MX2014008638A - Proceso para la produccion de hexametilendiamina a partir de 5-hidroximetilfurfural. - Google Patents

Proceso para la produccion de hexametilendiamina a partir de 5-hidroximetilfurfural.

Info

Publication number
MX2014008638A
MX2014008638A MX2014008638A MX2014008638A MX2014008638A MX 2014008638 A MX2014008638 A MX 2014008638A MX 2014008638 A MX2014008638 A MX 2014008638A MX 2014008638 A MX2014008638 A MX 2014008638A MX 2014008638 A MX2014008638 A MX 2014008638A
Authority
MX
Mexico
Prior art keywords
hexanediol
production
hexamethylenediamine
reduction
hmda
Prior art date
Application number
MX2014008638A
Other languages
English (en)
Other versions
MX336933B (es
Inventor
Eric L Dias
James A W Shoemaker
Thomas R Boussie
Vincent J Murphy
Original Assignee
Rennovia Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Rennovia Inc filed Critical Rennovia Inc
Publication of MX2014008638A publication Critical patent/MX2014008638A/es
Publication of MX336933B publication Critical patent/MX336933B/es

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/15—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively
    • C07C29/151—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases
    • C07C29/153—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases characterised by the catalyst used
    • C07C29/156—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases characterised by the catalyst used containing iron group metals, platinum group metals or compounds thereof
    • C07C29/157—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases characterised by the catalyst used containing iron group metals, platinum group metals or compounds thereof containing platinum group metals or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C209/00—Preparation of compounds containing amino groups bound to a carbon skeleton
    • C07C209/04—Preparation of compounds containing amino groups bound to a carbon skeleton by substitution of functional groups by amino groups
    • C07C209/14—Preparation of compounds containing amino groups bound to a carbon skeleton by substitution of functional groups by amino groups by substitution of hydroxy groups or of etherified or esterified hydroxy groups
    • C07C209/16—Preparation of compounds containing amino groups bound to a carbon skeleton by substitution of functional groups by amino groups by substitution of hydroxy groups or of etherified or esterified hydroxy groups with formation of amino groups bound to acyclic carbon atoms or to carbon atoms of rings other than six-membered aromatic rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/132—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/132—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group
    • C07C29/136—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH
    • C07C29/14—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of a —CHO group
    • C07C29/141—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of a —CHO group with hydrogen or hydrogen-containing gases
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/17—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by hydrogenation of carbon-to-carbon double or triple bonds
    • C07C29/175—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by hydrogenation of carbon-to-carbon double or triple bonds with simultaneous reduction of an oxo group
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D307/00—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom
    • C07D307/02—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings
    • C07D307/34—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
    • C07D307/38—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with substituted hydrocarbon radicals attached to ring carbon atoms
    • C07D307/40—Radicals substituted by oxygen atoms
    • C07D307/46—Doubly bound oxygen atoms, or two oxygen atoms singly bound to the same carbon atom
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D307/00—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom
    • C07D307/02—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings
    • C07D307/34—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
    • C07D307/38—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with substituted hydrocarbon radicals attached to ring carbon atoms
    • C07D307/40—Radicals substituted by oxygen atoms
    • C07D307/46—Doubly bound oxygen atoms, or two oxygen atoms singly bound to the same carbon atom
    • C07D307/48—Furfural
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D307/00—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom
    • C07D307/02—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings
    • C07D307/34—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
    • C07D307/38—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with substituted hydrocarbon radicals attached to ring carbon atoms
    • C07D307/40—Radicals substituted by oxygen atoms
    • C07D307/46—Doubly bound oxygen atoms, or two oxygen atoms singly bound to the same carbon atom
    • C07D307/48—Furfural
    • C07D307/50—Preparation from natural products

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

Se describen procesos para la conversión de una fuente de carbohidratos a hexametilendiamina (HMDA) y a intermediarios útiles para la producción de hexametilendiamina y otros químicos industriales. La HMDA se produce por reducción directa de un substrato de furfural a 1,6-hexanodiol en presencia de hidrógeno y un catalizador de reducción heterogéneo que comprende Pt o por reducción indirecta de un substrato de furfural a 1,6-hexanodiol en donde 1,2,6-hexanotriol se produce por la reducción del substrato de furfural en presencia de hidrógeno y un catalizador que comprende Pt y 1,2,6-hexanodiol luego se convierte por hidrogenación en presencia de un catalizador que comprende Pt a 1,6 hexanodiol, cada proceso luego procede a la producción de HMDA por rutas conocidas, tal como aminación del 1,6 hexanodiol. También se describen catalizadores útiles para la producción directa e indirecta de 1,6 -hexanodiol.
MX2014008638A 2012-01-18 2013-01-11 Proceso para la produccion de hexametilendiamina a partir de 5-hidroximetilfurfural. MX336933B (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US201261588093P 2012-01-18 2012-01-18
PCT/US2013/021315 WO2013109477A1 (en) 2012-01-18 2013-01-11 Process for production of hexamethylenediamine from 5 - hydroxymethylfurfural

