TW200514296A - Composite particle and negative electrode material using the same, negative electrode and lithium ion secondary battery - Google Patents

Composite particle and negative electrode material using the same, negative electrode and lithium ion secondary battery

Info

Publication number
TW200514296A
TW200514296A TW093129041A TW93129041A TW200514296A TW 200514296 A TW200514296 A TW 200514296A TW 093129041 A TW093129041 A TW 093129041A TW 93129041 A TW93129041 A TW 93129041A TW 200514296 A TW200514296 A TW 200514296A
Authority
TW
Taiwan
Prior art keywords
negative electrode
secondary battery
lithium ion
ion secondary
electrode material
Prior art date
Application number
TW093129041A
Other languages
Chinese (zh)
Other versions
TWI258883B (en
Inventor
Yasushi Madokoro
Kunihiko Eguchi
Katsuhiro Nagayama
Toshinide Suzuki
Tatsuya Nobusawa
Original Assignee
Jfe Chemical Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from JP2003403079A external-priority patent/JP4785341B2/en
Priority claimed from JP2004053793A external-priority patent/JP3957692B2/en
Application filed by Jfe Chemical Corp filed Critical Jfe Chemical Corp
Publication of TW200514296A publication Critical patent/TW200514296A/en
Application granted granted Critical
Publication of TWI258883B publication Critical patent/TWI258883B/en

Links

Classifications

    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
    • H01M4/131—Electrodes based on mixed oxides or hydroxides, or on mixtures of oxides or hydroxides, e.g. LiCoOx
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/052—Li-accumulators
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
    • H01M4/133—Electrodes based on carbonaceous material, e.g. graphite-intercalation compounds or CFx
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/362—Composites
    • H01M4/364—Composites as mixtures
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/38—Selection of substances as active materials, active masses, active liquids of elements or alloys
    • H01M4/386—Silicon or alloys based on silicon
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2002/00—Crystal-structural characteristics
    • C01P2002/70—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00—Particle morphology
    • C01P2004/60—Particles characterised by their size
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00—Particle morphology
    • C01P2004/60—Particles characterised by their size
    • C01P2004/61—Micrometer sized, i.e. from 1-100 micrometer
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00—Particle morphology
    • C01P2004/60—Particles characterised by their size
    • C01P2004/62—Submicrometer sized, i.e. from 0.1-1 micrometer
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/052—Li-accumulators
    • H01M10/0525—Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M2004/021—Physical characteristics, e.g. porosity, surface area
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/38—Selection of substances as active materials, active masses, active liquids of elements or alloys
    • H01M4/40—Alloys based on alkali metals
    • H01M4/405—Alloys based on lithium
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/58—Selection of substances as active materials, active masses, active liquids of inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy; of polyanionic structures, e.g. phosphates, silicates or borates
    • H01M4/583—Carbonaceous material, e.g. graphite-intercalation compounds or CFx
    • H01M4/587—Carbonaceous material, e.g. graphite-intercalation compounds or CFx for inserting or intercalating light metals
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10—Energy storage using batteries

Abstract

The present invention relates to composite particles comprising a metal alloyable with lithium and a graphite material and carbon material, wherein at least portion of the metal is in contact with at least one material selected from the group consisting of graphite materials and carbon materials and wherein the ratio of void around the metal to total void is 20% or more. There are further provided, utilizing the composite particles, a negative electrode material for lithium ion secondary battery, negative electrode and lithium ion secondary battery. When these composite particles are used in a negative electrode material for lithium ion secondary battery, there can be accomplished three characteristics of large discharge capacity, excellent cycle performance and excellent initial charge discharge efficiency among the properties of lithium ion secondary battery.
TW093129041A 2003-09-26 2004-09-24 Composite particle and negative electrode material using the same, negative electrode and lithium ion secondary battery TWI258883B (en)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
JP2003336422 2003-09-26
JP2003403079A JP4785341B2 (en) 2003-12-02 2003-12-02 Negative electrode material for lithium ion secondary battery, negative electrode for lithium ion secondary battery, and lithium ion secondary battery
JP2004053793A JP3957692B2 (en) 2004-02-27 2004-02-27 Composite graphite particles for negative electrode material of lithium ion secondary battery, negative electrode and lithium ion secondary battery
JP2004083282 2004-03-22

