TW200535234A - Fuel and lubricant additive concentrates comprising at least one anthraquinone derivative as a marker - Google Patents

Abstract

The invention relates to fuel and lubricant additive concentrates which comprise at least one anthraquinone derivative as a marker, to the use of such concentrates for additizing mineral oils and also for mineral oils which comprise such concentrates.

Description

200535234 九、發明說明： 【發明所屬之技術領域】 本發明關於包含至少一 及潤滑劑添加劑濃縮物 途，及包含此濃縮物之礦 種恩醌衍生物作為標識劑之燃料 ’將此濃縮物添加至礦物油之用 物油。 【先前技術】 為了礦物油添加用而使用添加劑濃縮物(以下依照相關 術居亦稱為包幻，其除了載劑油及不同燃料添加劑混合 物，通常亦包含染料且，例如，亦為了無形之檢查或製造 者區別標識而另外包含標識劑。這些包裝可自無添加礦物 油槽供應給不同之礦物油經銷商，其中為了公司區別用而 添加之顏色與標識劑僅在’例如，將礦物油充填至適當之 運輸油罐車時，藉其個別包裝之助而賦與。 標識劑通常為自礦物油萃取繼而藉衍生化轉化成有色化 合物之物質，或在光譜（例如，NIR)之可見或不可見波長區 域具吸收之物質。已提議且發現本身有用之標識劑，即， 並非僅在進行衍生化之後，包括高差異化合物種類，例如， 酞青、奈青、鎳-二硫醇烯錯合物、芳胺之鋁化合物、曱川 染料、與奥方形酸（azulenesquaric acid)染料（例如，w〇 94/02570 A卜WO 96/10620 A1號專利），及重氮染料（例如， EP 256 460 A1號專利）。用於將汽油或礦物油著色之蒽醌衍 生物敘述於文件US 2,611，772、US 2,068,372、EP 1 〇〇1 〇〇3 A1、及 EP 1 323 8 1 1 A2 號專利。 經驗顯示’許多種目前上市者在礦物油中在稀釋條件下 98462.doc 200535234 下則否；包裝成分之作用在 特敛（例如，消光）。 安定’但是在包裝之濃縮條件 非常短之時間内改變標識劑之 八占為非常良好之長期儲存 安定性之燃料及潤滑劑添加劑濃縮物，特別是關於存在於 其中之標識劑對抗這些濃縮物之其餘成分之作用之安定 性0 【發明内容】 因此，已發現開頭所提及之燁料芬、叫1 “、、料及潤滑劑添加劑濃縮物 (包裝）’其包含至少一種葱職衍生物作為標識劑。 本發明包裝之成分特別地為 a) 至少一種蒽醌衍生物， b) 至少一種載劑油， 〇至少-種選自以下組成之群組之添加劑 清潔劑， 分散劑，及 閥座磨損抑制添加劑， d)如果適田，及其他之添加劑與助劑。 使用之成分&)特別sώ ·、，τ ,200535234 IX. Description of the invention: [Technical field to which the invention belongs] The present invention relates to a fuel containing at least one and a lubricant additive concentrate, and a mineral enquinone derivative containing the concentrate as a marker fuel. 'Add this concentrate It is a mineral oil. [Prior art] Additive concentrates are used for the addition of mineral oil (hereinafter also referred to as the package magic according to the related arts, which in addition to carrier oil and different fuel additive mixtures usually also contain dyes and, for example, also for invisible inspection Or the manufacturer distinguishes the logo and additionally contains a marking agent. These packages can be supplied from different mineral oil tanks without added mineral oil tanks, where the color and marking agent added for the company's distinctive use is only in the example of filling mineral oil to When transporting a suitable tanker truck, it is aided by its individual packaging. Markers are usually substances that are extracted from mineral oil and then converted to colored compounds by derivatization, or are visible or invisible in the spectrum (for example, NIR) Substances with absorption in the wavelength region. Markers have been proposed and found to be useful, that is, not only after derivatization, including highly differentiated compound species, such as phthalocyanine, necyanine, nickel-dithiolene complexes , Arylamines, aluminum compounds, Takikawa dyes, and azulenesquaric acid dyes (for example, WO 94/02570 A BU WO 96/1062 0 A1 patent), and diazo dyes (for example, EP 256 460 A1 patent). Anthraquinone derivatives used to color gasoline or mineral oils are described in documents US 2,611,772, US 2,068,372, EP 1 001 〇〇3 A1, and EP 1 323 8 1 1 A2 patents. Experience shows that 'many of the current marketers in mineral oil under dilution conditions 98462.doc 200535234 do not; the role of packaging ingredients is particularly condensed (for example, Matting). Stable 'but changing the eighth of the labeling agent in a very short period of time in the packaging to a very good long-term storage stability of fuel and lubricant additive concentrates, especially regarding the labeling agent present in it The stability of the role of the remaining ingredients of the concentrate 0 [Summary of the invention] Therefore, it has been found that the material mentioned in the beginning, called "1", additives, and lubricant additive concentrates (packaging) 'contains at least one onion derivative The ingredients of the packaging of the present invention are in particular a) at least one anthraquinone derivative, b) at least one carrier oil, and at least one addition selected from the group consisting of Detergents, dispersants and valve seat wear-inhibiting additive, d) if appropriate fields, and other additives the use of adjuvants amp &component;.) Special sώ · ,, τ,

衍生物 式I 疋k自以下化合物組成之群組之蒽醌DerivativesAnthraquinones of the formula I 疋 k

式II 98462.doc 〇Formula II 98462.doc

〇 (II) 200535234〇 (II) 200535234

及式IIIAnd formula III

其中 Ί)、7} Ri、R2 X n、m R9、R10 R3 R4至 R8 及 R 各獨立地為氫、羥基、OR、NHR、或NR2， 各獨立地為R或COR， 為氫、氰基、硝基、羥基、OR、胺基、NHR、 R、或 ch(r9)(r】〇)， 各為0、1、2、3、或4，而且在n4m大於1之 各情形，R或X基團可各為相同或不同， 各獨立地為氰基、COOH或COOR， 為氫、R或NHR，Where Ί), 7} Ri, R2 X n, m R9, R10 R3 R4 to R8 and R are each independently hydrogen, hydroxyl, OR, NHR, or NR2, each independently R or COR, hydrogen or cyano , Nitro, hydroxy, OR, amine, NHR, R, or ch (r9) (r] 〇), each of which is 0, 1, 2, 3, or 4, and in each case where n4m is greater than 1, R or X groups can be the same or different, each independently is cyano, COOH or COOR, is hydrogen, R or NHR,

各獨立地為氫、R或NHR 為ci-Cm烷基，其視情況地在醚官能基中經^ 至4個氧原子***，（^{^環烷基，其視情況 地、、二或多個crC2〇-烷基（其視情況地在醚官 能基中經丨至4個氧原子***）取代，飽和雜環 98462.doc 200535234 五或六員基團，其視情況地經—或多個 G-C^-烷基（其視情況地在醚官能基中經1至* 個氧原子插人）取代，或為C6_c]g_芳基，其視 情況地經-❹㈣素、氰基“肖基、經基、 胺基Cl-C2〇-烷基（其視情況地在醚官能其 經⑽氧原子***）、Cl_M氧基、=_ 烷胺基、或Cl-C2(r二烧胺基取代，或為具有3 至12個碳原子之雜芳基，其視情況地經一或多 個烷基（其視情況地在醚官能基中經1 至4個氧原子***）、Ci_c2G·烷氧基、Ci/t 烷胺基、或Cl-c2G-二烷胺基取代，或為 芳基-CrCr烷基，其視情況地在芳基中經一 或夕個鹵素、氰基、硝基、經基、胺基、Ci k基（其視情況地在鱗官能基中經丨至4個氧原 子***）、cvc2(r烷氧基、Ci_C2(r烷胺基、或 C】-C2〇-二烷胺基取代，或為在雜芳基中具有3 至12個碳原子之雜芳基_Ci-C4_烷基，前者視 情況地經一或多個Cl-C2G_烷基（其視情況地在 醚官能基中經1至4個氧原子***）、Ci-C2〇-烷 氧基、CVC20-烷胺基、或Ci-C2()_二烷胺基取 代。 【實施方式】 視情況地在醚官能基中經i至4個氧原子***之C1 -C2〇_院 基包括，例如，曱基、乙基、丙基、異丙基、丁基、異丁 98462.doc 200535234 基、第二-丁基、第三_ 丁基、戊基、異戊基、新戊基、第三 -戊基、己基、2-曱基戊基、庚基、庚基、辛基、2-乙基 己基、異辛基、壬基、異壬基、癸基、異癸基、十一碳基、 十二碳基、十三碳基、3,5,5,7-四曱基壬基、異十三碳基（以 上名詞異辛基、異壬基、異癸基、與異十三碳基為俗稱且 源自藉羰氧化法而得之醇，關於此點，參考UllmannsEach independently is hydrogen, R or NHR is ci-Cm alkyl, which is optionally inserted in the ether functional group through ^ to 4 oxygen atoms, (^ {^ cycloalkyl, which optionally, Multiple crC2O-alkyls (which are optionally inserted in the ether functional group with 4 to 4 oxygen atoms) are substituted, saturated heterocycle 98462.doc 200535234 five or six member groups, which are optionally-or more GC ^ -alkyl (which is optionally substituted by 1 to * oxygen atoms in the ether functional group), or C6_c] g_aryl, which is optionally substituted by -fluorene, cyano "Xiao Group, mesogen, amine group Cl-C2O-alkyl (which is optionally inserted in the ether function via a fluorene oxygen atom), Cl_Moxy, = _ alkylamino group, or Cl-C2 (r dialkylamino group Substituted, or a heteroaryl group having 3 to 12 carbon atoms, optionally via one or more alkyl groups (optionally inserted through 1 to 4 oxygen atoms in the ether functional group), Ci_c2G · alkane Oxy, Ci / t alkylamino, or Cl-c2G-dialkylamino, or aryl-CrCr alkyl, optionally with one or more halogens, cyano, nitro groups in the aryl group , Meridian, amine, Ci k (as appropriate In some cases, it is substituted in the scale functional group with 4 to 4 oxygen atoms), cvc2 (r alkoxy, Ci_C2 (r alkylamino, or C) -C20-dialkylamino, or substituted in heteroaryl Heteroaryl_Ci-C4_alkyl having 3 to 12 carbon atoms in the former, optionally via one or more Cl-C2G_alkyls (which optionally pass through 1 to 4 in the ether functional group Oxygen atom insertion), Ci-C2O-alkoxy, CVC20-alkylamino, or Ci-C2 ()-dialkylamino group. [Embodiment] Optionally, from i to 4 in the ether functional group The C1-C2O_ group with an oxygen atom inserted includes, for example, fluorenyl, ethyl, propyl, isopropyl, butyl, isobutyl 98462.doc 200535234, second-butyl, and third_butyl , Pentyl, isopentyl, neopentyl, third-pentyl, hexyl, 2-fluorenylpentyl, heptyl, heptyl, octyl, 2-ethylhexyl, isooctyl, nonyl, iso Nonyl, decyl, isodecyl, undecyl, dodecyl, tridecyl, 3,5,5,7-tetrafluorenylnonyl, isotridecyl (the above isooctyl) , Isononyl, isodecyl, and isotridecyl are commonly known and derived from carbonyl oxidation , In this regard, reference Ullmanns

Encyklopadie der technischen CJhemie，第 4版，第 7卷，第 215至217頁，及第丨丨卷，第435與436頁）、十四碳基、十五 碳基、十六碳基、十七碳基、十八碳基、十九碳基、二十 碳基、曱氧基甲基、2_乙基己氧基甲基、2_甲氧基乙基、2_ 乙氧基乙基、2-丙氧基乙基、孓異丙氧基乙基、2_丁基乙基、 、2-或4-曱氧基丁基、2_或心乙氧基丁基、Encyklopadie der technischen CJhemie, 4th edition, volume 7, pages 215 to 217, and volumes 丨 丨, pages 435 and 436), fourteen-carbon-based, fifteen-carbon-based, sixteen-carbon-based, seventeen-carbon Alkyl, octadecyl, nineteen carbon, icosyl, methoxymethyl, 2-ethylhexyloxymethyl, 2-methoxyethyl, 2-ethoxyethyl, 2- Propoxyethyl, isopropyloxyethyl, 2-butylethyl, 2- or 4-methoxyoxybutyl, 2-or diethoxybutyl,

2-或3·甲氧基丙基、2.或3_乙氧基丙基、2•或％丙氧基丙基、 2 -或3 -丁氧基丙1、94田条# Λ 基、3,6,9-三吟十一碳基、3,6,9, 3，6,9,12 -四ρ号十四碳基。 、環己基與環庚基。這些2- or 3-methoxypropyl, 2. or 3-ethoxypropyl, 2 or% propoxypropyl, 2- or 3-butoxypropyl 1, 94 田 条 # Λ 基, 3,6,9-Sanyin eleven carbon group, 3,6,9, 3,6,9,12-four rhodium fourteen carbon group. , Cyclohexyl and cycloheptyl. These ones

