MX2014003469A - Catalizador para la oxidacion de diesel, con estructura estratificada que contiene una composicion de cerio como material de soporte de paladio para mejorar la conversion de gas hc y co. - Google Patents

Catalizador para la oxidacion de diesel, con estructura estratificada que contiene una composicion de cerio como material de soporte de paladio para mejorar la conversion de gas hc y co.

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Publication number
MX2014003469A
MX2014003469A MX2014003469A MX2014003469A MX2014003469A MX 2014003469 A MX2014003469 A MX 2014003469A MX 2014003469 A MX2014003469 A MX 2014003469A MX 2014003469 A MX2014003469 A MX 2014003469A MX 2014003469 A MX2014003469 A MX 2014003469A
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MX
Mexico
Prior art keywords
support material
diesel oxidation
layer
oxidation catalyst
enhanced
Prior art date
Application number
MX2014003469A
Other languages
English (en)
Other versions
MX368239B (es
Inventor
Gerd Grubert
Torsten Neubauer
Alfred Punke
Marcus Hilgendorff
Torsten Müller-Stach
Olga Gerlach
Xinyi Wei
Jeffrey Hoke
Shiang Sung
Stanley Roth
Original Assignee
Basf Se
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Publication date
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Application filed by Basf Se filed Critical Basf Se
Publication of MX2014003469A publication Critical patent/MX2014003469A/es
Publication of MX368239B publication Critical patent/MX368239B/es

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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/42Platinum
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/92Chemical or biological purification of waste gases of engine exhaust gases
    • B01D53/94Chemical or biological purification of waste gases of engine exhaust gases by catalytic processes
    • B01D53/944Simultaneously removing carbon monoxide, hydrocarbons or carbon making use of oxidation catalysts
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/02Boron or aluminium; Oxides or hydroxides thereof
    • B01J21/04Alumina
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/44Palladium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/56Platinum group metals
    • B01J23/63Platinum group metals with rare earths or actinides
    • BPERFORMING OPERATIONS; TRANSPORTING
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    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00Catalysts comprising molecular sieves
    • B01J29/04Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/064Crystalline aluminosilicate zeolites; Isomorphous compounds thereof containing iron group metals, noble metals or copper
    • B01J29/068Noble metals
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    • B01J29/00Catalysts comprising molecular sieves
    • B01J29/04Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B01J29/7007Zeolite Beta
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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    • B01J29/00Catalysts comprising molecular sieves
    • B01J29/04Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B01J29/7049Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65 containing rare earth elements, titanium, zirconium, hafnium, zinc, cadmium, mercury, gallium, indium, thallium, tin or lead
    • B01J29/7057Zeolite Beta
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00Catalysts comprising molecular sieves
    • B01J29/04Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B01J29/72Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65 containing iron group metals, noble metals or copper
    • B01J29/74Noble metals
    • B01J29/7415Zeolite Beta
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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    • B01J35/40Catalysts, in general, characterised by their form or physical properties characterised by dimensions, e.g. grain size
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    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • B01J35/50Catalysts, in general, characterised by their form or physical properties characterised by their shape or configuration
    • B01J35/56Foraminous structures having flow-through passages or channels, e.g. grids or three-dimensional monoliths
    • BPERFORMING OPERATIONS; TRANSPORTING
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    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • B01J37/0027Powdering
    • B01J37/0036Grinding
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    • B01J37/02Impregnation, coating or precipitation
    • B01J37/0201Impregnation
    • BPERFORMING OPERATIONS; TRANSPORTING
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    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02Impregnation, coating or precipitation
    • B01J37/024Multiple impregnation or coating
    • B01J37/0244Coatings comprising several layers
    • BPERFORMING OPERATIONS; TRANSPORTING
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    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
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    • B01J37/024Multiple impregnation or coating
    • B01J37/0246Coatings comprising a zeolite
    • BPERFORMING OPERATIONS; TRANSPORTING
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    • B01D2255/1023Palladium
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    • B01D2255/9025Three layers
    • BPERFORMING OPERATIONS; TRANSPORTING
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    • B01D2255/912HC-storage component incorporated in the catalyst
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2258/00Sources of waste gases
    • B01D2258/01Engine exhaust gases
    • B01D2258/012Diesel engines and lean burn gasoline engines
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/92Chemical or biological purification of waste gases of engine exhaust gases
    • B01D53/94Chemical or biological purification of waste gases of engine exhaust gases by catalytic processes
    • B01D53/9459Removing one or more of nitrogen oxides, carbon monoxide, or hydrocarbons by multiple successive catalytic functions; systems with more than one different function, e.g. zone coated catalysts
    • BPERFORMING OPERATIONS; TRANSPORTING
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    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30After treatment, characterised by the means used
    • B01J2229/42Addition of matrix or binder particles

