BR0015235A - Catalyst compositions, polymerization methods, and polymers thereof - Google Patents

Catalyst compositions, polymerization methods, and polymers thereof

Info

Publication number
BR0015235A
BR0015235A BR0015235-8A BR0015235A BR0015235A BR 0015235 A BR0015235 A BR 0015235A BR 0015235 A BR0015235 A BR 0015235A BR 0015235 A BR0015235 A BR 0015235A
Authority
BR
Brazil
Prior art keywords
catalyst compositions
polymers
metal compound
polymerization methods
catalyst
Prior art date
Application number
BR0015235-8A
Other languages
Portuguese (pt)
Inventor
David H Mcconville
Donald R Loveday
Matthew W Holtcamp
John F Szul
Kersten Anne Erickson
Simon Mawson
Tae Hoon Kwack
Frederick J Karol
David James Schreck
Mark G Goode
Paul T Daniell
Matthew G Mckee
Clark C Williams
Original Assignee
Univation Tech Llc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US09/425,387 external-priority patent/US6274684B1/en
Priority claimed from US09/435,409 external-priority patent/US6300439B1/en
Priority claimed from US09/442,813 external-priority patent/US6417304B1/en
Priority claimed from US09/443,551 external-priority patent/US6265505B1/en
Priority claimed from US09/451,792 external-priority patent/US6399722B1/en
Priority claimed from US09/460,179 external-priority patent/US6380328B1/en
Application filed by Univation Tech Llc filed Critical Univation Tech Llc
Publication of BR0015235A publication Critical patent/BR0015235A/en

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/02Ethene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04Homopolymers or copolymers of ethene
    • C08L23/08Copolymers of ethene
    • C08L23/0807Copolymers of ethene with unsaturated hydrocarbons only containing more than three carbon atoms
    • C08L23/0815Copolymers of ethene with aliphatic 1-olefins
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/16Elastomeric ethene-propene or ethene-propene-diene copolymers, e.g. EPR and EPDM rubbers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659Component covered by group C08F4/64 containing a transition metal-carbon bond
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65916Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/02Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2314/00Polymer mixtures characterised by way of preparation
    • C08L2314/06Metallocene or single site catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Manufacture Of Macromolecular Shaped Articles (AREA)

Abstract

"COMPOSIçõES CATALISDORAS, MéTODOS DE POLIMERIZAçãO, E POLìMEROS DISSO". A presente invenção fornece composições catalisadoras úteis em processos de polimerização, incluindo composto de metal contendo Grupo 15, composições de catalisadores mistas incluindo o composto de metal contendo Grupo 15 e um segundo composto de metal o qual é preferivelmente um catalisador de metaloceno de ligante volumoso, sistemas de catalisadores fornecidos e não fornecidos disso, e um processo para polimerizar olefina(s) utilizando-os A invenção também revela uma nova poliolefina, geralmente polietileno, particularmente um polímero multimodal e mais especificamente, um polímero bimodal, e seu uso em várias aplicações de uso final tais como película, molde e tubo."CATALYST COMPOSITIONS, POLYMERIZATION METHODS, AND POLYMERS OF THIS". The present invention provides catalyst compositions useful in polymerization processes, including Group 15 containing metal compound, mixed catalyst compositions including Group 15 containing metal compound and a second metal compound which is preferably a bulky binder metallocene catalyst, catalyst systems supplied and not supplied thereto, and a process for polymerizing olefin (s) using them The invention also discloses a new polyolefin, generally polyethylene, particularly a multimodal polymer and more specifically, a bimodal polymer, and its use in various applications of end use such as film, mold and tube.

BR0015235-8A 1999-10-22 2000-05-15 Catalyst compositions, polymerization methods, and polymers thereof BR0015235A (en)

Applications Claiming Priority (7)

Application Number Priority Date Filing Date Title
US09/425,387 US6274684B1 (en) 1999-10-22 1999-10-22 Catalyst composition, method of polymerization, and polymer therefrom
US09/435,409 US6300439B1 (en) 1999-11-08 1999-11-08 Group 15 containing transition metal catalyst compounds, catalyst systems and their use in a polymerization process
US09/442,813 US6417304B1 (en) 1999-11-18 1999-11-18 Method of polymerization and polymer produced therefrom
US09/443,551 US6265505B1 (en) 1999-11-18 1999-11-18 Catalyst system and its use in a polymerization process
US09/451,792 US6399722B1 (en) 1999-12-01 1999-12-01 Solution feed of multiple catalysts
US09/460,179 US6380328B1 (en) 1999-12-10 1999-12-10 Catalyst systems and their use in a polymerization process
PCT/US2000/013313 WO2001030861A1 (en) 1999-10-22 2000-05-15 Catalyst compositions, methods of polymerization, and polymers therefrom

