201117942 六、發明說明： 【發明所屬之技術領域】 本發明係關於一種用於模内轉印（In-Mold Roller， IMR，IMR)之軟性模具及其製造方法，及具有此軟性模具 的模内裝飾材料，以及利用模内裝飾材料所製成的射出外 觀件。 【先前技術】 現今的消費性產品多重視包裝，尤其是講求要有質感 及個性化，才能刺激消費者的購買慾望。因此現在的電子 產品外殼設計有越來越多不同的變化，以滿足使用者對質 感的要求。相對的，如何在單調的物件外殼上產生變化， 使其具有多彩光滑面的外殼，以及有層次感的圖案，也是 業者所追求的方向。 相較於傳統的表面裝飾方法，如喷塗、熱轉印、覆膜 等技術相比，模内轉印技術是目前風行的表面裝飾技術。 因為其製作過程能在射出充填的同時，對塑膠件表面進行 印刷與裝飾，進而提高塑膠製品的附加價值，不需二次加 工、顏色的多樣性、塑膠件表面的耐化學性、而ί刮性等， 並讓外表呈現光滑且有層次感，而且可連續式生產自動化 程度較高。 請參照圖1Α所示，其為一種習知之模内轉印材料之 示意圖。模内轉印薄膜1包括一基材11、一離型層12、 一高硬度的保護層13、一圖案層14以及一接著層15。通 201117942 =:模内轉印薄膜1送入射出模具内進行注塑 二it :此模内轉印薄膜1附著在塑料16上。注 將基材11從模内轉印_上分離， θ所不’表面為平面且有—高硬度的保護層u 保護並帶有圖案層14的射出件2 湖 5000903 所揭露。 β 寻扪 4343752 舍，^讓射出件的表面更具立體感以及色彩更加豐 及圖案層的多色印二層的；面霧度以 膜— m ㈣如圖2A所不，模内轉印薄 、匕括-基材U，此基材u的表面 :=:17,再塗佈-高硬度的保護二it 色P刷的方式得到一多色圖案層14、i4a、i4b、 内接下來再塗佈一接著層15。通過送膜機將此模 P賴la送人射出模具内進行注塑（圖未顯示 此模内轉㈣膜la时在_ 16上。、 U上分離，得到如圖2B;=; ^此射出件2a表面有一局部帶有凹陷的顆粒狀霧化表面 :案層⑷，、1心 /成之f7刷層，如美國專利5955204所揭露。 另外還有-種稱為髮絲紋的產品，顧名思義是產品表 面上有細長條紋如髮絲般的條紋因而 :二 參―在一以刷輪在基材llb表面上刷二= 髮絲般的髮絲(刷輪方式未顯示），接續如圖= 八依序在基材iib上以塗佈方式塗佈成一離型層⑶、 201117942 —保護層13b、一圖案層14與接著層15，得到一模内轉 印薄膜lb。請參閱目3C，最後通過送膜機，將此模内轉 印薄膜lb送入射出才莫具内進行注塑（圖未顯示），則此模 内轉印薄膜lb附著在塑料16上。注塑後將基材⑽與離 型層12b從模内轉印薄膜lb上分離，得到如目3c所示的 射出件2b。此射出件2b#立體觸感之髮絲面⑶b，此髮 絲面mb的表面結構與基材llb上的髮絲自⑴互為鏡像 結構。利用控制刷輪的粗細以及壓力等參數，可得到不同 的外觀效果，如長髮絲、短髮絲等。 相較於習知技術，模内轉印技術製程中要讓射出件的 1 卜親有層次感f靠多次套色印刷技術，或是在基材尚未塗 布保護層前先在基材表面局部塗佈結構，藉以製造表面立 體結構，但是局部塗佈結構無法製作精細的微結構圖宰。 若是以習知的刷輪方式製作髮絲紋，雖可在表面形成 立體觸感的髮絲面，但是在刷輪製程中產生的毛屑卻會造 成良率與工序上的困難。 σ 因此，如何針對上述問題提供一種新賴的模*** :題:相式生產又擁有立體結構的圖案，實為當前重要 【發明内容】 具 於上述課題，本發明之目的為提供—種軟性模 刹、厂造方式、具有此軟性模具賴内裝飾材料、以及 利用核内㈣材料所製成的射出外觀件。軟性模具係能在 201117942 模内轉印製程中作為生產過程中的一個載體，又具有立體 微結構圖案，使具有軟性模具的模内裝飾材料可得到具有 立體觸感甚至是多色圖案之射出外觀件。 緣是，為達上述目的，依據本發明之一種軟性模具用 於立體結構轉印製程，軟性模具包括一基材以及一微結構 圖案層，微結構圖案層具有一第一圖案，微結構圖案層設 置於基材之上。 於本發明之一實施例中，軟性模具更包括一黏著層， • 黏著層設置於基材與微結構圖案層之間。 於本發明之一實施例中，基材的厚度係介於ΙΟμιη至 . 250μιη 〇 • 於本發明之一實施例中，軟性模具在攝氏160至350 度時，縱向以及橫向的拉伸率在10%至200%之間。 於本發明之一實施例中，微結構圖案層具有至少一第 一子圖案及一第二子圖案，第一子圖案之平均深度係與第 φ 二子圖案之平均深度不相同。 於本發明之一實施例中，第一子圖案之密度係與第二 子圖案之密度不相同。 為達上述目的，依據本發明之一種用於立體結構轉印 製程之軟性模具製作方法，製作方法包括下列步驟：提供 一基材；塗佈一光硬化樹脂於基材；將一具有微結構圖案 的金屬滾輪壓印該光硬化樹脂；以及形成一微結構圖案層 於基材之上。 於本發明之一實施例中，製作方法更包括步驟：以紫 201117942 外光硬化微結構圖案層。 為達上述目的，依據本發明之一種模内裝飾材料，用 於立體結構轉印製程，模内裝飾材料包括一軟性模具、一 離型層以及一轉印材料層。軟性模具具有一基材以及一微 結構圖案層。離型層設置於微結構圖案層。轉印材料層設 置於離型層。 於本發明之一實施例中，轉印材料層具有一保護層、 一印刷層及一接著層。保護層設置於離型層。印刷層設置 於保護層。接著層設置於印刷層。 於本發明之一實施例中，離型層的厚度係介於〇·〇5μηι 至3 μηι之間。 於本發明之一實施例中，模内裝飾材料係應用於平面 熱轉印、立體熱轉印、模***出轉印及水轉寫製程。 為達上述目的，依據本發明之一種射出外觀件係由一 軟性模具成型，軟性模具具有一第一圖案，射出外觀件包 括一轉印材料層以及一塑料。轉印材料層具有一第二圖 案，其中第二圖案係與第一圖案互成鏡像，且第二圖案之 表面粗糖度Ra為0.7 μηι以上或Rz為6.5 μηι以上，塑料承 載轉印材料層。 承上所述，本發明藉由設置一微結構圖案層於軟性模 具之基材上，再以具有微結構圖案層之軟性模具，加工得 到模内裝飾材料，以及利用模内裝飾材料之製作的射出外 觀件。更詳細來說，利用具有立體結構軟性模具，製造得 到模内裝飾材料，再利用於此模内裝飾材料經過注塑之製 201117942 程之後，可得到具有立體結構表面之射出外觀件。如此一 來’生產者可藉由軟性模具上微結顧案之深度及角度設 计，而於射出外觀件上形成任意深度及任意角度變化的立 體結構（其圖案與軟性模具的微結構圖案互為鏡像），並 能增加觸感甚至是提升色彩姊度，其是财習知技術的 產品無法比較的。 【實施方式】 一以下將參照相關圖式，說明依據本發明較佳實施例之 應用此軟性模具製造之模嶋材料以及 的模内靖程。其中相同的元件將 以相同的符號加以說明。 第一實施例 的干’其為本發明第一實施例之軟性模具 程，:二㈣例之軟性模具3係用於立體結構轉印製 壬 明立體結構轉印製程係包含埶 模***出轉印及水轉以韓㈣3…轉Ηρ立體熱轉印、 或圖宰，且苴胸丨田程，而產生了立體的結構 或H其所利用的模具包含但不限制為滾輪（邊r) 权性模具3包括-基材31與一微社槿円柰思 結構圖荦声盔目士 。说'纟口構圖案層32，微 案層32之表面，微結構_二:=於=圖 ”’基…材質可為聚上基 201117942 (Polyethylene Terephthalate, PET )、聚碳酸酉旨 (polycarbonate, PC )、無延伸聚丙烯（Casted PolyPropylene， CPP )、共撥M 定向聚丙稀·（ Oriented polypropylene, OPP )。 而基材31之厚度係介於ΙΟμπι至250μπι。本實施例中，基 材31係以厚度50μηι之聚對苯二曱酸乙二酸酯 (Polyethylene Terephthalate，PET)為例。 基材31上的一微結構圖案層32，其係以光硬化樹脂 組成，此光硬化樹脂係由複數個官能基之壓克力高分子寡 聚合物、環氧樹酯系高分子寡聚合物、聚氨酯壓克力系寡 聚合物、單體或是上述之任意組合之其中之一。當形成之 軟性模具3在攝氏16〇至350度時，縱向以及橫向的拉伸 率在10%至200%之間。 本發明揭露一種用於立體結構轉印製程之軟性模具 製作方法，製作方法包括下列步驟：提供一基材31 ;塗佈 -光硬化树脂於基材31 ;將—具有微結構圖案的金屬滚輪 C印光=化樹脂’以及形成—微結構圖案層於基材 之上明同日守參照圖5與圖6，以說明較佳實施例之製造 方法。 圖 '、’、、、召知技術的電鑄槽的示意圖。一 JL有全像 效綠結構圖案面411之玻瑪板41(微結構圖案面AH係 可為I 生模具上的微結構圖案）置放於—以氨基 石黃酸=鍍液42之電鑄槽4中，以錄金屬…乍為陽極，已 'Hi 理的具有全像效果的微結構圖案面411 之；反41做為陰極，控制時間與電流則可得到-厚度 10 201117942 為50μιη到200μηι厚度之具有立體結構圖案441之金屬薄 板44,而玻璃板41之微結構圖案面411與金屬薄板44之 立體結構圖案441互為鏡像效果。利用雷射在一塗佈光阻 的玻璃板41上製作全像微結構圖案為一習知技術，在此 則不加敘述，但其精細程度、以及圖案的深度、角度均可 任意變化。在此實施例中，以電鑄方式製作的微結構圖案 之金屬薄板44厚度為70μιη。 請同時參閱圖4、圖5及圖6所示，其中圖6為軟性 ® 模具的製作過程之一示意圖。本實施例之軟性模具3係藉 由連續式紫外光硬化壓花（UV embossing)方式製作。基 .材31經過一上膠機構45將光硬化樹脂46塗佈在基材31 上，經過一包覆金屬薄板44的金屬滾輪47，且金屬薄板 44具有立體結構圖案441，再以紫外光源48照射硬化後， 則可得到一種具有微結構圖案層32的軟性模具3。微結構 圖案層32具有一第一圖案321，第一圖案321係與金屬薄 φ 板44之立體結構圖案441互成鏡像。本實施例之微結構 圖案層32的厚度則可藉由壓制輪49a與49b來控制。 由於軟性模具3的微結構圖案層32係可由玻璃板41 上的微結構圖案面411來定義。因此，生產者可藉由對玻 璃板41上微結構圖案面411的設計，來產出任何想形成 於軟性模具3上的圖案。 請參照圖7所示，其為第一實施例之模内裝飾材料的 示意圖。本實施例之模内裝飾材料5係用於立體結構轉 印製程，模内裝飾材料5包括一軟性模具3、一離型層51 11 201117942 及-轉印材料層52。軟性模具3具有 結構圖案層32。離型層51設置 ^ M及一微 材料層5 2設置於離型# 5 ^ ^ —構圖案層3 2。轉印 右一… 本貧施例之轉印材料層52且 曰521、一印刷層522與一接著層523 保護層521設置於離型層51，印刷層曰 ’ 切’接著層523設置於印刷層μ/ 護層 ⑶具有複數色彩522a、522b、522e之印刷層 52更且有—奔荽恳r回+ 一 522d。轉印材料層 與印刷層5^之^ 1 )，黏著層設置於保護層切 之間。本貫施例之離型層 請μη】至3_之間。 义層5】之厚度係介於 立a 1+V、!* 8所7’其為第―實施例之射出外觀件的干 ::内裝飾材料5係具有軟性模具3。當圖 5以达膜機將送入射出模具内進 、 注塑後將軟性模具3及離型層51從射示）， 則可得到具有立體觸感的微結構圖案面之卜一 及多色圖案之射出外圖案524 轉印材料層52兔 出外减件6係包括 盆中，㈣6 塑料61係承载轉印材料層52。 :”係指射出成型產品的塑膠射出件部八，， :疋爾話的外殼、筆記型電腦的外殼、二:刀:例 或其他電子裝置的外殼等射出件。 二圖案似，係與軟性模具3之第—圖宰^ 52上的第 且第二圖案524 ' 1互成鏡像， 6.5_以上。