MXPA97001953A - Employment of ariluracils in the semi-selective and non-selective field of the fight against bad hier - Google Patents

Employment of ariluracils in the semi-selective and non-selective field of the fight against bad hier

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Publication number
MXPA97001953A
MXPA97001953A MXPA/A/1997/001953A MX9701953A MXPA97001953A MX PA97001953 A MXPA97001953 A MX PA97001953A MX 9701953 A MX9701953 A MX 9701953A MX PA97001953 A MXPA97001953 A MX PA97001953A
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Mexico
Prior art keywords
carbon atoms
alkyl
alkoxy
phenyl
substituted
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MXPA/A/1997/001953A
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Spanish (es)
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MX9701953A (en
Inventor
Wilhelm Drewes Mark
Andree Roland
Dollinger Markus
Wetcholowsky Ingo
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Bayer Ag 51373 Leverkusen De
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Priority claimed from DE4432888A external-priority patent/DE4432888A1/en
Application filed by Bayer Ag 51373 Leverkusen De filed Critical Bayer Ag 51373 Leverkusen De
Publication of MXPA97001953A publication Critical patent/MXPA97001953A/en
Publication of MX9701953A publication Critical patent/MX9701953A/en

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Abstract

The invention relates to the use of aryluracils and arylthiouracils of the general formula (I9) or of the isomeric compounds thereof of the general formula (Ia), in which formulas Q1, Q2, R1, R2, R3, R4, R5, and R6 have respectively the meanings indicated in the description, and optionally one or several compounds of a second group of herbicides for the semi-selective and non-selective fight against weeds.

Description

EMPLOYMENT OF ARILURACILQ8 IN THE SEMI-SELECTIVE AND NON-SELECTIVE FIELD OF THE FIGHT AGAINST THE BAD HERBS. DESCRIPTION OF THE INVENTION The invention relates to the use of known aryluracils (or of aryl-thio-uracils- or of isomeric compounds of these uracils or aryl-thiouracils) for the semi-selective and non-selective fight against weeds. . Aryluracils (or aryl thio-uracils) are herbicides that are the subject of a series of patent applications (see WO-A 91/00278, US-P 4979982, US-P 5169430, EP-A 408382, EP -A 563384, US-P 5084084, US-P 5127935, US-P 5154755, DE-P 4327743, DE-P 4343451, DE-P 4414326). However, nothing has yet been made known about the use of the known aryluracils (or aryl- (thio) uracils) in the semi-selective and non-selective field of weed control. Surprisingly it has now been found that a series of known herbicidal active compounds from the group of aryluracils (or of the aryl thiouracils or of the isomeric compounds of these aryluracils or arylthiouracils) are suitable in a very good manner for the fight against monocotyledonous and dicotyledonous weeds in the semi-selective and non-selective field either alone or in conjunction with herbicidal active compounds known, for example, from the product classes of carboxylic acids, of diphenyl ethers , of the diazin (onas) or of the triazin (onas), of the REF: 24108 ureas and the pyridine- derivatives. The object of the invention are therefore agents for the control of weeds in the semi-selective and non-selective field, characterized in that they have an active content of at least one aryluracil or of an aryl-thiouracil of the general formula (I), or of an isomeric compound with the same of the general formula (la) in which formulas (I) and (la) respectively Q1 signifies oxygen or sulfur, Q2 signifies oxygen or sulfur, R1 signifies hydrogen or halogen, R2 signifies halogen or cyano, R3 signifies the following grouping: -A1-A2-A3 wherein A1 means a single bond, means oxygen, sulfur, -SO-, -S02, -CO- or the group -N-A4-, where A4 means hydrogen, hydroxy, alkyl, alkoxy, aryl, alkylsulfonyl or arylsulfonyl, or A1 further denotes alkanediyl, alkenodiyl, azaalkenediyl, alkynediyl, cycloalkanediyl, cycloalkenodiyl or arenediyl, respectively substituted if appropriate, A2 means a single bond, means oxygen, sulfur, -SO-, -S02-, -CO- or means the grouping -N-A4-, where A4 means hydrogen, alkyl, aryl, alkylcarbonyl, alkylsulfonyl or arylsulfonyl, or A2 further means alkanediyl, alkenodiyl, azaalkenediyl, alkynediyl, azaalkenodiyl, alkynediyl, cycloalkanediyl, cycloalkenediyl or arenediyl , respectively substituted if appropriate, and A3 means hydrogen, hydroxy, mercapto, amino, cyano, isocyano, thiocyanate, nitro, carboxy, carbamoyl, thiocarbamoyl, sulfo, chlorosulfonyl, halogen or means alkyl, alkoxy, alkylthio, alkylsulfinyl, alkylsulfonyl, alkylamino, dialkylamino, alkoxycarbonyl, dialkoxy (thio) phosphoryl, alkenyl, alkenyloxy, alkenylene, alkylidene, alkenyloxycarbonyl, alkynyl, alkynyloxy, alkynylamino, alkynyloxycarbonyl, cycloalkyl, cycloalkyloxy, cycloalkylalkyl, cycloalkylalkoxy, cycloalkylideneamino, cycloalkyloxycarbonyl, cycloalkylalkoxycarbonyl, aryl, aryloxy, arylalkyl, arylalkoxy, aryloxycarbonyl, arylalkoxycarbonyl, heterocyclyl, heterocyclylalkyl, heterocyclyl-alkoxy or heterocyclylalcoxycarbonyl, respectively substituted if appropriate, R4 means hydrogen, halogen or means alkyl, in In the given case, R 5 means hydrogen, halogen or means optionally substituted alkyl, and R 6 is hydrogen, hydroxy, amino or means substituted alkyl, alkoxy, alkenyl or alkynyl, respectively.and, if appropriate, one or more compounds of a second group of herbicides, containing the classes of compounds (a) to (e) mentioned below: (a) carboxylic acids such as, for example, 2,4-dichloro- phenoxyacetic acid (2,4-D), 4-amino-3,5,6,6-trichloro-pyridin-2-yl-oxy acetic acid (Triclopyr), the ammonium salt of 2-amino-4- (hydro) ? imetilfos-finil) -butyric (Glufosinate-ammonium), the? - (hydroxymethylphosphinyl) -1-a-aminobutyryl-l-alanyl-1-alanine (Bialaphos), N-phosphonomethyl-glycine (Glyphosate) as