Publications (1)

Publication Number Publication Date
BR0015235A true BR0015235A (en) 2002-12-31

Family

ID=27559972

Family Applications (1)

Application Number Title Priority Date Filing Date
BR0015235-8A BR0015235A (en) 1999-10-22 2000-05-15 Catalyst compositions, polymerization methods, and polymers thereof

Country Status (18)

Country Link
EP (1) EP1226190A1 (en)
JP (1) JP4117822B2 (en)
KR (1) KR100553288B1 (en)
CN (1) CN100484969C (en)
AR (1) AR023991A1 (en)
AU (1) AU767697B2 (en)
BR (1) BR0015235A (en)
CA (1) CA2388137A1 (en)
CZ (1) CZ20021402A3 (en)
IL (1) IL149262A0 (en)
MX (1) MXPA02003999A (en)
MY (1) MY129717A (en)
NO (1) NO20021862L (en)
PL (1) PL355103A1 (en)
SA (1) SA00210262B1 (en)
SK (1) SK5502002A3 (en)
TR (1) TR200201767T2 (en)
WO (1) WO2001030861A1 (en)

Families Citing this family (66)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6281306B1 (en) * 1999-12-16 2001-08-28 Univation Technologies, Llc Method of polymerization
CN1271089C (en) * 2000-12-18 2006-08-23 尤尼威蒂恩技术有限责任公司 Start-up procedure for multiple catalyst polymerization systems
KR100844062B1 (en) 2001-02-21 2008-07-07 미쓰이 가가쿠 가부시키가이샤 Catalyst for olefin polymerizaion and method for producing olefin polymers using the catalyst
US6875828B2 (en) * 2002-09-04 2005-04-05 Univation Technologies, Llc Bimodal polyolefin production process and films therefrom
US7094848B2 (en) 2003-05-13 2006-08-22 Exxonmobil Chemical Patents Inc. Olefin polymerization catalyst system
US7045583B2 (en) 2003-12-22 2006-05-16 Exxon Mobil Chemical Patents Inc. Olefin polymerization catalyst system
US7858706B2 (en) * 2004-03-17 2010-12-28 Dow Global Technologies Inc. Catalyst composition comprising shuttling agent for ethylene multi-block copolymer formation
AU2005224257B2 (en) * 2004-03-17 2010-08-19 Dow Global Technologies Inc. Catalyst composition comprising shuttling agent for higher olefin multi-block copolymer formation
US7193017B2 (en) * 2004-08-13 2007-03-20 Univation Technologies, Llc High strength biomodal polyethylene compositions
EP1805226A1 (en) 2004-10-29 2007-07-11 Exxonmobil Chemical Patents Inc. Catalyst compound containing divalent tridentate ligand
US7321015B2 (en) * 2004-12-07 2008-01-22 Nova Chemicals (International) S.A. Adjusting polymer characteristics through process control
US7323523B2 (en) * 2004-12-07 2008-01-29 Nova Chemicals (International) S.A. Adjusting polymer characteristics through process control
EP1861438B1 (en) * 2005-03-17 2015-03-04 Dow Global Technologies LLC Catalyst composition comprising shuttling agent for regio-irregular multi-block copolymer formation
US7247594B2 (en) 2005-04-13 2007-07-24 Chevron Phillips Chemical Co. Lp Catalysts for olefin polymerization
EP2081968B1 (en) 2006-11-14 2015-09-16 Univation Technologies, LLC Catalyst systems and polymerization processes
TW200936619A (en) 2007-11-15 2009-09-01 Univation Tech Llc Polymerization catalysts, methods of making, methods of using, and polyolefin products made therefrom
ES2407121T3 (en) 2007-12-18 2013-06-11 Univation Technologies, Llc Method to control the activity of a bimodal catalyst during a polymerization
EP2204410A1 (en) 2008-12-31 2010-07-07 Borealis AG Article coated with a composition comprising polyethylene prepared with a single site catalyst
