MX2014002011A - Production of polymers by means of controlled radical polymerisation. - Google Patents

Production of polymers by means of controlled radical polymerisation.

Info

Publication number
MX2014002011A
MX2014002011A MX2014002011A MX2014002011A MX2014002011A MX 2014002011 A MX2014002011 A MX 2014002011A MX 2014002011 A MX2014002011 A MX 2014002011A MX 2014002011 A MX2014002011 A MX 2014002011A MX 2014002011 A MX2014002011 A MX 2014002011A
Authority
MX
Mexico
Prior art keywords
addition
several
alkyl
general formula
monomers
Prior art date
Application number
MX2014002011A
Other languages
Spanish (es)
Inventor
Pascal Hesse
Sven Fleischmann
Florian Becker
Klaus Mühlbach
Klaus-Dieter Hungenberg
Markus Brym
Matthias Kleiner
Original Assignee
Basf Se
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Basf Se filed Critical Basf Se
Publication of MX2014002011A publication Critical patent/MX2014002011A/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/01—Processes of polymerisation characterised by special features of the polymerisation apparatus used
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/38—Polymerisation using regulators, e.g. chain terminating agents, e.g. telomerisation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F293/00—Macromolecular compounds obtained by polymerisation on to a macromolecule having groups capable of inducing the formation of new polymer chains bound exclusively at one or both ends of the starting macromolecule
    • C08F293/005—Macromolecular compounds obtained by polymerisation on to a macromolecule having groups capable of inducing the formation of new polymer chains bound exclusively at one or both ends of the starting macromolecule using free radical "living" or "controlled" polymerisation, e.g. using a complexing agent
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/40—Redox systems
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/12—Esters of monohydric alcohols or phenols
    • C08F220/14—Methyl esters, e.g. methyl (meth)acrylate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/12—Esters of monohydric alcohols or phenols
    • C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
    • C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
    • C08F220/1804—C4-(meth)acrylate, e.g. butyl (meth)acrylate, isobutyl (meth)acrylate or tert-butyl (meth)acrylate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2438/00—Living radical polymerisation
    • C08F2438/01—Atom Transfer Radical Polymerization [ATRP] or reverse ATRP
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2438/00—Living radical polymerisation
    • C08F2438/02—Stable Free Radical Polymerisation [SFRP]; Nitroxide Mediated Polymerisation [NMP] for, e.g. using 2,2,6,6-tetramethylpiperidine-1-oxyl [TEMPO]

Abstract

Method for producing polymers by means of controlled radical polymerisation, wherein the polymerisation of one or several radically polymerisable monomers of general formula (I), where R1, R2, R3 are H, C1-C4 alkyl, R4 is C(=O)OR5, C(=O)NHR15, C(=O)NR5R6, OC(=O)CH3, C(=O)OH, CN, aryl, hetaryl, C(=O)OR5OH, C(=O)OR5Si(OR5)3, halogen, NHC(O)H, P(=O)(OR7)2, R5 is C1-C20 alkyl, R15 is C1-C20-alkyl, R6 is C1-C20 alkyl, and R7 is H, C1-C20 alkyl, occurs in the presence of a. one or several catalysts containing Cu in the form of Cu(0), Cu(l), Cu (II) or mixtures thereof, b. one or several initiators selected from the group of organic halogenides or pseudohalogenides, c. one or several ligands, d. optionally one or several solvents, and e. optionally one or several inorganic halogenide salts, said method consisting of the following steps i) addition of the catalyst a., ii) optional addition of monomers of general formula (I), iii) optional addition of solvent d., iv) addition of ligand c., v) addition of initiator b., vi) addition of monomers of general formula (I), and vii) optional addition of inorganic halogenide salts e., on the proviso that the addition of at least some of the monomers of general formula (I) occurs immediately before or shortly after the last of the steps i), iv) and v).
MX2014002011A 2011-08-30 2012-08-30 Production of polymers by means of controlled radical polymerisation. MX2014002011A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP11179291 2011-08-30
PCT/EP2012/066838 WO2013030261A1 (en) 2011-08-30 2012-08-30 Production of polymers by means of controlled radical polymerisation

Publications (1)

Publication Number Publication Date
MX2014002011A true MX2014002011A (en) 2014-03-27

Family

ID=46796583

Family Applications (1)

Application Number Title Priority Date Filing Date
MX2014002011A MX2014002011A (en) 2011-08-30 2012-08-30 Production of polymers by means of controlled radical polymerisation.