well as the isopropyl onium salt and the trimethylsulfonium salt thereof, or the acid 2- (4,5-dihydro-4-methyl-4-i-propyl-5-oxo-lH-imidazol-2-yl) -pyridine-3-carboxylic acid (I azapyr) as well as the isopropylammonium salt thereof; (b) Diphenyl ethers, such as, for example, 2-chloro-4-trifluoromethyl-phenyl-3-ethoxy-4-nitrophenyl ether (Oxyfluorfen); (c) Diazin (onas), or triazin (onas), such as, for example, 2-chloro-4-ethylamino-6-i-propyl-amino-1,3,5-triazine (Atrazin), 2-chloro- 4,6-bis-ethylamino-l, 3,5-triazine (Simazin), 5-bromo-3-s-butyl-6-methyl-uracil (Bromacil) or 4-amino-6-t-butyl- 4,5-dihydro-3-methylthio-l, 2,4-triazin-5-one (Metribuzin); (d) Ureas, such as, for example, 3- (3,4-dichloro-phenyl) -1,1-dimethyl-urea (Diuron) or 3- (4,6-dimethyl-pyrimidin-2-yl) ) -1- (2-methoxycarbonyl-phenylsulfonyl) -urea (Sulphometuron-methyl); (e) Derivatives of pyridine, such as, for example, l, 1-dimethyl-4,4'-bipyridinium chloride (Paraquat) or l, 1-ethylene-2,2'-bipyridinium chloride (Diquat ). According to the invention, herbicidal agents with a compound of the formula (I) or (the) above are of particular interest in which Q 1 signifies oxygen or sulfur, Q 2 signifies oxygen or sulfur, R 1 signifies hydrogen, fluorine, chlorine or bromine, R2 means fluorine, chlorine, bromine, iodine or cyano, R3 means the following group -A1-A2-A3 where A1 means a single bond, means oxygen, sulfur -SO-, -S02-, -CO- or means grouping -N-A4-, where A4 means hydrogen, hydroxy, alkyl with 1 to 4 carbon atoms, alkoxy with 1 to 4 carbon atoms, phenyl, alkylsulfonyl or phenylsulfonyl, or A1 further means alkanediyl with 1 to 6 carbon atoms , alkenodiyl with 2 to 6 carbon atoms, azaalkenodiyl with 2 to 6 carbon atoms, alkynediyl with 2 to 6 carbon atoms, cycloalkanediyl with 3 to 6 carbon atoms, cycloalkenodiyl with 3 to 6 carbon atoms or phenylene, respectively substituted, if appropriate, by fluorine, by gold or bromine, A2 means a single bond, means oxygen, sulfur, -SO-, -S02-, -CO- or means the group -N-A4-, where A4 means hydrogen, hydroxy, alkyl with 1 to 4 atoms of carbon, alkoxy with 1 to 4 carbon atoms, phenyl, alkylsulfonyl with 1 to 4 carbon atoms or phenylsulfonyl, or A2 also means alkanediyl with 1 to 6 carbon atoms, alkenodiyl with 2 to 6 carbon atoms, azaalkenodiyl with 2 to 6 carbon atoms, alkynediyl with 2 to 6 carbon atoms, cycloalkanediyl with 3 to 6 carbon atoms, cycloalkenodiyl with 3 to 6 carbon atoms or phenylene substituted, where appropriate, by fluorine, chlorine or bromine, hydrogen, hydroxy, amino, cyano, isocyano, thiocyanate, nitro, carboxy, carbamoyl, thiocarba oyl, sulfo, chlorosulfonyl, halogen, means, substituted respectively by halogen or by alkoxy with 1 to 4 carbon atoms, alkyl, alkoxy , alkylthio, alkylsulfi-nyl, alkylsulfo nyl, alkylamino, dialkylamino, alkoxycarbonyl or dialkoxy (thio) phosphoryl, respectively having 1 to 6 carbon atoms in the alkyl groups, respectively means substituted, if appropriate, by halogen, alkenyl, alkenyloxy, alkenyl, n-alkylidene, alkenyloxycarbonyl, alkynyl, alkynyloxy, alkynylamino or alkynyloxycarbonyl with 2 to 6 carbon atoms in the alkenyl, alkylidene or alkynyl groups, respectively, optionally substituted by halogen, by cyano, by carboxy, by alkyl with 1 to 4 carbon atoms and or by alkoxycarbonyl having 1 to 4 carbon atoms, cycloalkyl, cycloalkyloxy, cycloalkylalkyl, cycloalkylalkoxy, cycloalkylideneamino, cycloalkyloxycarbonyl or cycloalkylalkoxycarbonyl with 3 to 6 carbon atoms in the cycloalkyl groups and given 1 to 4 carbon atoms in the alkyl groups, or means, substituted respectively by nitro, by cyano, by carboxy, by halogen, by alkyl with 1 to 4 carbon atoms, by haloalkyl with 1 to 4 carbon atoms, by alkoxy with 1 to 4 carbon atoms, by haloalkyloxy with 1 to 4 carbon atoms, and no / or by alkoxycarbonyl having 1 to 4 carbon atoms, phenyl, phenyloxy, phenyl-alkyl with 1 to 4 carbon atoms, phenyl-alkoxy with 1 to 4 carbon atoms, phenyl-oxycarbonyl or phenyl-alkoxycarbonyl with 1 to 4 carbon atoms. carbon, (each optionally hydrogenated in whole or in part) pyrrolyl, pyrazolyl, imidazolyl, triazolyl, furyl, thienyl, oxazolyl, isoxazolyl, thiazolyl, isothiazolyl, oxadiazolyl, thiadiazolyl, pyridinyl, pyrimidinyl, triazinyl, pyrazolyl-C 1 -C 4 -alkyl, furyl-C 1 -C 4 -alkyl, thienyl-C 4 -alkyl, oxazolyl-C 1 -C 4 -alkyl, isoxazole- alkyl with 1 to 4 carbon atoms, thiazolyl with 1 to 4 carbon atoms, pyridinyl-alkyl with 1 to 4 carbon atoms, pyridinyl-alkyl with 4 carbon atoms, pyrazolylmethoxy, furylmethoxy, means perhydropyranylmethoxy or pyridylmethoxy R4 means hydrogen, fluorine, chlorine, bromine or means alkyl with 1 to 4 carbon atoms, optionally substituted by fluorine and / or chlorine, R5 means hydrogen, fluorine, chlorine, bromine or means alkyl with 1 to 4 atoms carbon, optionally substituted by fluorine and / or chlorine, and R6 is hydrogen, hydroxy, amino, or represents alkyl, alkoxy, alkenyl or alkynyl with, respectively, up to 4 carbon atoms, respectively substituted, if appropriate, by fluorine, by chlorine or by cyano, ye n case given with one or two compounds more than a second group of herbicides, containing the classes of compounds (a) to (e) cited below: (a) carboxylic acids such as for example 2,4-dichloro- phenoxyacetic acid (2,4-D), 4-amino-3,5,6,6-trichloro-pyridin-2-yl-oxy-acetic acid (Triclopyr), the ammonium salt of 2-amino-4- (hydroxymethylphosphonic acid - finyl) -butyric (Glufosinate-monium), the α- (hydroxymethylphosphinyl) -1-a-aminobutyryl-1-alanyl-1-alanine (Bialaphos), the N-phosphonothnethyl-glycine (Glyphosate) as well as the salt of isopropylammonium and the trimethylsulfonium salt thereof, or the acid 2- (4,5-dihydro-4-methyl-4-i-propyl-5-oxo-lH-imidazol-2-yl) -pyridin- 3- carboxylic acid (I azapyr) as well as the isopropylammonium salt thereof; (b) Diphenyl ethers, such as, for example, 2-chloro-4-trifluoromethyl-phenyl-3-ethoxy-4-nitrophenyl ether (Oxyfluorfen); (c) Diazin (onas), or triazin (onas), such as, for example, 2-chloro-4-ethylamino-6-i-propyl-amino-1,3,5-triazine (Atrazin), 2-chloro-4,6-bis-ethylamino-l, 3, 5-triazine (Simazin), 5-bromo-3 -s-butyl-6-methyl-uracil (bromate) or 4-amino-6-t-butyl-4,5-dihydro-3-methylthio-1,2,4-triazin-5-one (Metribuzin); (d) Ureas, such as, for example, 3- (3,4-dichloro-phenyl) -1,1-dimethyl-urea (Diuron) or 3- (6-dimethyl-pyrimidin-2-yl) -1- (2-methoxycarbonyl-phenylsulfonyl) -urea (Sulphometuron-methyl); (e) Derivatives of pyridine, such as, for example, 1, 1-dimethyl-4,4-bipyridinium chloride (Paraquat) or 1, 1-ethylene-2,2'-bipyridinium chloride (Diquat) . Of particular interest are the herbicidal agents according to the invention with a compound of the formula (I) or (a) - above - where Q 1 signifies oxygen or sulfur, Q 2 signifies oxygen or sulfur, R 1 signifies hydrogen, fluorine, chlorine or bromine , R2 means fluorine, chlorine, bromine, iodine or cyano, • R3 means the following grouping, -A1-A2-A3 where A1 means a single bond, means oxygen, sulfur, -SO-, -S02-, -CO- or means the group -N-A4-, where A4 means hydrogen, hydroxy, methyl, ethyl, n- or i-propyl , methoxy, ethoxy, n- or i-propoxy, methylsulfonyl or ethylsulfonyl, or A1 further means methylene, ethane-1, 1-diyl, ethane-1,2-diyl, propane-1, 1-diyl, propane-1, 2-diyl, propane-1,3-diyl, ethene-1, 2-diyl, propene-1, 2-diyl, propene-1,3-diyl, etino-1, 2-diyl, propino-1, 2- diyl or propino-1,3-diyl, A2 means a single bond, means oxygen, sulfur, -SO-, -S02-, -CO-, or means the group -N-A4-, where A4 means hydrogen, hydroxy, methyl, ethyl, n- or i-propyl, methoxy, ethoxy, n- or i-propoxy, metilsulfo- nile, ethylsulfonyl, n- or i-propylsulfonyl or fenilsul- fonilo or A2 further means methylene, ethane-1, l -diyl, ethane-1,2-diyl, propane-1, l-diyl, propane-l, 2-diyl, propane-1,3-diyl, ethene-l, 2-diyl, propene-l, 2-diyl , propene-l, 3-diyl, etino-l, 2-diyl, propyl-1, 2-diyl or pro-1,3-diyl, A3 means hydrogen, hydroxy, amino, cyano, nitro, carboxy, carbamoyl, sulfo, fluoro, chloro, bromo, respectively means substituted by fluorine , by chlorine, by methoxy or by ethoxy, methyl, ethyl, n- or i-propyl, n-, i-, s- or t-butyl, n-, i-, s- or t-pentyl, methoxy, ethoxy n- or i-propoxy, n-, i-, s- or t-butoxy, n-, i-, s- or t-pentyloxy, ethylthio, ethylthio, n- or i-propylthio, n-, i-, s- or t-butylthio, methylsulfinyl, ethyl sulfinyl, i-propylsulfinyl, methylsulfonyl, ethyl sulfonyl, i-propylsulfonyl not, methylamino, etilami- no, i -propylamino, n - i-, s- or t-butylamino, methyl-amino dimethyl, diethylamino, methoxycarbonyl, ethoxycarbonyl, n- or i-propoxycarbonyl, dimethoxyphosphoryl, dietoxifos- forilo or dipropoxifosforilo, diisopropoxifosforilo means, each substituted optionally fluorine- or chlorine, propenyl, butenyl, propenyloxy, butenyloxy, propenylamino, butenylamino, propylidene, butyl denamino, propenyloxycarbonyl, buteniloxicar-bonilo, propynyl, butynyl, propynyloxy, butynyloxy, propynylamino, butynylamino, propynyloxycarbonyl or bu-tiniloxicarbonilo means, respective-ly substituted n optionally fluorine-, chlorine, cyano, carboxy, methyl, ethyl, n- or i-propyl, methoxycarbonyl or ethoxycarbonyl, cyclopropyl, cyclobutyl-ci, cyclopentyl, cyclohexyl, cyclopropyloxy-cyclobutyloxy, cyclopentyloxy, cyclohexyloxy, ciclopro-pilmetilo, cyclobutylmethyl, cyclopentylmethyl, ciclohe-xilmetilo, cyclopropylmethoxy, cyclobutylmethoxy , cycle-pentilmetoxi, cyclohexylmethoxy, cyclopentylideneamino, ciclohexilidenamino, cyclopentyloxycarbonyl, xiloxicarbonilo cyclohexyl, xilmetoxicarbonilo ciclopentilmetoxicarbonilo or cyclohexyl, or represents, in each case optionally substituted by nitro, cyano, carboxy, fluorine, chlorine, bromine, methyl, by ethyl, by n- or i-propyl, by trifluoromethyl, by methoxy, by ethoxy, by n- oi -propoxy, by difluoro ethoxy, by trifluoromethoxy, by methoxycarbonyl and / or by ethoxycarbonylphenyl, phenyloxy, benzyl, phenylethyl, benzyloxy, phenyloxycarbonyl, benzyloxycarbonyl, (each optionally hydrogenated, in whole or in part) pyrrolyl, pyrazolyl, imidazolyl, triazolyl, furyl, thienyl, oxazolyl, isoxazolyl, thiazolyl, isothiazolyl , oxadiazolyl, thiadiazolyl, pyridinyl, pyrimidinyl, triazinyl, pyrazolylmethyl, furylmethyl, thienylmethyl, oxazolylmethyl, isoxazolylmethyl, thiazolethyl, pyridinylmethyl, pyrimidinylmethyl, pyrazolmethoxy, furylmethoxy or pyridylmethoxy, R4 means hydrogen, fluorine, chlorine, or means methyl or ethyl, respectively substituted, if appropriate, by fluorine and / or by chlorine, R5 is hydrogen, fluorine, chlorine or means methyl or ethyl substituted respectively by fluorine and / or chlorine, and R6 is hydrogen, hydroxy, amino, or means, respectively substituted, if appropriate, by fluorine, by chlorine or by cyano, methyl, ethyl, n- or i-propyl, methoxy, ethoxy, n- or i-propoxy, propenyl or pro phenyl, and optionally with one or two compounds more than a second group of herbicides, containing the classes of compounds (a) to (e) mentioned below: (a) carboxylic acids such as, for example, acid -dichloro-phenoxyacetic acid (2,4-D), 4-amino-3, 5,6-trichloro-pyridin-2-yl-oxy-acetic acid (Triclopyr), the ammonium salt of 2-amino-4 - (hydroxymethylphosphoryl) -butyric (Glufosinate-ammonium), y- (hydroxymethylphosphinyl) -1-a-aminobutyryl-1-alanyl-1-alanine (Bialaphos), N-phosphonomethyl-glycine (Glyphosate) such as the isopropylammonium salt and the trimethylsulfonium salt thereof, or the acid 2- (4,5-dihydro-4-methyl-4-i-propyl-5-oxo-lH-imidazol-2-yl) -pyridine-3-carboxylic acid (Imazapyr) as well as the isopropylammonium salt thereof; (b) Diphenyl ethers, such as, for example, 2-chloro-4-trifluoromethyl-phenyl-3-ethoxy-4-nitrophenyl ether (Oxyfluorfen); (c) Diazin (onas), or triazin (onas), such as for example 2-chloro-4-ethylamino-6-i-propyl-amino-1, 3,5-triazine (Atrazin), 2-chloro- 4,6-bis-ethylamino-l, 3,5-triazine (Simazin), 5-bromo-3-s-butyl-6-methyl-uracil (Bromacil) or 