列於以上。 可用之Cs-Cr環烷基包括環戊基、 環烷基視情況地經一或多個，特別 取代，而且後者可視情況地在醚官Listed above. Useful Cs-Cr cycloalkyls include cyclopentyl, cycloalkyl optionally substituted by one or more, and the latter may optionally be in the ether

視情況地經一或多個c^ 98462.doc 200535234 基中經1至4個氧原子***）取代之飽和、雜環五或六員美團 係衍生自，例如，吡咯啶、2-或甲基吡咯啶、2,‘二甲美 -3-乙基吡咯啶、咄唑啶、2-、3_、4…或5•甲基呲唑啶、咪 唑啶、2-、3-、4-、或5-曱基咪唑啶、p号唑啶、2…（戋5 甲基哼唑啶、異噚唑啶、3_、4_或5_甲基異呤唑啶、哌啶、 2-、3-或4-甲基或乙基哌啶、2,6-二甲基哌啶、哌畊 烷基）哌畊（如4-甲基或4_乙基哌畊）、嗎啉、硫嗎啉、或嗎 琳S，S-氧化物。 … 在變數Z1及/或Z2定義中之0R、NHR與NR2基中、在變數 X定義中之OR與NHR基中、在R9與Ri〇基定義中之c〇〇R基 中、在變數R3及R4至R8定義中之NHR基中之汉對應適當（視 情況地經取代）之飽和、雜環五或六員基團時，其係經雜環 五或六員環之碳原子鍵結至所述基之特定雜原子。其在變 數R1與R2定義中及變數R3定義中之尺單獨對應適當（視情況 地經取代）之飽和、雜環五或六員基團時亦適用。在其他之 情形，此鍵結可經由雜環五或六員環之適合鍵結之碳原子 或雜原子。 C6-C1Q-芳基特別地包括苯基與萘基。其視情況地經一或 多個i素（如氟、氣或漠）、氰基、硝基、羥基、胺基、C1_C20_ 烷基（其視情況地在醚官能基中經丨至4個氧原子***卜 CVC，烷氧基、Cl-C2。-烷胺基、或Ci_C2『二烷胺基取代。 適當之視情況地在醚官能基中經i至4個氧原子***之 CrCM烧基、及存在於Cl_c2〇_院氧基、Ci_C2G_烧胺基、或 q-C2。-二烷胺基中之h-Ct烷基已列於以上作為實例。 98462.doc • 11 - 200535234 視情況地經一或多個Cl-C2Q_烷基（其視情況地在醚官能 基中經1至4個氧原子***）烷氧基烷胺基、 SC^-C2。-二烷胺基取代之具有3至12個碳原子之雜芳基係 衍生自，例如，吡咯、呋喃、噻吩、吡唑、異噚唑、異噻 唑、咪唑、***、1Η·ΐ52,4_***、吡啶、吡;二 嗒畊' 1Η-苯并氮呼、2Η-苯并氮呼、呤唑、噻唑、^弘、 況地及苯或二苯融合環，例如，喹啉、異喹啉、吲哚、苯 并[b]呋喃（薰草素酮）、苯并[b]噻吩（噻茚）、咔唑、二苯并 呋喃、二苯并噻吩、1Η·節唑、茚嘮唑、苯并[d]異噻唑、 苯曱醯亞胺酸、苯㈣唾、苯并嗤、苯并㈣、哮琳、 酞井、哇唑啉、喹呤啉、或啡畊。視情況地在醚官能基中 經1至4個氧原子***之Ci_C2〇_烧基取代基已在以上指定作 為實例。 在變數Z1及/或Z2定義中之〇R、NHR與NR2基中、在變數 X定義中之OR與NHR基中、在R^Rl0基定義中之⑶⑽基 :、在變數R3及R4至義中之舰基中之崎應適當（視 ί月况地經取代）之雜環基時，其係經雜環之碳原子鍵結至所 述基之特定雜原子。其在變數…及/或以定義中及變數尺3定 義中之R單獨對應適# (視情況地經取代）之”基時亦適 用。在其他之情形’此鍵結可經由雜芳基之適合鍵結之碳 原子或雜原子。 /見U况地在芳基中經一或多個鹵素、氰基、硝基、羥基、 女基c 1 -Ct烷基（其視情況地在醚官能基申經〗至4個氧原 98462.doc -12- 200535234 子***）、氧基、C^-Czg-烧胺基、或二炫胺 基取代之C6-C1(r芳基-C1-C4-烧基特別地包括苄基、苯乙 基、3_苯基丙基、與4-苯基丁基。適當之視情況地在醚官能 基中、、、工1至4個氧原子***之烧基、及存在於(^<20-烧氧基、CVC2(r烷胺基、或Cl-C20_二烷胺基中之Ci_C2〇-烷 基已列於以上作為實例。 在雜芳基中具有3至12個碳原子之雜芳基-Ci_c4-烷基，前 者經一或多個C^C^o-烷基（其視情況地在醚官能基中經J至 4個氧原子***）、Cl-C2G_烷氧基、Ci-C2G_烷胺基、或 二烷氧基取代，係衍生自，例如，以上指定之雜芳基，其 係經雜芳基之適合鍵結之碳原子或雜原子鍵結至Ci_c^烷 基適^之視情況地在鱗官能基中經1至4個氧原子***之 C】-C2〇-烷基、及存在於^化烷氧基、Ci-Ci烷胺基、或 Cl-C^-二烷胺基中之Ci-C2〇_烷基已列於以上作為實例。 較佳之本發明燃料及潤滑劑添加劑濃縮物包含式z 111之恩S昆少于生物，其中 Ζ、Ζ2 各獨立地為氫或NHR， R、R2 各獨立地為R， χ 為氫、氰基或CH(R9)(R10)， 1 為〇、1、2、3、或4，而且在11或01大於1時，1^ 或X基為相同或不同， R、RlG各獨立地為氰基或COOR， ο 3 為氫、R或NHR， R至R 為氫或NHR， 98462.doc 200535234Saturated, heterocyclic five- or six-membered US-groups substituted with one or more c ^ 98462.doc 200535234 groups inserted with 1 to 4 oxygen atoms, as appropriate, derived from, for example, pyrrolidine, 2-, or formazan Methylpyrrolidine, 2, 'dimethylmet-3-ethylpyrrolidine, oxazolidine, 2-, 3_, 4 ... or 5methyloxazolidine, imidazolidine, 2-, 3-, 4-, Or 5-fluorenimidazolidine, p-oxazole, 2 ... (戋 5 methyloxazosin, isoxazosin, 3_, 4_ or 5_methylisoxazine, piperidine, 2-, 3 -Or 4-methyl or ethyl piperidine, 2,6-dimethyl piperidine, piperinyl) piperine (such as 4-methyl or 4-ethyl piperidine), morpholine, thiomorpholine , Or Morin S, S-oxide. … In the OR, NHR, and NR2 groups in the definition of variable Z1 and / or Z2, in the OR and NHR groups in the definition of variable X, in the c〇R group in the definition of R9 and Ri〇, And when the Chinese in the NHR group in the definition of R4 to R8 corresponds to a suitable (optionally substituted) saturated, heterocyclic five- or six-membered group, it is bonded to the carbon atom of the heterocyclic five- or six-membered ring to The specific heteroatom of the group. It also applies when the scales in the definitions of variables R1 and R2 and the definition of variable R3 individually correspond to appropriate (optionally substituted) saturated, heterocyclic five- or six-membered groups. In other cases, the bonding may be through a carbon atom or heteroatom of the heterocyclic five- or six-membered ring suitable for bonding. C6-C1Q-aryl includes, in particular, phenyl and naphthyl. It optionally passes one or more i elements (such as fluorine, gas, or molybdenum), cyano, nitro, hydroxyl, amine, C1_C20_ alkyl (optionally via ether functional groups to 4 oxygen CVC, alkoxy group, Cl-C2.-Alkylamino group, or Ci_C2 "dialkylamino group substitution. CrCM alkyl group inserted through i to 4 oxygen atoms in the ether functional group, as appropriate, And the h-Ct alkyl group present in Cl_c2O_co-oxyl, Ci_C2G_alkylamino, or q-C2.-dialkylamino groups have been listed above as examples. 98462.doc • 11-200535234 as the case may be Alkoxyalkylamino, SC ^ -C2.-dialkylamino substituted with one or more Cl-C2Q_alkyl (which is optionally inserted in the ether functional group by 1 to 4 oxygen atoms) Heteroaryl groups of 3 to 12 carbon atoms are derived from, for example, pyrrole, furan, thiophene, pyrazole, isoxazole, isothiazole, imidazole, triazole, 1Η · ΐ52,4-triazole, pyridine, pyridine; Didagen '1'-benzothiazepine, 2'-benzothiazepine, pyrazol, thiazole, hydrazine, and benzene or diphenyl fusion ring, such as quinoline, isoquinoline, indole, benzo [b] furan (humulone , Benzo [b] thiophene (thienindene), carbazole, dibenzofuran, dibenzothiophene, 1Η · azole, indazole, benzo [d] isothiazole, phenylimine acid, benzene Sialane, benzopyrene, benzopyrene, oxolin, phthaloline, oxazoline, quinoline, or morphine. Optionally, Ci_C2〇_burned with 1 to 4 oxygen atoms in the ether functional group The substituents have been specified above as examples. In the OR, NHR, and NR2 groups in the definition of variable Z1 and / or Z2, in the OR and NHR groups in the definition of variable X, and in the definition of R ^ Rl0 group. Base: In the case of the variable R3 and R4 to Yoshizumi's naval base, a heterocyclic group that should be appropriate (substituted depending on the month), it is a specific group bonded to the base via a heterocyclic carbon atom Heteroatom. It also applies when the variable ... and / or R in the definition and in the definition of variable rule 3 corresponds to the appropriate "(optionally substituted)" base. In other cases, this bond can be Carbon atoms or heteroatoms suitable for bonding of aryl groups. / See U.S.A. through one or more halogen, cyano, nitro, hydroxyl, female C1-Ct alkyl groups (optionally In ether Energetic radicals to four oxygen atoms 98462.doc -12-200535234 insertion), oxygen, C ^ -Czg-alkylamine, or dioxamine substituted C6-C1 (raryl-C1- C4-alkyl includes, in particular, benzyl, phenethyl, 3-phenylpropyl, and 4-phenylbutyl. Where appropriate, in the ether functional group, 1 to 4 oxygen atoms are inserted. The alkyl group and the Ci_C2O-alkyl group present in (^ < 20-alkyloxy group, CVC2 (r alkylamino group, or Cl-C20_dialkylamino group) have been listed above as examples. Heteroaryl-Ci_c4-alkyl having 3 to 12 carbon atoms in heteroaryl, the former via one or more C ^ C ^ o-alkyl (which optionally passes J to 4 in the ether functional group Oxygen atoms inserted), Cl-C2G_alkoxy, Ci-C2G_alkylamino, or dialkoxy substitution, derived from, for example, the heteroaryl groups specified above, which are suitable for heteroaryl groups Bonded carbon atom or heteroatom is bonded to Ci_c ^ alkyl, optionally C is inserted in the scale functional group through 1 to 4 oxygen atoms] -C2O-alkyl, and is present in alkylene Ci-C20-alkyl groups in oxy, Ci-Ci alkylamino, or Cl-C ^ -dialkylamino groups have been listed above as examples. The preferred fuel and lubricant additive concentrates of the present invention include enz Kun less than the organism of formula z 111, where Z, Z2 are each independently hydrogen or NHR, R, R2 are each independently R, and χ is hydrogen and cyano Or CH (R9) (R10), 1 is 0, 1, 2, 3, or 4, and when 11 or 01 is greater than 1, the 1 or X groups are the same or different, and R and R1G are each independently a cyano group Or COOR, ο 3 is hydrogen, R or NHR, and R to R are hydrogen or NHR, 98462.doc 200535234