阳以上或Rz為 12 201117942 如圖7所示，離型居201117942 VI. Description of the Invention: [Technical Field] The present invention relates to a soft mold for In-Mold Roller (IMR, IMR) and a method for manufacturing the same, and an in-mold having the same Decorative materials, as well as injection appearance parts made of in-mold decorative materials. [Prior Art] Today's consumer products pay more attention to packaging, especially in order to have a sense of quality and personalization, in order to stimulate consumers' desire to buy. Therefore, there are more and more different changes in the design of electronic product casings to meet the user's requirements for quality. In contrast, how to make changes in the monotonous object shell, so that it has a colorful smooth surface shell, and a layered pattern is also the direction pursued by the industry. In-mold transfer technology is currently popular surface decoration technology compared to conventional surface decoration methods such as spray coating, thermal transfer, and film coating. Because the production process can print and decorate the surface of the plastic part while the injection is filled, thereby increasing the added value of the plastic product, without secondary processing, color diversity, chemical resistance of the surface of the plastic part, and scraping Sex, etc., and make the appearance smooth and layered, and the degree of automation of continuous production is high. Referring to Figure 1A, it is a schematic view of a conventional in-mold transfer material. The in-mold transfer film 1 includes a substrate 11, a release layer 12, a high-hardness protective layer 13, a pattern layer 14, and an adhesive layer 15. 201117942 =: In-mold transfer film 1 is sent into the mold for injection molding. Second: This in-mold transfer film 1 is attached to the plastic 16. Note The substrate 11 is separated from the in-mold transfer, and the surface of the θ is not planar and the protective layer u having a high hardness is protected and the exit member 2 having the patterned layer 14 is disclosed by Lake 5000903.扪 扪 4343752 舍, ^ make the surface of the injection piece more stereoscopic and more colorful and multi-color printing of the layer of the pattern匕 - - Substrate U, the surface of the substrate u: =: 17, and then coated - high hardness protection two it color P brush to obtain a multi-color pattern layer 14, i4a, i4b, inside and then An adhesive layer 15 is applied. The mold is sprayed into the mold by a film feeding machine to be injected into the mold for injection molding (the figure is not shown in the in-mold (4) film la when it is on _16, and U is separated, and as shown in Fig. 2B; =; ^ this injection piece The surface of 2a has a partially atomized atomized surface with a depression: a layer (4), a core/f1 brush layer, as disclosed in U.S. Patent 5,955,204. There is also a product called hairline, as the name implies. There are slender stripes on the surface of the product, such as hairline-like stripes. Therefore, the two ginseng--a brush-like hair on the surface of the substrate llb is brushed (the brush wheel is not shown), and the following figure = eight A release layer (3), 201117942 - a protective layer 13b, a pattern layer 14 and an adhesive layer 15 are applied to the substrate iib in a coating manner to obtain an in-mold transfer film lb. See Item 3C, and finally The film feeding machine feeds the in-mold transfer film 1b into the mold (not shown), and the in-mold transfer film 1b is attached to the plastic 16. After the injection, the substrate (10) and the release film are separated. The layer 12b is separated from the in-mold transfer film 1b to obtain an injection member 2b as shown in Fig. 3c. This injection member 2b# is stereoscopic The hair surface (3)b, the surface structure of the hair surface mb and the hair on the substrate 11b are mirror images of each other (1). By controlling the thickness of the brush wheel and the pressure, etc., different appearance effects, such as long hair, can be obtained. Short hair, etc. Compared with the prior art, the in-mold transfer technology process requires the layer of the injection member to have a layered feel by multiple color printing techniques, or before the substrate is coated with a protective layer. The surface of the substrate is partially coated to form a three-dimensional structure, but the partial coating structure cannot produce a fine microstructure. If the hair is made by a conventional brush wheel method, a stereoscopic touch can be formed on the surface. Hair surface, but the dander generated in the brush wheel process will cause yield and process difficulties. σ Therefore, how to provide a new type of in-mold shot for the above problems: Title: Phase production and three-dimensional structure The pattern is actually important [invention] In view of the above problems, the object of the present invention is to provide a soft mold brake, a factory manufacturing method, a decorative material having the soft mold, and a nuclear core (4) The injection molding made of the material. The soft mold can be used as a carrier in the production process in the 201117942 in-mold transfer process, and has a three-dimensional microstructure pattern, so that the in-mold decoration material with a soft mold can be obtained with a stereo touch. The sensation is even the appearance of the multi-color pattern. The edge is that, in order to achieve the above object, a soft mold