RU2013108831A - Способ синтеза углеводородов с5+ в присутствии катализатора, полученного при помощи по меньшей мере одного циклического олигосахарида - Google Patents

Способ синтеза углеводородов с5+ в присутствии катализатора, полученного при помощи по меньшей мере одного циклического олигосахарида Download PDF

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RU2013108831A
RU2013108831A RU2013108831/04A RU2013108831A RU2013108831A RU 2013108831 A RU2013108831 A RU 2013108831A RU 2013108831/04 A RU2013108831/04 A RU 2013108831/04A RU 2013108831 A RU2013108831 A RU 2013108831A RU 2013108831 A RU2013108831 A RU 2013108831A
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hydrocarbon synthesis
synthesis method
oxide
catalyst
group viii
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Фабрис ДИЛЬ
Анн ГРИБОВАЛЬ-КОНСТАН
Андрей ХОДАКОВ
Алан ЖАН-МАРИ
Эрик Монфлье
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Ифп Энержи Нувелль
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Abstract

1. Способ синтеза главным образом линейных и насыщенных углеводородов С5+, заключающийся в приведении в контакт загрузки, содержащей синтез-газ, по меньшей мере с одним катализатором, активная фаза которого содержит по меньшей мере один металл группы VIII, нанесенный на носитель, состоящий по меньшей мере из одного оксида, при этом указанный катализатор получают способом, включающим в себя:i) по меньшей мере одну стадию приведения в контакт по меньшей мере указанного носителя по меньшей мере с одним раствором, содержащим по меньшей мере один предшественник указанного металла группы VIII,ii) по меньшей мере одну стадию приведения в контакт по меньшей мере указанного носителя по меньшей мере с одним органическим соединением, образованным по меньшей мере одним циклическим олигосахаридом, состоящим по меньшей мере из 6 остатков глюкопиранозы, объединенных α-(1,4)-связями,iii) по меньшей мере одну стадию прокаливания для получения по меньшей мере указанного металла указанной группы VIII в форме оксида,при этом стадии i) и ii) могут осуществляться раздельно в любом порядке или одновременно.2. Способ синтеза углеводородов по п.1, где указанная активная фаза содержит кобальт.3. Способ синтеза углеводородов по п.1 или 2, где указанная активная фаза содержит по меньшей мере один дополнительный металл, выбираемый из платины, палладия, рения, рутения, марганца и тантала.4. Способ синтеза углеводородов по п.1, где указанный катализатор содержит кристаллиты оксида указанного металла группы VIII, имеющие средний диаметр по меньшей мере 6 нм.5. Способ синтеза углеводородов по п.1, где указанный носитель образован по меньшей мере простым оксидом, в�

Claims (15)

1. Способ синтеза главным образом линейных и насыщенных углеводородов С5+, заключающийся в приведении в контакт загрузки, содержащей синтез-газ, по меньшей мере с одним катализатором, активная фаза которого содержит по меньшей мере один металл группы VIII, нанесенный на носитель, состоящий по меньшей мере из одного оксида, при этом указанный катализатор получают способом, включающим в себя:
i) по меньшей мере одну стадию приведения в контакт по меньшей мере указанного носителя по меньшей мере с одним раствором, содержащим по меньшей мере один предшественник указанного металла группы VIII,
ii) по меньшей мере одну стадию приведения в контакт по меньшей мере указанного носителя по меньшей мере с одним органическим соединением, образованным по меньшей мере одним циклическим олигосахаридом, состоящим по меньшей мере из 6 остатков глюкопиранозы, объединенных α-(1,4)-связями,
iii) по меньшей мере одну стадию прокаливания для получения по меньшей мере указанного металла указанной группы VIII в форме оксида,
при этом стадии i) и ii) могут осуществляться раздельно в любом порядке или одновременно.
2. Способ синтеза углеводородов по п.1, где указанная активная фаза содержит кобальт.
3. Способ синтеза углеводородов по п.1 или 2, где указанная активная фаза содержит по меньшей мере один дополнительный металл, выбираемый из платины, палладия, рения, рутения, марганца и тантала.
4. Способ синтеза углеводородов по п.1, где указанный катализатор содержит кристаллиты оксида указанного металла группы VIII, имеющие средний диаметр по меньшей мере 6 нм.
5. Способ синтеза углеводородов по п.1, где указанный носитель образован по меньшей мере простым оксидом, выбираемым из оксида алюминия (Al2O3), диоксида кремния (SiO2), оксида титана (TiO2), церина (CeO2) и циркона (ZrO2).
6. Способ синтеза углеводородов по п.1, где указанный носитель образован шпинелью, включенной в оксид алюминия или диоксид кремния-оксид алюминия.
7. Способ синтеза углеводородов по п.1, где указанное органическое соединение выбирают из циклодекстринов, замещенных циклодекстринов, полимеризированных циклодекстринов и смесей циклодекстринов.
8. Способ синтеза углеводородов по п.7 где циклодекстрины представляют собой α-циклодекстрин, β-циклодекстрин и γ-циклодекстрин, соответственно состоящие из 6, 7 и 8 остатков глюкопиранозы, объединенных α-(1,4)-связями.
9. Способ синтеза углеводородов по п.7 где замещенные циклодекстрины представляют собой гидроксипропил бета-циклодекстрин и метилированные бета-циклодекстрины.
10. Способ синтеза углеводородов по п.1, где указанное органическое соединение для осуществления указанной стадии ii) является таким, что молярное отношение {(металл(ы) группы VIII в форме оксида, присутствующего в активной фазе катализатора, полученного по окончании указанной стадии iii)/органическое соединение}, составляет от 10 до 300.
11. Способ синтеза углеводородов по п.1, где в случае, если указанные стадии i) и ii) осуществляют одновременно, получение катализатора включает осуществление одной или нескольких стадий i).
12. Способ синтеза углеводородов по п.1, где указанную стадию i) осуществляют перед стадией ii).
13. Способ синтеза углеводородов по п.1, где указанную стадию ii) осуществляют перед стадией i).
14. Способ синтеза углеводородов по п.1, где указанную стадию iii) прокаливания осуществляют при температуре от 200 до 800°С.
15. Способ синтеза углеводородов по п.1 который проводят при общем давлении от 0,1 до 15 МРа при температуре от 150 до 350°С, объемной скорости от 100 до 20000 объемов синтез-газа на объем катализатора в час (100-20000 ч-1).
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