NO812190L - Katalysator. - Google Patents

Katalysator.

Info

Publication number: NO812190L
Authority: NO; Norway
Prior art keywords: carbon atoms; phosphite; compound; titanium; titanium halide
Prior art date: 1980-06-27

Application number

NO812190A

Other languages

English (en)

Norwegian (no)

Inventor

Ronald Alan Epstein

Robert Mink

Original Assignee

Stauffer Chemical Co

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1980-06-27

Filing date

1981-06-26

Publication date

1981-12-28

1981-06-26 Application filed by Stauffer Chemical Co filed Critical Stauffer Chemical Co

1981-12-28 Publication of NO812190L publication Critical patent/NO812190L/no

Links

239000003054 catalyst Substances 0.000 title claims abstract description 47
-1 titanium halide Chemical class 0.000 claims abstract description 97
239000010936 titanium Substances 0.000 claims abstract description 54
229910052719 titanium Inorganic materials 0.000 claims abstract description 43
150000001875 compounds Chemical class 0.000 claims abstract description 40
238000010298 pulverizing process Methods 0.000 claims abstract description 30
239000000047 product Substances 0.000 claims abstract description 24
239000007795 chemical reaction product Substances 0.000 claims abstract description 19
HVLLSGMXQDNUAL-UHFFFAOYSA-N triphenyl phosphite Chemical compound C=1C=CC=CC=1OP(OC=1C=CC=CC=1)OC1=CC=CC=C1 HVLLSGMXQDNUAL-UHFFFAOYSA-N 0.000 claims abstract description 19
OJMIONKXNSYLSR-UHFFFAOYSA-N phosphorous acid Chemical compound OP(O)O OJMIONKXNSYLSR-UHFFFAOYSA-N 0.000 claims abstract description 18
150000002681 magnesium compounds Chemical class 0.000 claims abstract description 16
229910052736 halogen Inorganic materials 0.000 claims abstract description 15
150000002367 halogens Chemical class 0.000 claims abstract description 14
XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical compound Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 claims abstract description 9
IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 claims description 67
125000004432 carbon atom Chemical group C* 0.000 claims description 35
VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 claims description 20
150000007933 aliphatic carboxylic acids Chemical class 0.000 claims description 10
WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical class OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 claims description 10
YONPGGFAJWQGJC-UHFFFAOYSA-K titanium(iii) chloride Chemical compound Cl[Ti](Cl)Cl YONPGGFAJWQGJC-UHFFFAOYSA-K 0.000 claims description 9
RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 7
125000003118 aryl group Chemical group 0.000 claims description 7
239000003350 kerosene Substances 0.000 claims description 6
239000000463 material Substances 0.000 claims description 6
229910052751 metal Inorganic materials 0.000 claims description 6
239000002184 metal Substances 0.000 claims description 6
239000004743 Polypropylene Substances 0.000 claims description 4
229920001155 polypropylene Polymers 0.000 claims description 4
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 3
BKHZQJRTFNFCTG-UHFFFAOYSA-N tris(2-methylphenyl) phosphite Chemical compound CC1=CC=CC=C1OP(OC=1C(=CC=CC=1)C)OC1=CC=CC=C1C BKHZQJRTFNFCTG-UHFFFAOYSA-N 0.000 claims description 3
239000004793 Polystyrene Substances 0.000 claims description 2
125000000217 alkyl group Chemical group 0.000 claims description 2
229910052810 boron oxide Inorganic materials 0.000 claims description 2
JKWMSGQKBLHBQQ-UHFFFAOYSA-N diboron trioxide Chemical compound O=BOB=O JKWMSGQKBLHBQQ-UHFFFAOYSA-N 0.000 claims description 2
125000005375 organosiloxane group Chemical group 0.000 claims description 2
229920002223 polystyrene Polymers 0.000 claims description 2
XTTGYFREQJCEML-UHFFFAOYSA-N tributyl phosphite Chemical compound CCCCOP(OCCCC)OCCCC XTTGYFREQJCEML-UHFFFAOYSA-N 0.000 claims description 2
229910052814 silicon oxide Inorganic materials 0.000 claims 1
238000006116 polymerization reaction Methods 0.000 abstract description 36
TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 abstract description 12
MTZQAGJQAFMTAQ-UHFFFAOYSA-N ethyl benzoate Chemical compound CCOC(=O)C1=CC=CC=C1 MTZQAGJQAFMTAQ-UHFFFAOYSA-N 0.000 abstract description 12
229910001629 magnesium chloride Inorganic materials 0.000 abstract description 6
229910052782 aluminium Inorganic materials 0.000 abstract description 4
XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 abstract description 2
239000004711 α-olefin Substances 0.000 abstract description 2
229910003074 TiCl4 Inorganic materials 0.000 abstract 1
230000000694 effects Effects 0.000 description 21
229920000642 polymer Polymers 0.000 description 21
239000000203 mixture Substances 0.000 description 17
238000006243 chemical reaction Methods 0.000 description 16
YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 13
VOITXYVAKOUIBA-UHFFFAOYSA-N triethylaluminium Chemical compound CC[Al](CC)CC VOITXYVAKOUIBA-UHFFFAOYSA-N 0.000 description 13
QSSJZLPUHJDYKF-UHFFFAOYSA-N methyl 4-methylbenzoate Chemical compound COC(=O)C1=CC=C(C)C=C1 QSSJZLPUHJDYKF-UHFFFAOYSA-N 0.000 description 12
150000002148 esters Chemical class 0.000 description 11
XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 9
238000000034 method Methods 0.000 description 9
QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 8
125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 8
239000002002 slurry Substances 0.000 description 8
239000007787 solid Substances 0.000 description 8
125000005907 alkyl ester group Chemical group 0.000 description 7
229920006395 saturated elastomer Polymers 0.000 description 7
239000012265 solid product Substances 0.000 description 7
FHUODBDRWMIBQP-UHFFFAOYSA-N Ethyl p-anisate Chemical compound CCOC(=O)C1=CC=C(OC)C=C1 FHUODBDRWMIBQP-UHFFFAOYSA-N 0.000 description 6
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 6
238000012662 bulk polymerization Methods 0.000 description 6
229910052739 hydrogen Inorganic materials 0.000 description 6
239000001257 hydrogen Substances 0.000 description 6
229910052757 nitrogen Inorganic materials 0.000 description 6
VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 5
239000005977 Ethylene Substances 0.000 description 5
239000003085 diluting agent Substances 0.000 description 5
239000007788 liquid Substances 0.000 description 5
239000011777 magnesium Substances 0.000 description 5
AQSJGOWTSHOLKH-UHFFFAOYSA-N phosphite(3-) Chemical class [O-]P([O-])[O-] AQSJGOWTSHOLKH-UHFFFAOYSA-N 0.000 description 5
238000003756 stirring Methods 0.000 description 5
VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 4
ZEYHEAKUIGZSGI-UHFFFAOYSA-N 4-methoxybenzoic acid Chemical compound COC1=CC=C(C(O)=O)C=C1 ZEYHEAKUIGZSGI-UHFFFAOYSA-N 0.000 description 4
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 4
125000002723 alicyclic group Chemical group 0.000 description 4
150000002430 hydrocarbons Chemical group 0.000 description 4
229910052749 magnesium Inorganic materials 0.000 description 4
QPJVMBTYPHYUOC-UHFFFAOYSA-N methyl benzoate Chemical compound COC(=O)C1=CC=CC=C1 QPJVMBTYPHYUOC-UHFFFAOYSA-N 0.000 description 4
150000002989 phenols Chemical class 0.000 description 4
238000002360 preparation method Methods 0.000 description 4
230000007306 turnover Effects 0.000 description 4