according to the present invention is used for a three-dimensional structure transfer process, and the flexible mold comprises a substrate and a microstructure pattern layer, and the microstructure pattern The layer has a first pattern, and the microstructure pattern layer is disposed on the substrate. In one embodiment of the invention, the flexible mold further comprises an adhesive layer, and the adhesive layer is disposed between the substrate and the microstructure pattern layer. In one embodiment of the present invention, the thickness of the substrate is between ΙΟμηη and .250μηη 〇• In one embodiment of the present invention, the tensile modulus of the flexible mold is 10 in the longitudinal and transverse directions at 160 to 350 degrees Celsius. Between % and 200%. In an embodiment of the invention, the microstructure pattern layer has at least a first sub-pattern and a second sub-pattern, and the average depth of the first sub-pattern is different from the average depth of the φ second sub-pattern. In an embodiment of the invention, the density of the first sub-pattern is different from the density of the second sub-pattern. In order to achieve the above object, a soft mold manufacturing method for a three-dimensional structure transfer process according to the present invention comprises the steps of: providing a substrate; coating a photo-curable resin on the substrate; and having a microstructured pattern The metal roller embosses the photohardenable resin; and forms a microstructured pattern layer on the substrate. In an embodiment of the invention, the manufacturing method further comprises the step of: hardening the microstructure pattern layer with purple 201117942 external light. To achieve the above object, an in-mold decorative material according to the present invention is used for a three-dimensional structure transfer process, and the in-mold decorative material comprises a flexible mold, a release layer and a transfer material layer. The flexible mold has a substrate and a microstructure pattern layer. The release layer is disposed on the microstructure pattern layer. The transfer material layer is placed on the release layer. In an embodiment of the invention, the transfer material layer has a protective layer, a printed layer and an adhesive layer. The protective layer is disposed on the release layer. The printed layer is placed on the protective layer. The layer is then placed on the printed layer. In one embodiment of the invention, the thickness of the release layer is between 〇·〇5μηι to 3 μηι. In one embodiment of the invention, the in-mold decorative material is applied to planar thermal transfer, stereo thermal transfer, in-mold ejection transfer, and water transfer processes. To achieve the above object, an ejection appearance member according to the present invention is formed by a flexible mold having a first pattern, and the injection appearance member includes a transfer material layer and a plastic. The transfer material layer has a second pattern in which the second pattern is mirror images of the first pattern, and the surface roughness of the second pattern is 0.7 μηι or more or Rz is 6.5 μηι or more, and the plastic carries the transfer material layer. According to the above description, the present invention is prepared by providing a microstructure pattern layer on a substrate of a flexible mold, and then using a soft mold having a microstructure pattern layer to obtain an in-mold decoration material, and using the in-mold decoration material. Shoot the appearance. More specifically, an in-mold decorative material is produced by using a soft mold having a three-dimensional structure, and an in-mold decorative material having a three-dimensional structure surface can be obtained after the in-mold decorative material is subjected to injection molding. In this way, the producer can form a three-dimensional structure of arbitrary depth and arbitrary angle change on the appearance part by the depth and angle design of the micro-junction on the soft mold (the pattern and the micro-structure pattern of the soft mold are mutually For mirroring), it can increase the tactile sensation and even increase the color ambiguity, which is incomparable to the products of the financial know-how. [Embodiment] Hereinafter, a mold material manufactured by using the flexible mold and an in-mold process according to a preferred embodiment of the present invention will be described with reference to the related drawings. The same elements will be described by the same symbols. The dry mold of the first embodiment is the soft mold process of the first embodiment of the present invention, and the soft mold 3 of the second (fourth) example is used for the three-dimensional structure transfer system, and the three-dimensional structure transfer process system includes the injection molding in the mold. Printing and water transfer to Han (four) 3... turn Η 立体 stereo heat transfer, or map slaughter, and 苴 chest 丨 field, and produced a three-dimensional structure or H the mold used to include but not limited to the wheel (side r) right The mold 3 includes a substrate 31 and a micro-cosmetic structure. Say 'the