsorbed saturated adsorbent material (3〇) Fall to the adsorption tower (1〇) After the tank (16) portion, by conveying means (20) is sent to the subsequent desorption column (4〇) top end 'desorption regeneration operation back to the adsorption column (1〇) of the top. Then, the adsorbent material (30) to be regenerated is slowly flowed down in the desorption column (40). The desorption column (40) includes an overflow portion (41) and an additional heat portion 201124196 (43). a cooling portion (44) and a sump portion (45); then, the adsorbing material (30) falling from the top end falls to the de-heating portion (43) through the overflow portion (41), and the desorbing gas is introduced from the bottom portion. When the adsorbent material (3〇) contacts, the organic gas adsorbed in the adsorbent material (3〇) is desorbed, and the high-concentration organic gas desorbed is guided to the condensation tower (50) to be condensed and recovered. Then, after the cooling unit (44) is cooled, it falls to the sump portion (45). Further, it is still possible to provide a desorption gas purifying portion (42) between the overflow portion (41) and the de-heating portion (43) to guide the condensed low-temperature desorbing gas. After purification (adsorption of residual organic gas), it is recycled back to the bottom of the desorption tower (); therefore, the organic gas which has just been desorbed by the de-heating portion (43) is in the de-heating portion ( 43) At the top edge, it will be exposed to the low-temperature desorption gas ready for purification. The high concentration organic gas is very easy to coagulate, which further causes the adsorption material (30) to block and block, and affects the flow of the adsorption material (3〇). The concentration of the airflow is destroyed to destroy the uniformity of the desorption, so that the airflow in the desorption tower (40) exceeds the fluidized velocity (Velidized Velocity), and even exceeds the fluidized velocity (Terminal Fluidized Velocity), and the phenomenon of carbon blowing is derived, which may cause Incomplete, empty towers and related parts are blocked. Further, 'the desorption gas purifying portion (42) is disposed between the overflow portion (41) and the de-heating portion (43); if it is desorbed by the de-heating portion (;43) The higher the concentration of organic gas, the higher the saturation temperature of the condensation (the condensation of the vapor phase into the liquid phase; Condensing), which is also likely to cause the surface of the adsorbent to coagulate and further agglomerate; In the cold operating environment, there may also be problems in that the surface of the adsorbent material condenses and further agglomerates. 201124196 SUMMARY OF THE INVENTION The main object of the present invention is to solve the problem that the prior art desorption tower desorption hot portion has a high concentration of organic gas condensation and agglomeration of the adsorbent material, and has the function of preventing coagulation and agglomeration on the surface of the adsorbent material. efficacy. Another object of the present invention is to prevent incomplete desorption, clogging of empty towers and related components. In order to achieve the above effects, the structural features of the first embodiment of the organic waste gas purification system for preventing condensation and agglomeration of the surface of the adsorbent material of the present invention include: a Lu adsorption tower, an organic waste gas inlet at the bottom, and a purge gas outlet at the top. The inside is divided into several layers by a perforated plate, and the adsorbent material dropped from the top end forms a floating layer above the perforated plate, and falls along the opening side of the perforated plate to the storage tank, and the organic gas in the exhaust gas is adsorbed to the pore of the adsorption material. a desorption tower, which allows the adsorbent material falling from the top to fall through the overflow portion to the de-heating portion, and the desorbed gas introduced into the bottom is contacted with the adsorbent material to desorb the organic gas adsorbed in the adsorbent material. The desorbed high-concentration organic gas φ is guided to the condensation tower for condensation recovery, and the desorbed adsorbent material is cooled to the sump portion after cooling in the cooling portion; and a conveying device transports the adsorbent material to the adsorption tower storage tank Up to the top of the desorption column, and transporting the adsorbent material falling to the desorption tower sump portion to the top of the adsorption tower; and an adsorbent preheating device disposed on the desorption The tower is removed from the hot section. Further, an organic waste gas preheating device is further provided at the upstream end of the organic waste gas inlet of the adsorption tower. Further, a precondensing device is further provided at the upstream end of the organic waste gas preheating device. Further, the heat source of the adsorbent preheating