NO126204B - - Google Patents

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Publication number: NO126204B
Authority: NO; Norway
Prior art keywords: copper; nickel; carrier; suspension; oxide
Prior art date: 1969-10-04

Application number

NO02021/70A

Other languages

English (en)

Norwegian (no)

Inventor

Jacobus Jozef Marinus Eurlings

John Wilhelm Geus

Cornelis Antonius Ma Weterings

Original Assignee

Stamicarbon

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1969-10-04

Filing date

1970-05-26

Publication date

1973-01-08

1969-10-04 Priority claimed from NL6915062A external-priority patent/NL6915062A/xx

1970-05-26 Application filed by Stamicarbon filed Critical Stamicarbon

1973-01-08 Publication of NO126204B publication Critical patent/NO126204B/no

Links

PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 76
239000003054 catalyst Substances 0.000 claims description 64
239000010949 copper Substances 0.000 claims description 60
RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 46
229910052802 copper Inorganic materials 0.000 claims description 46
229910052759 nickel Inorganic materials 0.000 claims description 36
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 29
229910052739 hydrogen Inorganic materials 0.000 claims description 29
239000001257 hydrogen Substances 0.000 claims description 29
239000000725 suspension Substances 0.000 claims description 26
229910000480 nickel oxide Inorganic materials 0.000 claims description 24
GNRSAWUEBMWBQH-UHFFFAOYSA-N oxonickel Chemical compound [Ni]=O GNRSAWUEBMWBQH-UHFFFAOYSA-N 0.000 claims description 24
238000000034 method Methods 0.000 claims description 19
238000001556 precipitation Methods 0.000 claims description 13
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 13
BERDEBHAJNAUOM-UHFFFAOYSA-N copper(i) oxide Chemical compound [Cu]O[Cu] BERDEBHAJNAUOM-UHFFFAOYSA-N 0.000 claims description 10
239000007864 aqueous solution Substances 0.000 claims description 9
239000012876 carrier material Substances 0.000 claims description 9
239000002923 metal particle Substances 0.000 claims description 9
238000003756 stirring Methods 0.000 claims description 8
239000000126 substance Substances 0.000 claims description 7
238000004519 manufacturing process Methods 0.000 claims description 6
238000001035 drying Methods 0.000 claims description 5
239000007788 liquid Substances 0.000 claims description 5
150000002815 nickel Chemical class 0.000 claims description 5
VEQPNABPJHWNSG-UHFFFAOYSA-N Nickel(2+) Chemical compound [Ni+2] VEQPNABPJHWNSG-UHFFFAOYSA-N 0.000 claims description 4
229910001453 nickel ion Inorganic materials 0.000 claims description 4
JPVYNHNXODAKFH-UHFFFAOYSA-N Cu2+ Chemical compound [Cu+2] JPVYNHNXODAKFH-UHFFFAOYSA-N 0.000 claims description 3
229910001431 copper ion Inorganic materials 0.000 claims description 3
XIPWCAOMSIUHSL-UHFFFAOYSA-N copper;2,3-dihydroxybutanedioic acid Chemical compound [Cu].OC(=O)C(O)C(O)C(O)=O XIPWCAOMSIUHSL-UHFFFAOYSA-N 0.000 claims description 3
150000002443 hydroxylamines Chemical class 0.000 claims description 3
150000002772 monosaccharides Chemical class 0.000 claims description 3
239000012670 alkaline solution Substances 0.000 claims description 2
230000007062 hydrolysis Effects 0.000 claims description 2
238000006460 hydrolysis reaction Methods 0.000 claims description 2
238000013019 agitation Methods 0.000 claims 1
239000012266 salt solution Substances 0.000 claims 1
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 31
239000002245 particle Substances 0.000 description 22
230000009467 reduction Effects 0.000 description 21
230000000694 effects Effects 0.000 description 19
239000003921 oil Substances 0.000 description 18
235000019198 oils Nutrition 0.000 description 18
238000005984 hydrogenation reaction Methods 0.000 description 16
238000002474 experimental method Methods 0.000 description 15
239000000377 silicon dioxide Substances 0.000 description 13
235000012239 silicon dioxide Nutrition 0.000 description 13
239000000243 solution Substances 0.000 description 13
229910052751 metal Inorganic materials 0.000 description 11
239000002184 metal Substances 0.000 description 11
239000000463 material Substances 0.000 description 10
ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 description 7
150000001875 compounds Chemical class 0.000 description 7
229910052740 iodine Inorganic materials 0.000 description 7
239000011630 iodine Substances 0.000 description 7
239000000203 mixture Substances 0.000 description 7
235000012424 soybean oil Nutrition 0.000 description 7
238000011282 treatment Methods 0.000 description 7
239000005749 Copper compound Substances 0.000 description 6
