GB876463A - Process for preparing hydroxymethyl furfural - Google Patents

Process for preparing hydroxymethyl furfural

Info

Publication number
GB876463A
GB876463A GB6201/60A GB620160A GB876463A GB 876463 A GB876463 A GB 876463A GB 6201/60 A GB6201/60 A GB 6201/60A GB 620160 A GB620160 A GB 620160A GB 876463 A GB876463 A GB 876463A
Authority
GB
United Kingdom
Prior art keywords
acid
mixture
dioxane
hexose
hydroxymethyl furfural
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB6201/60A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Atlas Powder Co
Original Assignee
Atlas Powder Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Atlas Powder Co filed Critical Atlas Powder Co
Publication of GB876463A publication Critical patent/GB876463A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D307/00—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom
    • C07D307/02—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings
    • C07D307/34—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
    • C07D307/38—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with substituted hydrocarbon radicals attached to ring carbon atoms
    • C07D307/40—Radicals substituted by oxygen atoms
    • C07D307/46—Doubly bound oxygen atoms, or two oxygen atoms singly bound to the same carbon atom

Abstract

Hydroxymethyl furfural is made by dehydrating a hexose, or a hexose polymer which yields simple hexoses on acid hydrolysis, at an elevated temperature in the presence of an acid catalyst and in a reaction medium comprising a mixture which contains from 5% to 70% by weight of water and correspondingly from 95% to 30% of an organic liquid having a normal boiling point no greater than about 280 DEG C. selected from acid-stable aliphatic ketones and acid-stable aliphatic and cycloaliphatic ethers. Specified examples are methyl isobutyl ketone, mesityl oxide, dichlorethyl ether, dioxane, glycol monoethyl ether, symmetrical dimethyl dioxane, tetrahydropyran and tetrahydro-2-methyl pyran. Suitable sugars for conversion are glucose, fructose, sorbose, mannose, sucrose and maltose. Molasses and starch conversion liquors containing dextrose and dextrose polymers are also suitable. The acid catalyst may be, for example, a mineral acid, toluene sulphonic acid, acetic acid, aluminium, zinc or chromium chloride, or a mixture of an acid and an acidic metal salt. Specification 817,139 is referred to.
GB6201/60A 1959-02-25 1960-02-22 Process for preparing hydroxymethyl furfural Expired GB876463A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US876463XA 1959-02-25 1959-02-25

Publications (1)

Publication Number Publication Date
GB876463A true GB876463A (en) 1961-09-06

Family

ID=22206405

Family Applications (1)

Application Number Title Priority Date Filing Date
GB6201/60A Expired GB876463A (en) 1959-02-25 1960-02-22 Process for preparing hydroxymethyl furfural

Country Status (1)

Country Link
GB (1) GB876463A (en)

Cited By (20)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2464260A1 (en) * 1979-09-05 1981-03-06 Roquette Freres PROCESS FOR PRODUCING 5-HYDROXYMETHYLFURFURAL
WO1996017837A1 (en) * 1994-12-07 1996-06-13 Agrichimie Method for making hydroxymethylfurfural from aldohexose
WO2007146636A1 (en) 2006-06-06 2007-12-21 Wisconsin Alumni Research Foundation Catalytic process for producing furan derivatives from carbohydrates in a biphasic reactor
DE102008009933A1 (en) 2008-02-18 2009-08-20 Friedrich-Schiller-Universität Jena Preparing 5-hydroxymethylfurfural, useful e.g. to manufacture pharmaceutical products such as fungicides, comprises thermally reacting carbohydrates in ionic liquid and discharging formed 5-hydroxymethylfurfural using extracting agent
WO2010144873A1 (en) 2009-06-13 2010-12-16 Rennovia, Inc. Production of adipic acid and derivatives from carbohydrate-containing materials
US7880049B2 (en) 2006-06-06 2011-02-01 Wisconsin Alumni Research Foundation Production of liquid alkanes in the jet fuel range (C8-C15) from biomass-derived carbohydrates
WO2011161141A1 (en) * 2010-06-22 2011-12-29 Shell Internationale Research Maatschappij B.V. Process for separating furfural from a liquid aqueous phase comprising furfural and one or more organic acids
US8314267B2 (en) 2009-06-26 2012-11-20 Uop Llc Carbohydrate route to para-xylene and terephthalic acid
US8324376B2 (en) 2008-06-17 2012-12-04 Wisconsin Alumni Research Foundation Chemical transformation of lignocellulosic biomass into fuels and chemicals
WO2013109477A1 (en) 2012-01-18 2013-07-25 Rennovia, Inc. Process for production of hexamethylenediamine from 5 - hydroxymethylfurfural
US8669397B2 (en) 2009-06-13 2014-03-11 Rennovia, Inc. Production of adipic acid and derivatives from carbohydrate-containing materials
US8669393B2 (en) 2010-03-05 2014-03-11 Rennovia, Inc. Adipic acid compositions
US8722878B2 (en) 2009-07-01 2014-05-13 Wisconsin Alumni Research Foundation Biomass hydrolysis
US8785683B2 (en) 2009-06-13 2014-07-22 Rennovia, Inc. Production of glutaric acid and derivatives from carbohydrate-containing materials
CN105658632A (en) * 2013-08-29 2016-06-08 韩国生产技术研究院 Method for preparing 5-hydroxymethyl-2-furfural using acid catalyst in presence of ethylene glycol-based compound solvent derived from biomass
US9586920B2 (en) 2014-12-02 2017-03-07 Rennovia Inc. Process for production of hexanetriol from 5-hydroxymethylfurfural
US9611241B2 (en) 2014-01-27 2017-04-04 Rennovia Inc. Conversion of fructose-containing feedstocks to HMF-containing product
US9770705B2 (en) 2010-06-11 2017-09-26 Rennovia Inc. Oxidation catalysts
US10208006B2 (en) 2016-01-13 2019-02-19 Stora Enso Oyj Processes for the preparation of 2,5-furandicarboxylic acid and intermediates and derivatives thereof
US11192872B2 (en) 2017-07-12 2021-12-07 Stora Enso Oyj Purified 2,5-furandicarboxylic acid pathway products

