NZ761110A - Spike resistant package and article - Google Patents

Spike resistant package and article Download PDF

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Publication number
NZ761110A
NZ761110A NZ761110A NZ76111018A NZ761110A NZ 761110 A NZ761110 A NZ 761110A NZ 761110 A NZ761110 A NZ 761110A NZ 76111018 A NZ76111018 A NZ 76111018A NZ 761110 A NZ761110 A NZ 761110A
Authority
NZ
New Zealand
Prior art keywords
ore
coarse
flotation
grade
stream
Prior art date
Application number
NZ761110A
Other versions
NZ761168B2 (en
Inventor
Yunzhang Wang
Heather J Hayes
Original Assignee
Milliken & Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US15/671,902 external-priority patent/US10513806B2/en
Priority claimed from US15/671,884 external-priority patent/US10513805B2/en
Application filed by Milliken & Co filed Critical Milliken & Co
Publication of NZ761110A publication Critical patent/NZ761110A/en
Publication of NZ761168B2 publication Critical patent/NZ761168B2/en

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Classifications

    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06NWALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/0056Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the compounding ingredients of the macro-molecular coating
    • D06N3/0063Inorganic compounding ingredients, e.g. metals, carbon fibres, Na2CO3, metal layers; Post-treatment with inorganic compounds
    • AHUMAN NECESSITIES
    • A41WEARING APPAREL
    • A41DOUTERWEAR; PROTECTIVE GARMENTS; ACCESSORIES
    • A41D31/00Materials specially adapted for outerwear
    • A41D31/04Materials specially adapted for outerwear characterised by special function or use
    • A41D31/24Resistant to mechanical stress, e.g. pierce-proof
    • A41D31/245Resistant to mechanical stress, e.g. pierce-proof using layered materials
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/12Layered products comprising a layer of synthetic resin next to a fibrous or filamentary layer
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B3/00Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form
    • B32B3/26Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form characterised by a particular shape of the outline of the cross-section of a continuous layer; characterised by a layer with cavities or internal voids ; characterised by an apertured layer
    • B32B3/28Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form characterised by a particular shape of the outline of the cross-section of a continuous layer; characterised by a layer with cavities or internal voids ; characterised by an apertured layer characterised by a layer comprising a deformed thin sheet, i.e. the layer having its entire thickness deformed out of the plane, e.g. corrugated, crumpled
    • BPERFORMING OPERATIONS; TRANSPORTING
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    • B32B5/00Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/02Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer
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    • B32B5/02Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer
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    • B32B5/24Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being a fibrous or filamentary layer
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    • B32B7/04Interconnection of layers
    • B32B7/08Interconnection of layers by mechanical means
    • B32B7/09Interconnection of layers by mechanical means by stitching, needling or sewing
    • BPERFORMING OPERATIONS; TRANSPORTING
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    • B32B7/04Interconnection of layers
    • B32B7/12Interconnection of layers using interposed adhesives or interposed materials with bonding properties
    • DTEXTILES; PAPER
    • D03WEAVING
    • D03DWOVEN FABRICS; METHODS OF WEAVING; LOOMS
    • D03D1/00Woven fabrics designed to make specified articles
    • D03D1/0035Protective fabrics
    • DTEXTILES; PAPER
    • D03WEAVING
    • D03DWOVEN FABRICS; METHODS OF WEAVING; LOOMS
    • D03D13/00Woven fabrics characterised by the special disposition of the warp or weft threads, e.g. with curved weft threads, with discontinuous warp threads, with diagonal warp or weft
    • D03D13/008Woven fabrics characterised by the special disposition of the warp or weft threads, e.g. with curved weft threads, with discontinuous warp threads, with diagonal warp or weft characterised by weave density or surface weight
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F41WEAPONS
    • F41HARMOUR; ARMOURED TURRETS; ARMOURED OR ARMED VEHICLES; MEANS OF ATTACK OR DEFENCE, e.g. CAMOUFLAGE, IN GENERAL
    • F41H5/00Armour; Armour plates
    • F41H5/02Plate construction
    • F41H5/04Plate construction composed of more than one layer
    • F41H5/0414Layered armour containing ceramic material
    • F41H5/0428Ceramic layers in combination with additional layers made of fibres, fabrics or plastics
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F41WEAPONS
    • F41HARMOUR; ARMOURED TURRETS; ARMOURED OR ARMED VEHICLES; MEANS OF ATTACK OR DEFENCE, e.g. CAMOUFLAGE, IN GENERAL
    • F41H5/00Armour; Armour plates
    • F41H5/02Plate construction
    • F41H5/04Plate construction composed of more than one layer
    • F41H5/0442Layered armour containing metal
    • F41H5/0457Metal layers in combination with additional layers made of fibres, fabrics or plastics
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F41WEAPONS
    • F41HARMOUR; ARMOURED TURRETS; ARMOURED OR ARMED VEHICLES; MEANS OF ATTACK OR DEFENCE, e.g. CAMOUFLAGE, IN GENERAL
    • F41H5/00Armour; Armour plates
    • F41H5/02Plate construction
    • F41H5/04Plate construction composed of more than one layer
    • F41H5/0471Layered armour containing fibre- or fabric-reinforced layers
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    • B32B2260/02Composition of the impregnated, bonded or embedded layer
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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Ceramic Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • General Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Laminated Bodies (AREA)
  • Separation Of Solids By Using Liquids Or Pneumatic Power (AREA)
  • Woven Fabrics (AREA)

Abstract

A spike resistant package (10) comprising a pouch (100) having an inner surface and an outer surface, and a first grouping (200) of spike resistant textile layer. The grouping has a first side (200a), a second side (200b), and comprises plurality of spike resistant textile layers (210). Each spike resistant textile layer comprises a plurality of interwoven yarns or fibers having a tenacity of about 14 or more grams per denier. The package further comprises a slip layer (300) having a thickness of less than about 0.1 mm, a stiffness of less than about 0.01 N-m, and a static coefficient of friction (COF) between the slip layer and the second side of the first grouping of less than about 0.40. The slip layer is located on the second side of the grouping of spike resistant textile layers. The pouch fully encapsulates the grouping of spike resistant textile layers and the slip layer, and the slip layer and the inner surface of the pouch are in direct and intimate contact. The invention provides a flexible light weight structure that resists penetration by spike-like threats, wherein the slip layer provides improved spike resistance compared with prior art multi layer fabric devices.