230000008859 change Effects 0.000 description 6
238000006243 chemical reaction Methods 0.000 description 6
150000001880 copper compounds Chemical class 0.000 description 6
239000003549 soybean oil Substances 0.000 description 6
230000015572 biosynthetic process Effects 0.000 description 5
238000001354 calcination Methods 0.000 description 5
239000003638 chemical reducing agent Substances 0.000 description 5
238000009826 distribution Methods 0.000 description 5
239000005909 Kieselgur Substances 0.000 description 4
235000014113 dietary fatty acids Nutrition 0.000 description 4
239000000194 fatty acid Substances 0.000 description 4
229930195729 fatty acid Natural products 0.000 description 4
150000004665 fatty acids Chemical class 0.000 description 4
150000002500 ions Chemical class 0.000 description 4
229910044991 metal oxide Inorganic materials 0.000 description 4
150000004706 metal oxides Chemical class 0.000 description 4
230000008569 process Effects 0.000 description 4
229910000570 Cupronickel Inorganic materials 0.000 description 3
KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 3
241000784732 Lycaena phlaeas Species 0.000 description 3
XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 3
238000010521 absorption reaction Methods 0.000 description 3
239000004202 carbamide Substances 0.000 description 3
230000003197 catalytic effect Effects 0.000 description 3
YOCUPQPZWBBYIX-UHFFFAOYSA-N copper nickel Chemical compound [Ni].[Cu] YOCUPQPZWBBYIX-UHFFFAOYSA-N 0.000 description 3
239000007789 gas Substances 0.000 description 3
150000002739 metals Chemical class 0.000 description 3
230000005012 migration Effects 0.000 description 3
238000013508 migration Methods 0.000 description 3
230000003647 oxidation Effects 0.000 description 3
238000007254 oxidation reaction Methods 0.000 description 3
CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
229910002012 Aerosil® Inorganic materials 0.000 description 2
WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 2
OYHQOLUKZRVURQ-HZJYTTRNSA-N Linoleic acid Chemical compound CCCCC\C=C/C\C=C/CCCCCCCC(O)=O OYHQOLUKZRVURQ-HZJYTTRNSA-N 0.000 description 2
229910004298 SiO 2 Inorganic materials 0.000 description 2
UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 2
GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
239000013543 active substance Substances 0.000 description 2
238000005054 agglomeration Methods 0.000 description 2
230000002776 aggregation Effects 0.000 description 2
229910045601 alloy Inorganic materials 0.000 description 2
239000000956 alloy Substances 0.000 description 2
DTOSIQBPPRVQHS-PDBXOOCHSA-N alpha-linolenic acid Chemical compound CC\C=C/C\C=C/C\C=C/CCCCCCCC(O)=O DTOSIQBPPRVQHS-PDBXOOCHSA-N 0.000 description 2
235000020661 alpha-linolenic acid Nutrition 0.000 description 2
239000000969 carrier Substances 0.000 description 2
239000003795 chemical substances by application Substances 0.000 description 2
RWGFKTVRMDUZSP-UHFFFAOYSA-N cumene Chemical compound CC(C)C1=CC=CC=C1 RWGFKTVRMDUZSP-UHFFFAOYSA-N 0.000 description 2
JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexanone Chemical compound O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 description 2
238000006356 dehydrogenation reaction Methods 0.000 description 2
239000008103 glucose Substances 0.000 description 2
235000020778 linoleic acid Nutrition 0.000 description 2
OYHQOLUKZRVURQ-IXWMQOLASA-N linoleic acid Natural products CCCCC\C=C/C\C=C\CCCCCCCC(O)=O OYHQOLUKZRVURQ-IXWMQOLASA-N 0.000 description 2
229960004488 linolenic acid Drugs 0.000 description 2
KQQKGWQCNNTQJW-UHFFFAOYSA-N linolenic acid Natural products CC=CCCC=CCC=CCCCCCCCC(O)=O KQQKGWQCNNTQJW-UHFFFAOYSA-N 0.000 description 2
150000002816 nickel compounds Chemical class 0.000 description 2
TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 2
LJCNRYVRMXRIQR-OLXYHTOASA-L potassium sodium L-tartrate Chemical compound [Na+].[K+].[O-]C(=O)[C@H](O)[C@@H](O)C([O-])=O LJCNRYVRMXRIQR-OLXYHTOASA-L 0.000 description 2
229940074439 potassium sodium tartrate Drugs 0.000 description 2
238000000746 purification Methods 0.000 description 2
238000005070 sampling Methods 0.000 description 2
238000005245 sintering Methods 0.000 description 2
235000011006 sodium potassium tartrate Nutrition 0.000 description 2
QPLDLSVMHZLSFG-UHFFFAOYSA-N Copper oxide Chemical compound [Cu]=O QPLDLSVMHZLSFG-UHFFFAOYSA-N 0.000 description 1
239000005751 Copper oxide Substances 0.000 description 1
FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 description 1
235000010469 Glycine max Nutrition 0.000 description 1
244000068988 Glycine max Species 0.000 description 1
BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 1
