KR920704180A - 술폰화된 폴리아닐린 염 조성물, 이것의 제조 방법 및 용도 - Google Patents

술폰화된 폴리아닐린 염 조성물, 이것의 제조 방법 및 용도

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KR920704180A
KR920704180A KR1019920700891A KR920700891A KR920704180A KR 920704180 A KR920704180 A KR 920704180A KR 1019920700891 A KR1019920700891 A KR 1019920700891A KR 920700891 A KR920700891 A KR 920700891A KR 920704180 A KR920704180 A KR 920704180A
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sulfonated polyaniline
polyaniline salt
sulfonated
light
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제이. 에프스테인 아서
위 지앙
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원본미기재
더 오하이오 스테이트 유니버시티 리서치 파운데이션
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Abstract

내용 없음

Description

술폰화된 폴리아닐린 염 조성물, 이것의 제조 방법 및 용도
[도면의 간단한 설명]
제1도는, (a) 자체-도우핑된 술폰화된 폴리아닐린; (b) 술폰화된 폴리아닐린의 어미 중합체인 에머럴딘 염기의 FTIR 스펙트럼을 파수(cm-1)로 나타낸 그래프이다.
제2도는, (a)…석영 기판에 NH4OH 수용액으로 부터 캐스팅된 후, 공기 중에서 건조된 술폰화된 폴리아닐린 막(0.1 NH4OH 에서 3.88 및 2.16 eV에서 피이크); (b)-NMP중의 에머럴딘 염 막(3.76 및 2.0 eV에서 피이크)의 전자 흡수 스펙트럼을 나타낸 그래프이다.
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (22)