CN102712701A (en) 2009-12-07 2012-10-03 尤尼威蒂恩技术有限责任公司 Methods for reducing static charge of a catalyst and methods for using the catalyst to produce polyolefins
EP2536767B1 (en) 2010-02-18 2015-05-06 Univation Technologies, LLC Methods for operating a polymerization reactor
KR20130026531A (en) 2010-02-22 2013-03-13 유니베이션 테크놀로지즈, 엘엘씨 Catalyst systems and methods for using same to produce polyolefin products
BR112012025925B1 (en) 2010-04-13 2020-03-17 Univation Technologies, Llc POLYMERIC MIXTURE AND FILM
EP2593217B1 (en) 2010-07-16 2014-07-02 Univation Technologies, LLC Systems and methods for measuring particle accumulation on reactor surfaces
WO2012009215A1 (en) 2010-07-16 2012-01-19 Univation Technologies, Llc Systems and methods for measuring static charge on particulates
WO2012015898A1 (en) 2010-07-28 2012-02-02 Univation Technologies, Llc Systems and methods for measuring velocity of a particle/fluid mixture
RU2587080C2 (en) 2010-11-30 2016-06-10 Юнивейшн Текнолоджиз, Ллк Methods for polymerisation of olefins using extracted metal carboxylates
BR112013012545B1 (en) 2010-11-30 2020-04-14 Univation Tech Llc catalyst composition, production process of a catalyst composition and polymerization process
CN103298842B (en) 2010-12-17 2016-08-31 尤尼威蒂恩技术有限责任公司 System and the method for hydrocarbon is reclaimed from polyolefin purging gaseous product
ES2640318T3 (en) 2010-12-22 2017-11-02 Univation Technologies, Llc Additive for olefin polymerization processes
US9637567B2 (en) 2011-05-13 2017-05-02 Univation Technologies, Llc Spray-dried catalyst compositions and polymerization processes employing the same
WO2013028283A1 (en) 2011-08-19 2013-02-28 Univation Technologies, Llc Catalyst systems and methods for using same to produce polyolefin products
BR112014010906B1 (en) 2011-11-08 2020-12-01 Univation Technologies, Llc method for producing a polyolefin
CN103917292B (en) 2011-11-08 2016-11-23 尤尼威蒂恩技术有限责任公司 The method preparing catalyst system
ES2918582T3 (en) 2012-12-28 2022-07-19 Univation Tech Llc Supported catalyst with improved fluidity
RU2656343C2 (en) 2013-01-30 2018-06-05 ЮНИВЕЙШН ТЕКНОЛОДЖИЗ, ЭлЭлСи Processes for making catalyst compositions having improved flowability
WO2014123598A1 (en) 2013-02-07 2014-08-14 Univation Technologies, Llc Preparation of polyolefin
US9718900B2 (en) 2013-03-15 2017-08-01 Univation Technologies, Llc Ligands for catalysts
EP2970524B1 (en) 2013-03-15 2018-03-07 Univation Technologies, LLC Tridentate nitrogen based ligands for olefin polymerisation catalysts
KR101464434B1 (en) * 2013-05-20 2014-11-21 삼성토탈 주식회사 A process for preparation of polyolefin comprising activation of a catalyst and prepolymerization
CN107266402A (en) 2013-06-05 2017-10-20 尤尼威蒂恩技术有限责任公司 Protect phenolic group
US9156970B2 (en) 2013-09-05 2015-10-13 Chevron Phillips Chemical Company Lp Higher density polyolefins with improved stress crack resistance
US9809667B2 (en) 2014-02-11 2017-11-07 Univation Technologies, Llc Producing polyolefin products
BR112016022780B1 (en) 2014-04-02 2021-08-17 Univation Technologies, Llc CONTINUITY COMPOSITION
