RU1799242C - Способ борьбы с насекомыми и клещами - Google Patents
Способ борьбы с насекомыми и клещамиInfo
- Publication number
- RU1799242C RU1799242C SU884355559A SU4355559A RU1799242C RU 1799242 C RU1799242 C RU 1799242C SU 884355559 A SU884355559 A SU 884355559A SU 4355559 A SU4355559 A SU 4355559A RU 1799242 C RU1799242 C RU 1799242C
- Authority
- RU
- Russia
- Prior art keywords
- denotes
- denote
- compounds
- carbon atom
- phenyl
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D213/00—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
- C07D213/02—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
- C07D213/04—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
- C07D213/60—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
- C07D213/62—Oxygen or sulfur atoms
- C07D213/63—One oxygen atom
- C07D213/64—One oxygen atom attached in position 2 or 6
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D211/00—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/34—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
- A01N43/40—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom six-membered rings
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
- A01N43/54—1,3-Diazines; Hydrogenated 1,3-diazines
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
- A01N43/58—1,2-Diazines; Hydrogenated 1,2-diazines
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
- A01N43/60—1,4-Diazines; Hydrogenated 1,4-diazines
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D213/00—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
- C07D213/02—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
- C07D213/04—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
- C07D213/60—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
- C07D213/61—Halogen atoms or nitro radicals
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D213/00—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
- C07D213/02—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
- C07D213/04—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
- C07D213/60—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
- C07D213/62—Oxygen or sulfur atoms
- C07D213/63—One oxygen atom
- C07D213/64—One oxygen atom attached in position 2 or 6
- C07D213/643—2-Phenoxypyridines; Derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D213/00—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
- C07D213/02—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
- C07D213/04—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
- C07D213/60—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
- C07D213/62—Oxygen or sulfur atoms
- C07D213/63—One oxygen atom
- C07D213/65—One oxygen atom attached in position 3 or 5
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D213/00—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
- C07D213/02—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
- C07D213/04—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
- C07D213/60—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
- C07D213/62—Oxygen or sulfur atoms
- C07D213/70—Sulfur atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D237/00—Heterocyclic compounds containing 1,2-diazine or hydrogenated 1,2-diazine rings
- C07D237/02—Heterocyclic compounds containing 1,2-diazine or hydrogenated 1,2-diazine rings not condensed with other rings
- C07D237/06—Heterocyclic compounds containing 1,2-diazine or hydrogenated 1,2-diazine rings not condensed with other rings having three double bonds between ring members or between ring members and non-ring members
- C07D237/10—Heterocyclic compounds containing 1,2-diazine or hydrogenated 1,2-diazine rings not condensed with other rings having three double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
- C07D237/12—Halogen atoms or nitro radicals
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D237/00—Heterocyclic compounds containing 1,2-diazine or hydrogenated 1,2-diazine rings
- C07D237/02—Heterocyclic compounds containing 1,2-diazine or hydrogenated 1,2-diazine rings not condensed with other rings
- C07D237/06—Heterocyclic compounds containing 1,2-diazine or hydrogenated 1,2-diazine rings not condensed with other rings having three double bonds between ring members or between ring members and non-ring members
- C07D237/10—Heterocyclic compounds containing 1,2-diazine or hydrogenated 1,2-diazine rings not condensed with other rings having three double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
- C07D237/14—Oxygen atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D237/00—Heterocyclic compounds containing 1,2-diazine or hydrogenated 1,2-diazine rings
- C07D237/02—Heterocyclic compounds containing 1,2-diazine or hydrogenated 1,2-diazine rings not condensed with other rings
- C07D237/06—Heterocyclic compounds containing 1,2-diazine or hydrogenated 1,2-diazine rings not condensed with other rings having three double bonds between ring members or between ring members and non-ring members
- C07D237/10—Heterocyclic compounds containing 1,2-diazine or hydrogenated 1,2-diazine rings not condensed with other rings having three double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
