TW201118111A - Composition for color filter, hardened matter, and color filter - Google Patents

Abstract

This invention provides an ink composition suited for forming pixel patterns on a glass substrate of large size, reducing costs and large scale production, more particularly a composition for color filters, which composition exhibits excellent anti-medicine property and adherence property, and the color filter formed by using a hardened matter obtained by hardening the composition. The composition contains as necessary components in a solvent a multi-functional epoxy compound (A) having two or more than two functions, a multiple functional carboxylic acid derivative compound (B) having three or more than three functions; a multiple functional amine resin (C) having two or more than two functions wherein the functional groups contained in the amine resin are represented by -NH, -NR', -NR'OH, or -NR'OR', wherein R' represents an alkyl group; and a coloring agent (D) which is contained at the ratio of 10% mass to 60% mass with respect to the total amount of mass of solid components excluding the solvent. The color filter contains pixels which are formed by using a hardened matter obtained by hardening the composition under the temperature of 160 DEG C to 250 DEG C.

Description

201118111 六、發明說明： 【發明所屬之技術領域】 本發明係W於適合藉由喷墨法製作濾、色片（c ο 1 〇 r filter)的濾色片用組成物、使該組成物硬化而得的硬化 物、及濾色片。 【先前技術】 衫色液晶顯示器件中所使用的濾色片的製造方法，至 今的主流皆為：在感光性樹脂中加入光聚合起始劑、各種 添加劑、及红色（R)、綠色（G)、藍色（B)的各著色材後，塗 佈由溶劑所調製而成的彩色阻劑（color resist)並乾燥 後，藉由一連串的步驟以光微影（photo lithography)法形 成像素圖案（pixel pattern’pixel有稱為晝素、像元、 像素等情形，本文中稱為像素）。然而，隨著近年來的素玻 璃（mother glass)的大型化，習知的藉由光微影法進行的 濾色片的製造方法，也在塗佈步驟等各步驟中開始產生技 術性上的問題。 例如：至今主要採用使用旋轉塗佈器（spin coater) 的塗佈方法’但隨著作為基底的素玻璃變大，在技術上也 會難以使用旋轉塗佈器進行塗佈，而採用使用狹縫塗佈器 (slit coater)的塗佈方法取代使用旋轉塗佈器的塗佈方 法。然而’即使是使用狹縫塗佈器的塗佈方法，也會由於 素玻璃的更進一步大型化而難以在全面形成均勻的塗膜， 特別是在8G、l〇G級的超大型素玻璃，此問題更為顯著。 此外，因光微影法必須對3色各別進行塗佈、乾燥、曝光、 4 322457 201118111 顯影、硬化的各處理，因此也有步驟數增加且成本變高的 問題，而期望與光微影法不同的像素形成手段。 ‘於是，作為取代光微影法的濾色片的製造方法，提案 有例如使用膠版印刷法（offset printing method)或喷墨 法的影像形成，並且正朝可實施化進展。其中，關於膠版 印刷法，目前正處在難以對超大型素玻璃充分安定地形成 像素的狀態，而實用化的進展緩慢。相對地，藉由噴墨法 而進行的影像形成方法，近年來正備受關注，且習知其實 •施後已留有某種程度的實績。而且，關於在喷墨法中所使 用的印墨（ink)，已揭示有數個專利（參照專利文獻1、2)。 習知的光微影法用濾色片用組成物，一般為將液狀丙 烯酸酯單體與光聚合起始劑混合而成的光硬化型的組成 物，且是藉由UV照射與熱乾燥製作成硬化膜。然而，在喷 墨法中，經常不進行光硬化，而是藉由熱硬化製作成濾色 片。因此，若藉由喷墨法將習知的光硬化型的濾色片用組 I成物進行像素形成，則硬化會不充分，而使硬化膜的耐性 變差。以熱硬化作為特徵的濾色片用組成物，已揭示有例 如：專利文獻3、專利文獻4、專利文獻5等。 其中，專利文獻3揭示一種以環氧單體作為必須成分 的濾色片用熱硬化性組成物，雖因其為低黏度的印墨而維 持喷出安定性，但耐溶劑性等耐性變差。專利文獻4揭示 一種以環氧單體作為必須成分的濾色片用熱硬化性組成 物，其為硬化收縮率少且平坦性、耐溶劑性優良者，但若 硬化收縮率較多才可降低顏料濃度，更有利於耐藥品性。 5 322457 201118111 專利文獻5揭示一種印墨，其是實質上以作為黏合劑樹脂 (binder resin)的三聚氰胺樹脂（melamine resin)及環氧 樹脂當作必須成分的印墨，且以喷墨法喷出時的像素内平 坦性優良，但由於未加入硬化劑，所以硬化會不充分，而 使对藥品性等财性不良。 [先前技術文獻] [專利文獻] [專利文獻1]曰 [專利文獻2]曰 [專利文獻3]曰 [專利文獻4]曰 [專利文獻5]曰201118111 VI. Description of the Invention: [Technical Field] The present invention is a composition for a color filter suitable for producing a filter or a color filter (c ο 1 〇r filter) by an inkjet method, and hardening the composition The resulting hardened material and color filter. [Prior Art] The method for producing a color filter used in a shirt color liquid crystal display device has hitherto been mainstream: adding a photopolymerization initiator, various additives, and red (R), green (G) to a photosensitive resin. After each coloring material of blue (B), a color resist prepared by a solvent is applied and dried, and a pixel pattern is formed by photolithography by a series of steps. (Pixel pattern 'pixel has a situation called a pixel, a pixel, a pixel, etc., referred to herein as a pixel). However, with the recent enlargement of mother glass, the conventional method of manufacturing a color filter by photolithography has begun to produce technical results in various steps such as a coating step. problem. For example, the coating method using a spin coater has been mainly used so far. However, as the base glass of the work becomes larger, it is technically difficult to apply the coating using a spin coater, and the slit is used. A coating method of a slit coater is used instead of a coating method using a spin coater. However, even in the coating method using a slit coater, it is difficult to form a uniform coating film due to the further enlargement of the plain glass, especially in the super large glass of 8G, lG class. This problem is more significant. In addition, since the photolithography method must apply, dry, expose, and process each of the three colors, 4 322 457 201118111 development and hardening, there is also a problem that the number of steps increases and the cost becomes high, and the expectation and the light lithography method are required. Different pixel formation means. </ RTI> As a method of producing a color filter in place of the photolithography method, for example, image formation using an offset printing method or an inkjet method has been proposed, and progress is progressing. Among them, the offset printing method is currently in a state in which it is difficult to form a pixel in a sufficiently stable manner for the super large-sized glass, and the progress in practical use is slow. In contrast, the image forming method by the ink jet method has been attracting attention in recent years, and it has been known that there has been some degree of performance after the application. Further, several patents have been disclosed regarding the ink used in the ink jet method (see Patent Documents 1 and 2). The composition for a color filter for a photolithography method is generally a photocurable composition obtained by mixing a liquid acrylate monomer and a photopolymerization initiator, and is irradiated by UV and thermally dried. Made into a cured film. However, in the ink jet method, photohardening is often not performed, but a color filter is produced by thermal hardening. Therefore, when a conventional photocurable color filter is formed into a pixel by the ink jet method, the curing is insufficient, and the durability of the cured film is deteriorated. For the color filter composition characterized by thermal hardening, for example, Patent Document 3, Patent Document 4, Patent Document 5, and the like have been disclosed. In addition, Patent Document 3 discloses a thermosetting composition for a color filter containing an epoxy monomer as an essential component, and maintains discharge stability due to a low-viscosity ink, but resistance to solvent resistance is deteriorated. . Patent Document 4 discloses a thermosetting composition for a color filter containing an epoxy monomer as an essential component, which has a small curing shrinkage ratio and is excellent in flatness and solvent resistance. However, if the curing shrinkage ratio is large, the pigment can be lowered. Concentration is more conducive to chemical resistance. 5 322457 201118111 Patent Document 5 discloses an ink which is an ink which is substantially an essential component of a melamine resin and an epoxy resin as a binder resin, and is ejected by an inkjet method. In the case of the pixel, the flatness is excellent, but since the hardener is not added, the hardening is insufficient, and the chemical properties such as pharmaceutical properties are poor. [Prior Art Document] [Patent Document 1] [Patent Document 1] 曰 [Patent Document 2] 曰 [Patent Document 3] 曰 [Patent Document 4] 曰 [Patent Document 5] 曰

本專利第3826561號公報 本特開2006 — 299090號公報 本特開2004— 22036號公報 本特開2007— 219302號公報 本特開2008- 242203號公報 【發明内容】 (發明欲解決的課題） 本發明的目的為提供一種濾色片用組成物，該組成物 係在適合對朝大型化進展的玻璃基板形成像素圖案且同時Japanese Patent Laid-Open No. Hei. No. Hei. No. Hei. No. Hei. No. Hei. No. Hei. No. Hei. No. Hei. No. Hei. No. Hei. It is an object of the invention to provide a composition for a color filter which is suitable for forming a pixel pattern on a glass substrate which is progressing toward enlargement and at the same time

