MX2022014035A - Proceso para la ciclopropanacion de olefinas utilizando compuestos de n-metil-n-nitroso. - Google Patents
Proceso para la ciclopropanacion de olefinas utilizando compuestos de n-metil-n-nitroso.Info
- Publication number
- MX2022014035A MX2022014035A MX2022014035A MX2022014035A MX2022014035A MX 2022014035 A MX2022014035 A MX 2022014035A MX 2022014035 A MX2022014035 A MX 2022014035A MX 2022014035 A MX2022014035 A MX 2022014035A MX 2022014035 A MX2022014035 A MX 2022014035A
- Authority
- MX
- Mexico
- Prior art keywords
- alkyl
- substrate
- cyclopropanation
- olefins
- methyl
- Prior art date
Links
- 238000000034 method Methods 0.000 title abstract 3
- 150000001336 alkenes Chemical class 0.000 title 1
- 238000005888 cyclopropanation reaction Methods 0.000 title 1
- 239000000758 substrate Substances 0.000 abstract 3
- 239000002585 base Substances 0.000 abstract 2
- 239000003054 catalyst Substances 0.000 abstract 2
- 239000002253 acid Substances 0.000 abstract 1
- 229910052783 alkali metal Inorganic materials 0.000 abstract 1
- -1 alkali metal nitrite Chemical class 0.000 abstract 1
- 150000003973 alkyl amines Chemical class 0.000 abstract 1
- 239000011203 carbon fibre reinforced carbon Substances 0.000 abstract 1
- 125000001559 cyclopropyl group Chemical group [H]C1([H])C([H])([H])C1([H])* 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- 229910052723 transition metal Inorganic materials 0.000 abstract 1
- 150000003624 transition metals Chemical class 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
- C07C2/86—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation between a hydrocarbon and a non-hydrocarbon
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C241/00—Preparation of compounds containing chains of nitrogen atoms singly-bound to each other, e.g. hydrazines, triazanes
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C13/00—Cyclic hydrocarbons containing rings other than, or in addition to, six-membered aromatic rings
- C07C13/02—Monocyclic hydrocarbons or acyclic hydrocarbon derivatives thereof
- C07C13/04—Monocyclic hydrocarbons or acyclic hydrocarbon derivatives thereof with a three-membered ring
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C243/00—Compounds containing chains of nitrogen atoms singly-bound to each other, e.g. hydrazines, triazanes
- C07C243/04—N-nitroso compounds
- C07C243/06—N-nitroso-amines
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals
- C07C2523/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals of the platinum group metals
- C07C2523/44—Palladium
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- C07C2531/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- C07C2531/20—Carbonyls
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2601/00—Systems containing only non-condensed rings
- C07C2601/02—Systems containing only non-condensed rings with a three-membered ring
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Catalysts (AREA)
Abstract
