KR970006536A - 철계 재료상에 방식층 및 내마모층을 생성하기 위한 방법 및 장치 - Google Patents

철계 재료상에 방식층 및 내마모층을 생성하기 위한 방법 및 장치 Download PDF

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KR970006536A
KR970006536A KR1019960027296A KR19960027296A KR970006536A KR 970006536 A KR970006536 A KR 970006536A KR 1019960027296 A KR1019960027296 A KR 1019960027296A KR 19960027296 A KR19960027296 A KR 19960027296A KR 970006536 A KR970006536 A KR 970006536A
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layer
resistant layer
iron
abrasion
nitriding
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KR1019960027296A
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KR100245361B1 (ko
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호페 스테펜
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한스, 뒤너
메타프라스 이오논 오베르프레헌페레델룽스테흐닉 게엠베하
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Application filed by 한스, 뒤너, 메타프라스 이오논 오베르프레헌페레델룽스테흐닉 게엠베하 filed Critical 한스, 뒤너
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    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C8/00Solid state diffusion of only non-metal elements into metallic material surfaces; Chemical surface treatment of metallic material by reaction of the surface with a reactive gas, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
    • C23C8/06Solid state diffusion of only non-metal elements into metallic material surfaces; Chemical surface treatment of metallic material by reaction of the surface with a reactive gas, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using gases
    • C23C8/34Solid state diffusion of only non-metal elements into metallic material surfaces; Chemical surface treatment of metallic material by reaction of the surface with a reactive gas, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using gases more than one element being applied in more than one step
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C8/00Solid state diffusion of only non-metal elements into metallic material surfaces; Chemical surface treatment of metallic material by reaction of the surface with a reactive gas, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
    • C23C8/06Solid state diffusion of only non-metal elements into metallic material surfaces; Chemical surface treatment of metallic material by reaction of the surface with a reactive gas, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using gases
    • C23C8/28Solid state diffusion of only non-metal elements into metallic material surfaces; Chemical surface treatment of metallic material by reaction of the surface with a reactive gas, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using gases more than one element being applied in one step
    • C23C8/30Carbo-nitriding
    • C23C8/32Carbo-nitriding of ferrous surfaces

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Solid-Phase Diffusion Into Metallic Material Surfaces (AREA)
  • Chemical Vapour Deposition (AREA)
  • Coating With Molten Metal (AREA)
  • Preventing Corrosion Or Incrustation Of Metals (AREA)
  • Laminated Bodies (AREA)
  • Other Surface Treatments For Metallic Materials (AREA)

Abstract

본 발명은 표면 인접 영역에 질소, 탄소 및 산소를 농축시키는, 철계 재료상에 방식층 및 내마모층을 생성하기 위한 방법에 관한 것이다. 특히 긴 내구 수명과 효과적인 방식층 및 내마모층을 가진 철계 재료를 생성하기 위해, 제1방법 단계로 철 탄질화물로 구성된 결합층을 형성하기 위한 질화·탄화를 수행한다. 이어서, 추가의 산화 공정에서 기존의 결합층상에 조밀하고 균일한 산화층을 형성하기 이전에 결합층을 가진 재료의 표면을 활성화시키기 위해 플라즈마에 의한 진공 처리를 수행한다. 질화·탄산 처리로 형성된 결합층을 플라즈마에 의한 진공 처리로 활성화시킴으로써, 표준화된 부식 시험에서 그 내구 수명이 종래의 보호층을 월등히 초과하는 방식층 및 내마모층이 얻어진다.

Description

철계 재료상에 방식층 및 내마모층을 생성하기 위한 방법 및 장치
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (7)

  1. 표면 인접 영역에 질소·탄소 및 산소를 농축시키는, 철계 재료상에 방식층 및 내나모층을 생성하기 위한 방법에 있어서, a) 철 탄질화물로 구성된 결합층을 형성하기 위해 재료를 질화·탄화시키는 단계; b) 재료의 표면을 플라즈마에 의한 진공 처리로 활성화시키는 단계; 및 c) 조밀한 산화층을 형성하기 위해 재료를 산화시키는 단계를 포함하는 것을 특징으로 하는 철계 재료상에 방식층 및 내나모층을 생성하기 위한 방법.
  2. 제1항에 있어서, 질화·탄화 방법 단계 및 산화 방법 단계는 표준 압력하에서 수행되는 것을 특징으로 하는 방법.
  3. 제1항 또는 제2항에 있어서, 질화·탄화 단계중 철 탄질화물 ε-Fe2(N, C)1-x및/또는 δ'Fe4(N, C)1-y이 형성되는 것을 특징으로 하는 방법.
  4. 제1항 내지 제3항 중 어느 한 항에 있어서, 산화는 정해진 조성의 질소-수증기 혼합물로 수행되는 것을 특징으로 하는 방법.
  5. 제1항 내지 제4항 중 어느 한 항에 있어서, 산화는 480℃ 내지 520℃의 온도로 수행되는 것을 특징으로 하는 방법.
  6. 제1항 내지 제5항 중 어느 한 항에 있어서, 활성화시 재료 표면은 질소 이온, 수소 이온, 탄소 이온 및 산소 이온으로 포격되는 것을 특징으로 하는 방법.
  7. 표준 압력 처리 및 플라즈마에 의한 진공 처리가 동일한 공정 설비에서 수행될 수 있는 것을 특징으로 하는 제2항 내지 제6항 중 어느 하나 이상의 항에 따른 방법을 수행하기 위한 장치.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019960027296A 1995-07-11 1996-07-05 철계 재료상에 내식성 및 내마모성 층을 형성하는 방법 KR100245361B1 (ko)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE19525182A DE19525182C2 (de) 1995-07-11 1995-07-11 Verfahren zur Erzeugung von Korrosions- und Verschleißschutzschichten auf Eisenbasiswerkstoffen
DE19525182.2 1995-07-11

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KR970006536A true KR970006536A (ko) 1997-02-21
KR100245361B1 KR100245361B1 (ko) 2000-03-02

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US (1) US5679411A (ko)
EP (1) EP0753599B2 (ko)
JP (1) JP3185015B2 (ko)
KR (1) KR100245361B1 (ko)
AT (1) ATE178659T1 (ko)
BR (1) BR9603031A (ko)
CA (1) CA2180927C (ko)
DE (2) DE19525182C2 (ko)

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DE102014006064A1 (de) 2013-12-18 2015-06-18 Daimler Ag Beschichtetes Grauguss-Bauteil und Herstellungsverfahren
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Also Published As

Publication number Publication date
ATE178659T1 (de) 1999-04-15
JPH09104960A (ja) 1997-04-22
EP0753599B2 (de) 2005-04-13
US5679411A (en) 1997-10-21
BR9603031A (pt) 1998-05-05
JP3185015B2 (ja) 2001-07-09
CA2180927A1 (en) 1997-01-12
KR100245361B1 (ko) 2000-03-02
DE59601585D1 (de) 1999-05-12
EP0753599B1 (de) 1999-04-07
DE19525182A1 (de) 1997-01-16
CA2180927C (en) 2006-10-03
EP0753599A1 (de) 1997-01-15
DE19525182C2 (de) 1997-07-17

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