mouth of the pattern layer 32, the surface of the micro-layer 32, the microstructure _ two: = = map" 'base... material can be poly-based base 201117942 (Polyethylene Terephthalate, PET), polycarbonate (polycarbonate, PC), Casted PolyPropylene (CPP), orientated polypropylene (Oriented polypropylene (OPP). The thickness of the substrate 31 is between ΙΟμπι and 250μπι. In this embodiment, the substrate 31 is A polyethylene terephthalate (PET) having a thickness of 50 μm is exemplified. A microstructure pattern layer 32 on the substrate 31 is composed of a photocurable resin, and the photohardenable resin is composed of a plurality of photohardenable resins. a functional acrylic oligo polymer, an epoxy resin oligo polymer, a urethane acrylate oligomer, a monomer, or any combination thereof, when formed soft When the mold 3 is between 16 〇 and 350 ° C, the stretching ratio in the longitudinal direction and the transverse direction is between 10% and 200%. The invention discloses a soft mold manufacturing method for a three-dimensional structure transfer process, and the manufacturing method comprises the following steps: provide a substrate 31; a coating-photohardening resin on the substrate 31; a metal roller C with a microstructure pattern C-printing = resin" and a formation-microstructure pattern layer on the substrate Figure 6 is a view showing a manufacturing method of the preferred embodiment. Fig. 2, a schematic view of an electroforming groove of the calling technology. A JL has a full-image green structure pattern surface 411 of a glass plate 41 (microstructure pattern) The surface AH can be a microstructured pattern on the I mold) placed in the electroforming tank 4 of the aminophosphoric acid=plating solution 42 to record the metal...乍 as the anode, and the HI has the holographic image. The effect of the microstructure pattern surface 411; the reverse 41 as the cathode, the control time and current can be obtained - the thickness 10 201117942 is 50μιη to 200μηι thickness of the metal sheet 44 having the three-dimensional structure pattern 441, and the microstructure pattern of the glass sheet 41 The surface 411 and the three-dimensional structure pattern 441 of the metal thin plate 44 are mirror images of each other. It is a conventional technique to form a holographic microstructure pattern on a glass plate 41 coated with photoresist by laser, and will not be described here, but The degree of detail, as well as the depth and angle of the pattern In this embodiment, the thickness of the thin metal plate 44 of the microstructure pattern produced by electroforming is 70 μm. Please refer to FIG. 4, FIG. 5 and FIG. 6 simultaneously, wherein FIG. 6 is a manufacturing process of the soft® mold. A schematic view of the flexible mold 3 of the present embodiment is produced by a continuous UV embossing method. The substrate 31 is coated on the substrate 31 via a gluing mechanism 45. After passing through a metal roller 47 covering the metal thin plate 44, and the metal thin plate 44 has a three-dimensional structure pattern 441, and then hardened by the ultraviolet light source 48, a soft mold 3 having the microstructured pattern layer 32 can be obtained. The microstructure pattern layer 32 has a first pattern 321 which is mirror images of the three-dimensional structure pattern 441 of the metal thin φ plate 44. The thickness of the microstructure pattern layer 32 of this embodiment can be controlled by the pressing wheels 49a and 49b. Since the microstructure pattern layer 32 of the flexible mold 3 can be defined by the microstructure pattern surface 411 on the glass sheet 41. Therefore, the manufacturer can produce any pattern desired to be formed on the flexible mold 3 by designing the microstructure pattern surface 411 on the glass plate 41. Referring to Fig. 7, it is a schematic view of the in-mold decorative material of the first embodiment. The in-mold decoration material 5 of the present embodiment is used for a three-dimensional structure transfer process, and the in-mold decoration material 5 includes a flexible mold 3, a release layer 51 11 201117942 and a transfer material layer 52. The flexible mold 3 has a structural pattern layer 32. The release layer 51 is provided with a M and a micro-material layer 52 which are disposed on the release pattern #5^^-pattern layer 3 2 . Transferring the right one... The transfer material layer 52 of the lean embodiment and the 曰521, a printed layer 522 and an adhesive layer 521 are disposed on the release layer 51, and the printed layer is cut and the layer 523 is disposed on the printing layer. The layer μ/layer (3) has a printed layer 52 of a plurality of colors 522a, 522b, 522e and has a rushed back + a 522d. The transfer material layer and the printed layer 5^1), the adhesive layer is disposed between the protective layer cut. The release layer of this embodiment should be between μη] and 3_. The thickness of the layer 5 is in the range of a 1+V, !*8, which is the dry of the appearance of the first embodiment. The inner decorative material 5 has a flexible mold 3. When the film is fed into the mold and injected into the mold, and the flexible mold 3 and the release layer 51 are imaged, the micro-pattern surface of the micro-pattern surface can be obtained. The exiting outer pattern 524, the transfer material layer 52, the rabbit outer stripping member 6 is included in the pot, and the (four) 6 plastic 61 series carrying the transfer material layer 52. "" refers to the plastic injection part 8 of the injection molding product, : the outer casing of the Muir dial, the outer casing of the notebook computer, the second: the knife: the case or the casing of other electronic devices, etc. The second pattern, the system and the softness The first and second patterns 524 '1 on the first and second patterns 524 '1 of the mold 3 are mirror images of each other, 6.5_ or more. The upper side of the yang or the Rz is 12 201117942.