- C07D237/18—Sulfur atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D239/00—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings
- C07D239/02—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings not condensed with other rings
- C07D239/24—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings not condensed with other rings having three or more double bonds between ring members or between ring members and non-ring members
- C07D239/26—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings not condensed with other rings having three or more double bonds between ring members or between ring members and non-ring members with only hydrogen atoms, hydrocarbon or substituted hydrocarbon radicals, directly attached to ring carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D239/00—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings
- C07D239/02—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings not condensed with other rings
- C07D239/24—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings not condensed with other rings having three or more double bonds between ring members or between ring members and non-ring members
- C07D239/28—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings not condensed with other rings having three or more double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, directly attached to ring carbon atoms
- C07D239/32—One oxygen, sulfur or nitrogen atom
- C07D239/34—One oxygen atom
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D239/00—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings
- C07D239/02—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings not condensed with other rings
- C07D239/24—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings not condensed with other rings having three or more double bonds between ring members or between ring members and non-ring members
- C07D239/28—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings not condensed with other rings having three or more double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, directly attached to ring carbon atoms
- C07D239/32—One oxygen, sulfur or nitrogen atom
- C07D239/38—One sulfur atom
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D241/00—Heterocyclic compounds containing 1,4-diazine or hydrogenated 1,4-diazine rings
- C07D241/02—Heterocyclic compounds containing 1,4-diazine or hydrogenated 1,4-diazine rings not condensed with other rings
- C07D241/10—Heterocyclic compounds containing 1,4-diazine or hydrogenated 1,4-diazine rings not condensed with other rings having three double bonds between ring members or between ring members and non-ring members
- C07D241/14—Heterocyclic compounds containing 1,4-diazine or hydrogenated 1,4-diazine rings not condensed with other rings having three double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
- C07D241/16—Halogen atoms; Nitro radicals
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D241/00—Heterocyclic compounds containing 1,4-diazine or hydrogenated 1,4-diazine rings
- C07D241/02—Heterocyclic compounds containing 1,4-diazine or hydrogenated 1,4-diazine rings not condensed with other rings
- C07D241/10—Heterocyclic compounds containing 1,4-diazine or hydrogenated 1,4-diazine rings not condensed with other rings having three double bonds between ring members or between ring members and non-ring members
- C07D241/14—Heterocyclic compounds containing 1,4-diazine or hydrogenated 1,4-diazine rings not condensed with other rings having three double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
- C07D241/18—Oxygen or sulfur atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D253/00—Heterocyclic compounds containing six-membered rings having three nitrogen atoms as the only ring hetero atoms, not provided for by group C07D251/00
- C07D253/02—Heterocyclic compounds containing six-membered rings having three nitrogen atoms as the only ring hetero atoms, not provided for by group C07D251/00 not condensed with other rings
- C07D253/06—1,2,4-Triazines
- C07D253/065—1,2,4-Triazines having three double bonds between ring members or between ring members and non-ring members
- C07D253/07—1,2,4-Triazines having three double bonds between ring members or between ring members and non-ring members with hetero atoms, or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D257/00—Heterocyclic compounds containing rings having four nitrogen atoms as the only ring hetero atoms
- C07D257/02—Heterocyclic compounds containing rings having four nitrogen atoms as the only ring hetero atoms not condensed with other rings
- C07D257/08—Six-membered rings
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D401/00—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom
- C07D401/02—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings
- C07D401/06—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings linked by a carbon chain containing only aliphatic carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D401/00—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom
- C07D401/02—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings
- C07D401/08—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings linked by a carbon chain containing alicyclic rings
