NO803615L - Fremgangsmaate ved og katalysator for polymerisering av alfa-olefiner. - Google Patents

Fremgangsmaate ved og katalysator for polymerisering av alfa-olefiner.

Info

Publication number: NO803615L
Authority: NO; Norway
Prior art keywords: catalyst component; titanium tetrachloride; compound; titanium; solvent
Prior art date: 1979-11-30

Application number

NO803615A

Other languages

English (en)

Norwegian (no)

Inventor

Joichi Sunada

Yoshikiazu Takahashi

Masaru Takitani

Original Assignee

Toyo Stauffer Chem Co

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1979-11-30

Filing date

1980-11-28

Publication date

1981-06-01

1980-11-28 Application filed by Toyo Stauffer Chem Co filed Critical Toyo Stauffer Chem Co

1981-06-01 Publication of NO803615L publication Critical patent/NO803615L/no

Links

239000003054 catalyst Substances 0.000 title claims description 127
238000000034 method Methods 0.000 title claims description 61
238000006116 polymerization reaction Methods 0.000 title claims description 40
-1 ether compound Chemical class 0.000 claims description 92
YONPGGFAJWQGJC-UHFFFAOYSA-K titanium(iii) chloride Chemical compound Cl[Ti](Cl)Cl YONPGGFAJWQGJC-UHFFFAOYSA-K 0.000 claims description 80
XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical compound Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 claims description 64
RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 50
239000012046 mixed solvent Substances 0.000 claims description 37
239000002904 solvent Substances 0.000 claims description 33
229910052782 aluminium Inorganic materials 0.000 claims description 32
230000008569 process Effects 0.000 claims description 30
238000001816 cooling Methods 0.000 claims description 24
239000004711 α-olefin Substances 0.000 claims description 24
239000004215 Carbon black (E152) Substances 0.000 claims description 17
229930195733 hydrocarbon Natural products 0.000 claims description 17
150000001336 alkenes Chemical class 0.000 claims description 15
239000000203 mixture Substances 0.000 claims description 13
JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims description 13
150000001338 aliphatic hydrocarbons Chemical class 0.000 claims description 12
150000002899 organoaluminium compounds Chemical class 0.000 claims description 11
125000004432 carbon atom Chemical group C* 0.000 claims description 10
150000001875 compounds Chemical class 0.000 claims description 10
229920006395 saturated elastomer Polymers 0.000 claims description 10
125000000217 alkyl group Chemical group 0.000 claims description 6
150000004945 aromatic hydrocarbons Chemical class 0.000 claims description 6
125000005843 halogen group Chemical group 0.000 claims description 5
125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 3
239000002245 particle Substances 0.000 description 58
229920000642 polymer Polymers 0.000 description 46
238000004519 manufacturing process Methods 0.000 description 17
QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 17
125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 17
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 14
MVPPADPHJFYWMZ-UHFFFAOYSA-N chlorobenzene Chemical compound ClC1=CC=CC=C1 MVPPADPHJFYWMZ-UHFFFAOYSA-N 0.000 description 13
VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 13
239000000243 solution Substances 0.000 description 13
