KR940013823A - 라미네이팅 방법 및 이 방법으로 제조된 제품 - Google Patents

라미네이팅 방법 및 이 방법으로 제조된 제품 Download PDF

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KR940013823A
KR940013823A KR1019930030117A KR930030117A KR940013823A KR 940013823 A KR940013823 A KR 940013823A KR 1019930030117 A KR1019930030117 A KR 1019930030117A KR 930030117 A KR930030117 A KR 930030117A KR 940013823 A KR940013823 A KR 940013823A
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싱클레어 노르 로날드
가빈 맥도날드 죤
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마틴 에이취. 마이클
킴벌리-클라크 코포레이션
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B32B37/12—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by using adhesives
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
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    • B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2201/00—Use of cellulose, modified cellulose or cellulose derivatives, e.g. viscose, as reinforcement
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2223/00—Use of polyalkenes or derivatives thereof as reinforcement
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
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    • B32B2305/00—Condition, form or state of the layers or laminate
    • B32B2305/10—Fibres of continuous length
    • B32B2305/20—Fibres of continuous length in the form of a non-woven mat
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2310/00—Treatment by energy or chemical effects
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    • B32B2310/0806—Treatment by energy or chemical effects by wave energy or particle radiation using electromagnetic radiation
    • B32B2310/0831—Treatment by energy or chemical effects by wave energy or particle radiation using electromagnetic radiation using UV radiation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2310/00—Treatment by energy or chemical effects
    • B32B2310/08—Treatment by energy or chemical effects by wave energy or particle radiation
    • B32B2310/0806—Treatment by energy or chemical effects by wave energy or particle radiation using electromagnetic radiation
    • B32B2310/0843—Treatment by energy or chemical effects by wave energy or particle radiation using electromagnetic radiation using laser
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    • B32—LAYERED PRODUCTS
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    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
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    • B—PERFORMING OPERATIONS; TRANSPORTING
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    • B—PERFORMING OPERATIONS; TRANSPORTING
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    • B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B32B37/12—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by using adhesives
    • B32B37/1284—Application of adhesive
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
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    • Y10S428/922—Static electricity metal bleed-off metallic stock
    • Y10S428/9335—Product by special process
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    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
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    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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    • Y10T428/24033—Structurally defined web or sheet [e.g., overall dimension, etc.] including stitching and discrete fastener[s], coating or bond
    • Y10T428/24041—Discontinuous or differential coating, impregnation, or bond
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
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    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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    • Y10T428/31504—Composite [nonstructural laminate]
    • Y10T428/31551—Of polyamidoester [polyurethane, polyisocyanate, polycarbamate, etc.]
    • Y10T428/31573—Next to addition polymer of ethylenically unsaturated monomer
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
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    • Y10T442/659—Including an additional nonwoven fabric
    • Y10T442/66—Additional nonwoven fabric is a spun-bonded fabric
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
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    • Y10T442/60—Nonwoven fabric [i.e., nonwoven strand or fiber material]
    • Y10T442/659—Including an additional nonwoven fabric
    • Y10T442/668—Separate nonwoven fabric layers comprise chemically different strand or fiber material

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Abstract

본 발명에 따르면 (A) 접착제조성물을 제1쉬트의 표면에 도포하고, (B) 제1쉬트의 표면상의 접착제조성물을 유전성 장벽 방전 엑시머 램프로부터의 비간섭성 펄스화 자외선에 노출시키고, (C) 제2쉬트의 표면을 제1쉬트의 접착제조성물 도포 표면과 접촉시키고, (D) 접착제조성물을 경화시키는 것으로 이루어지는 박리 강도 및 내용제성이 중가된 라미네이트의 제조방법이 개시된다 비간섭성 펄스화 자외선은 약 260 내지 약 360nm 범위에서 하나의 좁은 파장 밴드를 갖는다. 접착제조성물은 접착제조성물 중량을 기준으로 약 94 내지 약 60중량%의 지환족 디에폭시드, 약 1 내지 약 10중량%의 양이온성 광개시제및 약 5 내지 약 30중량%의 비닐클로라이드-비닐아세테이트-비닐알콜 삼원 중합체를 포함한다. 바람직하기로는, 쉬트는 필름, 및 셀룰로오스 섬유, 폴리올레핀 섬유, 또는 셀룰로오스와 폴리올레핀 섬유로 이루어진 부직웹이다. 본 발명의 방법은 특히 공업용 와이퍼, 작업복, 의료용 직물 등을 제조하는데 적합할 것이다.