WSSSPWUEQFSQQG-UHFFFAOYSA-N 4-methyl-1-pentene Chemical compound CC(C)CC=C WSSSPWUEQFSQQG-UHFFFAOYSA-N 0.000 description 3
CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 3
UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 3
ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 3
239000002253 acid Substances 0.000 description 3
150000001298 alcohols Chemical class 0.000 description 3
VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminium trichloride Chemical compound Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 description 3
JFDZBHWFFUWGJE-UHFFFAOYSA-N benzonitrile Chemical compound N#CC1=CC=CC=C1 JFDZBHWFFUWGJE-UHFFFAOYSA-N 0.000 description 3
230000015572 biosynthetic process Effects 0.000 description 3
238000004519 manufacturing process Methods 0.000 description 3
125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 3
125000002370 organoaluminium group Chemical group 0.000 description 3
150000002902 organometallic compounds Chemical class 0.000 description 3
229910052760 oxygen Inorganic materials 0.000 description 3
239000001301 oxygen Substances 0.000 description 3
238000010926 purge Methods 0.000 description 3
229930195734 saturated hydrocarbon Natural products 0.000 description 3
239000002904 solvent Substances 0.000 description 3
150000003609 titanium compounds Chemical class 0.000 description 3
OJVAMHKKJGICOG-UHFFFAOYSA-N 2,5-hexanedione Chemical compound CC(=O)CCC(C)=O OJVAMHKKJGICOG-UHFFFAOYSA-N 0.000 description 2
KWOLFJPFCHCOCG-UHFFFAOYSA-N Acetophenone Chemical compound CC(=O)C1=CC=CC=C1 KWOLFJPFCHCOCG-UHFFFAOYSA-N 0.000 description 2
QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
239000005711 Benzoic acid Substances 0.000 description 2
OIFBSDVPJOWBCH-UHFFFAOYSA-N Diethyl carbonate Chemical compound CCOC(=O)OCC OIFBSDVPJOWBCH-UHFFFAOYSA-N 0.000 description 2
UUGLJVMIFJNVFH-UHFFFAOYSA-N Hexyl benzoate Chemical compound CCCCCCOC(=O)C1=CC=CC=C1 UUGLJVMIFJNVFH-UHFFFAOYSA-N 0.000 description 2
KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 2
BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 description 2
QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
229910010068 TiCl2 Inorganic materials 0.000 description 2
229910010062 TiCl3 Inorganic materials 0.000 description 2
150000001299 aldehydes Chemical class 0.000 description 2
125000001931 aliphatic group Chemical group 0.000 description 2
150000001336 alkenes Chemical class 0.000 description 2
125000003545 alkoxy group Chemical group 0.000 description 2
AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical class [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 description 2
229910000147 aluminium phosphate Inorganic materials 0.000 description 2
150000001408 amides Chemical class 0.000 description 2
150000001412 amines Chemical class 0.000 description 2
229920006125 amorphous polymer Polymers 0.000 description 2
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
235000010233 benzoic acid Nutrition 0.000 description 2
NMJJFJNHVMGPGM-UHFFFAOYSA-N butyl formate Chemical compound CCCCOC=O NMJJFJNHVMGPGM-UHFFFAOYSA-N 0.000 description 2
150000001735 carboxylic acids Chemical class 0.000 description 2
238000010908 decantation Methods 0.000 description 2
LDCRTTXIJACKKU-ARJAWSKDSA-N dimethyl maleate Chemical compound COC(=O)\C=C/C(=O)OC LDCRTTXIJACKKU-ARJAWSKDSA-N 0.000 description 2
FKRCODPIKNYEAC-UHFFFAOYSA-N ethyl propionate Chemical compound CCOC(=O)CC FKRCODPIKNYEAC-UHFFFAOYSA-N 0.000 description 2
238000001914 filtration Methods 0.000 description 2
238000000227 grinding Methods 0.000 description 2
150000004820 halides Chemical class 0.000 description 2
125000005843 halogen group Chemical group 0.000 description 2
239000003701 inert diluent Substances 0.000 description 2
239000012948 isocyanate Substances 0.000 description 2
229940095102 methyl benzoate Drugs 0.000 description 2
GTCAXTIRRLKXRU-UHFFFAOYSA-N methyl carbamate Chemical compound COC(N)=O GTCAXTIRRLKXRU-UHFFFAOYSA-N 0.000 description 2
TZIHFWKZFHZASV-UHFFFAOYSA-N methyl formate Chemical compound COC=O TZIHFWKZFHZASV-UHFFFAOYSA-N 0.000 description 2
DDIZAANNODHTRB-UHFFFAOYSA-N methyl p-anisate Chemical compound COC(=O)C1=CC=C(OC)C=C1 DDIZAANNODHTRB-UHFFFAOYSA-N 0.000 description 2
125000004108 n-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 2
LQNUZADURLCDLV-UHFFFAOYSA-N nitrobenzene Chemical compound [O-][N+](=O)C1=CC=CC=C1 LQNUZADURLCDLV-UHFFFAOYSA-N 0.000 description 2
150000002894 organic compounds Chemical class 0.000 description 2
239000003960 organic solvent Substances 0.000 description 2
YWAKXRMUMFPDSH-UHFFFAOYSA-N pentene Chemical compound CCCC=C YWAKXRMUMFPDSH-UHFFFAOYSA-N 0.000 description 2
PGMYKACGEOXYJE-UHFFFAOYSA-N pentyl acetate Chemical compound CCCCCOC(C)=O PGMYKACGEOXYJE-UHFFFAOYSA-N 0.000 description 2
230000000737 periodic effect Effects 0.000 description 2
150000008301 phosphite esters Chemical class 0.000 description 2
229920002959 polymer blend Polymers 0.000 description 2
230000000379 polymerizing effect Effects 0.000 description 2
150000003138 primary alcohols Chemical group 0.000 description 2
UDEWPOVQBGFNGE-UHFFFAOYSA-N propyl benzoate Chemical compound CCCOC(=O)C1=CC=CC=C1 UDEWPOVQBGFNGE-UHFFFAOYSA-N 0.000 description 2
230000035484 reaction time Effects 0.000 description 2
235000003441 saturated fatty acids Nutrition 0.000 description 2
150000004671 saturated fatty acids Chemical class 0.000 description 2
229920002545 silicone oil Polymers 0.000 description 2
ZWYDDDAMNQQZHD-UHFFFAOYSA-L titanium(ii) chloride Chemical compound [Cl-].[Cl-].[Ti+2] ZWYDDDAMNQQZHD-UHFFFAOYSA-L 0.000 description 2
MCULRUJILOGHCJ-UHFFFAOYSA-N triisobutylaluminium Chemical compound CC(C)C[Al](CC(C)C)CC(C)C MCULRUJILOGHCJ-UHFFFAOYSA-N 0.000 description 2
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
KYVBNYUBXIEUFW-UHFFFAOYSA-N 1,1,3,3-tetramethylguanidine Chemical compound CN(C)C(=N)N(C)C KYVBNYUBXIEUFW-UHFFFAOYSA-N 0.000 description 1
QEGNUYASOUJEHD-UHFFFAOYSA-N 1,1-dimethylcyclohexane Chemical compound CC1(C)CCCCC1 QEGNUYASOUJEHD-UHFFFAOYSA-N 0.000 description 1
UAIVFDJJMVMUGY-UHFFFAOYSA-N 1,2,4-trimethylpiperazine Chemical compound CC1CN(C)CCN1C UAIVFDJJMVMUGY-UHFFFAOYSA-N 0.000 description 1
HNAGHMKIPMKKBB-UHFFFAOYSA-N 1-benzylpyrrolidine-3-carboxamide Chemical compound C1C(C(=O)N)CCN1CC1=CC=CC=C1 HNAGHMKIPMKKBB-UHFFFAOYSA-N 0.000 description 1
YPJRYQGOKHKNKZ-UHFFFAOYSA-N 1-ethyl-1-methylcyclohexane Chemical compound CCC1(C)CCCCC1 YPJRYQGOKHKNKZ-UHFFFAOYSA-N 0.000 description 1
LNETULKMXZVUST-UHFFFAOYSA-N 1-naphthoic acid Chemical compound C1=CC=C2C(C(=O)O)=CC=CC2=C1 LNETULKMXZVUST-UHFFFAOYSA-N 0.000 description 1
IEOPZUMPHCZMCS-UHFFFAOYSA-N 2-(methoxymethyl)oxolane Chemical compound COCC1CCCO1 IEOPZUMPHCZMCS-UHFFFAOYSA-N 0.000 description 1
IKCLCGXPQILATA-UHFFFAOYSA-M 2-chlorobenzoate Chemical compound [O-]C(=O)C1=CC=CC=C1Cl IKCLCGXPQILATA-UHFFFAOYSA-M 0.000 description 1
WOYWLLHHWAMFCB-UHFFFAOYSA-N 2-ethylhexyl acetate Chemical compound CCCCC(CC)COC(C)=O WOYWLLHHWAMFCB-UHFFFAOYSA-N 0.000 description 1
UADWUILHKRXHMM-UHFFFAOYSA-N 2-ethylhexyl benzoate Chemical compound CCCCC(CC)COC(=O)C1=CC=CC=C1 UADWUILHKRXHMM-UHFFFAOYSA-N 0.000 description 1
229940106004 2-ethylhexyl benzoate Drugs 0.000 description 1
YBFYRBILSHBEHV-UHFFFAOYSA-N 2-ethylhexyl naphthalene-1-carboxylate Chemical compound C1=CC=C2C(C(=O)OCC(CC)CCCC)=CC=CC2=C1 YBFYRBILSHBEHV-UHFFFAOYSA-N 0.000 description 1
