RU2018114460A - 4-амино-6-(4-замещенные-фенил)-пиколинаты и 6-амино-2-(4-замещенные-фенил)-пиримидин-4-карбоксилаты и их применение в качестве гербицидов - Google Patents
4-амино-6-(4-замещенные-фенил)-пиколинаты и 6-амино-2-(4-замещенные-фенил)-пиримидин-4-карбоксилаты и их применение в качестве гербицидов Download PDFInfo
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D213/00—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
- C07D213/02—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
- C07D213/04—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
- C07D213/06—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom containing only hydrogen and carbon atoms in addition to the ring nitrogen atom
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N31/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic oxygen or sulfur compounds
- A01N31/04—Oxygen or sulfur attached to an aliphatic side-chain of a carbocyclic ring system
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/34—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
- A01N43/40—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom six-membered rings
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
- A01N43/54—1,3-Diazines; Hydrogenated 1,3-diazines
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D213/00—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
- C07D213/02—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
- C07D213/04—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
- C07D213/60—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
- C07D213/78—Carbon atoms having three bonds to hetero atoms, with at the most one bond to halogen, e.g. ester or nitrile radicals
- C07D213/79—Acids; Esters
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D239/00—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings
- C07D239/02—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings not condensed with other rings
- C07D239/24—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings not condensed with other rings having three or more double bonds between ring members or between ring members and non-ring members
- C07D239/28—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings not condensed with other rings having three or more double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, directly attached to ring carbon atoms
- C07D239/32—One oxygen, sulfur or nitrogen atom
- C07D239/42—One nitrogen atom
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D239/00—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings
- C07D239/02—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings not condensed with other rings
- C07D239/24—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings not condensed with other rings having three or more double bonds between ring members or between ring members and non-ring members
- C07D239/28—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings not condensed with other rings having three or more double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, directly attached to ring carbon atoms
- C07D239/46—Two or more oxygen, sulphur or nitrogen atoms
- C07D239/47—One nitrogen atom and one oxygen or sulfur atom, e.g. cytosine
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D213/00—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
- C07D213/02—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
- C07D213/04—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
- C07D213/60—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
- C07D213/72—Nitrogen atoms
- C07D213/73—Unsubstituted amino or imino radicals
Claims (25)
1. Соединение формулы (I)
в которой X означает N или CY; где Y означает водород, галоген, C1-C3-алкил, C1-C3-галогеналкил, C1-C3-алкоксигруппу, C1-C3-галогеналкоксигруппу, C1-C3-алкилтиогруппу или C1-C3-галогеналкилтиогруппу;
R1 означает OR1′, в которой R1′ означает H, C1-C8-алкил или C7-C10-арилалкил;
R2 означает галоген, C1-C4-алкил, C1-C4-галогеналкил, C2-C4-алкенил, C1-C4-алкоксигруппу или C1-C4-галогеналкоксигруппу;
R3 и R4 все независимо означают водород, C1-C6-алкил, C1-C6-галогеналкил, C3-C6-алкенил, C3-C6-галогеналкенил, C3-C6-алкинил, гидроксигруппу, C1-C6-алкоксигруппу, C1-C6-галогеналкоксигруппу, формил, (C1-C3-алкил)карбонил, (C1-C3-галогеналкил)карбонил, (C1-C6-алкокси)карбонил, (C1-C6-алкил)карбамил, C1-C6-алкилсульфонил, три(C1-C6-алкил)силил, ди(C1-C6-алкил)фосфонил, или R3 и R4 вместе с атомом азота, к которому они присоединены, образуют 5- или 6-членное насыщенное кольцо, или R3 и R4, взятые вместе, означают =CR3′R4′, где R3′ и R4′ все независимо означают водород, C1-C6-алкил, C3-C6-алкенил, C3-C6-алкинил, C1-C6-алкоксигруппу или C1-C6-алкиламиногруппу или R3′ и R4′ вместе с атомом углерода, к которому они присоединены, образуют 5- или 6-членное насыщенное кольцо;
Ar означает:
где
X1 означает H, F, Cl, Br, I, этинил, галогенэтинил, CF2H, OCF2H, OCF3, CN, CONH2, CO2H, CO2СН3 или NO2;
или его N-оксид, или сельскохозяйственно-приемлемая соль.
2. Соединение по п.1, в котором R2 означает Cl.
3. Соединение по п.1, в котором R2 означает C1-C4-алкоксигруппу.
4. Соединение по п.1, в котором R2 означает OСН3 или OСН2СН3.
5. Соединение по любому из пп.1-4, в котором X означает N, CH, CF, CCl или CCH3.
6. Соединение по любому из пп.1-4, в котором X означает CF.
7. Соединение по любому из пп.1-4, в котором X означает N.
8. Соединение по любому из пп.1-7, в котором X1 означает I, этинил или CN.
9. Соединение по любому из пп.1-7, в котором X1 означает I.
10. Соединение по любому из пп.1-7, в котором X1 означает этинил.
11. Соединение по любому из пп.1-7, в котором X1 означает CN.
