KR970026964A - 중성, 고성능, 내 저-e 유리코팅시스팀, 그들로 만든 단열유리 유닛 및 그 제조방법 - Google Patents

중성, 고성능, 내 저-e 유리코팅시스팀, 그들로 만든 단열유리 유닛 및 그 제조방법 Download PDF

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KR970026964A
KR970026964A KR1019960051517A KR19960051517A KR970026964A KR 970026964 A KR970026964 A KR 970026964A KR 1019960051517 A KR1019960051517 A KR 1019960051517A KR 19960051517 A KR19960051517 A KR 19960051517A KR 970026964 A KR970026964 A KR 970026964A
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glass
layer
sputter
layer system
insulating
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KR1019960051517A
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더블류. 하티그 클라우스
엘. 라슨 스티븐
제이. 링글 필립
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존 가스파로빅
가디안 인더스트리즈 코포레이션
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Publication of KR970026964A publication Critical patent/KR970026964A/ko

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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
    • B32B17/06—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
    • B32B17/10—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
    • B32B17/10005—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing
    • B32B17/10165—Functional features of the laminated safety glass or glazing
    • B32B17/10174—Coatings of a metallic or dielectric material on a constituent layer of glass or polymer
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
    • C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
    • C03C17/36—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
    • C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
    • C03C17/36—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal
    • C03C17/3602—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer
    • C03C17/3618—Coatings of type glass/inorganic compound/other inorganic layers, at least one layer being metallic
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
    • C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
    • C03C17/36—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal
    • C03C17/3602—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer
    • C03C17/3626—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer one layer at least containing a nitride, oxynitride, boronitride or carbonitride
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
    • C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
    • C03C17/36—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal
    • C03C17/3602—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer
    • C03C17/3644—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer the metal being silver
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
    • C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
    • C03C17/36—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal
    • C03C17/3602—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer
    • C03C17/3652—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer the coating stack containing at least one sacrificial layer to protect the metal from oxidation
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
    • C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
    • C03C17/36—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal
    • C03C17/3602—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer
    • C03C17/3657—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer the multilayer coating having optical properties
    • C03C17/366—Low-emissivity or solar control coatings
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
    • C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
    • C03C17/36—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal
    • C03C17/3602—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer
    • C03C17/3681—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer the multilayer coating being used in glazing, e.g. windows or windscreens
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C2217/00—Coatings on glass
    • C03C2217/70—Properties of coatings
    • C03C2217/78—Coatings specially designed to be durable, e.g. scratch-resistant
    • E—FIXED CONSTRUCTIONS
    • E06—DOORS, WINDOWS, SHUTTERS, OR ROLLER BLINDS IN GENERAL; LADDERS
    • E06B—FIXED OR MOVABLE CLOSURES FOR OPENINGS IN BUILDINGS, VEHICLES, FENCES OR LIKE ENCLOSURES IN GENERAL, e.g. DOORS, WINDOWS, BLINDS, GATES
    • E06B3/00—Window sashes, door leaves, or like elements for closing wall or like openings; Layout of fixed or moving closures, e.g. windows in wall or like openings; Features of rigidly-mounted outer frames relating to the mounting of wing frames
    • E06B3/66—Units comprising two or more parallel glass or like panes permanently secured together
    • E06B3/663—Elements for spacing panes
    • E06B3/66304—Discrete spacing elements, e.g. for evacuated glazing units
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/12—All metal or with adjacent metals
    • Y10T428/12493—Composite; i.e., plural, adjacent, spatially distinct metal components [e.g., layers, joint, etc.]
    • Y10T428/12535—Composite; i.e., plural, adjacent, spatially distinct metal components [e.g., layers, joint, etc.] with additional, spatially distinct nonmetal component
    • Y10T428/12542—More than one such component
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/12—All metal or with adjacent metals
    • Y10T428/12493—Composite; i.e., plural, adjacent, spatially distinct metal components [e.g., layers, joint, etc.]
    • Y10T428/12535—Composite; i.e., plural, adjacent, spatially distinct metal components [e.g., layers, joint, etc.] with additional, spatially distinct nonmetal component
    • Y10T428/12542—More than one such component
    • Y10T428/12549—Adjacent to each other
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/12—All metal or with adjacent metals
    • Y10T428/12493—Composite; i.e., plural, adjacent, spatially distinct metal components [e.g., layers, joint, etc.]
    • Y10T428/12535—Composite; i.e., plural, adjacent, spatially distinct metal components [e.g., layers, joint, etc.] with additional, spatially distinct nonmetal component
    • Y10T428/12576—Boride, carbide or nitride component
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/12—All metal or with adjacent metals
    • Y10T428/12493—Composite; i.e., plural, adjacent, spatially distinct metal components [e.g., layers, joint, etc.]
    • Y10T428/12535—Composite; i.e., plural, adjacent, spatially distinct metal components [e.g., layers, joint, etc.] with additional, spatially distinct nonmetal component
    • Y10T428/12597—Noncrystalline silica or noncrystalline plural-oxide component [e.g., glass, etc.]
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/12—All metal or with adjacent metals
    • Y10T428/12493—Composite; i.e., plural, adjacent, spatially distinct metal components [e.g., layers, joint, etc.]
    • Y10T428/12535—Composite; i.e., plural, adjacent, spatially distinct metal components [e.g., layers, joint, etc.] with additional, spatially distinct nonmetal component
    • Y10T428/12611—Oxide-containing component
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/12—All metal or with adjacent metals
    • Y10T428/12493—Composite; i.e., plural, adjacent, spatially distinct metal components [e.g., layers, joint, etc.]
    • Y10T428/12771—Transition metal-base component
    • Y10T428/12861—Group VIII or IB metal-base component
    • Y10T428/12896—Ag-base component