device and the cold source of the condensation tower or/and the precondenser are further connected by a heat pump. Further, the heat source of the organic waste gas preheating device and the cold source of the condensation tower or/and the precondenser are further connected by a heat pump. In addition, the structural features of the second embodiment of the organic waste gas purification system for preventing condensation and agglomeration on the surface of the adsorbent material of the present invention include: an adsorption tower, an organic waste gas inlet at the bottom, and a purification gas φ body outlet at the top, the interior The porous plate is divided into several layers, and the adsorbent material dropped from the top end forms a floating layer above the porous plate, and falls along the open side of the porous plate to the storage tank', and the organic gas in the exhaust gas is adsorbed into the pore of the adsorption material. a desorption tower, so that the adsorbent material dropped from the top falls to the de-heating portion through the overflow portion, and the desorbed gas introduced into the bottom is contacted with the adsorbent material to desorb the organic gas adsorbed in the adsorbent material, The attached high-concentration organic gas is led to the condensation tower for condensation recovery, and the desorbed adsorbent material is cooled to Φ to the sump portion; a conveying device transports the adsorbent material falling to the adsorption tower storage tank to the detachment Attaching to the top of the tower and transporting the adsorbent material falling to the sump portion of the desorption tower to the top of the adsorption tower; and an organic waste gas preheating device, the organic waste gas disposed in the adsorption tower By opening the upstream end. Next, a precondensing device is further disposed at the upstream end of the organic waste gas preheating device. Further, the heat source of the organic waste gas preheating device and the cold source of the condensing tower or/and the precondensing device of 201124196 are further connected by a hot pump. However, the method of the organic exhaust gas purifying system of the present invention for preventing condensation and agglomeration of the surface of the adsorbent is to add a preheating program before the desorption process. Wherein the preheating procedure preheats the adsorbent material and/or preheats the organic exhaust gas. [Embodiment] First, referring to the second figure, the first embodiment of the organic waste gas purification system for preventing condensation and agglomeration of the surface of the adsorbent material of the present invention includes: • an adsorption tower (10), and an organic waste gas is disposed at the bottom. The inlet (13) is provided with a purge gas outlet (15) at the top, and the inside is divided into a plurality of layers by a perforated plate (11), so that the adsorbent (30) dropped from the top forms a floating layer above the perforated plate (11), and is porous The open side of the plate (11) on one layer falls to the storage tank (16), and the organic gas in the exhaust gas is adsorbed into the pores of the adsorbent material (30); a desorption tower (40) allows the adsorbent material to fall from the top end ( 30) The overflow portion (41) is further dropped to the de-heating portion (43), and the desorption gas introduced into the bottom is brought into contact with the adsorbing material (30) to desorb the organic gas adsorbed in the adsorbing material (3〇) , the desorbed organic gas is led to the condensation tower (50) for condensation recovery, and the desorbed adsorbent material (30) is cooled to the sump portion (45) after cooling (44); a conveying device ( 20) conveying the adsorbent material (30) falling to the storage tank (10) storage tank (16) to the a top end of the tower (4〇), and the adsorbent material (30) falling to the sump portion (45) of the desorption tower (45) is transported to the top end of the adsorption tower (10); and an adsorbent preheating device (60) ) is disposed upstream of the de-heating portion (43) of the desorption column (40). Next, referring to the third figure, the second embodiment of the organic waste gas purification system for preventing and agglomerating the surface of the adsorbent material 201124196 of the present invention includes: an adsorption tower (10), and an organic waste gas inlet at the bottom (13) The top is provided with a purge gas outlet (15), and the inside is divided into a plurality of layers by a perforated plate (11), so that the adsorbent material (30) dropped from the top end forms a floating layer above the perforated plate (11), and along the perforated plate (11) The layered opening side falls to the storage tank (16), and the organic gas in the exhaust gas is adsorbed into the pores of the adsorbing material (30); a desorption tower (40) allows the adsorbing material (30) falling from the top end to pass through The overflow portion (41) is further dropped to the de-heating portion (43), and the