KR970074798A - 폴리(비닐 아세탈) 및 폴리(비닐 케탈)의 제조방법 - Google Patents
폴리(비닐 아세탈) 및 폴리(비닐 케탈)의 제조방법 Download PDFInfo
- Publication number
- KR970074798A KR970074798A KR1019970016947A KR19970016947A KR970074798A KR 970074798 A KR970074798 A KR 970074798A KR 1019970016947 A KR1019970016947 A KR 1019970016947A KR 19970016947 A KR19970016947 A KR 19970016947A KR 970074798 A KR970074798 A KR 970074798A
- Authority
- KR
- South Korea
- Prior art keywords
- poly
- vinyl
- support
- acid
- reaction
- Prior art date
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F8/00—Chemical modification by after-treatment
- C08F8/28—Condensation with aldehydes or ketones
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/06—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing polymers
- B01J31/08—Ion-exchange resins
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/06—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing polymers
- B01J31/08—Ion-exchange resins
- B01J31/10—Ion-exchange resins sulfonated
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F116/00—Homopolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal or ketal radical
- C08F116/02—Homopolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal or ketal radical by an alcohol radical
- C08F116/04—Acyclic compounds
- C08F116/06—Polyvinyl alcohol ; Vinyl alcohol
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F8/00—Chemical modification by after-treatment
- C08F8/48—Isomerisation; Cyclisation
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/582—Recycling of unreacted starting or intermediate materials
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- General Chemical & Material Sciences (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
폴리(비닐 알콜)을 반응 매질에서 불용성인 시트형 지지체에 화학적으로 결합된 산 그룹을 포함하는 촉매의 존재하에 알데히드 또는 케톤과 반응시켜 폴리(비닐 아세탈) 및 폴리(비틸 케탈)을 제조하는 방법이다.
Description
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
제1도는 발명의 폴리(비닐 아세날) 및 폴리(비닐 케탈)을 제조하기 위한 반응 흐름도를 도시한 것이다.
Claims (10)
- 폴리(비닐 알콜)을 반응 매질에서 불용성인 시트형 지지체에 화학적으로 결합된 산 그룹을 포함하는 촉매의 존재하에 알데히드 또는 케톤과 반응시켜 폴리(비닐 아세탈) 및 폴리(비틸 케탈)을 제조하는 방법.
- 제1항에 있어서, 사용하는 시트형 지지체가 중합체필름인 방법.
- 제1항에 있어서, 산 그룹이 결합된, 사용하는 지지체가 양이온 교환 막인 방법.
- 제1항에 있어서, 사용하는 지지체가 제올라이트, 벤토나이트 및 유리로 이루어진 그룹으로부터 선택된 무기재료의 시트인 방법.
- 제1항에 있어서, 설폰산, 포스포산 및 카복실산으로 이루어진 그룹으로부터 선택된 산 그룹을 포함하는 지지체가 사용되는 방법.
- 제1항에 있어서, 사용하는 알데히드가 n-부티르알데히드인 방법.
- 제1항에 있어서, 가수분해도가 60 내지 100mol%이고, 중합도가 150 내지 5000인 폴리(비닐 알콜)이 사용되는 방법.
- 제1항에 있어서, 폴리(비닐 아세탈) 또는 폴리(비닐 케탈)이 연속적으로 제조되는 방법.
- 제1항에 있어서, 폴리(비닐 알콜) 및 알데히드 또는 케톤이 예비 반응기로 연속 계량 부가되고, 산 그룹을 포함하는 지지체의 존재하에 일부 반응되며, 주 반응기로 이동되고, 산 그룹을 포함하는 지지체의 존재하에 계속 반응되는 방법.