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D401/00—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom
- C07D401/02—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings
- C07D401/12—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings linked by a chain containing hetero atoms as chain links
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D409/00—Heterocyclic compounds containing two or more hetero rings, at least one ring having sulfur atoms as the only ring hetero atoms
- C07D409/02—Heterocyclic compounds containing two or more hetero rings, at least one ring having sulfur atoms as the only ring hetero atoms containing two hetero rings
- C07D409/06—Heterocyclic compounds containing two or more hetero rings, at least one ring having sulfur atoms as the only ring hetero atoms containing two hetero rings linked by a carbon chain containing only aliphatic carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D409/00—Heterocyclic compounds containing two or more hetero rings, at least one ring having sulfur atoms as the only ring hetero atoms
- C07D409/02—Heterocyclic compounds containing two or more hetero rings, at least one ring having sulfur atoms as the only ring hetero atoms containing two hetero rings
- C07D409/08—Heterocyclic compounds containing two or more hetero rings, at least one ring having sulfur atoms as the only ring hetero atoms containing two hetero rings linked by a carbon chain containing alicyclic rings
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D491/00—Heterocyclic compounds containing in the condensed ring system both one or more rings having oxygen atoms as the only ring hetero atoms and one or more rings having nitrogen atoms as the only ring hetero atoms, not provided for by groups C07D451/00 - C07D459/00, C07D463/00, C07D477/00 or C07D489/00
- C07D491/02—Heterocyclic compounds containing in the condensed ring system both one or more rings having oxygen atoms as the only ring hetero atoms and one or more rings having nitrogen atoms as the only ring hetero atoms, not provided for by groups C07D451/00 - C07D459/00, C07D463/00, C07D477/00 or C07D489/00 in which the condensed system contains two hetero rings
- C07D491/04—Ortho-condensed systems
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Wood Science & Technology (AREA)
- Environmental Sciences (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Zoology (AREA)
- Pest Control & Pesticides (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Plural Heterocyclic Compounds (AREA)
- Pyridine Compounds (AREA)
- Heterocyclic Carbon Compounds Containing A Hetero Ring Having Nitrogen And Oxygen As The Only Ring Hetero Atoms (AREA)
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Nitrogen And Oxygen Or Sulfur-Condensed Heterocyclic Ring Systems (AREA)
Abstract
Использование: сельское хоз йство, химический способ защиты растений от насекомых и клещей. Сущность изобретени : способ заключаетс в обработке растений соединениемформулы C2ABCDH C(R2R3)CH2XCH(R4)-R5. где А, В, С, О - азот или СН; RI - этокси, хлор, 2,2,2- трифторэтокси; Ra и R3 - метил или совместно с атомом углерода, к которому они присоединены, циклопропил; Ro - водород; RS - 3-феноксилфенил, который может быть замещен фтором в количестве 0,5-1 кг/га. 1 табл.
Description
Изобретение относитс к химическим способам защиты растений.
Известно использование в качестве активного вещества способа производного 1- (3-феноксифенил)-4 фенил-4-метилпентана.
Однако известный способ обладает недостаточной зкарицидной активностью.
Целью изобретени вл етс повышение инсехтоакарициднрй активности.
Указанна цель достигаетс использованием соединени формулы (I)
А-В
R,
1
K1 C-D 1
R3
сн.
-х-сн .
R
5
где А, В, С. D - азот или СН; RI - зтокси, хлор, 2,2,2-трифторэтокси; Hz и Ra - метил или совместно с атомом углерода цепи образуют циклопропил: R4 - водород; RS - 3- Феноксифенил, который может быть замещен фтором в количестве 0,5-1 кг/га.
Изобретение иллюстрируетс следующими примерами, в которых в качестве действующего вещества использовали соединени формулы (I), указанные в таблице .
Соединени формулы (I) получают известными методами. Представлен способ получени соединени 6 из таблицы.
Способ получени 2-(6-хлор-пирид-3- ил}-2-метил-пропил-(3-феноксибензил)-эфи- ра.
1,9 г (10,2 ммол )2-(-6-хлор-пирид-3-ил)2-метил-пропанола раствор ют в 15 мл толуола , добавл ют 2.7 г (10,3 ммол )
3-фенокси-бензилбромида и разбавл ют раствором 0,6 г (1,8 ммол ) тетра-н-бутилам- мониум-гидроген-сульфата в 5 г 50% натриевой щелочи. В течение 2 с при 70-80°С перемешивают, затем смешивают со
XI
ю ю ю
Ј to
СлЭ
смесью из 2 мл метанола и 2 мл концентрированного водного аммиака и, наконец, раздел ют между водой и толуолом. Органическа фракци промываетс раствором хлорида аммони , растворитель выпариваетс и сырой продукт очищаетс в колонке с силикагелем. Так получают 2,4 г (62,9% от теоретического) слабо-голубого масл нистого вещества. Дистиллируют в трубке с шариками при 0,03 мбар и 230-240°С (температура аппарата), ho 1,5812. Остальные соединени получают аналогичным образом.
Соединени из таблицы были использованы в следующих биологических примерах .
