NO750117L - - Google Patents
Info
- Publication number
- NO750117L NO750117L NO750117A NO750117A NO750117L NO 750117 L NO750117 L NO 750117L NO 750117 A NO750117 A NO 750117A NO 750117 A NO750117 A NO 750117A NO 750117 L NO750117 L NO 750117L
- Authority
- NO
- Norway
- Prior art keywords
- substituted
- salts
- acids
- esters
- amides
- Prior art date
Links
- 150000003839 salts Chemical class 0.000 claims description 24
- 239000000203 mixture Substances 0.000 claims description 16
- 230000002363 herbicidal effect Effects 0.000 claims description 10
- 150000001875 compounds Chemical class 0.000 claims description 7
- 239000004009 herbicide Substances 0.000 claims description 4
- 125000000217 alkyl group Chemical group 0.000 claims description 2
- 125000004432 carbon atom Chemical group C* 0.000 claims description 2
- 229910052736 halogen Inorganic materials 0.000 claims description 2
- 150000002367 halogens Chemical class 0.000 claims description 2
- 125000000956 methoxy group Chemical group [H]C([H])([H])O* 0.000 claims description 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 2
- 125000001424 substituent group Chemical group 0.000 claims description 2
- 239000013543 active substance Substances 0.000 description 23
- -1 fatty alcohol sulfates Chemical class 0.000 description 19
- 150000002148 esters Chemical class 0.000 description 16
- 150000001408 amides Chemical class 0.000 description 15
- 241000196324 Embryophyta Species 0.000 description 14
- 239000003795 chemical substances by application Substances 0.000 description 12
- 239000002253 acid Substances 0.000 description 9
- 239000003921 oil Substances 0.000 description 9
- 239000002689 soil Substances 0.000 description 8
- 150000007513 acids Chemical class 0.000 description 7
- 239000006185 dispersion Substances 0.000 description 7
- 239000000839 emulsion Substances 0.000 description 6
- 239000000126 substance Substances 0.000 description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 6
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 4
- 239000012876 carrier material Substances 0.000 description 4
- 239000008187 granular material Substances 0.000 description 4
- 239000000843 powder Substances 0.000 description 4
- 239000007787 solid Substances 0.000 description 4
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 239000003513 alkali Substances 0.000 description 3
- 239000012141 concentrate Substances 0.000 description 3
- 150000002169 ethanolamines Chemical class 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- 150000002790 naphthalenes Chemical class 0.000 description 3
- 159000000000 sodium salts Chemical class 0.000 description 3
- 239000000243 solution Substances 0.000 description 3
- UOCUSOBVEHOMMB-UHFFFAOYSA-N 2h-1$l^{6},2,3-benzothiadiazine 1,1-dioxide Chemical class C1=CC=C2S(=O)(=O)NN=CC2=C1 UOCUSOBVEHOMMB-UHFFFAOYSA-N 0.000 description 2
- ZNOVDQNFEJCRQZ-UHFFFAOYSA-N 3-propan-2-yl-2$l^{4},1,3-benzothiadiazine 2-oxide Chemical compound C1=CC=CC2=NS(=O)N(C(C)C)C=C21 ZNOVDQNFEJCRQZ-UHFFFAOYSA-N 0.000 description 2
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 description 2
- IAZDPXIOMUYVGZ-UHFFFAOYSA-N Dimethylsulphoxide Chemical compound CS(C)=O IAZDPXIOMUYVGZ-UHFFFAOYSA-N 0.000 description 2
- 241000551547 Dione <red algae> Species 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- DHMQDGOQFOQNFH-UHFFFAOYSA-N Glycine Chemical compound NCC(O)=O DHMQDGOQFOQNFH-UHFFFAOYSA-N 0.000 description 2
- CSNNHWWHGAXBCP-UHFFFAOYSA-L Magnesium sulfate Chemical compound [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 description 2
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 2
- UFWIBTONFRDIAS-UHFFFAOYSA-N Naphthalene Chemical compound C1=CC=CC2=CC=CC=C21 UFWIBTONFRDIAS-UHFFFAOYSA-N 0.000 description 2
- 240000007594 Oryza sativa Species 0.000 description 2
- 235000007164 Oryza sativa Nutrition 0.000 description 2
- 239000000853 adhesive Substances 0.000 description 2
- 230000001070 adhesive effect Effects 0.000 description 2
- 230000000844 anti-bacterial effect Effects 0.000 description 2
- 230000002303 anti-venom Effects 0.000 description 2
- 239000003899 bactericide agent Substances 0.000 description 2
- 235000013877 carbamide Nutrition 0.000 description 2
- MVPPADPHJFYWMZ-UHFFFAOYSA-N chlorobenzene Chemical compound ClC1=CC=CC=C1 MVPPADPHJFYWMZ-UHFFFAOYSA-N 0.000 description 2
- 239000007859 condensation product Substances 0.000 description 2
- JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexanone Chemical compound O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 description 2
- 239000002270 dispersing agent Substances 0.000 description 2
- 239000003995 emulsifying agent Substances 0.000 description 2
- 150000002170 ethers Chemical class 0.000 description 2