為NHR 為Ci Ci 5-纟兀基，其視情況地在 至-氧原子***，環己基，其視情況^ 或多個Ci-Cir烷基（其視情況地在醚官能基中 經1至4個氧原子***）取代，飽和雜環五或六 員基團，其視情況地經一或多個Ci_Ci5_烷基 (其視情況地在醚官能基中經1至4個氧原子插 入）取代，或為C6_C1(r芳基，其視情況地經一 或多個Cl-c】5_烷基（其視情況地在醚官能基中 經1至4個氧原子***）、Ci-C〗5_烷氧基、Ci_Ci5_ 烷胺基、或c^c】5-二烷胺基取代，或為具有3 至5個碳原子之雜芳基，其視情況地經一或多 個C^C!5-烷基（其視情況地在醚官能基中經工 至4個氧原子***）、Ci_Ci5•烷氧基、KM· 烷胺基、或CrC】5-二烷胺基取代，或為苯基 _ A-C4-院基，其視情況地在苯基中經一或多 個c^c】5-烷基（其視情況地在醚官能基中經i 至4個氧原子***）、Ci_Ci5-烷氧基、c^Civ 烷胺基、或二烷胺基取代，或為在雜 芳基中具有3至5個碳原子之雜芳基烷 基，前者視情況地經一或多個c厂Cis_烷基（其 視情況地在醚官能基中經1至4個氧原子插 ‘ 入）、-烧氧基、C]-Ci5-烷胺基、或 98462.doc - 14 - 200535234 二烷胺基取代， 較佳之R基已列於以上例示表列中。 式I之恩醍α衍生物特別地為下示之式以至If化合物··NHR is Ci Ci 5-pentyl, which is optionally inserted at the-oxygen atom, cyclohexyl, which is optionally ^ or more Ci-Cir alkyl (which is optionally in the ether functional group via 1 to 4 oxygen atoms inserted) substituted, saturated heterocyclic five- or six-membered groups, optionally via one or more Ci_Ci5_ alkyl groups (which, if appropriate, are inserted through 1 to 4 oxygen atoms in the ether functional group) Substituted, or C6_C1 (r aryl, optionally via one or more Cl-c] 5-alkyls (which are optionally inserted through 1 to 4 oxygen atoms in the ether functional group), Ci-C 〖5_Alkoxy, Ci_Ci5_ alkylamino, or c ^ c] 5-dialkylamino substituted, or a heteroaryl group having 3 to 5 carbon atoms, optionally with one or more C ^ C! 5-alkyl (optionally inserted to 4 oxygen atoms in the ether functional group), Ci_Ci5 · alkoxy, KM · alkylamino, or CrC] 5-dialkylamine substituted, or Is phenyl_A-C4-codyl, optionally via one or more c ^ c] 5-alkyl groups in the phenyl group (which is optionally inserted via i to 4 oxygen atoms in the ether functional group) ), Ci_Ci5-alkoxy, c ^ Civ alkylamino, or dialkylamino, To be a heteroarylalkyl group having 3 to 5 carbon atoms in the heteroaryl group, the former optionally passes one or more Cis Cis alkyl groups (which optionally passes 1 to 4 in the ether functional group). An oxygen atom is inserted), -alkyloxy, C] -Ci5-alkylamino group, or 98462.doc-14-200535234 dialkylamino group substitution, and the preferred R group is listed in the above exemplified table. Formula I The 醍 α derivative is specifically the following formula to the If compound ...

數尺為心-心5-烷基，其視情況地在醚官能基中經丨至4個氧原The ruler is heart-heart 5-alkyl, which optionally passes through 4 to 2 oxygen atoms in the ether functional group.

子***，及C6-c1G-芳基，其視情況地經一或多個Ci_c^_烷 基（其視情況地在醚官能基中經丨至4個氧原子***）取代。And C6-c1G-aryl, which are optionally substituted with one or more Ci_c ^ _ alkyl groups (which are optionally inserted in the ether functional group with 1-4 oxygen atoms).

在視情況地在醚官能基中經丨至4個氧原子***之Ci_Ci5_ 烷基之定義中，變數R較佳為選自以下組成之群組··甲基、 乙基、丙基、異丙基、丁基、異丁基、第二_ 丁基、第三_ 丁基、戊基、異戊基、新戊基、第三_戊基、己基、2-甲基 戊基、庚基、庚-3-基、辛基、2_乙基己基、異辛基、壬基、 異壬基、癸基、異癸基、十—碳基、十二碳基、十三碳基、 3,5,5,7-四甲基壬基、異十三碳基、十四碳基、十五碳基、 甲氧基甲基、2-乙基己氧基甲基、甲氧基乙基、乙氧基 乙基、2_丙氧基乙基、2_異丙氧基乙基、2-丁基乙基、2-與3-甲氧基丙基、2·與3义氧基丙基、2•與3•丙氧基丙基、 98462.doc -15- 200535234 2-與3-丁氧基丙基、n4 基丁基、2-與4-乙氧基丁基、 2-與4-丙氧基丁基、2_盥 一 一 』虱基丁基、3,6-二啰庚基、3,6- 二啊基、4H壬基、3,7·二啊基、3,7〇f壬基、 4,7 - τ辛基、4,7-二口号壬基、4,8-二崎癸基、3,6,8_三崎癸 基3,6,9-二π十一碳基、3,6,9，12_四^十三碳基、及 3，6,9,12 -四p号十四碳基。 在視情況地經一或多個r h 仏 夕個Ci-Ci5_烷基（其視情況地在醚官 此基中經1至4個氧原子***)取代之C6_C1❶-芳基之定義 中’變數R較佳為選自以下組成之群組：未取代苯基、2_、 3-與4-單取代、2 3-、？ 4你ι 5 K與 3,4_ 二取代、及 2,3,4-、2,3,5-、 ，5 2,4,6…與3,4,5-三取代苯基，其經視情況 地㈣官能基中經1至4個氧原子***且已列於以上作為實 例之C1 - C丨5 -烧基取代。 在式la至Ie化合物中之特定以基較佳為相同。In the definition of Ci_Ci5_ alkyl, which is optionally inserted in the ether functional group through four to four oxygen atoms, the variable R is preferably selected from the group consisting of methyl, ethyl, propyl, isopropyl Base, butyl, isobutyl, second butyl, third butyl, pentyl, isopentyl, neopentyl, third pentyl, hexyl, 2-methylpentyl, heptyl, Hept-3-yl, octyl, 2-ethylhexyl, isooctyl, nonyl, isononyl, decyl, isodecyl, ten-carbon, dodecyl, tridecyl, 3, 5,5,7-tetramethylnonyl, isotridecyl, tetradecyl, pentadecyl, methoxymethyl, 2-ethylhexyloxymethyl, methoxyethyl, Ethoxyethyl, 2-propoxyethyl, 2-isopropoxyethyl, 2-butylethyl, 2- and 3-methoxypropyl, 2 and 3-isopropyloxy , 2 • and 3 • propoxypropyl, 98462.doc -15- 200535234 2- and 3-butoxypropyl, n4 butyl, 2- and 4-ethoxybutyl, 2- and 4 -Propoxybutyl, 2-hydroxy-l-butylyl, 3,6-difluorheptyl, 3,6-diahyl, 4H nonyl, 3,7 · diahyl, 3,7 〇f nonyl, 4,7-τ octyl 4,7-II slogan nonyl, 4,8-Nisaki decyl, 3,6,8_Misaki decyl 3,6,9-diπ undecyl, 3,6,9,12_tetra ^ Thirteen carbon groups, and 3,6,9,12-four p fourteen carbon groups. 'Variable in the definition of C6_C1❶-aryl, optionally substituted with one or more rh-Ci-Ci5_alkyl (which is optionally inserted in the ether base with 1 to 4 oxygen atoms) R is preferably selected from the group consisting of: unsubstituted phenyl, 2_, 3- and 4-monosubstituted, 2 3-,? 4 你 ι 5 K and 3,4_ disubstituted, and 2,3,4-, 2,3,5-,, 5, 2,4,6 ... and 3,4,5-trisubstituted phenyl, which are In the case, the fluorene functional group is substituted with 1 to 4 oxygen atoms and has been listed as the C1-C1-5-alkyl group substituted as an example above. The specific radicals in the compounds of the formulae la to Ie are preferably the same.

•x2 (He) (Ha) 在式山至山中，變數R、Rl與R2各獨立地為Cl-C『烧基， 其視情況地在_官能基中經1至4個氧原子***，及C6_Cl。· 芳基’其視情況地經-或多個CA5{基（其視情況地在鱗 官能基中經1至4個氧原子***）取代。 式Ila至lie中之X為恩醌結構之兩個氫原子、或厂排 98462.doc -16- 200535234 列之兩個氰基、或2,3-或6,7-排列之兩個相同ch(r9)(rI0) 之意義。後兩個ch(R9)(ri。）基為兩個ch(c〇〇r)2、 CH(CN)COOR^CH(CN)2^ , 其視情況地在醚官能基中經1至4個氧原子***，及c6_Ct 芳基，其視情況地經^-心5-烷基（其視情況地在醚官能基7 經1至4個氧原子***）取代。 在視情況地在醚官能基中經丨至4個氧原子***之 烷基之定義中，變數R、R1與R2較佳為選自以下組成之群 組：甲基、乙基、丙基、異丙基、丁基、異丁基、第二-丁 基第一-丁基、戊基、異戊基、新戊基、第三戊基、己基、 2-甲基戊基、庚基、庚_3_基、辛基、2_乙基己基、異辛基、 壬基、異壬基、癸基、異癸基、十一碳基、十二碳基、十 三碳基、3,5,5,7-四甲基壬基、異十三碳基、十四碳基、十 五碳基、甲氧基甲基、2_乙基己氧基甲基、甲氧基乙基、 2-乙氧基乙基、2-丙氧基乙基、2_異丙氧基乙基、2_ 丁基乙 基、2-與3-甲氧基丙基、2-與弘乙氧基丙基、2_與3_丙氧基 丙基、2-與3-丁氧基丙基、2-與4_甲氧基丁基、2_與‘乙氧 基丁基、2-與4-丙氧基丁基、2-與4_ 丁氧基丁基、3,6-二噚 庚基、3,6-二吟辛基、4,8-二噚壬基、3,7-二噚辛基、3,7一 一1壬基、4,7-二唠辛基、4,7•二呤壬基、4,8-二呤癸基、 3,6,8 一咢六基、3,6,9-三口号十一碳基、3,6,9,12-四口号十三碳 基、及3,6,9，12-四唠十四碳基。 在視U况地、，二或多個C i _ C15 -烧基（其視情況地在喊官 旎基中經1至4個氧原子***）取代之C6-C1G-芳基之定義 98462.doc 200535234 中，變數R、R】與R2較佳為選自以下組成之群組：未取代苯 基、2-、3-與 4-單取代、2,3_、254_與3,‘ 二取代、及 2,3,4_、 2’3’5-、2,3,6-、2,4,5-、2,4,6-、與 3,4,5-三取代苯基，其經 視情況地在醚官能基中經丨至4個氧原子***且已列於以上 作為實例之CrCi5-烷基取代。 特佺為其中變數R、Ri與R2、或尺、…與^2、或…與^2彼 \相同之式^、IIb、„c化合物，gp，此對應化合物包括： 州 Q hi<R r、nh 〇 hn^r• x2 (He) (Ha) In the formula to the mountain, each of the variables R, Rl, and R2 is independently a Cl-C group, which is optionally inserted through a functional group through 1 to 4 oxygen atoms, and C6_Cl. · Aryl 'which is optionally substituted by-or more CA5 {groups (which are optionally inserted in the scale functional group by 1 to 4 oxygen atoms). X in the formulae Ila to lie are two hydrogen atoms of the enquinone structure, or two cyano groups in the row 98462.doc -16- 200535234, or two identical chs in a 2,3- or 6,7-arrangement (r9) (rI0). The last two ch (R9) (ri.) Groups are two ch (c〇〇r) 2, CH (CN) COOR ^ CH (CN) 2 ^, and optionally 1 to 4 in the ether functional group. An oxygen atom is inserted, and a c6_Ct aryl group is optionally substituted with a ^ -alkyl 5-alkyl group (which is optionally inserted in the ether functional group 7 with 1 to 4 oxygen atoms). In the definition of an alkyl group optionally inserted through one to four oxygen atoms in the ether functional group, the variables R, R1 and R2 are preferably selected from the group consisting of methyl, ethyl, propyl, Isopropyl, butyl, isobutyl, second-butyl first-butyl, pentyl, isopentyl, neopentyl, third pentyl, hexyl, 2-methylpentyl, heptyl, Heptyl, octyl, 2-ethylhexyl, isooctyl, nonyl, isononyl, decyl, isodecyl, undecyl, dodecyl, tridecyl, 3, 5,5,7-tetramethylnonyl, isotridecyl, tetradecyl, pentadecyl, methoxymethyl, 2-ethylhexyloxymethyl, methoxyethyl, 2-ethoxyethyl, 2-propoxyethyl, 2-isopropoxyethyl, 2-butylethyl, 2- and 3-methoxypropyl, 2- and ethoxypropyl Group, 2- and 3-propoxypropyl, 2- and 3-butoxypropyl, 2- and 4-methoxybutyl, 2- and 'ethoxybutyl, 2- and 4- Propoxybutyl, 2- and 4-butoxybutyl, 3,6-difluorenylheptyl, 3,6-dioctyloctyl, 4,8-difluorenylnonyl, 3,7-dioxoctyl Base, 3,7 one-one nonyl, 4,7-dioxanyl, 4,7 • Dipyridinyl nonyl, 4,8-dipyridinyl decyl, 3,6,8 monohexadecyl, 3,6,9-three slogans undecyl carbon, 3,6,9,12-four slogans thirteen Carbon-based, and 3,6,9,12-tetrakistridecyl. In the case of U, the definition of C6-C1G-aryl, which is substituted by two or more C i _ C15 -alkyl radicals (which are optionally inserted in the alkyl radical by 1 to 4 oxygen atoms) 98462. In doc 200535234, the variables R, R] and R2 are preferably selected from the group consisting of unsubstituted phenyl, 2-, 3- and 4-monosubstituted, 2,3_, 254_ and 3, 'disubstituted , And 2,3,4_, 2'3'5-, 2,3,6-, 2,4,5-, 2,4,6-, and 3,4,5-trisubstituted phenyl, which are CrCi5-alkyl substitution, as appropriate, which is inserted in the ether functional group with one to four oxygen atoms and has been listed above as an example. The special formula is a compound in which the variables R, Ri and R2, or ruler, ... and ^ 2, or ... and ^ 2 are the same formula ^, IIb, „c, gp. This corresponding compound includes: State Q hi < R r , Nh 〇hn ^ r