CMAOLVNGLTWICC-UHFFFAOYSA-N 2-fluoro-5-methylbenzonitrile Chemical compound CC1=CC=C(F)C(C#N)=C1 CMAOLVNGLTWICC-UHFFFAOYSA-N 0.000 description 1
DUAYDERMVQWIJD-UHFFFAOYSA-N 2-n,2-n,6-trimethyl-1,3,5-triazine-2,4-diamine Chemical compound CN(C)C1=NC(C)=NC(N)=N1 DUAYDERMVQWIJD-UHFFFAOYSA-N 0.000 description 1
PZRWFKGUFWPFID-UHFFFAOYSA-N 3,9-dioctadecoxy-2,4,8,10-tetraoxa-3,9-diphosphaspiro[5.5]undecane Chemical compound C1OP(OCCCCCCCCCCCCCCCCCC)OCC21COP(OCCCCCCCCCCCCCCCCCC)OC2 PZRWFKGUFWPFID-UHFFFAOYSA-N 0.000 description 1
XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 1
MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 1
ICMAFTSLXCXHRK-UHFFFAOYSA-N Ethyl pentanoate Chemical compound CCCCC(=O)OCC ICMAFTSLXCXHRK-UHFFFAOYSA-N 0.000 description 1
KMTRUDSVKNLOMY-UHFFFAOYSA-N Ethylene carbonate Chemical compound O=C1OCCO1 KMTRUDSVKNLOMY-UHFFFAOYSA-N 0.000 description 1
239000002879 Lewis base Substances 0.000 description 1
VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 1
FXHOOIRPVKKKFG-UHFFFAOYSA-N N,N-Dimethylacetamide Chemical compound CN(C)C(C)=O FXHOOIRPVKKKFG-UHFFFAOYSA-N 0.000 description 1
SECXISVLQFMRJM-UHFFFAOYSA-N N-Methylpyrrolidone Chemical compound CN1CCCC1=O SECXISVLQFMRJM-UHFFFAOYSA-N 0.000 description 1
CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 1
OLBVUFHMDRJKTK-UHFFFAOYSA-N [N].[O] Chemical class [N].[O] OLBVUFHMDRJKTK-UHFFFAOYSA-N 0.000 description 1
YUWBVKYVJWNVLE-UHFFFAOYSA-N [N].[P] Chemical class [N].[P] YUWBVKYVJWNVLE-UHFFFAOYSA-N 0.000 description 1
150000007513 acids Chemical class 0.000 description 1
238000013019 agitation Methods 0.000 description 1
150000008431 aliphatic amides Chemical class 0.000 description 1
150000001338 aliphatic hydrocarbons Chemical class 0.000 description 1
125000003342 alkenyl group Chemical group 0.000 description 1
125000005234 alkyl aluminium group Chemical group 0.000 description 1
150000001350 alkyl halides Chemical class 0.000 description 1
150000001413 amino acids Chemical class 0.000 description 1
229910021529 ammonia Inorganic materials 0.000 description 1
159000000032 aromatic acids Chemical class 0.000 description 1
150000008430 aromatic amides Chemical class 0.000 description 1
150000004982 aromatic amines Chemical class 0.000 description 1
150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
150000008365 aromatic ketones Chemical class 0.000 description 1
150000008378 aryl ethers Chemical class 0.000 description 1
UADWUILHKRXHMM-ZDUSSCGKSA-N benzoflex 181 Natural products CCCC[C@H](CC)COC(=O)C1=CC=CC=C1 UADWUILHKRXHMM-ZDUSSCGKSA-N 0.000 description 1
XSIFPSYPOVKYCO-UHFFFAOYSA-N benzoic acid butyl ester Natural products CCCCOC(=O)C1=CC=CC=C1 XSIFPSYPOVKYCO-UHFFFAOYSA-N 0.000 description 1
KYZHGEFMXZOSJN-UHFFFAOYSA-N benzoic acid isobutyl ester Natural products CC(C)COC(=O)C1=CC=CC=C1 KYZHGEFMXZOSJN-UHFFFAOYSA-N 0.000 description 1
OBNCKNCVKJNDBV-UHFFFAOYSA-N butanoic acid ethyl ester Natural products CCCC(=O)OCC OBNCKNCVKJNDBV-UHFFFAOYSA-N 0.000 description 1
GWCTUKHUBWMAMI-GQCTYLIASA-N butyl (e)-but-2-enoate Chemical compound CCCCOC(=O)\C=C\C GWCTUKHUBWMAMI-GQCTYLIASA-N 0.000 description 1
YCURFOQQPNHZAO-UHFFFAOYSA-N butyl naphthalene-1-carboxylate Chemical compound C1=CC=C2C(C(=O)OCCCC)=CC=CC2=C1 YCURFOQQPNHZAO-UHFFFAOYSA-N 0.000 description 1
230000002308 calcification Effects 0.000 description 1
BVKZGUZCCUSVTD-UHFFFAOYSA-N carbonic acid Chemical compound OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 description 1
150000001732 carboxylic acid derivatives Chemical class 0.000 description 1
150000001733 carboxylic acid esters Chemical class 0.000 description 1
230000003197 catalytic effect Effects 0.000 description 1
239000003795 chemical substances by application Substances 0.000 description 1
HYZXMVILOKSUKA-UHFFFAOYSA-K chloro(dimethyl)alumane;dichloro(methyl)alumane Chemical compound C[Al](C)Cl.C[Al](Cl)Cl HYZXMVILOKSUKA-UHFFFAOYSA-K 0.000 description 1
229920001577 copolymer Polymers 0.000 description 1
125000004122 cyclic group Chemical group 0.000 description 1
125000000753 cycloalkyl group Chemical group 0.000 description 1
VJRUISVXILMZSL-UHFFFAOYSA-M dibutylalumanylium;chloride Chemical compound CCCC[Al](Cl)CCCC VJRUISVXILMZSL-UHFFFAOYSA-M 0.000 description 1
DENRZWYUOJLTMF-UHFFFAOYSA-N diethyl sulfate Chemical compound CCOS(=O)(=O)OCC DENRZWYUOJLTMF-UHFFFAOYSA-N 0.000 description 1
229940008406 diethyl sulfate Drugs 0.000 description 1
YNLAOSYQHBDIKW-UHFFFAOYSA-M diethylaluminium chloride Chemical compound CC[Al](Cl)CC YNLAOSYQHBDIKW-UHFFFAOYSA-M 0.000 description 1
BEPAFCGSDWSTEL-UHFFFAOYSA-N dimethyl malonate Chemical compound COC(=O)CC(=O)OC BEPAFCGSDWSTEL-UHFFFAOYSA-N 0.000 description 1
229940052296 esters of benzoic acid for local anesthesia Drugs 0.000 description 1
150000002170 ethers Chemical class 0.000 description 1
HHEIMYAXCOIQCJ-UHFFFAOYSA-N ethyl 2,2-dimethylpropanoate Chemical compound CCOC(=O)C(C)(C)C HHEIMYAXCOIQCJ-UHFFFAOYSA-N 0.000 description 1
LMXMLKHKWPCFTG-UHFFFAOYSA-N ethyl 4-butoxybenzoate Chemical compound CCCCOC1=CC=C(C(=O)OCC)C=C1 LMXMLKHKWPCFTG-UHFFFAOYSA-N 0.000 description 1
RWBYCMPOFNRISR-UHFFFAOYSA-N ethyl 4-chlorobenzoate Chemical compound CCOC(=O)C1=CC=C(Cl)C=C1 RWBYCMPOFNRISR-UHFFFAOYSA-N 0.000 description 1
NWPWRAWAUYIELB-UHFFFAOYSA-N ethyl 4-methylbenzoate Chemical compound CCOC(=O)C1=CC=C(C)C=C1 NWPWRAWAUYIELB-UHFFFAOYSA-N 0.000 description 1
XDRMBCMMABGNMM-UHFFFAOYSA-N ethyl benzenesulfonate Chemical compound CCOS(=O)(=O)C1=CC=CC=C1 XDRMBCMMABGNMM-UHFFFAOYSA-N 0.000 description 1
JJOYCHKVKWDMEA-UHFFFAOYSA-N ethyl cyclohexanecarboxylate Chemical compound CCOC(=O)C1CCCCC1 JJOYCHKVKWDMEA-UHFFFAOYSA-N 0.000 description 1
125000004494 ethyl ester group Chemical group 0.000 description 1
125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
VAJCYQHLYBTSHG-UHFFFAOYSA-N ethyl n,n-diethylcarbamate Chemical compound CCOC(=O)N(CC)CC VAJCYQHLYBTSHG-UHFFFAOYSA-N 0.000 description 1
HQKSINSCHCDMLS-UHFFFAOYSA-N ethyl naphthalene-2-carboxylate Chemical compound C1=CC=CC2=CC(C(=O)OCC)=CC=C21 HQKSINSCHCDMLS-UHFFFAOYSA-N 0.000 description 1
MGDOJPNDRJNJBK-UHFFFAOYSA-N ethylaluminum Chemical compound [Al].C[CH2] MGDOJPNDRJNJBK-UHFFFAOYSA-N 0.000 description 1
UAIZDWNSWGTKFZ-UHFFFAOYSA-L ethylaluminum(2+);dichloride Chemical compound CC[Al](Cl)Cl UAIZDWNSWGTKFZ-UHFFFAOYSA-L 0.000 description 1
239000007789 gas Substances 0.000 description 1
ZRALSGWEFCBTJO-UHFFFAOYSA-O guanidinium Chemical compound NC(N)=[NH2+] ZRALSGWEFCBTJO-UHFFFAOYSA-O 0.000 description 1
150000003977 halocarboxylic acids Chemical class 0.000 description 1
GNOIPBMMFNIUFM-UHFFFAOYSA-N hexamethylphosphoric triamide Chemical compound CN(C)P(=O)(N(C)C)N(C)C GNOIPBMMFNIUFM-UHFFFAOYSA-N 0.000 description 1
229920001519 homopolymer Polymers 0.000 description 1
229930195733 hydrocarbon Natural products 0.000 description 1
239000012442 inert solvent Substances 0.000 description 1
239000004615 ingredient Substances 0.000 description 1
229910003480 inorganic solid Inorganic materials 0.000 description 1
125000000959 isobutyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 description 1
150000002513 isocyanates Chemical class 0.000 description 1
150000002576 ketones Chemical class 0.000 description 1
150000002596 lactones Chemical class 0.000 description 1
150000007527 lewis bases Chemical class 0.000 description 1