- 제9항에 있어서, 예비 반응기에서의 반응이 1 내지 70℃의 온도와 10 내지 120분의 평균체류시간에 수행되고 주 반응기에서의 반응이 1 내지80℃의 온도와 60 내지 300분의 평균체류시간에서 수행되는 방법.※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE19617893.2 | 1996-05-04 | ||
DE19617893A DE19617893C1 (de) | 1996-05-04 | 1996-05-04 | Verfahren zur Herstellung von Polyvinylacetalen und -ketalen |
Publications (2)
Publication Number | Publication Date |
---|---|
KR970074798A true KR970074798A (ko) | 1997-12-10 |
KR100479252B1 KR100479252B1 (ko) | 2005-07-11 |
Family
ID=7793307
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
KR1019970016947A KR100479252B1 (ko) | 1996-05-04 | 1997-05-02 | 폴리(비닐아세탈)및폴리(비닐케탈)의제조방법 |
Country Status (13)
Country | Link |
---|---|
US (1) | US5866654A (ko) |
EP (1) | EP0805167B1 (ko) |
JP (1) | JPH1036446A (ko) |
KR (1) | KR100479252B1 (ko) |
CN (1) | CN1074770C (ko) |
AT (1) | ATE227745T1 (ko) |
DE (2) | DE19617893C1 (ko) |
DK (1) | DK0805167T3 (ko) |
ES (1) | ES2187694T3 (ko) |
PT (1) | PT805167E (ko) |
RU (1) | RU2205839C2 (ko) |
SG (1) | SG73451A1 (ko) |
TW (1) | TW335404B (ko) |
Families Citing this family (15)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6528025B1 (en) * | 2000-06-26 | 2003-03-04 | Roche Vitamins Inc. | Process of manufacturing equipment for preparing acetals and ketals |
AT410211B (de) * | 2000-12-15 | 2003-03-25 | Agrolinz Melamin Gmbh | Halbzeuge und formstoffe aus aminoplasten |
CA2436995A1 (en) * | 2000-12-15 | 2002-06-20 | Agrolinz Melamin Gmbh | Polymer-modified inorganic particles |
EP1384732B1 (en) * | 2001-03-28 | 2016-11-09 | Sekisui Chemical Co., Ltd. | Polyvinyl acetal resin for coating and ink, and coating and ink compositions |
CN100351287C (zh) * | 2001-11-19 | 2007-11-28 | Ami-阿格罗林茨三聚氰胺国际有限公司 | 含三嗪链段聚合物的产品、其制备方法及用途 |
CA2475255C (en) | 2002-02-07 | 2011-04-19 | Denki Kagaku Kogyo Kabushiki Kaisha | Polyvinylacetal resin and process for its production |
DE10242417A1 (de) * | 2002-09-12 | 2004-03-25 | Wacker Polymer Systems Gmbh & Co. Kg | Verfahren zur Herstellung von Polyvinylacetalen |
US7674854B2 (en) * | 2004-08-04 | 2010-03-09 | Sekisui Chemical Co., Ltd. | Process for producing polyvinyl acetal resin, polyvinyl butyral resin, and process for producing esterified polyvinyl alcohol resin |
US9012570B2 (en) * | 2009-04-18 | 2015-04-21 | Eastman Chemical Company | Continuous production of poly(vinyl butyral) |
US7960503B2 (en) | 2009-05-26 | 2011-06-14 | Solutia, Inc. | Continuous washing of poly(vinyl butyral) |
CN103288989A (zh) * | 2013-06-05 | 2013-09-11 | 扬州大学 | 一种离子液体制备聚乙烯醇缩醛类化合物的方法 |
CN104193859B (zh) * | 2014-08-26 | 2016-06-15 | 浙江德斯泰塑胶有限公司 | 一种大密度聚乙烯醇缩丁醛树脂的合成方法 |
CN109906233B (zh) * | 2016-11-02 | 2021-10-08 | 日本瓦姆&珀巴尔株式会社 | 悬浮聚合用分散助剂和使用其制备乙烯基系聚合物的方法 |
CN110655746A (zh) * | 2019-10-28 | 2020-01-07 | 怀集县怀德新材料有限公司 | 一种无机纳米pvb树脂粉的生产方法 |
CN115073633B (zh) * | 2021-08-31 | 2024-07-09 | 乐凯光电材料有限公司 | 一种聚乙烯醇缩醛树脂及其制备方法 |
Family Cites Families (16)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE891745C (de) * | 1939-05-24 | 1953-10-01 | Hoechst Ag | Verfahren zur Herstellung von Polyvinylacetalen |
US2258410A (en) * | 1939-06-20 | 1941-10-07 | Monsanto Chemicals | Method of making stable vinyl resins |
US2496480A (en) * | 1946-06-12 | 1950-02-07 | Shawinigan Resins Corp | Preparation of polyvinyl acetal resins of improved stability |
