KR970701231A - 열가소성 수지 발포체 및 이의 제조 방법(Thermoplastic Resin Foam and Method of Production Thereof) - Google Patents

열가소성 수지 발포체 및 이의 제조 방법(Thermoplastic Resin Foam and Method of Production Thereof)

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Publication number
KR970701231A
KR970701231A KR1019960704520A KR19960704520A KR970701231A KR 970701231 A KR970701231 A KR 970701231A KR 1019960704520 A KR1019960704520 A KR 1019960704520A KR 19960704520 A KR19960704520 A KR 19960704520A KR 970701231 A KR970701231 A KR 970701231A
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KR
South Korea
Prior art keywords
foam
thermoplastic resin
expansion
thermoplastic
pellets
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KR1019960704520A
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English (en)
Inventor
도모유끼 고바야시
겐지 미야자끼
미치아끼 사사야마
Original Assignee
니시자와 스스므
세끼스이 가가쿠 고교 가부시끼가이샤
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Application filed by 니시자와 스스므, 세끼스이 가가쿠 고교 가부시끼가이샤 filed Critical 니시자와 스스므
Publication of KR970701231A publication Critical patent/KR970701231A/ko

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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B27/065—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of foam
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/16—Making expandable particles
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C44/00—Shaping by internal pressure generated in the material, e.g. swelling or foaming ; Producing porous or cellular expanded plastics articles
    • B29C44/02—Shaping by internal pressure generated in the material, e.g. swelling or foaming ; Producing porous or cellular expanded plastics articles for articles of definite length, i.e. discrete articles
    • B29C44/04—Shaping by internal pressure generated in the material, e.g. swelling or foaming ; Producing porous or cellular expanded plastics articles for articles of definite length, i.e. discrete articles consisting of at least two parts of chemically or physically different materials, e.g. having different densities
    • B29C44/06—Making multilayered articles
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C44/00—Shaping by internal pressure generated in the material, e.g. swelling or foaming ; Producing porous or cellular expanded plastics articles
    • B29C44/20—Shaping by internal pressure generated in the material, e.g. swelling or foaming ; Producing porous or cellular expanded plastics articles for articles of indefinite length
    • B29C44/22—Shaping by internal pressure generated in the material, e.g. swelling or foaming ; Producing porous or cellular expanded plastics articles for articles of indefinite length consisting of at least two parts of chemically or physically different materials, e.g. having different densities
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/18—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by features of a layer of foamed material
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/18—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by features of a layer of foamed material
    • B32B5/20—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by features of a layer of foamed material foamed in situ
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2105/00—Condition, form or state of moulded material or of the material to be shaped
    • B29K2105/04—Condition, form or state of moulded material or of the material to be shaped cellular or porous
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B38/00—Ancillary operations in connection with laminating processes
    • B32B2038/0052—Other operations not otherwise provided for
    • B32B2038/0076—Curing, vulcanising, cross-linking
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2305/00—Condition, form or state of the layers or laminate
    • B32B2305/72—Cured, e.g. vulcanised, cross-linked
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/70—Other properties
    • B32B2307/718—Weight, e.g. weight per square meter
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/249921—Web or sheet containing structurally defined element or component
    • Y10T428/249953—Composite having voids in a component [e.g., porous, cellular, etc.]

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
  • Laminated Bodies (AREA)

Abstract

본 발명은 경량이며, 굽휨 강도에서 우수하며, 압축 강도와 압축 영구적인 스트래인 사이에서 조화가 잘된 발포 성형체에 관한 것이다. 본 발명의 발포체는 열가소성 수지 저-팽창-발포 박층으로 전체 외부면이 둘러싸인 열가소성 수지 고팽창 발포체가 상술한 저-팽창-발포체 박층을 통해서 서로 열로 융합되는 발포체이다.

Description

열가소성 수지 발포체 및 이의 제조 방법(Thermoplastic Resin Foam and Method of Production Thereof)
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (13)

