NO20060301L - Vannfri bearbeiding av metan til metansulfonsyre, metanol og andre forbindelser - Google Patents
Vannfri bearbeiding av metan til metansulfonsyre, metanol og andre forbindelserInfo
- Publication number
- NO20060301L NO20060301L NO20060301A NO20060301A NO20060301L NO 20060301 L NO20060301 L NO 20060301L NO 20060301 A NO20060301 A NO 20060301A NO 20060301 A NO20060301 A NO 20060301A NO 20060301 L NO20060301 L NO 20060301L
- Authority
- NO
- Norway
- Prior art keywords
- methane
- radicals
- msa
- reactor
- methanesulfonic acid
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
- C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
- C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C303/00—Preparation of esters or amides of sulfuric acids; Preparation of sulfonic acids or of their esters, halides, anhydrides or amides
- C07C303/02—Preparation of esters or amides of sulfuric acids; Preparation of sulfonic acids or of their esters, halides, anhydrides or amides of sulfonic acids or halides thereof
- C07C303/04—Preparation of esters or amides of sulfuric acids; Preparation of sulfonic acids or of their esters, halides, anhydrides or amides of sulfonic acids or halides thereof by substitution of hydrogen atoms by sulfo or halosulfonyl groups
- C07C303/06—Preparation of esters or amides of sulfuric acids; Preparation of sulfonic acids or of their esters, halides, anhydrides or amides of sulfonic acids or halides thereof by substitution of hydrogen atoms by sulfo or halosulfonyl groups by reaction with sulfuric acid or sulfur trioxide
-
- C—CHEMISTRY; METALLURGY
- C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
- C12C—BEER; PREPARATION OF BEER BY FERMENTATION; PREPARATION OF MALT FOR MAKING BEER; PREPARATION OF HOPS FOR MAKING BEER
- C12C11/00—Fermentation processes for beer
- C12C11/02—Pitching yeast
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/582—Recycling of unreacted starting or intermediate materials
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- General Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- Food Science & Technology (AREA)
- Bioinformatics & Cheminformatics (AREA)
- General Engineering & Computer Science (AREA)
- Biochemistry (AREA)
- Genetics & Genomics (AREA)
- Mycology (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Microbiology (AREA)
- Combustion & Propulsion (AREA)
- Inorganic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
Radikaler med uparede elektroner initierer en kjedereaksjon hvor lavere hydrokarboner som metan omdannes til oksygenerte væsker. En initiator som Marshalls syre anvendes til å danne metylradikaler. Disse radikaler kombinerer seg med svoveltrioksid og danner metylsulfonatradikaler som så fjerner hydrogen fra metan tilført i reaktoren, og det dannes stabil metansulfonsyre (MSA, HCSOH) og nye metylradikaler slik at kjedereaksjonen opprettholdes mens metan og S0tilføres kontinuerlig til reaktoren. Vannfne betingelser unngår bruk eller dannelse av vann. MSA i reaktoren øker løseligheten av metan og SOog reaksjonshastighetene. MSA kan oppvarmes for å frigjøre metanol, eller bli bearbeidet til bensin, dimetyleter, formaldehyd eller andre verdifulle væsker. Eventuelt S0frigjort ved behandlingen av MSA kan bli oksidert til SOog resirkulert i systemet. Forsøk viser svært høye utbytter og selektiviteter (over 95 %).