П р и м е р 1. Посев бобовых (Vlcia faba), сильно пораженный бобовой лиственной тлей, опрыскивают водными разбавленными эмульсионными концентратами при норме расхода 1 кг/га до стадии образовани капель. По истечении 3 дней гибель достигала 100% в случае использовани соединений 1-6, 8-13. При указанной дозе известное соединение А/1-(3-феноксифе- нил)-4-фенил-4-метилпентан/ было эффективно только на. 65%.
П р и ме р 2. Сильно пораженные белой мукой (Trialeurodes Vaporarium) бобовые растени (Phaseokis vulgaris) опрыскивали водными разбавленными эмульсионными концентратами при дозе 1 кг/га до начинающихс капель. После помещени растений в теплицу через 14 дней микроскопического контрол последовал результат почти 100% гибели в. случае использовани соединений 1-3, 5-8, 10. 1.1. Соединение А эффективно при указанной дозе только на 43%.
ПримерЗ. Проведение опыта: аналогично примеру 2. Подопытное насекомое: Tetranychus urticae (бобовый пауковый клещ).
Испытуемое растение: Phascolus vulgaris (кустистые бобы).
Норма расхода: 0,5 кг/га активного вещества в составе дл опрыскивани . При этой дозе соединени 10,11 через 8 дней показали 100% активность. В то врем как соединение .А не про вл ло никакого действи .
При м е р 4. Бобовые растени (Phaseolus vulgaris), сильно пораженные цитрусовой жирной тлей, опрыскивали водным разбавленным эмульсионным концентратом при дозе 1 кг/га до стадии образовани капель. После пребывани в теплице в течение 7 дней при 20-25°С сделали контроль. Установили 100% смертность дл соединений 1-7, 9, 10. Соединение А про вило 35%-ное действие.
П р и м е р 5. Хлопковые клещи (Oncopeltus faslstus) обрабатывали разбавленным водным эмульсионным концентратом при дозе 1 кг/га соединени ми 1-6, 8,
Ю, 11, 13 из примера. В конце опыта клещи были помещены в сосуды, покрытые воздухонепроницаемыми накидками; температура комнатна . По истечении 5 дней после обработки была установлена 100% гибель в
каждом отдельном случае. Соединение А при указанной дозе показало 20% эффективность .
Приме р 6. Лепестки бобов (Phaseolus vulgaris) обрабатывали водной эмульсией
соединени формулы (I) при дозе 1 кг/га (отнесенна на активное вещество) и поставили к одновременно обработанным личинками мексиканского бобового насекомого (Epllachna varlvestts) в наблюдательные
клетки, Оценка после 48 ч показала 100% уничтожение подопытных насекомых. Одц- наково активными оказались соединени соответственно примерам 1-3,5, 6,8,10,11. Соединение А оказалось активным всего на
67%.
П р и м е р 7. На внутренней стороне крышки и дна чашки Петри равномерно внесли соединени формулы (1) при дозе 0,5 кг/га вещества и оставили открытыми
до полного улетучивани растворител . После этого поместили по 10 комнатных мух (Musca domestica) в чашку Петри, чашки закрыли крышками, после 3 ч была об- наруженэ 100% гибель. Активными
оказались соединени 1-8, 10, 12, 13. Соединение А эффективно при указанной дозе на 45%.
