TR200201767T2 - Catalyst composition, polymerization method and polymer obtained therefrom - Google Patents
Catalyst composition, polymerization method and polymer obtained therefromInfo
- Publication number
- TR200201767T2 TR200201767T2 TR2002/01767T TR200201767T TR200201767T2 TR 200201767 T2 TR200201767 T2 TR 200201767T2 TR 2002/01767 T TR2002/01767 T TR 2002/01767T TR 200201767 T TR200201767 T TR 200201767T TR 200201767 T2 TR200201767 T2 TR 200201767T2
- Authority
- TR
- Turkey
- Prior art keywords
- metal compound
- polymerization method
- catalyst composition
- polymer obtained
- obtained therefrom
- Prior art date
Links
Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F10/02—Ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/08—Copolymers of ethene
- C08L23/0807—Copolymers of ethene with unsaturated hydrocarbons only containing more than three carbon atoms
- C08L23/0815—Copolymers of ethene with aliphatic 1-olefins
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/16—Elastomeric ethene-propene or ethene-propene-diene copolymers, e.g. EPR and EPDM rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2314/00—Polymer mixtures characterised by way of preparation
- C08L2314/06—Metallocene or single site catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
Abstract
Bu bulus, polimerizasyon yöntemlerinde yararli olan, bir Grup 15 içeren metal bilesigi ihtiva eden katalizör terkipleri, Grup 15 içeren metal bilesigini ve tercihan bir hacimli ligand metalosen katalizöründen olusan bir ikinci metal bilesigi ihtiva eden karisik katalizör terkipleri, bunlari içeren tasiyicili ve tasiyicisiz katalizör sistemleri, ve bunlarin kullanan, olefinleri polimerize etmeye mahsus bir yöntem saglar. Bu bulus ayrica, yeni bir poliolefin, genel olarak polietilen, özellikle çok modlu bir polimer ve daha spesifik olarak bir bimodal polimer, ve bunun film, kaliplama ve boru gibi çesitli nihai kullanim uygulamalarinda kullanimini açiklar.This invention is useful in polymerization methods, catalyst compositions containing a Group 15 containing metal compound, a metal compound containing Group 15, and a second metal compound consisting preferably of a bulky ligand metallocene catalyst, carrier and non-carrier catalyst systems containing them, and using them provides a method for polymerizing olefins. This invention also discloses a new polyolefin, generally polyethylene, especially a multimodal polymer, and more specifically a bimodal polymer, and its use in a variety of end use applications such as film, molding and tubing.
Applications Claiming Priority (6)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US09/425,387 US6274684B1 (en) | 1999-10-22 | 1999-10-22 | Catalyst composition, method of polymerization, and polymer therefrom |
US09/435,409 US6300439B1 (en) | 1999-11-08 | 1999-11-08 | Group 15 containing transition metal catalyst compounds, catalyst systems and their use in a polymerization process |
US09/442,813 US6417304B1 (en) | 1999-11-18 | 1999-11-18 | Method of polymerization and polymer produced therefrom |
US09/443,551 US6265505B1 (en) | 1999-11-18 | 1999-11-18 | Catalyst system and its use in a polymerization process |
US09/451,792 US6399722B1 (en) | 1999-12-01 | 1999-12-01 | Solution feed of multiple catalysts |
US09/460,179 US6380328B1 (en) | 1999-12-10 | 1999-12-10 | Catalyst systems and their use in a polymerization process |
Publications (1)
Publication Number | Publication Date |
---|---|
TR200201767T2 true TR200201767T2 (en) | 2002-11-21 |
Family
ID=27559972
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
TR2002/01767T TR200201767T2 (en) | 1999-10-22 | 2000-05-15 | Catalyst composition, polymerization method and polymer obtained therefrom |
Country Status (18)