230000000707 stereoselective effect Effects 0.000 description 13
DURPTKYDGMDSBL-UHFFFAOYSA-N 1-butoxybutane Chemical compound CCCCOCCCC DURPTKYDGMDSBL-UHFFFAOYSA-N 0.000 description 12
239000000374 eutectic mixture Substances 0.000 description 12
230000037048 polymerization activity Effects 0.000 description 12
239000000047 product Substances 0.000 description 9
238000005406 washing Methods 0.000 description 9
IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 8
230000003197 catalytic effect Effects 0.000 description 7
230000007423 decrease Effects 0.000 description 7
YNLAOSYQHBDIKW-UHFFFAOYSA-M diethylaluminium chloride Chemical compound CC[Al](Cl)CC YNLAOSYQHBDIKW-UHFFFAOYSA-M 0.000 description 7
229910052757 nitrogen Inorganic materials 0.000 description 7
238000005453 pelletization Methods 0.000 description 7
229920000098 polyolefin Polymers 0.000 description 7
238000002360 preparation method Methods 0.000 description 7
239000010936 titanium Substances 0.000 description 6
229910052719 titanium Inorganic materials 0.000 description 6
RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 5
239000007787 solid Substances 0.000 description 5
238000003756 stirring Methods 0.000 description 5
VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 4
238000009835 boiling Methods 0.000 description 4
QARVLSVVCXYDNA-UHFFFAOYSA-N bromobenzene Chemical compound BrC1=CC=CC=C1 QARVLSVVCXYDNA-UHFFFAOYSA-N 0.000 description 4
239000003795 chemical substances by application Substances 0.000 description 4
DMEGYFMYUHOHGS-UHFFFAOYSA-N cycloheptane Chemical compound C1CCCCCC1 DMEGYFMYUHOHGS-UHFFFAOYSA-N 0.000 description 4
230000000694 effects Effects 0.000 description 4
239000007788 liquid Substances 0.000 description 4
UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
KSKPGAGLAZXNEO-UHFFFAOYSA-H aluminum;titanium(3+);hexachloride Chemical compound [Al+3].[Cl-].[Cl-].[Cl-].[Cl-].[Cl-].[Cl-].[Ti+3] KSKPGAGLAZXNEO-UHFFFAOYSA-H 0.000 description 3
230000015572 biosynthetic process Effects 0.000 description 3
ACSXHCOUYYOVPA-UHFFFAOYSA-N chlorobenzene;hexane Chemical compound CCCCCC.ClC1=CC=CC=C1 ACSXHCOUYYOVPA-UHFFFAOYSA-N 0.000 description 3
238000007334 copolymerization reaction Methods 0.000 description 3
238000001035 drying Methods 0.000 description 3
238000001914 filtration Methods 0.000 description 3
150000002430 hydrocarbons Chemical class 0.000 description 3
TVMXDCGIABBOFY-UHFFFAOYSA-N octane Chemical compound CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 3
238000010298 pulverizing process Methods 0.000 description 3
238000006722 reduction reaction Methods 0.000 description 3
AKXKKSAGNHWXPQ-UHFFFAOYSA-N 1,2-dibromo-3,4-dimethylbenzene Chemical group CC1=CC=C(Br)C(Br)=C1C AKXKKSAGNHWXPQ-UHFFFAOYSA-N 0.000 description 2
LUIVNNXFXHFZFD-UHFFFAOYSA-N 1,2-dibromo-3-methylbenzene Chemical compound CC1=CC=CC(Br)=C1Br LUIVNNXFXHFZFD-UHFFFAOYSA-N 0.000 description 2
WQONPSCCEXUXTQ-UHFFFAOYSA-N 1,2-dibromobenzene Chemical compound BrC1=CC=CC=C1Br WQONPSCCEXUXTQ-UHFFFAOYSA-N 0.000 description 2
UZPZYFDULMKDMB-UHFFFAOYSA-N 1,2-dichloro-3,4-dimethylbenzene Chemical group CC1=CC=C(Cl)C(Cl)=C1C UZPZYFDULMKDMB-UHFFFAOYSA-N 0.000 description 2
OCJBOOLMMGQPQU-UHFFFAOYSA-N 1,4-dichlorobenzene Chemical compound ClC1=CC=C(Cl)C=C1 OCJBOOLMMGQPQU-UHFFFAOYSA-N 0.000 description 2