239000007791 liquid phase Substances 0.000 description 1
OTCKOJUMXQWKQG-UHFFFAOYSA-L magnesium bromide Chemical compound [Mg+2].[Br-].[Br-] OTCKOJUMXQWKQG-UHFFFAOYSA-L 0.000 description 1
229910001623 magnesium bromide Inorganic materials 0.000 description 1
BLQJIBCZHWBKSL-UHFFFAOYSA-L magnesium iodide Chemical compound [Mg+2].[I-].[I-] BLQJIBCZHWBKSL-UHFFFAOYSA-L 0.000 description 1
229910001641 magnesium iodide Inorganic materials 0.000 description 1
238000010907 mechanical stirring Methods 0.000 description 1
150000002739 metals Chemical class 0.000 description 1
WVWZECQNFWFVFW-UHFFFAOYSA-N methyl 2-methylbenzoate Chemical compound COC(=O)C1=CC=CC=C1C WVWZECQNFWFVFW-UHFFFAOYSA-N 0.000 description 1
ZQWPRMPSCMSAJU-UHFFFAOYSA-N methyl cyclohexanecarboxylate Chemical compound COC(=O)C1CCCCC1 ZQWPRMPSCMSAJU-UHFFFAOYSA-N 0.000 description 1
HMRROBKAACRWBP-UHFFFAOYSA-N methyl naphthalene-1-carboxylate Chemical compound C1=CC=C2C(C(=O)OC)=CC=CC2=C1 HMRROBKAACRWBP-UHFFFAOYSA-N 0.000 description 1
150000007522 mineralic acids Chemical class 0.000 description 1
229930003658 monoterpene Natural products 0.000 description 1
235000002577 monoterpenes Nutrition 0.000 description 1
RLVGHTRVYWUWSH-UHFFFAOYSA-N n,n,2,2-tetramethylpropanamide Chemical compound CN(C)C(=O)C(C)(C)C RLVGHTRVYWUWSH-UHFFFAOYSA-N 0.000 description 1
SKECXRFZFFAANN-UHFFFAOYSA-N n,n-dimethylmethanethioamide Chemical compound CN(C)C=S SKECXRFZFFAANN-UHFFFAOYSA-N 0.000 description 1
150000002825 nitriles Chemical class 0.000 description 1
125000004433 nitrogen atom Chemical group N* 0.000 description 1
VECVSKFWRQYTAL-UHFFFAOYSA-N octyl benzoate Chemical compound CCCCCCCCOC(=O)C1=CC=CC=C1 VECVSKFWRQYTAL-UHFFFAOYSA-N 0.000 description 1
125000001477 organic nitrogen group Chemical group 0.000 description 1
239000002245 particle Substances 0.000 description 1
239000012071 phase Substances 0.000 description 1
125000000951 phenoxy group Chemical group [H]C1=C([H])C([H])=C(O*)C([H])=C1[H] 0.000 description 1
150000003003 phosphines Chemical class 0.000 description 1
150000008039 phosphoramides Chemical class 0.000 description 1
229910052698 phosphorus Inorganic materials 0.000 description 1
239000011574 phosphorus Substances 0.000 description 1
239000002685 polymerization catalyst Substances 0.000 description 1
229920001296 polysiloxane Polymers 0.000 description 1
239000000843 powder Substances 0.000 description 1
150000003141 primary amines Chemical class 0.000 description 1
WEHMFTWWOGBHCR-UHFFFAOYSA-N propyl 4-methoxybenzoate Chemical compound CCCOC(=O)C1=CC=C(OC)C=C1 WEHMFTWWOGBHCR-UHFFFAOYSA-N 0.000 description 1
DVFZYEJUWGWKLC-UHFFFAOYSA-N propyl naphthalene-1-carboxylate Chemical compound C1=CC=C2C(C(=O)OCCC)=CC=CC2=C1 DVFZYEJUWGWKLC-UHFFFAOYSA-N 0.000 description 1
RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 description 1
239000000377 silicon dioxide Substances 0.000 description 1
235000012239 silicon dioxide Nutrition 0.000 description 1
239000002210 silicon-based material Substances 0.000 description 1
239000011949 solid catalyst Substances 0.000 description 1
239000000126 substance Substances 0.000 description 1
125000001424 substituent group Chemical group 0.000 description 1
238000006467 substitution reaction Methods 0.000 description 1
229910052717 sulfur Inorganic materials 0.000 description 1
239000011593 sulfur Substances 0.000 description 1
239000000725 suspension Substances 0.000 description 1
DVKJHBMWWAPEIU-UHFFFAOYSA-N toluene 2,4-diisocyanate Chemical compound CC1=CC=C(N=C=O)C=C1N=C=O DVKJHBMWWAPEIU-UHFFFAOYSA-N 0.000 description 1
VHAHQCUPIDGTHM-UHFFFAOYSA-N trianthracen-9-yl phosphite Chemical compound C1=CC=C2C(OP(OC=3C4=CC=CC=C4C=C4C=CC=CC4=3)OC=3C4=CC=CC=C4C=C4C=CC=CC4=3)=C(C=CC=C3)C3=CC2=C1 VHAHQCUPIDGTHM-UHFFFAOYSA-N 0.000 description 1
FICPQAZLPKLOLH-UHFFFAOYSA-N tricyclohexyl phosphite Chemical compound C1CCCCC1OP(OC1CCCCC1)OC1CCCCC1 FICPQAZLPKLOLH-UHFFFAOYSA-N 0.000 description 1
XBEXIHMRFRFRAM-UHFFFAOYSA-N tridodecylalumane Chemical compound CCCCCCCCCCCC[Al](CCCCCCCCCCCC)CCCCCCCCCCCC XBEXIHMRFRFRAM-UHFFFAOYSA-N 0.000 description 1
AJSTXXYNEIHPMD-UHFFFAOYSA-N triethyl borate Chemical compound CCOB(OCC)OCC AJSTXXYNEIHPMD-UHFFFAOYSA-N 0.000 description 1
JLTRXTDYQLMHGR-UHFFFAOYSA-N trimethylaluminium Chemical compound C[Al](C)C JLTRXTDYQLMHGR-UHFFFAOYSA-N 0.000 description 1
ADQGXUHCBBVRGM-UHFFFAOYSA-N trinaphthalen-1-yl phosphite Chemical compound C1=CC=C2C(OP(OC=3C4=CC=CC=C4C=CC=3)OC=3C4=CC=CC=C4C=CC=3)=CC=CC2=C1 ADQGXUHCBBVRGM-UHFFFAOYSA-N 0.000 description 1
LFXVBWRMVZPLFK-UHFFFAOYSA-N trioctylalumane Chemical compound CCCCCCCC[Al](CCCCCCCC)CCCCCCCC LFXVBWRMVZPLFK-UHFFFAOYSA-N 0.000 description 1
YIVQLLZRHJPWTH-UHFFFAOYSA-N triphenanthren-4-yl phosphite Chemical compound C1=CC=CC2=C3C(OP(OC=4C5=C6C=CC=CC6=CC=C5C=CC=4)OC=4C5=C6C=CC=CC6=CC=C5C=CC=4)=CC=CC3=CC=C21 YIVQLLZRHJPWTH-UHFFFAOYSA-N 0.000 description 1
WEDGIYFCSMJGTP-UHFFFAOYSA-N tris(10-cyclodecylanthracen-9-yl) phosphite Chemical compound C1CCCCCCCCC1C(C1=CC=CC=C11)=C(C=CC=C2)C2=C1OP(OC=1C2=CC=CC=C2C(C2CCCCCCCCC2)=C2C=CC=CC2=1)OC(C1=CC=CC=C11)=C(C=CC=C2)C2=C1C1CCCCCCCCC1 WEDGIYFCSMJGTP-UHFFFAOYSA-N 0.000 description 1
XUHUMYVYHLHMCD-UHFFFAOYSA-N tris(2-cyclohexylphenyl) phosphite Chemical compound C1CCCCC1C1=CC=CC=C1OP(OC=1C(=CC=CC=1)C1CCCCC1)OC1=CC=CC=C1C1CCCCC1 XUHUMYVYHLHMCD-UHFFFAOYSA-N 0.000 description 1
HECNCEQNDSEKBN-UHFFFAOYSA-N tris(3-cyclopentylphenyl) phosphite Chemical compound C1CCCC1C1=CC=CC(OP(OC=2C=C(C=CC=2)C2CCCC2)OC=2C=C(C=CC=2)C2CCCC2)=C1 HECNCEQNDSEKBN-UHFFFAOYSA-N 0.000 description 1
VAURMQDVZLSKAA-UHFFFAOYSA-N tris(4-propan-2-ylphenyl) phosphite Chemical compound C1=CC(C(C)C)=CC=C1OP(OC=1C=CC(=CC=1)C(C)C)OC1=CC=C(C(C)C)C=C1 VAURMQDVZLSKAA-UHFFFAOYSA-N 0.000 description 1
OCWODPBASKRIFT-UHFFFAOYSA-N tris(6-cycloheptylnaphthalen-2-yl) phosphite Chemical compound C1CCCCCC1C1=CC=C(C=C(OP(OC=2C=C3C=CC(=CC3=CC=2)C2CCCCCC2)OC=2C=C3C=CC(=CC3=CC=2)C2CCCCCC2)C=C2)C2=C1 OCWODPBASKRIFT-UHFFFAOYSA-N 0.000 description 1
DHILVJHGUPRKCF-UHFFFAOYSA-N tris(6-phenylanthracen-2-yl) phosphite Chemical compound C=1C=C2C=C3C=C(C=4C=CC=CC=4)C=CC3=CC2=CC=1OP(OC=1C=C2C=C3C=CC(=CC3=CC2=CC=1)C=1C=CC=CC=1)OC(C=C1C=C2C=C3)=CC=C1C=C2C=C3C1=CC=CC=C1 DHILVJHGUPRKCF-UHFFFAOYSA-N 0.000 description 1
IYBHTOZULFOMEW-UHFFFAOYSA-N tris(7-phenylnaphthalen-1-yl) phosphite Chemical compound C=1C=CC2=CC=C(C=3C=CC=CC=3)C=C2C=1OP(OC=1C2=CC(=CC=C2C=CC=1)C=1C=CC=CC=1)OC(C1=C2)=CC=CC1=CC=C2C1=CC=CC=C1 IYBHTOZULFOMEW-UHFFFAOYSA-N 0.000 description 1
NBPZCUCIKOQELK-UHFFFAOYSA-N tris(7-phenylphenanthren-1-yl) phosphite Chemical compound C=1C=CC(C2=CC=C(C=C2C=C2)C=3C=CC=CC=3)=C2C=1OP(OC=1C2=C(C3=CC=C(C=C3C=C2)C=2C=CC=CC=2)C=CC=1)OC1=CC=CC(C2=CC=3)=C1C=CC2=CC=3C1=CC=CC=C1 NBPZCUCIKOQELK-UHFFFAOYSA-N 0.000 description 1
235000021122 unsaturated fatty acids Nutrition 0.000 description 1
150000004670 unsaturated fatty acids Chemical class 0.000 description 1
ABDKAPXRBAPSQN-UHFFFAOYSA-N veratrole Chemical compound COC1=CC=CC=C1OC ABDKAPXRBAPSQN-UHFFFAOYSA-N 0.000 description 1
125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
239000008096 xylene Substances 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/904—Monomer polymerized in presence of transition metal containing catalyst at least part of which is supported on a polymer, e.g. prepolymerized catalysts