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US48018303P | 2003-06-21 | 2003-06-21 | |
PCT/US2004/019977 WO2005069751A2 (en) | 2003-06-21 | 2004-06-21 | Anhydrous processing of methane into methane-sulfonic acid, methanol, and other compounds |
Publications (1)
Publication Number | Publication Date |
---|---|
NO20060301L true NO20060301L (no) | 2006-03-08 |
Family
ID=34806865
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
NO20060301A NO20060301L (no) | 2003-06-21 | 2006-01-20 | Vannfri bearbeiding av metan til metansulfonsyre, metanol og andre forbindelser |
Country Status (4)
Country | Link |
---|---|
US (1) | US7282603B2 (no) |
NO (1) | NO20060301L (no) |
OA (1) | OA13183A (no) |
WO (1) | WO2005069751A2 (no) |
Families Citing this family (57)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US7838708B2 (en) | 2001-06-20 | 2010-11-23 | Grt, Inc. | Hydrocarbon conversion process improvements |
EA200500779A1 (ru) * | 2002-11-05 | 2006-02-24 | Алан К. Ричардс | Безводное преобразование метана и других легких алканов в метанол и другие производные |
US20050171393A1 (en) | 2003-07-15 | 2005-08-04 | Lorkovic Ivan M. | Hydrocarbon synthesis |
WO2005021468A1 (en) | 2003-07-15 | 2005-03-10 | Grt, Inc. | Hydrocarbon synthesis |
US20050045467A1 (en) * | 2003-09-03 | 2005-03-03 | King Fahd University Of Petroleum And Minerals | Method for the conversion of methane into hydrogen and higher hydrocarbons using UV laser |
US20080275284A1 (en) | 2004-04-16 | 2008-11-06 | Marathon Oil Company | Process for converting gaseous alkanes to liquid hydrocarbons |
US7244867B2 (en) | 2004-04-16 | 2007-07-17 | Marathon Oil Company | Process for converting gaseous alkanes to liquid hydrocarbons |
US8642822B2 (en) | 2004-04-16 | 2014-02-04 | Marathon Gtf Technology, Ltd. | Processes for converting gaseous alkanes to liquid hydrocarbons using microchannel reactor |
US7674941B2 (en) | 2004-04-16 | 2010-03-09 | Marathon Gtf Technology, Ltd. | Processes for converting gaseous alkanes to liquid hydrocarbons |
US8173851B2 (en) | 2004-04-16 | 2012-05-08 | Marathon Gtf Technology, Ltd. | Processes for converting gaseous alkanes to liquid hydrocarbons |
US20060100469A1 (en) | 2004-04-16 | 2006-05-11 | Waycuilis John J | Process for converting gaseous alkanes to olefins and liquid hydrocarbons |
US7119226B2 (en) * | 2004-04-20 | 2006-10-10 | The Penn State Research Foundation | Process for the conversion of methane |
EP1993979A4 (en) | 2006-02-03 | 2011-07-06 | Grt Inc | CONTINUOUS PROCESS FOR CONVERTING NATURAL GAS TO LIQUID HYDROCARBONS |
UA95943C2 (ru) | 2006-02-03 | 2011-09-26 | ДжиАрТи, ИНК. | Отделение легких газов от галогенов |
US20070282151A1 (en) * | 2006-05-19 | 2007-12-06 | Richards Alan K | Manufacture of higher hydrocarbons from methane, via methanesulfonic acid, sulfene, and other pathways |
EA017699B1 (ru) | 2007-05-24 | 2013-02-28 | Грт, Инк. | Зонный реактор с обратимым захватыванием и высвобождением галогеноводородов |
US8026403B2 (en) | 2007-06-27 | 2011-09-27 | H R D Corporation | System and process for production of liquid product from light gas |
US8394861B2 (en) | 2007-06-27 | 2013-03-12 | Hrd Corporation | Gasification of carbonaceous materials and gas to liquid processes |
US8282810B2 (en) | 2008-06-13 | 2012-10-09 | Marathon Gtf Technology, Ltd. | Bromine-based method and system for converting gaseous alkanes to liquid hydrocarbons using electrolysis for bromine recovery |
SG192538A1 (en) | 2008-07-18 | 2013-08-30 | Grt Inc | Continuous process for converting natural gas to liquid hydrocarbons |
US8367884B2 (en) | 2010-03-02 | 2013-02-05 | Marathon Gtf Technology, Ltd. | Processes and systems for the staged synthesis of alkyl bromides |