EP3183059A1 (en) 2014-08-19 2017-06-28 Univation Technologies, LLC Fluorinated catalyst supports and catalyst systems
BR112017003170B1 (en) 2014-08-19 2022-02-15 Univation Technologies, Llc METHOD FOR MAKING A FLUORINED ALUMINA SILICA CATALYST SUPPORT AND FLUORORATED ALUMINA SILICA CATALYST SYSTEM
CA2958435C (en) 2014-08-19 2023-06-13 Univation Technologies, Llc Fluorinated catalyst supports and catalyst systems
SG11201703851UA (en) 2014-11-25 2017-06-29 Univation Tech Llc Methods of controlling polyolefin melt index
SG11201705576YA (en) 2015-01-21 2017-08-30 Univation Tech Llc Methods for gel reduction in polyolefins
WO2016118599A1 (en) 2015-01-21 2016-07-28 Univation Technologies, Llc Methods for controlling polymer chain scission
SG11201707037TA (en) 2015-03-10 2017-09-28 Univation Tech Llc Spray dried catalyst compositions, methods for preparation and use in olefin polymerization processes
ES2719407T3 (en) 2015-04-08 2019-07-10 Univation Tech Llc Transitions in closed reactor between metallocene catalysts
WO2016171810A1 (en) 2015-04-20 2016-10-27 Exxonmobil Chemical Patents Inc. Supported catalyst systems and processes for use thereof
SG11201708626SA (en) 2015-04-27 2017-11-29 Univation Tech Llc Supported catalyst compositions having improved flow properties and preparation thereof
CN110114374A (en) * 2016-11-03 2019-08-09 埃克森美孚化学专利公司 Multicomponent catalyst composition supply system and the method for preparing polymer
WO2018151903A1 (en) 2017-02-20 2018-08-23 Exxonmobil Chemical Patents Inc. Supported catalyst systems and processes for use thereof
US11274196B2 (en) 2017-08-04 2022-03-15 Exxonmobil Chemical Patents Inc. Polyethylene compositions and films prepared therefrom
US20210147658A1 (en) * 2017-09-11 2021-05-20 Dow Global Technologies Llc Polyethylene composition
KR101904496B1 (en) * 2017-12-13 2018-11-28 대림산업 주식회사 Multimodal polyolefin resin and article prepared with the same
US11041031B2 (en) 2018-04-26 2021-06-22 Exxonmobil Chemical Patents Inc. Non-coordinating anion type activators containing cation having branched alkyl groups
WO2019246069A1 (en) 2018-06-19 2019-12-26 Exxonmobil Chemical Patents Inc. Polyethylene compositions and films prepared therefrom
WO2021119089A1 (en) 2019-12-11 2021-06-17 Exxonmobil Chemical Patents Inc. Processes for introduction of liquid activators in olefin polymerization reactions
WO2021126523A1 (en) 2019-12-19 2021-06-24 Exxonmobil Chemical Patents Inc. Production of impact copolymer polypropylene using metallocene and ziegler-natta catalysts in parallel reactors
US20230141606A1 (en) 2020-03-25 2023-05-11 Exxonmobil Chemical Patents Inc. Alkylation of Transition Metal Coordination Catalyst Complexes
WO2021262838A1 (en) 2020-06-26 2021-12-30 Exxonmobil Chemical Patents Inc. Copolymers composed of ethylene, a-olefin, non-conjugated diene, and substituted styrene and articles therefrom
WO2021262842A1 (en) 2020-06-26 2021-12-30 Exxonmobil Chemical Patents Inc. COPOLYMERS OF ETHYLENE, α-OLEFIN, NON-CONJUGATED DIENE, AND ARYL-SUBSTITUTED CYCLOALKENE, METHODS TO PRODUCE, BLENDS, AND ARTICLES THEREFROM
EP4192888A1 (en) 2020-08-10 2023-06-14 ExxonMobil Chemical Patents Inc. Methods for delivery of non-aromatic solutions to polymerization reactors

