MX2016013269A - Proceso para la produccion de alquenoles y uso de los mismos para la produccion de 1,3-butadieno. - Google Patents

Proceso para la produccion de alquenoles y uso de los mismos para la produccion de 1,3-butadieno.

Info

Publication number
MX2016013269A
MX2016013269A MX2016013269A MX2016013269A MX2016013269A MX 2016013269 A MX2016013269 A MX 2016013269A MX 2016013269 A MX2016013269 A MX 2016013269A MX 2016013269 A MX2016013269 A MX 2016013269A MX 2016013269 A MX2016013269 A MX 2016013269A
Authority
MX
Mexico
Prior art keywords
production
alkenols
butadiene
butanediol
diol
Prior art date
Application number
MX2016013269A
Other languages
English (en)
Inventor
Raffaele Cesana
Ramello Stefano
Spano' Guido
Original Assignee
Versalis Spa
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Versalis Spa filed Critical Versalis Spa
Publication of MX2016013269A publication Critical patent/MX2016013269A/es

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/60—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by elimination of -OH groups, e.g. by dehydration
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/12—Silica and alumina
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/10—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of rare earths
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/612—Surface area less than 10 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/613—10-100 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • B01J37/0027—Powdering
    • B01J37/0036—Grinding
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/03—Precipitation; Co-precipitation
    • B01J37/031—Precipitation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/20—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms
    • C07C1/24—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms by elimination of water
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/12—Silica and alumina

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

Proceso para la producción de alquenoles que comprende la deshidratación de al menos un diol en la presencia de al menos un catalizador basado en óxido de cerio, en donde el catalizador basado en óxido de cerio se obtiene mediante precipitación, en la presencia de al menos una base, de al menos un compuesto que tiene cerio. De manera preferente, el diol puede ser un butanodiol, de manera más preferente 1,3-butanodiol, de manera aún más preferente bio-10 1,3-butanodiol derivado de procesos biosintéticos. Estos alquenoles se pueden usar de manera ventajosa para la producción de 1,3-butadieno, en particular de bio-1,3- butadieno.
MX2016013269A 2014-05-16 2015-05-15 Proceso para la produccion de alquenoles y uso de los mismos para la produccion de 1,3-butadieno. MX2016013269A (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
ITMI20140897 2014-05-16
PCT/IB2015/053592 WO2015173780A1 (en) 2014-05-16 2015-05-15 Process for the production of alkenols and use thereof for the production of 1,3-butadiene

Publications (1)

Publication Number Publication Date
MX2016013269A true MX2016013269A (es) 2017-02-22

Family

ID=51220686

Family Applications (1)

Application Number Title Priority Date Filing Date
MX2016013269A MX2016013269A (es) 2014-05-16 2015-05-15 Proceso para la produccion de alquenoles y uso de los mismos para la produccion de 1,3-butadieno.

Country Status (14)

Country Link
US (1) US9862664B2 (es)
EP (1) EP3142785B1 (es)
JP (1) JP6804300B2 (es)
CN (1) CN106414383B (es)
BR (1) BR112016026512A2 (es)
DK (1) DK3142785T3 (es)
ES (1) ES2924482T3 (es)
HU (1) HUE059279T2 (es)
MX (1) MX2016013269A (es)
PL (1) PL3142785T3 (es)
PT (1) PT3142785T (es)
RU (1) RU2695786C2 (es)
TW (1) TWI659946B (es)
WO (1) WO2015173780A1 (es)