4-amino-6-t- butyl-4, 5-dihydro-3-methylthio-1,2,4-triazin-5-one (Metribuzin); (d) Ureas, such as, for example, 3- (3,4-dichloro-phenyl) -1,1-dimethyl-urea (Diuron) or 3- (4,6-dimethyl-pyrimidin-2-yl) ) -l- (2-methoxycarbonyl-phenylsulfonyl) -urea (Sulphometuron-methyl); (e) Derivatives of pyridine, such as, for example, 1, 1-dimethyl-4,4'-bipyridinium chloride (Paraquat) or l, 1-ethylene-2,2'-bipyridinium chloride (Diquat ). As examples of compounds of the formula (I) to be used as components of mixtures according to the invention, mention may be made in particular of 1- (4-chloro-3-methylsulfonylaine-phenyl) -3,6-dihydro-2, 6- dioxo-3-methyl-4-trifluoromethyl-l (2H) -pyrimidine, 1- (4-chloro-3-methylsulfonylamino-phenyl) -3,6-dihydro-2,6-dioxo-3-amino-4 -trifluromethyl-l (2H) -pyrimidine, 1- (4-cyano-3-methylsulfo-nylamino-phenyl) -3,6-dihydro-2,6-dioxo-3-methyl-4-trifluoromethyl-1 ( 2H) -pyrimidine, 1- (4-chloro-3-ethylsulfonylamino-phenyl) -3,6-dihydro-2,6-dioxo-3-methyl-4-trifluoromethyl-1 (2H) -pyrimidine, 1- (4-Chloro-3-ethylsulphonylamino-f-enyl) -3,6-dihydro-2,6-dioxo-3-amino-4-tr if lumeromethyl-1 (2H) -pyrimidine, 1- (4- cyano-3-ethylsulphonylamino-f-enyl) -3,6-dihydro-2,6-dioxo-3-methyl-4-trifluoromethyl-1 (2H) -pyrimidine, 1- (4-chloro-3-n- propylsulphonylamino-f-enyl) -3,6-dihydro-2,6-dioxo-3-methyl-4-trifluoromethyl-l (2H) -pyrimidine, 1- (4-chloro-3-n-propylsulfo-nylamino- f-enyl) -3,6-dihyd ro-2, 6-dioxo-3-amino-4-trif lúorme-til-1 (2H) -pirimidina, l- (4-cyano-3-n-propylsulfonylamino-f-enyl) -3,6-dihydro- 2,6-dioxo-3-methyl-4-trifluoromethyl-1 (2H) -pyrimidine, 1- (4-chloro-3-i-propylsulphonylamino-f-enyl) -3,6-dihydro-2-6- dioxo-3-methyl-4-trif lumeromethyl-1 (2H) -pyrimidine, 1- (4-chloro-3-i-propylsulphonylamino-f-enyl) -3,6-dihydro-2,6-dioxo-3- amino-4-trifluoromethyl-l (2H) -pyrimidine, 1- (4-cyano-3-i-propylsulphonylamino-f-enyl) -3,6-dihydro-2,6-dioxo-3-methyl-4 -trif lúormetil-l (2H) -pirimidine, l- (4-chloro-5-methyl-sulfonylamino-2-f lúor-f enyl) -3,6-dihydro-2,6-dioxo-3-methyl- 4-trifluoromethyl-1 (2H) -pyrimidine, 1- (4-chloro-5-methylsulphonylamino-2-f-lucor-phenyl) -3,6-dihydro-2,6-dioxo-3-amino-4 - trifluoromethyl-1 (2H) -pyrimidine, 1- (4-cyano-5-methylsulfonyl-amino-2-f-lucor-phenyl) -3,6-dihydro-2,6-dioxo-3-methyl-4- trifluoromethyl-l (2H) -pyrimidine, l- (4-chloro-5-ethylsulphonylamino-2-f-lucor-f-enyl) -3,6-dihydro-2,6-dioxo- 3-Methyl-4-trifluoromethyl-l (2H) -pyrimidine, 1- (4-chloro-5-ethylsulfonylamino-2- f-lucor-f-enyl) -3,6-dihydro-2,6-dioxo- 3-amino-4-trif lumeromethyl-1 (2H) -pyrimidine, 1- (4-cyano-5-ethylsulfonylamino-2-f-lucor-phenyl) -3,6-dihydro-2,6-dioxo-3-methyl -4-trif lúormetil-1 (2H) -pyrimidine, 1- (4-chloro-5-n-propylsulfonylamino-2-f lúor-f e-nil) -3,6-dihydro-2,6-dioxo-3 -methyl-4-trifluoromethyl-l (2H) -pyrimidine, 1- (4-chloro-5-n-propylsulfonylamino-2-fluoro-phenyl) -3,6-dihydro-2,6-dioxo-3-amino- 4-trifluoromethyl-l (2H) -pyrimidine, 1- (4-cyano-5-n-propylsulfonylamino-2-fluoro-phenyl) -3,6-dihydro-2,6-dioxo-3-methyl-4-trifluoromethyl -l- (2H) -pyrimidine, 1- (4-chloro-5-i-propylsulfonylamino-2-fluoro-phenyl) -3,6-dihydro-2,6-dioxo-3-methyl-4-trifluoromethyl-1 (2 H) -pyrimidine, 1- (4-chloro-5-y-propylsulfonylamino-2-fluoro-phenyl) -3,6-dihydro-2,6-dioxo-3-amino-4-trifluoromethyl-1 (2H) -pyrimidine, 1- (4-cyano-5-i-propylsulfonylamino-2-fluoro-phenyl) -3,6-dihydro-2,6-dioxo-3-methyl-4-t riflumomethyl-1 (2H) -pyrimidine, 1- (4-cyano-5-n-butylsulfonylamino-2-fluoro-phenyl) -3,6-dihydro-2,6-dioxo-3-methyl-4-trifluoromethyl-1 (2H) -pyrimidine. The compounds of the formula (I) - or (a) - have been described in the patent applications or in the descriptions of the aforementioned patents. It has been found now, surprisingly, that the active compounds of the formula (I) - or (a) - defined above, optionally in combination with the active compounds mentioned in the second group - exhibit a particularly high level of herbicidal activity in the fight against herbs in the semi-selective and non-selective field. The active compounds or the active ingredient mixtures, to be used according to the invention, can be used both in conventional growing methods (row crops with a suitable row width), in plantation crops (for example wheat, fruit trees, citrus fruits). ) as well as in industrial and railway installations, on roads and squares, as well as for the treatment of stubble and in the minimum tillage procedure. They are also suitable as mulchers (removing herbs for example in potato crops) or as defoliants (for example in cotton crops). They are also suitable for use on bare surfaces. Other fields of application are nurseries, forests, green land and ornamental plant crops. As weeds, which can be combated perfectly by means of the active products or of the active compound combinations according to the invention, we can mention, for example: Bad dicotyledonous herbs of the classes Sinapis, Lepidium, Galium, Stellaria, Matricaria , Anthemis, Galensoga, Chenopodium, Urtica, Senecio, Amaranthus, Portu- laca, Xanthium, Convolvulus, Ipomoea, Polygonum, Sesbania, Ambrosia, Solanum, Cirsium, Carduus, Sonchus, Rorippa, Ro- tala, Lindernia, Laum, Veronica, Abutilon, Emex, Aids, Datura, Viola, Geleopsis, Papaver, Centaurea, Trifolium, Ranunculus, Taraxum, Mentha. Echinochloa, Setaria, Panicum, Digitaria, Phleu, Poa, Festuca, Eleusine, Brachiaria, Lolium, Bromus, Oats, Cy-perus, Sorghu, Agropyron, Cynodon, Monochoria, Fimbris-tylis, Sagittaria, Eleocharis, Scirpus, Paspalum, Ischae-mum, Sphenoclea, Dactyloctenium, Agrostis, Alopecurus, Apera. The use of the active compounds and the combinations of the active compounds according to the invention is, however, not limited in any way to these classes, but they also extend to other plants in the same way. Insofar as mixtures of the compounds of the formula (I) or (a) are used with the aforementioned herbicides in (a) to (e) ("second group of herbicides"), the proportions by weight