RU2015102031A - Сополимер для улучшения термического сопротивления метакриловой смолы - Google Patents
Сополимер для улучшения термического сопротивления метакриловой смолы Download PDFInfo
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Abstract
1. Сополимер для улучшения термического сопротивления метакриловой смолы, содержащий:от 45 до 85% по весу ароматического винилового мономера,от 5 до 45% по весу мономера сложного эфира мет(акриловой) кислоты иот 10 до 20% по весу мономера ангидрида ненасыщенной дикарбоновой кислоты,при этом указанный сополимер имеет общий коэффициент пропускания света 88% или более, измеренный согласно ASTM D1003 на образце толщиной 2 мм.2. Сополимер по п. 1, содержащий:от 50 до 80% по весу ароматического винилового мономера,от 8 до 38% по весу мономера сложного эфира мет(акриловой) кислоты иот 12 до 18% по весу мономера ангидрида ненасыщенной дикарбоновой кислоты.3. Сополимер по п. 1 или 2, в котором среднемассовая молекулярная масса (Mw) сополимера составляет от 10×10до 20×10.4. Композиция смолы, содержащая:от 5 до 50% по весу сополимера по любому из пп. 1-3 и от 50 до 95% по весу метакриловой смолы.5. Композиция смолы по п. 4, в которой метакриловая смола содержит:от 70 до 100% по весу мономера сложного эфира мет(акриловой) кислоты и от 0 до 30% по весу ароматического винилового мономера.6. Литое изделие, содержащее композицию смолы по п. 4 или 5.7. Литое изделие по п. 6, являющееся оптической деталью.8. Литое изделие по п. 7, являющееся оптической пленкой.9. Литое изделие по п. 8, являющееся защитной пленкой для поляризационной пленки, фазокомпенсирующей пленкой или просветляющей пленкой.
Claims (9)
1. Сополимер для улучшения термического сопротивления метакриловой смолы, содержащий:
от 45 до 85% по весу ароматического винилового мономера,
от 5 до 45% по весу мономера сложного эфира мет(акриловой) кислоты и
от 10 до 20% по весу мономера ангидрида ненасыщенной дикарбоновой кислоты,
при этом указанный сополимер имеет общий коэффициент пропускания света 88% или более, измеренный согласно ASTM D1003 на образце толщиной 2 мм.
2. Сополимер по п. 1, содержащий:
от 50 до 80% по весу ароматического винилового мономера,
от 8 до 38% по весу мономера сложного эфира мет(акриловой) кислоты и
от 12 до 18% по весу мономера ангидрида ненасыщенной дикарбоновой кислоты.
3. Сополимер по п. 1 или 2, в котором среднемассовая молекулярная масса (Mw) сополимера составляет от 10×104 до 20×104.
4. Композиция смолы, содержащая:
от 5 до 50% по весу сополимера по любому из пп. 1-3 и от 50 до 95% по весу метакриловой смолы.
5. Композиция смолы по п. 4, в которой метакриловая смола содержит:
от 70 до 100% по весу мономера сложного эфира мет(акриловой) кислоты и от 0 до 30% по весу ароматического винилового мономера.
6. Литое изделие, содержащее композицию смолы по п. 4 или 5.
7. Литое изделие по п. 6, являющееся оптической деталью.
8. Литое изделие по п. 7, являющееся оптической пленкой.
9. Литое изделие по п. 8, являющееся защитной пленкой для поляризационной пленки, фазокомпенсирующей пленкой или просветляющей пленкой.