Publications (2)

Publication Number Publication Date
MX2014008638A true MX2014008638A (es) 2014-12-08
MX336933B MX336933B (es) 2016-02-08

Family

ID=47605786

Family Applications (1)

Application Number Title Priority Date Filing Date
MX2014008638A MX336933B (es) 2012-01-18 2013-01-11 Proceso para la produccion de hexametilendiamina a partir de 5-hidroximetilfurfural.

Country Status (18)

Country Link
US (7) US8853458B2 (es)
EP (2) EP2804848B1 (es)
JP (1) JP6253203B2 (es)
KR (1) KR20140113706A (es)
CN (2) CN104066710B (es)
AR (1) AR089707A1 (es)
AU (2) AU2013210005B2 (es)
BR (1) BR112014017585B1 (es)
CA (1) CA2860886A1 (es)
EA (1) EA025555B1 (es)
HK (1) HK1204318A1 (es)
IN (1) IN2014DN06596A (es)
MX (1) MX336933B (es)
MY (1) MY165219A (es)
SA (2) SA115360430B1 (es)
SG (3) SG11201404098XA (es)
WO (1) WO2013109477A1 (es)
ZA (2) ZA201405258B (es)

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CN110935447B (zh) * 2018-09-25 2021-12-07 中国科学院大连化学物理研究所 一种用于甘油水溶液氢解制1,3-丙二醇的催化剂及其制备方法
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CN110420637B (zh) * 2019-08-06 2020-10-02 北京化工大学 一种W改性载体负载金属Pd制备复合型催化剂的方法及其应用
CN111072490A (zh) * 2019-12-16 2020-04-28 中国科学院大连化学物理研究所 一种基于Ni基催化剂的己二醛制备己二胺的方法
CN110981691B (zh) * 2019-12-16 2021-01-15 北京大学 一种利用单糖合成1,6-己二醇的方法
JP7324721B2 (ja) * 2020-02-12 2023-08-10 株式会社ダイセル １，４－アンヒドロエリスリトール水素化分解触媒、及び前記触媒を使用した１，３－ブタンジオールの製造方法
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JP2015506943A (ja) 2015-03-05
US9783473B2 (en) 2017-10-10
SA113340200B1 (ar) 2015-07-09
CA2860886A1 (en) 2013-07-25
AU2013210005A1 (en) 2014-07-31
EP2804848B1 (en) 2018-10-03
US20180170844A1 (en) 2018-06-21
BR112014017585A2 (pt) 2017-06-13
JP6253203B2 (ja) 2017-12-27
WO2013109477A1 (en) 2013-07-25
AU2017208286A1 (en) 2017-08-10
KR20140113706A (ko) 2014-09-24
CN104066710B (zh) 2016-06-29
EA025555B1 (ru) 2017-01-30
US20160068470A1 (en) 2016-03-10
US20130184495A1 (en) 2013-07-18
IN2014DN06596A (es) 2015-05-22
BR112014017585B1 (pt) 2020-11-24
MX336933B (es) 2016-02-08
SG11201404098XA (en) 2014-10-30
AR089707A1 (es) 2014-09-10
BR112014017585A8 (pt) 2017-07-04
US20170144962A1 (en) 2017-05-25
US9518005B2 (en) 2016-12-13
ZA201405258B (en) 2016-08-31
ZA201505891B (en) 2016-12-21
US20160068469A1 (en) 2016-03-10
CN104066710A (zh) 2014-09-24
SG10201913670TA (en) 2020-03-30
AU2013210005B2 (en) 2017-04-27
US20170050906A1 (en) 2017-02-23
EP3466919B1 (en) 2021-10-06
US20140343323A1 (en) 2014-11-20
SA115360430B1 (ar) 2015-09-03
HK1204318A1 (en) 2015-11-13
US9035109B2 (en) 2015-05-19
CN106008163A (zh) 2016-10-12
EA201491289A1 (ru) 2014-12-30
EP3466919A1 (en) 2019-04-10
CN106008163B (zh) 2019-10-08
EP2804848A1 (en) 2014-11-26
MY165219A (en) 2018-03-09
SG10201700153WA (en) 2017-03-30
US8853458B2 (en) 2014-10-07

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