Publications (2)

Publication Number Publication Date
TW200514296A true TW200514296A (en) 2005-04-16
TWI258883B TWI258883B (en) 2006-07-21

Family

ID=34397120

Family Applications (1)

Application Number Title Priority Date Filing Date
TW093129041A TWI258883B (en) 2003-09-26 2004-09-24 Composite particle and negative electrode material using the same, negative electrode and lithium ion secondary battery

Country Status (3)

Country Link
KR (1) KR100702980B1 (en)
TW (1) TWI258883B (en)
WO (1) WO2005031898A1 (en)

Families Citing this family (26)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8709653B2 (en) 2004-03-08 2014-04-29 Samsung Sdi Co., Ltd. Negative active material for a rechargeable lithium battery, a method of preparing the same, and a rechargeable lithium battery comprising the same
KR101328982B1 (en) * 2006-04-17 2013-11-13 삼성에스디아이 주식회사 Anode active material and method of preparing the same
CN100438149C (en) * 2006-06-06 2008-11-26 北京大学 Method for preparing high capacity lithium ion cells cathode material
KR100835883B1 (en) * 2006-07-14 2008-06-09 금호석유화학 주식회사 Negative electrode material hybridizing carbon nanofiber for lithium ion secondary battery
US20080206641A1 (en) * 2007-02-27 2008-08-28 3M Innovative Properties Company Electrode compositions and electrodes made therefrom
US20080206631A1 (en) * 2007-02-27 2008-08-28 3M Innovative Properties Company Electrolytes, electrode compositions and electrochemical cells made therefrom
JP5623686B2 (en) 2007-06-01 2014-11-12 パナソニック株式会社 Composite negative electrode active material and non-aqueous electrolyte secondary battery
KR100981909B1 (en) * 2008-04-15 2010-09-13 애경유화 주식회사 Negative active material for lithium secondary battery, method of preparing same, and lithium secondary battery comprising same
EP2211398B1 (en) * 2009-01-19 2018-01-10 Renata AG Heavy-duty galvanic element
EP2497144A4 (en) 2009-11-03 2014-04-23 Envia Systems Inc High capacity anode materials for lithium ion batteries
CN102893430B (en) * 2010-08-03 2015-11-25 日立麦克赛尔能源株式会社 Non-aqueous secondary batteries negative pole and non-aqueous secondary batteries
US9166222B2 (en) 2010-11-02 2015-10-20 Envia Systems, Inc. Lithium ion batteries with supplemental lithium
US9601228B2 (en) 2011-05-16 2017-03-21 Envia Systems, Inc. Silicon oxide based high capacity anode materials for lithium ion batteries
KR101920806B1 (en) * 2011-08-22 2018-11-21 코넥스 시스템스 가부시키가이샤 Composite active material for lithium secondary batteries and method for producing same
WO2013099278A1 (en) 2011-12-28 2013-07-04 パナソニック株式会社 Negative electrode for nonaqueous electrolyte secondary batteries, and nonaqueous electrolyte secondary battery using same
US9139441B2 (en) 2012-01-19 2015-09-22 Envia Systems, Inc. Porous silicon based anode material formed using metal reduction
CN102637857A (en) * 2012-04-23 2012-08-15 中国海洋大学 Preparation method of large-aperture foamy graphite composite electrode
US10553871B2 (en) 2012-05-04 2020-02-04 Zenlabs Energy, Inc. Battery cell engineering and design to reach high energy
US9780358B2 (en) 2012-05-04 2017-10-03 Zenlabs Energy, Inc. Battery designs with high capacity anode materials and cathode materials
CN102969509B (en) * 2012-10-15 2016-03-23 宁德新能源科技有限公司 A kind of preparation method of lithium ion battery silicon-carbon composite material
CN102891297B (en) * 2012-11-10 2015-05-13 江西正拓新能源科技股份有限公司 Silicon-carbon composite material for lithium ion battery and preparation method thereof
EP3032620B1 (en) * 2013-08-05 2020-01-22 Showa Denko K.K. Negative electrode material for lithium ion batteries and use thereof
CN105474437A (en) * 2013-08-05 2016-04-06 昭和电工株式会社 Method for producing composite, and lithium ion battery negative electrode material
US11476494B2 (en) 2013-08-16 2022-10-18 Zenlabs Energy, Inc. Lithium ion batteries with high capacity anode active material and good cycling for consumer electronics
US20200044241A1 (en) * 2017-02-07 2020-02-06 Wacker Chemie Ag Core-shell composite particles for anode materials of lithium ion batteries
US11094925B2 (en) 2017-12-22 2021-08-17 Zenlabs Energy, Inc. Electrodes with silicon oxide active materials for lithium ion cells achieving high capacity, high energy density and long cycle life performance