R p^NH ο HNR p ^ NH ο HN

r^NH 〇 hNr ^ NH 〇 hN

〇 HN、〇 HN,

CH(R9)(R10) CH(R9〉(Ri〇) r^NH 〇 hn 、RCH (R9) (R10) CH (R9> (Ri〇) r ^ NH 〇 hn, R

CH(R»)(Ri〇) CH(R9)(Ri〇) r/NH 〇 Hn 及CH (R ») (Ri〇) CH (R9) (Ri〇) r / NH 〇 Hn and

CH(R9)(Ri〇) CH(R9)(ri〇) O HN、 、R ，變數R對 及6,7-經氰基或CH(R9)(R，取代之對應化合物 應上列之選擇。 98462.doc -18- 200535234 用於本發明之式III之蒽醌衍生物特別妯去 ^马下示之式Ilia 至Illd化合物：CH (R9) (Ri〇) CH (R9) (ri〇) O HN,, R, variable R pair and 6,7- the corresponding compound substituted by cyano or CH (R9) (R, should be listed above. 98462.doc -18- 200535234 The anthraquinone derivatives of formula III used in the present invention are specifically eliminated ^ compounds of formulae Ilia to Illd shown below:

其中 R3 為 R或 NHR，Where R3 is R or NHR,

R8 為 NHR W 為氫或NHR定義中之…至!^基， p 為卜2、3、或4’及在p大於1時’各基團相同， 及 R 為^^15-烷基，其視情況地在醚官能基中經！ 至4個氧原子***，環己基，其視情況地經一 或夕個C1 - C丨5 -；):元基（其視情況地在_官能基中 經1至4個氧原子***）取代，飽和雜環五或六 員基團，其視情況地經一或多個Ci_Ci5_烷基 (其視情況地在醚官能基中經丨至4個氧原子插 98462.doc -19- 200535234 入）取代，或為C6-C1Q-芳基，其視情況地經一 或夕個c1 - c 15 -垸基（其視情況地在_官能基中 經1至4個氧原子***^广^”烷氧基、 烷胺基、或CrCir二烷胺基取代，或為具有3 至5個蛱原子之雜芳基，其視情況地經一或多 個CrC]5·院基（其視情況地在醚官能基中經工 至4個氧原子***）、Ci-Ci5_烷氧基、Ci_Ci5_ 烷胺基、或二烷胺基取代，或為苯基 基’其視情況地在苯基中經一或多 個C^-C!5-烷基（其視情況地在醚官能基中經i 至4個氧原子***）、Ci-Ci5_烷氧基、Ci_Ci5_ 烷胺基、或CrCw二烷胺基取代，或為在雜 芳基中具有3至5個碳原子之雜芳基-c〗_c4-烧 基，前者視情況地經一或多個Cl_Cl5_烷基（其 視情況地在醚官能基中經1至4個氧原子插 入烧氧基烧胺基、或CrCu-二烷胺基取代， 較佳之R基已列於以上作為上述R基一般定義之實例。 式Ilia至Illd中之R更佳為Cl_Cl5_烷基，其視情況地在醚 官能基中經1至4個氧原子***，或C6-C1G-芳基，其視情況 地經一或多個Ci-Ci5_烷基（其視情況地在醚官能基中經1至 4個氧原子***）取代。 特別地，式Ilia至Illd中之R係選自以下組成之群組：甲 基、乙基、丙基、異丙基、丁基、異丁基、第二-丁基、第 98462.doc -20- 200535234 三-丁基、戊基、異戊基、新戊基、第三_戊基、己基、2 甲基戊基、庚基、庚I基、辛基、2-乙基己基、異辛基、 壬基、異壬基、癸基、異癸基、十一碳基、十二碳基、十 三碳基、3,5,5,7_四甲基壬基、異十三碳基、十四碳基、十 五碳基、甲氧基甲基、2_乙基己氧基甲基、"氧基乙基、 2-乙氧基乙基、2-丙氧基乙基、2-異丙氧基乙基、2_ 丁基乙 基、2-與3·甲氧基丙基、2_與3_乙氧基丙基、與丙氧基 丙基、2-與3-丁氧基丙基、2_與4-甲氧基丁基、2_與4_乙氧 基丁基、2·與4-丙氧基丁基、孓與‘ 丁氧基丁基、3,6_二噚 庚基、3,6-二π辛基、4,8-二呤壬基、3,7-二嘮辛基、 一5壬基、4,7-二啰辛基、4,7•二唠壬基、4,8•二呤癸基、 3,6,8-三’癸基、3,6,9_三，号十一碳基、3,6,9，12-四嘮十三碳 基、3,6,9，12-四嘮十四碳基、未取代苯基、2-、3-與4-單取 代、2,3_、2,心與 3,4_二取代、及2,3,4-、2,3,5-、2,3,6-、2,4,5-、 2,4,6-、與3,4,5-三取代苯基，其經視情況地在醚官能基中 經1至4個氧原子***且已列於以上作為實例之a/π烷基 取代，此烷基係選自以下組成之群組：甲基、乙基、丙基、 異丙基、丁基、異丁基、第二-丁基、第三_ 丁基、戊基、異 戊基、新戊基、第三—戊基、己基、2-甲基戊基、庚基、庚 -3-基、辛基、2-乙基己基、異辛基、壬基、異壬基、癸基、 異六基十石厌基、十一碳基、十三碳基、3,5，5,7-四甲基 壬基、異十二碳基、十四碳基、十五碳基、甲氧基甲基、 2-乙基己氧基甲基、2_甲氧基乙基、2-乙氧基乙基、2_丙氧 基乙基、2-異丙氧基乙基、2-丁基乙基、2-與3-甲氧基丙基、 98462.doc -21 - 200535234 2-與3 -乙氧基丙基、2-盥3 -丙4 A。 ，、丙虱基丙基、2-與3-丁氧基丙基、 2-與4 -甲氧基丁基、與4_乙氣其 、己虱基丁基、2-與4-丙氧基丁基、 2_與4-丁氧基丁基、3,6_二号庚基、3,6_二崎辛基、48_二吟 壬基、3,7-二口号辛基、3,7_〕号壬基、❹二啊基、π 二3壬基、4,8_二，癸基、3，m_三号癸基、3,6,9_三巧十一 碳基、3,6,9，12，啊三碳基、及3,6,9，12_四号十四碳基。 使用之載劑油—般為黏性，高冻點，及特別是熱安定液 體。其以薄液膜覆蓋熱金屬表面，例如，進入閥，如此防 止或延後分解產物在金屬表面上之形成及沈積。 可作為本發明燃料及潤滑劑添加劑濃縮物之成分b)之載 劑油為’例如，礦物載劑油（基油），特別是S〇Ivent Neutral _ 500至2_黏度級，以Mn=彻至刪之婦烴聚合物為 特另!疋以♦丁烯或聚異丁烯（氫化或未氫化）為主、以聚 〜稀烴或聚（内烯烴）為主之合成載劑油，及以烧氧化長鍵醇 或盼為^合成載劑油。依照本發明，作為載劑油之環氧 乙烧、環氧丙烧及/或環氧丁炫對聚丁醇或聚異丁醇之加成 物敘述於，例如，Ep 277 345 Am專利；依照本發明使用 之其他聚稀醇聚炫氧化物敘述於wo 00/50543 Am專利。 依知、本發明使用之其他載劑油亦包括聚烯醇聚麵胺，如购 00/61708號專利所詳述。 應了解，亦可使用不同載劑油之混合物，只要其彼此及 與本發明包裝之其餘成分相容。 内燃機之化油器及進入系統，及燃料計量用喷射系統， 因雜貝（例如，由來自空氣之塵粒及來自燃燒室之未燃烴所 98462.doc -22- 200535234 造成）而提高污染。 為了降低或防止這此污毕,〇-r 八 —7木將添加劑（「清潔劑」）加 燃料以將閥及化油器或喷射车铋仅 、 糸、、死保持清潔。載劑油施加名員 外之「清洗功能」，支持且你推、、主、知 促進^ >糸劑之清潔及保持清潔作 用，因此可促成所需清潔劑量之減少。 般作為载劑油之物質顯示額外 在此亦應提及，許多種一 之作用’如清潔劑及/❹散劑’其為在此情形可降低後者 比例之原因。此種具清潔劑/分散劑作用之載劑油詳述於， 例如，前述之WO文件。 亦經常無法清楚地劃定清潔劑、分散劑及閥座磨損抑制 添加劑之作用模式，其為這些化合物在發明内容中列於成 分C)下之原因。可用於本發明包裝之慣用清潔劑列於，例 如，WO 00/50543 Α1及wo 00/61708 Α1號專利，而且包括： 聚異丁烯胺，其係依照ΕΡ-Α 244 616號專利，藉由將高 反應性聚異丁烯氫甲醯化，繼而以氨、單胺或多胺（如二 亞曱胺基丙胺、乙二胺、二伸乙三胺、三伸乙四胺、或 四伸乙五胺）還原性胺化而得， 聚（異）丁烯胺，其係藉由將具有雙鍵（主要在b-與g-位置） 之聚丁晞或聚異丁烯氯化，繼而以氨、單胺或上述多胺 胺化而得， 聚（異）丁烯胺，其係藉由以空氣或臭氧將聚（異）丁烯中 之雙鍵氧化而得羰基或羧基化合物，繼而在還原（氫化） 條件下胺化而得， 聚異丁烯胺，其係依照DE-A 196 20 262號專利，由聚 98462.doc -23 - 200535234R8 is NHR, W is hydrogen or a ... to! ^ Group in the definition of NHR, p is B2, 3, or 4 'and when p is greater than 1, each group is the same, and R is 15-alkyl, As appropriate in the ether functional group! Insertion of 4 to 4 oxygen atoms, cyclohexyl, which is optionally substituted by one or one C1-C 丨 5-;): elementary group (which is optionally substituted by 1 to 4 oxygen atoms in the _ functional group) , A saturated heterocyclic five- or six-membered group, optionally via one or more Ci_Ci5_ alkyl groups (which optionally, through the ether functional group, are inserted via 丨 to 4 oxygen atoms 98462.doc -19- 200535234) ) Substituted, or C6-C1Q-aryl, optionally via one or one c1-c 15 -fluorenyl groups (optionally inserted in the _ functional group via 1 to 4 oxygen atoms ^ 广 ^ " Alkoxy, alkylamino, or CrCir dialkylamino substituted, or a heteroaryl group having 3 to 5 fluorene atoms, optionally with one or more CrC] 5 Substituted in the ether functional group by 4 oxygen atoms), Ci-Ci5_alkoxy, Ci_Ci5_ alkylamino, or dialkylamino substituted, or phenyl group, which is optionally substituted in phenyl group One or more C ^ -C! 5-alkyl (which is optionally inserted in the ether functional group via i to 4 oxygen atoms), Ci-Ci5_alkoxy, Ci_Ci5_ alkylamino, or CrCw dioxane Amine substitution, or having 3 in heteroaryl Heteroaryl group of 5 carbon atoms-c〗 _c4-alkyl group, the former optionally via one or more Cl_Cl5_ alkyl groups (which optionally insert alkoxy groups through 1 to 4 oxygen atoms in the ether functional group The amine group or CrCu-dialkylamino group is substituted, and the preferred R group is listed above as an example of the general definition of the above R group. R in the formulae Ilia to Ild is more preferably Cl_Cl5_ alkyl group, as appropriate in The ether functional group is inserted via 1 to 4 oxygen atoms, or a C6-C1G-aryl group, optionally via one or more Ci-Ci5_alkyl groups (which, if appropriate, are passed through the ether functional group via 1 to 4 Oxygen atoms are inserted) substitution. In particular, R in formulae Ilia to Illd is selected from the group consisting of methyl, ethyl, propyl, isopropyl, butyl, isobutyl, and second-butyl Base, 98462.doc -20- 200535234 tri-butyl, pentyl, isopentyl, neopentyl, tert-pentyl, hexyl, 2 methylpentyl, heptyl, heptyl, octyl, 2-ethylhexyl, isooctyl, nonyl, isononyl, decyl, isodecyl, undecyl, dodecyl, tridecyl, 3,5,5,7-tetramethyl Nonyl, isotridecyl, 14 carbon, 15 carbon , Methoxymethyl, 2-ethylhexyloxymethyl, " oxyethyl, 2-ethoxyethyl, 2-propoxyethyl, 2-isopropoxyethyl, 2_ Butylethyl, 2- and 3-methoxypropyl, 2- and 3-ethoxypropyl, and propoxypropyl, 2- and 3-butoxypropyl, 2- and 4- Methoxybutyl, 2- and 4-ethoxybutyl, 2 · and 4-propoxybutyl, fluorene and 'butoxybutyl, 3,6-difluorenylheptyl, 3,6- Di-π-octyl, 4,8-diamidonyl, 3,7-diamidino-octyl, 1-5 nonyl, 4,7-diamidino-octyl, 4,7 • diamidino-nonyl, 4,8 • Dipictyl decyl, 3,6,8-tri'decyl, 3,6,9-tris, undecyl carbon, 3,6,9, 12-tetrakistridecyl, 3,6,9 , 12-tetrafluorotetradecyl, unsubstituted phenyl, 2-, 3-, and 4-monosubstituted, 2,3_, 2, and 3,4-disubstituted, and 2,3,4-, 2 , 3,5-, 2,3,6-, 2,4,5-, 2,4,6-, and 3,4,5-trisubstituted phenyl groups, optionally through ether functional groups A / π alkyl substitution with 1 to 4 oxygen atoms inserted and listed above as examples, this alkyl is selected from the group consisting of methyl, ethyl, propyl, isopropyl, butyl, Isobutyl, second- Butyl, tert-butyl, pentyl, isopentyl, neopentyl, tert-pentyl, hexyl, 2-methylpentyl, heptyl, hept-3-yl, octyl, 2-ethyl Hexyl, isooctyl, nonyl, isononyl, decyl, isohexyl, decylthio, undecyl, tridecyl, 3,5,5,7-tetramethylnonyl, iso Dodecyl, tetradecyl, pentadecyl, methoxymethyl, 2-ethylhexyloxymethyl, 2-methoxyethyl, 2-ethoxyethyl, 2-propyl Ethoxyethyl, 2-isopropoxyethyl, 2-butylethyl, 2- and 3-methoxypropyl, 98462.doc -21-200535234 2- and 3-ethoxypropyl, 2-3-C 4 A. , Propionylpropyl, 2- and 3-butoxypropyl, 2- and 4-methoxybutyl, and 4-acetylene, hexylbutyl, 2- and 4-propoxy Butyl, 2- and 4-butoxybutyl, 3,6_-diheptyl, 3,6_- dizyl octyl, 48-di-nonyl, 3,7-di-slogan octyl, 3 , 7_] nonyl, arsenyl, π di-3 nonyl, 4,8_di, decyl, 3, m_tridecyl, 3,6,9_tridecyl undecyl, 3 , 6,9,12, ah three carbon group, and 3,6,9,12_ fourteen carbon group. The carrier oils used are generally viscous, high freezing points, and especially thermally stable liquids. It covers a hot metal surface with a thin liquid film, for example, into a valve, thus preventing or delaying the formation and deposition of decomposition products on the metal surface. Carrier oils that can be used as component b) of the fuel and lubricant additive concentrates of the present invention are, for example, mineral carrier oils (base oils), especially SOIvent Neutral _ 500 to 2_ viscosity grades, with Mn = thorough The deleted hydrocarbon polymers are special! 合成 Synthetic carrier oils mainly composed of butene or polyisobutylene (hydrogenated or unhydrogenated), poly ~ dilute hydrocarbons or poly (internal olefins), and Oxidized long-bond alcohols or lanthanides are synthetic carrier oils. In accordance with the present invention, the addition of ethylene oxide, propylene oxide, and / or butylene oxide to polybutanol or polyisobutanol as a carrier oil is described in, for example, the Ep 277 345 Am patent; Other polyalcohols used in the present invention are described in the WO 00/50543 Am patent. It is known that other carrier oils used in the present invention also include polyenol polyamines, as detailed in the patent No. 00/61708. It will be appreciated that mixtures of different carrier oils can also be used as long as they are compatible with one another and with the remaining ingredients of the packaging of the present invention. The carburetor and access system of the internal combustion engine and the fuel metering injection system increase pollution due to impurities (for example, caused by dust particles from the air and unburned hydrocarbons from the combustion chamber 98462.doc -22- 200535234). In order to reduce or prevent this contamination, 〇-r Ya 7-7 fuels additives ("detergents") to keep the valve and carburetor or injection car bismuth clean, pure, pure. Carrier oil is applied to the "cleaning function" outside of the celebrities. It supports and promotes the cleaning and maintenance of tinctures. Therefore, it can help reduce the amount of cleaning required. Substances which are generally used as carrier oils have been shown to be extra. It should also be mentioned here that many kinds of effects, such as detergents and / or dispersants, are the reasons why the latter ratio can be reduced in this case. Such a carrier oil having a detergent / dispersant effect is described in detail in, for example, the aforementioned WO document. It is also often not possible to clearly define the mode of action of detergents, dispersants and valve seat wear suppressing additives, which is why these compounds are listed under component C) in the summary of the invention. Conventional cleaning agents that can be used in the packaging of the present invention are listed in, for example, WO 00/50543 A1 and wo 00/61708 A1, and include: Polyisobutyleneamine, which is in accordance with EP-A 244 616, by Reactive polyisobutylene hydroformylation followed by ammonia, monoamine, or polyamine (such as diiminoaminopropylamine, ethylenediamine, diethylene glycol triamine, triethylene glycol tetraamine, or tetraethylene glycol pentaamine) Obtained by reductive amination, poly (iso) butenamine, which is obtained by chlorinating polybutane or polyisobutene with a double bond (mainly at the b- and g-positions), followed by ammonia, monoamine or The polyamine is obtained by amination of the above-mentioned polyamine, which is obtained by oxidizing the double bond in the poly (iso) butene with air or ozone to obtain a carbonyl or carboxyl compound, and then under reducing (hydrogenating) conditions Polyisobutylene amine, which is obtained by the following amination, according to DE-A 196 20 262 patent, poly 98462.doc -23-200535234