Description

Maximise the Vaiue of a Sulphide Ore Resource through Sequential Waste Rejection BACKGROUND TO THE INVENTION Sulphide ores containing metais such as copper, gold, platinum group metais, nickel, lead and zinc are recovered commerciaiiy by fine grinding and flotation to concentrate the valuable component and discard the gangue.
The conventional process es grade l drilling to delineate the ore, blasting the necessary waste (below economic cutoff-grade (00(3)) and ore, ioading trucks to haui the ore for primary crushing and the waste to a. disposal area. The crushed ore is conveyed to a miiling process, typicaliy using semi-autogenous grinding (SAG) or high pressure grinding rolls (HPGR); foilowed by bali miiiing to fuily liberate the valuable particles at a p80 of around 75—200 micron. Then the ore is ted using a flotation process to produce a saleabie concentrate and taiiings. The gs from flotation are pumped to a taiiings storage facility (TSF) and stored in perpetuity.
As the conventional process chain requires ali of the ore to be ground finely, it consumes large quantities of energy (typicaliy ZOkwhl’t ore) and water (0.5-1.0 tonne water per tonne of ore). The majority of this water is lost in the fine tailings, where it is intimately mixed and retained with the very fine residue produced from the conventional flotation process.
The shortage of available water in some ons has generated different approaches to water saving. Some mines have instailed desalination piants on the adjacent coast, and pumped the nated water to the processing ty. Others have instailed large filter s to squeeze as much water from taiiings as possible. However these solutions both suffer very high 2017/053963 capitai and operating costs. The high cost of fine grinding and high water consumption aiso means the recovery efficiency of the in~ground resource is limited to that which is economic to process.
At any particular time in the mine iife, the (DOS for ore is set to maximise the feed grade and hence production from the avaiiabie processing capacity.
This CoG may be variously constrained by available water, or tailings capacity, or the instalied processing capacity. Whichever constraint applies, ically attractive ore is often being rejected to a waste pile, simply because higher grade materials are available at the time. Even if a low grade ile is introduced to manage the material which is above economic processing grade but beiow the 008 of the day, the materials handling cost of iling and reclaiming this marginally attractive material iater in the mine life, impiies a fraction of the economic resource wiil be lost to the waste rock piie.
If the run—ofnmine ore couid be beneficiated prior to fine grinding, to reject as waste material which is below economic cutoff-grade, with a high recovery of the values and a reasonabiy high upgrade ratio, and in a relatively low cost operation, the unit costs and consumption of water would be reduced. The consequential grade of feed to processing wouid be increased. And the grade of any stockpile required by a constraint to ble processing ty would be higher, resuiting in improved margins when eventuaily recovered. ising the value associated with removing a fraction of the ore that is below 606, and preferably beiow economic treatment grade, various beneficiation techniques have been proposed. For sulphides, these are y based around gravity techniques such as dense media separation, spirais, etc, and rock sorting methods. But for most suiphide ores, these beneficiation ques iaii either the upgrade ratio/recovery or cost hurdles for implementation. 2017/053963 if the beneficiation parameters are set to reject sufficient ore (i.e. achieve a high upgrade ratio) to economically warrant the cost of the beneficiation process, the loss of values is excessive. This means an increase in mining cost per tonne of product, and a decrease in the effective utilisation of the overall ce.
Hence run of mine (ROM) ores are conventionally ground to very fine sizes to achieve complete liberation of the valuabie components then floated, despite the obviously high cost of comminution and water consumption.
Recently, the y to use a chemically based coarse ion process for beneficiating sulphides, using a fit for purpose ion cell has been proposed by Eriez ion Division (EFD), a wholly owned subsidiary of Eriez Manufacturing Co. Using this coarse flotation technology, the ability to dry stack sand residue was recognised, thus opening up another potential beneficiation technique to reduce water and energy 6l170437). As a one off process for water recovery, it is very useful, but due to particle size vs. recovery constraints on coarse flotation, and the size separation precision of hydrocyciones, only 30—50% of the ore ends up as sand. Hence water consumptions and tailings volumes are typically only reduced by some 25-40%. in a second beneficiation technique for sulphidic ores, the differential fracture along the mineraiised grain boundaries, g most of the sulphides to concentrate in'the finer size ranges, has been recognised.