of the products Active ingredients in active product combinations may vary within a relatively broad range. In general, they correspond respectively, in this case, to 1 part by weight of active compound of the formula (I) or (la), from 0.001 to 1000 parts by weight, preferably from 0.01 to 100 parts by weight, particularly preferably from 0.1 to 10 parts by weight, of one or two of the herbicides mentioned above in (a) to (e) The active compounds can be converted into customary formulations, such as solutions, and ions, sprayable powders, suspensions, powders, dusts, pastes, soluble powders, granules, suspension-emulsion concentrates, natural and synthetic materials impregnated with the active product, as well as micro-encapsulated in polymer materials. These formulations are prepared in known manner, for example by mixing the active ingredients with extender materials, that is, with liquid solvents and / or solid excipients, if appropriate, using surfactants, that is, emulsifiers and / or dispersants and / or foam generating means. When using water as a filler, it is also possible, for example, to use organic solvents as auxiliary solvents. Suitable liquid solvents are, in particular, aromatics, such as xylene, toluene, or alkylnaphthalenes, chlorinated aromatics and chlorinated aliphatic hydrocarbons, such as chlorobenzenes, chloroethylenes or methylene chloride, aliphatic hydrocarbons, such as cyclohexanes. hexane or paraffins, for example, fractions of crude oil, mineral and vegetable oils, alcohols, such as butanol, or glycol, as well as their esters and ethers, ketones, such as acetone, methyl ethyl ketone, ethyl isobutyl ketone, or cyclohexanone , strongly polar solvents, such as dimethylformamide and dimethyl sulfoxide, as well as water. Suitable solid excipients are, for example, ammonium salts and the ground natural minerals, such as kaolins, clays, talc, chalk, quartz, attapulgite, montmorillonite or diatomaceous earth and ground synthetic minerals, such as silicic acid, highly dispersed, aluminum oxide and silicates as solid excipients for granulates are considered: for example, broken and fractionated natural minerals such as calcite, marble, pumice, sepiolite, dolomite, as well as synthetic granules of inorganic and organic flours, as well as granulates of organic materials, such as sawdust, coconut husks, corn ears and tobacco stems; Examples of suitable emulsifiers and / or foam generators are nonionic and anionic emulsifiers, such as polyoxyethylenated esters of fatty acids, for example, alkylaryl polyglycol ether, alkylsulfonates, alkyl sulfates, arylsulphonates, and the like. albumin hydrolysates; Suitable dispersants are: for example, sulfitic leaching of lignin and methylcellulose. In the formulations, adhesives such as carboxymethylcellulose, natural and synthetic polymers, powdered, granulated or in the form of latex, such as gum arabic, polyvinyl alcohol, polyvinyl acetate, as well as natural phospholipids, such as cefalin and lecithin, can be used. , and synthetic phospholipids. Other additives can be mineral and vegetable oils. Dyes, such as inorganic pigments, for example, iron oxide, titanium oxide, ferrocyanic blue, and organic dyes, such as alizarin dyes, metallic azo and phthalocyanine dyes, and trace nutrients, can be employed. salts of iron, manganese, boron, copper, cobalt, molybdenum and zinc. The formulations generally contain between 0.1 to 95% by weight of active substance, preferably between 0.5 and 90%. The active compound combinations according to the invention will be used, in general, as ready-to-use formulations. The active products, contained in the combinations of active products, can be mixed in the case of their application, in individual formulations, ie they can be used in the form of tank mixes. The active compounds or the active compound combinations according to the invention can be used as such or in their formulations, as well as in a mixture of other known herbicides for controlling weeds, while formulations ready for use or mixtures are possible in turn. of tank. A mixture with other known active ingredients is also possible, such as fungicides, insecticides, acaricides, nematicides, protective substances against ingestion by birds, growth substances, nutrient substances of the plants and means for improving the structure of the ground. For certain purposes of application it may also be advantageous to incorporate, in the form of other additional products, vegetable or mineral oils compatible with the plants (for example the commercially available "Dupont HE") or ammonium salts, such as as, for example, ammonium sulfate or ammonium rodanide. The active compounds and the active compound combinations according to the invention can be used as such, in the form of their formulations or in the application forms prepared therefrom by further dilutions, such as ready-to-use solutions, suspensions, emulsions, powders, pastes and granulates. The use is carried out in the usual way, for example, by watering, spraying, spraying, spreading. In the application tests carried out, the compounds of the formula (I) or (la) showed - also in combination with the herbicides mentioned above in (a) to (e) of the second group, such as the isopropyl ammonium salt of N-phosphonomethyl-glycine ("Roundup") - very good properties for the application in the semi-selective and non-selective field in the fight against weeds. It is noted that in relation to this date, the best method known to the applicant to carry out the aforementioned invention, is that which is clear from the present description of the invention. Having described the invention as above, property is claimed as contained in the following:

Claims (8)