可低成本化及量產化的喷墨法所使用的印墨組成物中，耐 藥品性及密著性等優良者。此外，本發明的另一目的為提 供一種使用使所述組成物硬化而得的硬化物形成的濾色 (解決課題的手段） 本發明人等為了解決所述課題而進行研究後結果發 現，在藉由喷墨法的步驟而進行濾色片用的像素形成時， 使用包含2官能以上的多官能環氧化合物、3官能以上的 6 322457 201118111 ’多官能羧酸衍生物化合物、及2官能以上的多官能胺基樹 脂的組成物，作為適合熱硬化的濾色片用組成物，即可製 作耐藥品性和密著性優良的濾色片，遂完成本發明。 • 換句話說，本發明為一種濾色片用組成物，其是在溶 劑中包含2官能以上的多官能環氧化合物（六）、3官能以: 的多官能羧酸衍生物化合物（B)、2官能以上的多官能胺基 樹脂（C)[惟，胺基樹脂所具有的官能基為_仙、_NR，、 _NR’ 0H、或-NR’ OR’（R，表示烷基）]、以及著色材（D)作為必 馨須成分，並且相對於去除溶劑後餘留的固形份的合計質 量，著色材（D)的質量比率為1〇%至6〇%。 此外，本發明的濾色片用組成物的較佳態樣為，相對 於所述（A)成分中的環氧乙燒（〇Xirane)環l〇Q當量，（B) 成分的缓酸基為在50至110當量的範圍，且同時（〇成八 的胺基官能基為在10至150當量的範圍。 並且，本發明為一種硬化物，其是使所述濾色片用級 成物硬化而得，再且，本發明為一種濾色片，其中的形成 像素的硬化膜是由所述的硬化物所構成。 以下，詳細說明本發明。 本發明是以包含2官能以上的多官能環氧化合物 (A)、3官能以上的多官能羧酸衍生物化合物（b)、及2官 能以上的多官能胺基樹脂（C)作為必須成分，並且，相對於 所述（A)成分的環氧乙烷環數100，較佳（B)成分的羧酸基 數為在50至110的範圍且同時（C)成分的胺基官能基數二 在10至150的範圍，而且，相對於所述（A)成分的環氧乙 322457 7 201118111 烷環數100，更較佳為（B)成分的羧酸基數為在60至105 · 的範圍或（C)成分的官能基數為在80至150的範圍、或是 (B)成分與（〇成分同時為在這樣的條件的範圍内。 — 關於所述（A)至（C)的化合物，（A)成分的環氧基與（B) ' 成分的羧基會反應形成交聯鍵結。此外，藉由（A)成分與（B) 成分的交聯鍵結而新生成的羥基會與（C)成分反應，而構成 堅固的交聯構造。若相對於（A)成分的環氧乙烷環數100， (B)成分的羧酸基數大於11〇,則會發生未反應的羧基大量 殘留而使黏度安定性惡化、或因交聯密度降低而使耐藥品 _ 性惡化等不良情形。此外，若相對於（A)成分的環氧乙烷環 數100，（C)成分的胺基官能基數大於150，則會因胺基樹 脂的自縮合所造成的膜收縮變得太大，而使像素内平坦性 惡化。 此外’作為本發明的濾色片用組成物的必須成分的著 色材（D)’其相對於去除溶劑後餘留的固形份的合計質量的 質量比重為10%至60% ’較佳為20%至50%。 關於所述（A)至（D)成分，首先，2官能以上的多官能鳙 環氧化合物（A)為在一分子中具有2個以上的環氧乙烷環 的環氧化合物，其代表例可舉例如：酚酚醛（phen〇1 novolac)型環氧樹脂、曱盼祕（⑽。！ n〇v〇iac)型環氧 樹脂等賴（novolac)型環氧樹脂系；雙紛A型環氧系、雙 驗F型環氧系等雙驗型環氧樹脂系；或聯苯（Μρ_η型 環氧樹脂系、脂環式環氧樹脂系等。這些可僅單獨使用其 中1種，且也可併用2種以上。 8 322457 201118111 具代表性的3官能以上的多官能羧酸衍生物化合物（B) 可舉例如：均苯三甲酸（trimesic acid)、偏苯三甲酸 (trimellitic acid)、均苯四曱酸（pyromel 1 itic acid)、 1，2, 3, 4-丁烷四甲酸、環戊烷四曱酸、二苯甲酮四曱酸、 偏苯三甲酸二酐、均苯四甲酸二酐、1，2, 3, 4-丁烷四甲酸 二酐、環戊烷四甲酸二酐等（在這裏，將酸酐基1莫耳計算 為2官能）。存在於這些.3官能以上的多官能羧酸衍生物化 合物（B)中的綾基及酸酐基，是與存在於組成物中的環氧基 鲁進行反應而形成交聯鍵結。 2官能以上的多官能胺基樹脂（c)可例示如：下述通式 (1)所示的完全烷基型、亞胺基型、羥曱基型、或其混合系 的三聚氰胺樹脂或其寡聚物。或者可舉例如♦•如通式（D 所示的具有S-三嗪（triazine)骨架且取代基一NRR的一部 分經不會與羧基或羥基進行縮合反應的芳香族烴基或碳數 1至4的烧基所取代的脈胺（guanamine)、乙醯胍胺 鲁（acetoguanamine)、苯并胍胺（benzoguanamine)、乙基二 胺基-S-三嗪、烷氧基曱基化甘脲（giycolurii)類、以及脲 樹脂或這些的類似物等。當任一取代基-NRR的至少一部分 可與羧基或羥基通過縮合反應形成交聯構造時，就將該 -NRR定義為胺基官能基。 9 322457 201118111The ink composition used in the ink jet method which can be reduced in cost and mass-produced is excellent in chemical resistance and adhesion. In addition, another object of the present invention is to provide a color filter formed by using a cured product obtained by curing the composition (a means for solving the problem). When a pixel for a color filter is formed by the step of the inkjet method, a polyfunctional epoxy compound containing two or more functional groups, a 6 322457 201118111 'polyfunctional carboxylic acid derivative compound having a trifunctional or higher functional group, and a bifunctional or higher functional group are used. The composition of the polyfunctional amine-based resin can be used as a color filter composition suitable for thermosetting, and a color filter excellent in chemical resistance and adhesion can be produced, and the present invention has been completed. In other words, the present invention is a color filter composition containing a polyfunctional epoxide compound (VI) having two or more functional groups in a solvent, and a polyfunctional carboxylic acid derivative compound (B) having a trifunctionality: a polyfunctional amine-based resin (C) having two or more functional groups [only, the functional group of the amino resin is _仙, _NR, _NR' 0H, or -NR' OR' (R, represents an alkyl group)], And the coloring material (D) is a must-have component, and the mass ratio of the coloring material (D) is from 1% to 6% by mass based on the total mass of the solid content remaining after the solvent is removed. Further, in a preferred embodiment of the color filter composition of the present invention, the acid-base group of the (B) component is compared with the epoxy group (〇Xirane) ring in the (A) component. It is in the range of 50 to 110 equivalents, and at the same time (the amino group functional group is in the range of 10 to 150 equivalents. Moreover, the present invention is a cured product which is a grade for the color filter. Further, the present invention is a color filter in which a cured film forming a pixel is composed of the cured product. Hereinafter, the present invention will be described in detail. The present invention is a polyfunctional compound containing two or more functional groups. The epoxy compound (A), the trifunctional or higher polyfunctional carboxylic acid derivative compound (b), and the bifunctional or higher polyfunctional amine-based resin (C) are essential components and are relative to the component (A). The number of oxirane rings is 100, preferably the number of carboxylic acid groups of the component (B) is in the range of 50 to 110 and the number of amino functional groups of the component (C) is in the range of 10 to 150, and The epoxy group of the component (A) is 322457 7 201118111 The number of the alkyl ring is 100, more preferably the carboxylic acid group of the component (B) The number of functional groups in the range of 60 to 105 · or (C) is in the range of 80 to 150, or the component (B) and (the composition of the oxime are within the range of such conditions at the same time. - about the above (A) ) to the compound of (C), the epoxy group of the component (A) reacts with the carboxyl group of the (B) ' component to form a cross-linking bond. Further, the cross-linking bond of the component (A) and the component (B) The newly formed hydroxyl group reacts with the component (C) to form a strong crosslinked structure. If the number of oxirane groups of the component (B) is greater than 11 Å, the number of carboxylic acid groups of the component (B) is greater than 11 Å. When a large amount of unreacted carboxyl groups remain, the viscosity stability is deteriorated, or the crosslinking resistance is lowered to deteriorate the chemical resistance, and the number of oxirane rings relative to the component (A) is 100. When the number of the amine functional groups of the component (C) is more than 150, the film shrinkage due to self-condensation of the amine-based resin becomes too large, and the flatness in the pixel is deteriorated. Further, 'as a color filter composition of the present invention The coloring material (D) of the essential component of the object is the total mass of the solid component remaining after the solvent is removed. The mass specific gravity is from 10% to 60%, preferably from 20% to 50%. Regarding the components (A) to (D), first, the polyfunctional fluorene epoxy compound (A) having two or more functional groups is in one molecule. Examples of the epoxy compound having two or more oxirane rings include a phenol novolac type epoxy resin and a (10). n〇v〇iac type ring. Oxygen resin, etc. (novolac) type epoxy resin; double-type epoxy type, double-type F-type epoxy type, etc.; or biphenyl (Μρ_η type epoxy resin, alicyclic) Epoxy resin type, etc. These may be used alone or in combination of two or more. 8 322457 201118111 Representative trifunctional or higher polyfunctional carboxylic acid derivative compound (B) may, for example, be trimesic acid, trimellitic acid or pyromel (pyromel) 1 itic acid), 1,2,3, 4-butane tetracarboxylic acid, cyclopentane tetradecanoic acid, benzophenone tetradecanoic acid, trimellitic acid dianhydride, pyromellitic dianhydride, 1,2 3, 4-butane tetracarboxylic dianhydride, cyclopentane tetracarboxylic dianhydride, etc. (here, the acid anhydride group 1 molar is calculated as a bifunctional). The mercapto group and the acid anhydride group which are present in the polyfunctional carboxylic acid derivative compound (B) of the above-mentioned trifunctional or higher functional group are reacted with the epoxy group present in the composition to form a crosslinked bond. The polyfunctional amine-based resin (c) having a bifunctional or higher functional group may, for example, be a completely alkyl type, an imido type, a hydroxyindole type, or a mixed melamine resin represented by the following formula (1) or Oligomer. Or, for example, an aromatic hydrocarbon group having a S-triazine skeleton represented by the formula (D) and a part of the substituent-NRR which is not subjected to a condensation reaction with a carboxyl group or a hydroxyl group, or a carbon number of 1 to 4 Guanamine, acetoguanamine, benzoguanamine, ethyldiamine-S-triazine, alkoxylated glycoluril (giycolurii) substituted by a burnt group And a urea resin or an analog of these, etc. When at least a part of any substituent -NRR can form a crosslinked structure by condensation reaction with a carboxyl group or a hydroxyl group, the -NRR is defined as an amine functional group. 322457 201118111

[惟，式中，R1至R6表示可與羧基或羥基通過縮合反應而 形成交聯構造的-H、-CH2〇H、~CH2〇R’（R’表示碳數1至4 的烷基），R1至R6可為相同或不同]。 _ 特別是宜較佳使用：在三聚氰胺與甲醛的縮合物中的 一部分或全部的羥曱基經烷基化的丁基化三聚氰胺樹脂、 曱基化三聚氰胺樹脂、混合烷基化三聚氰胺樹脂、含亞胺 基的烷基化三聚氰胺樹脂、及含羥曱基/亞胺基的烷基化 三聚氰胺樹脂。這些的市售物的具體例有：CYMEL系列及 MYC0AT系列（日本Cytec Industries(股）製）等。這些胺基 樹脂（C)是與藉由加熱使存在於組成物中的環氧基與羧基 $ 反應後結果生成的經基進行縮合，而形成交聯，並且也發 生自縮合。 著色材（D)可為有機顏料、無機顏料及染料的任一種， 這些可僅單獨使用其中1種，且也可併用2種以上。其中， 有機顏料可舉例如：偶氮色澱（azo lake)系、不溶性偶氮 (PY150)系、包含酞菁（phthalocyanirje)系（PG7、PG36&amp; PB15.6)的花菁（cyanine)系、啥酜酮（quinophthalone)系 (PY138)、喧吖0定酮（quinacridone)系、二^^(dioxazine) 10 322457 201118111 (PV23)系、異0弓卜朵琳酉同（is〇ind〇linone)(PY139)系、紫環 酮（perinone)系、蒽醌（PR177)系、吡咯并吡咯系（PR254)、 茈（perylene)系等顏料，也可使用其中1種或併用2種以 上。無機顏料可舉例如：米洛麗藍（Mi lari blue)、氧化鐵、 姑系、猛系、群青、甜青、姑藍、天藍（cerulean blue)、[In the formula, R1 to R6 represent -H, -CH2〇H, ~CH2〇R' (R' represents an alkyl group having 1 to 4 carbon atoms) which can form a crosslinked structure by a condensation reaction with a carboxyl group or a hydroxyl group. , R1 to R6 may be the same or different]. _ In particular, it is preferred to use: some or all of the hydroxymethyl group in the condensate of melamine and formaldehyde, alkylated butylated melamine resin, thiolated melamine resin, mixed alkylated melamine resin, containing An amine-based alkylated melamine resin, and an alkylated melamine resin containing a oxindole/imine group. Specific examples of such commercially available products include CYMEL series and MYC0AT series (made by Cytec Industries Co., Ltd.). These amine-based resins (C) are condensed with a radical formed by reacting an epoxy group present in the composition with a carboxyl group by heating to form a crosslink, and also undergo self-condensation. The coloring material (D) may be any of an organic pigment, an inorganic pigment, and a dye, and these may be used alone or in combination of two or more. Among them, the organic pigment may, for example, be an azo lake system, an insoluble azo (PY150) system, or a cyanine system containing a phthalocyanirje system (PG7, PG36 &amp; PB15.6). Quinophthalone (PY138), quinacridone, dioxazine 10 322457 201118111 (PV23), different 0 bow 酉 朵 〇 (is〇ind〇linone) (PY139), a pigment such as a perinone, a ruthenium (PR177), a pyrrolopyrrole (PR254), or a perylene, may be used alone or in combination of two or more. Examples of the inorganic pigments include: Mila blue, iron oxide, phylum, ramets, ultramarine, sweet blue, guaran, cerulean blue,