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Organic Chemistry (AREA)
  • Civil Engineering (AREA)
  • Structural Engineering (AREA)
  • Surface Treatment Of Glass (AREA)
  • Laminated Bodies (AREA)
  • Glass Compositions (AREA)
  • Shielding Devices Or Components To Electric Or Magnetic Fields (AREA)
  • Insulating Bodies (AREA)

Abstract

정방사율값(En)이 0.06이하이며 좋은 내구성과 중성액이 가능한 특히 단열유리(IG)유닛으로 유용한 유리기판상의 스퍼터코팅된 층 시스템임.
층시스템은 두층의 Si3N4가 은의층을 끼우며 충분한 양의 스테인리스강과 결합되어 특출한 저-E, 중성색, 비거울유사광(빛) 관리특성을 달성한다.

Description

중성, 고성능, 내 저-E 유리코팅시스팀, 그들로 만든 단열유리 유닛 및 그 제조방법
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
제1도는 본 발명에 따른 층 시스템의 1실시예의 부분측단면도.
제1a도는 본 발명에 따른 층 시스템의 다른 실시예의 부분측단면도.
제2도는 본 발명에 의하여 시도되는 IC유닛의 부분 횡단면도.
제3도는 제2도에서 IG유닛을 윈도우, 도어 및 벽으로 사용하여 지은 주거의 부분 사시도.
제4도는 본 발명에 의해 시도되는 공기 빼기와 밀봉전 예비 제작단계에서의 IG유닛의 한 실시예의 부분 횡단 설명도.

Claims (34)