m 1尽度在0.05jum到3M 且均勻地塗佈在微結椹 j 3帥1之間， 口稱圖案層32的結構面 於冨模内裝倚材料5细|6 /、功能在 赵由射出成型與塑料貼合德〜 離型層51將軟性模且 後，可藉由 -、3撕除。離型層51可於^4^ 製作時一併形成，或者 性模具3 再一 故於 者了於製作轉印材料層52 併形成。離型層51^丨 2 ^ 的材料組成並非本發明之重 此不加贅述。 里，·、，占m 1 degree is between 0.05jum and 3M and is evenly coated between the micro-junction j 3 handsome 1, the structural surface of the pattern layer 32 is said to be in the die, and the material is thin. Molding and plastic bonding De~ The release layer 51 will be soft-molded and then peeled off by -, 3. The release layer 51 can be formed at the time of fabrication, or the mold 3 can be formed and formed on the transfer material layer 52. The material composition of the release layer 51^丨 2 ^ is not the weight of the present invention and will not be described again. Li,·,,zhan
以外保;Π的功用除了防止印刷層522被刮傷與脫落 ^八 重要功能是要讓射出外觀件ό表面具有與軟 性模具3鏡像效果的立體圖案。保護層521是由光硬_ 脂、溶劑型_或是上述材料任意組成之，以塗佈 佈在離型層51上。 a 印刷層522是由設計者依照其外觀設計的圖案，可利 用網版印刷、凸版印刷、凹版印刷的套色方式製作，該印 刷層522可構成特定的色彩分部或圖案排列，或是以蒸鍍 或濺鍍方式達到一亮面的光澤效果。 如圖8所示，接著層523的功用在於使轉印材料層52 能夠黏著在—物體表面上。在此實施例中，塑料61可藉 由射出成型到接著層523與轉印材料層52結合。 苐一實施例 請參照圖9八及圖9B所示，其中圖9A為本發明第二 實施例之軟性模具的示意圖，圖9B為第二實施例之軟性 模具之微結構圖案層的俯視示意圖。軟性模具3a包括一基 材31與一微結構圖案層32a，而此微結構圖案層32a具有 13 201117942 一髮絲紋圖案之一第一子圖案322與一具有立體結構圖案 之一第二子圖案323。其中，基材31之材質可為聚對苯二 曱酸乙二酸酉旨（Polyethylene Terephthalate，PET)、聚碳酸 西旨(polycarbonate, PC )、無延伸聚丙烯（Casted PolyPropylene，CPP )、共擠壓定向聚丙稀（Oriented polypropylene, 0PP)。而基材 31 之厚度為 ΙΟμιη 至 250μιη。 本實施例中，基材31係以厚度為50μιη之聚對苯二甲酸乙 二酸醋（Polyethylene Terephthalate，PET)為例。 設置於基材31上的一微結構圖案層32，其係以光硬 化樹脂組成，此光硬化樹脂係由複數個官能基之壓克力高 分子寡聚合物、環氧樹脂系高分子寡聚合物、聚氨酯壓克 力系寡聚合物、單體或是上述之任意組合之其中之一。當 軟性模具3a於攝氏160至350度時，軟性模具3a之縱向 以及橫向的拉伸率於10%至200%之間。 本實施例之微結構圖案層32具有至少一第一子圖案 322以及至少一第二子圖案323。第一子圖案322之平均 深度係與第二子圖案323之平均深度不相同，第一子圖案 322之密度係與第二子圖案323之密度不相同。舉例來說， 本實施例之第一子圖案322係以髮絲紋圖案為例，而第二 子圖案323係以公司名或品牌名稱的立體結構圖案為例， 第二子圖案323係以位於整個軟性模具3a的中央為例，可 作為醒目圖案的標示，然非用以限定本發明。藉由將第— 子圖案322之平均深度或密度設計與第二子圖案323之平 均深度或密度不相同，以突顯第一子圖案322或第二子圖 14 201117942 案323之立體結構。值得一提的 二子圖㈡23交界處係可為霧面狀之表面。案，、弟 接著’請參照圖1〇至圖12B，以說明製作出圖9A及 9B :具有第一子圖案及第二子圖案的軟性模具，所需 的金屬溥板或金屬滾輪。請先參照圖ig，其為金屬薄板 術^製作流程圖。於步驟—中，先依實際圖面設計，先 、電細排版„又汁一立體結構圖案441a，立體結構圖案 具3a上的第二子圖案323互為鏡像圖案，再將此 ==比例…輸出，製作成一光軍版;光罩版的 1=:一習知技術，在此則不加敘述。本實施例中， 第㈣具3a係具有第—子圖案322 (髮絲紋路）以及 =子圖案323 (立體結構圖案，公司名 係用以形成第二子圖案323 光罩 滾輪47上為例。 再將金屬核44a貼至金屬 面，：二:?1，在—金屬滾輪307上金屬薄板…的表 薄板44 1、石、砂紙等具有粗糙表面的物體，在全屬 涛板44a的立德纟士播固杰 你孟屬 紋。適用於製作 的表面研磨刷出髮絲 、襄作髮、、、糸紋路的鋼刷、磨 到500翻之間。 入我其翻號在40 於步驟二及步驟四中 之金屬薄板44a塗佈光阻’細3磨後传到髮絲紋路表面 驟一之光罩;s ，，二巧冼、預烤、烘乾後，取步 尤罩板以平行曝光機曝光。 於步驟五中，將步驟 他表面經過頻影、^驟:已曝先的髮絲紋路金屬薄板 ^先、電解拋光等，即可得到如圖η 15 201117942 所示之金屬滚輪47a，其上具有髮絲紋圖案442與立體結 構圖案441a。其中髮絲紋圖案442與軟性模具3a上的第 一子圖案322互為鏡像圖案，而立體結構圖案441亦與軟 性模具3a上的第二子圖案323互為鏡像圖案。步驟四與步 驟五稱為曝光顯影技術，此為一習知技術，在此不加贅述。 更詳細來說，本實施例將光阻設置於金屬薄板44a 上，再對金屬薄板44a及光罩板進行曝光，將光罩板之圖 案將轉移到具有光阻的金屬薄板44a上；接著，於金屬薄 板44a上喷灑顯影劑，以將曝光後的光阻溶解於顯影劑 中，進而以蝕刻之方式，將未受光阻保護之金屬薄板44a 進行蝕刻，以呈現我們所設計之立體結構圖案441a。最 後，再以去光阻液及有機溶液去除金屬薄板44a上的光 阻。經由上述之步驟後，即可呈現如圖12A所示之金屬薄 板44a，金屬薄板44a具有髮絲紋圖案442與立體結構圖 案441a。本實施例之立體結構圖案441a之密度係小於髮 絲紋圖案442之密度，而立體結構圖案44la之平均深度係 * 大於髮絲紋圖案442之平均深度（故形成的軟性模具的第 一子圖案之平均深度係小於第二子圖案之平均深度），然 其非用以限定本發明，立體結構圖案及髮絲紋圖案之密度 及平均深度，甚至是圖案的角度皆可以依據設計或客戶之 需求，而設計有所不同。 請參照圖12B，其為金屬薄板之另一示意圖。設計者 亦可直接將一具有立體結構圖案441b之一塑膠模具7,設 置於金屬薄板44b上，以簡化製作金屬薄板44b的過程。 16 201117942 接下來再利用如圖11之帶有圖案之金屬滚輪47a以連 續式紫外線壓印成型的方式得到一軟性模具3a。連續式紫 外線壓印成型的方法在第一實施例中已詳細闡述，故在此 則不加贅述。 接下來請參照圖13所示，本實施例製作之軟性模具 3a作為模内裝飾材料應用於模内裝飾（IMR)之較佳實施 例。模内裝飾材料5a係包括一具有微結構圖案的軟性模具 3a、一離型層51a與一轉印材料層52a。轉印材料層52a • 係具有一保護層521a、一印刷層522與一接著層523。其 中，印刷層522具有一色彩522a。 -請參閱圖14，當模内裝飾材料5a以送膜機將送入射 出模具内進行注塑（圖未顯示），注塑後將此軟性模具3a 從射出件上分離，則可得到一射出外觀件6a。射出外觀件 6a係包含一轉印材料層52a與一塑料61。其中，轉印材料 層52a上的保護層521a已具有由軟性模具3a轉印而來的 φ 立體觸感的髮絲紋圖案之第一子圖案525與立體結構圖案 之第二子圖案526。值得一提的是，由於軟性模具3a上的 第一子圖案525之平均深度係小於第二子圖案526的平均 深度，且第一子圖案525之平均密度係大於第二子圖案526 的平均密度，因此，射出外觀件52a中的第一子圖案525 之平均深度也小於第二子圖案526之平均深度，第一子圖 案525之平均密度也大於第二子圖案526的平均密度，可 以突顯第一子圖案525或第二子圖案526之立體觸感。其 中，圖案密度較高可指平坦未經過加工的表面較少，圖案 17 201117942 密度較低可指平坦未經過加工的表面較多。 在本實施例f的_層51a、_4 521 的功能與製作方式在第—杏竑似击认 a 不加贊述。在$ -例中均已詳細闊述，在此則 印刷層522是由設計者依照其外觀設計的圖宰，可利 用網版印刷、凸版印刷、凹版印刷的套色方式制： 層522可構成特定的色彩分部或圖案排列，或== _方式的到一亮面的光澤效果，在本實施例中，I有= 絲紋圖案之第-子圖案525與具有立體結構 : 圖案似分別以不同的顏色區塊之印刷層522來呈:一子 且之=述再本發明藉由設置一微結構圖案層於軟性模 "# 再以具有該微結構圖案屬之軟性模具’加工 得到模内裝飾材料，以及利用模内裝飾材料之製ς的 外親件。更詳細來說，利用具有立體結構軟性模呈，制迭 ^到模内裝飾材料，再利用於此模内裝飾材料經過注塑^ =產體結構表面之射出外觀件。如此 一末生產者可猎由軟性模具上微結構圖案之深度及角产 觀件上形成任意深度及任意角度變化的 、二:構（其圖案與軟性模具的微結構圖案互為鏡像）， 亚此增加觸感甚至是提升色彩飽和度， 的產品無法比㈣。 ^現有習知技術 以上所述僅為舉例性，而非為限制性者。θ 明可以被製成以各式的改變以及變化 ^ λ 的領域與精神。舉例來說，微結 18 201117942 度、微結構呈現出的目視效果、以及搭配微結構不同的印 刷圖案效果、各實施例中微結構與印刷圖案的搭配方式均 可全面調整或部分調整，任何未脫離本發明之精神與範 疇，而對其進行之等效修改或變更，均應包含於履附之申 請專利範圍中。 