229910000831 Steel Inorganic materials 0.000 description 1
FEWJPZIEWOKRBE-UHFFFAOYSA-N Tartaric acid Natural products [H+].[H+].[O-]C(=O)C(O)C(O)C([O-])=O FEWJPZIEWOKRBE-UHFFFAOYSA-N 0.000 description 1
WGLPBDUCMAPZCE-UHFFFAOYSA-N Trioxochromium Chemical compound O=[Cr](=O)=O WGLPBDUCMAPZCE-UHFFFAOYSA-N 0.000 description 1
230000009471 action Effects 0.000 description 1
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
229910052799 carbon Inorganic materials 0.000 description 1
239000002801 charged material Substances 0.000 description 1
229910000423 chromium oxide Inorganic materials 0.000 description 1
238000000975 co-precipitation Methods 0.000 description 1
229910052681 coesite Inorganic materials 0.000 description 1
229910000431 copper oxide Inorganic materials 0.000 description 1
229910052906 cristobalite Inorganic materials 0.000 description 1
HPXRVTGHNJAIIH-UHFFFAOYSA-N cyclohexanol Chemical compound OC1CCCCC1 HPXRVTGHNJAIIH-UHFFFAOYSA-N 0.000 description 1
230000007423 decrease Effects 0.000 description 1
230000008021 deposition Effects 0.000 description 1
FMQXRRZIHURSLR-UHFFFAOYSA-N dioxido(oxo)silane;nickel(2+) Chemical compound [Ni+2].[O-][Si]([O-])=O FMQXRRZIHURSLR-UHFFFAOYSA-N 0.000 description 1
238000004090 dissolution Methods 0.000 description 1
230000001747 exhibiting effect Effects 0.000 description 1
238000001914 filtration Methods 0.000 description 1
235000021588 free fatty acids Nutrition 0.000 description 1
238000004817 gas chromatography Methods 0.000 description 1
239000002638 heterogeneous catalyst Substances 0.000 description 1
229930195733 hydrocarbon Natural products 0.000 description 1
150000002430 hydrocarbons Chemical class 0.000 description 1
238000005470 impregnation Methods 0.000 description 1
238000011065 in-situ storage Methods 0.000 description 1
230000006698 induction Effects 0.000 description 1
238000002347 injection Methods 0.000 description 1
239000007924 injection Substances 0.000 description 1
230000003993 interaction Effects 0.000 description 1
239000000395 magnesium oxide Substances 0.000 description 1
CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 1
AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 1
230000007246 mechanism Effects 0.000 description 1
238000012544 monitoring process Methods 0.000 description 1
BFDHFSHZJLFAMC-UHFFFAOYSA-L nickel(ii) hydroxide Chemical compound [OH-].[OH-].[Ni+2] BFDHFSHZJLFAMC-UHFFFAOYSA-L 0.000 description 1
229910052755 nonmetal Inorganic materials 0.000 description 1
229910052760 oxygen Inorganic materials 0.000 description 1
239000001301 oxygen Substances 0.000 description 1
229910021426 porous silicon Inorganic materials 0.000 description 1
239000002244 precipitate Substances 0.000 description 1
238000002360 preparation method Methods 0.000 description 1
238000012545 processing Methods 0.000 description 1
150000003254 radicals Chemical class 0.000 description 1
229920006395 saturated elastomer Polymers 0.000 description 1
239000011734 sodium Substances 0.000 description 1
229910000030 sodium bicarbonate Inorganic materials 0.000 description 1
235000017557 sodium bicarbonate Nutrition 0.000 description 1
229910000029 sodium carbonate Inorganic materials 0.000 description 1
238000001179 sorption measurement Methods 0.000 description 1
239000007858 starting material Substances 0.000 description 1
239000010959 steel Substances 0.000 description 1
229910052682 stishovite Inorganic materials 0.000 description 1
239000011975 tartaric acid Substances 0.000 description 1
235000002906 tartaric acid Nutrition 0.000 description 1
239000004408 titanium dioxide Substances 0.000 description 1
229910052905 tridymite Inorganic materials 0.000 description 1

Landscapes

Catalysts (AREA)
Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Fats And Perfumes (AREA)

NO02021/70A 1969-10-04 1970-05-26 NO126204B (es)

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
NL6915062A NL6915062A (es)	1969-10-04	1969-10-04

Publications (1)

Publication Number	Publication Date
NO126204B true NO126204B (es)	1973-01-08

Family

ID=19808047

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
NO02021/70A NO126204B (es)	1969-10-04	1970-05-26

Country Status (3)

Country	Link
JP (1)	JPS4937519B1 (es)
ES (1)	ES380061A1 (es)
NO (1)	NO126204B (es)

1970
- 1970-05-26 NO NO02021/70A patent/NO126204B/no unknown
- 1970-05-26 ES ES380061A patent/ES380061A1/es not_active Expired
- 1970-06-16 JP JP45052293A patent/JPS4937519B1/ja active Pending

Also Published As

Publication number	Publication date
JPS4937519B1 (es)	1974-10-09
ES380061A1 (es)	1973-04-16

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