KR930016522A - 오가노실리콘 화합물을 함유하는 발수제 - Google Patents

오가노실리콘 화합물을 함유하는 발수제 Download PDF

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KR930016522A
KR930016522A KR1019930000797A KR930000797A KR930016522A KR 930016522 A KR930016522 A KR 930016522A KR 1019930000797 A KR1019930000797 A KR 1019930000797A KR 930000797 A KR930000797 A KR 930000797A KR 930016522 A KR930016522 A KR 930016522A
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마빈 뱅크 하워드
나룰라 디파크
앤 스타크 로리
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노만 에드워드 루이스
다우 코닝 코포레이션
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Abstract

본 발명은 (ⅰ) 규소에 C1내지 C6알킬 그룹을 갖는 알킬트리알콕시실란; (ⅱ) 실란 커플링제, (ⅲ) 아미노수지 및 (iv) 4급 암모늄 실란을 함유하는 수용액인 조성물에 관한 것이다. 당해 조성물은 표면이 발수성으로 되도록 하기 위해 사용된다.

Description

오가노실리콘 화합물을 함유하는 발수제
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (3)

  1. 물, (ⅰ) 규소에서 C1내지 C6알킬 그룹을 갖는 알킬트리알콕시실란 및 규소에서 C1내지 C6알킬 그룹을 갖는 알킬트리알콕시실란의 블렌드로 이루어진 그룹으로부터 선택된 알킬트리알콕시실란, (ⅱ) 수용성 실란 커필링제 또는 이의 가수분해 생성물, (ⅲ) 아미노 수지 및 (ⅳ) 하기 일반식(Ⅰ), (Ⅱ), (Ⅲ) 및 (Ⅳ)로 이루어진 그룹으로부터 선택된 일반식을 갖는 4급 암모늄 실란을 혼합함으로써 수득된 생성물을 포함하는 조성물.
    상기식에서, Y는 RO(여기서, R은 탄소수가 1내지 4인 알킬 라디칼이다)이고; a는 0.1 또는 2의 값을 갖고; R´은 메틸 또는 에틸 라디칼이고;R"은 탄소수가 1내지 4인 알킬렌 그룹이고;R'",R"" 및 Rv는 각각 독립적으로 탄소수가 1내지 18인 알킬 라디칼, -CH2C6H5, -CH2CH2OH-, -CH2OH 및 -(CH2)wNHC(O)Rⅵ(여기서, x는 2내지 10의 값을 갖고 Rⅵ는 탄소수가 1내지 12인 피플루오로알킬 라디칼이다)로 이루어진 그룹으로부터 선택되고;X는 염화물, 브롬화물, 불화물, 요오드화물, 아세테이트 또는 토실레이트이고;Z는 일반식 C5H6N+-의 양하전된 방향족 피리디늄 환이다.
  2. 물, (ⅰ) 규소에서 C1내지 C6알킬 그룹을 갖는 알킬트리알콕시실란 및 규소에서 C1내지 C6알킬 그룹을 갖는 알킬트리알콕시실란의 블렌드로 이루어진 그룹으로부터 선택된 알킬트리알콕시실란,(ⅱ) 아미노 수지 및 (ⅲ) 하기 일반식(Ⅰ), (Ⅱ), (Ⅲ) 및 (Ⅳ)로 이루어진 그룹으로부터 선택된 일반식을 갖는 4급 암모늄실란을 혼합함으로써 수득된 생성물을 포함하는 조성물.
    상기식에서, Y는 RO(여기서, R은 탄소수가 1내지 4인 아릴 라디칼이다)이고; a는 0,1 또는 2의 값을 갖고;R´은 에틸 또는 에틸 라디칼이고;R˝은 탄소수가 1내지 4인 알킬렌 그룹이고;R'", R"" 및 Rv는 각각 독립적으로 탄소수가 1내지 18인 알킬 라디칼, -CH2C6H5, -CH2CH2OH-, -CH2OH 및 -(CH2)wNHC(O)Rⅵ(여기서, x는 2내지 10의 값을 갖고 Rⅵ는 탄소수가 1내지 12인 피플루오로알킬 라디칼이다)로 이루어진 그룹으로부터 선택되고;X는 염화물, 브롬화물, 불화물, 요오드화물, 아세테이트 또는 토실레이트이고;Z는 일반식 C5H6N+-의 양하전된 방향족 피리디늄 환이다.
  3. 물, (ⅰ) 규소에서 C1내지 C6알킬 그룹을 갖는 알킬트리알콕시실란 및 규소에서 C1내지 C6알킬 그룹을 갖는 알킬트리알콕시실란의 블렌드로 이루어진 그룹으로부터 선택된 알킬트리알콕시실란,(ⅱ) 아미노 수지 및 (ⅲ) 하기 일반식(Ⅰ), (Ⅱ), (Ⅲ) 및 (Ⅳ)로 이루어진 그룹으로부터 선택된 일반식을 갖는 4급 암모늄 실란을 혼합함으로써 형성된 수용액을 표면에 적용시킴을 특징으로 하여, 표면이 발수성으로 되도록 처리하는 방법.
    상기식에서, Y는 RO(여기서, R은 탄소수가 1내지 4인 알킬 라디칼이다)이고; a는 0,1 또는 2의 값을 갖고;R'은 메틸 또는 에틸 라디칼이고;R"은 탄소수가 1내지 4인 알킬렌 그룹이고;R'",R"" 및 Rv는 각각 독립적으로 탄소수가 1내지 18인 알킬 라디칼, -CH2C6H5, -CH2CH2OH-, -CH2OH 및 -(CH2)wNHC(O)Rⅵ(여기서, x는 2내지 10의 값을 갖고 Rⅵ는 탄소수가 1내지 12인 피플루오로알킬 라디칼이다)로 이루어진 그룹으로부터 선택되고;X는 염화물, 브롬화물, 불화물, 요오드화물, 아세테이트 또는 토실레이트이고;Z는 일반식 C5H6N+-의 양하전된 방향족 피리디늄 환이다.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019930000797A 1992-01-23 1993-01-21 오가노 실리콘 화합물을 함유하는 발수제 KR100219764B1 (ko)