- 239000000417 fungicide Substances 0.000 description 2
- 230000012010 growth Effects 0.000 description 2
- 239000003630 growth substance Substances 0.000 description 2
- 239000002917 insecticide Substances 0.000 description 2
- HJOVHMDZYOCNQW-UHFFFAOYSA-N isophorone Chemical compound CC1=CC(=O)CC(C)(C)C1 HJOVHMDZYOCNQW-UHFFFAOYSA-N 0.000 description 2
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 description 2
- PSZYNBSKGUBXEH-UHFFFAOYSA-N naphthalene-1-sulfonic acid Chemical class C1=CC=C2C(S(=O)(=O)O)=CC=CC2=C1 PSZYNBSKGUBXEH-UHFFFAOYSA-N 0.000 description 2
- 230000001069 nematicidal effect Effects 0.000 description 2
- 239000005645 nematicide Substances 0.000 description 2
- SIOXPEMLGUPBBT-UHFFFAOYSA-N picolinic acid Chemical class OC(=O)C1=CC=CC=N1 SIOXPEMLGUPBBT-UHFFFAOYSA-N 0.000 description 2
- 230000008635 plant growth Effects 0.000 description 2
- 229920000151 polyglycol Polymers 0.000 description 2
- 239000010695 polyglycol Substances 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- VZGDMQKNWNREIO-UHFFFAOYSA-N tetrachloromethane Chemical compound ClC(Cl)(Cl)Cl VZGDMQKNWNREIO-UHFFFAOYSA-N 0.000 description 2
- 235000013311 vegetables Nutrition 0.000 description 2
- 238000009736 wetting Methods 0.000 description 2
- 239000000080 wetting agent Substances 0.000 description 2
- FTDGDIFUDKDKAW-UHFFFAOYSA-N 1,1a,5,5a,6,6a-hexahydrocyclopropa[a]indene Chemical class C12C(CC3CC=CC=C13)C2 FTDGDIFUDKDKAW-UHFFFAOYSA-N 0.000 description 1
- FNQJDLTXOVEEFB-UHFFFAOYSA-N 1,2,3-benzothiadiazole Chemical class C1=CC=C2SN=NC2=C1 FNQJDLTXOVEEFB-UHFFFAOYSA-N 0.000 description 1
- CSNIZNHTOVFARY-UHFFFAOYSA-N 1,2-benzothiazole Chemical class C1=CC=C2C=NSC2=C1 CSNIZNHTOVFARY-UHFFFAOYSA-N 0.000 description 1
- MFVFDTCSVFBOTL-UHFFFAOYSA-N 1,3-diazetidine Chemical class C1NCN1 MFVFDTCSVFBOTL-UHFFFAOYSA-N 0.000 description 1
- FKKAGFLIPSSCHT-UHFFFAOYSA-N 1-dodecoxydodecane;sulfuric acid Chemical class OS(O)(=O)=O.CCCCCCCCCCCCOCCCCCCCCCCCC FKKAGFLIPSSCHT-UHFFFAOYSA-N 0.000 description 1
- XUJLWPFSUCHPQL-UHFFFAOYSA-N 11-methyldodecan-1-ol Chemical compound CC(C)CCCCCCCCCCO XUJLWPFSUCHPQL-UHFFFAOYSA-N 0.000 description 1
- QZEDXQFZACVDJE-UHFFFAOYSA-N 2,3-dibutylnaphthalene-1-sulfonic acid Chemical class C1=CC=C2C(S(O)(=O)=O)=C(CCCC)C(CCCC)=CC2=C1 QZEDXQFZACVDJE-UHFFFAOYSA-N 0.000 description 1
- PAWQVTBBRAZDMG-UHFFFAOYSA-N 2-(3-bromo-2-fluorophenyl)acetic acid Chemical compound OC(=O)CC1=CC=CC(Br)=C1F PAWQVTBBRAZDMG-UHFFFAOYSA-N 0.000 description 1
- NFAOATPOYUWEHM-UHFFFAOYSA-N 2-(6-methylheptyl)phenol Chemical class CC(C)CCCCCC1=CC=CC=C1O NFAOATPOYUWEHM-UHFFFAOYSA-N 0.000 description 1
- ODWASQWJJUOKNN-UHFFFAOYSA-N 2-phenoxyprop-2-enoic acid Chemical class OC(=O)C(=C)OC1=CC=CC=C1 ODWASQWJJUOKNN-UHFFFAOYSA-N 0.000 description 1
- REEXLQXWNOSJKO-UHFFFAOYSA-N 2h-1$l^{4},2,3-benzothiadiazine 1-oxide Chemical compound C1=CC=C2S(=O)NN=CC2=C1 REEXLQXWNOSJKO-UHFFFAOYSA-N 0.000 description 1
- HQQTZCPKNZVLFF-UHFFFAOYSA-N 4h-1,2-benzoxazin-3-one Chemical class C1=CC=C2ONC(=O)CC2=C1 HQQTZCPKNZVLFF-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 1
- 241000234282 Allium Species 0.000 description 1
- 244000291564 Allium cepa Species 0.000 description 1
- 235000005255 Allium cepa Nutrition 0.000 description 1
- 239000004254 Ammonium phosphate Substances 0.000 description 1
- 244000099147 Ananas comosus Species 0.000 description 1
- 235000007119 Ananas comosus Nutrition 0.000 description 1
- 241000234670 Bromeliaceae Species 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- 235000008733 Citrus aurantifolia Nutrition 0.000 description 1
- 244000024469 Cucumis prophetarum Species 0.000 description 1
- 235000010071 Cucumis prophetarum Nutrition 0.000 description 1
- 240000008067 Cucumis sativus Species 0.000 description 1
- 235000009849 Cucumis sativus Nutrition 0.000 description 1
- 241000219104 Cucurbitaceae Species 0.000 description 1
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 description 1
- 241000220223 Fragaria Species 0.000 description 1
- 239000004471 Glycine Substances 0.000 description 1
- 240000005979 Hordeum vulgare Species 0.000 description 1
- 235000007340 Hordeum vulgare Nutrition 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 239000005909 Kieselgur Substances 0.000 description 1
- 241000234280 Liliaceae Species 0.000 description 1
- 235000019738 Limestone Nutrition 0.000 description 1
- SECXISVLQFMRJM-UHFFFAOYSA-N N-Methylpyrrolidone Chemical compound CN1CCCC1=O SECXISVLQFMRJM-UHFFFAOYSA-N 0.000 description 1
- 229930192627 Naphthoquinone Natural products 0.000 description 1
- IGFHQQFPSIBGKE-UHFFFAOYSA-N Nonylphenol Natural products CCCCCCCCCC1=CC=C(O)C=C1 IGFHQQFPSIBGKE-UHFFFAOYSA-N 0.000 description 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- 240000004713 Pisum sativum Species 0.000 description 1