Country | Link |
---|---|
EP (1) | EP1226190A1 (en) |
JP (1) | JP4117822B2 (en) |
KR (1) | KR100553288B1 (en) |
CN (1) | CN100484969C (en) |
AR (1) | AR023991A1 (en) |
AU (1) | AU767697B2 (en) |
BR (1) | BR0015235A (en) |
CA (1) | CA2388137A1 (en) |
CZ (1) | CZ20021402A3 (en) |
IL (1) | IL149262A0 (en) |
MX (1) | MXPA02003999A (en) |
MY (1) | MY129717A (en) |
NO (1) | NO20021862L (en) |
PL (1) | PL355103A1 (en) |
SA (1) | SA00210262B1 (en) |
SK (1) | SK5502002A3 (en) |
TR (1) | TR200201767T2 (en) |
WO (1) | WO2001030861A1 (en) |
Families Citing this family (66)
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US6281306B1 (en) * | 1999-12-16 | 2001-08-28 | Univation Technologies, Llc | Method of polymerization |
CN1271089C (en) * | 2000-12-18 | 2006-08-23 | 尤尼威蒂恩技术有限责任公司 | Start-up procedure for multiple catalyst polymerization systems |
KR100844062B1 (en) | 2001-02-21 | 2008-07-07 | 미쓰이 가가쿠 가부시키가이샤 | Catalyst for olefin polymerizaion and method for producing olefin polymers using the catalyst |
US6875828B2 (en) * | 2002-09-04 | 2005-04-05 | Univation Technologies, Llc | Bimodal polyolefin production process and films therefrom |
US7094848B2 (en) | 2003-05-13 | 2006-08-22 | Exxonmobil Chemical Patents Inc. | Olefin polymerization catalyst system |
US7045583B2 (en) | 2003-12-22 | 2006-05-16 | Exxon Mobil Chemical Patents Inc. | Olefin polymerization catalyst system |
US7858706B2 (en) * | 2004-03-17 | 2010-12-28 | Dow Global Technologies Inc. | Catalyst composition comprising shuttling agent for ethylene multi-block copolymer formation |
AU2005224257B2 (en) * | 2004-03-17 | 2010-08-19 | Dow Global Technologies Inc. | Catalyst composition comprising shuttling agent for higher olefin multi-block copolymer formation |
US7193017B2 (en) * | 2004-08-13 | 2007-03-20 | Univation Technologies, Llc | High strength biomodal polyethylene compositions |
EP1805226A1 (en) | 2004-10-29 | 2007-07-11 | Exxonmobil Chemical Patents Inc. | Catalyst compound containing divalent tridentate ligand |
US7321015B2 (en) * | 2004-12-07 | 2008-01-22 | Nova Chemicals (International) S.A. | Adjusting polymer characteristics through process control |
US7323523B2 (en) * | 2004-12-07 | 2008-01-29 | Nova Chemicals (International) S.A. | Adjusting polymer characteristics through process control |
EP1861438B1 (en) * | 2005-03-17 | 2015-03-04 | Dow Global Technologies LLC | Catalyst composition comprising shuttling agent for regio-irregular multi-block copolymer formation |
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TW200936619A (en) | 2007-11-15 | 2009-09-01 | Univation Tech Llc | Polymerization catalysts, methods of making, methods of using, and polyolefin products made therefrom |
ES2407121T3 (en) | 2007-12-18 | 2013-06-11 | Univation Technologies, Llc | Method to control the activity of a bimodal catalyst during a polymerization |
EP2204410A1 (en) | 2008-12-31 | 2010-07-07 | Borealis AG | Article coated with a composition comprising polyethylene prepared with a single site catalyst |
CN102712701A (en) | 2009-12-07 | 2012-10-03 | 尤尼威蒂恩技术有限责任公司 | Methods for reducing static charge of a catalyst and methods for using the catalyst to produce polyolefins |
EP2536767B1 (en) | 2010-02-18 | 2015-05-06 | Univation Technologies, LLC | Methods for operating a polymerization reactor |
KR20130026531A (en) | 2010-02-22 | 2013-03-13 | 유니베이션 테크놀로지즈, 엘엘씨 | Catalyst systems and methods for using same to produce polyolefin products |
BR112012025925B1 (en) | 2010-04-13 | 2020-03-17 | Univation Technologies, Llc | POLYMERIC MIXTURE AND FILM |
EP2593217B1 (en) | 2010-07-16 | 2014-07-02 | Univation Technologies, LLC | Systems and methods for measuring particle accumulation on reactor surfaces |
