NO20062531L - Zirconia-containing catalyst support material - Google Patents

Zirconia-containing catalyst support material

Info

Publication number
NO20062531L
NO20062531L NO20062531A NO20062531A NO20062531L NO 20062531 L NO20062531 L NO 20062531L NO 20062531 A NO20062531 A NO 20062531A NO 20062531 A NO20062531 A NO 20062531A NO 20062531 L NO20062531 L NO 20062531L
Authority
NO
Norway
Prior art keywords
catalyst
support material
palladium
relates
zirconia
Prior art date
Application number
NO20062531A
Other languages
Norwegian (no)
Inventor
Alfred Hagemeyer
Tao Wang
Leslie E Wade
Victor Wong
Valery Sokolovskii
Jun Han
David Lowe
Original Assignee
Celanese Int Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Celanese Int Corp filed Critical Celanese Int Corp
Publication of NO20062531L publication Critical patent/NO20062531L/en

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/48—Silver or gold
    • B01J23/52—Gold
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • B01J21/066—Zirconium or hafnium; Oxides or hydroxides thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/007—Mixed salts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/44—Palladium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/40—Catalysts, in general, characterised by their form or physical properties characterised by dimensions, e.g. grain size
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • B01J37/0018—Addition of a binding agent or of material, later completely removed among others as result of heat treatment, leaching or washing,(e.g. forming of pores; protective layer, desintegrating by heat)
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/16—Reducing
    • B01J37/18—Reducing with gases containing free hydrogen
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/04—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides onto unsaturated carbon-to-carbon bonds
    • C07C67/05—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides onto unsaturated carbon-to-carbon bonds with oxidation
    • C07C67/055—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides onto unsaturated carbon-to-carbon bonds with oxidation in the presence of platinum group metals or their compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • B01J35/396—Distribution of the active metal ingredient
    • B01J35/397—Egg shell like
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • B01J35/396—Distribution of the active metal ingredient
    • B01J35/398—Egg yolk like
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • B01J35/396—Distribution of the active metal ingredient
    • B01J35/399—Distribution of the active metal ingredient homogeneously throughout the support particle
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/612—Surface area less than 10 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/613—10-100 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/615—100-500 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/16—Reducing

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

Oppfinnelsen angår minst fire forskjellige aspekter vedrørende katalysatorstruktur, fremgangsmåter for fremstilling av katalysatorene og anvendelse av katalysatorene ved fremstilling av alkenylalkanoater. De forskjellige aspekter ved oppfinnelsen, hver for seg eller i kombinasjon, er spesielt rettet på å forbedre produksjonen av alkenylalkanoalter og VA, innbefattende minskning av biprodukter og forbedre produksjonseffektiviteten. Et første aspekt ved oppfinnelsen angår en palladium/gull katalysator eller prekatalysator (eventuelt kalsinert) som innbefatter rhodium eller et annet metall. Et andre aspekt angår en palladium/gull katalysator eller prekatalysator som er basert på et lagdelt bærermateriale hvor ett lag i bærermaterialet er hovedsakelig fritt for katalytiske komponenter. Et tredje aspekt angår en palladium/gull katalysator eller pre-katalysator på et zirkoniaholdig bærermateriale. Et fjerde aspekt angår en palladium/gull katalysator eller pre-katalysator som fremstilles av hovedsakelig kloridfrie katalytiske komponenterThe invention relates to at least four different aspects regarding catalyst structure, processes for preparing the catalysts and the use of the catalysts in the preparation of alkenyl alkanoates. The various aspects of the invention, individually or in combination, are particularly aimed at improving the production of alkenyl alkanoalts and VA, including the by-product reduction and the production efficiency. A first aspect of the invention relates to a palladium / gold catalyst or pre-catalyst (optionally calcined) which includes rhodium or another metal. A second aspect relates to a palladium / gold catalyst or precatalyst based on a layered support material wherein one layer of the support material is substantially free of catalytic components. A third aspect relates to a palladium / gold catalyst or pre-catalyst on a zirconia-containing support material. A fourth aspect relates to a palladium / gold catalyst or pre-catalyst made from substantially chloride-free catalytic components

NO20062531A 2003-12-19 2006-06-01 Zirconia-containing catalyst support material NO20062531L (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US53148603P 2003-12-19 2003-12-19
PCT/US2004/039039 WO2005061107A1 (en) 2003-12-19 2004-11-19 Zirconia containing support material for catalysts