  1. 하기 일반식(I)의 화학적 조성을 갖는 술폰화된 폴리아닐린 조성물:
    상기식에서, 0≤y≤1 이고, R1, R2, R3, R4,R5및 R6는 독립적으로 H, -SO3H, -R7SO3H -SO3M, -R7SO3M, -OCH3, -CH3, -C2H5, -F, -Cl, -Br, -I, -NR7 2,-NHCOR7,-OH, -O-, -SR7, -OR7, -OCOR7, -NO2, -COOH, -COOR7, -COR7, -CHO 및 -CN으로 구성된 군으로 부터 선택되고, 여기에서 R7은 C1-C8-알킬, 아릴 또는 아릴킬기이고, M은 양이온이며, X는 -SO3-기를 갖는 페닐 또는 퀴노이드 고리의 분율이고, Z는 M양이노을 갖는 상기 페널 또는 퀴노이드 고리의 분율이며; Z가 X보다 작을때, 조성물은 도체이고, Z가 X에 근접함에 따라 조성물은 비전도성이 된다.
  2. 제1항에 있어서, -SO3M 또는 -R7SO3M인 R1, R2, R3또는 R4기중 적어도 하나릍 함유하는 고리의 분율이 20%로 부터 100%까지 변화됨을 특징으로 하는 조성물.
  3. 제1항에 있어서, 술폰화뒨 폴리아닐린 조성물의 분자량이 300(술폰화된 폴리아닐린의 올리고머) 내지 100,000 이상임을 특징으로 하는 조성물.
  4. 제1항에 있어서, R1이 -SO3M 및 -R7SO3M으로 구성된 군으로 부터 선택되고, R2=R3=R4=H이고, y는 약 0.5임을 특징으로 하는 조성물.
  5. 제1항에 있어서, M이 Li+, Na+, K+, Rb+, Cs+, MH4 +, Ca++, 및 Ba++로 구성된 군으로 부터 선택됨을 특징으로 하는 조성물.
  6. 제1항에 있어서, Z=1 임을 특징으로 하는 조성물.
  7. 자체-도우핑된 술폰화된 폴리아닐린 중합체를 염기성 수용액과 반응시키는 것으로 이루어지는 제1항이 폴리아닐린 조성물을 제조하는 방법.
  8. 제7항에 있어서, 반응이 실온에서 수행됨을 특징으로 하는 방법.
  9. 제7항에 있어서, 반응이 공기 중에서 수행됨을 특징으로 하는 방법.
  10. 제7항에 있어서, 폴리아닐린 조성물이, 반응하는 동안 길이가 감소하지 않는 사전 결정된 사슬 길이를 가짐을 특징으로 하는 방법.
  11. 자체-도우핑된 술폰화된 조성물을 만드는 데이 있어서 중간 물질로서 사용하기 위한 일반식(I)의 술폰화된 폴리아닐린 염 조성물.
  12. (a) 술폰화된 폴리아닐린 염 조성물을 물에 용해시키고; (b) 용해된 술폰화된 폴리아닐린 염 조성물을 기판에 도포시키고; (c) 술폰화된 폴리아닐린 염 조성물을 산으로 세척함으로써 자체-양성자 첨가된 폴리아닐린 조성물로 전환시키는 것으로 이루어지는, 자체-양성자 첨가된 술폰화된 폴리아닐린 조성물을 만드는 데에 있어서 중간 물질로서 일반식(I)의 술폰화된 폴리아닐린 염 조성물을 사용하는 방법.
  13. 전자기 복사가 일반적으로 1000Å 내지 50m의 파장을 갖고 조성물이 일반식(I)의 술폰화된 폴리아닐린염 조성물로 이루어지는 전자기 복사를 흡수하기 위한 조성물.
  14. 일반식(I)의 술폰화된 폴리아닐린 염 조성물을 전자기 복사에 노출시키고, 이것에 의해 전자기 복사를 술폰화된 폴리아닐린 조성물에 흡수시키는 것으로 이루어지는, 전자기 복사를 흡수하는 방법.
  15. (a) 술폰화된 폴리아닐린 염 조성물을 제1 및 제2광 투과성 기판사이에 도포시켜서, 술폰화된 염 조성물을 광 투과성 기판 둘 모두에 접촉시키고; (b) 제1광 투과성 기판을 통해 광 신호를 유도시키고; (c) 술폰화된 폴리아닐린 염 조성물의 굴절 지수를 변화시키기에 충분한 세기 및 파장의 광에 술폰화된 폴리아닐린 염 조성물을 노출시켜서, 제1광 투과성 기판으로 부터 유도된 광 신호가 술폰화된 폴리아닐린 염 조성물을 통해 제2광 투과성 기판으로 커플링되게 하고, 이것에 의해 광 신호를 제2광 투과성 기판을 통해 투과시키는 것으로 기판으로 부터 다른 하나의 광 투과성 기판으로 광 신호를 커플링시키는 방법.
  16. Z가 1이 아닌, 마이크로파의 전파 경로에 위치한 일반식(I)의 일단의 전자기 복사 흡수성 폴리아닐린염 조성물로 이루어지는 마이크로파 감쇄기.
  17. (a) 술폰화된 폴리아닐린 염 조성물로 이루어지는 회진 광학 디스크; (b) 정보의 쓰기 비트를 의한 쓰기 레이저 및 거울의 결합물 ;(c) 광 유도된 정보를 읽기 위한 읽기 레이저 및 거울의 결합물; (d) 정보의 비트식 소거를 위한 소거 레이저 및 거울의 결합물;및 (e) 기억된 정보를 출력시키기 위한 검파기로 이루어지는 소거성 광학 정보 기억 장치.
  18. (a) 100K이하의 온도에서 술폰화된 폴리아닐린 염 조성물의 막으로 부분적으로 이루어진 기억 장치를 유지시키고; (b) 술폰화된 폴리아닐린 염 막의 광 흡수 특성을 변화시키기 위해 공지된 광 주파수 및 세기를 갖는, 정보 또는 데이타를 표시하는 쓰기 비임에 기억 장치를 노출시키고; (c) 막의 변화된 광 흡수 스펙트럼에 부합시키기 위해 사전 결정된 제2의 공지된 광 주파수 및 세기를 갖는 읽기 비임에 기억 장치를 노출시키고, 이것에 의해, 변화된 광 흡수 스펙트럼으로 부터 정보 또는 데이타를 검색하는 것으로 이루어지는, 광학적 고밀도 소거성 형식으로 정보를 기억시키고 검색하는 방법.
  19. 제18항에 있어서, 쓰기 비임이 632.8nm에서 작용하는 헬륨-네온 레이저에 의해 생성된 초점 조정 비임이고, 기억 장치가 술폰화된 폴리아닐린 염 조성물로 이루어진 1미크론 이하의 얇은 막을 부분적으로 포함하고 읽기 비임이 800nm 또는 1550nm에서 작용하는 반도체 다이오드 레이저에 의해 생성됨을 특징으로 하는 방법.
  20. (a) 일반식(I)의 술폰화된 폴리아닐린 염 조성물의 막의 두꺼운 시편을 카프톤 또는 폴리카아보네이트와 같은 투명한 호스트 중합체에 분산시키고; (b) 술폰화된 폴리아닐린 염 막에서 2개의 광선을 초점 조정하여, 술폰화된 폴리아닐린 염 막을 사용하여 초점 조정된 광선 사이의 계면 패턴을 만들고; (c) 술폰화된 폴리아닐린 염 막을 쓰기 비임에 노출시키는 것으로 이루어지는, 3차원 홀로그래프 격자를 생성하는 방법.
  21. 제20항에 있어서, 2개의 초점 조정된 광선이 632.8nm에서 작용하는 저-동력 헬륨-네온 례이저에 의해 생성되고, 읽기 비임이 800mn,1300mn 또는 1550nm에서 작용하는 반도체 다이오드 레이저에 의해 생성됨을 특징으로 하는 방법.
  22. (a) 일반식(I)의 술폰화된 폴리아닐린 염 조성물의 폴리오르토 톨루이딘 및 나프탈 전환물의 막으로 부분적으로 이루어진 기억 장치를 제공하고; (b) 술폰화된 폴리아닐린 염 막의 광 흡수 특성을 변화시키기 위해 공지된 광 주파수 및 세기를 갖는, 정보 및 데이타를 표시하는 쓰기 비임에 기억장치를 노출시키고; (c) 술폰화된 폴리아닐린 염 막의 변화된 광 흡수 스펙트럼에 부합시키기 위해 사진 결정된 제2의 공지된 광 주파수 및 세기를 갖는 읽기 비임에 기억 장치를 노출시키고, 이것에 의해, 변화된 광 흡수 스펙트럼으로 부터 정보 또는 데이타를 검색하는 것으로 이루어지는, 광학적 고밀도 소거성 형식으로 데이타 또는 정보를 기억시키고 검색하는 방법.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019920700891A 1989-10-24 1990-10-23 술폰화된 폴리아닐린 염 조성물, 이것의 제조 방법 및 용도 KR920704180A (ko)