WLPXNBYWDDYJTN-UHFFFAOYSA-N 1-bromo-2,3-dimethylbenzene Chemical group CC1=CC=CC(Br)=C1C WLPXNBYWDDYJTN-UHFFFAOYSA-N 0.000 description 2
QSSXJPIWXQTSIX-UHFFFAOYSA-N 1-bromo-2-methylbenzene Chemical compound CC1=CC=CC=C1Br QSSXJPIWXQTSIX-UHFFFAOYSA-N 0.000 description 2
NVLHGZIXTRYOKT-UHFFFAOYSA-N 1-chloro-2,3-dimethylbenzene Chemical group CC1=CC=CC(Cl)=C1C NVLHGZIXTRYOKT-UHFFFAOYSA-N 0.000 description 2
CMAOLVNGLTWICC-UHFFFAOYSA-N 2-fluoro-5-methylbenzonitrile Chemical compound CC1=CC=C(F)C(C#N)=C1 CMAOLVNGLTWICC-UHFFFAOYSA-N 0.000 description 2
CAHQGWAXKLQREW-UHFFFAOYSA-N Benzal chloride Chemical compound ClC(Cl)C1=CC=CC=C1 CAHQGWAXKLQREW-UHFFFAOYSA-N 0.000 description 2
XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 2
VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 2
239000005977 Ethylene Substances 0.000 description 2
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 2
KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 2
239000004743 Polypropylene Substances 0.000 description 2
XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminium trichloride Chemical compound Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 description 2
125000003118 aryl group Chemical group 0.000 description 2
KCXMKQUNVWSEMD-UHFFFAOYSA-N benzyl chloride Chemical compound ClCC1=CC=CC=C1 KCXMKQUNVWSEMD-UHFFFAOYSA-N 0.000 description 2
HQMRIBYCTLBDAK-UHFFFAOYSA-M bis(2-methylpropyl)alumanylium;chloride Chemical compound CC(C)C[Al](Cl)CC(C)C HQMRIBYCTLBDAK-UHFFFAOYSA-M 0.000 description 2
229910052799 carbon Inorganic materials 0.000 description 2
229910052801 chlorine Inorganic materials 0.000 description 2
239000000460 chlorine Substances 0.000 description 2
DIOQZVSQGTUSAI-UHFFFAOYSA-N decane Chemical compound CCCCCCCCCC DIOQZVSQGTUSAI-UHFFFAOYSA-N 0.000 description 2
229940117389 dichlorobenzene Drugs 0.000 description 2
238000007865 diluting Methods 0.000 description 2
239000007789 gas Substances 0.000 description 2
238000010438 heat treatment Methods 0.000 description 2
239000001257 hydrogen Substances 0.000 description 2
229910052739 hydrogen Inorganic materials 0.000 description 2
230000006872 improvement Effects 0.000 description 2
UAEPNZWRGJTJPN-UHFFFAOYSA-N methylcyclohexane Chemical compound CC1CCCCC1 UAEPNZWRGJTJPN-UHFFFAOYSA-N 0.000 description 2
238000002156 mixing Methods 0.000 description 2
239000000178 monomer Substances 0.000 description 2
239000012299 nitrogen atmosphere Substances 0.000 description 2
229920001155 polypropylene Polymers 0.000 description 2
239000002244 precipitate Substances 0.000 description 2
230000009467 reduction Effects 0.000 description 2
238000000926 separation method Methods 0.000 description 2
239000012798 spherical particle Substances 0.000 description 2
VOITXYVAKOUIBA-UHFFFAOYSA-N triethylaluminium Chemical compound CC[Al](CC)CC VOITXYVAKOUIBA-UHFFFAOYSA-N 0.000 description 2
MCULRUJILOGHCJ-UHFFFAOYSA-N triisobutylaluminium Chemical compound CC(C)C[Al](CC(C)C)CC(C)C MCULRUJILOGHCJ-UHFFFAOYSA-N 0.000 description 2
230000007306 turnover Effects 0.000 description 2
239000002699 waste material Substances 0.000 description 2
XEMRAKSQROQPBR-UHFFFAOYSA-N (trichloromethyl)benzene Chemical compound ClC(Cl)(Cl)C1=CC=CC=C1 XEMRAKSQROQPBR-UHFFFAOYSA-N 0.000 description 1
HHPUADFPUXGYTC-UHFFFAOYSA-N 1,2,3-tribromo-5-methylbenzene;1,2,5-tribromo-3-methylbenzene;1,3,5-tribromo-2-methylbenzene Chemical compound CC1=CC(Br)=C(Br)C(Br)=C1.CC1=CC(Br)=CC(Br)=C1Br.CC1=C(Br)C=C(Br)C=C1Br HHPUADFPUXGYTC-UHFFFAOYSA-N 0.000 description 1