Landscapes

Chemical & Material Sciences (AREA)
Health & Medical Sciences (AREA)
Chemical Kinetics & Catalysis (AREA)
Medicinal Chemistry (AREA)
Polymers & Plastics (AREA)
Organic Chemistry (AREA)
Engineering & Computer Science (AREA)
Materials Engineering (AREA)
Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Catalysts (AREA)

NO812190A 1980-06-27 1981-06-26 Katalysator. NO812190L (no)

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
US06/163,615 US4347160A (en)	1980-06-27	1980-06-27	Titanium halide catalyst system

Publications (1)

Publication Number	Publication Date
NO812190L true NO812190L (no)	1981-12-28

Family

ID=22590797

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
NO812190A NO812190L (no)	1980-06-27	1981-06-26	Katalysator.

Country Status (16)

Country	Link
US (1)	US4347160A (ko)
EP (1)	EP0043185B1 (ko)
JP (1)	JPS5731909A (ko)
KR (1)	KR840001736B1 (ko)
AT (1)	ATE9807T1 (ko)
AU (1)	AU543559B2 (ko)
BR (1)	BR8103956A (ko)
CA (1)	CA1159043A (ko)
DD (1)	DD159880A5 (ko)
DE (1)	DE3166568D1 (ko)
ES (1)	ES503428A0 (ko)
NO (1)	NO812190L (ko)
PT (1)	PT73235B (ko)
RO (1)	RO82539B (ko)
YU (1)	YU156281A (ko)
ZA (1)	ZA813374B (ko)