  1. 유리로부터 외측방향으로 다음 층 시스템을 그 유리평판면상에 가지는 유리기판으로 구성되는 스퍼터 코팅 유리제품. a) Si3N4와 스테인리스강으로 구성된 층, 여기에서 상기 스테인리스강은 상기 층의 약 0.5~15중량%의 양으로 됨. b) 니켈 또는 니크롬 층. c) 은(Ag)층. d) 니켈 또는 니크롬 층 : 및, e) Si3N4와 스테인리스강으로 된 층. 여기에서 상기 스테인리스강은 상기 층의 약 0.5~1.5중량%의 양이며 여기에서 상기 유리기판은 약 2mm~6mm의 두께를 가지며, 상기 코팅된 유리판은 약 0.06이하의 정방사율(En)을 가지고, 약 0.07이하의 반구형 방사율(Eh), 약 5.0옴/sg이하의 시이트저항(Rs)이며 유리측에서 관측하였을 때, 거의 중성의 가시성 반사색을 가진다.
  2. 제1항에 있어서, 상기 코팅된 유리기판을 적어도 약 70%의 가시성 투과율을 가지는 스퍼터 코팅 유리제품.
  3. 제1항에 있어서, 상기 유리제품은 가열처리 가능한 것인 스퍼터 코팅 유리제품.
  4. 제1항에 있어서, 상기 층 시스템은 TiO2로 된 하부코팅층을 추가로 가지며 그 층은 대략 다음 두께를 가지는 스퍼터 코팅 유리제품.
  5. 제4항에 있어서, 상기 유리판은 약 0.05이하의 정방사율(En)을 가지며 반구형 방사율(Eh)는 약 0.06이하, 시이트 저항(Rs)은 약 5.0옴/sg. 이하 인 스퍼터 코팅 유리제품.
  6. 제5항에 있어서, 상기 하부코트 층과(a)~(e)층을 필수적으로 가지며 여기에서 상기 (a)~(e)층의 상기 스테인리스강은 상기 층의 약 6중량%의 양으로 된 스퍼터 코팅 유리제품.
  7. 제6항에 있어서, 층들은 대략 다음의 두께를 가지는 스퍼터 코팅 유리제품..
  8. 제7항에 있어서, 상기 층(b)와 (d)는 질소화크롬으로 구성되고 상기 스테인리스강은 질소화크롬으로 구성되는 스퍼터 코팅 유리제품.
  9. 제8항에 있어서, 대략 다음 두께를 가지는 층들.
    여기에서 유리기판은 그 위에 다음 특성을 가지는 층 시스템을 가지며,
    유리측
    RGY는 약 11.0
    ah는 약 2.3
    bh는 약 -8.8
    필름측
    RfY는 약 6.0
    ah는 약 5.4
    bh는 약 -17.5
    여기서 RY는 반사율이며 ah와 bh는 허터유닛스 I11. C, 10°관측기로 측정한 색관련치이며 여기에서 상기 층 시스템은 기계적 화학적 내구성을 가지며 약 76%의 가시투과율을 가지는 스퍼터 코팅 유리제품.
  10. 제9항에 있어서, 상기 층 시스템은 열처리 가능한 것인 스퍼터 코팅 유리제품.
  11. 제1항에 있어서, 상기 층 시스템은 필수적으로 상기층(a)~(e)으로 구성되고 상기 층 등은 대략 다음 두께를 가지는 것인 스퍼터 코팅 유리제품.
  12. 제11항에 있어서, 층들은 대략 다음 두께를 가지는 스퍼터 코팅 제품.
  13. 제12항에 있어서, 상기 층 시스템은 화학적 기계적 내구성이 있는 것인 스퍼터 코팅 유리제품.
  14. 제13항에 있어서, 상기 층들은 약 다음의 두께를 가지며,
    여기에서 상기 유리기판은 그 위에 약 70% 이상으로 큰 가시 투과율을 가지는 층 시스템을 가지는 스퍼터 코팅 유리제품.
  15. 제14항에 있어서, 상기 유리기판은 그 위에 다음 특성을 가지는 층 시스템을 가지며,
    유리측
    RGY는 약 11.0
    ah는 약 2.3
    bh는 약 -8.8
    필름측
    RfY는 약 6.0
    ah는 약 5.4
    bh는 약 -17.5
    여기서 RY는 반사율이며 ah와 bh는 헌터유닛스 I11. C, 10°관측기로 측정한 색관련치인 스퍼터 코팅 유리제품.
  16. 제15항에 있어서, 상기 층 시스템은 열처리 가능한 것인 스퍼터 코팅된 유리제품.
  17. 제16항에 있어서, 상기 스테인리스강은 층(a)와 (e)중에 있으며, 상기 층의 약 6중량%의 양인 스퍼터 코팅 유리제품.
  18. 제17항에 있어서, 상기 층(b)와 (c)는 질화크롬으로 구성된 것이며, 상기 스테인리스강은 질화크롬으로 된 것인 스퍼터코팅 제품.
  19. 제1항에 있어서, 상기 스테인리스강은 316번 스테인리스강인 스퍼터 코팅 제품.
  20. 제1항에 있어서, 상기 유리기판은 그들의 1표면 상에 다음 특성을 가지는 상기 층 시스템을 가지는 스퍼터 코팅 제품.
    유리측
    RGY는 약 8 내지 18
    ah는 약 -3 내지 +3
    bh는 약 0 내지 -15
    필름측
    RfY는 약 4 내지 15
    ah는 약 0 내지 +8
    bh는 약 -5 내지 -20
    여기서 RY는 반사율이며 ah와 bh는 헌터유닛스, I11. C, 10°관측기로 측정한 색관련치이다.