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JP2012-168675 | 2012-07-30 | ||
JP2012168675 | 2012-07-30 | ||
PCT/JP2013/070484 WO2014021264A1 (ja) | 2012-07-30 | 2013-07-29 | メタクリル樹脂耐熱性向上用の共重合体 |
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RU2015102031A true RU2015102031A (ru) | 2016-09-20 |
RU2623732C2 RU2623732C2 (ru) | 2017-06-29 |
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US (2) | US20150203610A1 (ru) |
EP (1) | EP2881407B1 (ru) |
JP (1) | JP6055832B2 (ru) |
KR (1) | KR102050371B1 (ru) |
CN (1) | CN104540860B (ru) |
IN (1) | IN2015DN01437A (ru) |
RU (1) | RU2623732C2 (ru) |
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WO (1) | WO2014021264A1 (ru) |
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WO2014065129A1 (ja) * | 2012-10-22 | 2014-05-01 | 電気化学工業株式会社 | 芳香族ビニル-シアン化ビニル系樹脂耐熱性向上用の共重合体 |
KR102244204B1 (ko) * | 2014-05-22 | 2021-04-26 | 덴카 주식회사 | 투명 내찰상성 판용 공중합체, 투명 내찰상성 판용 적층체 |
JP6693041B2 (ja) * | 2014-07-14 | 2020-05-13 | 三菱ケミカル株式会社 | 積層体 |
JP2016037522A (ja) * | 2014-08-06 | 2016-03-22 | デンカ株式会社 | 発泡成形体用スチレン系共重合体 |
EP3181600B1 (en) * | 2014-08-11 | 2018-06-13 | Denka Company Limited | Copolymer suitable for improving heat resistance of methacrylic resin |
CN104497461B (zh) * | 2014-12-15 | 2017-08-29 | 上海锦湖日丽塑料有限公司 | 一种耐热耐刮擦高透过率pmma合金树脂组合物及其制备方法 |
US20170369694A1 (en) * | 2015-01-15 | 2017-12-28 | Denka Company Limited | Transparent, highly heat resistant resin composition |
JP6475501B2 (ja) * | 2015-01-26 | 2019-02-27 | デンカ株式会社 | 塩化ビニル樹脂耐熱改質用共重合体、成形体、塩化ビニル配管 |
CN107250261B (zh) | 2015-02-20 | 2020-07-28 | 株式会社可乐丽 | 树脂组合物、成型品和层叠体 |
CN107960084B (zh) * | 2015-05-11 | 2020-08-11 | 电化株式会社 | 树脂组合物、汽车透明部件用树脂组合物、仪表面板透明盖、半球形透镜 |
KR20180011140A (ko) * | 2015-05-20 | 2018-01-31 | 덴카 주식회사 | 투명한 수지 조성물 및 그의 제조 방법 |
JPWO2017033989A1 (ja) * | 2015-08-25 | 2018-06-14 | デンカ株式会社 | 発泡成形用熱可塑性樹脂組成物、発泡体 |
KR101874160B1 (ko) | 2015-09-30 | 2018-07-04 | 롯데첨단소재(주) | 투명 열가소성 수지 조성물 및 이로부터 형성된 성형품 |
TW201720846A (zh) * | 2015-11-30 | 2017-06-16 | Denka Company Ltd | 透明之高耐熱性苯乙烯系共聚物 |
WO2017162393A1 (en) * | 2016-03-21 | 2017-09-28 | Sabic Global Technologies B.V. | Polymer composition comprising a (meth)acrylic polymer having good optical properties and heat resistance |
JP6707400B2 (ja) * | 2016-05-31 | 2020-06-10 | Psジャパン株式会社 | スチレン系樹脂、スチレン系樹脂組成物、そのシート及び成形品、並びにスチレン系樹脂の製造方法 |
CN109477922B (zh) * | 2016-07-06 | 2021-10-08 | 电化株式会社 | 偏振器保护膜用树脂组合物、偏振器保护膜 |
JP2018012530A (ja) * | 2016-07-21 | 2018-01-25 | デンカ株式会社 | 二軸延伸シートおよび包装用容器 |
CN109476899B (zh) | 2016-07-22 | 2020-12-22 | 电化株式会社 | 树脂组合物和由该树脂组合物构成的膜 |
FR3056218B1 (fr) * | 2016-09-20 | 2020-10-02 | Arkema France | Composition de polymere, son procede de preparation, son utilisation et objet comprenant celle-ci |
EP3581609B1 (en) | 2017-02-07 | 2023-08-02 | Kuraray Co., Ltd. | Acrylic resin biaxially stretched film and method for manufacturing the same |