  1. CLAIMS 1.- Semi-selective and non-selective herbicidal agents, characterized by an active content of at least one aryluracil or of an aryl-thiouracil of the general formula (I), or of an isomeric compound with the same of the general formula (la) in which formulas (I) and (la) respectively Q1 signifies oxygen or sulfur, Q2 signifies oxygen or sulfur, R1 signifies hydrogen or halogen, R2 signifies halogen or cyano, R3 signifies the following grouping: -A1-A2-A3 wherein A1 means a single bond, means oxygen, sulfur, -SO-, -S02, -CO- or the group -N-A4-, where A4 means hydrogen, hydroxy, alkyl, alkoxy, aryl, alkylsulfonyl or arylsulfonyl, or A1 further denotes alkanediyl, alkenodiyl, azaalkenediyl, alkynediyl, cycloalkanediyl, cycloalkenodiyl or arenediyl, respectively substituted if appropriate, A2 means a single bond, means oxygen, sulfur, -SO-, -S02-, -CO- or means the group -N-A4-, wherein A4 means hydrogen, alkyl, aryl, alkylcarbonyl, alkylsulfonyl or arylsulfonyl, or A2 further means alkanediyl, alkenodiyl, azaalkenediyl, alkynediyl, azaalkenodiyl, alkynediyl, cycloalkanediyl, cycloalkenediyl or arenediyl, substituted where appropriate, and A3 means hydrogen, hydroxy, mercapto, amino, cyano, isocyano, thiocyanate, nitro, carboxy, carbamoyl, thiocarbamoyl, sulfo, chlorosulfonyl, halogen or means alkyl, alkoxy, quiltium, alkylsulfinyl, alkylsulfonyl, alkylamino, dialkylamino, alkoxycarbonyl, dialkoxy (thio) phosphoryl, alkenyl, alkenyloxy, alkynylamino, alkylidenamino, alkenyloxycarbonyl, alkynyl, alkynyloxy, alkynylamino, alkynyloxycarbonyl, cycloalkyl, cycloalkyloxy, cycloalkylalkyl, cycloalkylalkoxy, cycloalkylisideamino, cycloalkyloxycarbonyl, cycloalkylalkoxycarbonyl, aryl, aryloxy, arylalkyl, arylalkoxy, aryloxycarbonyl, arylalkoxycarbonyl, heterocyclyl, heterocyclylalkyl, heterocyclyl-alkoxy or heterocyclylalcoxycarbonyl, respectively substituted, if appropriate, R4 means hydrogen, halogen or means alkyl, optionally substituted, R 5 means hydrogen, halogen or means optionally substituted alkyl, and R 6 signifies hydrogen, hydroxy, amino or means substituted alkyl, alkoxy, alkenyl or alkynyl, respectively, if appropriate. 2.- Semi-selective and non-selective herbicidal agents, characterized by an active content in at least one aryluracil or an aryl thiouracil of the general formula (I), or of an isomeric compound with the same of the general formula (la) in which formulas (I) and (la) respectively Q1 means oxygen or sulfur, Q2 means oxygen or sulfur, R1 means hydrogen or halogen, R2 means halogen or cyano, R3 means the following grouping:
  2. -A1-A2-A3 wherein A1 means a single bond, means oxygen, sulfur, -SO-, -S02, -CO- or the group -N-A4-, where A4 means hydrogen, hydroxy, alkyl, alkoxy, aryl, alkylsulfonyl or arylsulfonyl, or A1 further denotes alkanediyl, alkenodiyl, azaalkenediyl, alkynediyl, cycloalkanediyl, cycloalkenodiyl or arenediyl, respectively substituted if appropriate, A2 means a single bond, means oxygen, sulfur, -SO-, -S02-, -CO- or means the group -N-A4-, where A4 means hydrogen, alkyl, aryl, alkylcarbonyl, alkylsulfonyl or arylsulfonyl, or A2 further means alkanediyl, alkenodiyl, azaalkenediyl, alkynediyl, azaalkenodiyl, alkynediyl, cycloalkanodiyl, cycloalkenediyl or arenediyl, substituted where appropriate, and A3 means hydrogen, hydroxy, mercapto, amino, cyano, isocyano, thiocyanate, nitro, carboxy, carbamoyl, thiocarbamoyl, sulfo, chlorosulfonyl, halogen or means alkyl, alkoxy, alkylthio, alkylsulfinyl, alkylsulfonyl, alkynyl, dialkylamino, alkoxycarbonyl, dialkoxy (thio) phosphoryl, alkenyl, alkenyloxy, alkenylamino, alkylidenamino, alkenyloxycarbonyl, alkynyl, alkynyloxy, alkynylamino, alkynyloxycarbonyl, cycloalkyl, cycloalkyloxy, cycloalkylalkyl, cycloalkylalkoxy, cycloalkylideneamino, cycloalkyloxycarbonyl, cycloalkylalkoxycarbonyl, aryl, aryloxy, arylalkyl, arylalkoxy, aryloxycarbonyl , arylalkoxycarbonyl, heterocyclyl, heterocyclylalkyl, heterocyclyl-alkoxy or heterocyclylalcoxycarbonyl, respectively substituted, if appropriate, R4 means hydrogen, halogen or means alkyl, optionally substituted, R5 means hydrogen, halogen or means alkyl, optionally substituted, and R6 means hydrogen, hydroxy, amino or means optionally substituted alkyl, alkoxy, alkenyl or alkynyl, and additionally one or more compounds of a second group of herbicides, containing the classes of compounds (a) to (e) cited below: (a) carboxylic acids such as or, for example, 2,4-dichloro-phenoxyacetic acid (2,4-D), 4-amino-3, 5,6-trichloro-pyridin-2-yl-oxy acetic acid (Triclopyr), the salt of ammonium of 2-amino-4- (hydroxymethylphosphoryl) -butyric acid (Glufosinate-monium), the? - (hydroxymethylphosphinyl) -1-a-aminobutyryl-1-alanyl-1-alanine (Bialaphos), N-phosphonomethyl -glycine (Glyphosate) as well as the isopropyl onium salt and the trimethylsulfonium salt thereof, or 2- (4,5-dihydro-4-methyl-4-y-propyl-5-oxo-lH) acid -imidazol-2-yl) -pyridine-3-carboxylic acid (Imazapyr) as well as the isopropylammonium salt thereof; (b) Diphenyl ethers, such as, for example, 2-chloro-4-trifluoromethyl-phenyl-3-ethoxy-4-n-phenyl ether (Oxyfluorfen); (c) Diazin (onas), or triazin (onas), such as, for example, 2-chloro-4-ethylamino-6-i-propyl-amino-1,3,5-triazine (Atrazin), 2-chloro- 4,6-bis-ethylamino-1,3,5-triazine (Simazin), 5-bromo-3-s-butyl-6-methyl-uracil (bromatyl) or 4-amino-6-t- butyl-4, 5-dihydro-3-methylthio-1,2,4-triazin-5-one (Metribuzin); (d) Ureas, such as, for example, 3- (3,4-dichloro-phenyl) -1,1-dimethyl-urea (Diuron) or 3- (4,6-dimethyl-pyrimidin-2-yl) ) -l- (2-methoxycarbonyl-phenylsulfonyl) -urea (Sulphometuron-methyl); (e) Derivatives of pyridine, such as, for example, l, 1-dimethyl-4,4'-bipyridinium chloride (Paraquat) or l, 1-ethyl-2,2 / -bipyridinium chloride (Diquat) . 3. Semi-selective or non-selective herbicidal agents, characterized in that they have an active content in at least one compound of the formula (I) or (la) according to claim 1, wherein Q1 signifies oxygen or sulfur, Q2 signifies oxygen or sulfur, R1 means hydrogen, fluorine, chlorine or bromine, R2 means fluorine, chlorine, bromine, iodine or cyano, R3 means the following grouping