Cited By (46)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2464260A1 (en) * 1979-09-05 1981-03-06 Roquette Freres PROCESS FOR PRODUCING 5-HYDROXYMETHYLFURFURAL
WO1996017837A1 (en) * 1994-12-07 1996-06-13 Agrichimie Method for making hydroxymethylfurfural from aldohexose
FR2727967A1 (en) * 1994-12-07 1996-06-14 Agrichimie Sa PROCESS FOR THE MANUFACTURE OF HYDROXYMETHYLFURFURAL FROM ALDOHEXOSE
WO2007146636A1 (en) 2006-06-06 2007-12-21 Wisconsin Alumni Research Foundation Catalytic process for producing furan derivatives from carbohydrates in a biphasic reactor
US7572925B2 (en) 2006-06-06 2009-08-11 Wisconsin Alumni Research Foundation Catalytic process for producing furan derivatives in a biphasic reactor
US7880049B2 (en) 2006-06-06 2011-02-01 Wisconsin Alumni Research Foundation Production of liquid alkanes in the jet fuel range (C8-C15) from biomass-derived carbohydrates
DE102008009933A1 (en) 2008-02-18 2009-08-20 Friedrich-Schiller-Universität Jena Preparing 5-hydroxymethylfurfural, useful e.g. to manufacture pharmaceutical products such as fungicides, comprises thermally reacting carbohydrates in ionic liquid and discharging formed 5-hydroxymethylfurfural using extracting agent
US8324376B2 (en) 2008-06-17 2012-12-04 Wisconsin Alumni Research Foundation Chemical transformation of lignocellulosic biomass into fuels and chemicals
US8680264B2 (en) 2008-06-17 2014-03-25 Wisconsin Alumni Research Foundation Chemical transformation of lignocellulosic biomass into fuels and chemicals
US8501989B2 (en) 2009-06-13 2013-08-06 Rennovia, Inc. Production of adipic acid and derivatives from carbohydrate-containing materials
US8927768B2 (en) 2009-06-13 2015-01-06 Rennovia, Inc. Production of adipic acid and derivatives from carbohydrate-containing materials
US9174911B2 (en) 2009-06-13 2015-11-03 Rennovia Inc. Production of glutaric acid and derivatives from carbohydrate-containing materials
US9434709B2 (en) 2009-06-13 2016-09-06 Rennovia Inc. Production of adipic acid and derivatives from carbohydrate-containing materials
US8669397B2 (en) 2009-06-13 2014-03-11 Rennovia, Inc. Production of adipic acid and derivatives from carbohydrate-containing materials
US9156766B2 (en) 2009-06-13 2015-10-13 Rennovia Inc. Production of adipic acid and derivatives from carbohydrate-containing materials
WO2010144873A1 (en) 2009-06-13 2010-12-16 Rennovia, Inc. Production of adipic acid and derivatives from carbohydrate-containing materials
US8785683B2 (en) 2009-06-13 2014-07-22 Rennovia, Inc. Production of glutaric acid and derivatives from carbohydrate-containing materials
US8314267B2 (en) 2009-06-26 2012-11-20 Uop Llc Carbohydrate route to para-xylene and terephthalic acid
US8722878B2 (en) 2009-07-01 2014-05-13 Wisconsin Alumni Research Foundation Biomass hydrolysis
US8669393B2 (en) 2010-03-05 2014-03-11 Rennovia, Inc. Adipic acid compositions
US11596927B2 (en) 2010-06-11 2023-03-07 Archer-Daniels-Midland Company Oxidation catalysts
US10807074B2 (en) 2010-06-11 2020-10-20 Archer-Daniels-Midland Company Oxidation catalysts
US9808790B2 (en) 2010-06-11 2017-11-07 Rennovia Inc. Processes for the manufacturing of oxidation catalysts
US9770705B2 (en) 2010-06-11 2017-09-26 Rennovia Inc. Oxidation catalysts
WO2011161141A1 (en) * 2010-06-22 2011-12-29 Shell Internationale Research Maatschappij B.V. Process for separating furfural from a liquid aqueous phase comprising furfural and one or more organic acids