【圖式簡單說明】 圖1A係習知之权内裝飾材料的不意圖， 圖1B係習知之模内轉印製程的示意圖； 圖2A係另一種習知之用於模内裝飾材料的示意圖； 圖2B係另一種習知之模内轉印製程的示意圖； 圖3A與圖3B係又一種習知之一種用於模内轉印髮絲 紋材料結構圖， 圖3C係又一種習知之髮絲膜模内轉印製程示意圖； 圖4係為本發明第一實施例之一種軟性模具的示意 圖； 圖5係為電鑄槽的示意圖； 圖6係為本發明第一實施例之軟性模具製造過程的示 意圖； 圖7係為本發明第一實施例之模内裝飾材料的示意 圖， 圖8係為本發明第一實施例之射出外觀件的示意圖； 圖9A係為本發明第二實施例之軟性模具的示意圖； 圖9B係為本發明第二實施例之軟性模具之微結構圖 19 201117942 案層的示意圖； 圖10係為本發明第三實施例之金屬純的製作流程 圖； 厂、立^ 11係為本發明第二實施例之㈣絲紋的金屬滾輪 圖12A係為本發明第二實施例之金屬薄板的示意圖； 圖12B係為本發明第二實施例之金屬薄板的另— 圖； 不忍In addition to preventing the printed layer 522 from being scratched and peeled off, the function of the cymbal is to make the surface of the appearance member have a three-dimensional pattern mirrored with the soft mold 3. The protective layer 521 is optionally composed of photohard grease, solvent type or the above materials to be coated on the release layer 51. a printing layer 522 is a pattern designed by the designer according to its design, and can be made by screen printing, letterpress printing, gravure printing, and the printing layer 522 can form a specific color division or pattern arrangement, or be steamed. Plating or sputtering to achieve a glossy finish. As shown in Fig. 8, the function of the subsequent layer 523 is to enable the transfer material layer 52 to adhere to the surface of the object. In this embodiment, the plastic 61 can be bonded to the transfer material layer 52 by injection molding to the adhesive layer 523. DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS Referring to Figures 9 and 9B, Fig. 9A is a schematic view of a flexible mold according to a second embodiment of the present invention, and Fig. 9B is a top plan view showing a microstructure pattern layer of the flexible mold of the second embodiment. The flexible mold 3a includes a substrate 31 and a microstructure pattern layer 32a, and the microstructure pattern layer 32a has 13 201117942 a hairline pattern, a first sub-pattern 322 and a second sub-pattern having a three-dimensional structure pattern. 323. The material of the substrate 31 may be Polyethylene Terephthalate (PET), Polycarbonate (PC), Casted PolyPropylene (CPP), and coextrusion. Oriented polypropylene (OPP). The thickness of the substrate 31 is ΙΟμιη to 250μηη. In the present embodiment, the substrate 31 is exemplified by polyethylene terephthalate (PET) having a thickness of 50 μm. a microstructure pattern layer 32 disposed on the substrate 31, which is composed of a photo-curable resin which is an oligo-polymerization of a plurality of functional groups of acrylic polymer oligomers and epoxy resin polymers. , polyurethane oligopolymer, monomer or one of any combination of the above. When the flexible mold 3a is at 160 to 350 degrees Celsius, the stretch ratio of the flexible mold 3a in the longitudinal direction and the transverse direction is between 10% and 200%. The microstructure pattern layer 32 of this embodiment has at least a first sub-pattern 322 and at least a second sub-pattern 323. The average depth of the first sub-pattern 322 is different from the average depth of the second sub-pattern 323, and the density of the first sub-pattern 322 is different from the density of the second sub-pattern 323. For example, the first sub-pattern 322 of the embodiment is exemplified by a hairline pattern, and the second sub-pattern 323 is exemplified by a three-dimensional structure pattern of a company name or a brand name, and the second sub-pattern 323 is located. The center of the entire flexible mold 3a is taken as an example and can be used as an indication of a bold pattern, but is not intended to limit the present invention. The three-dimensional structure of the first sub-pattern 322 or the second sub-picture 14 201117942 323 is highlighted by the average depth or density design of the first sub-pattern 322 being different from the average depth or density of the second sub-pattern 323. It is worth mentioning that the two subgraphs (2) 23 junctions can be matte surface. The case, please refer to FIG. 1A to FIG. 12B to illustrate the production of the metal raft or metal roller of FIGS. 9A and 9B: a soft mold having a first sub-pattern and a second sub-pattern. Please refer to the figure ig first, which is a flow chart of the metal sheet. In the step--first, according to the actual drawing design, first, electric fine typesetting „Cake a three-dimensional structure pattern 441a, the second sub-pattern 323 on the three-dimensional structure pattern piece 3a is mirror image of each other, and then this == ratio... The output is made into a light army version; the mask version 1 =: a conventional technique, which is not described here. In this embodiment, the fourth (4) has a first sub-pattern 322 (hairline) and = Sub-pattern 323 (stereo structure pattern, the company name is used to form the second sub-pattern 323. The reticle roller 47 is taken as an example. The metal core 44a is attached to the metal surface, two: ?1, the metal on the metal roller 307 Sheets 44 1 , such as stone, sandpaper, etc., have rough surfaces, and are all in the genre 44a of the dynasty singer. You can use it to make the surface abrasive brush. The steel brush of the hair, the road, and the crepe line is ground to between 500 ft. Into the metal sheet 44a