這些反應產物氫化而得， 由反應聚異丁烯環氧化物與氨、 含羥基聚異丁烯胺，其係依照EP_A 476 485號專利，藉 •氣、單胺或上述多胺而得， π至c3G-烷醇、C6jc3G_烷二 C!•至C3〇-烷基環己醇、或Ci_These reaction products are obtained by hydrogenation, and are obtained by reacting polyisobutylene epoxide with ammonia and hydroxyl-containing polyisobutyleneamine, which are obtained by using gas, monoamine or the above polyamine in accordance with EP_A 476 485 patent, π to c3G-alkane Alcohol, C6jc3G_alkanediC! To C3O-alkylcyclohexanol, or Ci_

聚鱗胺，其係藉由反應c2-至 醇、單或二c2-至C3G-烷胺、CV 至烷基酚，與每個羥基或胺基為1至3〇莫耳之環氧乙 烷及/或環氧丙烷及/或環氧丁烷，繼而以氨、單胺或上述 多胺還原性胺化而得，及 「聚異丁烯Mannich鹼」，其係依照EP-A 831 141號專 利，藉由反應經聚異丁烯取代酚與醛及單胺或上述多胺 用於本發明之其他清潔劑及/或閥座磨損抑制添加劑列 於，例如，W〇00/47698 A1號專利，而且包括具有至少— 個數量平均分子量（Mn)為85至2〇 〇〇〇之疏水性烴基及至少 一個極性部份之化合物，而且其係選自： (0 具有至多6個氮原子之單或多胺基，其中至少一個氮 原子具有驗性質； (H) 確基，其視情況地組合經基； (ni)組合胺或多胺基之羥基，其中至少一個氮原子具有驗 98462.doc -24- 200535234 性質； (iv) 竣基或其驗金屬或其驗土金屬鹽； (v) 文基或其驗金屬或其驗土金屬鹽； (V1)以羥基、單或多胺基（其中至少一個氮原子具有鹼性 質）或以胺甲酸基封端之聚環氧{广至^厂烷基； (vii)羧酸酯基； (VH!)衍生自琥珀酸酐且具有羥基及/胺基及/或醯胺基及/ 或醯亞胺基之部份；及/或 ⑻藉由經取代齡與越及單或多胺之Mannich反應而得之_ 部份。 合單或多胺基之添加劑⑴較佳為MN=300至 5000，以聚丙 烯或以高反應性（即，主要具有終端雙鍵，通常在心及y位 置）或習知（即，主要具有内部雙鍵）之聚丁烯或聚異丁烯為 主之聚伸烷胺或聚伸烷多胺。此種高反應性聚異丁烯為主 之添加劑特別地揭示於EP 244 61ό A2號專利，其可由聚異 丁烯（其可含至多20重量％之正丁烯單位）藉由氫甲醯化及 _ 以氨、單胺或多胺（如二亞曱胺基丙胺、乙二胺、二伸乙三 月安、— 、二伸乙四胺、或四伸乙五胺）還原性胺化而製備。在添 蜊製備中使用主要具有内部雙鍵（通常在卜及位置）之 =丁烯或聚異丁烯作為原料時，可能之製備途徑為藉氣化 龜而胺化，或藉由以空氣或臭氧將雙鍵氧化而得羰基或羧 · 基化口物，繼而在還原性（氫化）條件下胺化。在此使用之胺 可為與以上用於經氫曱醯化高反應性聚異丁烯之還原性胺 -Polysquamamine, which reacts by reacting c2- to alcohol, mono- or di-c2- to C3G-alkylamine, CV to alkylphenol, and ethylene oxide with 1 to 30 moles per hydroxyl or amine group And / or propylene oxide and / or butylene oxide, followed by reductive amination with ammonia, monoamine, or the above polyamines, and "polyisobutylene Mannich base", which is in accordance with EP-A 831 141 patent, Other cleaning agents and / or valve seat wear suppressing additives used in the present invention by polyisobutylene-substituted phenols with aldehydes and monoamines or polyamines as described above are listed in, for example, WO 00/47698 A1, and include At least one compound having a hydrophobic hydrocarbon group having a number average molecular weight (Mn) of 85 to 2000 and at least one polar moiety, and is selected from: (0) a mono- or polyamine group having up to 6 nitrogen atoms , At least one of the nitrogen atoms has a test property; (H) an exact group, which optionally combines warp groups; (ni) a hydroxyl group of an amine or a polyamine group, in which at least one nitrogen atom has a test 98462.doc -24- 200535234 Nature; (iv) end foundation or metal test or soil test metal salt; (v) foundation or metal test or soil test Metal salts; (V1) polyepoxides (up to ^ alkyl) terminated with hydroxy, mono or polyamine groups (where at least one nitrogen atom has basic properties) or carbamate groups; (vii) carboxylate groups ; (VH!) A moiety derived from succinic anhydride and having a hydroxyl group and / or an amino group and / or amidinyl group and / or amidinyl group; and / or Mannich reaction _ part. Mono- or polyamine-based additives ⑴ preferably MN = 300 to 5000, with polypropylene or with high reactivity (ie, mainly with terminal double bonds, usually in the heart and y position) Or conventional (ie, mainly having internal double bonds) polybutene or polyisobutylene-based polyalkyleneamine or polyalkylenepolyamine. Such highly reactive polyisobutylene-based additives are specifically disclosed in EP 244 61ό A2 patent, which can be made from polyisobutylene (which can contain up to 20% by weight of n-butene units) by hydroformylation and _ with ammonia, monoamine or polyamine (such as diimidoaminopropylamine, ethylenediamine Amine, diethylene glycol, diethylene glycol, diethylene glycol, diethylene glycol, tetraethylene glycol, or tetraethylene glycol.) Prepared by reductive amination. Used in the preparation of clams. When an internal double bond (usually at the position) = butene or polyisobutylene is used as a raw material, the possible preparation method is amination by gasification of the turtle, or carbonyl group is obtained by oxidizing the double bond with air or ozone Or carboxylated compounds, and then aminated under reducing (hydrogenating) conditions. The amines used herein may be the reducing amines used above for the hydrogenation of highly reactive polyisobutylene-

δ °以聚丙稀為主之對應添加劑特別地敘述於WQ 98462.doc -25- 200535234 94/24231 A1 號專利。 含單胺基之其他較佳添加劑⑴為平均聚合度p==5至ι〇〇之 聚異丁燁與氧化氮或氧化氮及氧之混合物之反應產物之氣 化產物’其特別地敘述於W〇 97/〇3946幻號專利。 含單胺基之其他較佳添加劑⑴為由聚異丁烯環氧化物藉 由以胺反應繼而將胺基醇脫水及還原而得之化合物，其特 別地敘述於DE 196 20 262 A1號專利。δ ° The corresponding additives mainly based on polypropylene are described in particular in WQ 98462.doc -25- 200535234 94/24231 A1. Other preferred additives containing monoamine groups are gasification products of the reaction product of polyisobutylene with an average degree of polymerization p == 5 to ι〇00 and nitrogen oxide or a mixture of nitrogen oxide and oxygen, which are specifically described in W〇97 / 〇3946 magic number patent. Other preferred additives containing monoamine groups are compounds obtained from polyisobutylene epoxides by dehydration and reduction of amino alcohols by amine reactions, which are specifically described in DE 196 20 262 A1.