- 235000010582 Pisum sativum Nutrition 0.000 description 1
- 241000209504 Poaceae Species 0.000 description 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
- 239000004721 Polyphenylene oxide Substances 0.000 description 1
- XBDQKXXYIPTUBI-UHFFFAOYSA-N Propionic acid Substances CCC(O)=O XBDQKXXYIPTUBI-UHFFFAOYSA-N 0.000 description 1
- WTKZEGDFNFYCGP-UHFFFAOYSA-N Pyrazole Chemical class C=1C=NNC=1 WTKZEGDFNFYCGP-UHFFFAOYSA-N 0.000 description 1
- 235000004789 Rosa xanthina Nutrition 0.000 description 1
- 241000220222 Rosaceae Species 0.000 description 1
- 244000082988 Secale cereale Species 0.000 description 1
- 235000007238 Secale cereale Nutrition 0.000 description 1
- 244000061456 Solanum tuberosum Species 0.000 description 1
- 235000002595 Solanum tuberosum Nutrition 0.000 description 1
- 240000006394 Sorghum bicolor Species 0.000 description 1
- 235000011684 Sorghum saccharatum Nutrition 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-N Sulfurous acid Chemical compound OS(O)=O LSNNMFCWUKXFEE-UHFFFAOYSA-N 0.000 description 1
- 235000011941 Tilia x europaea Nutrition 0.000 description 1
- 241000219793 Trifolium Species 0.000 description 1
- 241000209140 Triticum Species 0.000 description 1
- 235000021307 Triticum Nutrition 0.000 description 1
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 1
- 241000219094 Vitaceae Species 0.000 description 1
- 240000006365 Vitis vinifera Species 0.000 description 1
- 235000014787 Vitis vinifera Nutrition 0.000 description 1
- 240000008042 Zea mays Species 0.000 description 1
- 235000007244 Zea mays Nutrition 0.000 description 1
- DHKHKXVYLBGOIT-UHFFFAOYSA-N acetaldehyde Diethyl Acetal Natural products CCOC(C)OCC DHKHKXVYLBGOIT-UHFFFAOYSA-N 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 150000007933 aliphatic carboxylic acids Chemical class 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 125000002877 alkyl aryl group Chemical group 0.000 description 1
- 150000008055 alkyl aryl sulfonates Chemical class 0.000 description 1
- 150000005215 alkyl ethers Chemical class 0.000 description 1
- 150000008051 alkyl sulfates Chemical class 0.000 description 1
- 229940045714 alkyl sulfonate alkylating agent Drugs 0.000 description 1
- 150000008052 alkyl sulfonates Chemical class 0.000 description 1
- 229910000148 ammonium phosphate Inorganic materials 0.000 description 1
- 235000019289 ammonium phosphates Nutrition 0.000 description 1
- 150000003863 ammonium salts Chemical class 0.000 description 1
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 description 1
- 229910052921 ammonium sulfate Inorganic materials 0.000 description 1
- 239000001166 ammonium sulphate Substances 0.000 description 1
- 235000011130 ammonium sulphate Nutrition 0.000 description 1
- 125000002490 anilino group Chemical class [H]N(*)C1=C([H])C([H])=C([H])C([H])=C1[H] 0.000 description 1
- 239000002518 antifoaming agent Substances 0.000 description 1
- 229940111121 antirheumatic drug quinolines Drugs 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
- 125000003785 benzimidazolyl group Chemical class N1=C(NC2=C1C=CC=C2)* 0.000 description 1
- 150000005130 benzoxazines Chemical class 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Inorganic materials [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 description 1
- 150000004657 carbamic acid derivatives Chemical class 0.000 description 1
- 239000004202 carbamide Substances 0.000 description 1
- 239000004359 castor oil Substances 0.000 description 1
- 235000019438 castor oil Nutrition 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 239000011280 coal tar Substances 0.000 description 1
- 125000004122 cyclic group Chemical group 0.000 description 1
- HPXRVTGHNJAIIH-UHFFFAOYSA-N cyclohexanol Chemical compound OC1CCCCC1 HPXRVTGHNJAIIH-UHFFFAOYSA-N 0.000 description 1
- FBMGYBLOSXPJOW-UHFFFAOYSA-N cyclohexyl 3-(2,4-dichlorophenoxy)prop-2-enoate Chemical compound ClC1=CC(Cl)=CC=C1OC=CC(=O)OC1CCCCC1 FBMGYBLOSXPJOW-UHFFFAOYSA-N 0.000 description 1
- 125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 description 1
- MNNHAPBLZZVQHP-UHFFFAOYSA-N diammonium hydrogen phosphate Chemical compound [NH4+].[NH4+].OP([O-])([O-])=O MNNHAPBLZZVQHP-UHFFFAOYSA-N 0.000 description 1
- 150000001991 dicarboxylic acids Chemical class 0.000 description 1
- 239000002283 diesel fuel Substances 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 1
- 238000007865 diluting Methods 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 150000002019 disulfides Chemical class 0.000 description 1
- 239000012990 dithiocarbamate Substances 0.000 description 1
- 150000004659 dithiocarbamates Chemical class 0.000 description 1