in steps 2 and 4, the photoresist is applied to the surface of the hairline. Step one of the mask; s,, two smart, pre-baked, dried, take the step to the parallel plate In step 5, the surface of the step is subjected to frequency shadowing, and the metal strip 47a shown in Fig. η 15 201117942 is obtained. There is a hairline pattern 442 and a three-dimensional structure pattern 441a. The hairline pattern 442 and the first sub-pattern 322 on the flexible mold 3a are mirror images of each other, and the three-dimensional structure pattern 441 is also associated with the second sub-piece on the flexible mold 3a. The patterns 323 are mirror images of each other. Steps 4 and 5 are called exposure development techniques, which is a conventional technique and will not be described herein. In more detail, the present embodiment places the photoresist on the metal thin plate 44a, and then Exposing the thin metal plate 44a and the photomask plate to transfer the pattern of the photomask plate to the thin metal plate 44a having photoresist; then, spraying the developer on the metal thin plate 44a to dissolve the exposed photoresist In the developer, the photoresist sheet 44a which is not protected by the photoresist is etched to form the three-dimensional structure pattern 441a designed by us. Finally, the photoresist is removed by removing the photoresist and the organic solution. After the above steps, the metal thin plate 44a as shown in Fig. 12A is obtained, and the metal thin plate 44a has the hairline pattern 442 and the three-dimensional structure pattern 441a. The density of the three-dimensional structure pattern 441a of the present embodiment The density is smaller than the density of the hairline pattern 442, and the average depth of the three-dimensional structure pattern 44la is greater than the average depth of the hairline pattern 442 (so the average depth of the first sub-pattern of the formed soft mold is smaller than the second sub-pattern. The average depth is not limited to the present invention. The density and average depth of the three-dimensional structure pattern and the hairline pattern, and even the angle of the pattern, may be different depending on the design or the needs of the customer. Please refer to FIG. 12B, which is another schematic view of a thin metal plate. The designer can also directly place a plastic mold 7 having a three-dimensional structure pattern 441b on the metal thin plate 44b to simplify the process of fabricating the metal thin plate 44b. 16 201117942 Next, a flexible mold 3a is obtained by continuous ultraviolet imprinting using the patterned metal roller 47a of Fig. 11. The method of continuous ultraviolet embossing has been described in detail in the first embodiment, and therefore will not be described herein. Next, referring to Fig. 13, the soft mold 3a produced in the present embodiment is applied as an in-mold decorative material to a preferred embodiment of the in-mold decoration (IMR). The in-mold decorative material 5a includes a flexible mold 3a having a microstructured pattern, a release layer 51a and a transfer material layer 52a. The transfer material layer 52a has a protective layer 521a, a printed layer 522 and an adhesive layer 523. The printed layer 522 has a color 522a. - Referring to Figure 14, when the in-mold decoration material 5a is sent into the mold by the film feeder for injection molding (not shown), after the injection molding, the soft mold 3a is separated from the injection member, and an appearance part can be obtained. 6a. The injection appearance member 6a includes a transfer material layer 52a and a plastic 61. Here, the protective layer 521a on the transfer material layer 52a has the first sub-pattern 525 of the hairline pattern of the φ stereoscopic touch transferred from the flexible mold 3a and the second sub-pattern 526 of the three-dimensional structure pattern. It is worth mentioning that the average depth of the first sub-pattern 525 on the flexible mold 3a is smaller than the average depth of the second sub-pattern 526, and the average density of the first sub-pattern 525 is greater than the average density of the second sub-pattern 526. Therefore, the average depth of the first sub-pattern 525 in the emission appearance member 52a is also smaller than the average depth of the second sub-pattern 526, and the average density of the first sub-pattern 525 is also greater than the average density of the second sub-pattern 526, which can be highlighted. The stereoscopic touch of a sub-pattern 525 or a second sub-pattern 526. Among them, a higher pattern density means that the flat unprocessed surface is less, and the pattern 17 201117942 has a lower density, which means that the flat unprocessed surface is more. The function and production method of the _ layer 51a, _4 521 of the present embodiment f are not mentioned in the first. In the $-example, it has been described in detail, in which the printed layer 522 is designed by the designer according to its design, and can be made by screen printing, letterpress printing, gravure printing: layer 522 can constitute a specific The color division or pattern arrangement, or the gloss effect of