US8198495B2 (en) | 2010-03-02 | 2012-06-12 | Marathon Gtf Technology, Ltd. | Processes and systems for the staged synthesis of alkyl bromides |
US8815050B2 (en) | 2011-03-22 | 2014-08-26 | Marathon Gtf Technology, Ltd. | Processes and systems for drying liquid bromine |
US8436220B2 (en) | 2011-06-10 | 2013-05-07 | Marathon Gtf Technology, Ltd. | Processes and systems for demethanization of brominated hydrocarbons |
US8829256B2 (en) | 2011-06-30 | 2014-09-09 | Gtc Technology Us, Llc | Processes and systems for fractionation of brominated hydrocarbons in the conversion of natural gas to liquid hydrocarbons |
US8802908B2 (en) | 2011-10-21 | 2014-08-12 | Marathon Gtf Technology, Ltd. | Processes and systems for separate, parallel methane and higher alkanes' bromination |
KR101346021B1 (ko) * | 2011-12-09 | 2013-12-31 | 주식회사 엠에스씨 | 주석-은 합금 도금액의 생성방법 및 그 도금액 |
US9193641B2 (en) | 2011-12-16 | 2015-11-24 | Gtc Technology Us, Llc | Processes and systems for conversion of alkyl bromides to higher molecular weight hydrocarbons in circulating catalyst reactor-regenerator systems |
CN105722819A (zh) | 2013-11-13 | 2016-06-29 | 格里洛凯米股份有限公司 | 由三氧化硫和烷烃制备烷基磺酸的方法 |
JP6412570B2 (ja) * | 2013-11-18 | 2018-10-24 | グリロ‐ヴェルケ アーゲー | アルカンおよび発煙硫酸からアルカンスルホン酸を製造するための新規な開始剤 |
MY188862A (en) | 2015-11-10 | 2022-01-10 | Basf Se | Process for purifying alkanesulfonic acids |
US9938944B2 (en) | 2015-11-25 | 2018-04-10 | General Electric Company | System including duel fuel injection engine and method of operation |
BR112019010643A2 (pt) | 2016-11-28 | 2019-10-01 | Grillo Werke Ag | sulfonação de alcanos isenta de solventes |
US20200115332A1 (en) | 2017-02-07 | 2020-04-16 | Grillo-Werke Ag | Method for the production of alkane sulfonic acids |
TW201841881A (zh) | 2017-04-18 | 2018-12-01 | 德商巴斯夫歐洲公司 | 純化烷烴磺酸酐的方法及使用純化的烷烴磺酸酐製造烷烴磺酸的方法 |
WO2018208701A1 (en) * | 2017-05-11 | 2018-11-15 | Arkema Inc. | Processes and systems for recovering methanesulfonic acid in purified form |
WO2018219726A1 (en) | 2017-05-30 | 2018-12-06 | Basf Se | Process for the production of alkanesulfonic acids |
TW201904938A (zh) | 2017-06-30 | 2019-02-01 | 德商葛里洛沃克股份有限公司 | 用於生產烷磺酸的調節劑 |
CA3072213A1 (en) | 2017-08-18 | 2019-02-21 | So3 Plus, Llc | Apparatus and method for producing hydrocarbons |
SG11202007292TA (en) | 2018-02-07 | 2020-08-28 | Basf Se | Process for the manufacturing of alkanesulfonic acids |
FR3077817B1 (fr) * | 2018-02-14 | 2020-02-28 | Arkema France | Procede de synthese industrielle en continu d'acide alcane-sulfonique |
TWI714964B (zh) | 2018-02-16 | 2021-01-01 | 巴斯夫歐洲公司 | 用於烷磺酸之合成的催化劑 |
TW201934533A (zh) | 2018-02-16 | 2019-09-01 | 德商格里洛工廠股份有限公司 | 使用異相催化自烷及三氧化硫直接合成烷磺酸 |
EP4159714A1 (en) | 2018-03-10 | 2023-04-05 | Veolia North America Regeneration Services, LLC | Compounds, processes, and machinery for converting methane gas into methane sulfonic acid |
TWI799586B (zh) * | 2018-05-25 | 2023-04-21 | 德商格里洛工廠股份有限公司 | 自三氧化硫及鹵烷製備鹵代烷磺酸的方法 |
WO2020064466A1 (en) | 2018-09-25 | 2020-04-02 | Basf Se | Catalyst for the synthesis of alkanesulfonic acids |
WO2020064515A1 (en) | 2018-09-25 | 2020-04-02 | Basf Se | Cations as catalyst in the production of alkane sulfonic acids |
WO2020064573A1 (en) | 2018-09-25 | 2020-04-02 | Basf Se | Catalysts for the synthesis of alkanesulfonic acids |
WO2020126855A1 (en) | 2018-12-21 | 2020-06-25 | Basf Se | Mixture comprising methanesulfonic acid and sulfuric acid |
WO2020212299A1 (en) | 2019-04-18 | 2020-10-22 | Basf Se | Process for the production of anhydrous methanesulfonic acid from methane and so3 |