含硝基添加物（π)，其視情況地組合羥基，較佳為平均聚 合度P為5至100或10至100之聚異丁烯與氧化氮或氧化氮及 氧之混合物之反應產物，其特別地敘述於W〇 96/〇3367幻 及WO 96/03479 A1號專利。這些反應產物通常為硝基聚異 丁烷（例如，《，心二硝基聚異丁烷）與混合羥基硝基聚異丁烷 (例如，α-硝基-/5-羥基聚異丁烷）之混合物。 含羥基組合單或多胺基之添加劑（ii〇特別地為由聚異丁 烯而得之聚異丁烯環氧化物（較佳為主要具有終端雙鍵及Nitrogen-containing additive (π), which optionally combines hydroxyl groups, preferably a reaction product of polyisobutylene having an average degree of polymerization P of 5 to 100 or 10 to 100 and nitrogen oxide or a mixture of nitrogen oxide and oxygen, which is particularly It is described in WO96 / 〇3367 and WO 96/03479 A1. The products of these reactions are usually nitro polyisobutane (for example, <RTI ID = 0.0>, </ RTI> cardiac dinitro polyisobutane) and mixed hydroxynitro polyisobutane (for example, α-nitro- / 5-hydroxy polyisobutane ) Of the mixture. Additives containing hydroxyl group mono- or polyamine groups (ii. In particular polyisobutylene epoxides obtained from polyisobutylene (preferably having mainly a terminal double bond and

ΜβΟί^ΟΟΟ)與氨或單或多胺之反應產物，其特別地敛述 於ΕΡ 476 485 Α1號專利。 含羧基或其鹼金屬或鹼土金屬鹽之添加劑（iv)較佳為 -烯烴與順丁烯二酸酐之共聚物，其具有5〇〇至2〇〇〇〇 之總分子量且其-些或所有縣已轉化成鹼金屬或驗土金 屬鹽’及任何其㈣基已與醇或胺反應。此添加劑特別地 揭示於EP 307 815 A1號專利。 此添加劑主要用以防止閥座 磨損，而且可有利地組合慣用清潔劑（如$(異）丁烯胺或聚 醚胺）使用，如WO 87/01 126 A1號專利所述。 98462.doc -26- 200535234 含續酸基或其驗金屬或驗土金屬鹽之添加劑（v)較佳為 硫號轴酸炫醋之驗金屬或驗土金屬鹽，其特別地敛述㈣ 639 632 A1號專利。此添加劑主要用以防止閥座磨損，而且 可有利地組合慣用清潔劑（如聚（異）丁稀胺或聚喊胺）使用。 含聚環氧-c2-c4-烧基部份之添加劑（vi)較佳為聚喊或聚 鍵胺，其係藉由反應c2-至c60_貌醇、Q•至C3〇_炫二醇、單 或二-c2-c30-烧胺、Cl_C30_院基環己醇、或c】_c3『烧基盼， 與每個經基或胺基為U30莫耳之環氧乙炫及/或環氧丙院 及/或環氧丁烷，及在聚醚胺之情形繼而以氨、單胺或多胺 還原性胺化而得。此產物特別地敘述於Ep3i〇 875 Ai、Ep 356 725 A1、EP 7〇〇 985 A1、及 us 4,877,4i6 號專利。在聚 醚之情形，此產物亦具有載劑油性質。其典型實例為十三 醇：氧化物、異十三醇、異壬齡丁氧化物、與聚異丁烯^ 丁氧化物，及與氨之對應反應產物。 含緩酸S旨基之添加劑（vii)較佳為單、二或三缓酸盘長鍵 烧醇或多醇之酉旨’特別是在⑽具有2平方毫米/秒之最小 ，度者’其特別地敘述於DE 38 38 918 A1號專利。使用之 单、二或三竣酸可為脂族或芳族酸，而且特別適合之 或酉旨多醇為長鏈，例如’具有⑴糊碳原子。此酉旨之典型 代表為異辛醇、異壬醇、異癸醇、與異十三醇之己二酸醋、 酞酸酉旨、異敗酸酿、對酞酸酉旨、與苯三甲酸酉旨。 物亦具有載劑油性質。 λ含衍生自琥轴酸酐且具有經基及/胺基及/或酿胺基及/或 ^亞月女基之部份之添加劑（viH)較佳為聚異丁稀基號王白酸酐 98462.doc -27- 200535234 之對應衍生物，其係藉由以熱途徑或經氣化聚異丁烯反應 MN〜300至5000之習知或高反應性聚異丁烯與順丁烯二酸 酐而得。特別有盈為具脂族多胺（如乙二胺、二伸乙三胺、 二伸乙四胺、或四伸乙五胺)之衍生物。此汽油燃料添加劑 特別地敘述於US 4,849,572號專利。 含藉由㈣«與酸及單或多胺之Mm—反應而得之 部份之添加劑（ix)較佳為έ&lt;τ&lt;取s π Μ ’ 1马、、工水異丁烯取代酚與甲醛及單或 多胺（如乙二胺、二伸乙三胺、三伸乙四胺、或四伸乙五胺） 之反應產物。此經聚異丁烯取代盼可源自ΜΝ=则至麵之 習知或高反應性聚異丁醇。此「 L 此聚異丁烯-Mannich鹼」特 別地敛述於EP831 141 A1號專利。 對於個別地詳述之添加劑 ^ if Φ ^ ^ 更精確疋義，在此明確地參 考上述先仃技藝文件之揭示。 作為成分C)之分散劑為，例如 凸脸、护… ♦異丁烯琥珀酸酐之醯 亞胺、酿胺、酯、及銨與鹼金 、 於潤滑油’但是有時亦在亀：2化合物特別地用 如果需要，可存在作為本發明2中作為清潔劑。 劑及助劑為 匕我之成分d)之其他添加 有機溶劑，例如，醇，如甲醇 丁醇、異丁醇、第二丁醇、戊醇二：丙醇、異丙醇、 醇，例如，二醇，如乙二醇”知、新戊醇、或己 2,3-、或仏丁二醇子，2-或丙二醇、1，2-、 一 一 Ci 二醇、式-、一 如，醚，如甲基第三丁基ϋ、二或三丙二醇，例 二醇二甲基_、1,2-乙二醇 ^甲基喊或1,2-乙 乙基醚或1，2-乙二醇二乙基 98462.doc -28- 200535234 醚、3 -曱氧其&amp; ^ 土 _予、3 -異丙氧基丙醇、四氫呋喃、哎-例如，_，士 &amp; ^ — ρτ 5 丙@同、甲乙酮或二丙酮醇，例如， 酸甲酯、乙酸Γ龄 酉曰，如乙 乙酉曰、乙酸丙酯、或乙酸丁酯 胺，如I曱其灿&amp; 例如，内醯 混合物，=各;定一，例如，脂族或芳族煙及其 甲苯、-甲己烧、庚文完、辛院、異辛燒、石油醚、 —甲本、乙基苯、四氫萘、十氫萘、_ Ψ其# 揮發油，例如，垆铷4 i &gt; 一甲基奈、或 H絲油，如汽油、燈油、柴油、或加熱油， 4 4抑制劑’例如，在鐵質金屬腐蝕保護之情形為以有 機《或雜環芳族之録鹽為主，其具有形成膜之趨=有 抗氧化劑或安定劑，例如，以胺（如對伸苯二胺、二環己 胺、或其衍生物)或酚(如2,二-第三-丁基酚或3,5·二_:三_ 丁基-4-羥基苯基丙酸）為主， 去乳化劑， 抗》靜電劑， 金屬錯合物，如二茂鐵或甲基環戍二稀基鐘三幾基， 潤滑改良劑（潤滑添加劑），如特定之脂肪酸、稀基破轴 酉欠S曰、一（羥烷基）脂肪胺、羥基乙醯胺、或萬麻油， 用於降低燃料之pH之胺， 蒽酉昆衍生物以外之其他標識劑，及 染料。 成刀a)，即，至少一種蒽醌衍生物，在本發明包裝中之 /辰度一般係選擇為在將此包裝加入礦物油後，其中存在所 需之標識劑濃度之程度。例如，礦物油中之標識劑之典型 濃度為0.01至數十ppm重量比之範圍。 98462.doc -29- 200535234 成分b)，即，至少一種載劑油，係以一般為i至％重量％， 特別是5至30重量％之濃度存在於本發明包裝中，及 成分c)，即，至少一種清潔劑及/或至少一種分散劑，一 般為25至90重量％ ’特別是3〇至8〇重量％， 其在各情形係基於成分心至咐叫存在時）之總量，而且 成分a)至e)及d)(存在時）之個別濃度之和加總^⑼重量％。 在腐餘抑·、抗氧化劑或安定劑、去乳化劑、抗靜電 劑、金屬錯合物、潤滑改良劑、及用於降低燃料之pH之胺 存在於本發明包裝中作為成分d)時，其濃度之和以包裝總 重量（即’成分a)至c)及d)之總量）計—般不超過1〇重量％， 腐姓抑制劑與去乳化劑之濃度在各情形一般為包裝總量之 約0.01至0.5重量％之範圍。 在額外有機溶劑（即，未隨其餘成分引入）存在於本發明 匕衣中作為成分d)時’其濃度之和以包裳總重量計-般不 超過20重里％。這些溶劑通常源自標識劑及，或染料之溶 液’其係以更精確計量之觀點代替純標識劑及/或染料加入籲 包裝。 在'1'_生物以外之其他標識劑存在於本發明包裝中作 為成分句時，其濃度係依序以將此包裝加入礦物油後其所 具有之含量計。成分a)所述者加以適當之變更即可適用。 狀在=料存在於本發明包裝中作為成分d)時，其濃度以包 瓜總1計—般為’例如，0·1至5重量％之間。 實例： - 調查下示之蒽醌衍生物。化合物丨至9係藉文件砂〇 323 98462.doc -30- 200535234 184A1中所述之方法，由1，4,5,8-四氯蒽醌與經適當地取代 之苯胺合成。ΜβΟί ^ ΟΟΟ) is the reaction product with ammonia or a mono- or polyamine, which is particularly described in EP 476 485 A1. The additive (iv) containing a carboxyl group or an alkali metal or alkaline earth metal salt thereof is preferably a copolymer of an olefin and maleic anhydride, which has a total molecular weight of 5000 to 20000 and some or all of them The county has converted the alkali metal or soil metal salt 'and any of its fluorenyl groups has reacted with alcohol or amine. This additive is disclosed in particular in EP 307 815 A1. This additive is mainly used to prevent valve seat wear, and can be advantageously used in combination with conventional cleaners such as $ (iso) butenamine or polyetheramine, as described in WO 87/01 126 A1. 98462.doc -26- 200535234 The additive (v) containing a continuous acid group or its metal or soil test metal salt (v) is preferably a metal or soil test metal salt of sulfur acid vinegar, which is specifically described ㈣ 639 Patent No. 632 A1. This additive is mainly used to prevent valve seat wear, and can be advantageously used in combination with conventional cleaners (such as poly (iso) butylamine or polyamine). The additive (vi) containing a polyepoxy-c2-c4-carbon-based moiety is preferably a polyamine or polybonded amine, which is obtained by reacting c2- to c60_ol, Q • to C3〇_diol , Mono- or di-c2-c30-burned amine, Cl_C30_recyclyl cyclohexanol, or c] _c3 "burned group, and each of the base or amine group is U30 mole of ethylene oxide and / or ring Oxypropane and / or butylene oxide, and in the case of polyetheramine, followed by reductive amination with ammonia, monoamine or polyamine. This product is described in particular in Ep 3 IO 875 Ai, Ep 356 725 A1, EP 700 985 A1, and US Patent No. 4,877,4i6. In the case of polyethers, this product also has carrier oil properties. Typical examples are tridecanols: oxides, isotridecanol, isononyl butoxide, polyisobutylene ^ butoxide, and corresponding reaction products with ammonia. The additive (vii) containing a delayed acid S radical is preferably a mono-, di-, or tri-acid disc long-chain burned alcohol or a polyhydric alcohol. 'Especially, it has a minimum of 2 square millimeters per second. It is described in particular in DE 38 38 918 A1. The mono-, di-, or tri-acids used may be aliphatic or aromatic acids, and are particularly suitable or the polyhydric alcohols are long-chain, e.g., having a carbon atom of a paste. Typical examples of this purpose are isooctanol, isononyl alcohol, isodecanol, adipic acid vinegar with isotridecanol, phthalic acid purpose, isostearic acid production, terephthalic acid purpose, and trimellitic acid Intent. It also has carrier oil properties. λ The additive (viH) containing a portion derived from succinic anhydride and having a base and / or an amino group and / or an amine group and / or an arylene group is preferably a polyisobutylene king white acid anhydride 98462 The corresponding derivative of .doc -27- 200535234 is obtained by reacting MN ~ 300 to 5000 by thermal route or gasified polyisobutylene, or the highly reactive polyisobutylene and maleic anhydride. In particular, Yingying is a derivative with aliphatic polyamines (such as ethylenediamine, ethylenediamine, ethylenediamine, or ethylenediamine). This gasoline fuel additive is described in particular in US Patent No. 4,849,572. The additive (ix) containing a portion obtained by the reaction of Mm with an acid and a mono- or polyamine (ix) is preferably 〈〈 τ〉 1 horse, isobutene in working water, substituted phenol and formaldehyde, and The reaction product of mono- or polyamines (such as ethylenediamine, ethylenediamine, triethylenetetraamine, or tetraethylenepentamine). This polyisobutylene substitution can be derived from the conventional or highly reactive polyisobutanol. This "L this polyisobutylene-Mannich base" is specifically described in EP831 141 A1. For the additives detailed individually ^ if Φ ^ ^, the meaning is more precise, and the disclosure of the prior art document is explicitly referred to here. The dispersant as component C) is, for example, a convex face, protecting ... ♦ isoimene succinic anhydride of imine, amine, ester, and ammonium and alkali gold, in lubricating oil 'but sometimes also in 亀: 2 compounds in particular It can be used as a cleaning agent in the present invention 2 if necessary. Additives and auxiliaries are ingredients of d), other added organic solvents, for example, alcohols, such as methanol butanol, isobutanol, second butanol, pentanol: propanol, isopropanol, alcohol, for example, Diols, such as ethylene glycol, neopentyl alcohol, or hexane 2,3-, or butanediol, 2- or propylene glycol, 1,2-, Ci glycol, formula-, as, ether , Such as methyl tert-butylphosphonium, di- or tripropylene glycol, such as glycol dimethyl_, 1,2-ethylene glycol ^ methyl or 1,2-ethylethyl ether or 1,2-ethanediethylene glycol Alcohol diethyl 98462.doc -28- 200535234 Ether, 3-Hydroxy, &amp; ^ 土 予, 3 -isopropoxypropanol, tetrahydrofuran, hey-for example, 士, + &gt; ρτ 5 propyl @ 同, methyl ethyl ketone or diacetone alcohol, for example, methyl acetate, acetic acid, such as ethyl acetate, propyl acetate, or butyl acetate amine, such as I 曱 其 灿 &amp; For example, an intrinsic mixture, = Each; set one, for example, aliphatic or aromatic tobacco and its toluene, -methylhexane, Gengwenwan, Xinyuan, isooctyl, petroleum ether, methylbenzene, ethylbenzene, tetrahydronaphthalene, decahydro Naphthalene, _ Ψ 其 # volatile oil, for example, 垆 铷 4 i &gt; Kenai, or H silk oil, such as gasoline, kerosene, diesel, or heating oil, 4 4 inhibitors' For example, in the case of ferrous metal corrosion protection is mainly organic or heterocyclic aromatic salts, which Has a tendency to form a film = has an antioxidant or stabilizer, for example, an amine (such as p-phenylenediamine, dicyclohexylamine, or a derivative thereof) or a phenol (such as 2, di-tertiary-butylphenol or 3,5 · di_: tri-butyl-4-hydroxyphenylpropionic acid), demulsifier, antistatic agent, metal complex, such as ferrocene or methylcyclofluorene Sanjiji, a lubricity improver (lubricant additive), such as a specific fatty acid, a dilute base, a monohydroxy (hydroxyalkyl) fatty amine, hydroxyacetamide, or sesame oil, used to lower the pH of fuel Amines, markers other than anthracene derivatives, and dyes. Knife a), that is, at least one anthraquinone derivative, is generally selected to include minerals in this package To the extent that the required concentration of the marking agent is present in the oil. For example, a typical concentration of the marking agent in mineral oil is 0.01 to tens of ppm by weight. The range of the amount ratio. 98462.doc -29- 200535234 Ingredient b), that is, at least one carrier oil is present in the packaging of the present invention in a concentration of generally i to %% by weight, especially 5 to 30% by weight, And ingredient c), that is, at least one cleaning agent and / or at least one dispersant, generally 25 to 90% by weight 'especially 30 to 80% by weight, which in each case is based on the presence of ingredients ), And the sum of the individual concentrations of components a) to e) and d) (when present) add up to ^ ⑼ by weight. , Metal complexes, lubricity improvers, and amines used to reduce the pH of fuels are present in the packaging of the present invention as component d), and the sum of their concentrations is based on the total weight of the package (ie, components a) to c) and d The total amount of) is generally not more than 10% by weight, and the concentration of the rotting inhibitor and deemulsifier is generally in the range of about 0.01 to 0.5% by weight of the total packaging. When additional organic solvents (i.e., not introduced with the remaining ingredients) are present in the dagger of the present invention as ingredient d) ', the sum of their concentrations is not more than 20% by weight based on the total weight of the package. These solvents are usually derived from a marking agent and / or a dye solution &apos; which is added to the packaging in place of pure marking agent and / or dye from a more accurate metering point of view. When other labeling agents other than '1' organisms are present in the package of the present invention as an ingredient sentence, the concentration is in order based on the content of the package after it is added to the mineral oil. Appropriate changes can be applied to component a). When the ingredient is present in the packaging of the present invention as the component d), its concentration is based on a total of 1 of the melon-generally '', for example, between 0.1 and 5% by weight. Examples:-Investigation of anthraquinone derivatives shown below. Compounds 丨 to 9 were synthesized from 1,4,5,8-tetrachloroanthraquinone and an appropriately substituted aniline by the method described in the document No. 323 98462.doc -30-200535234 184A1.