Publications (1)

Publication Number Publication Date
NO20062531L true NO20062531L (en) 2006-07-03

Family

ID=34710229

Family Applications (1)

Application Number Title Priority Date Filing Date
NO20062531A NO20062531L (en) 2003-12-19 2006-06-01 Zirconia-containing catalyst support material

Country Status (14)

Country Link
EP (1) EP1694436A1 (en)
JP (1) JP4772695B2 (en)
KR (1) KR100886048B1 (en)
CN (1) CN100457257C (en)
AU (1) AU2004305515C1 (en)
BR (1) BRPI0417185A (en)
CA (1) CA2547187C (en)
NO (1) NO20062531L (en)
NZ (1) NZ547072A (en)
PL (1) PL215127B1 (en)
RU (2) RU2006119185A (en)
UA (1) UA96563C2 (en)
WO (1) WO2005061107A1 (en)
ZA (1) ZA200604362B (en)

Families Citing this family (19)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8168562B2 (en) 2006-02-02 2012-05-01 Lyondell Chemical Technology, L.P. Preparation of palladium-gold catalysts
DE102007025358A1 (en) * 2007-05-31 2009-01-08 Süd-Chemie AG Process for the preparation of a coated with Pd and / or Au shell catalyst
DE102007025362A1 (en) 2007-05-31 2008-12-11 Süd-Chemie AG Doped Pd / Au coated catalyst, process for its preparation and its use
DE102007025443A1 (en) 2007-05-31 2008-12-04 Süd-Chemie AG Pd / Au coated catalyst containing HfO 2, process for its preparation and its use
DE102007025442B4 (en) 2007-05-31 2023-03-02 Clariant International Ltd. Use of a device for producing a coated catalyst and coated catalyst
DE102007025223A1 (en) 2007-05-31 2008-12-04 Süd-Chemie AG Zirconia-doped VAM shell catalyst, process for its preparation and its use
DE102007025356A1 (en) * 2007-05-31 2009-01-08 Süd-Chemie AG Process for the preparation of a coated catalyst and coated catalyst
DE102007025444A1 (en) * 2007-05-31 2008-12-11 Süd-Chemie AG VAM shell catalyst, process for its preparation and its use
DE102007043446B4 (en) 2007-09-12 2013-08-22 Süd-Chemie Ip Gmbh & Co. Kg Catalyst support with increased thermal conductivity
DE102007043447B4 (en) 2007-09-12 2014-02-13 Süd-Chemie Ip Gmbh & Co. Kg Catalyst support with increased thermal conductivity
DE102008058971A1 (en) * 2008-11-25 2010-07-15 Süd-Chemie AG Shell catalyst, process for its preparation and use
DE202008017277U1 (en) * 2008-11-30 2009-04-30 Süd-Chemie AG catalyst support
DE102008059340A1 (en) 2008-11-30 2010-06-10 Süd-Chemie AG Catalyst support, process for its preparation and its use
DE102008059342A1 (en) 2008-11-30 2010-06-10 Süd-Chemie AG Shell catalyst, process for its preparation and use
DE102010026462A1 (en) * 2010-07-08 2012-01-12 Süd-Chemie AG Process for the preparation of a coated catalyst and coated catalyst
CN102153189A (en) * 2010-12-16 2011-08-17 哈尔滨工业大学 Method for removing organic matters in water through pumice catalytic ozonation
DE102012008714A1 (en) * 2012-05-03 2013-11-07 Clariant Produkte (Deutschland) Gmbh Pre-impregnation of coated catalysts with an acetate
CN106215561B (en) * 2016-08-31 2018-04-20 苏州贝捷环保设备有限公司 A kind of coal-fired flue gas treatment method
CN107096532B (en) * 2017-05-16 2019-12-10 嘉兴学院 Au-ZrO 2 catalyst and application thereof