GMVJKSNPLYBFSO-UHFFFAOYSA-N 1,2,3-tribromobenzene Chemical compound BrC1=CC=CC(Br)=C1Br GMVJKSNPLYBFSO-UHFFFAOYSA-N 0.000 description 1
RELMFMZEBKVZJC-UHFFFAOYSA-N 1,2,3-trichlorobenzene Chemical compound ClC1=CC=CC(Cl)=C1Cl RELMFMZEBKVZJC-UHFFFAOYSA-N 0.000 description 1
QBELEDRHMPMKHP-UHFFFAOYSA-N 1-bromo-2-chlorobenzene Chemical compound ClC1=CC=CC=C1Br QBELEDRHMPMKHP-UHFFFAOYSA-N 0.000 description 1
NMLLTHLOSVNFMY-UHFFFAOYSA-N 1-butoxy-3-methylbutane Chemical compound CCCCOCCC(C)C NMLLTHLOSVNFMY-UHFFFAOYSA-N 0.000 description 1
HLKBESQBAMRXPZ-UHFFFAOYSA-N 1-butoxyoctane Chemical compound CCCCCCCCOCCCC HLKBESQBAMRXPZ-UHFFFAOYSA-N 0.000 description 1
LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 description 1
AOPDRZXCEAKHHW-UHFFFAOYSA-N 1-pentoxypentane Chemical compound CCCCCOCCCCC AOPDRZXCEAKHHW-UHFFFAOYSA-N 0.000 description 1
YGZQJYIITOMTMD-UHFFFAOYSA-N 1-propoxybutane Chemical compound CCCCOCCC YGZQJYIITOMTMD-UHFFFAOYSA-N 0.000 description 1
JLQBXJSLMWXEFL-UHFFFAOYSA-N 1-propoxyhexane Chemical compound CCCCCCOCCC JLQBXJSLMWXEFL-UHFFFAOYSA-N 0.000 description 1
MNNZINNZIQVULG-UHFFFAOYSA-N 2-chloroethylbenzene Chemical compound ClCCC1=CC=CC=C1 MNNZINNZIQVULG-UHFFFAOYSA-N 0.000 description 1
LQIIEHBULBHJKX-UHFFFAOYSA-N 2-methylpropylalumane Chemical compound CC(C)C[AlH2] LQIIEHBULBHJKX-UHFFFAOYSA-N 0.000 description 1
NMVXHZSPDTXJSJ-UHFFFAOYSA-L 2-methylpropylaluminum(2+);dichloride Chemical compound CC(C)C[Al](Cl)Cl NMVXHZSPDTXJSJ-UHFFFAOYSA-L 0.000 description 1
WSSSPWUEQFSQQG-UHFFFAOYSA-N 4-methyl-1-pentene Chemical compound CC(C)CC=C WSSSPWUEQFSQQG-UHFFFAOYSA-N 0.000 description 1
XRLPWAWAJCCSPO-UHFFFAOYSA-L 4-methylpentylaluminum(2+);dichloride Chemical compound [Cl-].[Cl-].CC(C)CCC[Al+2] XRLPWAWAJCCSPO-UHFFFAOYSA-L 0.000 description 1
ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 description 1
238000004438 BET method Methods 0.000 description 1
WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 1
VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 description 1
VQTUBCCKSQIDNK-UHFFFAOYSA-N Isobutene Chemical group CC(C)=C VQTUBCCKSQIDNK-UHFFFAOYSA-N 0.000 description 1
239000002841 Lewis acid Substances 0.000 description 1
CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
239000011954 Ziegler–Natta catalyst Substances 0.000 description 1
238000005054 agglomeration Methods 0.000 description 1
230000002776 aggregation Effects 0.000 description 1
239000012298 atmosphere Substances 0.000 description 1
230000009286 beneficial effect Effects 0.000 description 1
230000008901 benefit Effects 0.000 description 1
AGEZXYOZHKGVCM-UHFFFAOYSA-N benzyl bromide Chemical compound BrCC1=CC=CC=C1 AGEZXYOZHKGVCM-UHFFFAOYSA-N 0.000 description 1
SIPUZPBQZHNSDW-UHFFFAOYSA-N bis(2-methylpropyl)aluminum Chemical compound CC(C)C[Al]CC(C)C SIPUZPBQZHNSDW-UHFFFAOYSA-N 0.000 description 1
ICKSOVDWLBHVCG-UHFFFAOYSA-N bis(4-methylpentyl)alumane Chemical compound C(CCC(C)C)[AlH]CCCC(C)C ICKSOVDWLBHVCG-UHFFFAOYSA-N 0.000 description 1
FNJDZTVBKCBTNF-UHFFFAOYSA-M bis(4-methylpentyl)alumanylium;chloride Chemical compound [Cl-].CC(C)CCC[Al+]CCCC(C)C FNJDZTVBKCBTNF-UHFFFAOYSA-M 0.000 description 1
GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 1