desorbing gas introduced into the bottom is brought into contact with the adsorbing material (30), and the organic gas adsorbed in the adsorbing material (30) is desorbed and desorbed. The organic gas is led to the condensation tower (50) for condensation recovery, and the desorbed adsorbent material (30) is cooled to the sump portion (45) after cooling (44); a conveying device (20) will fall The adsorbent material (30) to the adsorption tank (10) storage tank (16) is sent to the desorption tower (40) And adsorbing the adsorbent material (30) falling to the sump portion (45) of the desorption tower (40) to the top of the adsorption tower (10); and an organic waste gas preheating device (70) disposed at the adsorption tower (1〇) The upstream end of the organic waste gas inlet (13). Further, the adsorbent preheating device (60) and the organic exhaust gas preheating device (70) can be simultaneously disposed. In addition, a precondensing device (80) is further disposed at an upstream end of the organic waste gas preheating device (7〇), and the higher boiling organic gas can be further pre-condensed and recovered to reduce the entering the adsorption tower (1〇). The concentration of organic waste ammonia. Further, the heat source of the adsorbent preheating device (6〇) or/and the organic exhaust gas preheating device (7〇) and the cooling source of the condensation tower (5〇) or/and the precondensing device (80) are further provided. Connected by a heat pump (90). Based on the configuration, if the amount of organic exhaust gas 201124196 entering the adsorption tower (10) is 350 NCMM (including 200 ppmv of DMF, 500 ppmv of T0L and 500 ppmv of MEK), the desorbed gas entering the desorption column (40) The circulating air volume is 90 Nm 3 /hr, and the desorption concentration ratio of the desorption tower (40) is 233 times (350*60/90); therefore, the concentration of DMF desorbed from the de-heating portion (43) is 200. * 233 ppmv (saturation temperature is about 63.5 ° C), T0L concentration is 500 * 233 ppmv (saturation temperature is about 49.2 ° C) and MEK concentration is 500 * 233 ppmv (saturation temperature is about 23.5 ° C); The temperature of 30) is lower than the saturation temperature of each of the above components, which causes the component to condense on the surface of the adsorbent (30). • that the adsorbent material (30) that is about to enter the de-heating portion (43) is heated by the adsorbent preheating device (60) (can be controlled at about 65 ° C; that is, must be greater than the saturation of the above DMF) The temperature of 63. 5 ° C can prevent DMF condensation), so that the desorbed high concentration organic gas (in the above embodiment, especially DMF) can be condensed by encountering the low temperature adsorption material (30). It has the effect of preventing condensation and agglomeration on the surface of the adsorbent. Further, in the case where the high concentration organic gas is desorbed due to the high desorption concentration ratio, the desorption gas purification unit (42) is provided in the overflow portion (41) and the de-heating portion φ ( Between 43), the adsorbing material preheating device (60) can also be used to heat the adsorbing material (30) that is about to enter the de-heating portion (43), so as to prevent the desorbed organic gas from encountering the low-temperature adsorbing material ( 30) Condensation, which has the effect of preventing coagulation and agglomeration on the surface of the adsorbent. However, if the organic gas is purified in a cold operating environment, the adsorbent preheating device (60) can be used to heat the adsorbent (30) that is about to enter the de-heating portion (43) to avoid desorption. The organic gas coming out is condensed by the low-temperature adsorbing material (30); or the organic waste gas preheating device (70) is used to heat the exhaust gas of 201124196 which is about to enter the adsorption tower (10), so that the transport is delivered to the desorption The adsorption material (30) of the tower (40) is heated to prevent the desorbed organic gas from coagulating with the low-temperature adsorption material (30), and has the effect of preventing condensation and agglomeration on the surface of the adsorption material; Complete, empty tower and related components are blocked. In summary, the technical means disclosed in the present invention have the invention patents such as "novelty", progressiveness, and "available for industrial use", and pray for the patents of the bureau to invent inventions. sense. However, the drawings and descriptions disclosed above are only preferred embodiments of the present invention. </ RTI> </ RTI> <RTIgt; </ RTI> <RTIgt; </ RTI> <RTIgt; 201124196 [Simple description of the diagram] The first diagram is a structural description of the conventional organic waste gas purification system. The second drawing is a structural explanatory view of the first embodiment of the present invention. The third drawing is a structural explanatory view of a second embodiment of the present invention.