The differential fracture enables screening to reject the coarsest rocks, which usually contain the lowest grade. This technique was first uced in Bougainville in the late 19808 (Australasian ute of Mining and Metallurgy, Papua New Guinea Minerai Development Symposium, 27-28 June 1986, Madang, The Application or centration by Screening at Bougainville Copper Limited, Bums RS and Grimes AW, the content of which is incorporated herein by reference). The beneficiation technique is being actively reexamined by a number of operations under the CRC Ore trademark of ‘Grade Engineering'. CRC ORE is a not for profit organisation funded by the Australian l Government and the giobal minerals ry httg:!lwww.crcore.orgau/mainlindex. phpleatutions/grade engineering.
And finally, beneficiating using bulk sorting has aiso been proposed. The development of s that can adequately determine average grades on a conveyor belt or shovel at a high rate, allows for the stream of broken rock to be identified and diverted to either ore or waste. Reference: Valery etai. World Mining Congress 2016; Minesense http:/Iwww.minesensesomlgroducts : The SenseTM shovel product is a real-time mineral telemetry and on support system for surface or underground applications. it is a retrofit package installed in the dipper of surface shovels or into the scoop of underground machines such as rams or LHD’s. The ShovelSense"M platform is used for: Measurement of ore quality while material is being scooped into the dipper; Reporting of ore quality and type to the grade controi/ore routing system Realutime, oniine decision support for orelwaste dispatch decisions.
Buik sorting takes advantage of the natural heterogeneity of ies, with the tion of zones of high and low grade material that would conventionaliy be mixed into homogenised run~ot~mine ore. The weakness of bulk sorting is it can only reject those zones that are low grade at the time of sensing, and hence to retain an acceptabie upgrade ratio it must be installed prior to significant homogenisation of the ore.
Despite these three recent and quite distinct beneficiation ques being reiativeiy well known, none has yet found widespread use in the mining industry. This may be at least partialiy attributed to the same upgrade ratio, recovery, and cost reasons that have hampered the implementation of traditionai gravity based beneficiation. in summary, the mining industry is very capital intensive, a iarge er of water and energy, and oniy partialiy recovers the values contained in the earth that is mined. Whilst beneficiation techniques are known which can potentially address these issues, they have been ered in isolation to resolve each constraint individually, and mostly found to be uneconomic.
SUMMARY OF THE lNVENTlON According to the present invention there is provided an integrated process for recovering vaiue metals from sulphide ore, including the steps of: a) obtaining a crushed ore; b) bulk sorting and screening the d ore to provide a sortedlscreened coarse ore stream and a waste ore stream; c) subjecting the sorted/screened coarse ore stream to grinding in a mill foliowed by classification to provide a coarse fraction suitabie for coarse flotation and a first tine fraction suitable for conventional ion; d) subjecting the coarse fraction suitable for coarse flotation to coarse ion thereby to obtain a gangue and an ediate concentrate; e) subiecting the ediate concentrate to grinding to provide a second fine traction suitable for conventions! flotation; and f) subjecting the first fine fraction and the second tine fraction to conventional flotation to e a concentrate and tailings.
Preferably, blending of the crushed ore is limited, for example to a truck load or shovel load, in order to limit homogenisation of the ore prior to step At step a), the ore is preferably crushed to a size suitable for tation on a conveyor, as a feed to a subsequent grinding stage, and is typically in the range of 5 to 40 cm.
The bulk sorting in step b) may be on a buik sorter comprising a or beit with a diverter mechanism lled by a continuous analysis sensor, wherein the diverter mechanism diverts low grade zones of rock which do not meet a selected cut off grade (COG) to the waste . The continuous analysis sensor preferabiy comprises a rapid scanning , preferably a magnetic resonance or neutron activation or X-ray sensor. in step b), the crushed ore may be subjected to buik sorting followed by screening or screening ed by bulk sorting.
Preferably, at step b), the crushed ore is subjected to bulk sorting to provide a sorted coarse ore stream which is subjected in to grinding in step c), and a first waste ore stream.
Advantageousiy. the sorted coarse ore stream is screened to e a screened coarse ore stream which is ted to grinding in step c), and a second waste ore stream.
Typicaiiy, the size of screen apertures of a screen used to screen the coarse ore stream are selected to provide a screened coarse ore stream that is about 80-90% by weight of the coarse ore stream from bulk sorting.
Preferably, at step b), the first waste stream is screened to provide a third waste ore stream and a higher grade fraction that is sent for grinding in the grinder at step c) together with the sortedlscreened ore stream.
Typically, the size of screen apertures of a screen used to screen the first waste ore stream are ed to recover from 15—25% by weight of the stream.
At step c), the ore is preferably ground in ciosed loop with a ciassification circuit, to aliow scatping of material that is already reduced to the appropriate size ranges for coarse and conventional flotation.