Families Citing this family (132)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US4451688A (en) *	1981-12-03	1984-05-29	Nippon Oil Company, Limited	Process for preparing polyolefins
US4525555A (en) *	1983-01-14	1985-06-25	Nippon Oil Company, Limited	Process for preparing polyolefins
JPH0446764Y2 (ko) *	1984-10-23	1992-11-04
US5278118A (en) *	1986-10-02	1994-01-11	Ausimont, S.P.A.	Catalysts for the preparation of elastomeric olefinic copolymers
IT1197320B (it) *	1986-10-02	1988-11-30	Ausimont Spa	Catalizzatori per la preparazione di copolimeri olefinici elastomerici,saturi ed insaturi,e vopolimeri con essi ottenuti
US5270276A (en) *	1989-04-25	1993-12-14	Shell Oil Company	Process for the production of elastomeric, primarily syndiotactic polypropylene and catalysts for use in said process
US5270410A (en) *	1989-04-25	1993-12-14	Shell Oil Company	Process for the production of elastomeric, primarily syndiotactic polypropylene and catalysts for use in said process
US4971936A (en) *	1989-07-10	1990-11-20	Shell Oil Company	Catalyst component for making primarily isotactic elastomeric polypropylene or polybutene
US5166340A (en) *	1989-07-26	1992-11-24	Himont Incorporated	Organosilane compounds
FR2658498B1 (fr) *	1990-02-19	1992-05-15	Atochem	Particules de chlorure de magnesium a structure tronc conique, composante catalytique supportee sur ces particules, polyolefines obtenues a partir de cette composante catalytique, procedes de fabrication de ces produits.
US5118649A (en) *	1990-02-26	1992-06-02	Shell Oil Company	Process for the production of elastomeric primarily isotactic polyolefins and catalysts for use in said process
US5118767A (en) *	1990-02-26	1992-06-02	Shell Oil Company	Process for producing mildly elastomeric primarily isotatic polypropylene and poly-1-butene
US5089573A (en) *	1990-02-26	1992-02-18	Shell Oil Company	Process for the production of elastomeric, primarily isotactic polyolefins and catalysts for use in said process
US5118768A (en) *	1990-05-11	1992-06-02	Shell Oil Company	Process for the production of elastomeric, primarily isotactic polyolefins and catalysts for use in said process
US5164352A (en) *	1990-05-11	1992-11-17	Shell Oil Company	Process for the production of elastomeric, primarily isotactic polyolefins and catalysts for use in said process
US5102842A (en) *	1990-08-23	1992-04-07	Himont Incorporated	Catalyst for the polymerization of alpha-olefins containing trifluoropropyl substituted silane compounds
JPH0518550U (ja) *	1991-08-28	1993-03-09	西日本鉄道株式会社	自動車用消火装置
US6130180A (en) *	1997-12-23	2000-10-10	Montell North America Inc.	Catalyst for the polymerization of alpha-olefins containing substituted amino silane compounds
US6015768A (en) *	1998-04-22	2000-01-18	Ray; Sabyasachi Sinha	Process for preparation of a heterogeneous catalyst useful for preparation of super high molecular weight polymers of alpha-olefin
JP4758583B2 (ja)	1999-12-22	2011-08-31	バセルテクノロジーカンパニービー．ブイ．	芳香族シラン化合物を含むα−オレフィン重合触媒系
KR101040388B1 (ko) *	2007-01-30	2011-06-09	주식회사 엘지화학	트리옥사실로칸을 포함하는 올레핀 중합용 촉매 및 이를이용한 올레핀 중합 방법
EP2174965B1 (en)	2008-10-08	2013-05-29	Borealis AG	Preparation of propylene copolymer with dynamically operated reactor
ATE535554T1 (de)	2008-10-08	2011-12-15	Borealis Ag	Verfahren zur herstellung von sehr steifem polyproylen
US8450421B2 (en)	2008-12-29	2013-05-28	Borealis Ag	Cable layer of modified soft polypropylene with improved stress whitening resistance
EP2216347A1 (en)	2009-01-30	2010-08-11	Borealis AG	A method of catalyst transitions in olefin polymerizations
ATE529450T1 (de)	2009-02-25	2011-11-15	Borealis Ag	Multimodales polymer aus propylen, zusammensetzung damit und verfahren zur herstellung davon
US20120095154A1 (en)	2009-04-09	2012-04-19	Klaus Bernreitner	Thermoplastic polyolefin composition
US7619049B1 (en)	2009-04-13	2009-11-17	Formosa Plastics Corporation, U.S.A.	Cyclic organosilicon compounds as electron donors for polyolefin catalysts
US7790819B1 (en)	2009-04-13	2010-09-07	Formosa Plastics Corporation, U.S.A.	Bicyclic organosilicon compounds as electron donors for polyolefin catalysts
EP2452959B1 (en)	2010-11-12	2015-01-21	Borealis AG	Process for producing propylene random copolymers and their use
EP2452960B1 (en)	2010-11-12	2015-01-07	Borealis AG	Process for preparing propylene polymers with an ultra high melt flow rate
EP2452956A1 (en)	2010-11-12	2012-05-16	Borealis AG	Improved process for polymerising propylene
EP2452975A1 (en)	2010-11-12	2012-05-16	Borealis AG	Soft heterophasic propylene copolymers
EP2452920A1 (en)	2010-11-12	2012-05-16	Borealis AG	A method for recovering transition metal tetrahalide and hydrocarbons from a waste stream
EP2452976A1 (en)	2010-11-12	2012-05-16	Borealis AG	Heterophasic propylene copolymers with improved stiffness/impact/flowability balance
EP2452957A1 (en)	2010-11-12	2012-05-16	Borealis AG	Improved process for producing heterophasic propylene copolymers
PL2495037T3 (pl)	2011-03-02	2021-01-11	Borealis Ag	Zespół reaktora o wysokiej przepustowości do polimeryzacji olefin
HUE052511T2 (hu)	2011-03-02	2021-05-28	Borealis Ag	Eljárás polimerek elõállítására
ES2605429T3 (es)	2011-06-15	2017-03-14	Borealis Ag	Mezcla del reactor in situ de un polipropileno nucleado catalizado por Ziegler-Natta y un polipropileno catalizado por metaloceno
EP2617741B1 (en)	2012-01-18	2016-01-13	Borealis AG	Process for polymerizing olefin polymers in the presence of a catalyst system and a method of controlling the process
US9815918B2 (en)	2012-03-19	2017-11-14	Formosa Plastics Corporation, U.S.A.	Catalyst component for high activity and high stereoselectivity in olefin polymerization
US8575283B1 (en)	2012-06-28	2013-11-05	Formosa Plastics Corporation, U.S.A.	Heterocyclic organic compounds as electron donors for polyolefin catalysts
WO2014032794A1 (en)	2012-08-29	2014-03-06	Borealis Ag	Reactor assembly and method for polymerization of olefins
EP2719725B1 (en)	2012-10-11	2018-12-05	Abu Dhabi Polymers Company Limited (Borouge)	Nucleated polypropylene composition for containers
EP2745926A1 (en)	2012-12-21	2014-06-25	Borealis AG	Gas phase polymerization and reactor assembly comprising a fluidized bed reactor and an external moving bed reactor
EP2745927A1 (en)	2012-12-21	2014-06-25	Borealis AG	Fluidized bed reactor with internal moving bed reaction unit
EP2749580B1 (en)	2012-12-28	2016-09-14	Borealis AG	Process for producing copolymers of propylene
EP2787034A1 (en)	2013-04-05	2014-10-08	Borealis AG	High stiffness polypropylene compositions
TR201808436T4 (tr)	2013-04-22	2018-07-23	Abu Dhabi Polymers Co Ltd Borouge	Boru uygulamaları için geliştirilmiş darbe dayanımına sahip polipropilen kompozisyonu.
EP2796502A1 (en)	2013-04-22	2014-10-29	Abu Dhabi Polymers Company Limited (Borouge)	Propylene random copolymer composition for pipe applications
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ES2569078T3 (es)	2013-04-22	2016-05-06	Abu Dhabi Polymers Company Limited (Borouge)	Composición de polipropileno multimodal para aplicaciones de tuberías