【主要元件符號說明】 (10) 吸附塔 (11) 多孔板 (12) 氣流分散板 (13) 有機廢氣入口 (14) 廢氣風機 (15) 淨化氣體出口 (16) 貯槽 (20)輸送裝置 (30)吸附材 (40)脫附塔 (41) 溢流部 (42) 脫附氣體純化部 (43) 脫附加熱部 (44) 冷卻部 (45) 貯槽部 (50)冷凝塔 (60)吸附材預熱裝置 (70)有機廢氣預熱裝置 (80)預冷凝裝置 (90)熱泵[Explanation of main components] (10) Adsorption tower (11) Perforated plate (12) Air flow dispersion plate (13) Organic waste gas inlet (14) Exhaust gas fan (15) Purified gas outlet (16) Storage tank (20) Conveying device (30 Adsorption material (40) desorption tower (41) overflow section (42) desorption gas purification section (43) desorption hot section (44) cooling section (45) sump section (50) condensation tower (60) adsorption material Preheating device (70) organic waste gas preheating device (80) precondensing device (90) heat pump

Claims (1)

201124196 七、申請專利範圍: 1·一種預防吸附材表面凝結與結塊之有機廢氣淨化 系統,係包括有: 一吸附塔’底部設置有機廢氣入口,頂部設置淨化氣 體出口 ’内部以多孔板分隔成數層,讓由頂端落下之吸附 材在多孔板上方形成浮動層,並沿著多孔板一層一層的開 口側落至貯槽,而將廢氣中的有機氣體吸附於吸附材的孔 洞内; 一脫附塔,讓自頂端落下之吸附材經溢流部再落至脫 附加熱部,而由底部導入脫附氣體與吸附材接觸,將吸附 材中所吸附之有機氣體脫附,脫附後之吸附材則於冷卻部 冷卻後落至貯槽部; 一輸送裝置,將落至該吸附塔貯槽之吸附材輸送至該 脫附塔頂端,且將落至該脫附塔貯槽部之吸附材輸送至該 吸附塔頂端;以及 一吸附材預熱t置,設置於該脫附塔之脫附加熱部上 游者。 2 ·如申請專利範圍第1項所述之預防吸附材表面凝 結與結塊之有機廢氣淨化系統,其中,進一步於該吸附塔 之有機廢氣入口上游端設置一有機廢氣預熱裝置。 3 _如申請專利範圍第1或2項所述之預防吸附材表 面凝結與結塊之有機廢氣淨化系統,其中,進一步於該有 -12- 201124196 機廢氣預熱裝置之上游端設置一預冷凝裝置。 4·如申請專利範圍第3項所述之預防吸附材表面凝 結與結塊之有機廢氣淨化系統,其中,進一步令該吸附材 預熱裝置之熱源與該冷凝塔或/及該預冷凝裝置之冷源藉 由熱泵予以連結。 5 ·如申請專利範圍第3項所述之預防吸附材表面凝 ,结與結塊之有機廢氣淨化系統,其中,進一步令該有機廢 氣預熱裝置之熱源與該冷凝塔或/及該預冷凝裝置之冷源 藉由熱泵予以連結。 6·—種預防吸附材表面凝結與結塊之有機廢氣淨化 系統,係包括有: 一吸附塔,底部設置有機廢氣入口,頂部設置淨化氣 體出口 ’内部以多孔板分隔成數層,讓由頂端落下之吸附 材在多孔板上方形成浮動層,並沿著多孔板一層一層的開 口側落至貯槽’而將廢氣中的有機氣體吸附於吸附材的孔 洞内; 一脫附塔,讓自頂端落下之吸附材經溢流部再落至脫 附加熱部’而由底部導入脫附氣體與吸附材接觸,將吸附 材中所吸附之有機氣體脫附,脫附出來的高濃度有機氣體 被導引至冷凝塔冷凝回收,脫附後之吸附材則於冷卻後落 至貯槽部; • 13 201124196 一輸送裳置,將落至該吸附塔貯槽之吸附材輸送至該 脫附塔頂端,且將落至該脫附塔貯槽部之吸附材輸送至該 吸附塔頂端;以及 一有機廢氣預熱裝置,設置於該吸附塔之有機廢氣入 口上游端者。 7 ·如申請專利範圍第6項所述之預防吸附材表面凝 結與結塊之有機廢氣淨化系統,其中,進一步於該有機廢 氣預熱裝置之上游端設置一預冷凝裝置。 8·如申請專利範圍第7項所述之預防吸附材表面凝 結與結塊之有機廢氣淨化系統,其中,進一步令該有機廢 氣預熱裝置之熱源與該冷凝塔或/及該預冷凝裝置之冷源 藉由熱泵予以連結。 9·一種有機廢氣淨化系統預防吸附材表面凝結與結 塊之方法’係於進行脫附程序之前增加一預熱程序者。 1◦·如申請專利範圍第9項所述之有機廢氣淨化系 統預防吸附材表面凝結與結塊之方法,其中,該預熱程序 係將吸附材預熱或/及將有機廢氣預熱。 -14-201124196 VII. Scope of application for patents: 1. An organic waste gas purification system for preventing condensation and agglomeration on the surface of adsorbent materials, including: an organic waste gas inlet at the bottom of an adsorption tower, and a purge gas outlet at the top. a layer, the adsorption material falling from the top forms a floating layer above the perforated plate, and falls along the open side of the perforated plate to the storage tank, and adsorbs the organic gas in the exhaust gas into the pore of the adsorption material; The adsorbent material dropped from the top portion is further dropped to the de-heating portion through the overflow portion, and the desorbed gas introduced into the bottom portion is brought into contact with the adsorbing material to desorb the organic gas adsorbed in the adsorbent material, and the adsorbed material after desorption is removed. Then, after cooling, the cooling unit falls to the sump portion; a conveying device transports the adsorption material falling to the adsorption tower storage tank to the top of the desorption tower, and transports the adsorption material falling to the desorption tower storage tank portion to the adsorption The top of the tower; and a preheating element of the adsorbing material are disposed upstream of the de-heating portion of the desorption tower. The organic waste gas purification system for preventing condensation and agglomeration of the surface of the adsorbent according to the first aspect of the invention, wherein an organic waste gas preheating device is further disposed at an upstream end of the organic waste gas inlet of the adsorption tower. 3 _ The organic waste gas purification system for preventing condensation and agglomeration of the surface of the adsorbent material according to claim 1 or 2, wherein a precondensation is further provided at the upstream end of the exhaust gas preheating device of the -12-201124196 Device. 