Claims (1)
- Формула изобретени Способ борьбы с насекомыми и клещами после обработки растений активнодейст- вующим веществом, отличающийс тем, что, с целью усилени инсектоакари- цидного действи , в качестве активнодейст- вующего вещества используют соединени общей формулыА--ВR,| «nJ-ОУ-С-СНNi 1ЧС-D ГХ-CH-R,55где А, В, С, D - азот или СН;RI - этокси, хлор, 2,2,2-трифторэтокси;R2 и Рз метил или совместно с углероRS - 3-феноксифендом, к которому они присоединены, образу- быть замещен фтором,в количестве 0,5-1 кг/гает циклбпил: R4 - водород;RS - 3-феноксифенил, который можетбыть замещен фтором,в количестве 0,5-1 кг/га.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE19873712752 DE3712752A1 (de) | 1987-04-15 | 1987-04-15 | Heterocyclische neophananaloga, verfahren zu ihrer herstellung und ihre verwendung als schaedlingsbekaempfungsmittel |
Publications (1)
Publication Number | Publication Date |
---|---|
RU1799242C true RU1799242C (ru) | 1993-02-28 |
Family
ID=6325668
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
SU884355559A RU1799242C (ru) | 1987-04-15 | 1988-04-14 | Способ борьбы с насекомыми и клещами |
Country Status (24)
Country | Link |
---|---|
US (1) | US4966902A (ru) |
EP (1) | EP0288810B1 (ru) |
JP (1) | JPS63290865A (ru) |
KR (1) | KR880012550A (ru) |
CN (2) | CN1027448C (ru) |
AT (1) | ATE82964T1 (ru) |
AU (1) | AU614742B2 (ru) |
BR (1) | BR8801785A (ru) |
CA (1) | CA1334198C (ru) |
DD (1) | DD273968A5 (ru) |
DE (2) | DE3712752A1 (ru) |
DK (1) | DK204988A (ru) |
ES (1) | ES2053604T3 (ru) |
GR (1) | GR3006875T3 (ru) |
HU (1) | HU202837B (ru) |
IL (1) | IL86079A (ru) |
MA (1) | MA21249A1 (ru) |
MY (1) | MY103360A (ru) |
NZ (1) | NZ224233A (ru) |
PH (1) | PH25946A (ru) |
PT (1) | PT87246B (ru) |
RU (1) | RU1799242C (ru) |
TR (1) | TR23440A (ru) |
ZA (1) | ZA882587B (ru) |
Families Citing this family (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE3810379A1 (de) * | 1988-03-26 | 1989-10-12 | Hoechst Ag | Azaneophyl- und silazaneophylsulfide, verfahren zu ihrer herstellung, sie enthaltende mittel und ihre verwendung als schaedlingsbekaempfungsmittel |
DE3907784A1 (de) * | 1989-03-10 | 1990-09-13 | Hoechst Ag | Heteroaryl-aryl-buten- und -butanderivate, verfahren zu ihrer herstellung, sie enthaltende mittel und ihre verwendung als schaedlingsbekaempfungsmittel |
DE4005155A1 (de) * | 1990-02-17 | 1991-08-22 | Hoechst Ag | Konzentrierte waessrige emulsionen von neophanen und azaneophanen zur anwendung im pflanzenschutz |
DE4005153A1 (de) * | 1990-02-17 | 1991-08-22 | Hoechst Ag | Hochkonzentrierte emulgierbare konzentrate von neophanen und azaneophanen zur anwendung im pflanzenschutz |
DE4005154A1 (de) * | 1990-02-17 | 1991-08-22 | Hoechst Ag | Wasserdispergierbare granulate von neophanen und azaneophanen zur anwendung im pflanzenschutz |
WO2013064462A1 (de) | 2011-10-31 | 2013-05-10 | Bayer Intellectual Property Gmbh | Substituierte 4-cyan-3-phenyl-4-(pyridin-3-yl)butanoate, verfahren zu deren herstellung und deren verwendung als herbizide und pflanzenwachstumsregulatoren |
AR089249A1 (es) | 2011-12-19 | 2014-08-06 | Bayer Ip Gmbh | 4-ciano-3-fenil-4-(piridin-3-il)butanoatos sustituidos, procedimientos para su preparacion y su uso como herbicidas y como reguladores del crecimiento de plantas |
Family Cites Families (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3188315A (en) * | 1960-05-18 | 1965-06-08 | Schering Corp | Novel compounds for lowering blood cholesterol levels |