  3. -A1-A2-A3 where A1 means a single bond, means oxygen, sulfur -SO-, -S02-, -CO- or means the grouping -N-A4-, where A4 means hydrogen, hydroxy, alkyl with the 4 atoms of carbon, alkoxy with 1 to 4 carbon atoms, phenyl, alkylsulfonyl or phenylsulfonyl, or A1 further means alkanediyl with 1 to 6 carbon atoms, alkenodiyl with 2 to 6 carbon atoms, azaalqueodium with 2 to 6 carbon atoms , alkynediyl with 2 to 6 carbon atoms, cycloalkanediyl with 3 to 6 carbon atoms, cycloalkenodiyl with 3 to 6 carbon atoms or phenylene, respectively substituted, where appropriate, by fluorine, chlorine or bromine, A2 means a bond simple, means oxygen, sulfur, -SO-, -S02-, -CO- or means the grouping -N-A4-, where A4 means hydrogen, hydroxy, alkyl with 1 to 4 carbon atoms, alkoxy with 1 to 4 atoms of carbon, phenyl, alkylsulfonyl with 1 to 4 carbon atoms or phenylsulfonyl, or A2 also means alk nodiyl with 1 to 6 carbon atoms, alkenodiyl with 2 to 6 carbon atoms, azaalkenodiyl with 2 to 6 carbon atoms, alkynediyl with 2 to 6 carbon atoms, cycloalkanediyl with 3 to 6 carbon atoms, cycloalkenodiyl with 3 to 6 carbon atoms or phenylene substituted respectively where appropriate by fluorine, chlorine or bromine, A3 means hydrogen, hydroxy, amino, cyano, isocyano, thiocyanate, nitro, carboxy, carbamoyl, thiocarba oyl, sulfo, chlorosulfonyl, halogen, means, substituted respectively by halogen or by alkoxy with 1 to 4 carbon atoms, alkyl, alkoxy, alkylthio, alkylsulfinyl, alkylsulfonyl, alkylamino, dialkylamino, alkoxycarbonyl or dialkoxy (thio) phosphoryl respectively 1 to 6 carbon atoms in the alkyl groups means, where appropriate, substituted by halogen, alkenyl, alkenyloxy, alkenylamino, alkylidenamino, alkenyloxycarbonyl, alkynyl, alkynyloxy, alkynylamino or alkynyloxycarbonyl with 2 to 6 carbon atoms in the groups alkenyl, alkylidene or alkynyl, means, optionally substituted by halogen, by cyano, by carboxy, by alkyl with 1 to 4 carbon atoms and / or by alkoxycarbonyl with 1 to 4 carbon atoms, cycloalkyl, cycloalkyloxy, cycloalkylalkyl, cycloalkylalkoxy, cycloalkylideneamino, cycloalkyloxycarbonyl or cycloalkylalkoxycarbonyl with 3 to 6 carbon atoms in the cycloalkyl groups and, optionally, 1 to 4 carbon atoms in the alkyl groups, or, respectively, substituted case given by nitro, by cyano, by carboxy, by halogen, by alkyl with 1 to 4 carbon atoms, by haloalkyl with 1 to 4 carbon atoms, by alkoxy with 1 to 4 carbon atoms, by haloalkyloxy with 1 to 4 carbon atoms and / or by alkoxycarbonyl with 1 to 4 carbon atoms, phenyl, phenyloxy, phenyl-alkyl with 1 to 4 atoms carbon, phenyl-C 1 -C 4 -alkoxy, phenyl-oxycarbonyl or phenyl-alkoxycarbonyl with 4 carbon atoms, (each optionally hydrogenated in whole or in part) pyrrolyl, pyrazolyl, imidazolyl, triazolyl, furyl, thienyl, oxazolyl, isoxazolyl, thiazolyl, isothiazolyl, oxadiazolyl, thiadiazolyl, pyridinyl, pyrimidinyl, triazinyl, pyrazolyl-alkyl with 1 to 4 carbon atoms, furyl-alkyl with 1 to 4 carbon atoms, thienyl-alkyl with 1 to 4 atoms of carbon, oxazolyl-C 1 -C 4 -alkyl, isoxazole-C 1 -C 4 -alkyl, thiazol- C 1 -C 4 -alkyl, pyridinyl-C 1 -C 4 -alkyl, pyridinyl- alkyl with 1 to 4 carbon atoms, pyrazolylmethoxy, furylmethoxy, means perhydropyranylmethoxy or pyridylmethoxy, R4 means hydrogen, fluorine, chlorine, bromine or means alkyl having 1 to 4 carbon atoms, optionally substituted by fluorine and / or chlorine, R5 means hydrogen, fluorine, chlorine, bromine or means alkyl with 1 to 4 carbon atoms, optionally substituted by fluorine and / or chlorineand R6 means hydrogen, hydroxy, amino, or means alkyl, alkoxy, alkenyl or alkynyl with respectively up to 4 carbon atoms, respectively substituted, if appropriate, by fluorine, by chlorine or by cyano.
  4. 4.- Semi-selective and non-selective herbicidal agents, characterized by an active content in at least one compound of the formula (I) or (la) according to claim 2, wherein Q1 means oxygen or sulfur, Q2 means oxygen or sulfur R1 means hydrogen, fluorine, chlorine or bromine, R2 means fluorine, chlorine, bromine, iodine or cyano, R3 means the following group -A1-A2-A3 where A1 means a single bond, means oxygen, sulfur -SO-, - S02-, -CO- or means the grouping -N-A4-, where A4 means hydrogen, hydroxy, alkyl with 1 to 4 carbon atoms, alkoxy with 1 to 4 carbon atoms, phenyl, alkylsulfonyl or phenylsulfonyl, or A1 means also alkanediyl having 1 to 6 carbon atoms, alkenodiyl having 2 to 6 carbon atoms, azaalkenodiyl having 2 to 6 carbon atoms, alkynediyl having 2 to 6 carbon atoms, cycloalkanediyl having 3 to 6 carbon atoms, cycloalkenodiyl having 3 to 6 carbon or phenylene atoms, substituted if appropriate, fluorine, chlorine or bromine, A2 means a single bond, means oxygen, sulfur, -SO-, -S02-, -CO- or means the group -N-A4-, where A4 means hydrogen, hydroxy, alkyl with 1 to 4 carbon atoms, alkoxy with 1 to 4 carbon atoms, phenyl, alkylsulfonyl with 1 to 4 carbon atoms or phenylsulfonyl, or A2 also means alkanediyl with 1 to 6 carbon atoms, alkenodiyl with 2 to 6 carbon atoms, azaalkonodule with 2 to 6 carbon atoms, alkynediyl with 2 to 6 carbon atoms, cycloalkanediyl with 3 to 6 carbon atoms, cycloalkenodiyl with 3 to 6 carbon atoms or phenylene, respectively substituted by fluorine, chlorine or bromine, A3 means hydrogen, hydroxy, amino, cyano, isocyano, thiocyanate, nitro, carboxy, carbamoyl, thiocarbamoyl, sulfo, chlorosulfonyl, halogen, means, substituted respectively by halogen or by alkoxy with the 4-carbon atoms. carbon, alkyl, al coxy, alkylthio, alkylsulfonynyl, alkylsulfonyl, alkylamino, dialkylamino, alkoxycarbonyl or dialkoxy (thio) phosphoryl with 1 to 6 carbon atoms in the alkyl groups respectively means substituted, if appropriate, by halogen, alkenyl, alkenyloxy, alkenylamino , alkylidenamino, alkenyloxycarbonyl, alkynyl, alkynyloxy, alkynylamino or alkynyloxycarbonyl with 2 to 6 carbon atoms in the alkenyl, alkylidene or alkynyl groups, respectively, optionally substituted by