WO2012009215A1 (en) | 2010-07-16 | 2012-01-19 | Univation Technologies, Llc | Systems and methods for measuring static charge on particulates |
WO2012015898A1 (en) | 2010-07-28 | 2012-02-02 | Univation Technologies, Llc | Systems and methods for measuring velocity of a particle/fluid mixture |
RU2587080C2 (en) | 2010-11-30 | 2016-06-10 | Юнивейшн Текнолоджиз, Ллк | Methods for polymerisation of olefins using extracted metal carboxylates |
BR112013012545B1 (en) | 2010-11-30 | 2020-04-14 | Univation Tech Llc | catalyst composition, production process of a catalyst composition and polymerization process |
CN103298842B (en) | 2010-12-17 | 2016-08-31 | 尤尼威蒂恩技术有限责任公司 | System and the method for hydrocarbon is reclaimed from polyolefin purging gaseous product |
ES2640318T3 (en) | 2010-12-22 | 2017-11-02 | Univation Technologies, Llc | Additive for olefin polymerization processes |
US9637567B2 (en) | 2011-05-13 | 2017-05-02 | Univation Technologies, Llc | Spray-dried catalyst compositions and polymerization processes employing the same |
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CN107266402A (en) | 2013-06-05 | 2017-10-20 | 尤尼威蒂恩技术有限责任公司 | Protect phenolic group |
US9156970B2 (en) | 2013-09-05 | 2015-10-13 | Chevron Phillips Chemical Company Lp | Higher density polyolefins with improved stress crack resistance |
US9809667B2 (en) | 2014-02-11 | 2017-11-07 | Univation Technologies, Llc | Producing polyolefin products |
BR112016022780B1 (en) | 2014-04-02 | 2021-08-17 | Univation Technologies, Llc | CONTINUITY COMPOSITION |
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BR112017003170B1 (en) | 2014-08-19 | 2022-02-15 | Univation Technologies, Llc | METHOD FOR MAKING A FLUORINED ALUMINA SILICA CATALYST SUPPORT AND FLUORORATED ALUMINA SILICA CATALYST SYSTEM |
CA2958435C (en) | 2014-08-19 | 2023-06-13 | Univation Technologies, Llc | Fluorinated catalyst supports and catalyst systems |
SG11201703851UA (en) | 2014-11-25 | 2017-06-29 | Univation Tech Llc | Methods of controlling polyolefin melt index |
SG11201705576YA (en) | 2015-01-21 | 2017-08-30 | Univation Tech Llc | Methods for gel reduction in polyolefins |
WO2016118599A1 (en) | 2015-01-21 | 2016-07-28 | Univation Technologies, Llc | Methods for controlling polymer chain scission |
SG11201707037TA (en) | 2015-03-10 | 2017-09-28 | Univation Tech Llc | Spray dried catalyst compositions, methods for preparation and use in olefin polymerization processes |
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CN110114374A (en) * | 2016-11-03 | 2019-08-09 | 埃克森美孚化学专利公司 | Multicomponent catalyst composition supply system and the method for preparing polymer |
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US11274196B2 (en) | 2017-08-04 | 2022-03-15 | Exxonmobil Chemical Patents Inc. | Polyethylene compositions and films prepared therefrom |
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KR101904496B1 (en) * | 2017-12-13 | 2018-11-28 | 대림산업 주식회사 | Multimodal polyolefin resin and article prepared with the same |
US11041031B2 (en) | 2018-04-26 | 2021-06-22 | Exxonmobil Chemical Patents Inc. | Non-coordinating anion type activators containing cation having branched alkyl groups |
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WO2021119089A1 (en) | 2019-12-11 | 2021-06-17 | Exxonmobil Chemical Patents Inc. | Processes for introduction of liquid activators in olefin polymerization reactions |
WO2021126523A1 (en) | 2019-12-19 | 2021-06-24 | Exxonmobil Chemical Patents Inc. | Production of impact copolymer polypropylene using metallocene and ziegler-natta catalysts in parallel reactors |
US20230141606A1 (en) | 2020-03-25 | 2023-05-11 | Exxonmobil Chemical Patents Inc. | Alkylation of Transition Metal Coordination Catalyst Complexes |