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Biomedical Technology (AREA)
  • Environmental & Geological Engineering (AREA)
  • Analytical Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Combustion & Propulsion (AREA)
  • Catalysts (AREA)
  • Exhaust Gas After Treatment (AREA)

Abstract

La presente invención se refiere a un catalizador para la oxidación de diesel (DOC) estratificado, que consiste en: a) un sustrato portador; b) un material catalítico para la oxidación de diesel que consiste en: b1) una primera capa colocada sobre el sustrato portador, la primera capa consistente en paladio impregnado sobre un material de soporte que contiene cerio en una cantidad de al menos 45% en peso, con base en el peso total del material de soporte, y como una opción contiene paladio; b2) una segunda capa colocada sobre la primer capa, la segunda capa consiste en paladio y platino cada uno impregnado sobre un material de soporte que consiste en un óxido metálico; en donde la relación en peso de platino a paladio de la primera capa es menor que la relación en peso de platino a paladio de la segunda capa.
MX2014003469A 2011-09-23 2012-09-21 Catalizador para la oxidación de diésel, con estructura estratificada que contiene una composición de cerio como material de soporte de paladio para mejorar la conversión de gas hc y co. MX368239B (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP11182585 2011-09-23
PCT/IB2012/055030 WO2013042080A1 (en) 2011-09-23 2012-09-21 Diesel oxidation catalyst with layered structure containing ceria composition as palladium support material for enhanced hc and co gas conversion

Publications (2)

Publication Number Publication Date
MX2014003469A true MX2014003469A (es) 2014-08-26
MX368239B MX368239B (es) 2019-09-25

Family

ID=47913964

Family Applications (1)

Application Number Title Priority Date Filing Date
MX2014003469A MX368239B (es) 2011-09-23 2012-09-21 Catalizador para la oxidación de diésel, con estructura estratificada que contiene una composición de cerio como material de soporte de paladio para mejorar la conversión de gas hc y co.

Country Status (10)

Country Link
EP (1) EP2758168B2 (es)
JP (1) JP6236389B2 (es)
KR (1) KR102064620B1 (es)
CN (1) CN103945936B (es)
BR (1) BR112014006900B8 (es)
CA (1) CA2849700C (es)
IN (1) IN2014CN02204A (es)
MX (1) MX368239B (es)
PL (1) PL2758168T3 (es)
WO (1) WO2013042080A1 (es)

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CN108569861A (zh) * 2018-07-05 2018-09-25 安徽思凯瑞环保科技有限公司 抗潮解的粗钛粉及其制备方法
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US20220212162A1 (en) * 2019-05-09 2022-07-07 Basf Corporation LOW TEMPERATURE NOx ADSORBER WITH ENHANCED HYDROTHERMAL STABILITY
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JP2014527909A (ja) 2014-10-23
JP6236389B2 (ja) 2017-11-22
CN103945936A (zh) 2014-07-23
KR20140073533A (ko) 2014-06-16
CA2849700C (en) 2020-02-18
EP2758168A4 (en) 2015-12-02
KR102064620B1 (ko) 2020-01-09
EP2758168B2 (en) 2022-11-16
EP2758168B1 (en) 2019-07-31
CN103945936B (zh) 2016-11-16
BR112014006900B1 (pt) 2019-08-20
MX368239B (es) 2019-09-25
EP2758168A1 (en) 2014-07-30
IN2014CN02204A (es) 2015-06-12
WO2013042080A1 (en) 2013-03-28
BR112014006900A2 (pt) 2017-04-11
CA2849700A1 (en) 2013-03-28
BR112014006900B8 (pt) 2019-10-15

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