鉻綠（viridian)、翡翠綠（emerald green)、銘綠等顏料， 也可使用其中1種或併用2種以上。為了可維持所得的著 色膜的透明性且同時進行著色，這些顏料較佳為分散成可 見光的波長的下限的〇. 4 // m以下的平均粒徑，實用上更較 佳為平均粒徑的範圍為lOOnm以下者。 此外’染料可使用習知作為遽色片用的染料，例如： 〇比0坐偶氮系、苯胺基偶氮（anilino azo)系、三笨基曱烧 系、蒽醌系、笨亞甲基（benZylidene)系、氧雜菁（〇χ〇η〇1) 系、吼唑并***偶氮系、吡啶酮偶氮系、花菁系、啡噻嗪 (phenothiazine)系、偶氮次曱基（az〇methine)系等。 濾色片用組成物中所含的溶劑無特別限制，當以噴墨 法形成濾色片時’相對於全溶劑份，較佳為沸點：。二 上的高沸點溶劑為80質量％者，更較佳為9〇質量％以上 ^存㈣點未達·。c的溶劑，則有時因乾燥時。間（期 減少而較佳’但若沸點未達的溶劑在全 、 質量％以上，則印墨組成物中的溶劑的蒸發變太^0 膜的平坦性降低。 、使者色 弗點2〇〇C以上的局彿點溶劑無特別限制 由二乙二醇單烷基醚及其末端乙酸酯類、_ 為從 、一丙二醇單烷基 322457A pigment such as viridian, emerald green, or green may be used alone or in combination of two or more. In order to maintain the transparency of the obtained colored film while performing coloring, these pigments are preferably an average particle diameter of //. 4 // m or less which is dispersed to a lower limit of the wavelength of visible light, and practically more preferably an average particle diameter. The range is below lOOnm. In addition, as the dye, a dye which is conventionally used as a enamel sheet can be used, for example, 〇 0 0 azo, anilino azo, trichome, lanthanum, stupid methyl (benZylidene), oxaphthalocyanine (〇χ〇η〇1), oxazolotriazole azo, pyridone azo, cyanine, phenothiazine, azo sulfhydryl (az〇methine) is the same. The solvent contained in the composition for a color filter is not particularly limited, and when the color filter is formed by an ink jet method, it is preferably a boiling point: relative to the total solvent portion. The high-boiling solvent on the second is 80% by mass, more preferably 9% by mass or more, and the (four) point is not reached. The solvent of c is sometimes due to drying. Between (the period is reduced and preferably 'but if the solvent whose boiling point is not reached is more than 5% by mass, the evaporation of the solvent in the ink composition becomes too small. The flatness of the film is lowered. The solvent of C or higher is not particularly limited by diethylene glycol monoalkyl ether and its terminal acetate, _ is a propylene glycol monoalkyl 322457

II 201118111 ϋ及其末端乙酸酯類或二喊類、二乙二醇二烧基醚類、二 乙二醇單烧基越類及其末端乙酸酯類、以及聚乙二醇的二 烷基醚類所成群組中選出的至少一種。 此外，沸點為200°C以下的低沸點溶劑無特別限制， 可例示如：甲基乙基酮等酮類；甲基溶纖劑（methyl ceIl0S0〗ve)、乙酸溶纖劑（(^11〇3〇1”％紂犲6)等溶纖劑 類，丙二醇單甲基醚、丙二醇單乙基醚等丙二醇單烷基醚 類，丙二醇單甲基醚乙酸酯等丙二醇單烷基醚乙酸酯類； 乳酸乙醋等乳酸醋類；乙酸正丁酯等乙酸有機溶劑。 在本發明的濾色片用組成物中，可包含所述（A)至（D) 成分的樹脂或單體以外的習知的硬化性樹脂或單體，例 如··可考慮到嘴墨滤色片的製造步驟而包含聚合起始劑。 聚合起始_以熱聚合起始劑為佳，但也可賦予光聚合起 始劑等。熱聚合起始劑-般是使用過氧化物，習知的且體 例可舉例如：過氧化苯㈣―卿丨咖心）、^基乙 基鯛過氧化物、三級了基異丙苯絲氧化物（卜㈣丨II 201118111 ϋ and its terminal acetate or dioxin, diethylene glycol dialkyl ether, diethylene glycol monoalkyl group and its terminal acetate, and dialkyl ether of polyethylene glycol At least one selected from the group of classes. Further, the low boiling point solvent having a boiling point of 200 ° C or less is not particularly limited, and examples thereof include ketones such as methyl ethyl ketone; methyl cellosolve (methyl ceIl0S0 ve), and cellosolve acetate ((^11〇) 3〇1"%纣犲6) and other cellosolve, propylene glycol monomethyl ether such as propylene glycol monomethyl ether, propylene glycol monoethyl ether, propylene glycol monoalkyl ether acetate such as propylene glycol monomethyl ether acetate An organic solvent such as lactic acid vinegar such as lactic acid acetacetate or acetic acid such as n-butyl acetate. The color filter composition of the present invention may contain a resin other than the components (A) to (D) or a monomer. A conventional curable resin or monomer, for example, may include a polymerization initiator in consideration of a production step of the ink filter for the nozzle. The polymerization initiation is preferably a thermal polymerization initiator, but may also impart photopolymerization. Starting agent, etc. The thermal polymerization initiator is generally a peroxide, and the conventional examples include, for example, benzoic acid benzene (four) - 丨 丨 丨 、, ^ 鲷 鲷 鲷 peroxide, three grades Isopropylbenzene oxide (Bu(四)丨

Peroxide)等。 本發明_色片用組成物是適合藉㈣墨法而形成像 ’例如：使藉由習知手段而噴出的組成物在⑽。c至25〇 硬化’即可形成既定的像素，而得到濾、色片。再者 ^明㈣色片用組成物可無礙地使用在嘴墨法以外的方 (發明的效果） 本發明令的遽色片用組成物，在藉由喷墨法製作成滤 322457 12 201118111 色片時，可製作充分地硬化且耐藥品性、密著性等優良的 濾色片。 【實施方式】 以下，依據實施例而具體說明本發明。再者，以下中 的「份」皆表示質量份。 (實施例） [實施例1] (濾色片用組成物的製作） • 以顏料紅（pigment red)254作為1〇〇份，並相對於該 顏料紅調配高分子系分散劑80份及二乙二醇單丁基趟乙 酸酉旨820份，使用塗料震盛機（paint shaker)進行分散處 理3小時，而得到分散液1000份。在這裏，塗料震盪機的 媒介疋以填充率20%使用0. 4ππη p氧化錯珠（zirconia beads)。其次’調配2官能聯苯型環氧樹脂（japan Epoxy Resins公司製，YX— 4000H)40份、偏苯三曱酸酐8份、三 鲁聚氰胺樹脂（日本Cytec Industries公司製，CYMEL37〇)23 份、二乙二醇單丁基醚乙酸酯239份、界面活性劑 (surfactant)0.3份、及矽烷耦合劑（silane coupling agent)5份，並充分攪拌.，而得到硬化性聚舍物315份。 在其中調配所述得到mgln的分散液685份，並充分攪拌， 而製作實施例1的濾色片用組成物1000份。 (雛型濾色片（model color fi Iter)的製作） 使用旋轉塗佈器將所述得到的濾色片用組成物塗佈在 5英叶見方、厚度1 mm的玻璃上，而製作試驗片。在加熱 13 322457 201118111 在熱風爐中於240Peroxide) and so on. The composition for a color sheet of the present invention is suitable for forming an image by the (four) ink method. For example, a composition which is ejected by a conventional means is (10). From c to 25 〇 hardening, a predetermined pixel can be formed, and a filter or a color patch can be obtained. Further, the composition of the color film can be used without any hindrance in the other aspects of the ink method (the effect of the invention). The composition for the color film of the present invention is produced by the ink jet method to filter 322457 12 201118111 color In the case of a sheet, it is possible to produce a color filter which is sufficiently hardened and excellent in chemical resistance, adhesion, and the like. [Embodiment] Hereinafter, the present invention will be specifically described based on examples. In addition, the "parts" in the following are all parts by mass. (Example) [Example 1] (Production of color filter composition) • Pigment red 254 was used as one part, and polymer red dispersant 80 parts and two were prepared with respect to the pigment red. Ethylene glycol monobutyl phthalate was used for 820 parts, and dispersion treatment was carried out for 3 hours using a paint shaker to obtain 1,000 parts of a dispersion. Here, the medium of the paint turret is used at a filling rate of 20% using 0.4 ππη p zirconia beads. Secondly, 40 parts of a bifunctional biphenyl type epoxy resin (YX-4000H, manufactured by Japan Epoxy Resins Co., Ltd.), 8 parts of trimellitic anhydride, and a tri-ruthenium amide resin (CYMEL37®, manufactured by Cytec Industries, Japan) 23 were prepared. Parts, 239 parts of diethylene glycol monobutyl ether acetate, 0.3 parts of surfactant, and 5 parts of silane coupling agent, and stirred well to obtain a hardening 315 Share. Into the above, 685 parts of the dispersion of the obtained Mgln was blended, and the mixture was thoroughly stirred to prepare 1000 parts of the color filter composition of Example 1. (Production of model color fiiter) The obtained color filter composition was applied onto a glass of 5 inches square and 1 mm thick using a spin coater to prepare a test piece. . At the heating 13 322457 201118111 in the hot blast stove at 240