229910052794 bromium Inorganic materials 0.000 description 1
VPCAAUUIFCAFRZ-UHFFFAOYSA-N butylalumane Chemical compound CCCC[AlH2] VPCAAUUIFCAFRZ-UHFFFAOYSA-N 0.000 description 1
SHOVVTSKTTYFGP-UHFFFAOYSA-L butylaluminum(2+);dichloride Chemical compound CCCC[Al](Cl)Cl SHOVVTSKTTYFGP-UHFFFAOYSA-L 0.000 description 1
230000008859 change Effects 0.000 description 1
238000006243 chemical reaction Methods 0.000 description 1
239000003638 chemical reducing agent Substances 0.000 description 1
150000008280 chlorinated hydrocarbons Chemical class 0.000 description 1
DFGSACBYSGUJDZ-UHFFFAOYSA-M chloro(dihexyl)alumane Chemical compound [Cl-].CCCCCC[Al+]CCCCCC DFGSACBYSGUJDZ-UHFFFAOYSA-M 0.000 description 1
HYZXMVILOKSUKA-UHFFFAOYSA-K chloro(dimethyl)alumane;dichloro(methyl)alumane Chemical compound C[Al](C)Cl.C[Al](Cl)Cl HYZXMVILOKSUKA-UHFFFAOYSA-K 0.000 description 1
SPWITGQNMOBZGJ-UHFFFAOYSA-M chloro(dipentyl)alumane Chemical compound [Cl-].CCCCC[Al+]CCCCC SPWITGQNMOBZGJ-UHFFFAOYSA-M 0.000 description 1
230000000052 comparative effect Effects 0.000 description 1
239000000470 constituent Substances 0.000 description 1
238000007796 conventional method Methods 0.000 description 1
239000013078 crystal Substances 0.000 description 1
WJTCGQSWYFHTAC-UHFFFAOYSA-N cyclooctane Chemical compound C1CCCCCCC1 WJTCGQSWYFHTAC-UHFFFAOYSA-N 0.000 description 1
239000004914 cyclooctane Substances 0.000 description 1
VJRUISVXILMZSL-UHFFFAOYSA-M dibutylalumanylium;chloride Chemical compound CCCC[Al](Cl)CCCC VJRUISVXILMZSL-UHFFFAOYSA-M 0.000 description 1
VTZJFPSWNQFPCQ-UHFFFAOYSA-N dibutylaluminum Chemical compound CCCC[Al]CCCC VTZJFPSWNQFPCQ-UHFFFAOYSA-N 0.000 description 1
HJXBDPDUCXORKZ-UHFFFAOYSA-N diethylalumane Chemical compound CC[AlH]CC HJXBDPDUCXORKZ-UHFFFAOYSA-N 0.000 description 1
HQWPLXHWEZZGKY-UHFFFAOYSA-N diethylzinc Chemical compound CC[Zn]CC HQWPLXHWEZZGKY-UHFFFAOYSA-N 0.000 description 1
CPDVHGLWIFENDJ-UHFFFAOYSA-N dihexylalumane Chemical compound C(CCCCC)[AlH]CCCCCC CPDVHGLWIFENDJ-UHFFFAOYSA-N 0.000 description 1
239000003085 diluting agent Substances 0.000 description 1
238000010790 dilution Methods 0.000 description 1
239000012895 dilution Substances 0.000 description 1
TUTOKIOKAWTABR-UHFFFAOYSA-N dimethylalumane Chemical compound C[AlH]C TUTOKIOKAWTABR-UHFFFAOYSA-N 0.000 description 1
JGHYBJVUQGTEEB-UHFFFAOYSA-M dimethylalumanylium;chloride Chemical compound C[Al](C)Cl JGHYBJVUQGTEEB-UHFFFAOYSA-M 0.000 description 1
GNPSMYTXIPVJDU-UHFFFAOYSA-N dioctylalumane Chemical compound C(CCCCCCC)[AlH]CCCCCCCC GNPSMYTXIPVJDU-UHFFFAOYSA-N 0.000 description 1
QRQUTSPLBBZERR-UHFFFAOYSA-M dioctylalumanylium;chloride Chemical compound CCCCCCCC[Al](Cl)CCCCCCCC QRQUTSPLBBZERR-UHFFFAOYSA-M 0.000 description 1
ZSSCJWAUUPQBQW-UHFFFAOYSA-N dipentylalumane Chemical compound C(CCCC)[AlH]CCCCC ZSSCJWAUUPQBQW-UHFFFAOYSA-N 0.000 description 1
POLCUAVZOMRGSN-UHFFFAOYSA-N dipropyl ether Chemical compound CCCOCCC POLCUAVZOMRGSN-UHFFFAOYSA-N 0.000 description 1
ZMXPNWBFRPIZFV-UHFFFAOYSA-M dipropylalumanylium;chloride Chemical compound [Cl-].CCC[Al+]CCC ZMXPNWBFRPIZFV-UHFFFAOYSA-M 0.000 description 1
238000009826 distribution Methods 0.000 description 1
MGDOJPNDRJNJBK-UHFFFAOYSA-N ethylaluminum Chemical compound [Al].C[CH2] MGDOJPNDRJNJBK-UHFFFAOYSA-N 0.000 description 1
UAIZDWNSWGTKFZ-UHFFFAOYSA-L ethylaluminum(2+);dichloride Chemical compound CC[Al](Cl)Cl UAIZDWNSWGTKFZ-UHFFFAOYSA-L 0.000 description 1