Un método para convertir un doble enlace de carbono-carbono en un sustrato en un anillo de ciclopropano, método que comprende el paso de tratar el sustrato con un compuesto de N-alquil-N-nitroso, un catalizador de metal de transición y una base acuosa, en donde el compuesto de N-alquil-N-nitroso se forma al hacer reaccionar una alquil-amina con un nitrito de metal alcalino en la presencia de un ácido monobásico o dibásico, o una mezcla de los mismos, y en donde el compuesto de N-alquil-N-nitroso no se destila antes de que se mezcle con el sustrato, el catalizador y la base.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GBGB1516396.7A GB201516396D0 (en) | 2015-09-16 | 2015-09-16 | Improvements in or relating to organic compounds |
Publications (1)
Publication Number | Publication Date |
---|---|
MX2022014035A true MX2022014035A (es) | 2022-11-30 |
Family
ID=54363254
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
MX2018002778A MX2018002778A (es) | 2015-09-16 | 2016-09-14 | Proceso para la ciclopropanacion de olefinas utilizando compuestos de n-metil-n-nitroso. |
MX2022014035A MX2022014035A (es) | 2015-09-16 | 2018-03-05 | Proceso para la ciclopropanacion de olefinas utilizando compuestos de n-metil-n-nitroso. |
Family Applications Before (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
MX2018002778A MX2018002778A (es) | 2015-09-16 | 2016-09-14 | Proceso para la ciclopropanacion de olefinas utilizando compuestos de n-metil-n-nitroso. |
Country Status (11)
Country | Link |
---|---|
US (2) | US10611704B2 (es) |
EP (2) | EP3882230A1 (es) |
JP (2) | JP6884767B2 (es) |
CN (2) | CN108025997B (es) |
BR (1) | BR112018004042B1 (es) |
ES (1) | ES2887223T3 (es) |
GB (1) | GB201516396D0 (es) |
IL (2) | IL257799B (es) |
MX (2) | MX2018002778A (es) |
SG (1) | SG10202003047PA (es) |
WO (1) | WO2017046122A1 (es) |
Families Citing this family (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB201516396D0 (en) * | 2015-09-16 | 2015-10-28 | Givaudan Sa | Improvements in or relating to organic compounds |
CN108484347B (zh) * | 2018-04-28 | 2021-02-05 | 江苏八巨药业有限公司 | 一种末端异戊二烯类化合物环丙烷化的制备方法 |
GB201810514D0 (en) * | 2018-06-27 | 2018-08-15 | Givaudan Sa | Improvements in or relating to organic compounds |
US11993552B2 (en) | 2019-07-02 | 2024-05-28 | Asymchem Laboratories (Tianjin) Co., Ltd. | Method and device for continuously synthesizing cyclopropane compounds |
CN113275032A (zh) * | 2020-02-20 | 2021-08-20 | 太原理工大学 | 用于甲苯甲醇侧链烷基化的分子筛催化剂及其制备方法和应用 |
Family Cites Families (20)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE855551C (de) | 1942-05-13 | 1952-11-13 | Knoll Ag | Verfahren zur Herstellung von Mono- bzw. symmetrischem Dimethylharnstoff |
US2960536A (en) * | 1957-04-11 | 1960-11-15 | Fmc Corp | Process for the production of nitrosamines |
JPS4933933B1 (es) * | 1970-02-16 | 1974-09-11 | ||
JPS54160325A (en) | 1978-06-05 | 1979-12-19 | Mitsubishi Petrochem Co Ltd | Nitrosation |
US4650881A (en) | 1985-04-01 | 1987-03-17 | Iowa State University Research Foundation, Inc. | Synthesis of isocoumarins via thallation-olefination of arenes |
US5854405A (en) * | 1997-11-13 | 1998-12-29 | Aerojet-General Corporation | Continuous process for diazomethane from an n-methyl-n-nitrosoamine and from methylurea through n-methyl-n-nitrosourea |
GB2357501B (en) | 1999-12-23 | 2001-11-28 | Phoenix Chemicals Ltd | Generation of diazomethane |
EP1269982A1 (en) | 2001-06-30 | 2003-01-02 | Givaudan SA | Fragrance and flavour compositions |
WO2010131145A1 (en) | 2009-05-12 | 2010-11-18 | Pfizer Limited | Cyclobutenedione derivatives |