板上於90°C使此試驗片乾燥3分鐘後， °C煅燒20分鐘， 的硬化膜（雛型濾色片A)。 [實施例2] (遽色片用組成物的製作） 並相對·於該顏料紅調配高 ^乙酸酯775份，使 而得到分散液1000 以顏料紅254作為140份，並相對^ 分子系分散劑85份及二乙二醇單丁基喊 用塗料震盪機進行分散處理3小時，而 份。在這裏，塗料震盪機的媒介是以填充率2⑽使用〇.4丽 P氧化鍅珠。其次，調配2官能聯苯型環氧樹脂（Japan Epoxy Resins公司製，γχ—4〇〇〇H)29份、偏苯三曱酸酐9 份、三聚氰胺樹脂（日本Cytec Industries公司製， CYMEL303)20份、觸媒（san —Apro股份有限公司製，U —CAT SA102)1份、二乙二醇單丁基醚乙酸酯236份、界面活性 劑0. 3份、及矽烷耦合劑5份，並充分攪拌，而得到硬化 性聚合物300份。在其中調配所述得到的分散液700份， 並充分攪拌，而製作實施例2的濾色片用組成物1000份。 (雛型濾色片的製作） 使用旋轉塗佈器將所述得到的濾色片用組成物塗佈在 5英吋見方、厚度imin的玻璃上，而製作試驗片。在加熱 板上於90°C使此試驗片乾燥3分鐘後，在熱風爐中於240 °C煅燒20分鐘，而製作作為離型濾色片的濾色片用組成物 的硬化膜（雛型濾色片B)。 [實施例3] 14 322457 201118111 (濾色片用組成物的製作） 以顏料紅254作為140份，並相對於該顏料紅調配高 分子系分散劑85份及二乙二醇單丁基醚乙酸酯775份，使 用塗料震盪機進行分散處理3小時，而得到分散液1〇〇〇 份。在這裏，塗料震盪機的媒介是以填充率20%使用〇. 4mm P氧化錯珠。其次，調配2宫能聯苯型環氧樹脂（japan £?〇^1^51113公司製，丫乂一4〇〇〇1〇33份、偏苯三甲酸酐6 份、三聚氰胺樹脂（日本Cytec Industries公司製， 鲁CYMEL303)19份、觸媒（San—Apro股份有限公司製，U —CAT SA102)1份、二乙二醇單丁基醚乙酸酯235份、界面活性 劑〇. 5份、及矽烷耦合劑5份，並充分攪拌，而得到硬化 性聚合物300份。在其中調配所述得到的分散液700份， 並充分授拌’而製作實施例3的濾色片用組成物1〇〇〇份。 (離型濾色片的製作） 使用旋轉塗佈器將所述得到的濾色片用組成物塗佈在 參5英时見方、厚度1mm的玻璃上，而製作試驗片。在加熱 板上於90。(：使此試驗片乾燥3分鐘後’在熱風爐中於240 °C锻燒20分鐘，而製作作為雛型濾色片的濾色片用組成物 的硬化膜（離型遽色片C)。 [實施例4] (濾色片用組成物的製作） 以顏料紅254作為140份，並相對於該顏料紅調配高 分子系分散劑85份及二乙二醇單丁基醚乙酸酯775份，使 用塗料震盪機進行分散處理3小時，而得到分散液1000 15 322457 201118111 份。在這裏，塗料震盪機的媒介是以填充率20%使用0. 4imn : p氧化錯珠。其次，調配雙紛苐（bisphenol f luorene)型 環氧樹脂（新日鐵化學公司製，商品名：ESF— 300)37份、 偏苯三曱酸酐6份、三聚氰胺樹脂（日本Cytec Industries ' 公司製，CYMEL370)18份、二乙二醇單丁基醚乙酸酯234 份、界面活性劑0. 3份、及矽烷耦合劑5份，並充分攪拌， 而得到硬化性聚合物300份。在其中調配所述得到的分散 液700份，並充分攪拌，而製作實施例4的濾色片用組成 物1000份。 籲 (雛型濾色片的製作） 使用旋轉塗佈器將所述得到的濾色片用組成物塗佈在 5英11寸見方、厚度1mm的玻璃上，而製作試驗片。在加熱 板上於90°C使此試驗片乾燥3分鐘後，在熱風爐中於240 °C煅燒20分鐘，而製作作為雛型濾色片的濾色片用組成物 的硬化膜（雛型濾色片D)。 [實施例5] (濾色片用組成物的製作） ® 以顏料紅254作為140份，並相對於該顏料紅調配高 分子系分散劑85份及二乙二醇單丁基醚乙酸酯775份，使 用塗料震盪機進行分散處理3小時，而得到分散液1000 份。在這裏，塗料震盪機的媒介是以填充率20%使用0. 4mm (/)氧化锆珠。其次，調配2官能聯苯型環氧樹脂（Japan Epoxy Resins公司製，YX — 4000H)30份、偏苯三曱酸酐 10份、三聚氰胺樹脂（日本Cytec Industries公司製， 16 322457 201118111 . CYMEL370)22份、二乙二醇單丁基醚乙酸酯233份、界面 活性劑0. 3份、及矽烷耦合劑5份，並充分攪拌，而得到 硬化性聚合物300份。在其中調配所述得到的分散液700 份，並充分攪拌，而製作實施例5的濾色片用組成物1000 份。 (雛型濾色片的製作） 使用旋轉塗佈器將所述得到的濾色片用組成物塗佈在 5英对見方、厚度1 mm的玻璃上，而製作試驗片。在加熱 籲板上於90°C使此試驗片乾燥3分鐘後，在熱風爐中於240 °C煅燒20分鐘，而製作作為雛型濾色片的濾色片用組成物 的硬化膜（雛型濾色片E)。 [實施例6] (濾色片用組成物的製作） 以顏料紅254作為140份，並相對於該顏料紅調配高 分子系分散劑85份及二乙二醇單丁基醚乙酸酯775份，使 φ用塗料震盪機進行分散處理3 .小時，而得到分散液1000 份。在這裏，塗料震盪機的媒介是以填充率2 0%使用0. 4mm φ氧化鍅珠。其次，調配2官能聯苯型環氧樹脂（Japan Epoxy Resins公司製，YX— 4000H)29份、偏苯三曱酸酐 10份、三聚氰胺樹脂（日本Cy tec Industries公司製， CYMEL303)21份、二乙二醇單丁基醚乙酸酯235份、界面 活性劑0. 3份、及矽烷耦合劑5份，並充分攪拌，而得到 硬化性聚合物300份。在其中調配所述得到的分散液700 份，並充分攪拌，而製作實施例6的濾色片用組成物1000 17 322457 201118111 份。 (雛型濾色片的製作） 使用旋轉塗佈器將所述得到的濾色片用組成物塗佈在 5英叶見方、厚度1 mm的玻璃上，而製作試驗片。在加熱 ^ 板上於90°C使此試驗片乾燥3分鐘後，在熱風爐中於240 °C煅燒20分鐘，而製作作為雛型濾色片的濾色片用組成物 的硬化膜（雛型濾色片F)。 [實施例7] (濾色片用組成物的製作） _ 以顏料紅254作為140份，並相對於該顏料紅調配高 分子系分散劑85份及二乙二醇單丁基醚乙酸酯775份，使 用塗料震盪機進行分散處理3小時，而得到分散液1000 份。在這裏，塗料震盪機的媒介是以填充率20%使用0. 4mm P氧化鍅珠。其次，調配雙酚S型環氧樹脂（新日鐵化學公 司製，商品名：ESF— 300)33份、偏苯三曱酸酐10份、三 聚氰胺樹脂（日本Cytec Industries公司製，CYMEL370)20 份、二乙二醇單丁基醚乙酸酯232份、界面活性劑0. 3份、 鲁 及矽烷耦合劑5份，並充分攪拌，而得到硬化性聚合物300 份。在其中調配所述得到的分散液700份，並充分攪拌， 而製作實施例7的濾色片用組成物1000份。 (雛型濾色片的製作） 使用旋轉塗佈器將所述得到的濾色片用組成物塗佈在 5英对見方、厚度1mm的玻璃上，而製作試驗片。在加熱 板上於9(TC使此試驗片乾燥3分鐘後，在熱風爐中於240 18 322457 201118111 . °C煅燒20分鐘，而製作作為雛型濾色片的濾色片用組成物 的硬化膜（雛型濾色片G)。 [實施例8] (濾色片用組成物的製作） 以顏料紅254作為140份，並相對於該顏料紅調配高 分子系分散劑85份及二乙二醇單丁基醚乙酸酯775份，使 用塗料震盪機進行分散處理3小時，而得到分散液1000 份。在這裏，塗料震盪機的媒介是以填充率20%使用0.4丽 參 P氧化锆珠。其次，調配雙酚苐型環氧樹脂（新日鐵化學公 司製，商品名：ESF — 300)31份、偏苯三曱酸酐9份、三 聚氰胺樹脂（日本Cytec Industries公司製，CYMEL303)19 份、二乙二醇單丁基醚乙酸酯236份、界面活性劑0.3份、 及矽烷耦合劑5份，並充分攪拌，而得到硬化性聚合物300 份。在其中調配所述得到的分散液700份，並充分攪拌， 而製作實施例8的濾色片用組成物1000份。 φ (雛型濾色片的製作） 使用旋轉塗佈器將所述得到的濾色片用組成物塗佈在 5英吋見方、厚度1mm的玻璃上，而製作試驗片。在加熱 板上於90°C使此試驗片乾燥3分鐘後，在熱風爐中於240 °C煅燒20分鐘，而製作作為雛型濾色片的瀘色片用組成物 的硬化膜（雛型濾色片H)。 [實施例9] (濾色片用組成物的製作） 以顏料紅254作為140份，並相對於該顏料紅調配高 19 322457 201118111 分子系分散劑85份及二乙二醇單丁基醚乙酸酯775份，使 用塗料震盪機進行分散處理3小時，而得到分散液1000 份。在這裏，塗料震盪機的媒介是以填充率20%使用0. 4mm φ氧化锆珠。其次，調配脂環式環氧樹脂（DAICEL化學工 業股份有限公司製，ΕΗΡΕ- 3150)29份、偏苯三曱酸酐10 份、三聚氰胺樹脂（日本Cytec Industries公司製， CYMEL303)21份、二乙二醇單丁基醚乙酸酯235份、界面 活性劑0. 3份、及矽烷耦合劑5份，並充分攪拌，而得到 硬化性聚合物300份。在其中調配所述得到的分散液700 份，並充分攪拌，而製作實施例9的濾色片用組成物1000 份。 (雛型濾色片的製作） 使用旋轉塗佈器將所述得到的濾色片用組成物塗佈在 5英忖見方、厚度1mm的玻璃上，而製作試驗片。在加熱 板上於90°C使此試驗片乾燥3分鐘後，在熱風爐中於240 °C煅燒20分鐘，而製作作為雛型濾色片的濾色片用組成物 的硬化膜（雛型濾色片I)。 [實施例10] (濾色片用組成物的製作） 以顏料紅254作為140份，並相對於該顏料紅調配高 分子系分散劑80份及二乙二醇單丁基醚乙酸酯820份，使 用塗料震盪機進行分散處理3小時，而得到分散液1000 份。在這裏，塗料震盪機的媒介是以填充率20%使用0. 4匪 φ氧化鍅珠。其次，調配具有雙酚苐骨架的環氧丙烯酸酯 20 322457 201118111 • 樹脂酸酐加成物的56.2質量％丙二醇單曱基醚乙酸酯溶液 (新日鐵化學公司製，商品名：V— 259MEM8份、2官能聯 苯型環氧樹脂（Japan Epoxy Resins 公司製，YX— 4000H)28 份、二聚氰胺樹脂（日本Cytec Industries公司製， CYMEL370)15份、二乙二醇單丁基醚乙酸酯223份、界面 活性劑0· 3份、及矽烷耦合劑5份，並充分攪拌，而得到 硬化性聚合物319份。在其中調配所述得到的分散液681 份’並充分授摔’而製作實施例1〇的濾色片用組成物1〇〇〇 •份。 (雛型濾色片的製作） #使用旋轉塗佈器將所述得到的濾色片用組成物塗佈在 5央忖見方、厚度lmm的破璃上，而製作試驗片。在加熱 板上於9G°C使此試驗片乾燥3分鐘後，在熱風爐中於240 C般燒20分鐘，而製作作為離型濾色片_色片用組成物 的硬化膜（雛型濾色片j)。 [實施例11] (濾色片用組成物的製作） 以顏料紅254作為 v ^ x V4i 40份，並相對於該顏料紅調配高 分子糸分散劑85份及二7 _ 〇 —乙〜醇皁丁基醚乙酸酯775份，使 用塗料震盪機進行分散虚理π 士 八,# 处理3小時，而得到分散液1000 伤。;在适裏1料震盪機的媒介是以填充 ρ氧化锆珠。其次，胡阶Λ u.4mm · 凋配2官能聯苯型環氧樹脂（JapanThe test piece was dried at 90 ° C for 3 minutes, and then calcined at ° C for 20 minutes to form a cured film (the prototype color filter A). [Example 2] (Preparation of a composition for a ruthenium sheet) 775 parts of a high-acetate ester was blended with respect to the pigment red, and a dispersion liquid 1000 was obtained as a pigment red 254 as 140 parts, and a molecular system was used. The dispersing agent 85 parts and the diethylene glycol monobutyl group were dispersed by a paint shaker for 3 hours. Here, the medium of the paint shaker is a 鍅.4 丽 P yttrium oxide bead at a filling rate of 2 (10). Next, 29 parts of a bifunctional biphenyl type epoxy resin (γ-χ4〇〇〇H, manufactured by Japan Epoxy Resins Co., Ltd.), 9 parts of trimellitic anhydride, and melamine resin (CYMEL303, manufactured by Cytec Industries, Japan) were prepared. 1 part of a catalyst (San-Apro Co., Ltd., U-CAT SA102), 236 parts of diethylene glycol monobutyl ether acetate, 0.3 parts of a surfactant, and 5 parts of a decane coupling agent. Stirring was carried out to obtain 300 parts of a curable polymer. 700 parts of the dispersion liquid obtained above was prepared and stirred well, and 1000 parts of the composition for color filters of Example 2 was produced. (Production of Young Color Filter) The obtained color filter composition was applied onto a glass of 5 inches square and thickness imin using a spin coater to prepare a test piece. The test piece was dried on a hot plate at 90 ° C for 3 minutes, and then calcined in a hot air oven at 240 ° C for 20 minutes to prepare a cured film of a color filter composition as a release filter. Color filter B). [Example 3] 14 322457 201118111 (Production of color filter composition) Pigment red 254 was used as 140 parts, and 85 parts of polymer dispersant and diethylene glycol monobutyl ether B were prepared with respect to the pigment red. 775 parts of the acid ester was subjected to dispersion treatment for 3 hours using a paint shaker to obtain 1 part of a dispersion. Here, the medium of the paint shaker is used at a filling rate of 20% 〇. 4mm P oxidized wrong beads. Secondly, a 2-terminated biphenyl type epoxy resin (made by japan £?〇^1^51113, 丫乂一〇〇〇4〇〇〇1〇33 parts, trimellitic anhydride 6 parts, melamine resin (Japan Cytec Industries) System, Lu CYMEL303) 19 parts, catalyst (San-Apro Co., Ltd., U-CAT SA102) 1 part, diethylene glycol monobutyl ether acetate 235 parts, surfactant 〇. 5 parts, and 5 parts of a decane coupling agent was stirred well to obtain 300 parts of a curable polymer, and 700 parts of the obtained dispersion liquid was blended therein, and sufficiently mixed, and the composition for a color filter of Example 3 was produced. (Preparation of release filter) The obtained color filter composition was applied onto a glass having a thickness of 1 mm and a test piece by using a spin coater. On the hot plate, at 90° (: the test piece was dried for 3 minutes, and then calcined in a hot air oven at 240 ° C for 20 minutes to prepare a cured film of a color filter composition as a prototype filter. Type enamel C). [Example 4] (Production of color filter composition) Pigment red 254 was used as 140 parts, and relative The pigment red was blended with 85 parts of a polymer dispersant and 775 parts of diethylene glycol monobutyl ether acetate, and subjected to dispersion treatment for 3 hours using a paint shaker to obtain a dispersion of 1000 15 322457 201118111 parts. Here, the paint The medium of the oscillating machine is 0. 4imn : p oxidized wrong beads. Secondly, bisphenol f luorene type epoxy resin (manufactured by Nippon Steel Chemical Co., Ltd., trade name: ESF-300) 37 parts, 6 parts of trimellitic anhydride, 18 parts of melamine resin (CYMEL370, manufactured by Cytec Industries, Japan), 234 parts of diethylene glycol monobutyl ether acetate, 0.3 parts of surfactant, and decane 5 parts of the coupling agent was stirred well to obtain 300 parts of a curable polymer, and 700 parts of the obtained dispersion liquid was blended therein, and stirred well, and 1000 parts of the color filter composition of Example 4 was produced. (Production of Young Color Filter) The obtained color filter composition was applied onto a glass of 5 inches by 11 square meters and a thickness of 1 mm using a spin coater to prepare a test piece. After drying the test piece at 90 ° C for 3 minutes, The film was fired at 240 ° C for 20 minutes in an air furnace to prepare a cured film (matter filter D) which is a composition for a color filter of a prototype color filter. [Example 5] (Constituent for color filter) Manufactured with ® Pigment Red 254 as 140 parts, and dispensed 85 parts of polymer dispersant and 775 parts of diethylene glycol monobutyl ether acetate with respect to the pigment red, and dispersed for 3 hours using a paint shaker. And 1000 parts of the dispersion were obtained. Here, the medium of the paint oscillating machine is 0. 