230000005496 eutectics Effects 0.000 description 1
239000000706 filtrate Substances 0.000 description 1
239000010419 fine particle Substances 0.000 description 1
229910052731 fluorine Inorganic materials 0.000 description 1
239000011737 fluorine Substances 0.000 description 1
238000012685 gas phase polymerization Methods 0.000 description 1
239000011521 glass Substances 0.000 description 1
238000000227 grinding Methods 0.000 description 1
229910052736 halogen Inorganic materials 0.000 description 1
150000002367 halogens Chemical class 0.000 description 1
VMLUVDHAXSZZSR-UHFFFAOYSA-L hexylaluminum(2+);dichloride Chemical compound CCCCCC[Al](Cl)Cl VMLUVDHAXSZZSR-UHFFFAOYSA-L 0.000 description 1
239000012442 inert solvent Substances 0.000 description 1
229910052740 iodine Inorganic materials 0.000 description 1
239000011630 iodine Substances 0.000 description 1
SZNYYWIUQFZLLT-UHFFFAOYSA-N isopropylmethyl ether Natural products CC(C)COCC(C)C SZNYYWIUQFZLLT-UHFFFAOYSA-N 0.000 description 1
150000007517 lewis acids Chemical class 0.000 description 1
239000007791 liquid phase Substances 0.000 description 1
239000000463 material Substances 0.000 description 1
238000002844 melting Methods 0.000 description 1
230000008018 melting Effects 0.000 description 1
GYNNXHKOJHMOHS-UHFFFAOYSA-N methyl-cycloheptane Natural products CC1CCCCCC1 GYNNXHKOJHMOHS-UHFFFAOYSA-N 0.000 description 1
CWEHKOAQFGHCFQ-UHFFFAOYSA-N methylalumane Chemical compound [AlH2]C CWEHKOAQFGHCFQ-UHFFFAOYSA-N 0.000 description 1
239000011259 mixed solution Substances 0.000 description 1
FVUDRZSBJPQJBX-UHFFFAOYSA-N n-Butyl-n-pentyl-aether Natural products CCCCCOCCCC FVUDRZSBJPQJBX-UHFFFAOYSA-N 0.000 description 1
230000003472 neutralizing effect Effects 0.000 description 1
239000012071 phase Substances 0.000 description 1
239000002685 polymerization catalyst Substances 0.000 description 1
238000001556 precipitation Methods 0.000 description 1
230000002265 prevention Effects 0.000 description 1
OBRKWFIGZSMARO-UHFFFAOYSA-N propylalumane Chemical compound [AlH2]CCC OBRKWFIGZSMARO-UHFFFAOYSA-N 0.000 description 1
238000002407 reforming Methods 0.000 description 1
230000000717 retained effect Effects 0.000 description 1
229930195734 saturated hydrocarbon Natural products 0.000 description 1
239000002002 slurry Substances 0.000 description 1
238000010557 suspension polymerization reaction Methods 0.000 description 1
SQBBHCOIQXKPHL-UHFFFAOYSA-N tributylalumane Chemical compound CCCC[Al](CCCC)CCCC SQBBHCOIQXKPHL-UHFFFAOYSA-N 0.000 description 1
ORYGRKHDLWYTKX-UHFFFAOYSA-N trihexylalumane Chemical compound CCCCCC[Al](CCCCCC)CCCCCC ORYGRKHDLWYTKX-UHFFFAOYSA-N 0.000 description 1
JLTRXTDYQLMHGR-UHFFFAOYSA-N trimethylaluminium Chemical compound C[Al](C)C JLTRXTDYQLMHGR-UHFFFAOYSA-N 0.000 description 1
LFXVBWRMVZPLFK-UHFFFAOYSA-N trioctylalumane Chemical compound CCCCCCCC[Al](CCCCCCCC)CCCCCCCC LFXVBWRMVZPLFK-UHFFFAOYSA-N 0.000 description 1
JOJQVUCWSDRWJE-UHFFFAOYSA-N tripentylalumane Chemical compound CCCCC[Al](CCCCC)CCCCC JOJQVUCWSDRWJE-UHFFFAOYSA-N 0.000 description 1
CNWZYDSEVLFSMS-UHFFFAOYSA-N tripropylalumane Chemical compound CCC[Al](CCC)CCC CNWZYDSEVLFSMS-UHFFFAOYSA-N 0.000 description 1
239000008096 xylene Substances 0.000 description 1
229940074411 xylene Drugs 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond

Landscapes

Chemical & Material Sciences (AREA)
Health & Medical Sciences (AREA)
Chemical Kinetics & Catalysis (AREA)
Medicinal Chemistry (AREA)
Polymers & Plastics (AREA)
Organic Chemistry (AREA)
Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)

NO803615A 1979-11-30 1980-11-28 Fremgangsmaate ved og katalysator for polymerisering av alfa-olefiner. NO803615L (no)

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
JP54155318A JPS5831090B2 (ja)	1979-11-30	1979-11-30	α−オレフィン重合用三塩化チタニウム触媒成分の製法

Publications (1)

Publication Number	Publication Date
NO803615L true NO803615L (no)	1981-06-01

Family

ID=15603258

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
NO803615A NO803615L (no)	1979-11-30	1980-11-28	Fremgangsmaate ved og katalysator for polymerisering av alfa-olefiner.

Country Status (6)

Country	Link
US (1)	US4361498A (ja)
EP (1)	EP0030018A3 (ja)
JP (1)	JPS5831090B2 (ja)
AU (1)	AU6469680A (ja)
CA (1)	CA1153755A (ja)
NO (1)	NO803615L (ja)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US5210362A (en) *	1989-06-07	1993-05-11	The Lubrizol Corporation	Alpha-olefin polymers

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
JPS5019155B1 (ja) *	1970-10-02	1975-07-04
JPS52110793A (en) *	1976-03-15	1977-09-17	Sumitomo Chem Co Ltd	Preparation of highly crystalline olefin polymers
JPS5438291A (en) *	1977-08-31	1979-03-22	Toyo Sutoufuaa Kemikaru Yuugen	Titanium trichloride catalyst ingredient and monopolymerization or copolymerization of alphaaolefin
JPS5490094A (en) *	1977-12-28	1979-07-17	Toyo Sutoufuaa Kemikaru Yuugen	Titanium trichloride catalyst component and monoo or copolymerization of alphaaolefin
JPS598362B2 (ja) *	1978-06-23	1984-02-24	有限会社東洋ストウフア−・ケミカル	α−オレフイン重合用触媒

1979
- 1979-11-30 JP JP54155318A patent/JPS5831090B2/ja not_active Expired
1980
- 1980-11-25 AU AU64696/80A patent/AU6469680A/en not_active Abandoned
- 1980-11-26 CA CA000365560A patent/CA1153755A/en not_active Expired
- 1980-11-27 EP EP80107440A patent/EP0030018A3/en not_active Withdrawn
- 1980-11-28 NO NO803615A patent/NO803615L/no unknown
- 1980-12-01 US US06/211,667 patent/US4361498A/en not_active Expired - Lifetime