At step c), the ore is preferably subjected to fication to provide a coarse fraction suitable for coarse flotation with a size of 100 pm up to 1000 pm, preferably 150 pm up to 800 pm, most preferably from 200 pm up to 600 pm, and a first fine traction suitable for conventional flotation with a size of less than 100 pm, typicalty less than 150 pm, preferably less than 200 pm.
At step e), the intermediate concentrate is abty ground to a size of less than 150 pm to provide a second tine fraction suitabie for conventional flotation. ably, a natural grade recovery curves is determined for the ore, and each of the following beneficiation steps: i) buik sorting; ii) screening; iii) coarse flotation; is arranged and controlled to permanently reject the maximum quantity of waste at a grade fess than an economic cut-off—grade.
The beneficiation steps: i) buik sorting; ii) screening; iii) coarse flotation; may be further arranged and controlled to also separate a low grade ore suitabte for stockpiiing or heap leaching, and hence produce a high grade feed to fitl the availabte comminution and tional ion capacity.
For the constraints of a particular mining asset, the design and set points are further selected for each ciation step, to: . optimise the production of the whoie mining and processing asset system, within the constraints of water or taiiings e capacity; and l or WO 34855 . optimise the capital costs of productive assets and infrastructure in a new or expanded mine; and I or . optimise the recovery of mineral vaiues from an orebody; and I or . optimise the overall operating costs per tonne of product by ultimateiy rejecting the maximum waste, at less than the economic cut off grade (CoG) for retreatment.
Preferabiy, nisation is minimised prior to bulk sorting to maximise the removal of gangue.
Screening may be used specificaily to scavenge the higher grade fines from the reject stream of bulk sorting Screening may aiso be used specificaiiy to scavenge the lower grade coarse materiai from the ore product stream of bulk sorting.
BRiEF DESCRIPTION OF THE DRAWINGS Figure 1 is a flow diagram of a beneficiation s according to an ment of the invention; Figure 2 is a graph g a grade tonnage curve for buik g of a typical copper porphyry ore; Figure3 is a graph of the upgrading achievable by screening at various proportions of a i copper porphyry ore Figure4 is a decision tree for a typical process design for an embodiment of the invention; and Figure 5 is a graph iilustrating the potential impact of the process of the present invention on power consumption, water consumption, and tailings generation in comparison with a conventional crushing, grinding and flotation process.
DESCRIPTiON OF PREFERRED EMBODIMENTS The present invention relates to a process that capitaiises on the natural heterogeneity of sulphide ies, and utilises beneficiation technologies in a novel muttistage configuration to reject the maximum quantity of waste gangue prior to fine comminution. This rejected gangue is normally below economic reprocessing grade (ie. waste) but might also be in the form of a feed to heap leach; or in the form of a low grade stockpile for treatment later in the mine life (grade profiling).
The exact quantum of ts will be dependent on the grade ry characteristics of a particular orebody. However, using ation of the techniques, the water and comminution energy consumption are typically reduced by 50-80% at the same mining cut—off—grade (CoG). Alternatively, the mining f—grade can be reduced. extending the life of mine, and achieve only ly lower reductions in overall water and energy consumption. The invention also enables unit costs of production, capital and operating, to be significantly reduced, and where appropriate the profile of tion to be brought forward to e the return on invested capital.
A simplified block flowsheet of one embodiment of the invention is shown in Figure 1. An orebody is mined 12 and fed to a primary crusher 14, from where it is bulk sorted to to provide a sorted coarse ore stream 18 for grinding and fying 20 and a sorted waste stream 22. A screen 24 recovers a high grade finer fraction 26 from the sorted waste stream 22, and this rejoins the high grade stream for grinding and classifying 20. If the sorted coarse ore stream 18 from buik sorting 16 is sufficiently low grade, it can be similarly screened 28 to reject the coarsest material 30 to the waste or low grade stockpile 32. Classification splits the ore after partial grinding into a coarse product stream 34 suitable for coarse flotation 36 and a fine product stream 38 suited to proceed direct to flotation 40. The coarse fiotation process 36 then rejects further gangue 42 to a sand iie 44, with an intermediate concentrate 46 being reground 48 to proceed to tional fiotation 40. A concentrate 50 and gs 52 are ed from the conventional flotation 40.
Thus, low grade materiai 32 and 44 is rejected from the sorter/screen combination 16/24128, and from the coarse flotation 36, thus requiring only a proportion of the original ore to be finely ground to achieve the full liberation required to produce a saieable concentrate.
The variable nature of ore mineralogy and/or mine designs, means that deportment of the values will be different at each mine. For exampie at occasional mines, it may be possible to reverse the screening and bulk sorting, whilst stili retaining the naturai ore heterogeneity. In this variant, the fine al from screening would proceed to ng, and the coarse fraction would be bulk sorted to reject waste. The system design would be such as to minimise nisation during sorting.
And for some mines with particularly attractive grade recovery curves for one or two of the beneficiation techniques, it may be economicaily more appropriate to utiiise only some of the components of the muiti-stage novel processing chain that is the subject of this invention.