JPS52125170A (en) * | 1976-04-12 | 1977-10-20 | Yoshitomi Pharmaceut Ind Ltd | Pyridine derivatives |
US4397864A (en) * | 1980-05-02 | 1983-08-09 | Mitsuitoatsu Chemicals Inc. | 2-Arylpropyl ether or thioether derivatives and insecticidal and acaricidal agents containing said derivatives |
JPS57116243A (en) * | 1981-01-12 | 1982-07-20 | Yokogawa Hokushin Electric Corp | Measuring element for degree of thermal conduction |
US4562213A (en) * | 1982-05-12 | 1985-12-31 | Sumitomo Chemical Company, Limited | Certain phenoxy-benzyloxy ether derivatives and an insecticidal and/or acaricidal composition containing the same and methods of use |
JPS58201737A (ja) * | 1982-05-18 | 1983-11-24 | Mitsui Toatsu Chem Inc | 新規芳香族アルカン誘導体、その製造法およびそれを有効成分とする殺虫、殺ダニ剤 |
GR79426B (ru) * | 1982-11-16 | 1984-10-22 | Lilly Co Eli | |
JPS59199673A (ja) * | 1983-04-25 | 1984-11-12 | Sumitomo Chem Co Ltd | 含窒素複素環化合物、その製造法およびそれを有効成分とする有害生物防除剤 |
US4664698A (en) * | 1984-09-21 | 1987-05-12 | Sumitomo Chemical Company, Limited | Ether compound, and an insecticidal and acaricidal composition containing it as an active ingredient |
DE3810379A1 (de) * | 1988-03-26 | 1989-10-12 | Hoechst Ag | Azaneophyl- und silazaneophylsulfide, verfahren zu ihrer herstellung, sie enthaltende mittel und ihre verwendung als schaedlingsbekaempfungsmittel |
-
1987
- 1987-04-15 DE DE19873712752 patent/DE3712752A1/de not_active Withdrawn
-
1988
- 1988-03-13 MY MYPI88000367A patent/MY103360A/en unknown
- 1988-04-11 ES ES88105711T patent/ES2053604T3/es not_active Expired - Lifetime
- 1988-04-11 DE DE8888105711T patent/DE3876276D1/de not_active Expired - Fee Related
- 1988-04-11 EP EP88105711A patent/EP0288810B1/de not_active Expired - Lifetime
- 1988-04-11 AT AT88105711T patent/ATE82964T1/de not_active IP Right Cessation
- 1988-04-13 ZA ZA882587A patent/ZA882587B/xx unknown
- 1988-04-13 PH PH36795A patent/PH25946A/en unknown
- 1988-04-13 DD DD88314703A patent/DD273968A5/de not_active IP Right Cessation
- 1988-04-13 US US07/181,705 patent/US4966902A/en not_active Expired - Fee Related
- 1988-04-13 TR TR284/88A patent/TR23440A/xx unknown
- 1988-04-13 NZ NZ224233A patent/NZ224233A/en unknown
- 1988-04-14 HU HU881920A patent/HU202837B/hu not_active IP Right Cessation
- 1988-04-14 IL IL86079A patent/IL86079A/xx not_active IP Right Cessation
- 1988-04-14 RU SU884355559A patent/RU1799242C/ru active
- 1988-04-14 PT PT87246A patent/PT87246B/pt not_active IP Right Cessation
- 1988-04-14 MA MA21489A patent/MA21249A1/fr unknown
- 1988-04-14 DK DK204988A patent/DK204988A/da not_active Application Discontinuation
- 1988-04-14 AU AU14625/88A patent/AU614742B2/en not_active Ceased
- 1988-04-14 BR BR8801785A patent/BR8801785A/pt unknown
- 1988-04-14 KR KR1019880004250A patent/KR880012550A/ko not_active Application Discontinuation
- 1988-04-14 JP JP63090449A patent/JPS63290865A/ja active Pending
- 1988-04-14 CA CA000564118A patent/CA1334198C/en not_active Expired - Fee Related
- 1988-04-15 CN CN88102112A patent/CN1027448C/zh not_active Expired - Lifetime
-
1993
- 1993-01-22 GR GR920402951T patent/GR3006875T3/el unknown
- 1993-11-19 CN CN93114683A patent/CN1091425A/zh active Pending
Non-Patent Citations (1)
Title |
---|
Патент DE №3317908. кл. С 07 С 43/29,1983. * |
Also Published As
Publication number | Publication date |