4mm (/) zirconia beads at a filling rate of 20%. Next, 30 parts of a bifunctional biphenyl type epoxy resin (YX-4000H, manufactured by Japan Epoxy Resins Co., Ltd.), 10 parts of trimellitic anhydride, and melamine resin (manufactured by Cytec Industries, Japan, 16 322457 201118111. CYMEL370) 22 parts were prepared. 233 parts of diethylene glycol monobutyl ether acetate, 0.3 parts of a surfactant, and 5 parts of a decane coupling agent were stirred well to obtain 300 parts of a curable polymer. Into this, 700 parts of the dispersion liquid obtained above was prepared and stirred well, and 1000 parts of the composition for color filters of Example 5 was produced. (Production of Young Color Filter) The obtained color filter composition was applied onto a glass of 5 inches square and 1 mm thick using a spin coater to prepare a test piece. The test piece was dried at 90 ° C for 3 minutes on a heating plate, and then calcined in a hot air oven at 240 ° C for 20 minutes to prepare a cured film of a color filter composition as a prototype filter. Type filter E). [Example 6] (Production of color filter composition) Pigment red 254 was used as 140 parts, and 85 parts of a polymer-based dispersing agent and ethylene glycol monobutyl ether acetate 775 were blended with respect to the pigment red. The φ was dispersed by a paint shaker for 3 hours to obtain 1000 parts of a dispersion. Here, the medium of the paint oscillating machine is 0. 4mm φ oxidized yttrium beads at a filling rate of 20%. Next, 29 parts of a bifunctional biphenyl type epoxy resin (YX-4000H, manufactured by Japan Epoxy Resins Co., Ltd.), 10 parts of trimellitic anhydride, and melamine resin (CYMEL303, manufactured by Cytec Industries, Japan) 21 parts, two 235 parts of diol monobutyl ether acetate, 0.3 parts of surfactant, and 5 parts of decane coupling agent were stirred well to obtain 300 parts of a curable polymer. 700 parts of the dispersion liquid obtained above was prepared and stirred well, and the composition for color filters of Example 6 was made into 1000 17 322457 201118111 parts. (Production of Young Filter) The obtained color filter composition was applied onto a glass of 5 inches square and 1 mm thick using a spin coater to prepare a test piece. The test piece was dried on a heating plate at 90 ° C for 3 minutes, and then calcined in a hot air oven at 240 ° C for 20 minutes to prepare a cured film of a color filter composition as a prototype color filter. Type filter F). [Example 7] (Preparation of composition for color filter) _ Pigment red 254 was used as 140 parts, and 85 parts of polymer dispersant and diethylene glycol monobutyl ether acetate were blended with respect to the pigment red. 775 parts were subjected to dispersion treatment using a paint shaker for 3 hours to obtain 1000 parts of a dispersion. 5毫米的氧化鍅珠。 Here, the medium of the paint oscillating machine is a filling rate of 20% using 0. 4mm P yttrium oxide beads. Next, 33 parts of bisphenol S-type epoxy resin (manufactured by Nippon Steel Chemical Co., Ltd., trade name: ESF-300), 10 parts of trimellitic anhydride, and 20 parts of melamine resin (CYMEL370, manufactured by Cytec Industries, Japan) were prepared. 232 parts of diethylene glycol monobutyl ether acetate, 0.3 parts of a surfactant, and 5 parts of a decane coupling agent were stirred well to obtain 300 parts of a curable polymer. 700 parts of the dispersion liquid obtained above was prepared and stirred well, and 1000 parts of the composition for color filters of Example 7 was produced. (Production of Young Filter) The obtained color filter composition was applied onto a glass of 5 inches square and 1 mm thick using a spin coater to prepare a test piece. The test piece was dried on a hot plate at 9 (TC for 3 minutes, and then calcined in a hot air oven at 240 18 322457 201118111 ° C for 20 minutes to prepare a hardening composition for the color filter as a prototype filter. Film (Pigmented Color Filter G) [Example 8] (Production of color filter composition) Pigment red 254 was used as 140 parts, and 85 parts of polymer dispersant and 2nd were prepared with respect to the pigment red. 775 parts of diol monobutyl ether acetate was subjected to dispersion treatment for 3 hours using a paint shaker to obtain 1000 parts of a dispersion. Here, the medium of the paint shaker was used at a filling rate of 20% using 0.4 ginseng P zirconia. Next, 31 parts of bisphenol-based epoxy resin (manufactured by Nippon Steel Chemical Co., Ltd., trade name: ESF-300), 9 parts of trimellitic anhydride, and melamine resin (CYMEL303, manufactured by Cytec Industries, Japan) 19 were prepared. 236 parts of diethylene glycol monobutyl ether acetate, 0.3 parts of surfactant, and 5 parts of decane coupling agent, and fully stirred to obtain 300 parts of a curable polymer. 700 parts of liquid and stirred well, and the filter of Example 8 was produced. 1000 parts of the composition for the sheet. φ (Production of the prototype filter) The obtained color filter composition was applied onto a glass of 5 inches square and 1 mm thick using a spin coater to prepare a test. The test piece was dried on a hot plate at 90 ° C for 3 minutes, and then calcined in a hot air oven at 240 ° C for 20 minutes to prepare a cured film of a composition for a enamel color film as a prototype filter ( [Formula 9] Color filter H) [Example 9] (Production of color filter composition) Pigment red 254 was used as 140 parts, and was mixed with the pigment red by 19 322457 201118111 molecular dispersant 85 parts and two 4mm φ氧化化。 The sulphuric acid is oxidized by a coating of 20%. Next, 29 parts of alicyclic epoxy resin (manufactured by DAICEL Chemical Industry Co., Ltd., ΕΗΡΕ-3150), 10 parts of trimellitic anhydride, and 21 parts of melamine resin (CYMEL303, manufactured by Cytec Industries, Japan) were prepared. 235 parts of diethylene glycol monobutyl ether acetate, interface 3 parts of the agent and 5 parts of the decane coupling agent were stirred well to obtain 300 parts of the curable polymer, and 700 parts of the obtained dispersion liquid was blended therein, and stirred well, and the filter of Example 9 was produced. The composition for a color sheet was 1000 parts. (Preparation of a prototype color filter) The obtained color filter composition was applied onto a glass of 5 inches square and 1 mm thick using a spin coater to prepare a test. The test piece was dried on a hot plate at 90 ° C for 3 minutes, and then calcined at 240 ° C for 20 minutes in a hot air oven to prepare a cured film of a color filter composition as a prototype color filter ( The prototype filter I). [Example 10] (Production of color filter composition) Pigment red 254 was used as 140 parts, and 80 parts of a polymer-based dispersant and ethylene glycol monobutyl ether acetate 820 were blended with respect to the pigment red. The dispersion treatment was carried out for 3 hours using a paint shaker to obtain 1000 parts of a dispersion. Here, the medium of the paint oscillating machine is 0. 4 匪 φ oxidized yttrium beads at a filling rate of 20%. Next, an epoxy acrylate having a bisphenol fluorene skeleton was prepared. 20 322457 201118111 • A 56.2% by mass propylene glycol monodecyl ether acetate solution of a resin anhydride adduct (manufactured by Nippon Steel Chemical Co., Ltd., trade name: V-259MEM8) , 2 parts biphenyl type epoxy resin (YX-4000H, manufactured by Japan Epoxy Resins Co., Ltd.), 15 parts, melamine resin (CYMEL370, manufactured by Cytec Industries, Japan), 15 parts, diethylene glycol monobutyl ether acetate 223 parts of the ester, 0. 3 parts of the surfactant, and 5 parts of the decane coupling agent were stirred well to obtain 319 parts of the curable polymer, in which 681 parts of the obtained dispersion were formulated and fully discarded. The composition for a color filter of Example 1 was prepared in 1 part by volume. (Production of a prototype color filter) # The obtained color filter composition was applied to a 5th phase using a spin coater. A test piece was prepared by seeing a square and a glass having a thickness of 1 mm. The test piece was dried on a hot plate at 9 G ° C for 3 minutes, and then fired in a hot air oven at 240 C for 20 minutes to prepare a release filter. The color film _ color film is a cured film of the composition (the prototype color filter j). Example 11] (Preparation of a color filter composition) Pigment red 254 was used as 40 parts of v ^ x V4i, and 85 parts of a polymer 糸 dispersant and 2 7 _ 〇 - 乙 〜 alcohol soap were prepared with respect to the pigment red. 775 parts of butyl ether acetate, using a paint shaker for dispersion disambiguation π Shi Ba, # treatment for 3 hours, and a dispersion of 1000 is obtained. The medium of the shaker is filled with ρ zirconia beads. Secondly, Hu JieΛ u.4mm · Withered 2-functional biphenyl type epoxy resin (Japan

