KR970001456A - 폴리(페닐렌 에테르)수지 및 폴리에스테르 수지의 혼화성 조성물 - Google Patents
폴리(페닐렌 에테르)수지 및 폴리에스테르 수지의 혼화성 조성물 Download PDFInfo
- Publication number
- KR970001456A KR970001456A KR1019960020156A KR19960020156A KR970001456A KR 970001456 A KR970001456 A KR 970001456A KR 1019960020156 A KR1019960020156 A KR 1019960020156A KR 19960020156 A KR19960020156 A KR 19960020156A KR 970001456 A KR970001456 A KR 970001456A
- Authority
- KR
- South Korea
- Prior art keywords
- resin
- composition
- phenylene ether
- poly
- electrophile
- Prior art date
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L71/00—Compositions of polyethers obtained by reactions forming an ether link in the main chain; Compositions of derivatives of such polymers
- C08L71/08—Polyethers derived from hydroxy compounds or from their metallic derivatives
- C08L71/10—Polyethers derived from hydroxy compounds or from their metallic derivatives from phenols
- C08L71/12—Polyphenylene oxides
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
- C08L67/02—Polyesters derived from dicarboxylic acids and dihydroxy compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L71/00—Compositions of polyethers obtained by reactions forming an ether link in the main chain; Compositions of derivatives of such polymers
- C08L71/08—Polyethers derived from hydroxy compounds or from their metallic derivatives
- C08L71/10—Polyethers derived from hydroxy compounds or from their metallic derivatives from phenols
- C08L71/12—Polyphenylene oxides
- C08L71/126—Polyphenylene oxides modified by chemical after-treatment
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L53/00—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C08L53/02—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers of vinyl-aromatic monomers and conjugated dienes
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S525/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S525/905—Polyphenylene oxide
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
본 발명은 친전자체-함유 폴리(페닐렌 에테르)수지, 폴리에스테르 수지, 및 작용화된 폴리올레핀계 수지와 탄성중합체성 블록 공중합체를 포함하는 충격 개질제 혼합물을 포함하고, 우수한 충격성, 연성 및 인장성을 갖는 제품을 제조할 수 있는 폴리(페닐렌 에테르)수지 및 폴리에스테르 수지의 혼화성 블렌드를 제공한다. 상기 조성물은 또한 보강제, 방염제 및 유동촉진제를 포함한다. 상기 조성물로부터 제조된 제품은 자동차 부품에 유용하다.
Description
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
Claims (17)
- (A) 친전자체-함유 폴리(페닐렌 에테르)수지; (B) 열가소성 폴리에스테르 수지; 및 (C) 작용화된 폴리 올레핀계 수지 및 탄성중합체성 블록 공중합체를 포함하는 충격 개질제 혼합물을 포함하는 조성물.
- 제1항에 있어서, 상기 친전자체-함유 폴리(페닐렌 에테르)수지가 에폭시 및 오르토에스테르로 이루어진 그룹의 하나 이상의 친전자성 종을 포함하는 조성물.
- 제2항에 있어서, 상기 친전자체-함유 폴리(페닐렌 에테르)수지가 일반식으로 나타내어지는 그룹을 포함하는 조성물.
- 제2항에 있어서, 상기 친전자체-함유 폴리(페닐렌 에테르)수지가 폴리(페닐렌 에테르)수지 및 그래프팅 가능한 불포화 오르토에스테르 단량체를 포함하는 조성물.
- 제4항에 있어서, 상기 그래프팅가능한 불포화 오르토에스테르 단량체가 일반식 또는으로 나타내어지는 조성물.
- 제2항에 있어서, 상기 천전자체-함유 폴리(페닐렌 에테르)수지가 폴리(페닐렌 에테르)수지, 및 (ⅰ)트리아진 그룹 및 (ⅱ) 에폭시 또는 오르토에스테르 그룹 둘 다를 포함하는 화합물을 포함하는 조성물.
- 제1항에 있어서, 상기 작용화된 폴리올레핀계 수지가 에폭시 및 오르토에스테르로 이루어진 그룹의 하나 이상의 종을 포함하는 조성물.
- 제1항에 있어서, 상기 작용화된 폴리올레핀계 수지가-올레핀과,,β-불포화 카복실산의 글리시딜에스테르의 공중합체인 조성물.
- 제1항에 있어서, 상기 탄성중합체성 블록 공중합체가 비닐 방향족-공역 디엔 블록 공중합체, 부분적으로 수소화된 비닐 방향족-공역 디엔 블록 공중합체, 완전히 수소화된 비닐 방향족-공역 디엔 블록 공중합체 및 그의 혼합물로 이루어진 그룹으로부터 선택되는 조성물.
- 제1항에 있어서, 상기 폴리에스테르가 연속상인 조성물.