a == _ mode to a glossy surface, in this embodiment, I has a first sub-pattern 525 of the silk pattern and has a three-dimensional structure: the patterns are different The printed layer 522 of the color block is represented by: a sub-paragraph and the present invention is obtained by providing a microstructure pattern layer in a soft mold "# and then using a soft mold having the microstructure pattern to process the in-mold Decorative materials, as well as outer members that make use of in-mold decorative materials. More specifically, the appearance of the in-mold decorative material is carried out by using a soft mold having a three-dimensional structure, and then the in-mold decorative material is subjected to injection molding to form an appearance of the surface of the body structure. In this way, the producer can hunt the depth of the microstructure pattern on the soft mold and form an arbitrary depth and any angle change on the viewing element. The structure (the pattern and the microstructure of the soft mold are mirror images of each other), This increased tactile sensation and even increased color saturation, the product can not be compared (4). The prior art is described above only as an example and not as a limitation. θ ming can be made into a variety of changes and changes in the field and spirit of ^ λ. For example, the micro-junction 18 201117942 degrees, the visual effect of the microstructure, and the printing pattern effect with different microstructures, the combination of the microstructure and the printed pattern in each embodiment can be fully adjusted or partially adjusted, any The equivalent modifications and variations of the present invention are intended to be included within the scope of the appended claims. BRIEF DESCRIPTION OF THE DRAWINGS FIG. 1A is a schematic view of a conventional in-mold decorative material, FIG. 1B is a schematic view of a conventional in-mold transfer process; FIG. 2A is another schematic view of an in-mold decorative material; FIG. FIG. 3A and FIG. 3B are another conventional structure for in-mold transfer hairline material, and FIG. 3C is another conventional hairline film in-mold transfer. Figure 4 is a schematic view of a soft mold according to a first embodiment of the present invention; Figure 5 is a schematic view of an electroforming tank; Figure 6 is a schematic view showing a manufacturing process of a soft mold according to a first embodiment of the present invention; 7 is a schematic view of an in-mold decorative material according to a first embodiment of the present invention, FIG. 8 is a schematic view of an ejection appearance member according to a first embodiment of the present invention; and FIG. 9A is a schematic view of a soft mold according to a second embodiment of the present invention; 9B is a schematic view of a microstructure of a soft mold according to a second embodiment of the present invention; FIG. 19 is a schematic diagram of a layer of 201117942; FIG. 10 is a flow chart of a metal pure process according to a third embodiment of the present invention; Invention (Iv) metal roller SiWen embodiment of FIG. 12A embodiment schematic view showing a second embodiment of the metal sheet of the present invention; FIG. 12B based metal sheet of the present invention, a second embodiment of another embodiment - FIG; bear
•圖13係為本發明第二實施例之模内裝飾材料的示意 圖；以及 …Figure 13 is a schematic view of an in-mold decorative material according to a second embodiment of the present invention;
圖14係為本發明第二實施例之模 内轉印製程的示意 【主要元件符號說明】 I、 la、lb :模内轉印薄膜 II、 lib、31 :基材 III、 131 b :髮絲面 12、 12b ' 51、51a :離型層 13、 13a、13b、521、521a :保護層 14、 14a、14b、14c、14d :圖案層 15、 523 :接著層 16、 61 :塑料 Π :樹脂層 171 :表面 20 201117942 2、 2a、2b :射出件 3、 3a :軟性模具 32、32a :微結構圖案層 321 :第一圖案 322、 525 :第一子圖案 323、 526 :第二子圖案 4 :電鑄槽 41 :玻璃板 • 411 :微結構圖案面 42 :氨基磺酸鎳鍍液 . 43 :鎳金屬 44、44a、44b :金屬薄板 441、441 a、441b :立體結構圖案 442 :髮絲紋圖案 45 :上膠機構 ^ 46 :光硬化樹脂 47、 47a :金屬滾輪 48、 72 :紫外光源 49a、49b :壓制輪 5、5 a :模内裝飾材料 52、52a :轉印材料層 522 :印刷層 522a、522b、522c、522d :色彩 524 :第二圖案 21 201117942 6、6a :射出夕卜觀件 7:塑膠模具Figure 14 is a schematic view of the in-mold transfer process of the second embodiment of the present invention. [Main component symbol description] I, la, lb: in-mold transfer film II, lib, 31: substrate III, 131 b: hair Face 12, 12b '51, 51a: release layer 13, 13a, 13b, 521, 521a: protective layer 14, 14a, 14b, 14c, 14d: pattern layer 15, 523: adhesive layer 16, 61: plastic enamel: resin Layer 171: surface 20 201117942 2, 2a, 2b: injection member 3, 3a: flexible mold 32, 32a: microstructure pattern layer 321: first pattern 322, 525: first sub-pattern 323, 526: second sub-pattern 4 : electroforming groove 41 : glass plate • 411 : microstructured surface 42 : nickel sulfamate plating solution 43 : nickel metal 44 , 44 a , 44 b : thin metal plate 441 , 441 a , 441b : three-dimensional structure pattern 442 : hair Pattern 45: Gluing mechanism ^ 46: Photo-curing resin 47, 47a: Metal roller 48, 72: Ultraviolet light source 49a, 49b: Pressing wheel 5, 5a: In-mold decorative material 52, 52a: Transfer material layer 522: Printed layers 522a, 522b, 522c, 522d: color 524: second pattern 21 201117942 6、6a: shot out of view 7: plastic mold