EP3763701A1 (en) | 2019-07-10 | 2021-01-13 | Grillo-Werke AG | Improved process for the purification of methane sulfonic acid |
EP3997067B1 (en) | 2019-07-10 | 2023-09-06 | Basf Se | Method for reducing the concentration of so 3 in a reaction mixture comprising methane sulfonic acid and so 3 |
EP3782981A1 (en) | 2019-08-20 | 2021-02-24 | Basf Se | Catalysts for the synthesis of alkanesulfonic acids |
WO2021063730A1 (en) | 2019-10-01 | 2021-04-08 | Basf Se | Process for manufacturing alkanesulfonic acids |
US20220324794A1 (en) * | 2021-04-07 | 2022-10-13 | Veolia North American Regeneration Services, LLC | Method for removing so3 and ch4 from mixtures which contain methane sulfonic acid |
US11767290B2 (en) | 2021-04-07 | 2023-09-26 | Veolia North America Regeneration Services, Llc | Method for removing SO3 and CH4 from mixtures which contain methane sulfonic acid |
EP4151774A1 (en) | 2021-09-21 | 2023-03-22 | Studiengesellschaft Kohle mbH | Process for the production of methane sulfonic acid |
Family Cites Families (16)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2493038A (en) * | 1946-05-31 | 1950-01-03 | Houdry Process Corp | Reaction of methane with sulfur trioxide |
US2492984A (en) * | 1946-05-31 | 1950-01-03 | Houdry Process Corp | Organic reactions |
GB632820A (en) | 1946-05-31 | 1949-12-05 | Houdry Process Corp | Improvements in or relating to the production of organic compounds by chemical transformation of methane or its sulfonated and/or oxygenated derivatives |
US2553576A (en) * | 1947-03-26 | 1951-05-22 | Houdry Process Corp | Production of organic compounds from methane sulfonic acid |
US3927189A (en) * | 1974-04-12 | 1975-12-16 | Du Pont | Method for making peroxydisulfuric acid and salts thereof |
US3969427A (en) * | 1974-11-19 | 1976-07-13 | Mobil Oil Corporation | Conversion of alcohols and/or ethers to hydrocarbons |
US5233113A (en) * | 1991-02-15 | 1993-08-03 | Catalytica, Inc. | Process for converting lower alkanes to esters |
US5306855A (en) * | 1991-02-15 | 1994-04-26 | Catalytica, Inc. | Catalytic process for converting lower alkanes to esters, alcohols, and to hydrocarbons |
DE19641483A1 (de) * | 1996-10-09 | 1998-04-16 | Basf Ag | Verfahren zur Herstellung von Methansulfonsäure |
DK128697A (da) * | 1997-11-12 | 1999-05-13 | Niels J Bjerrum | Katalyseproces |
DE19854428A1 (de) * | 1998-11-25 | 2000-05-31 | Basf Ag | Verfahren zur Herstellung von Alkansulfonsäuren |
DE19904262A1 (de) * | 1999-02-03 | 2000-08-10 | Basf Ag | Verfahren zur Herstellung von Alkansulfonsäuren |
US6538162B2 (en) * | 2001-01-30 | 2003-03-25 | Exxonmobil Chemical Patents Inc. | Method for converting alkanes to oxygenates |
US6384271B1 (en) * | 2001-05-04 | 2002-05-07 | E.I. Du Pont De Nemours And Company | Sulfonation, sulfation and sulfamation |
US6452058B1 (en) * | 2001-05-21 | 2002-09-17 | Dow Global Technologies Inc. | Oxidative halogenation of C1 hydrocarbons to halogenated C1 hydrocarbons and integrated processes related thereto |
DE10132526A1 (de) | 2001-07-09 | 2003-01-30 | Ruhrgas Ag | Verfahren zum Herstellen eines Alkanderivats |
-
2004
- 2004-06-21 WO PCT/US2004/019977 patent/WO2005069751A2/en active Application Filing
- 2004-06-21 OA OA1200500373A patent/OA13183A/en unknown
- 2004-06-21 US US10/873,361 patent/US7282603B2/en not_active Expired - Lifetime
-
2006
- 2006-01-20 NO NO20060301A patent/NO20060301L/no not_active Application Discontinuation
Also Published As
Publication number | Publication date |
---|---|
US7282603B2 (en) | 2007-10-16 |
WO2005069751A3 (en) | 2006-09-21 |
WO2005069751A2 (en) | 2005-08-04 |
US20050070614A1 (en) | 2005-03-31 |
OA13183A (en) | 2006-12-13 |
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