Epoxy Resins 公司製,νγ 衣 U〜4000H)26份、偏苯三甲酸針8 份、三聚氰胺樹脂（日太p ^ tytec Industries 公司製， 322457 21 201118111 CYMEL303)24份、觸媒（San-Apro股份有限公司製’U —CAT SA102)1份、二乙二醇單丁基醚乙酸酯236份、界面活性 劑0. 3份、及矽烷耦合劑5份，並充分攪拌’而得到硬化 性聚合物300份。在其中調配所述得到的分散液700份’ 並充分攪拌，而製作實施例11的濾色片用組成物1000份。 (雛型濾色片的製作） 使用旋轉塗佈器將所述得到的濾色片用組成物塗佈在 5英时見方、厚度lmm的玻璃上，而製作試驗片。在加熱 板上於90°C使此試驗片乾燥3分鐘後，在熱風爐中於240 。(：煅燒20分鐘’而製作作為雛型濾色片的濾色片用組成物 的硬化膜（離型濾色片K)。 [比較例1] (濾色片用組成物的製作） 以顏料紅254作為140份，並相對於該顏料紅調配高 分子系分散劑80份及二乙二醇單丁基醚乙酸酯820份，使 用塗料震盪機進行分散處理3小時，而得到分散液1000 份。在這裏，塗料震盪機的媒介是以填充率20%使用0. 4mm p氧化锆珠。其次，調配3官能丙烯酸系單體（SART0MER 股份有限公司製’ SR — 444)20份、雙酚第型環氧樹脂（新 日鐵化學公司製，商品名：ESF— 300)25份、三聚氰胺樹 脂（日本 Cytec Industries 公司製，CYMEL370)24 份、二 乙二醇單丁基醚乙酸酯246份、界面活性劑0. 3份、及矽 烷耦合劑5份，並充分攪拌，而得到硬化性聚合物320份。 在其中調配所述得到的分散液680份，並充分攪拌，而製 22 322457 201118111 作比較例1的濾色片用組成物l〇〇〇份。 (雛型濾色片的製作） 使用旋轉塗佈器將所述得到的濾色片用組成物塗佈在 5英吋見方、厚度1mm的玻璃上，而製作試驗片。在加熱 板上於90 C使此試驗片乾燥3分鐘後，在熱風爐中於24〇 °C煅燒20分鐘，而製作作為雛型濾色片的濾色片用組成物 的硬化膜（雛型濾色片L)。 [比較例2] (濾色片用組成物的製作） 以顏料紅254作為140份，並相對於該顏料紅調配高 分子糸分散劑85份及二乙二醇單丁基趟乙酸酯775份，使 用塗料震盈機進行分散處理3小時，而得到分散液woo 份。在這裏’塗料震盪機的媒介是以填充率2〇%使用〇 4丽 φ氧化錯珠。其次’調配具有雙_骨架的 樹脂的56.2質量％丙二醇單曱基醚乙酸 丙烯駄酉曰 學公司製’商品名：V— 259ΜΕ)43份、2官妒、啊日鐵化 脂（Japan Epoxy Resins公司製，γχ〜本坦環氧樹 份、過氧化苯甲醯的40質量％二曱笨溶液（日、…、、列 司製，NYPERBMT —Κ40)3 份、二Λ -鮮 π _ 艰:份有 份 能丙烯酸系單體（SART0MER股份有限公司努10份、3官 份、過氣化笨甲醯的40質量％二甲岔、n ' H 368)24 限公 醇單乙基醚r 、界面活性劑0.5份、及矽烷耦合劑5份，' G酸酯215 而得到硬化性聚合物300份。在並充分攪拌， 八τ碉配所 液700份，並充分攪拌，而製作比較例2 件到的分散 物1000份。 白;慮色片用組成 322457 23 201118111 (離型濾色片的製作） “使用旋轉塗佈器將所述得到的遽色片肋成物塗佈在 5英吋見方、厚度lmm的玻璃上，而製作試驗片。在加熱 板上於9G C使此試驗片乾燥3分鐘後’在熱風爐中於240 °C锻燒20分鐘’而製作作為雛型濾色片的遽色片用組成物 的硬化膜（雛型濾色片M)。 [比較例3] (濾色片用組成物的製作） 以顏料紅254作為140份，並相對於該顏料紅調配高 刀子系分散劑85份及二乙二醇單丁基醚乙酸酯份，使 用塗料震堡機進行分散處理3小時，而得到分散液1〇〇〇 伤。在14裏，塗料震盪機的媒介是以填充率2〇%使用〇. 4mm 0氧化鍅珠。其次，調配偏苯三曱酸酐25份、三聚氰胺樹 脂（日本 Cytec Industries 公司製，CYMEL370)52 份、二 乙二醇單乙基醚乙酸酯218份、界面活性劑〇 5份、及矽 烷耦合劑5份，並充分攪拌，而得到硬化性聚合物3卯份。 在其中調配所述得到的分散液7〇〇份，並充分攪拌，而製 作比較例3的濾色片用組成物J〇〇〇份。 (雛型濾色片的製作） 使用旋轉塗佈器將所述得到的濾色片用組成物塗佈在 5英吋見方、厚度imm的玻璃上，而製作試驗片。在加熱 板上於90°C使此試驗片乾燥3分鐘後，在熱風爐中於240 C锻燒20分鐘’而製作作為雛型濾色片的濾色片用組成物 的硬化膜（雛型濾色片N)。 24 322457 201118111Epoxy Resins, 26 parts of νγ clothing U~4000H), 8 parts of trimellitic acid needle, melamine resin (made by Ritai Ptytech Industries, 322457 21 201118111 CYMEL303) 24 parts, catalyst (San-Apro limited stock) 1 part of the company 'U-CAT SA102), 236 parts of diethylene glycol monobutyl ether acetate, 0.3 parts of surfactant, and 5 parts of decane coupling agent, and fully stirred to obtain a hardening polymer 300 copies. Into the obtained dispersion liquid, 700 parts' was placed therein and stirred well, and 1000 parts of the color filter composition of Example 11 was produced. (Production of Young Color Filter) The obtained color filter composition was applied onto a glass having a thickness of 1 mm and a thickness of 1 mm using a spin coater to prepare a test piece. The test piece was dried on a hot plate at 90 ° C for 3 minutes and then at 240 in a hot air oven. (: calcination for 20 minutes) to produce a cured film (release color filter K) of a color filter composition as a color filter. [Comparative Example 1] (Production of color filter composition) Pigment Red 254 was used as 140 parts, and 80 parts of a polymer dispersant and 820 parts of diethylene glycol monobutyl ether acetate were blended with respect to the pigment red, and dispersion treatment was carried out for 3 hours using a paint shaker to obtain a dispersion 1000. Here, the medium of the paint oscillating machine is 0. 4 mm p zirconia beads at a filling rate of 20%. Secondly, 20 parts of a trifunctional acryl monomer (SR-444, manufactured by SART0MER Co., Ltd.), bisphenol 25 parts of the first type epoxy resin (manufactured by Nippon Steel Chemical Co., Ltd., trade name: ESF-300), 24 parts of melamine resin (CYMEL370, manufactured by Cytec Industries, Japan), 246 parts of diethylene glycol monobutyl ether acetate 5 parts of the surfactant, and 5 parts of the decane coupling agent, and fully stirred to obtain 320 parts of the curable polymer. The 680 parts of the obtained dispersion was prepared therein and stirred well to make 22 322457 201118111 The composition for a color filter of Comparative Example 1 (Production of Young Filter) The obtained color filter composition was applied onto a glass of 5 inches square and 1 mm thick using a spin coater to prepare a test piece. After the test piece was dried at 90 C for 3 minutes, it was calcined in a hot air oven at 24 ° C for 20 minutes to prepare a cured film of a color filter composition as a prototype filter (the prototype color filter L). [Comparative Example 2] (Preparation of a color filter composition) Pigment red 254 was used as 140 parts, and 85 parts of a polymer oxime dispersing agent and diethylene glycol monobutyl phthalate acetic acid were prepared with respect to the pigment red. 775 parts of ester, using a coating shaker for dispersion treatment for 3 hours, to obtain a dispersion of woo. Here, the medium of the paint shaker is a 填充4 φ oxidized wrong bead with a filling rate of 2%. 56.2% by mass of the resin of the double-skeleton, propylene glycol monodecyl ether acetate, propylene, and the company's 'product name: V-259ΜΕ', 43 parts, 2 bureaucratic, ah, Japan's iron oxide (made by Japan Epoxy Resins Co., Ltd., γχ) ~ Bentan epoxy tree, 40% by mass of bismuth peroxide, diterpene solution (Day, ,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,, Mass % dimethyl hydrazine, n ' H 368) 24 phenolic monoethyl ether r, 0.5 part of surfactant, and 5 parts of decane coupling agent, 'G acid ester 215 to obtain 300 parts of curable polymer. After thoroughly stirring, 700 parts of the solution was placed and stirred well, and 1000 parts of the dispersion of Comparative Example 2 was prepared. White; color component composition 322457 23 201118111 (production of release filter) "The obtained enamel ribs were coated on a glass of 5 inches square and 1 mm thick using a spin coater. A test piece was prepared, and the test piece was dried on a hot plate at 9 G C for 3 minutes, and then calcined at 240 ° C for 20 minutes in a hot air oven to prepare a composition for a enamel color film as a prototype color filter. (Comparative Example 3) (Preparation of a color filter composition) Pigment red 254 was used as 140 parts, and high-knife dispersion agent 85 parts and two were prepared with respect to the pigment red. Ethylene glycol monobutyl ether acetate fraction was dispersed for 3 hours using a paint shaker machine to obtain a dispersion of 1 dispersion. In 14 miles, the medium of the paint shaker was used at a filling rate of 2%. 4. 4mm 0 yttrium oxide beads. Secondly, 25 parts of trimellitic anhydride, 52 parts of melamine resin (CYMEL370, manufactured by Cytec Industries, Japan), 218 parts of diethylene glycol monoethyl ether acetate, and surfactant 5 parts, 5 parts of decane coupling agent, and stirred well to obtain a hardening polymer 3 The 7 parts of the dispersion obtained above were prepared and thoroughly stirred to prepare a composition for a color filter of Comparative Example 3 (manufacture of a prototype filter) using a spin coating The test piece was prepared by coating the obtained color filter composition on a glass of 5 inches square and thickness imm, and drying the test piece at 90 ° C for 3 minutes on a hot plate. In a hot air oven, calcined at 240 C for 20 minutes to produce a cured film (matter filter N) which is a composition for a color filter of a prototype filter. 24 322457 201118111