Country Status (11)

Country Link
EP (1) EP2751143A1 (en)
JP (1) JP2014525486A (en)
KR (1) KR20140069032A (en)
CN (1) CN103764688A (en)
BR (1) BR112014003922A2 (en)
IN (1) IN2014CN02321A (en)
MX (1) MX2014002011A (en)
RU (1) RU2014111849A (en)
SG (1) SG2014014492A (en)
WO (1) WO2013030261A1 (en)
ZA (1) ZA201402272B (en)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8883941B2 (en) * 2013-03-18 2014-11-11 Henkel Corporation Methods and apparatus for controlled single electron transfer living radical polymerization
EP2899215A1 (en) 2014-01-24 2015-07-29 Basf Se Method for the processing of a mixture (M), comprising an organic component (A), that comprises at least one halogen carbon bond, and a transition metal component (B)
WO2016005214A1 (en) * 2014-07-09 2016-01-14 Basf Se Reactive monomers as comonomers for the production of polymers

Family Cites Families (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5763548A (en) * 1995-03-31 1998-06-09 Carnegie-Mellon University (Co)polymers and a novel polymerization process based on atom (or group) transfer radical polymerization
US5807937A (en) 1995-11-15 1998-09-15 Carnegie Mellon University Processes based on atom (or group) transfer radical polymerization and novel (co) polymers having useful structures and properties
FR2757865B1 (en) 1996-12-26 1999-04-02 Atochem Elf Sa METHOD FOR CONTROLLED RADICAL POLYMERIZATION OR COPOLYMERIZATION OF (METH) ACRYLIC, VINYLIC, VINYLIDENIC AND DIENE MONOMERS AND (CO) POLYMERS OBTAINED
TW593347B (en) 1997-03-11 2004-06-21 Univ Carnegie Mellon Improvements in atom or group transfer radical polymerization
AU3919500A (en) 1999-03-23 2000-10-09 Carnegie Wave Energy Limited Catalytic processes for the controlled polymerization of free radically (co)polymerizable monomers and functional polymeric systems prepared thereby
US6639029B1 (en) 2000-11-13 2003-10-28 Rohmax Additives Gmbh Process for continuous synthesis of polymer compositions as well as use of same
JP4237483B2 (en) * 2002-12-27 2009-03-11 株式会社カネカ Method for producing vinyl polymer
JP5597325B2 (en) 2006-08-04 2014-10-01 ザ トラスティーズ オブ ザ ユニバーシティ オブ ペンシルバニア Living radical polymerization of activated and deactivated monomers containing electron withdrawing side groups.
CN101959912A (en) * 2008-02-29 2011-01-26 株式会社钟化 Curable composition
JP5642671B2 (en) 2008-06-18 2014-12-17 ヘンケル コーポレイションＨｅｎｋｅｌ Ｃｏｒｐｏｒａｔｉｏｎ Apparatus and method for controlled radical polymerization
JP2010241907A (en) * 2009-04-02 2010-10-28 Kaneka Corp Method for producing (meth)acrylic block copolymer

Also Published As

Publication number Publication date
JP2014525486A (en) 2014-09-29
CN103764688A (en) 2014-04-30
EP2751143A1 (en) 2014-07-09
ZA201402272B (en) 2015-12-23
KR20140069032A (en) 2014-06-09
WO2013030261A1 (en) 2013-03-07
RU2014111849A (en) 2015-10-10
SG2014014492A (en) 2014-05-29
IN2014CN02321A (en) 2015-06-19
BR112014003922A2 (en) 2017-03-28

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