Also Published As

Publication number	Publication date
CA1153755A (en)	1983-09-13
EP0030018A3 (en)	1982-02-24
AU6469680A (en)	1981-06-04
EP0030018A2 (en)	1981-06-10
US4361498A (en)	1982-11-30
JPS5679105A (en)	1981-06-29
JPS5831090B2 (ja)	1983-07-04

Publication	Publication Date	Title
US4120820A (en)	1978-10-17	High efficiency catalyst for polymerizing olefins
US4352915A (en)	1982-10-05	Process for the polymerization of ethylene
NO163960B (no)	1990-05-07	Fremgangsmaate for fremstilling av en baaret katalysator oganvendelse av denne ved kopolymerisering av etylen.
NO176571B (no)	1995-01-16	Fast katalysator og prepolymer for fremstilling av polyolefiner, fremgangsmåter for fremstilling av katalysatoren og prepolymeren samt fremgangsmåte for fremstilling av polyolefiner
NO309722B1 (no)	2001-03-19	Katalysator-komponent på bærer samt fremgangsmåte for fremstilling derav, og fremgangsmåte for polymerisasjon av olefiner
NO162158B (no)	1989-08-07	Fremgangsmaate for fremstilling av polyolefiner.
NO166867B (no)	1991-06-03	Fremgangsmaate for polymerisasjon eller kopolymerisasjon av alfa-olefiner i et virvelsjikt i naervaer av et ziegler-natta-katalysatorsystem.
NO306393B1 (no)	1999-11-01	Poröse partikler av magnesiumklorid med kjeglestruktur, fremgangsmaater for fremstilling av partiklene samt katalytisk preparat bestaaende av disse partikler impregnert med en overgangsmetall-forbindelse
JPS63146906A (ja)	1988-06-18	アルフアーオレフインの立体特異性重合に使用できる固形触媒
NO178732B (no)	1996-02-12	Katalysator, fremstilling av denne og fremgangsmåte til polymerisasjon av alkener
NO168044B (no)	1991-09-30	Fremgangsmaate for polymerisasjon av olefiner ved bruk av modifisert ziegler-natta katalysator.
NO178154B (no)	1995-10-23	Fast katalysatorbestanddel og katalysator for (ko)polymerisering av etylen, fremstilling av bestanddel og anvendelse av katalysator
WO1996034899A1 (en)	1996-11-07	Process and catalyst component for homo- and copolymerization of olefins
NO153534B (no)	1985-12-30	Fremgangsmaate ved polymerisering av et olefin inneholdende 3-8 karbonatomer, eller kopolymerisering av slike med hverandre eller med maksimalt 10 mol % etylen og/eller et dien, samt katalysator for utfoerelse av fremgangsmaaten.
NO175263B (no)	1994-06-13	Fremgangsmåte for fremstilling av elastomere kopolymerer av propylen i gassfase
US4189553A (en)	1980-02-19	High efficiency catalyst for polymerizing olefins
JPH01289809A (ja)	1989-11-21	チーグラー―ナッタ触媒
NO166946B (no)	1991-06-10	Fremgangsmaate for samtidig dimerisering av etylen og kopolymerisering av etylen med det dimeriserte produkt.
NO159858B (no)	1988-11-07	Titantrikloridkatalysatorbestanddel, samt anvendelse av denne ved polymerisering av alfa-olefiner.
US4209602A (en)	1980-06-24	Process for the production of polyolefins
NO178070B (no)	1995-10-09	Kokatalysatorpreparat, katalytisk system og fremgangsmåte ved polymerisering av
US4235745A (en)	1980-11-25	Titanium trichloride catalytic component and method for homo-or co-polymerization of α-olefin
US4273905A (en)	1981-06-16	Process for producing propylene polymer or copolymer
NO803615L (no)	1981-06-01	Fremgangsmaate ved og katalysator for polymerisering av alfa-olefiner.
CA1128916A (en)	1982-08-03	Magnesium containing support, catalyst and process for polymerizing olefins