WO2013109477A1 (en) 2012-01-18 2013-07-25 Rennovia, Inc. Process for production of hexamethylenediamine from 5 - hydroxymethylfurfural
US9035109B2 (en) 2012-01-18 2015-05-19 Rennovia, Inc. Process for production of hexamethylenediamine from carbohydrate-containing materials and intermediates therefor
US8853458B2 (en) 2012-01-18 2014-10-07 Rennovia, Inc. Process for production of hexamethylenediamine from carbohydrate-containing materials and intermediates therefor
EP3466919A1 (en) 2012-01-18 2019-04-10 Archer-Daniels-Midland Company Process for production of 1,6-hexanediol from 1,2-6-hexanetriol
US9518005B2 (en) 2012-01-18 2016-12-13 Rennovia Inc. Process for production of hexamethylenediamine from carbohydrate-containing materials and intermediates therefor
US9783473B2 (en) 2012-01-18 2017-10-10 Rennovia Inc. Process for production of hexamethylenediamine from carbohydrate-containing materials and intermediates therefor
CN105658632A (en) * 2013-08-29 2016-06-08 韩国生产技术研究院 Method for preparing 5-hydroxymethyl-2-furfural using acid catalyst in presence of ethylene glycol-based compound solvent derived from biomass
US9802910B2 (en) * 2013-08-29 2017-10-31 Korea Institute Of Industrial Technology Method for preparing 5-hydroxymethyl-2-furfural using acid catalyst in presence of ethylene glycol-based compound solvent derived from biomass
CN105658632B (en) * 2013-08-29 2018-07-06 韩国生产技术研究院 The method for preparing HMF 5 hydroxymethyl 2 furaldehyde using acid catalyst in the presence of the compound solvent based on ethylene glycol from biomass
US20160207896A1 (en) * 2013-08-29 2016-07-21 Korea Institute Of Industrial Technology Method for preparing 5-hydroxymethyl-2-furfural using acid catalyst in presence of ethylene glycol-based compound solvent derived from biomass
US10017486B2 (en) 2014-01-27 2018-07-10 Archer-Daniels-Midland Company Conversion of fructose-containing feedstocks to HMF-containing product
US9611241B2 (en) 2014-01-27 2017-04-04 Rennovia Inc. Conversion of fructose-containing feedstocks to HMF-containing product
US10081612B2 (en) 2014-12-02 2018-09-25 Archer-Daniels-Midland Company Process for production of hexanetriol from 5-hydroxymethylfurfural
US9586920B2 (en) 2014-12-02 2017-03-07 Rennovia Inc. Process for production of hexanetriol from 5-hydroxymethylfurfural
US10208006B2 (en) 2016-01-13 2019-02-19 Stora Enso Oyj Processes for the preparation of 2,5-furandicarboxylic acid and intermediates and derivatives thereof
US10654819B2 (en) 2016-01-13 2020-05-19 Stora Enso Oyj Processes for the preparation of 2,5-furandicarboxylic acid and intermediates and derivatives thereof
US10851074B2 (en) 2016-01-13 2020-12-01 Stora Enso Oyj Processes for the preparation of 2,5-furandicarboxylic acid and intermediates and derivatives thereof
US10442780B2 (en) 2016-01-13 2019-10-15 Stora Enso Oyj Processes for the preparation of 2,5-furandicarboxylic acid and intermediates and derivatives thereof
US11613523B2 (en) 2016-01-13 2023-03-28 Stora Enso Oyj Processes for the preparation of 2,5-furandicarboxylic acid and intermediates and derivatives thereof
US11891370B2 (en) 2016-01-13 2024-02-06 Stora Enso Ojy Processes for the preparation of 2,5-furandicarboxylic acid and intermediates and derivatives thereof
US11192872B2 (en) 2017-07-12 2021-12-07 Stora Enso Oyj Purified 2,5-furandicarboxylic acid pathway products

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