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE19501891C1 (en) * 1995-01-23 1996-09-26 Degussa Process for the preparation of a supported catalyst and its use for the production of vinyl acetate
US6072078A (en) * 1997-12-12 2000-06-06 Celanese International Corporation Vinyl acetate production using a catalyst comprising palladium, gold, copper and any of certain fourth metals
US6015769A (en) * 1998-06-02 2000-01-18 Celanese International Corporation Vinyl acetate catalyst comprising metallic palladium, gold and copper supported on a carrier and prepared with potassium aurate
DE19843693A1 (en) * 1998-09-24 2000-03-30 Degussa Catalyst for vinyl acetate production from ethylene, acetic acid and oxygen contains palladium and other metals on a pyrogenic mixed oxide support based on silicon, aluminum, titanium and/or zirconium oxide
US6358882B1 (en) * 1998-12-08 2002-03-19 The Standard Oil Company Fluid bed vinyl acetate catalyst
DE10030039A1 (en) * 2000-06-17 2002-01-10 Celanese Chem Europe Gmbh Preparation of catalyst, useful in gas phase production of vinyl acetate, involves impregnation with alkaline solution of palladium and other metal compounds fixed by conversion to insoluble compounds on contact with support

Also Published As

Publication number Publication date
WO2005061107A1 (en) 2005-07-07
CA2547187C (en) 2010-11-02
CN1894035A (en) 2007-01-10
AU2004305515B2 (en) 2008-08-28
CA2547187A1 (en) 2005-07-07
AU2004305515A1 (en) 2005-07-07
RU2006119185A (en) 2007-12-20
RU2011131292A (en) 2013-02-10
CN100457257C (en) 2009-02-04
KR20060103514A (en) 2006-10-02
AU2004305515C1 (en) 2009-06-25
ZA200604362B (en) 2007-11-28
JP4772695B2 (en) 2011-09-14
EP1694436A1 (en) 2006-08-30
KR100886048B1 (en) 2009-02-26
PL215127B1 (en) 2013-10-31
NZ547072A (en) 2010-05-28
UA96563C2 (en) 2011-11-25
BRPI0417185A (en) 2007-03-06
PL380021A1 (en) 2006-12-11
JP2007514543A (en) 2007-06-07

Similar Documents

Publication Publication Date Title
NO20062531L (en) Zirconia-containing catalyst support material
NO20062528L (en) Layered catalyst support material
NO20062529L (en) Halogen-free precursor materials for catalysts
MY142644A (en) Methods of making alkenyl alkanoates
JP2010504205A5 (en)
TW200633776A (en) Modified support materials for catalysts
MY158126A (en) Supported palladium-gold catalysts and preparation of vinyl acetate therewith
DK1222024T3 (en) Process for producing synthesis gas using nickel-rhodium-based catalysts
ATE278468T1 (en) THREE-DIMENSIONAL CATALYST NETWORK KNITTED IN TWO OR MORE LAYERS
HUP0102638A2 (en) Vinyl acetate catalyst comprising metallic palladium and gold prepared with potassium aurate
JP2010533113A5 (en)
WO2001053196A8 (en) Thermal shock resistant catalysts for synthesis gas production
AR017429A1 (en) VINYL ACETATE CATALYST INCLUDING PALADIO, GOLD, COPPER AND A FOUR METAL AND PROCESS FOR THE PRODUCTION OF VINYL ACETATE BY REACTION OF ETHYLENE, OXYGEN OR ACETIC ACID AS REAGENTS
RU2012131219A (en) EXHAUST SYSTEM FOR A VEHICLE HAVING AN ENGINE WITH IGNITION FROM COMPRESSION WITH THE START-STOP SYSTEM
NO20062530L (en) Rhodium-containing catalysts
JP6293416B2 (en) Method for autothermal reforming of hydrocarbon compounds
WO2007019390A3 (en) Enhancement of surface-active solid-phase heterogeneous catalysts
JP2010017707A (en) Oxidation catalyst
RU2008129062A (en) SUBSTANCES OF CATALYSTS USED IN FISCHER-TROPSH SYNTHESIS AND THEIR APPLICATION
WO2007134723A3 (en) Method for producing chlorine by gas phase oxidation
DE602004005449D1 (en) SUPPORTED METAL PHOSPHINE AMINOPHOSPHINE CATALYSTS
ATE500878T1 (en) HIGHLY EFFICIENT CATALYTIC PROCESS
TH63202A (en) Metal catalyst And methods of preparation and use of such substances
RU2004111480A (en) METHOD FOR PRODUCING N-METHYLANILINE
Chen et al. Different Wetting Behaviors of Pd and Rh on the CeO 2 (111) Surface. A DFT and Hrtem Study

Legal Events

Date Code Title Description
FC2A Withdrawal, rejection or dismissal of laid open patent application