The grade recovery curve for bulk sorting is weii suited to waste removai, providing the nature! spatial heterogeneity of the orebody is retained.
Screening is well suited to ging vaiues (the tines) from low grade streams, but only for occasionai orebodies does the selective fracture enable high recoveries and immediate rejection of waste. Coarse ion is well suited to rejection of waste with a high recovery, albeit after partial comminution.
First Comgonent —~ Bulk Sorting The first component beneficiation step in the most common configuration of this invention. is bulk g. Ore that has been fragmented by blasting, is transported by truck or conveyor to a primary crusher, and by conveyor to grinding. On the conveyor either before or after the primary crusher, the grade of the ore (or rious contaminants) can be anaiysed, using techniques such as magnetic resonance, for example an cit—conveyor MR Analyser for a species other than chaicopyrite being devetoped by CSERO in collaboration with CRCOre, which will resuit in the on-conveyor MR technology attaining a TRL 4 for detection of ed alcopyrite mineral s httgzllwww.crcore.org.au/mainlimages/snagshotlgroiects/CRC-ORE~ Sna shot---Research~i.003-«Buik-sensin with-ma netic-resonance. cit- or neutron activation, for e a cross belt analyser avaiiabie from SODERN which makes use of a CNA (Controiled Neutron Analyser) using an ical neutron source with stabilised emission httg:liwww.sodern.comlsiteslenlret/Cross-belt—Anatyser 7t.htmi, aliowing a decision to divert the stream of rock to ore or to waste. NA is a nuclear process used for determining the concentrations of elements in a vast amount of materials. CNA aliows discrete sampling of elements as it disregards the chemical form of a , and focuses solely on its nucleus.
By minimising homogenisation wherever possible in the materiais handling, the high and tow grade zones of ore are retained almost intact. This point of analysis for bulk sorting may be before or after the y crushing ing on the nature of fragmentation in blasting. But the bulk sorting must be located prior to a SAG or bait mitt where biending and recirculating loads eliminate the heterogeneity. Any intermediate stockpiles between the mine and the bulk sorter shouid aiso be avoided.
These zones of high and low grade rock, when loaded on the conveyor belt, translate into corresponding iengths. Some sections along the iength of the loaded conveyor belt are below the economic processing cut-oft: grade, while others are made up from the high grade zones. Based on the continuous sensor analysis, a diverter mechanism is used to divert those iow grade lengths of rock, which do not meet the desired COG, to a separate waste stream.
The typical grade tonnage curve for bulk sorting will be very dependent on the orebody geneity, h retaining this natural zonai heterogeneity and using a rapid scanning sensor, the effective g lot size is considerably smalier than the l 20~25rn grid used for conventional in—pit grade l. (in conventions? grade control, everything in this grid being averaged and deciared as either ore or waste). Thus, the buik sorting process discriminates more accurately between waste and ore than tional grade control.
The quantity of rock that is below f~grade, and hence can be removed from conventional ore can be estimated from gee-statistical analysis of drill core. Assuming the rock is homogenised at the granularity of a 300i truck delivered to the conveyor, a grade tonnage curve is iilustrated in Figure 2, for a typical copper orebody in Chile, illustrates that up to 25% of the run- of—rnine ore can be rejected as waste.
An even more amenable Piatreef pgm ore from South Africa can yield up to 40% waste ion at below the processing COG. Similarly, a reasonably homogeneous porphyry copper RoM from Peru, can yield up to 20% waste at beiow the 0.25% COG.
Optionally, the process can be configured such that one stream from the first diverter can be further sorted, using a second diverter system. This technique can be used to create three fractions (high grade stream for immediate processing: and lower grade stream of ore to be stockpiled, or heap leached: and a waste stream). This grade profiting technique is idealiy suited where mining costs are modest relative to processing, and the orebody is iarge enough to t retreating of the lower grade fraction at some later date. if water is highiy constrained, this enabies high production in early years (grade ing) within an available water constraint.
Minimlsing the ievei of blending that occurs prior to this bulk sorting sensor and diverter is ant to maximise the rejection of low grade ore. The partially blended lot size (eg. a truckload) that can be analysed and diverted is smaller than that achievable with the spacing of normal grade control drilling. Due to natural orebody heterogeneity, a significant proportion of the tional RoM feed is below the mine COG, and can be diverted to waste or assigned to a tow grade stockpile.
This eariy rejection of a waste stream that would otherwise be processed as ore, has implications for both resource ation and costs. The waste is no longer ground (energy savings) and is stored dry (water savings). The separation efficiency of bulk sensing is better than grade controi driiling and seiective loading, so that this grade control activity can be limited to delineating the ultimate pit shell, saving further costs and simplifying mining activities. The removal of waste means that unit costs of sing are reduced. and hence a lower COG can be used for this te pit shell.
Thus the overall ation of the resource endowment can be improved.
Second Component - Screening in the second component of the muitiple beneficiation steps that make up this invention, one or both of the waste and ore streams from butk sorting are ed. Sulphide ores selectively fracture along the mineralised grain boundaries during biasting and crushing. As such the finest fraction of the rocks in any ore zone will be of a higher grade.