- LQZZUXJYWNFBMV-UHFFFAOYSA-N dodecan-1-ol Chemical compound CCCCCCCCCCCCO LQZZUXJYWNFBMV-UHFFFAOYSA-N 0.000 description 1
- 239000010459 dolomite Substances 0.000 description 1
- 229910000514 dolomite Inorganic materials 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- QQSGDKKFXBGYON-UHFFFAOYSA-N ethoxy-methylperoxy-(6-methyl-2-propan-2-ylpyrimidin-4-yl)oxy-sulfanylidene-$l^{5}-phosphane Chemical class CCOP(=S)(OOC)OC1=CC(C)=NC(C(C)C)=N1 QQSGDKKFXBGYON-UHFFFAOYSA-N 0.000 description 1
- 239000000194 fatty acid Chemical class 0.000 description 1
- 229930195729 fatty acid Chemical class 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 150000002191 fatty alcohols Chemical class 0.000 description 1
- 239000003337 fertilizer Substances 0.000 description 1
- 239000000499 gel Substances 0.000 description 1
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 1
- 235000002532 grape seed extract Nutrition 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- GOQYKNQRPGWPLP-UHFFFAOYSA-N heptadecan-1-ol Chemical class CCCCCCCCCCCCCCCCCO GOQYKNQRPGWPLP-UHFFFAOYSA-N 0.000 description 1
- BXWNKGSJHAJOGX-UHFFFAOYSA-N hexadecan-1-ol Chemical class CCCCCCCCCCCCCCCCO BXWNKGSJHAJOGX-UHFFFAOYSA-N 0.000 description 1
- 150000001469 hydantoins Chemical class 0.000 description 1
- 229940042795 hydrazides for tuberculosis treatment Drugs 0.000 description 1
- 150000002460 imidazoles Chemical class 0.000 description 1
- 238000005470 impregnation Methods 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 239000003350 kerosene Substances 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 229920005610 lignin Polymers 0.000 description 1
- 239000004571 lime Substances 0.000 description 1
- 239000006028 limestone Substances 0.000 description 1
- 239000000395 magnesium oxide Substances 0.000 description 1
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 1
- 229910052943 magnesium sulfate Inorganic materials 0.000 description 1
- 235000019341 magnesium sulphate Nutrition 0.000 description 1
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 235000012054 meals Nutrition 0.000 description 1
- 229920000609 methyl cellulose Polymers 0.000 description 1
- 239000001923 methylcellulose Substances 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 235000010755 mineral Nutrition 0.000 description 1
- 239000002480 mineral oil Substances 0.000 description 1
- 235000010446 mineral oil Nutrition 0.000 description 1
- 150000002791 naphthoquinones Chemical class 0.000 description 1
- SNQQPOLDUKLAAF-UHFFFAOYSA-N nonylphenol Chemical compound CCCCCCCCCC1=CC=CC=C1O SNQQPOLDUKLAAF-UHFFFAOYSA-N 0.000 description 1
- QNMLMAVEXUCXRG-UHFFFAOYSA-N oxadiazinane-4,5-dione Chemical class O=C1CONNC1=O QNMLMAVEXUCXRG-UHFFFAOYSA-N 0.000 description 1
- SDRLFDJOSQLRPB-UHFFFAOYSA-N oxadiazine-4,5-dione Chemical class O=C1CON=NC1=O SDRLFDJOSQLRPB-UHFFFAOYSA-N 0.000 description 1
- 150000004866 oxadiazoles Chemical class 0.000 description 1
- DTHHUAXKOMWYBI-UHFFFAOYSA-N oxadiazolidine Chemical class C1CONN1 DTHHUAXKOMWYBI-UHFFFAOYSA-N 0.000 description 1
- YDCVQGAUCOROHB-UHFFFAOYSA-N oxadiazolidine-4,5-dione Chemical class O=C1NNOC1=O YDCVQGAUCOROHB-UHFFFAOYSA-N 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- 239000006072 paste Substances 0.000 description 1
- 150000002989 phenols Chemical class 0.000 description 1
- REJGOFYVRVIODZ-UHFFFAOYSA-N phosphanium;chloride Chemical class P.Cl REJGOFYVRVIODZ-UHFFFAOYSA-N 0.000 description 1
- AQSJGOWTSHOLKH-UHFFFAOYSA-N phosphite(3-) Chemical class [O-]P([O-])[O-] AQSJGOWTSHOLKH-UHFFFAOYSA-N 0.000 description 1
- 150000003009 phosphonic acids Chemical class 0.000 description 1
- 235000011007 phosphoric acid Nutrition 0.000 description 1
- 150000003016 phosphoric acids Chemical class 0.000 description 1
- 150000003053 piperidines Chemical class 0.000 description 1
- 239000002798 polar solvent Substances 0.000 description 1
- 229920000570 polyether Polymers 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 1
- 150000003217 pyrazoles Chemical class 0.000 description 1
- 150000004892 pyridazines Chemical class 0.000 description 1
- 150000003222 pyridines Chemical class 0.000 description 1
- 150000005299 pyridinones Chemical class 0.000 description 1
- 150000003230 pyrimidines Chemical class 0.000 description 1
- 150000008318 pyrimidones Chemical class 0.000 description 1
- 150000003235 pyrrolidines Chemical class 0.000 description 1
- 150000004040 pyrrolidinones Chemical class 0.000 description 1
- 150000003246 quinazolines Chemical class 0.000 description 1
- 150000003248 quinolines Chemical class 0.000 description 1
- 150000003254 radicals Chemical class 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 239000000741 silica gel Substances 0.000 description 1
