RU2016104896A - МЕТАЛЛИЧЕСКИЕ БЛЕСТЯЩИЕ ПИГМЕНТЫ НА ОСНОВЕ ПЛАСТИНОК СУБСТРАТА С ТОЛЩИНОЙ ОТ 1 нм ДО 50 нм - Google Patents

МЕТАЛЛИЧЕСКИЕ БЛЕСТЯЩИЕ ПИГМЕНТЫ НА ОСНОВЕ ПЛАСТИНОК СУБСТРАТА С ТОЛЩИНОЙ ОТ 1 нм ДО 50 нм Download PDF

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RU2016104896A
RU2016104896A RU2016104896A RU2016104896A RU2016104896A RU 2016104896 A RU2016104896 A RU 2016104896A RU 2016104896 A RU2016104896 A RU 2016104896A RU 2016104896 A RU2016104896 A RU 2016104896A RU 2016104896 A RU2016104896 A RU 2016104896A
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oxide
coating
thickness
substrate
aluminum
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RU2658063C2 (ru
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Кайман ШИМИЦУ
Фабиан ПИХ
Адальберт ХУБЕР
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Шленк Металлик Пигментс Гмбх
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    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/02Cosmetics or similar toiletry preparations characterised by special physical form
    • A61K8/0241Containing particulates characterized by their shape and/or structure
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    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
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    • C09C1/0051Pigments exhibiting interference colours, e.g. transparent platelets of appropriate thinness or flaky substrates, e.g. mica, bearing appropriate thin transparent coatings comprising a stack of coating layers with alternating low and high refractive indices, wherein the first coating layer on the core surface has the low refractive index
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    • C09C1/00Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
    • C09C1/0015Pigments exhibiting interference colours, e.g. transparent platelets of appropriate thinness or flaky substrates, e.g. mica, bearing appropriate thin transparent coatings
    • C09C1/0051Pigments exhibiting interference colours, e.g. transparent platelets of appropriate thinness or flaky substrates, e.g. mica, bearing appropriate thin transparent coatings comprising a stack of coating layers with alternating low and high refractive indices, wherein the first coating layer on the core surface has the low refractive index
    • C09C1/0057Pigments exhibiting interference colours, e.g. transparent platelets of appropriate thinness or flaky substrates, e.g. mica, bearing appropriate thin transparent coatings comprising a stack of coating layers with alternating low and high refractive indices, wherein the first coating layer on the core surface has the low refractive index comprising at least one light-absorbing layer
    • C09C1/0066Pigments exhibiting interference colours, e.g. transparent platelets of appropriate thinness or flaky substrates, e.g. mica, bearing appropriate thin transparent coatings comprising a stack of coating layers with alternating low and high refractive indices, wherein the first coating layer on the core surface has the low refractive index comprising at least one light-absorbing layer consisting of at least one coloured inorganic material
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    • C09C3/00Treatment in general of inorganic materials, other than fibrous fillers, to enhance their pigmenting or filling properties
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    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
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    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
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Claims (13)

1. Металлический блестящий пигмент на основе алюминиевых пластинок субстрата с покрытием, отличающийся тем, что:
- алюминиевые пластинки субстрата имеют толщину от 1 до 50 нм, предпочтительно - от 1 до 30 нм, имеют монолитную структуру и необязательно пассивированы, и окружены по меньшей мере покрытием В, состоящим из высокопреломляющего оксида металла, который имеет показатель преломления по меньшей мере 1,9,
- покрытие В имеет толщину по меньшей мере 50 нм и состоит, по существу, из высокопреломляющего оксида металла, выбранного из по меньшей мере одного из оксида железа (III), оксида хрома (III), оксида ванадия (V), оксида титана (III), диоксида титана и/или оксида циркония, и
- между поверхностью алюминиевых пластинок субстрата и покрытием В имеется по меньшей мере одно дополнительное окружающее пластинки субстрата покрытие А, состоящее по меньшей мере из одного низкопреломляющего оксида металла, который имеет показатель преломления, не превышающий 1,8, и который выбран из группы, состоящей из SiO2, B2O3, MnO2, MgO, GeO2 и Al2O3,
- пластинки субстрата содержат дополнительное покрытие С, отличающееся от нижележащего покрытия В и состоящее из по меньшей мере одного (гидрата) оксида металла, выбранного из (ди)оксида кремния, гидрата оксида кремния, оксида алюминия, гидрата оксида алюминия, оксида цинка, оксида олова, диоксида титана, оксида циркония, оксида железа (III) или оксида хрома (III).
2. Металлический блестящий пигмент по п. 1, отличающийся тем, что покрытие А состоит из SiO2.
3. Металлический блестящий пигмент по п. 1 или 2, отличающийся тем, что покрытие А имеет толщину от 1 до 100 нм.
4. Металлический блестящий пигмент по п. 1 или 2, отличающийся тем, что алюминиевые пластинки субстрата имеют толщину от 5 до 30 нм, покрытие А, состоит из SiO2 и имеет толщину от 5 до 50 нм, а покрытие В состоит из Fe2O3 и имеет толщину от 50 до 300 нм.
5. Металлический блестящий пигмент по п. 3, отличающийся тем, что алюминиевые пластинки субстрата имеют толщину от 5 до 30 нм, покрытие А состоит из SiO2 и имеет толщину от 5 до 50 нм, а покрытие В состоит из Fe2O3 и имеет толщину от 50 до 300 нм.
6. Способ получения металлического блестящего пигмента по любому из пп. 1-5, включающий стадии:
- получения необязательно пассивированных алюминиевых пластинок субстрата,
- нанесения покрытия на алюминиевые пластинки субстрата посредством гидролитического разложения одного или более органических соединений металлов и/или посредством осаждения одной или более растворенных солей металлов.
7. Применение металлического блестящего пигмента по любому из пп. 1-5 для окрашивания лаков, печатных красок, чернил, полимерных материалов, стекол, керамических изделий и композиций декоративной косметики.
RU2016104896A 2013-08-02 2014-07-29 МЕТАЛЛИЧЕСКИЕ БЛЕСТЯЩИЕ ПИГМЕНТЫ НА ОСНОВЕ ПЛАСТИНОК СУБСТРАТА С ТОЛЩИНОЙ ОТ 1 нм ДО 50 нм RU2658063C2 (ru)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP13003870.6 2013-08-02
EP13003870.6A EP2832801A1 (de) 2013-08-02 2013-08-02 Metallische Glanzpigmente basierend auf Substratplättchen mit einer Dicke von 1-50 nm
PCT/EP2014/002073 WO2015014484A1 (de) 2013-08-02 2014-07-29 Metallische glanzpigmente basierend auf substratplättchen mit einer dicke von 1-50 nm

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BR112016002297A2 (pt) 2020-07-14
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WO2015014484A1 (de) 2015-02-05
PT3053967T (pt) 2018-03-15
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US10227494B2 (en) 2019-03-12
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ES2663864T3 (es) 2018-04-17
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MX2021004254A (es) 2021-05-28
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ES2629045T3 (es) 2017-08-07
KR20160039616A (ko) 2016-04-11
US11236240B2 (en) 2022-02-01
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