Description

라미네이팅 방법 및 이 방법으로 제조된 제품
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
제1도는 실시예 1,2,5,6.9 및 10에서 사용된 장치의 개략도,
제2도는 본 발명에 따라서 제조된 라미네이트와 융합 램프로 제조된 라미네이트의 박리 강도를, 또한 본 발명에 따라서 제조된 라미네이트와 열경화성 접착제로 제조한 라미네이트의 박리 강도를 비교하여 나타내는 막대 그래프.

Claims (26)

  1. (A) 제1쉬트 재료의 표면에 접착제조성물을 도포하는 단계 : (B) 상기 제1쉬트 재료 표면상의 접착제조성물을 유전성 장벽 방전 엑시머 램프로부터의 비간섭성 펄스화 자외선에 노출시키는 단계 ; (C) 제2쉬트 재료 표면을 상기 제1쉬트 재료의 접착제조성물 도포 표면과 접촉시키는 단계 ; 및 (D) 상기 접촉제조성물을 경화시키는 단계로 이루어지며, 여기서 (1) 상기 비간섭성 펄스화 자외선이 약 260 내지 360nm 범위에서 하나의 좁은 파장 밴드를 가지며, (2) 상기 접착제조성물이 접착제조성물의 중량을 기준으로 약 94 내지 약 60중량%의 지환족 디에폭시드, 약 1 내지 약 10중량%의 양이온성 광개시제및 약 5 내지 약 37중량%의 비닐클로라이드-비닐아세테이트-비닐알콜 삼원 중합체로 이루어진 것을 특징으로 하는 2개 이상의 쉬트 재료층으로 이루어진 라미네이트의 제조방법.
  2. 제1항에 있어서, 상기 제1 및 제2쉬트 재료 각각이 독립적으로 필름 또는 섬유 쉬트 재료인 방법.
  3. 제2항에 있어서, 섬유 쉬트 재료가 셀룰로오스 섬유. 폴리올레핀 섬유 또는 셀룰로오스 섬유와 폴리올레핀 섬유의 혼합물로 이루어진 부직웹의 군으로부터 선택된 것인 방법.
  4. 제3항에 있어서. 상기 부직웹이 티슈웹, 멜트블로운웹. 코폼웹, 및 스펀본딩웹으로 이루어진 군으로부터 선택된 것인 방법.
  5. 제1항에 있어서. 상기 양이온성 광개시제가 아릴술포늄염으로 이루어진 군으로부터 선택된 것인 방법.
  6. 제5항에 있어서, 상기 양이온성 광개시제가 트리아릴술포늄염인 방법.
  7. 제1항에 있어서, 상기 삼원 중합체가 약 15,000 내지 약 30,000범위의 분자량을 갖는 것인 방법.
  8. 제1항에 있어서, 상기 비간섭성 펄스화 자외선이 308nm에서 하나의 좁은 파장 밴드를 갖는 방법.
  9. 제2항에 있어서, 상기 라미네이트가 필수적으로 제1쉬트 재료 및 제2쉬트 재료로 이루어진 방법.
  10. 제9항에 있어서, 상기 제1쉬트 재료가 필름이고. 상기 제2쉬트 재료가 부직웹인 방법.
  11. 제10항에 있어서, 상기 필름이 미세 다공질 폴리에틸렌 필름이고, 상기 제2쉬트 재료가 티슈웹인 방법.
  12. 제10항에 있어서, 상기 제1쉬트 재료가 폴리프로필렌 필름이고, 상기 제2쉬트 재료가 폴리프로필렌 스펀본딩웹인 방법.