---|---|
GR3006875T3 (ru) | 1993-06-30 |
PT87246B (pt) | 1992-08-31 |
EP0288810B1 (de) | 1992-12-02 |
CN1027448C (zh) | 1995-01-18 |
DE3876276D1 (de) | 1993-01-14 |
PH25946A (en) | 1992-01-13 |
DK204988A (da) | 1988-10-16 |
EP0288810A1 (de) | 1988-11-02 |
PT87246A (pt) | 1988-05-01 |
BR8801785A (pt) | 1988-11-16 |
ZA882587B (en) | 1988-10-06 |
AU614742B2 (en) | 1991-09-12 |
IL86079A (en) | 1993-01-31 |
CN88102112A (zh) | 1988-10-26 |
JPS63290865A (ja) | 1988-11-28 |
KR880012550A (ko) | 1988-11-28 |
CN1091425A (zh) | 1994-08-31 |
ATE82964T1 (de) | 1992-12-15 |
MY103360A (en) | 1993-06-30 |
AU1462588A (en) | 1988-10-20 |
MA21249A1 (fr) | 1988-12-31 |
ES2053604T3 (es) | 1994-08-01 |
CA1334198C (en) | 1995-01-31 |
DD273968A5 (de) | 1989-12-06 |
IL86079A0 (en) | 1988-09-30 |
US4966902A (en) | 1990-10-30 |
HUT49330A (en) | 1989-09-28 |
NZ224233A (en) | 1990-11-27 |
DK204988D0 (da) | 1988-04-14 |
TR23440A (tr) | 1989-12-29 |
HU202837B (en) | 1991-04-29 |
DE3712752A1 (de) | 1988-11-03 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
KR930007992B1 (ko) | 치환된 실릴기를 갖는 신규 에테르 화합물의 제조방법 | |
KR920003628B1 (ko) | 티아디아자비시클로노난 유도체의 제조방법 | |
JPH0393785A (ja) | 3‐アリール‐ピロリジン‐2,4‐ジオン誘導体類 | |
JPH05201949A (ja) | 1種より多い殺虫活性成分を含む結晶性混合物並びにその製造方法 | |
RU1799242C (ru) | Способ борьбы с насекомыми и клещами | |
JP3137455B2 (ja) | N−アルカノイルアミノメチルおよびn−アロイルアミノメチルピロール殺昆虫および殺ダニ剤 | |
GB2043643A (en) | Phosphorus containing pyrimidine compounds | |
US3332943A (en) | Carbamoylthio derivatives | |
JPS5945649B2 (ja) | 新規有機ホスホロチオレ−トおよびホスホロジチオレ−ト含有殺虫組成物ならびに殺虫方法 | |
PL95242B1 (ru) | ||
IL45780A (en) | Urea thiolphosphonates their preparation and their use in pest control | |
DK142082B (da) | Insecticidt acaricidt og nematodicidt virksomme tert.butyl-substituerede pyrazolyl-(thiono) (thiol)-phossphor (phosphon)-syreestere eller-e-steramider til anvendelse ved plantebeskyttelse og andre tekniske formaal | |
KR20000035479A (ko) | 2-(치환 티오)티아졸로-[4,5-비]피리딘 화합물의 살충 및구충용도 | |
NO811720L (no) | Fremgangsmaate for bekjempelse av insekter, midd og nematoder | |
US4469688A (en) | Pesticidal cyano enol phosphates | |
IE44595B1 (en) | Pesticidal organic phosphorus compounds, processes for theior preparation and compositions containing them | |
JPH01153671A (ja) | 新規チオイミデート及びアミジン殺虫剤 | |
EP0065287B1 (en) | N-containing heterocyclic ring-substituted o-arylphosphate derivatives, preparation thereof, and insecticides containing said derivatives | |
US4582825A (en) | 2-(substituted phenyl)-3-chloro-2-butene thio phosphates as insecticides | |
US3920671A (en) | Certain phosphorus acid esters | |
DK167188B1 (da) | Substituerede heterobicyclooctaner, pesticide praeparater indeholdende saadanne forbindelser, ikke terapeutiske fremgangsmaader til bekaempelse af arthropoder eller orm eller angreb af skadelige organismer samt fremgangsmaade til fremstilling af forbindelserne | |
US3891728A (en) | O-alkyl-S-alkyl-O-substituted phenyl-thiophosphoric acid esters | |
EP0037851A2 (en) | Carboxylates, a process for their production, an insecticidal and/or acaricidal composition and the use of the compounds as insecticides and/or acaricides | |
EP0068823B1 (en) | Novel phosphoro (di or tri) thioate derivatives, pesticidal compositions containing them and the use of the novel derivatives for combating pests | |
CA1037049A (en) | Succinic acid oximidophosphoric esters |