halogen, by cyano, by carboxy, by alkyl with 1 to 4 carbon atoms and / or by alkoxycarbonyl having 1 to 4 carbon atoms, cycloalkyl, cycloalkyloxy, cycloalkylalkyl, cycloalkylalkoxy, cycloalkylideneamino, cycloalkyloxycarbonyl or cycloalkylalkoxycarbonyl with 3 to 6 carbon atoms respectively in the cycloalkyl groups and, if appropriate, 1 to 4 carbon atoms in the alkyl groups, or means, substituted resp. ectively, if appropriate, by nitro, by cyano, by carboxy, by halogen, by alkyl with 1 to 4 carbon atoms, by haloalkyl with 1 to 4 carbon atoms, by alkoxy with 1 to 4 carbon atoms, by haloalkyloxy with 1 to 4 carbon atoms and / or by alkoxycarbonyl with 1 to 4 carbon atoms, phenyl, phenyloxy, phenyl-alkyl with 1 to 4 carbon atoms, phenyl-alkoxy with 4 carbon atoms, phenyl-oxycarbonyl or phenyl-alkoxycarbonyl having 4 carbon atoms, (each optionally hydrogenated in whole or in part) pyrrolyl, pyrazolyl, imidazolyl, triazolyl, furyl, thienyl, oxazolyl, isoxazolyl, thiazolyl, isothiazolyl, oxadiazolyl, thiadiazolyl, pyridinyl, pyrimidinyl , triazinyl, pyrazolyl-alkyl with 1 to 4 carbon atoms, furyl-alkyl with 4 carbon atoms, thienyl-alkyl with 1 to 4 carbon atoms, oxazolyl-C 1 -C 4 -alkyl, isoxazole-C 1 -C 4 -alkyl, thiazol-C 1 -C 4 -alkyl, pyridinyl-C 1 -C 4 -alkyl, pyrimidinyl-1-alkyl to 4 carbon atoms, pyrazolylmethoxy, furylmethoxy, means perhydropyranylmethoxy or pyridylmethoxy, R4 means hydrogen, fluorine, chlorine, bromine or means alkyl having 1 to 4 carbon atoms, optionally substituted by fluorine and / or chlorine, R5 means hydrogen , fluorine, chlorine, bromine or means alkyl having 1 to 4 carbon atoms, optionally substituted by fluorine and / or chlorine, and R6 means hydrogen, hydroxy, amino, or means alkyl, alkoxy, alkenyl or alkynyl respectively up to 4 carbon atoms, respectively substituted, if appropriate, by fluorine, chlorine or cyano, and additionally one or more compounds of a second group of herbicides, containing the classes of compounds (a) to (e) cited below: (a) acids carboxylic acids such as, for example, 2,4-dichloro-phenoxyacetic acid (2,4-D), 4-amino-3, 5,6-trichloro-pyridin-2-yl-oxy-acetic acid (Triclopyr), ammonium salt of 2-amino-4- (hydroxymethylphosphyl) -butyric acid (Glufosinate-ammonium), the α- (hydroxy-methylphosphinyl) -1-a-aminobutyryl-1-alanyl-1-alanine (Bialaphos), the N-phosphonomethyl-glycine (Glyphosate) as well as the isopropylammonium salt and the trimethylsulfonium salt thereof, or the 2- (4,5-dihydro-4-methyl-4-i-propyl-5- oxo-lH-imidazol-2-yl) -pyridine-3-carboxylic acid (Imazapyr) as well as the isopropylammonium salt thereof; (b) Diphenyl ethers, such as, for example, 2-chloro-4-trifluoromethyl-phenyl-3-ethoxy-4-nitrophenyl ether (Oxyfluorfen); (c) Diazin (onas), or triazin (onas), such as, for example, 2-chloro-4-ethylamino-6-i-propyl-amino-1,3,5-triazine (Atrazin), 2-chloro- 4,6-bis-ethylamino-1,3,5-triazine (Simazin), 5-bromo-3-s-butyl-6-methyl-uracil (bromatyl) or 4-amino-6-t- butyl-4, 5-dihydro-3-methylthio-1,2,4-triazin-5-one (Metribuzin); (d) Ureas, such as, for example, 3- (3,4-dichloro-phenyl) -1,1-dimethyl-urea (Diuron) or 3- (4,6-dimethyl-pyrimidin-2-yl) ) -1- (2-methoxycarbonyl-phenylsulfonyl) -urea (Sulphometuron-methyl); (e) Derivatives of pyridine, such as, for example, l, 1-dimethyl-4,4'-bipyridinium chloride (Paraquat) or 1, 1-ethylene-2,2'-bipyridinium chloride (Diquat ).
  5. 5.- Semi-selective and non-selective herbicidal agents according to claim 2, characterized in that in the active compound combination the proportion by weight between the aryluracil or the aryl-thiouracil of the formula (I) or the isomeric compound of the same of the formula (la) and an active product of a second group of herbicides of the class of compounds (a) to (e) mentioned in claim 2, is between 1: 0.001 and 1: 1,000.
  6. 6. Procedure for the semi-selective and non-selective fight against weeds, characterized in that an active product according to claims 1 or 3, or a combination thereof, is allowed to act on the weeds and / or on its environment. active products according to claims 2 or 4.
  7. 7. Use of the active ingredients according to claims 1 or 3 or of the combinations of active products according to claims 2 or 4, for the semi-selective and non-selective fight against weeds.
  8. 8. - Process for the preparation of herbicidal, semi-selective and non-selective agents, characterized in that active ingredients are combined according to claims 1 or 3 or combinations of active products according to claims 2 or 4, with extenders and / or with surfactants.
MX9701953A 1994-09-15 1995-09-04 Use of aryluracils in semi-selective and non-selective weed control. MX9701953A (en)

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EP4230620A1 (en) 2022-02-22 2023-08-23 Bayer Aktiengesellschaft Substituted n-amino-n-benzoic acid uracils, their salts and use of said compounds as herbicidal agents
WO2023161172A1 (en) 2022-02-22 2023-08-31 Bayer Aktiengesellschaft Substituted n-benzoic acid uracils and salts thereof, and use thereof as herbicidal active substances
EP4230621A1 (en) 2022-02-22 2023-08-23 Bayer AG Substituted n-benzoic acid uracils, their salts and use of said compounds as herbicidal agents
WO2024078906A1 (en) 2022-10-10 2024-04-18 Bayer Aktiengesellschaft Substituted n-phenyluracils and salts thereof, and use thereof as herbicidal active substances
WO2024104952A1 (en) 2022-11-16 2024-05-23 Bayer Aktiengesellschaft Substituted cyclopropyloxyphenyluracils and salts thereof, and use thereof as herbicidal active substances
WO2024104956A1 (en) 2022-11-16 2024-05-23 Bayer Aktiengesellschaft Substituted cycloalkylsulfanylphenyluracils and their salts, and their use as herbicidal active substances
WO2024104954A1 (en) 2022-11-16 2024-05-23 Bayer Aktiengesellschaft Substituted cycloalkyloxyphenyluracils and salts thereof, and use thereof as herbicidal active substances

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