DE1247663C2 (de) * | 1961-02-24 | 1975-11-27 | E.I. Du Pont De Nemours And Company, Wilmington, Del. (V.St.A.) | Verfahren zur herstellung von polyvinylacetalen |
JPS4990792A (ko) * | 1972-12-30 | 1974-08-29 | ||
US4400565A (en) * | 1982-04-28 | 1983-08-23 | Texaco Inc. | Co-catalyst for use with boron trifluoride in olefin oligomerization |
US4464204A (en) * | 1982-11-29 | 1984-08-07 | A. E. Staley Manufacturing Company | Alkylidenation of fructose with perfluorinated acid catalysts |
DE3246605A1 (de) * | 1982-12-16 | 1984-06-20 | Hoechst Ag, 6230 Frankfurt | Feinteilige polyvinylacetale, verfahren zu ihrer herstellung und ihre verwendung fuer einbrennbeschichtungen |
DD216028A1 (de) * | 1983-06-20 | 1984-11-28 | Buna Chem Werke Veb | Verfahren zur herstellung von modifizierten polymeren |
JP3053231B2 (ja) * | 1991-02-19 | 2000-06-19 | 株式会社クラレ | インクジェット用記録シート |
DE4109739A1 (de) * | 1991-03-25 | 1992-10-01 | Hoechst Ag | Oxoacetale von polyvinylalkoholen, verfahren zu ihrer herstellung und ihre verwendung |
US5238994A (en) * | 1991-09-09 | 1993-08-24 | Monsanto Company | Forming polyvinyl butyral |
GB9206783D0 (en) * | 1992-03-27 | 1992-05-13 | British Petroleum Co Plc | Deposition process |
US5371110A (en) * | 1993-06-21 | 1994-12-06 | The United States Of America As Represented By The Administrator Of The National Aeronautics And Space Administration | Ion exchange polymers and method for making |
US5425879A (en) * | 1993-11-01 | 1995-06-20 | E. I. Du Pont De Nemours And Company | Removal of base residues from poly(vinyl alcohol) reaction-slurries |
KR100216028B1 (ko) * | 1996-12-21 | 1999-08-16 | 구자홍 | 이동통신 시스템의 억세스 채널 검색 방법 및 장치 |
-
1996
- 1996-05-04 DE DE19617893A patent/DE19617893C1/de not_active Expired - Fee Related
-
1997
- 1997-04-01 TW TW086104174A patent/TW335404B/zh active
- 1997-04-28 EP EP97107020A patent/EP0805167B1/de not_active Expired - Lifetime
- 1997-04-28 DE DE59708690T patent/DE59708690D1/de not_active Expired - Fee Related
- 1997-04-28 PT PT97107020T patent/PT805167E/pt unknown
- 1997-04-28 AT AT97107020T patent/ATE227745T1/de not_active IP Right Cessation
- 1997-04-28 DK DK97107020T patent/DK0805167T3/da active
- 1997-04-28 ES ES97107020T patent/ES2187694T3/es not_active Expired - Lifetime
- 1997-04-29 RU RU97107423/04A patent/RU2205839C2/ru not_active IP Right Cessation
- 1997-04-30 CN CN97110820A patent/CN1074770C/zh not_active Expired - Fee Related
- 1997-05-01 JP JP9113982A patent/JPH1036446A/ja active Pending
- 1997-05-02 US US08/850,555 patent/US5866654A/en not_active Expired - Fee Related
- 1997-05-02 SG SG1997001372A patent/SG73451A1/en unknown
- 1997-05-02 KR KR1019970016947A patent/KR100479252B1/ko not_active IP Right Cessation
Also Published As
Publication number | Publication date |
---|---|
EP0805167B1 (de) | 2002-11-13 |
TW335404B (en) | 1998-07-01 |
US5866654A (en) | 1999-02-02 |
DE19617893C1 (de) | 1997-10-02 |
EP0805167A3 (de) | 1998-11-18 |
KR100479252B1 (ko) | 2005-07-11 |
ATE227745T1 (de) | 2002-11-15 |
CN1168892A (zh) | 1997-12-31 |
DE59708690D1 (de) | 2002-12-19 |
JPH1036446A (ja) | 1998-02-10 |
EP0805167A2 (de) | 1997-11-05 |
RU2205839C2 (ru) | 2003-06-10 |
DK0805167T3 (da) | 2003-03-03 |
CN1074770C (zh) | 2001-11-14 |
SG73451A1 (en) | 2000-06-20 |
PT805167E (pt) | 2003-02-28 |
ES2187694T3 (es) | 2003-06-16 |
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