ES2632593T3 (es)	2013-04-22	2017-09-14	Borealis Ag	Procedimiento de dos fases de producción de composiciones de polipropileno
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MX2016001930A (es)	2013-08-21	2016-05-26	Borealis Ag	Composicion de poliolefina de alto flujo con alta rigidez y tenacidad.
WO2015024891A1 (en)	2013-08-21	2015-02-26	Borealis Ag	High flow polyolefin composition with high stiffness and toughness
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US9751962B2 (en)	2013-11-22	2017-09-05	Borealis Ag	Low emission propylene homopolymer with high melt flow
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EP2886600B1 (en)	2013-12-19	2018-05-30	Abu Dhabi Polymers Co. Ltd (Borouge) LLC.	Multimodal polypropylene with respect to comonomer content
SG11201604698RA (en)	2013-12-24	2016-07-28	Abu Dhabi Polymers Co Ltd Borouge Llc	Superior impact strength at low temperature by rubber design
EP3094660B1 (en)	2014-01-17	2018-12-19	Borealis AG	Process for preparing propylene/1-butene copolymers
JP6474417B2 (ja)	2014-02-06	2019-02-27	ボレアリスエージー	軟質及び透明衝撃コポリマー
CN105934475A (zh)	2014-02-06	2016-09-07	北欧化工公司	高冲击强度的柔性共聚物
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EP2913346B1 (en)	2014-02-28	2016-11-02	Borealis AG	Process for polymerizing olefins in a fluidized bed
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EP2933291A1 (en)	2014-04-17	2015-10-21	Borealis AG	Propylene copolymer composition for pipe applications
ES2659731T3 (es)	2014-05-20	2018-03-19	Borealis Ag	Composición de polipropileno para aplicaciones en interiores de automóviles
EP2995631A1 (en)	2014-09-12	2016-03-16	Borealis AG	Process for producing graft copolymers on polyolefin backbone
US9593184B2 (en)	2014-10-28	2017-03-14	Formosa Plastics Corporation, Usa	Oxalic acid diamides as modifiers for polyolefin catalysts
EP3018156B1 (en)	2014-11-05	2023-03-22	Borealis AG	Branched polypropylene for foam applications
EP3023450B1 (en)	2014-11-21	2017-07-19	Borealis AG	Process for producing pellets of soft copolymers
PL3103818T3 (pl)	2015-06-12	2018-12-31	Borealis Ag	Sposób i aparat do polimeryzacji olefin w fazie gazowej
EP3124567A1 (en)	2015-07-30	2017-02-01	Borealis AG	Polypropylene based hot-melt adhesive composition
JP6487602B2 (ja)	2015-07-30	2019-03-20	ボレアリス・アクチェンゲゼルシャフトＢｏｒｅａｌｉｓＡｇ	ホットタック力が向上したポリプロピレン組成物
EP3147324B1 (en)	2015-09-28	2018-09-26	Borealis AG	Polypropylene pipes with improved pressure resistance
WO2017068106A1 (en)	2015-10-21	2017-04-27	Borealis Ag	Long-chain branched polypropylene composition with increased melt strength stability
PL3368605T3 (pl)	2015-10-28	2022-08-22	Borealis Ag	Kompozycja polipropylenowa dla elementu warstwowego
EP3178853B1 (en)	2015-12-07	2018-07-25	Borealis AG	Process for polymerising alpha-olefin monomers
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US9777084B2 (en)	2016-02-19	2017-10-03	Formosa Plastics Corporation, Usa	Catalyst system for olefin polymerization and method for producing olefin polymer
WO2017157484A1 (en)	2016-03-14	2017-09-21	Borealis Ag	Polypropylene composition comprising flame retardant
EP3243622B1 (en)	2016-05-13	2020-09-09	Borealis AG	Process for hydraulic conveying of polyolefin pellets
EP3281973A1 (en)	2016-08-11	2018-02-14	Borealis AG	Polypropylene composition with flame retardant activity
US11427660B2 (en)	2016-08-17	2022-08-30	Formosa Plastics Corporation, Usa	Organosilicon compounds as electron donors for olefin polymerization catalysts and methods of making and using same
US9815920B1 (en)	2016-10-14	2017-11-14	Formosa Plastics Corporation, Usa	Olefin polymerization catalyst components and process for the production of olefin polymers therewith
CN109923164B (zh)	2016-11-09	2021-07-06	博里利斯股份公司	聚丙烯组合物
US20220347980A1 (en)	2017-02-01	2022-11-03	Borealis Ag	Article comprising a layer element
US10822438B2 (en)	2017-05-09	2020-11-03	Formosa Plastics Corporation	Catalyst system for enhanced stereo-specificity of olefin polymerization and method for producing olefin polymer
US10124324B1 (en)	2017-05-09	2018-11-13	Formosa Plastics Corporation, Usa	Olefin polymerization catalyst components and process for the production of olefin polymers therewith
ES2786756T3 (es)	2017-06-20	2020-10-13	Borealis Ag	Un método, una disposición y uso de una disposición para la polimerización de olefinas
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CN109135067A (zh)	2017-06-27	2019-01-04	阿布扎比聚合物有限责任公司(博禄)	用于制造高压管的聚丙烯组合物
DK3473674T3 (da)	2017-10-19	2022-06-20	Abu Dhabi Polymers Co Ltd Borouge Llc	Polypropylensammensætning
EP3479896A1 (en)	2017-11-03	2019-05-08	Borealis AG	Polymerization reactor system comprising at least one withdrawal valve
EP3483189A1 (en)	2017-11-14	2019-05-15	Borealis AG	Automated method for terminating an olefin polymerization reaction under emergency conditions
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EP3486261B1 (en)	2017-11-17	2020-06-24	Borealis AG	Method for improving the cooling capacity of a gas solids olefin polymerization reactor
TWI736891B (zh)	2018-05-18	2021-08-21	***聯合大公國商阿布達比聚合物股份有限公司（波魯）	熱塑性聚烯烴組成物之改良的流變性質
CN112119584A (zh)	2018-05-28	2020-12-22	北欧化工公司	用于光伏（pv）模块的装置
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US11680114B2 (en)	2018-07-19	2023-06-20	Borealis Ag	Process for the preparation of an UHMWPE homopolymer
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US20210277290A1 (en)	2018-08-06	2021-09-09	Borealis Ag	Propylene random copolymer based hot melt adhesive composition
EP3608364A1 (en)	2018-08-06	2020-02-12	Borealis AG	Multimodal propylene random copolymer based composition suitable as hot melt adhesive composition
US11897975B2 (en)	2018-09-28	2024-02-13	Borealis Ag	Multi-stage process for producing a C2 to C8 olefin polymer composition
US20210317242A1 (en)	2018-09-28	2021-10-14	Borealis Ag	Process for producing a prepolymerized solid ziegler-natta catalyst
EP3873954A1 (en)	2018-10-31	2021-09-08	Borealis AG	Polyethylene composition for high pressure resistant pipes with improved homogeneity
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CN113166292A (zh)	2018-11-30	2021-07-23	博里利斯股份公司	洗涤工艺
CN113993616B (zh)	2019-06-04	2023-06-02	北欧化工股份公司	用于增强气固流化床反应器中流体动力学的方法和反应器组件
EP3986608B1 (en)	2019-06-24	2023-08-02	Borealis AG	Process for preparing polypropylene with improved recovery
EP3868793A1 (en)	2020-02-24	2021-08-25	Borealis AG	Process for producing alpha-olefin polymers in a multistage polymerization process
EP3915782B1 (en)	2020-05-25	2024-07-17	Borealis AG	Layer element suitable as integrated backsheet element of a photovoltaic module
CA3184018A1 (en)	2020-05-25	2021-12-02	Borealis Ag	Layer element suitable as integrated backsheet for a bifacial photovoltaic module
EP4144435A1 (en)	2021-09-01	2023-03-08	Borealis AG	Gas phase polymerization process with improved gas recycling
EP4389776A1 (en)	2022-12-20	2024-06-26	Borealis AG	Process
EP4389783A1 (en)	2022-12-20	2024-06-26	Borealis AG	Catalyst transition process
EP4389820A1 (en)	2022-12-21	2024-06-26	Borealis AG	Polypropylene random copolymer compositions with improved impact resistance for pipe applications