- 제10항에 있어서, 성분 (A), (B) 및 (C)의 총중량을 기준으로, 성분(A)가 약 10중량% 내지 약 60중량%로 존재하고, 성분(B)가 약 85중량% 내지 약 25중량%로 존해하고, 성분(C)가 약 3중량% 내지 약 20중량%로 존재하는 조성물.
- 제1항에 있어서, 충격 개질제, 보강 충전재, 유동촉진제, 방염재, 적하방지제, 염료, 안료, 착색제, 안정화제, 대전방지제, 가소제, 비보강 충전재 및 윤활제로 이루어진 그룹으로부터 선택되는 하나 이상의 첨가제를 또한 포함하는 조성물.
- 제1항의 조성물로부터 제조된 제품.
- 제1항에 있어서, 하나 이상의 비작용화된 폴리올레핀계 수지를 또한 포함하는 조성물.
- 제10항에 있어서, 극한 인장 신장률이 25%보다 크고, 노치 아이조드 충격 강도가 2ft-lb/in보다 큰 조성물.
- (A) 친전자체-함유 폴리(페닐렌 에테르)수지; (B) 열가소성 폴리에스테르 수지; 및 (C) 작용화된 폴리올레핀계 수지 및 탄성중합체성 블록 공중합체를 포함하는 충격 개질제 혼합물로 필수적으로 이루어진 조성물.
- (1) 작용화제를 폴리(페닐렌 에테르)수지와 예비블렌딩시켜 친전자체-함유 폴리(페닐렌 에테르)수지를 제조하고; (2) 상기 친전자체-함유 폴리(페닐렌 에테르)수지를, 작용화된 폴리올레핀계 수지와 탄성중합체성 블록 공중합체를 포함하는 충격 개질제 혼합물 및 폴리에스테르 수지를 포함하는 혼합물과 혼합시킴을 포함하는, 제1항의 조성물을 제조하는 방법.※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US08/474,822 | 1995-06-07 | ||
US08/474,822 US5583179A (en) | 1995-06-07 | 1995-06-07 | Compositions of poly(phenylene ether) resins and polyester resins |
Publications (1)
Publication Number | Publication Date |
---|---|
KR970001456A true KR970001456A (ko) | 1997-01-24 |
Family
ID=23885080
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
KR1019960020156A KR970001456A (ko) | 1995-06-07 | 1996-06-05 | 폴리(페닐렌 에테르)수지 및 폴리에스테르 수지의 혼화성 조성물 |
Country Status (6)
Country | Link |
---|---|
US (1) | US5583179A (ko) |
EP (1) | EP0747437B1 (ko) |
JP (1) | JPH09124929A (ko) |
KR (1) | KR970001456A (ko) |
CN (1) | CN1082981C (ko) |
DE (1) | DE69610665T2 (ko) |
Families Citing this family (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP4530506B2 (ja) * | 2000-08-30 | 2010-08-25 | 旭化成ケミカルズ株式会社 | 耐熱部品 |
US6759460B2 (en) | 2001-03-08 | 2004-07-06 | Asahi Kasei Kabushiki Kaisha | Resin composition |
JP4186617B2 (ja) * | 2002-12-24 | 2008-11-26 | 東レ株式会社 | 樹脂組成物 |
US20070049690A1 (en) * | 2005-08-29 | 2007-03-01 | Pravin Borade | Impact modified poly(arylene ether)/polyester blends and method |
US8536272B2 (en) * | 2007-07-12 | 2013-09-17 | Sabic Innovative Plastics Ip B.V. | Thermoplastic poly(arylene ether)/polyester blends and method of making |
US8092717B2 (en) * | 2007-07-12 | 2012-01-10 | Sabic Innovative Plastics Ip B.V. | Thermoplastic poly(arylene ether) / polyester blends and articles thereof |
US20110294961A1 (en) * | 2010-05-28 | 2011-12-01 | E. I. Du Pont De Nemours And Company | Thermoplastic polyester elastomer compositions |
TWI506066B (zh) * | 2012-03-19 | 2015-11-01 | Asahi Kasei E Materials Corp | Pre - impregnated polyphenylene ether particles |
CN114853992B (zh) * | 2022-04-26 | 2024-04-26 | 四川大学 | 可溶低介电常数低介电损耗阻燃全芳共聚酯及其制备方法和应用 |
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US4315086A (en) * | 1979-08-08 | 1982-02-09 | Sumitomo Chemical Company, Limited | Resin compositions |
EP0030417B2 (en) * | 1979-11-30 | 1994-03-30 | Imperial Chemical Industries Plc | Compositions of melt-processable polymers having improved processibility, and method of processing |
US4873286A (en) * | 1985-05-20 | 1989-10-10 | General Electric Company | Modified polyphenylene ether-polyamide compositions and process |
US4732938A (en) * | 1985-12-06 | 1988-03-22 | Borg-Warner Chemicals, Inc. | Thermoplastic polyamide--polyphenylene ether compositions |
US4664972A (en) * | 1986-04-23 | 1987-05-12 | E. I. Du Pont De Nemours And Company | Optically anisotropic melt forming aromatic copolyesters based on t-butylhydroquinone |
US4732937A (en) * | 1986-05-27 | 1988-03-22 | General Electric Company | Epoxide-functionalized polyphenylene ethers and method of preparation |
US4845160A (en) * | 1986-07-14 | 1989-07-04 | General Electric Company | Polyphenylene ether-polyester copolymers and method for their preparation |