12. Соединение по любому из пп.1-11, в котором R3 и R4 каждый означают водород.
13. Соединение по п.1, в котором X означает CF, R1 означает OН, R2 означает Cl, R3 и R4 каждый означают водород, и X1 означает I.
14. Соединение по п.1, в котором X означает CF, R1 означает OСН3, R2 означает Cl, R3 и R4 каждый означают водород, и X1 означает CN.
15. Соединение по п.1, в котором X означает CF, R1 означает OН, R2 означает Cl, R3 и R4 каждый означают водород, и X1 означает этинил.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
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US13/840,233 US9113629B2 (en) | 2013-03-15 | 2013-03-15 | 4-amino-6-(4-substituted-phenyl)-picolinates and 6-amino-2-(4-substituted-phenyl)-pyrimidine-4-carboxylates and their use as herbicides |
US13/840,233 | 2013-03-15 |
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RU2015143829A Division RU2652132C2 (ru) | 2013-03-15 | 2014-03-12 | 4-амино-6-(4-замещенные-фенил)-пиколинаты и 6-амино-2-(4-замещенные-фенил)-пиримидин-4-карбоксилаты и их применение в качестве гербицидов |
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RU2018114460A true RU2018114460A (ru) | 2019-03-04 |
RU2018114460A3 RU2018114460A3 (ru) | 2021-09-01 |
RU2771326C2 RU2771326C2 (ru) | 2022-04-29 |
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RU2015143829A RU2652132C2 (ru) | 2013-03-15 | 2014-03-12 | 4-амино-6-(4-замещенные-фенил)-пиколинаты и 6-амино-2-(4-замещенные-фенил)-пиримидин-4-карбоксилаты и их применение в качестве гербицидов |
RU2018114460A RU2771326C2 (ru) | 2013-03-15 | 2014-03-12 | 4-амино-6-(4-замещенные-фенил)-пиколинаты и 6-амино-2-(4-замещенные-фенил)-пиримидин-4-карбоксилаты и их применение в качестве гербицидов |
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US (1) | US9113629B2 (ru) |
EP (2) | EP2967069B1 (ru) |
JP (4) | JP6527502B2 (ru) |
KR (2) | KR102414529B1 (ru) |
CN (2) | CN108689924B (ru) |
AP (1) | AP2015008772A0 (ru) |
AR (2) | AR095449A1 (ru) |
AU (3) | AU2014235571C1 (ru) |
BR (2) | BR102014006229B8 (ru) |
CA (2) | CA2902347C (ru) |
CL (1) | CL2015002665A1 (ru) |
CR (1) | CR20150521A (ru) |
DK (1) | DK2967069T3 (ru) |
ES (2) | ES2706504T3 (ru) |
HR (1) | HRP20182056T1 (ru) |
HU (1) | HUE063201T2 (ru) |
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PT (1) | PT2967069T (ru) |
RS (1) | RS58151B1 (ru) |
RU (2) | RU2652132C2 (ru) |
SI (1) | SI2967069T1 (ru) |
UA (2) | UA125174C2 (ru) |
UY (1) | UY35477A (ru) |
WO (1) | WO2014150850A1 (ru) |
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BR112018076990B1 (pt) | 2016-06-27 | 2022-08-23 | Moghu Research Center Ltd. | Composto baseado em piridina incluindo anel de isoxazolina, herbicida, composição herbicida e método de preparação do dito composto |
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KR20130131334A (ko) | 2010-10-22 | 2013-12-03 | 바이엘 인텔렉쳐 프로퍼티 게엠베하 | 신규 치환된 피콜린산, 그의 염 및 산 유도체, 및 제초제로서의 그의 용도 |
CA2821584A1 (en) | 2010-12-16 | 2012-06-21 | Marco Brunjes | 6-(2-aminophenyl)picolinates and their use as herbicides |
TWI592401B (zh) | 2011-01-25 | 2017-07-21 | 陶氏農業科學公司 | 用於製備4-胺基-3-氯-5-氟-6-(經取代的)吡啶甲酸酯的方法(一) |
US8658568B2 (en) * | 2011-01-25 | 2014-02-25 | Dow Agrosciences, Llc. | 6-amino-2-substituted-5-vinylsilylpyrimidine-4-carboxylic acids and esters and 4-amino-6-substituted-3-vinylsilylpyridine-2-carboxylic acids and esters as herbicides |
US8835409B2 (en) | 2011-01-25 | 2014-09-16 | Dow Agrosciences, Llc. | 3-alkenyl-6-halo-4-aminopicolinates and their use as herbicides |
TWI596088B (zh) | 2011-01-25 | 2017-08-21 | 陶氏農業科學公司 | 4-胺基-6-(經取代的苯基)吡啶甲酸酯及6-胺基-2-(經取代的苯基)-4-嘧啶羧酸酯之芳烷酯以及其等作為除草劑之用途 |
UA113412C2 (xx) * | 2011-06-30 | 2017-01-25 | 3-алкокси, тіоалкіл і аміно-4-аміно-6-(заміщені) піколінати та їхнє застосування як гербіцидів |
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