  1. 열가소성 수지로 이루어진 고팽창 발포체; 열가소성 수지로 이루어진 상기 고팽창 발포체의 외부면을 덮고 있는 열가소성 수지로 이루어진 저-팽창-발포 박층을 포함하고, 복수개의 상기 고팽창 발포체가 저-팽창-발포 박층을 통해 서로 열로 융합됨을 특징으로 하는 발포체.
  2. 제1항에 있어서, 전체 외부면이 상기 저-팽창-발포 박층으로 둘러싸인 열가소성 수지로 이루어진 고팽창 발포체는 두께 방향을 따라 서로 겹치지 않게 단층으로 배열되며, 횡방향을 따라 저-팽창-발포 박층을 통해서 서로 열로 융합됨을 특징으로 발포체.
  3. 제1항 또는 제2항에 있어서, 저-팽창-발포 박층의 팽창비가 1.1∼10배이며, 두께는 30∼500㎛임을 특징으로 하는 발포체.
  4. 제1항 또는 제2항에 있어서, 고팽창 발포의 팽창비가 20∼50배임을 특징으로 하는 발포체.
  5. 제1항 내지 제4항 중에 어느 한 항에 있어서, 적어도 한면 상에 축적되며, 강화 섬유 및 열가소성 수지로 이루어진 합성 시트를 더 포함함을 특징으로 하는 발포체.
  6. 제1항 또는 제2항에 있어서, 열가소성 수지가 바다의 섬과 같은 구조로 형성된 부분들인, 높은 교차 결합밀도를 갖은 교차 결합된 부분을 많이 지니며, 낮은 교차결합 밀도를 갖은 교차 결합된 부분을 적게 지님을 특징으로 하는 발포체.
  7. 발포체를 함유하는 패창 가능한 열가소성 수지 펠릿 또는 환형 물질을 뿌리는 단계, 미 팽창 가능한 열가소성 수지 펠릿 또는 환형 물질을 팽창 가능한 열가소성 수지에 함유된 발포체의 발포 온도를 초과하는 온도로 가열하여 팽창시키는 단계를 포함함을 특징으로 하는 발포체의 제조방법.
  8. 제7항에 있어서, 팽창 가능한 열가소성 수지 펠릿 또는 환형 물질이 두께 방향을 따라 서로 겹치지 않게 단일층으로 뿌려짐을 특징으로 하는 제조방법.
  9. 제7항 또는 제8항에 있어서, 팽창 가능한 열가소성 수지 펠릿 또는 환형 물질이 뿌려져서, 팽창 가능한 열가소성 수지 펠릿 또는 환형 물질의 하향 투영 면적이 팽창 가능한 열가소성 수지 펠릿 또는 환형 물질이 설포된 영역의 외부 가장자리로 둘러싸인 부분의 하향 투영 면적의 10∼75%를 차지함을 특징으로 하는 제조방법.
  10. 제7항 또는 제8항에 있어서, 제8항에 있어서, 팽창 가능한 열가소성 수지 펠릿 또는 환형 물질의 융해 점도가 190℃에서 5000∼20000포이즈(poise)임을 특징으로 하는 제조방법.
  11. 제7항 또는 제8항에 있어서, 팽창 가능한 열가소성 수지에서 수지 겔비율 10∼30중량%임을 특징으로 하는 제조방법.
  12. 제7항 또는 제8항에 있어서, 상기 팽창 열가소성 수지가 서로 조회될 수 없는 두 가지 형태의 비교차 결합된 열가소성 수지를 함유하며, 3 내지 7대 7 내지 3의 중량비의 범위로 두 형태의 비교차 결합된 열가소성 수지를 혼합함으로써 제조되는; 열가소성 수지 합성물의 100중량부 상기 비교차 결합된 열가소성 수지중의 하나와 동일한 형태의 열가소성 수지를 사용한 실란 변성 열가소성 수지 1∼50중량부; 실란 교차 결합 촉매; 및 발포제를 함유함을 특징으로 하는 제조방법.
  13. 팽창 가능한 열가소성 수지 펠릿 또는 환형 물질을 강화 섬유 및 열가소성 수지로 이루어진 합성 시트상에 뿌리는 단계; 뿌려진 팽창 가능한 열가소성 수지 펠릿 또는 환형 물질 상에 강화 섬유 및 열가소성 수지로 이루어진 제2의 합성 시트를 적층하여 적층판을 얻는 단계; 및 발포체의 발포 온도를 초과하는 온도로 상기 적층판을 가열하여, 상기 적층판이 융합되도록 팽창 가능한 열가소성 수지 펠릿 또는 환형 물질을 팽창시키는 단계를 포함함을 특징으로 하는 발포제의 제조방법.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019960704520A 1994-12-14 1994-12-14 열가소성 수지 발포체 및 이의 제조 방법(Thermoplastic Resin Foam and Method of Production Thereof) KR970701231A (ko)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
PCT/JP1994/002088 WO1996018671A1 (fr) 1994-12-14 1994-12-14 Mousse de resine thermoplastique et son procede de production

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KR970701231A true KR970701231A (ko) 1997-03-17

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Country Status (8)

Country Link
US (1) US5939180A (ko)
EP (1) EP0745641B1 (ko)
JP (1) JP3844499B2 (ko)
KR (1) KR970701231A (ko)
AT (1) ATE260950T1 (ko)
AU (1) AU690945B2 (ko)
DE (1) DE69433595T2 (ko)
WO (1) WO1996018671A1 (ko)

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JP2993997B2 (ja) * 1990-03-28 1999-12-27 旭硝子株式会社 ガスケット付き窓ガラスの製造方法
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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100407502B1 (ko) * 2001-09-13 2003-11-28 (주)해은켐텍 에멀전형 점착제층을 포함하는 가열박리형 발포시트

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DE69433595T2 (de) 2005-02-10
ATE260950T1 (de) 2004-03-15
JP3844499B2 (ja) 2006-11-15
AU690945B2 (en) 1998-05-07
DE69433595D1 (de) 2004-04-08
EP0745641A4 (en) 1998-11-04
AU1200195A (en) 1996-07-03
US5939180A (en) 1999-08-17
EP0745641B1 (en) 2004-03-03
EP0745641A1 (en) 1996-12-04

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