- 229910002027 silica gel Inorganic materials 0.000 description 1
- 150000004760 silicates Chemical class 0.000 description 1
- 125000005624 silicic acid group Chemical class 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- 239000000600 sorbitol Substances 0.000 description 1
- 238000009331 sowing Methods 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 238000003892 spreading Methods 0.000 description 1
- 125000003011 styrenyl group Chemical class [H]\C(*)=C(/[H])C1=C([H])C([H])=C([H])C([H])=C1[H] 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- CXWXQJXEFPUFDZ-UHFFFAOYSA-N tetralin Chemical compound C1=CC=C2CCCCC2=C1 CXWXQJXEFPUFDZ-UHFFFAOYSA-N 0.000 description 1
- OLPRIZQBWZMBAS-UHFFFAOYSA-N thiadiazolidine 1,1-dioxide Chemical class O=S1(=O)CCNN1 OLPRIZQBWZMBAS-UHFFFAOYSA-N 0.000 description 1
- 150000003566 thiocarboxylic acids Chemical class 0.000 description 1
- 150000003582 thiophosphoric acids Chemical class 0.000 description 1
- 150000003585 thioureas Chemical class 0.000 description 1
- 150000003918 triazines Chemical class 0.000 description 1
- 150000003852 triazoles Chemical class 0.000 description 1
- 150000003672 ureas Chemical class 0.000 description 1
- 244000045561 useful plants Species 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D285/00—Heterocyclic compounds containing rings having nitrogen and sulfur atoms as the only ring hetero atoms, not provided for by groups C07D275/00 - C07D283/00
- C07D285/15—Six-membered rings
- C07D285/16—Thiadiazines; Hydrogenated thiadiazines
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N39/00—Biocides, pest repellants or attractants, or plant growth regulators containing aryloxy- or arylthio-aliphatic or cycloaliphatic compounds, containing the group or, e.g. phenoxyethylamine, phenylthio-acetonitrile, phenoxyacetone
- A01N39/02—Aryloxy-carboxylic acids; Derivatives thereof
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical & Material Sciences (AREA)
- Dentistry (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Plant Pathology (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Pest Control & Pesticides (AREA)
- Agronomy & Crop Science (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Description
Den foreliggende oppfinnelse angår et herbicid.som inneholder en blanding av virksomme stoffer. L}$ ltCi& ?
Det er kjent at benzotiadiazinondioksyder (DT-PS 1 542 836) og substituerte fenoksyakrylater (Dérwent Central Patent Index, Section G, AGDOC'/ \l971, 40. uke, referat nr. 64 4915-C, og Patert schnellbericht Teil B, Referat B 32-278/68) har en herbicid virkning. Deres herbicide virkning er imidlertid litoen.
Det ble funnet at en blanding av en
a) forbindelse med formelen
hvor R, er et lavere alkyl, eller salter deråv, og
b) en forbindelse med formelen
hvor R er en eventuelt med halogen eller metyl substituert cyk«
1'oalkylrest med 3-12 C-atomer, X betyr like eller forskjellige substituenter fra gruppen halogen, metyl og metoksy, og hvor n = 0 til 3,
harren bedre herbicid virkning enn de enkelte virksomme stoffer.
Blandingene kan inneholde en eller flere forbindelser med
formelen a og forbindelser med formelen b.
Blandingsforholdene kan velges etter ønske.Blandingsfor-holdet mellom de virksomme Istbffer a og b er eksempelvis 0,1 til 10 vektdeler a til 1 vektdel b, fortrinnsvis 0,3 til 3 vektdeler a til 1 vektdel b.
De mengder som anvendes av midlene ifølge oppfinnelsen, kan variere. Mengden avhenger hovedsakelig av arten av den ønskede virkning. Den mengde som anvendes, ligger vanligvis mellom 0,1 og 30 eller mer, fortrinnsvis 0,2-6 kg virksomt stoff pr.hektar. Midlene ifølge oppfinnelsen kan blant annet anvendes før plantingen, etter plantingen, før såingen, før plantene kommer opp av jorden, etter at plantene kommer opp av jorden eller mens kulturplantene eller de uønskede planter er iferd med å komme opp av jorden, og midlene kan anvendes en eller flere ganger.
Blandingene er egnet til bruk.i[nytteplanter, for eksempel Oryza sativa, Triticum spp.,Hordeum vulgare, Secale cereale,Zea mays, Sorghum spp.,Glycine maS^ Solanum tuberosum,Cucumis sativus, Pisum sativum, Allium cepa, Trifolium spp., Festuca spp., Poa spp. Videre kan blandingene anvendes som totalmiddel ved graver, langs elver og bekker, langs jernbaneskinner, på øde fla-ter etc.
Anvendelsen skjer eksempelvis i form av direkte sprøyt-bare løsninger, pulvere, suspensjoner eller dispersjoner, emulsjoner, oljedispersjoner, pastaer, støvformige midler, strømidler eller granulater, ved sprøyting, forstøvning, utspreding eller uthelling. Anvendelsesformene retter seg hlelt etter anvendelsesformålet; man tar alltid sikte på å oppnå en .mest mulig fin fordeling av de virk« somme stoffer ifølge oppfinnelsen.