EP2438182B1 (de) | 2009-06-05 | 2018-10-10 | Basf Se | Biokatalytische herstellung von ambroxan |
JP2011105691A (ja) * | 2009-11-20 | 2011-06-02 | M Carreira Erick | トリフルオロメチルシクロプロパン化合物の製造方法 |
CN102127070A (zh) * | 2010-01-15 | 2011-07-20 | 山东轩竹医药科技有限公司 | 吡啶并环衍生物 |
WO2013039988A1 (en) | 2011-09-13 | 2013-03-21 | Glax0Smithkline Llc | Azaindazoles |
GB201201066D0 (en) * | 2012-01-23 | 2012-03-07 | Bakhu Ltd | A method for the preparation of diazoalkanes |
US20130273619A1 (en) | 2012-04-16 | 2013-10-17 | Basf Se | Process for the Preparation of (3E, 7E)-Homofarnesol |
CN102976945A (zh) * | 2012-12-29 | 2013-03-20 | 贵阳柏丝特化工有限公司 | 一种利用微反应器合成菊酸乙酯化合物的方法 |
GB201318894D0 (en) | 2013-10-25 | 2013-12-11 | Givaudan Sa | Improvements in or relating to organic compounds |
GB201318886D0 (en) | 2013-10-25 | 2013-12-11 | Givaudan Sa | Improvements i or relating to organic compounds |
GB201319677D0 (en) * | 2013-11-07 | 2013-12-25 | Eth Z Rich | Cyclopropanation |
GB201516396D0 (en) * | 2015-09-16 | 2015-10-28 | Givaudan Sa | Improvements in or relating to organic compounds |
-
2015
- 2015-09-16 GB GBGB1516396.7A patent/GB201516396D0/en not_active Ceased
-
2016
- 2016-09-14 CN CN201680053827.6A patent/CN108025997B/zh active Active
- 2016-09-14 BR BR112018004042-8A patent/BR112018004042B1/pt active IP Right Grant
- 2016-09-14 WO PCT/EP2016/071630 patent/WO2017046122A1/en active Application Filing
- 2016-09-14 EP EP21173454.6A patent/EP3882230A1/en active Pending
- 2016-09-14 SG SG10202003047PA patent/SG10202003047PA/en unknown
- 2016-09-14 JP JP2018513781A patent/JP6884767B2/ja active Active
- 2016-09-14 ES ES16766534T patent/ES2887223T3/es active Active
- 2016-09-14 US US15/758,795 patent/US10611704B2/en active Active
- 2016-09-14 EP EP16766534.8A patent/EP3350144B1/en active Active
- 2016-09-14 MX MX2018002778A patent/MX2018002778A/es unknown
- 2016-09-14 CN CN202110033366.9A patent/CN112778071A/zh active Pending
-
2018
- 2018-02-28 IL IL257799A patent/IL257799B/en active IP Right Grant
- 2018-03-05 MX MX2022014035A patent/MX2022014035A/es unknown
-
2019
- 2019-12-31 US US16/731,361 patent/US11034628B2/en active Active
-
2020
- 2020-10-13 IL IL278017A patent/IL278017B/en unknown
-
2021
- 2021-05-12 JP JP2021080880A patent/JP7330226B2/ja active Active
Also Published As
Publication number | Publication date |
---|---|
IL257799A (en) | 2018-04-30 |
IL278017B (en) | 2021-10-31 |
ES2887223T3 (es) | 2021-12-22 |
SG10202003047PA (en) | 2020-05-28 |
US20190055172A1 (en) | 2019-02-21 |
CN108025997A (zh) | 2018-05-11 |
GB201516396D0 (en) | 2015-10-28 |
JP2018527373A (ja) | 2018-09-20 |
MX2018002778A (es) | 2018-04-13 |
BR112018004042B1 (pt) | 2022-03-22 |
EP3350144B1 (en) | 2021-06-23 |
JP6884767B2 (ja) | 2021-06-09 |
CN112778071A (zh) | 2021-05-11 |
IL257799B (en) | 2020-10-29 |
CN108025997B (zh) | 2021-01-15 |
US10611704B2 (en) | 2020-04-07 |
BR112018004042A2 (es) | 2018-10-02 |
JP2021113234A (ja) | 2021-08-05 |
US20200172453A1 (en) | 2020-06-04 |
WO2017046122A1 (en) | 2017-03-23 |
EP3350144A1 (en) | 2018-07-25 |
JP7330226B2 (ja) | 2023-08-21 |
EP3882230A1 (en) | 2021-09-22 |
US11034628B2 (en) | 2021-06-15 |
IL278017A (en) | 2020-11-30 |
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