WO2021262838A1 (en) | 2020-06-26 | 2021-12-30 | Exxonmobil Chemical Patents Inc. | Copolymers composed of ethylene, a-olefin, non-conjugated diene, and substituted styrene and articles therefrom |
WO2021262842A1 (en) | 2020-06-26 | 2021-12-30 | Exxonmobil Chemical Patents Inc. | COPOLYMERS OF ETHYLENE, α-OLEFIN, NON-CONJUGATED DIENE, AND ARYL-SUBSTITUTED CYCLOALKENE, METHODS TO PRODUCE, BLENDS, AND ARTICLES THEREFROM |
EP4192888A1 (en) | 2020-08-10 | 2023-06-14 | ExxonMobil Chemical Patents Inc. | Methods for delivery of non-aromatic solutions to polymerization reactors |
Family Cites Families (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1220672A (en) * | 1997-02-07 | 1999-06-23 | 三井化学株式会社 | Olefin polymerization catalyst and process for production of olefin polymers |
US6451938B1 (en) * | 1997-02-25 | 2002-09-17 | Exxon Mobil Chemical Patents Inc. | Polymerization catalyst system comprising heterocyclic fused cyclopentadienide ligands |
TW420693B (en) * | 1997-04-25 | 2001-02-01 | Mitsui Chemicals Inc | Olefin polymerization catalysts, transition metal compounds, and <alpha>-olefin/conjugated diene copolymers |
JPH10330412A (en) * | 1997-05-27 | 1998-12-15 | Mitsui Chem Inc | Catalyst for olefin polymerization and polymerization of the same |
US6103657A (en) * | 1997-07-02 | 2000-08-15 | Union Carbide Chemicals & Plastics Technology Corporation | Catalyst for the production of olefin polymers |
ID27209A (en) * | 1998-03-12 | 2001-03-08 | Bp Chem Int Ltd | POLYMERIZATION CATALYSTS |
WO1999046303A1 (en) * | 1998-03-12 | 1999-09-16 | Bp Chemicals Limited | Polymerisation catalysts |
-
2000
- 2000-05-15 PL PL00355103A patent/PL355103A1/en not_active Application Discontinuation
- 2000-05-15 BR BR0015235-8A patent/BR0015235A/en not_active Application Discontinuation
- 2000-05-15 JP JP2001533857A patent/JP4117822B2/en not_active Expired - Fee Related
- 2000-05-15 CA CA002388137A patent/CA2388137A1/en not_active Abandoned
- 2000-05-15 IL IL14926200A patent/IL149262A0/en unknown
- 2000-05-15 WO PCT/US2000/013313 patent/WO2001030861A1/en not_active Application Discontinuation
- 2000-05-15 EP EP00928987A patent/EP1226190A1/en not_active Withdrawn
- 2000-05-15 CN CNB008164428A patent/CN100484969C/en not_active Expired - Fee Related
- 2000-05-15 MX MXPA02003999A patent/MXPA02003999A/en active IP Right Grant
- 2000-05-15 MY MYPI20002131A patent/MY129717A/en unknown
- 2000-05-15 KR KR1020027005182A patent/KR100553288B1/en not_active IP Right Cessation
- 2000-05-15 SK SK550-2002A patent/SK5502002A3/en unknown
- 2000-05-15 CZ CZ20021402A patent/CZ20021402A3/en unknown
- 2000-05-15 TR TR2002/01767T patent/TR200201767T2/en unknown
- 2000-05-15 AU AU47139/00A patent/AU767697B2/en not_active Ceased
- 2000-05-15 AR ARP000102335A patent/AR023991A1/en unknown
- 2000-07-25 SA SA00210262A patent/SA00210262B1/en unknown
-
2002
- 2002-04-19 NO NO20021862A patent/NO20021862L/en unknown
Also Published As
Publication number | Publication date |
---|---|
SA00210262B1 (en) | 2006-06-04 |
NO20021862L (en) | 2002-06-24 |
AR023991A1 (en) | 2002-09-04 |
IL149262A0 (en) | 2002-11-10 |
CZ20021402A3 (en) | 2002-11-13 |
AU4713900A (en) | 2001-05-08 |
JP2003513114A (en) | 2003-04-08 |
SK5502002A3 (en) | 2002-12-03 |
AU767697B2 (en) | 2003-11-20 |
WO2001030861A1 (en) | 2001-05-03 |
EP1226190A1 (en) | 2002-07-31 |
NO20021862D0 (en) | 2002-04-19 |
MY129717A (en) | 2007-04-30 |
PL355103A1 (en) | 2004-04-05 |
MXPA02003999A (en) | 2002-10-23 |
CA2388137A1 (en) | 2001-05-03 |
BR0015235A (en) | 2002-12-31 |
KR100553288B1 (en) | 2006-02-22 |
CN1402739A (en) | 2003-03-12 |
KR20020060956A (en) | 2002-07-19 |
CN100484969C (en) | 2009-05-06 |
JP4117822B2 (en) | 2008-07-16 |
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