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP3369589B2 (en) * 1992-04-07 2003-01-20 三菱化学株式会社 Electrode material
JP3897709B2 (en) * 2002-02-07 2007-03-28 日立マクセル株式会社 Electrode material, method for producing the same, negative electrode for non-aqueous secondary battery, and non-aqueous secondary battery

Also Published As

Publication number Publication date
KR20060024325A (en) 2006-03-16
TWI258883B (en) 2006-07-21
WO2005031898A1 (en) 2005-04-07
KR100702980B1 (en) 2007-04-06

Similar Documents

Publication Publication Date Title
TW200514296A (en) Composite particle and negative electrode material using the same, negative electrode and lithium ion secondary battery
WO2004049473A3 (en) Electrode material comprising silicon and/or tin particles and production method and use thereof
WO2003096449A1 (en) Nonaqueous electrolyte secondary cell
CA2341693A1 (en) Nonaqueous electrolyte secondary battery, manufacturing method thereof, and carbon material composition
TWI256158B (en) Lithium secondary battery
EP1361194A4 (en) Artificial graphite particle and method for producing the same, nonaqueous electrolyte secondary battery negative electrode and method for producing the same, and lithium secondary battery
EP1148563A3 (en) Lithium ion secondary battery
EP1644999A4 (en) Anode material for lithium secondary cell with high capacity
TW366600B (en) Powdery material, electrode member, method for manufacturing same and secondary cell
KR950010159A (en) Lithium secondary battery
EP1052716A3 (en) Positive electrode active material, positive electrode active material composition and lithium ion secondary battery
EP1184918A3 (en) Rechargeable lithium ion battery
EP2237347A3 (en) Positive electrode material, its manufacturing method and lithium batteries
EP1179869A3 (en) Non-aqueous electrolyte secondary battery and positive electrode for the same
TW200608622A (en) Anode for lithium ion cell
CA2423043A1 (en) Nonaqueous lithium secondary battery
EP1363341A3 (en) Conductive silicon composite, preparation thereof, and negative electrode material for non-aqueous electrolyte secondary cell
TW200705737A (en) New system of lithium ion battery containing material with high irreversible capacity
WO2009002053A3 (en) Anode material of excellent conductivity and high power secondary battery employed with the same
TW200729586A (en) Lithium secondary cell with high charge and discharge rate capability and low impedance growth
TW200603468A (en) Negative electrode material for nonacqueous electrolyte secondary battery of high input/output current, method for producing the same and battery employing negative electrode material
TW200520290A (en) Non-aqueous electrolyte secondary battery-use cathode material, production method therefore, non-aqueous electrolyte secondary battery-use cathode and non-aqueous electrolyte secondary battery using the cathode material
WO2003058145A1 (en) Lithium-ion secondary battery
CA2175297A1 (en) Process for preparing carbonaceous material for negative electrode of cell and non-aqueous electrolyte secondary cell using same
WO2002082567A1 (en) Negative electrode for non-aqueous electrolyte secondary cell and non-aqueous electrolyte secondary cell using the negative electrode