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
CA920299A (en) *	1968-08-01	1973-01-30	Mitsui Petrochemical Industries	Process for the polymerization and/or copolymerization of olefins with use of ziegler-type catalytsts supported on carrier
BE765033R (fr) *	1970-04-06	1971-09-30	Inst Francais Du Petrole	Nouveau procede d'hydrogenation et catalyseurs d'hydrogenation correspondants
US3953414A (en) *	1972-09-13	1976-04-27	Montecatini Edison S.P.A.,	Catalysts for the polymerization of olefins to spherically shaped polymers
GB1527736A (en) *	1975-11-20	1978-10-11	Mitsui Petrochemical Ind	Process for preparing a polymerisation catalyst component
SE7613662L (sv) *	1975-12-10	1977-06-11	Mitsui Petrochemical Ind	Polymerisation av alfa-olefiner
JPS52104593A (en) *	1976-03-01	1977-09-02	Mitsui Petrochem Ind Ltd	Polymerization of olefins
US4180636A (en) *	1976-06-24	1979-12-25	Showa Denko Kabushiki Kaisha	Process for polymerizing or co-polymerizing propylene
US4130503A (en) *	1977-12-23	1978-12-19	Phillips Petroleum Company	Phosphite in MgX2 supported TiX3 /AlCl3 catalyst system
US4243552A (en) *	1978-12-11	1981-01-06	Phillips Petroleum Company	Polymerization catalyst and process

1980
- 1980-06-27 US US06/163,615 patent/US4347160A/en not_active Expired - Lifetime
1981
- 1981-05-07 CA CA000377072A patent/CA1159043A/en not_active Expired
- 1981-05-07 AU AU70248/81A patent/AU543559B2/en not_active Expired - Fee Related
- 1981-05-20 ZA ZA00813374A patent/ZA813374B/xx unknown
- 1981-05-29 AT AT81302378T patent/ATE9807T1/de not_active IP Right Cessation
- 1981-05-29 DE DE8181302378T patent/DE3166568D1/de not_active Expired
- 1981-05-29 EP EP81302378A patent/EP0043185B1/en not_active Expired
- 1981-06-05 JP JP8675781A patent/JPS5731909A/ja active Pending
- 1981-06-09 KR KR1019810002061A patent/KR840001736B1/ko active IP Right Grant
- 1981-06-22 PT PT73235A patent/PT73235B/pt unknown
- 1981-06-22 YU YU01562/81A patent/YU156281A/xx unknown
- 1981-06-23 BR BR8103956A patent/BR8103956A/pt unknown
- 1981-06-24 DD DD81231100A patent/DD159880A5/de unknown
- 1981-06-26 RO RO104703A patent/RO82539B/ro unknown
- 1981-06-26 ES ES503428A patent/ES503428A0/es active Granted
- 1981-06-26 NO NO812190A patent/NO812190L/no unknown

Also Published As

Publication number	Publication date
RO82539B (ro)	1984-05-30
JPS5731909A (en)	1982-02-20
KR830006338A (ko)	1983-09-24
DE3166568D1 (en)	1984-11-15
AU543559B2 (en)	1985-04-26
US4347160A (en)	1982-08-31
ATE9807T1 (de)	1984-10-15
AU7024881A (en)	1982-01-07
KR840001736B1 (ko)	1984-10-18
RO82539A (ro)	1984-04-12
ES8203638A1 (es)	1982-04-16
ZA813374B (en)	1982-06-30
PT73235A (en)	1981-07-01
CA1159043A (en)	1983-12-20
ES503428A0 (es)	1982-04-16
YU156281A (en)	1983-12-31
EP0043185B1 (en)	1984-10-10
EP0043185A1 (en)	1982-01-06
DD159880A5 (de)	1983-04-13
BR8103956A (pt)	1982-03-09
PT73235B (en)	1982-07-22

Publication	Publication Date	Title
NO812190L (no)	1981-12-28	Katalysator.
US4435550A (en)	1984-03-06	Method for polymerizing α-olefin
US4393182A (en)	1983-07-12	Olefin polymerization process with novel supported titanium catalyst compositions
EP1572756B1 (en)	2013-04-10	Catalyst components for the polymerization of olefins
EP0206817B1 (en)	1990-02-07	Catalyst for producing olefin polymers and polymerization process using the catalyst
NO812459L (no)	1982-01-19	Katalysatorsystem for anvendelse ved polymerisering av alfa-olefiner.
EP0026027B1 (en)	1983-06-08	Method for polymerizing alpha olefin
US4250287A (en)	1981-02-10	1-Olefin polymerization catalyst
EP0040711B1 (en)	1983-09-28	Titanium halide catalyst for polymerization
EP1511780B1 (en)	2007-06-27	Ziegler natta catalyst components for the polymerization of olefins
US4220745A (en)	1980-09-02	Process for polymerization of α-olefins
US4365048A (en)	1982-12-21	Method for polymerizing α-olefin
JPS6247446B2 (ko)	1987-10-08
JPS6119644B2 (ko)	1986-05-19
US4364853A (en)	1982-12-21	Catalyst for polymerizing olefins
KR100251599B1 (ko)	2000-04-15	구상 촉매 성분의 제조방법
US20040152590A1 (en)	2004-08-05	Ziegler natra catalyst for the polymerization of olefins
US5258474A (en)	1993-11-02	Process for producing α-olefin polymer
US4349483A (en)	1982-09-14	Process for the preparation of aluminum trihydrocarbyls
US4680350A (en)	1987-07-14	Purified catalyst support
JPH0680092B2 (ja)	1994-10-12	オレフイン重合用触媒成分の調製法
JP3496999B2 (ja)	2004-02-16	オレフィン重合用固体触媒成分の製造方法
KR930001065B1 (ko)	1993-02-15	α-올레핀의 단독 중합체 또는 공중합체의 제조방법
CA1095885A (en)	1981-02-17	Magnesium reducing agent for producing titanium trihalide catalyst component
JPH07109305A (ja)	1995-04-25	エチレン系重合体の製造方法