VV

[比較例4] (濾色&gt;1用組成物的製作） 以顏料紅254作為140份，並相對於該顏料紅調配高 分子系分散劑85份及二乙二醇單丁基醚乙酸酯775份，使 用塗料震盪機進行分散處理3小時，而得到分散液1000 份。在這裏，塗料震盪機的媒介是以填充率20%使用0. 4mni P氧化鍅珠。其次，調配3官能丙烯酸系單體（SARTOMER 股份有限公司製，SR— 368)58份、過氧化苯甲醯的40質 • 量％二曱苯溶液（日油股份有限公司製，NYPER BMT-K40)3 份、二乙二醇單丁基醚乙酸酯234份、界面活性劑0. 3份、 及矽烷耦合劑5份，並充分攪拌，而得到硬化性聚合物300 份。在其中調配所述得到的分散液700份，並充分攪拌， 而製作比較例4的濾、色片用組成物10 0 0份。 (雛型濾色片的製作） 使用旋轉塗佈器將所述得到的濾色片用組成物塗佈在 φ 5英忖見方、厚度1mm的玻璃上，而製作試驗片。在加熱 板上於90°C使此試驗片乾燥3分鐘後，在熱風爐中於240 °C煅燒20分鐘，而製作作為雛型濾色片的濾色片用組成物 的硬化膜（雛型濾色片0)。 將所述實施例及比較例中所得的濾色片用組成物的調 配方式彙整表示在表1及表2。此外，對於由各濾色片用 組成物所得的硬化膜，進行如下述的評估。將結果彙整記 載在表1。再者，表1中所記載的使用材料是如下述。 YX— 4000H :聯苯型環氧樹脂（Japan Epoxy Resins公司 25 322457 201118111 製） ESF — 300 :雙酚苇型環氧樹脂（新日鐵化學公司製） EHPE:脂環式環氧樹脂（DAICEL化學工業股份有限公司 製，EHPE-3150) 偏苯三曱酸酐：（三菱瓦斯化學公司製） V — 259ME :具有雙酚荞骨架的環氧丙烯酸酯樹脂的56. 2 質量％丙二醇單曱基醚乙酸酯溶液（新日鐵化學公司製） CYMEL370 :羥曱基型甲基化三聚氰胺樹脂（日本Cytec Industries公司製），有效成分88〇/〇 CYMEL303:完全烷基型曱基化三聚氰胺樹脂（日本Cytec Industries 公司製） SR—444 :季戊四醇三丙烯酸酯（sart〇MER公司製） SR _ 368 :參（2-羥基乙基）異氰脲酸酯三丙烯酸酯 (SART0MER 公司製） 矽烷耦合劑：3-縮水甘油氧基丙基三曱氧基矽烷（cjjisso 公司製，Sila-Ace S—510) 界面活性劑：聚醚改質聚二甲基矽氧烷的51%丙二醇單 丁基醚乙酸醋溶液（BYK Japan公司製，byk — 330) 觸媒：過氧化苯曱醯的40質量％二甲笨溶液（日油股份有 限公司製，NYPER BMT-K40) 溶劑：二乙二醇單丁基醚乙酸g旨（DA ICEL·化學公司製） 322457 26 201118111 表1 實施例 11 CD CO i 1 〇〇 i t LO CO o CD CO οα o o c=&gt; o CO Oi 5 m 〇 ◎ 〇 ◎ ◎ 婼S ^«； 00 C&lt;I 1 〇〇 LO 1 in CO o CO CS3 00 CD g OO LO OO CO CO 〇 〇 〇 ◎ ◎ 實施例9 Cft CM o 1 1 LO CO 1 LO ΓΟ CO o o o r-^ OO cr&gt; o o LO 呀 〇 ◎ 〇 ◎ ◎ 實施例8 I CO 1 1 1 σ&gt; 1 1 LO CO Q 1 CO CO C&gt;3 o o g T&quot;H CO CO s ΙΛ 呀 〇 ◎ 〇 ◎ ◎ 實施例7 i CO CO c=&gt; 1 s 1 I 1 m CO o 1 CM CO C^J o o g r—H s r—^ 0¾ 05 LO 兮 〇 ◎ 〇 ◎ 〇 實施例6 05 CNI 1 1 CS 1 1 1 1 ΙΛ CO CD 1 in CO CS3 o o g OO o LO 呀 〇 ◎ 〇 ◎ 〇 實施例5 另 1 1 1 (N1 CM 1 1 1 LO CO 1 CO CO &lt;NI o o g g CO o LO 却 〇 ◎ ◎ ◎ 〇 實施例4 1 1 CO 1 OO 1 1 1 m CO o 1 CO CV] o o g r—H in u〇 ΙΛ 呀 〇 〇 〇 ◎ 〇 實施例3 CO CO 1 1 CO 1 1 ΟΪ 1 1 in LO O LO CO oa o o 〇 ◦ CO ir&gt; CO 00 in 〇 〇 〇 ◎ ◎ 實施例2 07 03 1 i σ&gt; 1 1 s I 1 m CO 〇 Η CO CO C&lt;I o o G&gt; cr&gt; 05 LT&gt; 〇 ◎ 〇 ◎ ◎ 實施例1 写 1 1 00 1 CO Cv] 1 1 1 in CO o 1 05 CO CM ΙΛ 00 CD 〇 〇 S. CO OO CO CO 〇 〇 ◎ 〇 〇 YX-4000H ESF-300 EHPE i偏笨三甲酸酐 1 V259ME ! CYMEL370 CYHEL303 1 SR-444 SR-368 矽烷耦合劑 界面活性劑 觸媒 溶劑 顏料分散體 &lt; CQ 顏料濃度（90 密著性（％) 溶劑浸潰後 煅燒後 室溫lw 40°C lw &lt; CQ 其他 成分比 (官能基數） _1 饋入量 Jj 黏度 安定性[Comparative Example 4] (Preparation of composition for color filter &gt; 1) Pigment red 254 was used as 140 parts, and 85 parts of a polymer-based dispersant and diethylene glycol monobutyl ether acetate were blended with respect to the pigment red. 775 parts of the ester was subjected to dispersion treatment for 3 hours using a paint shaker to obtain 1000 parts of a dispersion. Here, the medium of the paint oscillating machine is 0. 4mni P yttrium oxide beads at a filling rate of 20%. Next, 58 parts of a trifunctional acrylic monomer (SR-368, manufactured by SARTOMER Co., Ltd.) and 40 mass% of a solution of benzamidine peroxide were prepared. (NYPER BMT-K40, manufactured by Nippon Oil Co., Ltd.) 3 parts, 234 parts of diethylene glycol monobutyl ether acetate, 0.3 parts of a surfactant, and 5 parts of a decane coupling agent were stirred well to obtain 300 parts of a curable polymer. Into this, 700 parts of the dispersion liquid obtained above was prepared, and the mixture was stirred well, and 100 parts of the composition for filtration and color sheets of Comparative Example 4 was prepared. (Production of Young Filter) The obtained color filter composition was applied onto a glass of φ 5 inches square and 1 mm thick using a spin coater to prepare a test piece. The test piece was dried on a hot plate at 90 ° C for 3 minutes, and then calcined in a hot air oven at 240 ° C for 20 minutes to prepare a cured film of a color filter composition as a prototype color filter. Color filter 0). Table 1 and Table 2 show the arrangement of the color filter composition obtained in the above examples and comparative examples. Further, the cured film obtained from the respective color filter compositions was evaluated as follows. The results are summarized in Table 1. Further, the materials used in Table 1 are as follows. YX—4000H: Biphenyl type epoxy resin (produced by Japan Epoxy Resins Co., Ltd. 25 322457 201118111) ESF — 300 : Bisphenolphthalein type epoxy resin (manufactured by Nippon Steel Chemical Co., Ltd.) EHPE: alicyclic epoxy resin (DAICEL chemistry) Industrial Co., Ltd., EHPE-3150) Trimellitic anhydride: (Mitsubishi Gas Chemical Co., Ltd.) V - 259ME: epoxy acrylate resin having a bisphenol fluorene skeleton, 56.2% by mass of propylene glycol monodecyl ether Acid solution (manufactured by Nippon Steel Chemical Co., Ltd.) CYMEL370: Hydroxyl-based methylated melamine resin (manufactured by Cytec Industries, Japan), active ingredient 88〇/〇CYMEL303: fully alkyl-type thiolated melamine resin (Japan Cytec) Manufactured by Industries, Inc. SR-444: Pentaerythritol triacrylate (sart MER) SR _ 368 : ginseng (2-hydroxyethyl) isocyanurate triacrylate (manufactured by SART0MER Co., Ltd.) decane coupling agent: 3- Glycidoxypropyltrimethoxy decane (Sily-Ace S-510, manufactured by CJ Jisso Co., Ltd.) Surfactant: 51% propylene glycol monobutyl ether acetate vinegar solution of polyether modified polydimethyl siloxane BYK Japa n company system, byk — 330) Catalyst: 40% by mass of benzoquinone solution (manufactured by Nippon Oil Co., Ltd., NYPER BMT-K40) Solvent: Diethylene glycol monobutyl ether acetate (manufactured by DA ICEL Chemical Co., Ltd.) 322457 26 201118111 Table 1 Example 11 CD CO i 1 〇〇it LO CO o CD CO οα ooc=&gt; o CO Oi 5 m 〇◎ 〇◎ ◎ 婼S ^«; 00 C&lt ; I 1 〇〇 LO 1 in CO o CO CS3 00 CD g OO LO OO CO CO 〇〇〇 ◎ ◎ Example 9 Cft CM o 1 1 LO CO 1 LO ΓΟ CO ooo r-^ OO cr> oo LO ◎ 〇 ◎ ◎ Example 8 I CO 1 1 1 σ&gt; 1 1 LO CO Q 1 CO CO C>3 oog T&quot;H CO CO s ΙΛ 〇 〇 〇 ◎ ◎ Example 7 i CO CO c=&gt; 1 s 1 I 1 m CO o 1 CM CO C^J oogr—H sr—^ 03⁄4 05 LO 兮〇◎ 〇◎ 〇Example 6 05 CNI 1 1 CS 1 1 1 1 ΙΛ CO CD 1 in CO CS3 oog OO o LO 〇 〇 〇 ◎ 〇 Example 5 Another 1 1 1 (N1 CM 1 1 1 LO CO 1 CO CO &lt; NI oogg CO o LO 〇 ◎ ◎ ◎ 〇 Example 4 1 1 CO 1 OO 1 1 1 m CO o 1 CO CV] oogr H in u〇ΙΛ 〇〇〇 〇〇〇 〇 Example 3 CO CO 1 1 CO 1 1 ΟΪ 1 1 in LO O LO CO oa oo 〇◦ CO ir&gt; CO 00 in 〇〇〇 ◎ ◎ Example 2 07 03 1 i σ &gt; 1 1 s I 1 m CO 〇Η CO CO C&lt;I oo G&gt;cr&gt; 05 LT&gt; 〇 ◎ 〇 ◎ ◎ Example 1 Write 1 1 00 1 CO Cv] 1 1 1 in CO o 1 05 CO CM ΙΛ 00 CD 〇〇S. CO OO CO CO 〇〇◎ 〇〇YX-4000H ESF-300 EHPE i Partial tricarboxylic anhydride 1 V259ME ! CYMEL370 CYHEL303 1 SR-444 SR-368 矽 耦合 coupling agent surfactant solvent Pigment Dispersion &lt; CQ Pigment Concentration (90 Adhesion (%) After solvent impregnation, room temperature lw 40°C lw &lt; CQ Other composition ratio (functional number of bases) _1 Feed amount Jj Viscosity stability