If an ore exhibits a significant selectivity, the waste stream from the bulk sorting is screened to further separate the higher grade, finer fraction.
These smaller rocks, are ed in the ore stream. An example of this is shown in Figure 3 for a reasonably selective Chilean copper ore, where the finest 10—20% of the ore. typically exhibits around twice the grade of the ing 8043096 of the ore. Thus a screening process is used to scavenge those fines, which are higher than the processing cut~off-grade., from the reject stream from bulk sorting. As such, the grade of the waste discard stream is further reduced, thus improving overall resource recovery.
Depending on the particular grade recovery curves for any ore, the set points for each beneficiation process can be selected to optimise the waste rejection by the overall butk sorting/screening system. ing on the selectivity of fracture of the particutar ore, this screening will typically require a screen aperture to recover around 15-25% by weight of the low grade stream. The coarse fraction ds to waste.
The high grade ore stream from y crushing also contains a mix of rock sizes. Due to selective fracture that occurs in blasting, and any crushing undertaken prior to the bulk sorting, the highest grade is concentrated in the finer fraction of rock. Removal of the lower grade coarsest rocks by screening can result in further ing of the feed to comminution. Whilst it may be unusual for such coarse material in the reject stream to be below economic processing grade, this fraction may be well suited to heap leach or low grade ile. lf screening of the coarsest rocks is applicable, the high grade fines stream will typically be around 80-90% of the total feed from bulk sorting. However for those ores where selective fracture is not pronounced, this high grade screening will not produce a sufficient grade differential to warrant the lower grade coarse material being rejected, and hence the screening of the bulk sorted ore will simply not be implemented.
The combined system of bulk sorting and screening of the high and low grade streams will have ent m set-points for each ore to be treated, and for the economic drivers of each mine. lt is apparent to those skilled in the art, that the set-points of the system can readily be sed to produce the maximum grade for comminution, while rejecting the m rock that is at or below the economic cut-off~grade for processing.
Third Component — Coarse Flotation The third stage of the multistage beneficiation is coarse particle flotation.
This process utiiises the geneity at the sand (sub 1mm) size level, for a chemically ed gravity separation. The partially ground ore is fied to produce a sand fraction, which is beneficiated using a fit for e flotation machine such as the Erie}:TM Hydrofioat. The Eriez Hydrofioatm, s out the concentration process based on a combination of fluidization and flotation using fiuidization water which has been aerated with micro—bubbles of air. The flotation is d out using a suitable activator and collector concentrations and residence time, for the particuiar mineral to be floated. At this size, the ore is sufficientiy ground to liberate most of the gangue and expose but not necessarily fully liberate the valuable mineral grains. The coarse flotation recoveries of partiaily exposed mineralisation is high, and the residual gangue forms a sand which does not warrant further comminution and conventional flotation. The reject sand from coarse flotation can be d and drained to recover water.
The system used to select a suitabiy sized feed for coarse flotation utilises ciassitication devices such as cyciones or lic classifiers to scalp that on of the stream that is suited to conventional flotation. in a typical configuration for this third beneficiation component, the material at a size less than the upper size iirnit for coarse flotation is separated from the bait miil circulating toad. This stream can then be further classified to separate the materiai that is already ground to below the lower bound for coarse flotation, and this finer fraction is sent directly to conventionai flotation. This creates the feed to coarse flotation at a size in which the residue which is ‘free draining’. in the normai configuration, the coarse flotation size range wiil be bounded by the maximum size where the vaiuabie minerals are sufficiently exposed to be floated, with sufficient recoveries such as to produce a sand residue suitable to discard. The minimum size is set by the particle size at which the coarse fiotation machine can operate efficiently to produce a free ng sand for disposal. Depending on the mineralogy, the fracture characteristics of the ore, and the design of the classification circuit; this lower size range is lly around 100—200 microns, and the upper size is typically n 350 and 600 micron. Depending on the size range for coarse flotation, and the classification efficiency. this scalping captures for coarse flotation between 40—60% of the total feed to comminuticn, with the remainder ing to tional flotation. in a conventional froth fiotation process, particle sizes are typicaily fess than 0.1 mm (100 pm). The ore particles is mixed with water to form a slurry and the desired mineral is rendered hydrophobic by the addition of a surfactant or coilector chemicai. The particular chemical depends on the nature of the l to be recovered. This slurry of hydrophobic les and hydrophilic particles is then introduced to tanks known as flotation cells that are aerated to produce bubbles. The hydrophobic particles attach to the air bubbles, which rise to the surface, forming a froth. The froth is removed from the calf, producing a concentrate of the target mineral.
Frothing agents, known as frothers, may be introduced to the slurry to promote the formation of a stable froth on top of the flotation cell. The minerals that do not float into the froth are referred to as the flotation tailings orflotation tails. These tailings may also be subjected to further stages of flotation to recover the valuable particles that did not float the first time. This is known as scavenging.
The undersize from the fication is ideally sized for conventional ion, as it does not suffer significantly from the poor ries that most conventional flotation exhibits with particles above around 200 micron.
The oversize from the initiai classification of the bail mill recirculating load (above the upper bound selected for coarse flotation) is recycled for r comminution. Due to the extended size range that is scalped, the comminution energy is significantly reduced.