Ved fremstilling av direkte sprøytbare løsninger, emulsjoner, pastaer og oljedispersjoner kan man bruke mineraloljefrak-sjoner med midlere til høyt kokepunkt, så som kerosih eller diesel-olje, ennvidere kulltjæreoljer etc., samt oljer av vegetabilsk eller animalsk opprinnelse, alifatiske, cykliske og aromatiske hydrokarboner,, for eksempel benzen, toluen, xylen, paraffin, tetra— hydronaftalin, alkylerte naftaliner eller deres derivater, for eksempel metanol, etanol, propanol, butanol, kloroform, karbontetra-klorid, cykloheksanol, cykloheksanon, klorbenzen, isoforon etc., sterkt polare løsningsmidler, som for eksempel dimetylformamid, dimetylsulfoksyd, n-metylpyrrolidon, vann etc.
Vandige bruksformer kan fremstilles av emulsjonskonsentra-ter,, pastaer eller fuktbaré pulvere (sprøytepulvere) eller oljedispersjoner ved tilsetning av vann. Ved fremstilling av emulsjoner, pastaer/eller pljedispersjoner kan stoffene .som isådanne eller løst i olje eller løsningsmiddel homogeniseres i vann ved hjelp av fukte-, klebe-, dispergerings- eller emulgeringsmidlér. Det kan imidlertid også fremstilles konsentrater bestående av virksomt stoff, fukte-, klebe-, dispergerings- eller emulgeringsmiddel og eventuelt løsningsmiddel eller olje, hvilke konsentrater er egnet til å fortynnes med vann.
Blant overflateaktivé stoffer kan nevnes: alkali-, jord-alkali-, ammoniumsalter av ligninsulfonsyre, naftalinsulfonsyrer, fenolsulfonsyrer, alkylarylsulfonater, alkylsulfater, alkylsulfo-nater, alkali- og jordalkalisalter av dibutylnaftalinsulfonsyre, lauryletersulfat, fettalkoholsulfater, fettsure alkali- og jord alkalisalter, salter av sulfaterte heksadekanoler, heptadekanoler, oktadekanoler, salter av sulfatert fettalkoholglykoleter, kondensasjonsprodukter av sulfonert naftalin og naftalinderivater med formaldehyd, kondensasjonsprodukter av. naftalin eller naftalinsulfonsyrer med fenol og formaldehyd, polyoksyetylenoktylfenoleter, etok-sylerte isooktylfenol-, oktylfenol-, nonylfenol-, alkylfenolpoly^-glykoleter, tributylfenylpolyglykoleter, alkylarylpolyeteralkoholer, isotridecylalkohol, fettalkoholetylenoksydkondensater, etoksylert ricinusolje, polyoksyetylenalkyleter, etoksylert polyoksyipropylen, laurylalkoholpolyglykoleteracetal, sorbitolester, lignin, sulfitt-avluter og metylcellulose.
Pulver, strø- og støvformige midler kan fremstilles ved blanding eller sammaling av de {virksomme stoffer med et fast bære-materiale.
Granulater, for eksempel omhyllings-, impregnerings- og homogengranulater kan fremstilles ved binding av de virksomme stoffer på faste bærematerialer. Faste bærematerialer er for eksempel mineralmaterialer så som silikagel, kiselsyrer, kiselgeler, sili-kater, talkum, ka&Tin, attaclay, kalkstein, kalk, kritt, bolus, løss, leire, dolomitt, diatoméjo!rd], kalsium- og magnesiumsulfat, magnesiumoksyd, malte harpikser, gjødningsstoffer som for eksempel ammoniumsulfat, ammoniumfosfat, ammoniumnitrat, urinstoffer og vege-tabilske produkter så.som mel av ko^n, bark, tre og nøtteskall, cellulosepulver og andre faste bærematerialer.
Preparatene inneholder mellom 0,1 og. 95 vekt% virksomt stoff, fortrinnsvis mellom 0,5 og 90 |vekt%.
Til blandingene eller de enkelte virksomme stoffer kan man, eventuelt først umiddelbart før anvendelsen (tankblanding), tilsette oljer av forskjellige typer, herbicider, fungicider, nematocider, insekticider, baktericider, spore lemeorvter,! g jødningsstof fer, skum-hindrende midler, (for eksempel silikoner), vekstregulatorer, mot-giftmidler eller andre herbicid virksomme forbindelser, som for eksempel
substituerte aniliner
substituerte aryloksykarboksylsyrer og deres salter, estere og amider
substituerte etere
substituerte arsomsyrer og deres salter, estere og amider substituerte benzimidazoler
substituerte benzisotiazoler
substituerte benztiadiazinondioksyder
i—.
substituerte benzoksaziner
substituerte benzoksazinoner
substituerte benztiadiazoler
substituerte biureter
substituerte kinoliner
substituerte karbamater
substituerte alifatiske karboksylsyrer og deres salter, estere og amider
substituerte aromatiske karboksylsyrer og deres salter, estere og amider
substituerte karbamoylaklyltiol- eller -ditiofosfater substituerte kinazoliner
substituerte cykloalkylaminokarbontiolsyrer og deres salter, estere og amider
substituerte cykloalkylkarbonamidotiazoler substituerte dikarboksylsyrer og deres salter, estere og amider substituerte dihydrobenzofuranylsulfonater
substituerte disulfider
substituerte dipyridyliumsalter
substituerte ditiokarbamater
substituerte ditiofosforsyrer og deres salter, estere og amider substituerte urinstoffer
substituerte heksahydro-l-H-karbotioater
substituerte hydantoiner
substituerte hydrazider
substituerte hydrazoniumsalter
substituerte isooksazolpyrimidoner
substituerte imidazoler
substituerte isotiazolpyrimidoner
substituerte ketoner
substituerte naftokinoner
substituerte alifatiske nitriler
substituerte aromatiske nitriler.
