EA201491289A1 - Способ получения гексаметилендиамина из 5-гидроксиметилфурфурола - Google Patents

Способ получения гексаметилендиамина из 5-гидроксиметилфурфурола

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Publication number
EA201491289A1
EA201491289A1 EA201491289A EA201491289A EA201491289A1 EA 201491289 A1 EA201491289 A1 EA 201491289A1 EA 201491289 A EA201491289 A EA 201491289A EA 201491289 A EA201491289 A EA 201491289A EA 201491289 A1 EA201491289 A1 EA 201491289A1
Authority
EA
Eurasian Patent Office
Prior art keywords
hexanediol
hmda
furfurol
hexamethylenediamine
reduction
Prior art date
Application number
EA201491289A
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English (en)
Other versions
EA025555B1 (ru
Inventor
Эрик Л. Диас
Джеймс А. В. Шумэйкер
Томас Р. Боусси
Винсент Дж. Мёрфи
Original Assignee
Ренновиа, Инк.
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Publication date
Application filed by Ренновиа, Инк. filed Critical Ренновиа, Инк.
Publication of EA201491289A1 publication Critical patent/EA201491289A1/ru
Publication of EA025555B1 publication Critical patent/EA025555B1/ru

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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/15—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively
    • C07C29/151—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases
    • C07C29/153—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases characterised by the catalyst used
    • C07C29/156—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases characterised by the catalyst used containing iron group metals, platinum group metals or compounds thereof
    • C07C29/157—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases characterised by the catalyst used containing iron group metals, platinum group metals or compounds thereof containing platinum group metals or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C209/00—Preparation of compounds containing amino groups bound to a carbon skeleton
    • C07C209/04—Preparation of compounds containing amino groups bound to a carbon skeleton by substitution of functional groups by amino groups
    • C07C209/14—Preparation of compounds containing amino groups bound to a carbon skeleton by substitution of functional groups by amino groups by substitution of hydroxy groups or of etherified or esterified hydroxy groups
    • C07C209/16—Preparation of compounds containing amino groups bound to a carbon skeleton by substitution of functional groups by amino groups by substitution of hydroxy groups or of etherified or esterified hydroxy groups with formation of amino groups bound to acyclic carbon atoms or to carbon atoms of rings other than six-membered aromatic rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/132—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/132—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group
    • C07C29/136—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH
    • C07C29/14—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of a —CHO group
    • C07C29/141—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of a —CHO group with hydrogen or hydrogen-containing gases
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/17—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by hydrogenation of carbon-to-carbon double or triple bonds
    • C07C29/175—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by hydrogenation of carbon-to-carbon double or triple bonds with simultaneous reduction of an oxo group
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D307/00—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom
    • C07D307/02—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings
    • C07D307/34—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
    • C07D307/38—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with substituted hydrocarbon radicals attached to ring carbon atoms
    • C07D307/40—Radicals substituted by oxygen atoms
    • C07D307/46—Doubly bound oxygen atoms, or two oxygen atoms singly bound to the same carbon atom
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D307/00—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom
    • C07D307/02—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings
    • C07D307/34—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
    • C07D307/38—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with substituted hydrocarbon radicals attached to ring carbon atoms
    • C07D307/40—Radicals substituted by oxygen atoms
    • C07D307/46—Doubly bound oxygen atoms, or two oxygen atoms singly bound to the same carbon atom
    • C07D307/48—Furfural
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D307/00—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom
    • C07D307/02—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings
    • C07D307/34—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
    • C07D307/38—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with substituted hydrocarbon radicals attached to ring carbon atoms
    • C07D307/40—Radicals substituted by oxygen atoms
    • C07D307/46—Doubly bound oxygen atoms, or two oxygen atoms singly bound to the same carbon atom
    • C07D307/48—Furfural
    • C07D307/50—Preparation from natural products

Abstract

Предложены способы, относящиеся к превращению источников углеводов в гексаметилендиамин (ГМДА) и промежуточные соединения, подходящие для получения гексаметилендиамина и других промышленных химических веществ. ГМДА получают путем прямого восстановления фурфурольного субстрата в 1,6-гександиол в присутствии водорода и гетерогенного катализатора восстановления, содержащего Pt, или косвенным восстановлением фурфурольного субстрата в 1,6-гександиол, при этом 1,2,6-гексантриол получают путем восстановления фурфурольного субстрата в присутствии водорода и катализатора, содержащего Pt, и затем 1,2,6-гександиол преобразовывают в 1,6-гександиол гидрированием в присутствии катализатора, содержащего Pt, и затем с помощью известных методов, таких как аминирование 1,6-гександиола, приводят к получению ГМДА. Также описаны катализаторы, пригодные для прямого и косвенного получения 1,6-гександиола.
EA201491289A 2012-01-18 2013-01-11 Способ получения гексаметилендиамина из 5-гидроксиметилфурфурола EA025555B1 (ru)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US201261588093P 2012-01-18 2012-01-18
PCT/US2013/021315 WO2013109477A1 (en) 2012-01-18 2013-01-11 Process for production of hexamethylenediamine from 5 - hydroxymethylfurfural

Publications (2)

Publication Number Publication Date
EA201491289A1 true EA201491289A1 (ru) 2014-12-30
EA025555B1 EA025555B1 (ru) 2017-01-30

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US (7) US8853458B2 (ru)
EP (2) EP2804848B1 (ru)
JP (1) JP6253203B2 (ru)
KR (1) KR20140113706A (ru)
CN (2) CN104066710B (ru)
AR (1) AR089707A1 (ru)
AU (2) AU2013210005B2 (ru)
BR (1) BR112014017585B1 (ru)
CA (1) CA2860886A1 (ru)
EA (1) EA025555B1 (ru)
HK (1) HK1204318A1 (ru)
IN (1) IN2014DN06596A (ru)
MX (1) MX336933B (ru)
MY (1) MY165219A (ru)
SA (2) SA115360430B1 (ru)
SG (3) SG10201913670TA (ru)
WO (1) WO2013109477A1 (ru)
ZA (2) ZA201405258B (ru)

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US8853458B2 (en) 2014-10-07
CN104066710A (zh) 2014-09-24
AR089707A1 (es) 2014-09-10
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