  21. 제20항에 있어서, 유리측과 필름측 특성이 다음과 같은 스퍼터 코팅 제품.
    유리측
    RGY는 약 9 내지 15
    ah는 약 -1 내지 +3
    bh는 약 -4 내지 -10
    필름측
    RfY는 약 4 내지 10
    ah는 약 +3 내지 +7
    bh는 약 -10 내지 -20.
  22. 제1항에 있어서, 상기 코팅된 유리판의 상기 가시투과율이 약 74%~76%인 스퍼터 코팅 제품.
  23. 최소한 두개의 거의 평행하며 간격이 떨어진 유리의 시이트 중 적어도 하나의 유리시이트는 제1항에 따르는 스퍼터 코팅된 유리시이트로 구성된 단열 유리유닛.
  24. 제23항에 있어서, 상기의 두 유리시이트는 그 주변 끝단에서 서로 함께 밀봉되어서 그 사이에 단열실을 만들게 되며, 여기에서 상기 층 시스템은 상기 단열실내의 상기 유리시이트의 한 표면상에 위치하며, 외측에서 관측하였을 때의 반사율과 색특성은
    RGY는 약 14 내지 20
    ah는 약 -2 내지 +2
    bh는 약 0 내지 -10
    그리고 내측으로부터 보았을 때는
    RfY는 약 11 내지 18
    ah는 약 0 내지 +4
    bh는 약 0 내지 -10
    이며, 가시성 투과율은 적어도 약 61%인 단열유리유닛.
  25. 제24항에 있어서, 상기 유닛은 단열유리윈도우, 도어 또는 벽이며 그 가시투과율은 적어도 약 63%인 단열유리유닛.
  26. 적어도 두개의 실질적으로 평행하며 간격이 떨어진 유리시이트를 그 주변끝단을 서로 밀봉하므로서 그 사이에 단열쳄버를 만들고 여기에서 상기 유리시이트의 적어도 하나는 제4항에 따르는 스퍼터코팅된 유리시이트이며 상기 층 시스템이 상기 단열 챔버내에 위치하는 구성으로 된 단열 유리유닛.
  27. 적어도 두장의 유리시이트를 거의 평행으로 간격사이를 두고 그 주변 끝단에서 서로 밀봉하므로서 그들 사이에 단열 쳄버를 정하고 여기에서 상기 유리시이트의 적어도 하나는 제8항에 르는 스퍼터 코팅된 유리시이트이며 상기 층 시스템은 상기 단열 쳄버 내에 위치하는 단열 유리유닛.
  28. 적어도 두개의 유리시이트를 실질적으로 평행으로 간격을 띄우고 그 주변 끝단을 서로 가열 밀봉하여 그 사이에 실질적으로 공기와 유리된 단열 쳄버를 만들고 여기에서 제10항에 의거하여 적어도 하나의 상기 유리시이트를 스퍼터 코팅된 유리시이트로하여 상기 층 시스템을 상기 단열 쳄버 안에 위치하게 한 단열 유리유닛.
  29. 적어도 두개의 실질적으로 평행하며 간격이 띄워진 유리시이트를 그 주변 끝단을 서로 밀봉하므로서 그 사이에 단열실을 만들고 여기에서 상기 유리시이트의 적어도 하나는 제11항에 따르는 스퍼터 코팅된 유리시이트로 하며 상기 층 시스템을 상기 단열실내에 위치하게 하는 단열 유리유닛.
  30. 적어도 두개의 실질적으로 평행하며 간격이 띄워진 유리시이트를 그 주변 끝단을 서로 밀봉하므로서 그 사이에 단열실을 만들고 여기에서 상기 유리시이트의 적어도 하나는 제18항에 따르는 스퍼터 코팅된 유리시이트로 하며 상기 층 시스템을 상기 단열실내에 위치하게 하는 단열 유리유닛.
  31. 적어도 두개의 실질적으로 평행하며 간격이 띄워진 유리시이트를 그 주변 끝단을 서로 밀봉하므로서 그 사이에 단열실을 만들고 여기에서 상기 유리시이트의 적어도 하나는 제18항에 따르는 스퍼터 코팅된 유리 시이트로 하며 상기 층 시스템을 상기 단열실내에 위치하게 하는 단열 유리유닛.
  32. 적어도 두 유리시이트를 그들의 주변끝단에서 서로 밀봉하므로서 그 사이에 적어도 하나의 단열실을 만드는 방법에 있어서, 상기 방법은 상기 유리시이트를 간격을 띄우고, 상기 시이트를 승온된 또는 그 이상의 온도에서 상기 시이트의 주변 모서리를 서로 밀봉하고 상기 유리시이트의 적어도 하나를 상기 제3항의 스퍼터 코팅된 유리제품을 사용하고, 상기 단열실내에 상기 층 시스템이 위치하는 단계를 사용하는 개선으로 이루어지는 단열 유리 유닛 제박 방법.
  33. 제32항의 방법에 있어서, 적어도 하나의 상기 유리시이트는 제10항에 따르는 스퍼터 코팅된 유리제품인 방법.
  34. 제32항의 방법에 있어서, 적어도 하나의 상기 유리시이트는 제16항에 따르는 스퍼터 코팅된 유리제품인 방법.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019960051517A 1995-11-02 1996-11-01 중성, 고성능, 내 저-e 유리코팅시스팀, 그들로 만든 단열유리 유닛 및 그 제조방법 KR970026964A (ko)

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