4. The organic waste gas purification system for preventing condensation and agglomeration of the surface of the adsorbent material according to claim 3, wherein the heat source of the adsorbent preheating device and the condensation tower or/and the precondensing device are further The cold source is connected by a heat pump. 5) The organic waste gas purification system for preventing condensation, agglomeration and agglomeration of the surface of the adsorbent according to claim 3, wherein the heat source of the organic waste gas preheating device and the condensation tower or/and the precondensation are further The cold source of the device is connected by a heat pump. 6. An organic waste gas purification system for preventing condensation and agglomeration on the surface of the adsorbent material, comprising: an adsorption tower, an organic waste gas inlet at the bottom, and a purge gas outlet at the top; the interior is separated by a perforated plate into several layers, allowing the top to fall The adsorbing material forms a floating layer above the perforated plate, and falls along the open side of the perforated plate to the storage tank' to adsorb the organic gas in the exhaust gas into the pore of the adsorbing material; a desorption tower is allowed to fall from the top end The adsorbent material falls to the de-heating portion through the overflow portion, and the desorbed gas is introduced into the adsorbent by the bottom, and the organic gas adsorbed in the adsorbent is desorbed, and the desorbed high-concentration organic gas is guided to The condensation tower is condensed and recovered, and the adsorbed material after desorption is cooled to the sump portion; • 13 201124196 A conveyor is placed, and the adsorbent material falling into the storage tank of the adsorption tower is transported to the top of the desorption tower, and will fall to The adsorbent material of the desorption tower sump portion is sent to the top of the adsorption tower; and an organic waste gas preheating device is disposed at the upstream end of the organic waste gas inlet of the adsorption tower. The organic waste gas purification system for preventing condensation and agglomeration of the surface of the adsorbent material according to claim 6, wherein a precondensing device is further disposed at an upstream end of the organic waste gas preheating device. 8. The organic waste gas purification system for preventing condensation and agglomeration of the surface of the adsorbent material according to claim 7, wherein the heat source of the organic waste gas preheating device and the condensation tower or/and the precondensing device are further The cold source is connected by a heat pump. 9. An organic waste gas purification system for preventing condensation and agglomeration on the surface of an adsorbent material&apos; is to add a preheating procedure before the desorption procedure. The method of preventing the coagulation and agglomeration of the surface of the adsorbent material by the organic waste gas purification system according to claim 9, wherein the preheating process preheats the adsorbent material and/or preheats the organic waste gas. -14-
TW100105347A 2011-02-18 2011-02-18 Organic waste gas purification system and method capable of preventing from surface condensation and agglomeration of the absorption material. TW201124196A (en)

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CN106693610B (en) * 2015-07-14 2019-10-29 杰智环境科技股份有限公司 Save the desorption apparatus and fluidized bed continous way adsorption desorption system of absorption grain dosage
CN108097016A (en) * 2016-11-24 2018-06-01 上海新昇半导体科技有限公司 A kind of exhaust gas processing device with spill cavity
CN108097016B (en) * 2016-11-24 2020-11-10 上海新昇半导体科技有限公司 Tail gas treatment device with overflow chamber

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