The sand residue from coarse flotation has a tow exposed sulphide content. it represents 7043096 of the scalped coarse flotation feed. It has a sufficiently high hydraulic conductivity and can be hydrautically stacked and drained to recover the water.
The intermediate concentrate produced by coarse flotation is the remaining -30% of the coarse flotation feed. This requires regrinding to fully tiberate the minerals, prior to conventional flotation in either the rougher section of conventional flotation along with the fines fraction from the ball mill classification, or direct to the conventional r cells. in a variant to coarse flotation, the size fraction of the feed to coarse flotation can be widened at the upper end to say 0.84.5mm. This variant of the invention is typically utilised when the throughput of the overall mine is constrained by the fine grinding, conventional flotation, or taiiings storage process, including total available water to the mine. in this variant, a greater proportion of the ball mili recirculating load is scalped and ciated, aibeit that the coarse fraction of the coarse flotation residue will not be of a grade that can be discarded directly. Some but not most of the st feed material has exposed sulphide surfaces that will float. Thus the coarse fraction is partialiy denuded of its values, albeit not sufficiently to justify immediate assignment as waste." 80 the overall residue from coarse ion, is r classified to te the partiatly denuded coarse sand that is above the normally selected upper bound for optimum recovery in coarse flotation. This partially denuded coarse material can then be dry d for processing tater in the mine life. In this variant the hput ty of the ball mills is r increased, and the consequential grade profiling enables higher production from conventional ion early in the mine tife.
Integration of the Beneticiation System By configuring bulk sorting and screening and coarse flotation, the benefits of zones of high and low grade ores, and the differential deportment of mineral values during fragmentation, and the ive liberation and separation of gangue, are synergistic. Bulk g utilises the naturai heterogeneity at the ore zone level. Screening es the natural heterogeneity at the individual rock level. And coarse fiotation captures the heterogeneity at the sand level. The tial steps are also compensatory, in that there can be a second, modest cost, backstop to avoid permanent disposal of values that may have found their way into the wrong stream in a prior beneficiation step, and reject gangue which has been misplaced into the values stream.
Whilst the multi-stage ciation s may be configured in various ways, the most ic decision for a long life mine is usually to maximise tion from existing assets. The decision tree illustrated for this case in Figure 4, is an example of the design principles that can be applied, and the associated rational for selection of set-points.
In Figure 4, the reference numerals indicate: 80 mine, 82 is the Ore above Processing 008?, 64 No, 66 Yes, 68 Waste, i’O Bulk Sort to reject waste, 72 Screen to scavenge vaiues, 74 Set points are seiected (bulk sensor setting and screen size) to maximize the waste rejection at a grade below ic 008, 78 is the available tonnage > processing capacity?, 78 Yes, 80 No, 82 Second stage bulk sort (and/or screen), 84 Classification and CPF, 86 Conventionai flotation, 88 Low grade stockpiie, 90 is throughput further constrained eg. water/tailing?, 92 Yes, 94 No, 98 fication to recover oversize, 98 Set points are selected for classification sizes to maximise grade and tonnage to conventional flotation whilst maintaining high overali processing recovery.
The exact distribution of beneficiation steps and their set~points for every y and every optimised business case will be different. As an example, Figure 5 iliustrates the potential impact on power consumption, water consumption, and tailings generation in an atternative configuration of the invention which is directed to increasing mine life, whiist continuing to save water and energy and se production. Through the invention, a tion of what would be permanently discarded in—pit and expanded pit mineraiised waste in a tionai mine, is now converted to ore (i_e. above the economic CoG). The expanded source of ore is sorted and screened to reject a substantive fraction of the ore as a waste (‘in pit waste rock' which is below the economic processing CoG). CPF s further waste as dry stacked sand, thus the quantity of ore progressing to fine comminution for conventional flotation is considerably reduced. Since most of the energy and water consumption is attributable to the requisite amount of fine grinding required for conventionai flotation (illustrated by the height of the tailings bar), the water and energy consumption per unit of product is more than halved, and the tits of the resource is extended. in summary, by combining the three beneficiation processes, each of which relies on a different form of ore heterogeneity; the invention achieves a greater recovery of the vaiues in an orebody through reducing the processing cut-off-grade, and enables more of the gangue to be discarded in dry form, and the potentiai for a low grade ore to be stockpiied prior to fine grinding later in the mine life. This in turn s the water consumption and ution energy, and reduces the amount of taiiings tion to a modest proportion of the originai ore. The resultant operating costs are d, and capital productivity of the processing facilities is much enhanced.
Advantages of the process of the present invention are: . Requirements for grade control activities in pit are sed, enabling simpier .
- The grade of ore to grinding may be increased by more than 10%, and more preferably by 20% and most preferably by more than %.
WO 34855 2017/053963 . The ultimate economic cutoff-grade for mining of an orebody may be d by more than 10% and preferably by more than 20%, and more preferably by more than 30%.
. The total amount of fine tailings produced from the conventionai run-of—mine ore may be reduced to tess than 50% of those resutting from conventionat processing technology, and preferably less than 40%, and even more preferably iess than 30%.