化合物l(Xmax ; =753 奈米，THF): rWi τττ η 化合物2(Xmax : =750奈米，THF) ·· ο ηνΌ^ fWS TTT 0 ΗΝιχ 化合物3(Xmax - =673奈米，THF):Compound 1 (Xmax; = 753 nm, THF): rWi τττ η Compound 2 (Xmax: = 750 nm, THF) ·· ο ηνΌ ^ fWS TTT 0 ΗNιχ Compound 3 (Xmax-= 673 nm, THF):

化合物 4(Xmax = 758奈米，THF):Compound 4 (Xmax = 758 nm, THF):

98462.doc -31 - 200535234 化合物 5(Xmax = 756奈米，THF):98462.doc -31-200535234 Compound 5 (Xmax = 756 nm, THF):

化合物 6(Xmax = 756奈米，THF):Compound 6 (Xmax = 756 nm, THF):

化合物 7(Xmax = 756奈米，THF) ··Compound 7 (Xmax = 756 nm, THF) ··

化合物8 :Compound 8:

98462.doc -32- 200535234 化合物 9(Xmax = 670奈米，THF):98462.doc -32- 200535234 Compound 9 (Xmax = 670 nm, THF):

三取代化合物係如化合物8製備之副產物而得。 化合物 10(λ_χ = 643奈米，THF):Tri-substituted compounds are obtained as by-products of the preparation of compound 8. Compound 10 (λ_χ = 643 nm, THF):

一 XXA XX

S.G· 33(由 BASF Aktiengesellschaft市售） 化合物 ll(Xmax = 328奈米，THF): 〇S.G. 33 (commercially available from BASF Aktiengesellschaft) Compound 11 (Xmax = 328 nm, THF): 〇

00

(由 BASF Aktiengesellschaft市售） 化合物 12(Xmax = 648奈米，THF): R:基團混合物(Commercially available from BASF Aktiengesellschaft) Compound 12 (Xmax = 648 nm, THF): R: group mixture

S.B. 79(由 BASF Aktiengesellschaft市售） 98462.doc -33- 200535234 比較 Omax = 770奈米，丁HP): 使用之比較性化合物為下式之g太青：S.B. 79 (commercially available from BASF Aktiengesellschaft) 98462.doc -33- 200535234 Comparison Omax = 770 nm, DHP): The comparative compound used is g too green of the following formula:

(依照WO 98/5 2950 A1號專利之實例製備） 儲存安定性之實驗： 使用之燃料與潤滑添加劑濃縮物之測試混合物，及其中 所含成分及其特定比例，詳述於以下表1 : 表1 : 成分 _____^化學組合物 重量％ 帝售清潔劑 聚異丁烯胺(PIBA) ; PIBA 濃度為5〇重量％之溶液 70 市售載劑油 脂肪醇丙氧化物 15 市售腐蝕保護 二聚合及寡聚合脂肪酸 0.1 市售去乳化劑 脂肪醇乙氧化物 0.1 溶劑 二甲整_— 14.8 (清潔劑、載劑油、腐蝕保護、與去乳化劑為，例如，得 自或經由 BASF Aktiengesellschaft市售） A)調查表1指定之化合物1至9及比較性化合物之儲存安 定性，比較主成分、清潔劑與載劑油。關於此點，將 50至100毫克之特定化合物溶於50毫升之Shellsol AB，或在此化合物於Shellso1 AB中之溶解度不足時， 首先最初將其以約5毫升之異丙醇或NMP溶解，然後以 98462.doc -34- 200535234(Prepared according to the example of WO 98/5 2950 A1 patent) Storage stability experiment: The test mixture of the fuel and lubricating additive concentrate used, and the components and specific proportions contained therein are detailed in Table 1 below: Table 1: Ingredients _____ ^% by weight of the chemical composition, polyisobutyleneamine (PIBA), a cleaner sold; a solution with a PIBA concentration of 50% by weight, 70 a commercially available carrier oil, fatty alcohol propoxide, 15 a commercially available corrosion protection dimerization, and Oligomeric fatty acid 0.1 Commercially available de-emulsifier fatty alcohol ethoxylate 0.1 Solvent dimethyl __ 14.8 (Detergents, carrier oils, corrosion protection, and de-emulsifiers are, for example, available from or commercially available through BASF Aktiengesellschaft) A) Check the storage stability of compounds 1 to 9 and comparative compounds specified in Table 1, and compare the main ingredients, detergents and carrier oil. In this regard, when 50 to 100 mg of the specific compound is dissolved in 50 ml of Shellsol AB, or when the solubility of the compound in Shellso1 AB is insufficient, it is firstly dissolved in about 5 ml of isopropanol or NMP, and then As 98462.doc -34- 200535234

Shellsol AB稀釋至50毫升。繼而將溶液經有凹槽渡紙 過濾。 以清潔劑或載劑油（對應0.01至〇·08%之特定化合物濃 度）將1至3毫升之濾液稀釋成1〇毫升，及在1毫米光析 管中對應無添加參考體而測量。 將樣品轉移至10毫升安瓿中，以氣密方式密封且儲存 於50°C水浴中。 結果在表2及3中再現。將所有之實驗相對起始消光樟 準化。 下 存安定性之比較Shellsol AB was diluted to 50 ml. The solution was then filtered through a fluted paper. Dilute 1 to 3 ml of the filtrate to 10 ml with a detergent or carrier oil (corresponding to a specific compound concentration of 0.01 to 0.08%), and measure in a 1 mm photoanalysis tube with no reference body added. The sample was transferred to a 10 ml ampoule, hermetically sealed and stored in a 50 ° C water bath. The results are reproduced in Tables 2 and 3. All experiments were normalized relative to the initial matting camphor. Comparison of storage stability