27 322457 201118111 表2 比較例1 比較例2 比較例3 比較例4 饋入$ A YX-4000H *— 10 — — ESF-300 25 — — — ΕΗΡΕ — — — — B 偏笨三曱酸酐 — — 25 — V259ME — 43 — — C CYMEL370 24 — 52 — CYMEL303 — — — — 其他 SR-444 20 — — — SR-368 — 24 — 58 矽烷耦合劑 5 5 5 5 界面活性劑 0.3 0.5 0.5 0.5 觸媒 — 3 — 3 溶劑 246 215 218 234 (D) 顏料分散體 681 700 700 700 成分比 (官能基數） A 100 100 0 0 B 0 151 100 0 C 158 0 100 0 顏料濃度(％) 36 45 45 45 密著性(％) X 〇 X 〇 膜變化率 溶劑浸潰後 無法測 定 〇 X 〇 煅燒後 無法測 定 X X X 黏度 安定性 室溫1 w ◎ ◎ 〇 ◎ 40°C lw ◎ ◎ 〇 ◎ (耐藥品性評估） 將硬化膜浸潰在40°C的N-曱基-2-吡咯啶酮（NMP)中 30分鐘後，在熱風爐中於230°C煅燒30分鐘，而進行耐藥 品性評估試驗後，以浸潰在丽P前的硬化膜的膜厚為基 準，求出浸潰處理後的硬化膜的膜厚變化率、及煅燒處理 後的硬化膜的膜厚變化率，並分別以下述基準進行評估。 28 322457 201118111 ◎:膜變化率未達±5% 〇：膜變化率未達±10% X :膜變化率為±10%以上 &quot;(密著性評估） 在所述耐藥品性評估試驗中，對於浸潰在溶劑中的硬化 膜，以製作至少100個棋盤格的方式進行橫切（cross-cut)， 接著使用〇611〇丨3口6(註冊商標）進行剝下(^661丨叩）試驗 後，分別藉由肉眼評估浸潰在疆P中的浸潰處理後的硬化 • 膜、及浸潰處理後再進行煅燒處理後的硬化膜的棋盤格的 剝離狀態。評估的基準如下述。 〇：完全未觀察到有剝離 X:觀察到有些許剝離 (安定性評估） 濾色片用組成物的黏度安定性評估，是以剛製作出濾 色片用組成物後的黏度為基準，求出在室溫保管濾色片用 Φ組成物經過1週後的黏度的變化率、及在40°C保管濾色片 用組成物經過1週後的黏度的變化率，並分別以下述基準 評估。 ◎:變化率未達10% 〇：變化率未達20% X :變化率為20%以上 如表1及表2所示，關於實施例及比較例中所得的雛 型濾色片的耐藥品性及密著性的評估，實施例的雛型濾色 片是密著性皆良好，且耐藥品性評估也是在膜變化率為土 29 322457 201118111 10%以内的範圍内。另一方面，比較例的雛型濾色片是密著 性不良，而發生剝離。此外得知，即使在密著性良好的比 較例2及4的情形中’耐藥品性試驗後賴變化率也大。 【圖式簡單說明】 無 【主要元件符號說明】 無 30 32245727 322457 201118111 Table 2 Comparative Example 1 Comparative Example 2 Comparative Example 3 Comparative Example 4 Feeding $ A YX-4000H *— 10 — — ESF-300 25 — — — ΕΗΡΕ — — — — B Partially tribasic anhydride — — 25 — — — — — — — — — — — — — — — — — — — — — — — — — — — — 3 Solvent 246 215 218 234 (D) Pigment dispersion 681 700 700 700 Component ratio (number of functional groups) A 100 100 0 0 B 0 151 100 0 C 158 0 100 0 Pigment concentration (%) 36 45 45 45 Adhesion (%) X 〇X 〇 film change rate cannot be measured after solvent impregnation 〇X 〇 Cannot be measured after calcination XXX Viscosity stability room temperature 1 w ◎ ◎ 〇 ◎ 40°C lw ◎ ◎ 〇 ◎ (anti-drug evaluation) The cured film was immersed in N-mercapto-2-pyrrolidone (NMP) at 40 ° C for 30 minutes, and then calcined in a hot air oven at 230 ° C for 30 minutes, and subjected to a chemical resistance evaluation test, followed by dipping The film thickness of the cured film before the ruthenium P is used as a reference, and after the impregnation treatment is obtained Cured film thickness change rate and thickness change rate of the cured film after the calcination process, and the following criteria were evaluated. 28 322457 201118111 ◎: The film change rate is less than ±5% 〇: The film change rate is less than ±10% X: The film change rate is ±10% or more&quot; (adhesion evaluation) In the drug resistance evaluation test For the cured film impregnated in the solvent, cross-cut is performed in a manner of making at least 100 checkerboards, and then peeled off using 〇611〇丨3口6 (registered trademark) (^661丨叩) After the test, the peeling state of the checkerboard after the impregnation treatment after the impregnation treatment in the P was inspected by the naked eye, and the cured film after the impregnation treatment was performed, respectively. The benchmark for evaluation is as follows. 〇: No peeling was observed at all X: A slight peeling (stability evaluation) was observed. The viscosity stability evaluation of the color filter composition was based on the viscosity immediately after the color filter composition was produced. The rate of change of the viscosity after one week of the Φ composition for the color filter was stored at room temperature, and the rate of change of the viscosity after one week of storage of the color filter composition at 40 ° C, and evaluated by the following criteria . ◎: The rate of change is less than 10% 〇: The rate of change is less than 20% X: The rate of change is 20% or more. As shown in Table 1 and Table 2, the drug resistance of the prototype filter obtained in the examples and the comparative examples is resistant. For the evaluation of the properties and the adhesion, the prototype color filters of the examples were all good in adhesion, and the evaluation of the chemical resistance was also within the range of the film change rate of 10 322457 201118111 10%. On the other hand, the prototype color filter of the comparative example was inferior in adhesion and peeled off. Further, it was found that even in the case of Comparative Examples 2 and 4 in which the adhesion was good, the rate of change after the drug resistance test was large. [Simple diagram description] None [Main component symbol description] None 30 322457

Claims (1)

201118111 七、申請專利範圍： 1. 一種濾色片用組成物，其特徵在於，在溶劑中包含2 • 官能以上的多官能環氧化合物（A)、3官能以上的多官 ' 能羧酸衍生物化合物（B)、2官能以上的多官能胺基樹 脂（C)[惟，胺基樹脂所具有的官能基為-NH、-NR’、 -NR’OH、或一NR’OR’（R’表示烷基）]、以及著色材（D) 作為必須成分，並且，相對於去除溶劑後餘留的固形份 的合計質量著色材（D)的質量比率為10%至60%。 鲁 2.如申請專利範圍第1項所述的濾色片用組成物，其特徵 在於，相對於所述（A)成分中的環氧乙烷環100當量， (B)成分的羧酸基為在50至110當量的範圍，且同時（C) 成分的胺基官能基為在10至150當量的範圍。 3. 如申請專利範圍第1項或第2項所述的濾色片用組成 物，其特徵在於，使用在藉由喷墨法而形成像素。 4. 一種硬化物，其特徵在於，是使申請專利範圍第1項至 第3項中任一項所述的濾色片用組成物在160至25(TC ♦進行硬化而得。 5. —種濾色片，其特徵在於，是使用申請專利範圍第4 項所述的硬化物而形成像素。 31 322457 201118111 四、指定代表圖：本案無圖式 (一)本案指定代表圖為：第（）圖。 •— (二)本代表圖之元件符號簡單說明： 五、本案若有化學式時，請揭示最能顯示發明特徵的化學式： 本案無代表化學式 3 322457201118111 VII. Patent application scope: 1. A composition for a color filter comprising a polyfunctional epoxy compound (A) having a function of 2 or more and a polyfunctional carboxylic acid derived from a trifunctional or higher functional group in a solvent. Compound (B), a bifunctional or higher polyfunctional amine-based resin (C) [However, the functional group of the amino resin is -NH, -NR', -NR'OH, or a NR'OR' (R) 'The alkyl group' and the coloring material (D) are essential components, and the mass ratio of the total mass material (D) to the solid content remaining after the solvent is removed is 10% to 60%. The color filter composition according to the first aspect of the invention, characterized in that the carboxylic acid group of the component (B) is 100 equivalents to the oxirane ring in the component (A). It is in the range of 50 to 110 equivalents, and at the same time, the amine functional group of the (C) component is in the range of 10 to 150 equivalents. 3. The color filter composition according to claim 1 or 2, wherein the pixel is formed by an inkjet method. 4. A cured product obtained by subjecting the color filter composition according to any one of claims 1 to 3 to 160 to 25 (TC ♦ hardened). A color filter characterized in that a pixel is formed using the cured material described in claim 4 of the patent application. 31 322457 201118111 IV. Designated representative figure: This case has no drawing (1) The designated representative figure of the case is: ) - (2) A brief description of the symbol of the representative figure: 5. If there is a chemical formula in this case, please disclose the chemical formula that best shows the characteristics of the invention: This case does not represent the chemical formula 3 322457