substituerte oksadiazoler
substituerte oksadiazinoner
substituerte oksadiazolidindioner
substituerte oksadiazindioner
substituerte fenoler og deres salter, estere og amider substituerte fosfonsyrer og deres salter, estere og amider
substituerte fosfoniumklorider
substituerte fosfonalkylglyciner
substituerte fosfiter
substituerte fosforsyrer og deres salter, estere og amider substituerte piperidiner
substituerte pyrazoler
substituerte pyrazolalkylkarboksylsyrer og deres salter, estere og amTder substituerte pyrazoliumsålter
substituerte pyrazoliumalkylsulfater
substituerte pyridaziner
substituerte pyridazoner
substituerte pyridinkarboksylsyrer og deres salter, estere og amider
substituerte pyridiner
substituerte pyridinkarboksylater
substituerte pyridinoner
substituerte pyrimidiner
substituerte pyrimidoner
substituert(r~pyrrplidinkarboksylsyre og dennes salter, estere og amider
substituerte pyrrolidiner
substituerte pyrrolidoner
substituerte arylsulfonsyrer og deres salter, estere og amider substituerte styrener
substituerte tetrahydrooksadiazindioner
substituerte tetrahydrooksadiazol'dioner
substituerte tetrahydrometanoindener
substituerte tetrahydrodiazoltioner
substituerte tetrahydrotiadiazintioner
substituerte tetrahydrotiadiazoldioner
substituerte aromatiske tiokarboksylsyreamider substituerte tiokarboksylsyrer og deres salter, estere og amider substituerte tiolkarbamater
substituerte tiourinstoffer
substituerte tiofosforsyrer og deres salter, estere og amider substituerte triaziner
substituerte triazoler
substituerte uraciler
substituerte uretidindioner.
De sistnevnte herbicide forbindelser kan etter ønske anvendes før eller etter de virksomme enkeltstoffer eller blandinger ifølge oppfinnelsen.
Tilblandingen av disse midler til herbicidene ifølge oppfinnelsen kan skje i yektforholSet 1:10 til 10:1. Det samme gjelder for olje, fungicider, nematocider, insekticider, baktericider, mot-giftmidler og vekstregulatorer.
Midlene oppviser en sterk herbicid virkning og kan derfor anvendes som ugrasdrepende midler eller til bekjempelse av uønsket plantevekst., Om midlene anvendes som totale eller selektive midler, avhé'nger hovedsakelig av den mengde virksomt stoff som anvendes pr.
flateenhet. •
Med ugras eller uønsket plantevekst menes her alle enfrø-bladede og tofrøbladede planter som vokser på steder hvor de ikke er ønsket.
Således kan eksempelvis de følgende planter bekjempes med midlene ifølge oppfinnelsen:
Planter av grasfamilien, så som
Rosaceae, f.eks.
Fragaria
Cucurbitaceae, f.eks.
Cucumis spp.
Liliaceae, f.eks.
Allium spp.
Vitaceae, f.eks.
Vitis vinifera
Bromeliaceae>f.eks.
Ananas satiyus.
Eksempel 1
I et drivhus ble forskjellige planter ved en veksthøyde på 2-»18 cm behandlet med de følgende virksomme enkeltstoffer dg deres blandinger som dispérsjon, emulsjon, oppløsning, i forsøks-kasser med størrels.e 20 x 20 x 15 cm:
I 3-isopropyl~2,1,3-benzotiadiazinon-(4)-2,2-dioksyd
II 3-=»'isppropyl-2,1, 3-benzotiadiazinon- (4) ~2, 2-dioksyd-na|triumsalt III 3-isopropyl-2,1,3-benzotiadiazinon~(4) .-2, 2-<dioksyd-dimetyl-aminsalt
IV 3-isopropyl«2, 1,3-*benzotiadiazinon~ (4)«2,2-dioksyd-etanolamin-salt
V Cykloheksyl.-3-(2,4-diklorfenoksy)-akrylat,
i hvert tilfelle 0,25 - 0,5 - 0, 15' og 1,0. kg/ha aktiyt stoff.
I + V, II + V, III + V i hvert tilfelle 0,25 + 0,75; 0,75 + 0,25;
0,5 +0,5 kg/ha aktivt stoff.
Deretter ble jordsmonnet satt under vann i 10 cm høyde.
Etter 12-18 dager ble det slått fast at blandingene visté en bedre herbicid virkning ved samme forenlighet medl kulturplantene enn de
.. enkelte. virksomme, stoffer.
Forsøksresultatet vil fremgå av den følgende .tabell.
Eksempel 2
I et drivhus ble forskjellige planter ved en veksthøyde på 3-25 cm behandlet med de følgende virksomme enkeltstdffer og deres blandinger som emulsjon, dispersjon eller vandig løsning:
I 3-isopropyl-2,1,3-benzotiadiazinon-(4)-2,2-dioksyd
II 3-isopropyl-2,1,3-benzotiadiazinon-(4)-2,2-dioksyd-natriumsalt
III 3-isopropyl-2,1,3-benzotiadiazinon-(4)-2,2-dioksyd-dimetylaminsalt
IV 3-isopropyl-2,1,3-benzotiadiazinon-(4)-2,2-dioksyd-etanolaminsalt
V Cykloheksyl-3-(2,4-diklorfenoksy)-akrylat
i hvert tilfelle 1,0 - 1,5 - 3,0 og 4,0 kg/ha aktivt stoff.
I + V, II + V, III + V, IV + V i hvert tilfelle 3 + 1,
1,5 + 1,5 kg/ha aktivt stoff,
og, .til sammenligning med
VI a-(2C3-diklorfenoksy)-propionsyre
med 3,0 og 4,0 kg/ha aktivt stoff
I +VI: 1,0 + 3,0 kg/ha aktivt stoff
II + VI: 1,0 + 3,0 kg/ha aktivt stoff.