98462.doc 20053523498462.doc 200535234

在載劑油存在下，比較^^ ^— 情來之mu Λ 5物相較於清潔劑存在之 h形之私卓化湞先如時間函數呈 因此其值無法再現。 〃 μ之㈣劇降低。 卿查化合物_12之儲存安定性，比較得自表ι之清潔 劑及燃枓與潤滑劑添加劑濃縮物。關於此點，製備在 清潔劑或燃料與潤滑劑添加劑濃縮物中且 之化合物10至12含量之溶液，而且在室溫及在二。 疋標準化消光如儲存時間之函數。標準化係相對儲存 開始時之消光值（即，恰在製備適當溶液後）。結果列 於以下。 4 化合物10 : 室溫之清潔劑：在7及14曰之儲存時間後，未谓測 化消光之變化。 40 C之清潔劑：在7及14日之儲存時間後，未伯測到桿 化消光之變化。 室溫之燃料及潤滑劑添加劑濃縮物··在7及14日之儲存時 間後，未偵測到標準化消光之變化。 、 40°C之燃料及潤滑劑添加劑濃縮物··在7及14日之儲存時 間後，未彳貞測到標準化消光之變化。 、 98462.doc -36- 200535234 化合物1 1 : 室溫之清潔劑··在4、〗？？ 12 28、及42曰之儲存時間後，夫 伯測到標準化消光之變化。 40°C之清潔劑··在4、】 12 28、及42日之儲存時間後，夫 偵測到標準化消光之變化。 士室溫之燃料及潤滑劑添加劑濃縮物：在21及28日之儲存 枯間後，未偵測到標準化消光之變化。 士 4〇 C之燃料及潤滑劑添加劑濃縮物：在21及28日之儲存 日守間後’未偵測到標準化消光之變化。 化合物12 : =清潔劑：在4、12、28、及42曰之儲存時間後，實 %上夫福、:目il W. 儲存時間 (日） 消光 (標準化) 0 L 1.00 4 1.00 12 0.99 28 0.97 42 0.99 質上未#、、!i潔劑·在4、12、28、及42日之儲存時間後 、 到標準化^果示於下表： 實 儲存時間 (日） 消光 (標準化) 0 1.00 ~ 4 1.00 12 0.99 28 0.98 42 0.98 98462.doc •37-In the presence of the carrier oil, the comparison ^^ ^ — The h-shaped private chemistry of the Mu Λ 5 in the presence of the detergent is as a function of time, so its value cannot be reproduced. 〃 μ decreases in drama. Check the storage stability of Compound_12 and compare the cleaning agents and flame and lubricant additive concentrates obtained from the table. In this regard, a solution having a content of 10 to 12 of the compound in a detergent or a fuel and lubricant additive concentrate was prepared, and at room temperature and at two.疋 Standardized extinction as a function of storage time. Normalization is the relative extinction value at the beginning of storage (ie, just after the appropriate solution is prepared). The results are listed below. 4 Compound 10: Cleaner at room temperature: after storage time of 7 and 14 days, it is not necessary to measure the change of extinction. 40 C cleaner: After 7 and 14 days of storage, no change in rod extinction was detected. Fuel and lubricant additive concentrates at room temperature ... No change in standardized extinction was detected after 7 and 14 days of storage. Fuel and Lubricant Additive Concentrates at 40 ° C ... After 7 and 14 days of storage, no change in standardized extinction was detected. 98462.doc -36- 200535234 Compound 1 1: Cleaner at room temperature ··· ? After the storage times of 28, 42 and 42, Hubert measured changes in standardized extinction. Detergent at 40 ° C ... After a storage time of 4, 12, 12, and 42 days, the husband detected a change in standardized extinction. Fuel and lubricant additive concentrates at room temperature: No changes in standardized extinction were detected after 21 and 28 days of storage. Fuel and Lubricant Additive Concentrate at 40 ° C: No change in standardized extinction was detected after storage between 21 and 28 days. Compound 12: = Detergent: After storage time of 4, 12, 28, and 42%, the actual% Fufu :: mesh W. Storage time (days) Extinction (standardized) 0 L 1.00 4 1.00 12 0.99 28 0.97 42 0.99 # ,,! I detergent on the quality · After storage time of 4, 12, 28, and 42 days, it is standardized ^ The results are shown in the table below: Actual storage time (days) Extinction (standardization) 0 1.00 ~ 4 1.00 12 0.99 28 0.98 42 0.98 98462.doc • 37-

Claims (1)

200535234 十、申請專利範圍： 1· 一種燃料及潤滑劑添加劑濃縮物，其包含至少/種蒽醌 衍生物作為標識劑。 2·如請求項1之濃縮物，其包含至少一種選自以卞化合物組 成之群組之蒽S昆衍生物： 式I200535234 10. Scope of patent application: 1. A fuel and lubricant additive concentrate containing at least / anthraquinone derivatives as a marking agent. 2. The concentrate as claimed in claim 1, comprising at least one anthracene quinone derivative selected from the group consisting of sulfonium compounds: Formula I (丨）(丨) 式IIFormula II Xm (II) R2 及式IIIXm (II) R2 and formula III Z1、Z2各獨立地為氫、羥基、OR、NHR、或NR2， R1、R2各獨立地為R或COR， X 為氫、氰基、硝基、羥基、OR、胺基、NHR、 R、或 ch(r9)(r10)， 98462.doc 200535234 n、m 各為〇、1、2、3、或4，而且在11或111大於1之 各情形，R或X基團可各為相同或不同， R、R各獨立地為氰基、COOH或COOR， R 為氫、R或NHR， R至R各獨立地為氫、R或NHR 及 R 烷基，其視情況地在 — 至4個氧原子***，環烷基，其視情況 地經一或多個Ci-Cw烷基（其視情況地在醚官 能基中經1至4個氧原子***）取代，飽和雜環 五或/、員基團，其視情況地經一或多個ciec2(r 烷基（其視情況地在醚官能基中經丨至4個氧原 子***）取代，或為C6_CiG_芳基，其視情況地 經一或多個鹵素、氰基、硝基、羥基、胺基、 Ci-Cm-烷基（其視情況地在醚官能基中經i至4 個氧原子***)、Cl_C2。-烷氧基、Ci_c2〇_烷胺 基、或二烷胺基取代，或為具有3至12 個碳原子之雜芳基，其視情況地經一或多個 Ci-C^-烷基（其視情況地在醚官能基中經1至4 個氧原子***)、Cl_C2。-烷氧基、Μ。·烷胺 基、或Cl-C2G-二烷胺基取代，或為C6_Ci『芳基 -C!-C4-烷基，其視情況地在芳基中經一或多個 豳素、氰基、硝基、經基、胺基、Ci_c2〇_烧基 (其視情況地在醚官能基中經丨至4個氧原子插 98462.doc 200535234 入）、Ci-Cso-烷氧基、C〗-C2G-烷胺基、或Ci_c2〇-一烧胺基取代’或為在雜芳基中具有3至12個 石反原子之雜芳基-C1-C4-烧基，前者視情況地經 一或多個Ci-C2〇-烧基（其視情況地在峻官能基 中經1至4個氧原子***）、〇1_〇：2〇-烷氧基、 Ci-C2(r烧胺基、或二烧胺基取代。 3·如請求項2之濃縮物，其中在式η中， Ζ1、Ζ2各獨立地為氫或NHR， R1、R2各獨立地為R， Χ 為氫、氰基或CH(R9)(R10)， n、m 為〇、1、2、3、或4，而且在11或111大於1時，尺 或X基團為相同或不同， R9、R10各獨立地為氰基或C〇〇r， R3 為氫、R或NHR， R4至R7為氫或NHR， R8 為 NHR 及 R 為Cl-Cl5-烷基，其視情況地在醚官能基中經i 至4個氧原子***，環己基，其視情況地經一 或夕個C1-C15-燒基（其視情況地在醚官能基中 經1至4個氧原子***）取代，飽和雜環五或六 員基團，其視情況地經一或多個Ci-Ci5-烷基 (其視情況地在醚官能基中經1至4個氧原子插 入）取代，或為C0-C1G-芳基，其視情況地經一 98462.doc 200535234 &gt;兀娄I丹祝信況地在醚官能基中經 4. 或多個Ci烷基（其視情況地在醚官能基中 經1至4個氧原子***）、0】{】5_烷氧基、Ci_c^_ 烷胺基、或二烷氧基取代，或為具有3 至5個碳原子之雜芳基，其視情況地經一或多 個烷基（其視情況地在醚官能基中經工 至4個氧原子***）、烷氧基、c]_Ci5-烷 胺基、或二烷胺基取代，或為苯基 C〗-C4_k基，其視情況地在苯基中經一或多個 個氧原子***）、Cl_Cl5_烷氧基、Ci_Ci5_烷胺 基、或C^C^-二烷胺基取代，或為在雜芳基中 具有3至5個碳原子之雜芳基_Ci_C4_烷基，前者 視情況地經一或多個Ci_Ci5_烷基(其視情況地 在醚官能基中經1至4個氧原子***）、 烷氧基、烷胺基、或Ci_Ci5_二烷胺基取 代。 一種如請求項 之用途。 1至3中任一項之濃縮物用於添加至礦物油 5 · 一種礦物油 其包含如請求項1至3中任一項之濃縮物。 98462.doc 200535234 七、指定代表圖： (一) 本案指定代表圖為：（無） (二) 本代表圖之元件符號簡單說明: 八、本案若有化學式時，請揭示最能顯示發明特徵的化學式： (無） 98462.docZ1, Z2 are each independently hydrogen, hydroxyl, OR, NHR, or NR2, R1, R2 are each independently R or COR, and X is hydrogen, cyano, nitro, hydroxyl, OR, amine, NHR, R, Or ch (r9) (r10), 98462.doc 200535234 n, m are 0, 1, 2, 3, or 4, and in the case where 11 or 111 is greater than 1, the R or X groups may be the same or Differently, R and R are each independently cyano, COOH or COOR, R is hydrogen, R or NHR, and R to R are each independently hydrogen, R or NHR and R alkyl, which are optionally in the range of-to 4 Oxygen atom insertion, cycloalkyl, optionally substituted by one or more Ci-Cw alkyl (which is optionally inserted in the ether functional group by 1 to 4 oxygen atoms), saturated heterocyclic penta or /, Member group, optionally substituted by one or more ciec2 (r alkyl (which is optionally inserted in the ether functional group by 丨 4 oxygen atoms), or C6_CiG_aryl, which optionally Via one or more halogen, cyano, nitro, hydroxyl, amine, Ci-Cm-alkyl (which is optionally inserted in the ether functional group via i to 4 oxygen atoms), Cl_C2. -Alkoxy , Ci_c20-alkylamino, or dioxane Group is substituted, or a heteroaryl group having 3 to 12 carbon atoms, optionally via one or more Ci-C ^ -alkyl groups (optionally via 1 to 4 oxygen atoms in the ether functional group) Insertion), Cl_C2.-alkoxy, M. alkylamino, or Cl-C2G-dialkylamino substituted, or C6-Ci "aryl-C! -C4-alkyl, optionally in aryl Via one or more halogens, cyano, nitro, mesityl, amine, Ci_c2o_ groups (which are optionally inserted in the ether functional group through 4 to 4 oxygen atoms 98462.doc 200535234) , Ci-Cso-alkoxy, C-C2G-alkylamino, or Ci_c20-monoalkylamino substituted 'or a heteroaryl-C1- with 1 to 12 stone counter atoms in the heteroaryl group C4-carbyl, the former optionally via one or more Ci-C20-carbyl groups (which are optionally inserted via 1 to 4 oxygen atoms in the functional group), 〇1_〇: 2〇-alkane Oxy, Ci-C2 (r-amino, or di-amino). 3. The concentrate as in claim 2, wherein in the formula η, each of Z1 and Z2 is independently hydrogen or NHR, and R1 and R2 are each Is independently R, X is hydrogen, cyano, or CH (R9) (R10), and n and m are 0, 1, 2, 3, Or 4, and when 11 or 111 is greater than 1, the feet or X groups are the same or different, R9 and R10 are each independently cyano or COr, R3 is hydrogen, R or NHR, and R4 to R7 are hydrogen Or NHR, R8 is NHR and R is Cl-Cl5-alkyl, which is optionally inserted in the ether functional group through i to 4 oxygen atoms, and cyclohexyl, which is optionally passed through one or more C1-C15- An alkyl group, which is optionally substituted with 1 to 4 oxygen atoms in the ether functional group, a saturated heterocyclic five or six member group, optionally with one or more Ci-Ci5-alkyl groups (which Optionally substituted with 1 to 4 oxygen atoms in the ether functional group, or a C0-C1G-aryl group, optionally through a 98462.doc 200535234 &gt; Wu Lou I Dan Functional group via 4. or more Ci alkyl groups (which are optionally inserted through 1 to 4 oxygen atoms in the ether functional group), 0] {] 5_alkoxy group, Ci_c ^ _ alkylamino group, or A dialkoxy substitution, or a heteroaryl group having 3 to 5 carbon atoms, optionally via one or more alkyl groups (which are optionally inserted into an ether functional group to 4 oxygen atoms) , Alkoxy, c] _Ci5-alkane Amine group, or dialkylamino group, or phenyl C-C4_k group, which is optionally inserted through one or more oxygen atoms in the phenyl group), Cl_Cl5_alkoxy group, Ci_Ci5_ alkylamino group , Or C ^ C ^ -dialkylamino group, or a heteroaryl_Ci_C4_alkyl group having 3 to 5 carbon atoms in the heteroaryl group, the former optionally through one or more Ci_Ci5_alkyl groups (Which is optionally inserted in the ether functional group by 1 to 4 oxygen atoms), alkoxy, alkylamino, or Ci_Ci5-dialkylamino. A use as a request. The concentrate according to any one of 1 to 3 for adding to mineral oil 5 · A mineral oil comprising the concentrate according to any one of claims 1 to 3. 98462.doc 200535234 7. Designated representative map: (1) The designated representative map of this case is: (none) (II) The component symbols of this representative map are briefly explained: 8. If there is a chemical formula in this case, please disclose the one that can best show the characteristics of the invention. Chemical formula: (none) 98462.doc