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1220672A (en) * 1997-02-07 1999-06-23 三井化学株式会社 Olefin polymerization catalyst and process for production of olefin polymers
US6451938B1 (en) * 1997-02-25 2002-09-17 Exxon Mobil Chemical Patents Inc. Polymerization catalyst system comprising heterocyclic fused cyclopentadienide ligands
TW420693B (en) * 1997-04-25 2001-02-01 Mitsui Chemicals Inc Olefin polymerization catalysts, transition metal compounds, and <alpha>-olefin/conjugated diene copolymers
JPH10330412A (en) * 1997-05-27 1998-12-15 Mitsui Chem Inc Catalyst for olefin polymerization and polymerization of the same
US6103657A (en) * 1997-07-02 2000-08-15 Union Carbide Chemicals & Plastics Technology Corporation Catalyst for the production of olefin polymers
ID27209A (en) * 1998-03-12 2001-03-08 Bp Chem Int Ltd POLYMERIZATION CATALYSTS
WO1999046303A1 (en) * 1998-03-12 1999-09-16 Bp Chemicals Limited Polymerisation catalysts

Also Published As

Publication number Publication date
SA00210262B1 (en) 2006-06-04
NO20021862L (en) 2002-06-24
AR023991A1 (en) 2002-09-04
IL149262A0 (en) 2002-11-10
TR200201767T2 (en) 2002-11-21
CZ20021402A3 (en) 2002-11-13
AU4713900A (en) 2001-05-08
JP2003513114A (en) 2003-04-08
SK5502002A3 (en) 2002-12-03
AU767697B2 (en) 2003-11-20
WO2001030861A1 (en) 2001-05-03
EP1226190A1 (en) 2002-07-31
NO20021862D0 (en) 2002-04-19
MY129717A (en) 2007-04-30
PL355103A1 (en) 2004-04-05
MXPA02003999A (en) 2002-10-23
CA2388137A1 (en) 2001-05-03
KR100553288B1 (en) 2006-02-22
CN1402739A (en) 2003-03-12
KR20020060956A (en) 2002-07-19
CN100484969C (en) 2009-05-06
JP4117822B2 (en) 2008-07-16

Similar Documents

Publication Publication Date Title
BR0015235A (en) Catalyst compositions, polymerization methods, and polymers thereof
DE69330674D1 (en) Process for the preparation of polyolefin catalysts
BR0211288A (en) Mixed metallocene catalyst systems containing a weak comonomer incorporator and a good comonomer incorporator
RU94045143A (en) Metallocenes, catalyst system containing said metallocenes, process for preparing polyolefins, and polyolefin
EA200001002A1 (en) METHOD OF POLYMERIZATION OF OLEFINS
HUP0002912A2 (en) Polymerization of olefins
KR960022753A (en) Polyethylene composition
DE69936341D1 (en) Polyethylene and process for its preparation
HUP0302646A2 (en) Polyethylene pipe resin and production thereof
HUP0100366A2 (en) Homopolymers and copolymers of ethylene
BR0317322A (en) Polyethylene molding composition, and process for the production and use thereof
BR9910611A (en) Catalyst composition for polymerizing monomers
CA2387877A1 (en) Catalyst systems and their use in a polymerization process
BR0316920A (en) Polyethylene composition, and process for producing and using polyethylene
BR0209401A (en) Process for the preparation of a propylene polymer, propylene polymer and copolymer, propylene polymer article, and use of a copolymer
DE69602391D1 (en) Solid catalyst component for the (co) polymerization of ethylene, process for its preparation, catalyst for the (co) polymerization of ethylene and process for the ethylene (co) polymerization
ES2164114T3 (en) CATALYTIC SYSTEMS FOR IMPROVED STEREOSELECTIVITY AND DISTRIBUTION OF WIDER MOLECULAR WEIGHT IN OLEFINE POLYMERIZATION.
BR0317343B1 (en) polyethylene composition with multimodal molecular weight distribution, process for its production, and use of same
BR0313011A (en) Polyolefin block copolymers
ATE226232T1 (en) AMORPHOUS PROPYLENE-POLYENE COPOLYMERS AND COMPOSITIONS CONTAINING SAME
CA2124273A1 (en) Resin-containing, biaxially oriented, multilayer polypropylene film, process for the production thereof, and the use thereof
BR0211290A (en) Low comonomer incorporation metallocene catalyst compounds
JP2006506495A (en) Branched polypropylene
DE69938367D1 (en) Process for the polymerization of olefins; Polyethylenes, and films, and articles made therewith
CA2504407A1 (en) Method of recycling of commingled plastics waste to tough thermoplastic materials

Legal Events

Date Code Title Description
B07A Application suspended after technical examination (opinion) [chapter 7.1 patent gazette]
B09B Patent application refused [chapter 9.2 patent gazette]

Free format text: INDEFIRO O PRESENTE PEDIDO DE PATENTE COMO INVENCAO - DE ACORDO COM O ART. 8O DA LPI.

B09B Patent application refused [chapter 9.2 patent gazette]

Free format text: MANTIDO O INDEFERIMENTO UMA VEZ QUE NAO FOI APRESENTADO RECURSO DENTRO DO PRAZO LEGAL.