US4994531A (en) * | 1986-09-29 | 1991-02-19 | General Electric Company | Functionalized polyphenylene ethers, method of preparation, and polyphenylene ether-polyamide compositions prepared therefrom |
US4916185A (en) * | 1987-09-09 | 1990-04-10 | Yates Iii John B | Olefinic impact modifiers for compatible blends of polyphenylene ethers and linear polyester resins |
US5096967A (en) * | 1988-04-18 | 1992-03-17 | General Electric Company | Solvent-resistant, compatible blends of polyphenylene ethers and thermoplastic polyester mixtures |
US5153267A (en) * | 1988-06-23 | 1992-10-06 | General Electric Company | Compositions comprising polyphenylene ether-polyester copolymers from epoxytriazine-capped polyphenylene ethers |
US5089566A (en) * | 1988-06-23 | 1992-02-18 | General Electric Company | Compositions comprising polyphenylene ether-polyester copolymers from epoxytriazine-capped polyphenylene ethers |
US5096979A (en) * | 1988-06-23 | 1992-03-17 | General Electric Company | Epoxytriazine-capped polyphenylene ethers and method of preparation |
JP2862303B2 (ja) * | 1990-01-19 | 1999-03-03 | ユニチカ株式会社 | ポリマーブレンドの成形方法 |
US5010144A (en) * | 1990-06-07 | 1991-04-23 | General Electric Company | Copolymer-containing compositions from substituted triazine-capped polyphenylene ethers |
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US5089567A (en) * | 1990-06-07 | 1992-02-18 | General Electric Company | Copolymer-containing compositions from substituted triazine-capped polyphenylene ethers |
US5132373A (en) * | 1990-08-13 | 1992-07-21 | General Electric Company | Ortho ester-capped polyphenylene ethers and copolymers prepared therefrom |
JPH04202462A (ja) * | 1990-11-30 | 1992-07-23 | Nippon G Ii Plast Kk | 液晶ポリエステルを含む組成物 |
JPH04202461A (ja) * | 1990-11-30 | 1992-07-23 | Nippon G Ii Plast Kk | 液晶ポリエステル組成物 |
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JPH0586266A (ja) * | 1991-03-15 | 1993-04-06 | Toray Ind Inc | 液晶ポリエステル樹脂組成物 |
JPH05117505A (ja) * | 1991-10-29 | 1993-05-14 | Nippon G Ii Plast Kk | 液晶ポリエステル組成物 |
US5214099A (en) * | 1992-02-25 | 1993-05-25 | General Electric Company | Epoxy-functionalized polyphenylene ethers of low gel content, method for their preparation, and copolymer-containing compositions prepared therefrom |
US5212255A (en) * | 1992-04-03 | 1993-05-18 | General Electric Company | Functionalization of polyphenylene ether with graftable orthoester |
US5247006A (en) * | 1992-04-03 | 1993-09-21 | General Electric Company | Polyphenylene ether-graft-orthoester copolymer blends and method of preparation |
JP3111662B2 (ja) * | 1992-07-27 | 2000-11-27 | 東レ株式会社 | 液晶ポリエステル樹脂組成物 |
US5539062A (en) * | 1995-06-07 | 1996-07-23 | General Electric Company | Compositions of poly(phenylene ether) resins and naphthalate polyester resins |
-
1995
- 1995-06-07 US US08/474,822 patent/US5583179A/en not_active Expired - Lifetime
-
1996
- 1996-05-30 JP JP8135624A patent/JPH09124929A/ja not_active Withdrawn
- 1996-06-05 KR KR1019960020156A patent/KR970001456A/ko not_active Application Discontinuation
- 1996-06-06 EP EP96304165A patent/EP0747437B1/en not_active Expired - Lifetime
- 1996-06-06 DE DE69610665T patent/DE69610665T2/de not_active Expired - Fee Related
- 1996-06-07 CN CN96106854A patent/CN1082981C/zh not_active Expired - Fee Related
Also Published As
Publication number | Publication date |
---|---|
CN1150959A (zh) | 1997-06-04 |
EP0747437B1 (en) | 2000-10-18 |
JPH09124929A (ja) | 1997-05-13 |
CN1082981C (zh) | 2002-04-17 |
DE69610665D1 (de) | 2000-11-23 |
DE69610665T2 (de) | 2001-05-03 |
US5583179A (en) | 1996-12-10 |
EP0747437A2 (en) | 1996-12-11 |
EP0747437A3 (en) | 1997-05-21 |
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