Derétter ble jordsmonnet satt utider vann i 10 cm høyde. Etter 12-18 dager ble det slått fast at blandingene viste en bedre forenlighet med kulturplanten og en bedre herbicid virkning enn stoffet VI og blandingene I + VI og II + VI.
Forsøksresultatet vil fremgå av den følgende tabell.
Eksempel 3
I et drivhus ble forsøkskasser fyllt med leirholdjig sand-jord, og forskjellige frø ble sådd. Deretter ble jorden behandlet med de følgende virksomme enkeltstoffer og deres blandinger som granulat:i 3-isopropyl-^,<l, 3-benzotiadiazinon-(4)-2, 2-dioksyd II . 3-isopropyl-2,1,3-benzotiadiazihon-(4)-2,2-dioksyd-natriumsalt III 3-isopropyl-2 ,1, 3-be!nzotiadiazinon-(4) -2 , 2-dipksyd-
r ~~dimetylami nsalt. ■ . }
IV 3-isopropyl-2,1,3-benzotiadiazinon~(4)-2,2-dioksyd-etanolaminsalt
V ' Cykloheksyl-3-(2,4-diklorfenoksy)-akrylat
i hvert tilfelle 1,0 - 1,5 - 2,0 - 2,5 - 3,0 - 4,0 -3/5 5,0 - 6,0 - 7,5 og 10 kg/ha aktivt stoff
I + V, II + V, III .+ V, IV + V
i hvert tilfelle 1,5 + 1,0; l,5[j- 1,5; 1,0 + 3,0; 3,0 + 1,0;
3,0 +2,0; 4,5 + 3,0 og 6,0 + 4,0 kg/ha aktivt stoff.
Deretter ble jordsmonnet satt under vann i 10 cm høyde. Etter 3-4 uker ble det slått fast at blandingene I + V, II + V, III + V, IV + V i hvert tilfelle 1,5 + 1,0; 1,5 + 1,5; 1,0 + 3,0; 3,0 +1,0; 3,0 + 2,0; 4,5 + 3,0, viste en bedre herbicid virkning ved samme f orehlighet med kulturplant en enn de enpcelté virksomme stoffer, og at blandingene I + V, II + V, III + V, IV + V, i hvert tilfelle 6,0 + 4,0 kg/ha aktivt stoff, viste en bedre forenlig/hét med Oryza sativa enn de enkelte virksomme stoffer i en mengde på 10 kg/ha.
Forsøksresultatet vil fremgå av den følgende tabell.
Claims (1)
- Herbicid, karakterisert ved at det inneholder en blanding ava) en forbindelse med formelenhvor er lavere alkyl, eller salter derav, og b) en forbindelse med formelenhvor R er en eventuelt med halogen eller metyl substituert cykloalkylrest med 3-12 C-atomer, x er like eller forskjellige substituenter fra gruppen halogen, metyl og metoksy, og n = 0 til 3.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE2403037A DE2403037A1 (de) | 1974-01-23 | 1974-01-23 | Herbizid |
Publications (1)
Publication Number | Publication Date |
---|---|
NO750117L true NO750117L (no) | 1975-08-18 |
Family
ID=5905438
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
NO750117A NO750117L (no) | 1974-01-23 | 1975-01-15 |
Country Status (11)
Country | Link |
---|---|
JP (1) | JPS50101535A (no) |
BE (1) | BE823654A (no) |
DE (1) | DE2403037A1 (no) |
DK (1) | DK632274A (no) |
FR (1) | FR2258128A1 (no) |
IL (1) | IL46337A0 (no) |
IT (1) | IT1050271B (no) |
NL (1) | NL7500477A (no) |
NO (1) | NO750117L (no) |
SE (1) | SE7500683L (no) |
ZA (1) | ZA75447B (no) |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP4003236B2 (ja) * | 1995-09-28 | 2007-11-07 | 住友化学株式会社 | 農薬含有粒状肥料組成物およびその製造方法 |
-
1974
- 1974-01-23 DE DE2403037A patent/DE2403037A1/de active Pending
- 1974-12-05 DK DK632274A patent/DK632274A/da unknown
- 1974-12-13 JP JP49142616A patent/JPS50101535A/ja active Pending
- 1974-12-20 BE BE151758A patent/BE823654A/xx unknown
- 1974-12-25 IL IL46337A patent/IL46337A0/xx unknown
-
1975
- 1975-01-15 NL NL7500477A patent/NL7500477A/xx unknown
- 1975-01-15 NO NO750117A patent/NO750117L/no unknown
- 1975-01-17 IT IT47730/75A patent/IT1050271B/it active
- 1975-01-17 FR FR7501428A patent/FR2258128A1/fr not_active Withdrawn
- 1975-01-22 SE SE7500683A patent/SE7500683L/xx unknown
- 1975-01-22 ZA ZA00750447A patent/ZA75447B/xx unknown
Also Published As
Publication number | Publication date |
---|---|
JPS50101535A (no) | 1975-08-12 |
IL46337A0 (en) | 1975-03-13 |
DE2403037A1 (de) | 1975-07-24 |
IT1050271B (it) | 1981-03-10 |
BE823654A (fr) | 1975-06-20 |
SE7500683L (no) | 1975-07-24 |
FR2258128A1 (en) | 1975-08-18 |
ZA75447B (en) | 1976-02-25 |
NL7500477A (nl) | 1975-07-25 |
DK632274A (no) | 1975-09-29 |
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