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US07/824,2710 1992-01-23
US07/824,271 US5209775A (en) 1992-01-23 1992-01-23 Water repellents containing organosilicon compounds
US7/824,271 1992-01-23

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KR100219764B1 KR100219764B1 (ko) 1999-09-01

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EP (1) EP0552875B1 (ko)
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DE (1) DE69313311T2 (ko)

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US5354494A (en) * 1992-01-21 1994-10-11 Betz Laboratories, Inc. Reactive silane composition and process for enhanced drainage of residual aqueous rinse on the external surfaces of plastic parts
JP2616640B2 (ja) * 1992-07-16 1997-06-04 信越化学工業株式会社 水系塗料用添加剤
GB9218841D0 (en) * 1992-09-05 1992-10-21 Dow Corning Process for producing organosiloxanes
US5393330A (en) * 1993-06-30 1995-02-28 Osi Specialties, Inc. Cationic emulsions of alkylalkoxysilanes
DE4330967A1 (de) * 1993-09-13 1995-03-16 Pfersee Chem Fab Organische Siliciumverbindungen enthaltende Zusammensetzungen für die Behandlung von Fasermaterialien
US5421866A (en) * 1994-05-16 1995-06-06 Dow Corning Corporation Water repellent compositions
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EP0552875B1 (en) 1997-08-27
CA2086795C (en) 2001-10-09
KR100219764B1 (ko) 1999-09-01
CA2086795A1 (en) 1993-07-24
EP0552875A3 (ko) 1994-03-09
EP0552875A2 (en) 1993-07-28
DE69313311D1 (de) 1997-10-02
DE69313311T2 (de) 1998-03-19
US5209775A (en) 1993-05-11

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