  13. (A) 제1표면 및 제2표면을 갖는 제1쉬트를 제공하는 단계 ; (B) 상기 제1쉬트의 상기 제1표면 및 상기 제2표면 각각에 접착제조성물을 도포하는 단계 ; (C) 상기 제1쉬트의 각각 상기 제1표면 및 상기 제2표면 위의 접착제조성물을 유전성 장벽 방전 엑시머 램프로부터의 비간섭성 펄스화 자외선에 노출시키는 단계 : (D) 제2쉬트의 표면을 상기 제1쉬트의 접착제조성물 도포 제1표면과 접촉시키는 단계 : (E) 제3쉬트의 표면을 상기 제1쉬트의 접착제조성물 도포 제2표면과 접촉시키는 단계 ; 및 (F) 접착제조성물을 경화시키는 단계로 이루어지며, 여기서 (1) 상기 비간섭성 펄스화 자외선이 약 260 내지 약 360nm 범위에서 하나의 좁은 파장 밴드를 가지며. (2) 상기 접착제조성물이 접착제조성물의 중량을 기준으로 약 94 내지 약 60중량%의 지환족 디에폭시드. 약 1 내지 약 10중량%의 양이온성 광개시제및 약 5 내지 약 30중량%의 비닐클로라이드-비닐아세테이트-비닐알콜 삼원 중합체로 이루어진 것임을 특징으로 하는 3개의 쉬트로 이루어진 라미네이트의 제조 방법.
  14. 제13항에 있어서, 상기 제1, 제2 및 제3쉬트 재료 각각이 독립적으로 필름 또는 섬유 쉬트 재료인 방법.
  15. 제14항에 있어서. 섬유 쉬트 재료가 셀룰로오스 섬유, 폴리올레핀 섬유 또는 셀룰로오스 섬유와 폴리올레핀 섬유의 혼합물로 이루어진 부직웹의 군으로부터 선택된 것인 방법.
  16. 제15항에 있어서, 상기 부직웹이 티슈웹, 멜트블로운웹, 코폼웹 및 스펀본딩웹으로 이루어진 군으로부터 선택된 것인 방법.
  17. 제13항에 있어서, 상기 양이온성 광개시제가 아릴술포늄염으로 이루어진 군으로부터 선택된 것인 방법.
  18. 제17항에 있어서, 상기 양이온성 광개시제가 트리아릴술포늄염인 방법.
  19. 제13항에 있어서, 상기 삼원 중합체가 약 15,000 내지 약 30,000 범위의 분자량을 갖는 것인 방법.
  20. 제13항에 있어서, 상기 비간섭성 펄스화 자외선이 308nm에서 하나의 좁은 파장 밴드를 갖는 방법.
  21. 제15항에 있어서, 상기 제1쉬트가 폴리프로필렌 스펀본딩웹이고, 상기 제2 및 제3쉬트가 각각 티슈 쉬트인 방법.
  22. 제2항의 방법에 따라서 제조된 라미네이트.
  23. 제3항의 방법에 따라서 제조된 라미네이트.
  24. 제13항의 방법에 따라서 제조된 라미네이트.
  25. 제14항의 방법에 따라서 제조된 라미네이트.
  26. (1) 쉬트 재료들이, 접착제조성물의 중량을 기준으로 약 94 내지 약 60중량%의 지환족 디에폭시드, 약 1 내지 약 5중량%의 양이온성 광개시제및 약 10 내지 약 30중량%의 비닐클로라이드-비닐아세테이트-비닐알콜 삼원 중합체로 이루어진 접착제조성물에 의해 함께 부착되고, (2) 접착제조성물의 경화는 유전성 장벽 방전 엑시머 램프로부터의 약 260 내지 약 360nm 범위에서 하나의 좁은 파장 밴드를 갖는 비간섭성 펄스화 자외선에 노출됨으로써 활성화되고, (3) 주변 온도에서 5분 이상 동안 지방족 탄화수소 용제에 의해서 큰 악영향을 받지 않으며, (4) 약 200g을 초과하는 박리 강도를 갖는, 필름 및 셀룰로오스 섬유, 폴리올레핀 섬유 또는 셀룰로오스 섬유와 폴리올레핀 섬유의 혼합물로 이루어진 부직 웹으로 이루어진 군으로부터 독립적으로 선택된 2개 이상의 쉬트 재료로 이루어진 라미네이트.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019930030117A 1992-12-29 1993-12-28 라미네이팅 방법 및 이 방법으로 제조된 제품 KR100236751B1 (ko)

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