CN111212875B (zh) * | 2017-08-29 | 2022-04-15 | Sabic环球技术有限责任公司 | 包括耐热聚合物的照明***组件 |
JP2020011517A (ja) * | 2019-10-09 | 2020-01-23 | 三菱ケミカル株式会社 | 積層体 |
JPWO2021193922A1 (ru) | 2020-03-26 | 2021-09-30 |
Family Cites Families (18)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3725360A (en) * | 1971-03-11 | 1973-04-03 | Dow Chemical Co | Process for polymerizing styrene and maleic anhydride |
JPS57153008A (en) * | 1981-03-19 | 1982-09-21 | Asahi Chem Ind Co Ltd | Methacrylic resin having excellent heat resistance |
US4387191A (en) * | 1982-03-25 | 1983-06-07 | Monsanto Company | Heat stabilized polymers |
JPH0686497B2 (ja) * | 1983-12-27 | 1994-11-02 | 三井東圧化学株式会社 | スチレン系共重合体 |
JPH0214207A (ja) * | 1988-06-30 | 1990-01-18 | Kyowa Gas Chem Ind Co Ltd | 離型性の改良された注型成形品の製造法 |
FR2852963A1 (fr) * | 2003-03-26 | 2004-10-01 | Atofina | Nouveau procede de synthese/fabrication de films acryliques |
EP1869507A2 (en) * | 2005-04-06 | 2007-12-26 | 3M Innovative Properties Company | Diffuse reflective polariziing films with orientable polymer blends |
JP5496656B2 (ja) * | 2006-05-23 | 2014-05-21 | アルケマ フランス | 多層共押出方法 |
JP5191667B2 (ja) * | 2007-01-29 | 2013-05-08 | 旭化成イーマテリアルズ株式会社 | スチレン系樹脂異方性フィルム |
WO2009031544A1 (ja) | 2007-09-04 | 2009-03-12 | Denki Kagaku Kogyo Kabushiki Kaisha | 熱可塑性共重合樹脂及びその光学成形体 |
CN101162364B (zh) * | 2007-11-30 | 2011-04-20 | 京东方科技集团股份有限公司 | 感光树脂组合物及其制备方法和成膜方法 |
WO2009082131A2 (en) * | 2007-12-20 | 2009-07-02 | Lg Chem, Ltd. | Multi-layered acrylic retardation film and fabrication method thereof |
KR101201168B1 (ko) * | 2007-12-27 | 2012-11-13 | 아사히 가세이 케미칼즈 가부시키가이샤 | 아크릴계 열가소성 수지, 및 광학 재료용 성형체 |
KR101065200B1 (ko) * | 2008-01-03 | 2011-09-19 | 주식회사 엘지화학 | 광학 필름, 편광자 보호 필름, 이를 이용한 편광판, 및 이를 이용한 화상 표시 장치 |
KR101105424B1 (ko) * | 2008-04-30 | 2012-01-17 | 주식회사 엘지화학 | 수지 조성물 및 이를 이용하여 형성된 광학 필름 |
KR101091537B1 (ko) * | 2009-01-06 | 2011-12-13 | 주식회사 엘지화학 | 광학 필름 및 이를 포함하는 액정 표시 장치 |
KR101312184B1 (ko) * | 2009-10-22 | 2013-09-26 | 아사히 가세이 케미칼즈 가부시키가이샤 | 메타크릴계 수지, 그 성형체 및 메타크릴계 수지의 제조 방법 |
WO2014065129A1 (ja) * | 2012-10-22 | 2014-05-01 | 電気化学工業株式会社 | 芳香族ビニル-シアン化ビニル系樹脂耐熱性向上用の共重合体 |
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2013
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EP2881407B1 (en) | 2017-12-06 |
KR20150037919A (ko) | 2015-04-08 |
RU2623732C2 (ru) | 2017-06-29 |
US20160326360A1 (en) | 2016-11-10 |
EP2881407A4 (en) | 2016-04-13 |
TWI572628B (zh) | 2017-03-01 |
TW201410718A (zh) | 2014-03-16 |
EP2881407A1 (en) | 2015-06-10 |
US20150203610A1 (en) | 2015-07-23 |
JPWO2014021264A1 (ja) | 2016-07-21 |
CN104540860A (zh) | 2015-04-22 |
CN104540860B (zh) | 2017-03-08 |
JP6055832B2 (ja) | 2016-12-27 |
KR102050371B1 (ko) | 2019-11-29 |
US9873787B2 (en) | 2018-01-23 |
WO2014021264A1 (ja) | 2014-02-06 |
IN2015DN01437A (ru) | 2015-07-03 |
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