Families Citing this family (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
PL3262023T3 (pl) * 2015-02-23 2021-07-05 Versalis S.P.A. Sposób wytwarzania dienów
JP6456231B2 (ja) * 2015-04-27 2019-01-23 昭和電工株式会社 ジエン化合物の製造方法
JP6684635B2 (ja) * 2016-04-06 2020-04-22 昭和電工株式会社 ジエン化合物の製造方法
JP6656074B2 (ja) * 2016-04-26 2020-03-04 昭和電工株式会社 アリル型不飽和アルコールの脱水による共役ジエン化合物の製造方法
JP6684641B2 (ja) * 2016-04-26 2020-04-22 昭和電工株式会社 共役ジエン化合物の製造方法及びアリル型不飽和アルコールの脱水触媒
WO2018040058A1 (en) * 2016-09-02 2018-03-08 Rhodia Operations Dehydration of diols
IT201600105178A1 (it) * 2016-10-19 2018-04-19 Versalis Spa Procedimento per la produzione di dieni
US10639621B2 (en) * 2018-03-05 2020-05-05 Qatar University Nanoporous cerium oxide with interconnected pores for catalysis and a cost-effective method of preparing thereof
MX2021003364A (es) 2018-09-21 2021-08-16 Versalis Spa Proceso para la purificacion de bio-1,3-butanodiol a partir de un caldo de fermentacion.
IT201900015069A1 (it) 2019-08-27 2021-02-27 Versalis Spa Catalizzatore comprendente coke e procedimento per la produzione di dieni.
CN110465298B (zh) * 2019-08-29 2022-01-28 湘潭大学 一种用于糖类发酵产物abe直接制备长碳链化合物的催化剂及其制备方法
IT201900025000A1 (it) 2019-12-20 2021-06-20 Versalis Spa Procedimento per la produzione di dieni.
CN113385212B (zh) * 2021-06-11 2022-12-27 上海巽田科技股份有限公司 用于制备烯醇的非金属掺杂的碳基催化剂及使用其制备烯醇的方法
CN115894171B (zh) * 2022-11-17 2024-04-16 凯瑞环保科技股份有限公司 一种醋酸仲丁酯加氢制备仲丁醇的方法

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DE1150671B (de) 1961-12-30 1963-06-27 Huels Chemische Werke Ag Verfahren zur Herstellung reiner Butenole
DE1908620A1 (de) 1969-02-21 1970-09-03 Basf Ag Verfahren zur Herstellung modifizierter Polyolefinwachse
FR2044085A5 (es) * 1969-05-08 1971-02-19 Raffinage Cie Francaise
SU396312A1 (ru) 1971-02-01 1973-08-29 Г. Д. Закумбаева, Закарина , Д. В. Сокольский Способ получения виниловых спиртов
US4400562A (en) 1981-07-02 1983-08-23 The United States Of America As Represented By The Secretary Of The Navy Alkenol synthesis
JPS63222135A (ja) 1987-03-11 1988-09-16 Nkk Corp 不飽和アルコ−ルの製造方法
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FR2748740B1 (fr) 1996-05-15 1998-08-21 Rhone Poulenc Chimie Composition a base d'oxyde de cerium et d'oxyde de zirconium a haute surface specifique et a capacite elevee de stockage d'oxygene, procede de preparation et utilisation en catalyse
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CN106119113A (zh) 2009-04-30 2016-11-16 基因组股份公司 用于生产 1,3‑丁二醇的生物
CN102686719A (zh) * 2009-10-30 2012-09-19 株式会社大赛璐 具有1,3-丁二醇生产功能的基因重组微生物及其应用
CN101759529B (zh) * 2010-01-19 2013-04-10 山西大学 一种由1,4-丁二醇合成3-丁烯-1-醇的方法
BR112013032516A2 (pt) * 2011-06-17 2017-03-01 Invista Tech Sarl método de biosintetizar butadieno e método para produzir butadieno
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BR112014003708A2 (pt) 2011-08-19 2017-03-07 Genomatica Inc microorganismos métodos para a produção de 2,4-pentadienoato, butadieno, propileno, 1,3-butanodiol e álcoois relacionados
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ITMI20132069A1 (it) 2013-12-11 2015-06-12 Versalis Spa Procedimento per la produzione di zuccheri da biomassa

Also Published As

Publication number Publication date
JP2017520511A (ja) 2017-07-27
DK3142785T3 (da) 2022-08-01
US9862664B2 (en) 2018-01-09
RU2695786C2 (ru) 2019-07-26
TW201602068A (zh) 2016-01-16
PL3142785T3 (pl) 2022-08-22
TWI659946B (zh) 2019-05-21
JP6804300B2 (ja) 2020-12-23
CN106414383A (zh) 2017-02-15
US20170057893A1 (en) 2017-03-02
RU2016140173A3 (es) 2018-09-21
BR112016026512A2 (pt) 2017-08-15
RU2016140173A (ru) 2018-06-20
PT3142785T (pt) 2022-07-29
EP3142785B1 (en) 2022-06-29
WO2015173780A1 (en) 2015-11-19
ES2924482T3 (es) 2022-10-07
CN106414383B (zh) 2019-10-25
EP3142785A1 (en) 2017-03-22
HUE059279T2 (hu) 2022-11-28

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