. The totat amount of energy used in comminution may be reduced to less than 50% of that resulting from conventional processing, and preferably less than 40%, and even more preferably less than 30%.
. The total amount of water consumed in taitings may be reduced to less than 50% of those resulting from conventional processing, and preferably less than 40%, and even more preferably less than 30%.

Claims (22)

1. An integrated process for recovering value metals from sulphide ore, including the steps of: a) obtaining a crushed ore; b) bulk sorting and screening the d ore to provide a sorted/screened coarse ore stream and a waste ore stream; c) subjecting the sorted/screened coarse ore stream to grinding in a mill followed by classification to provide a coarse fraction suitable for coarse flotation and a first fine fraction le for conventional flotation; d) subjecting the coarse fraction suitable for coarse flotation to coarse flotation thereby to obtain a gangue and an intermediate concentrate; e) subjecting the intermediate concentrate to ng to provide a second fine fraction suitable for flotation; and f) subjecting the first fine on and the second fine fraction to conventional flotation to e a concentrate and tailings.
2. The process claimed in claim 1, wherein, at step a), the ore is crushed to a size suitable for presentation on a conveyor, as a feed to grinding stage at step c).
3. The s claimed in claim 2, wherein, at step a), the ore is crushed to a size in the range of 5 to 40 cm.
4. The s claimed in any one of claims 1 to 3, wherein bulk sorting in step b) is on a bulk sorter comprising a conveyor belt with a diverter mechanism controlled by a continuous analysis sensor, wherein the diverter mechanism s low grade zones of rock which do not meet a selected cut off grade (CoG) to the waste stream.
5. The process claimed in claim 4, wherein the uous analysis sensor comprises a rapid scanning sensor.
6. The process claimed in claim 5, wherein the sensor is a magnetic resonance or neutron activation or an X-ray sensor.
7. The process claimed in any one of claims 4 to 6, wherein the cut off grade (CoG) is determined from geo-statistical analysis of drill core from the source of the ore.
8. The process claimed in any one of claims 1 to 7, wherein, at step b), the crushed ore is subjected to bulk g followed by screening or screening followed by bulk sorting.
9. The process claimed in any one of claims 1 to 8, wherein, at step b), the crushed ore is subjected to bulk sorting to provide a sorted coarse ore stream, which is subjected in to grinding in step c), and a first waste ore .
10. The process claimed in claim 9, wherein the sorted coarse ore stream is screened to provide a ed coarse ore stream, which is subjected to grinding in step c), and a second waste ore stream.
11. The process claimed in claim 10, wherein the size of screen apertures of a screen used to screen the coarse ore stream are selected to e a screened coarse ore stream that is about 80- 90% by weight of the coarse ore stream from bulk g.
12. The process claimed in claim 10 or 11, wherein, at step b), the first waste stream is screened to provide a third waste ore stream and a higher grade fraction that is sent for grinding in the grinder at step c) together with the sorted/screened ore stream.
13. The process claimed in claim 12, wherein the size of screen apertures of a screen used to screen the first waste ore stream are selected to recover from 15-25% by weight of the .
14. The process claimed in any one of claims 1 to 13, wherein, at step c), the ore is ground and classified to separate a size of less than 1000 micron.
15. The process claimed in any one of claims 1 to 14, wherein, at step c), the ore is ground in closed loop with a classification circuit such that material that is already d to the appropriate size ranges for coarse and conventional flotation can be scalped.
16. The s claimed in claim 15, wherein, at step c), the ore is subjected to classification to provide a coarse fraction suitable for coarse flotation with a size range of 100 µm up to 1000 µm, and a first fine fraction suitable for conventional flotation with a size of less than 100 µm.
17. The process claimed in claim 16, wherein, at step c), the ore is subjected to classification to provide a coarse fraction suitable for coarse flotation with a size range of 150 µm up to 1000 µm, and a first fine fraction suitable for conventional flotation with a size of less than 150 µm.
18. The process claimed in claim 17, n, at step c), the ore is ted to classification to provide a coarse fraction suitable for coarse flotation with a size range of 200 µm up to 1000 µm, and a first fine fraction le for conventional flotation with a size of less than 200 µm.
19. The process claimed in any one of claims 1 to 18, wherein, at step e), the intermediate concentrate is ground a size of less than 150 µm to provide a second fine fraction suitable for conventional flotation.
20. The s claimed in any one of claims 1 to 19, in which l grade recovery curves are determined for the ore, and each of the following beneficiation steps: iv) bulk sorting; v) screening; vi) coarse flotation; is arranged and lled to permanently reject the maximum quantity of waste at a grade less than an economic cut-off-grade.
21. The process claimed in claim 20, in which the beneficiation steps iv) bulk sorting; v) screening; vi) coarse flotation; are further arranged and lled to also separate a low grade ore suitable for stockpiling or heap leaching, and hence produce a high grade feed to fill the available comminution and conventional flotation capacity.
22. The process as claimed in claim 1, substantially as herein described with reference to any one of the
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US15/671,884 US10513805B2 (en) 2017-08-08 2017-08-08 Spike resistant package and article
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