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US07/426,959 US5164465A (en) 1988-05-13 1989-10-24 Sulfonated polyaniline salt compositions, processes for their preparation and uses thereof
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PCT/US1990/006118 WO1991006887A1 (en) 1989-10-24 1990-10-23 Sulfonated polyaniline salt compositions, processes and uses

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Families Citing this family (50)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5378403A (en) * 1987-08-07 1995-01-03 Alliedsignal Inc. High electrically conductive polyanaline complexes having polar substitutents
KR900003916A (ko) * 1988-08-03 1990-03-27 이.아이.듀 퐁 드 네모어 앤드 캄파니 전도성 제품
US5378404A (en) * 1991-04-22 1995-01-03 Alliedsignal Inc. Process for forming dispersions or solutions of electrically conductive conjugated polymers in a polymeric or liquid phase
WO1993005519A1 (en) * 1991-08-29 1993-03-18 Allied-Signal Inc. Solubility modification of conductive conjugated backbone polymers via the dopant moieties
US5422423A (en) * 1992-06-03 1995-06-06 Alliedsignal Inc. Thermally stable electrically conductive conjugated polymer complexes having hydrogen bonding counterions
JP3112745B2 (ja) * 1992-06-17 2000-11-27 富士通株式会社 パターン形成用導電性組成物及び該組成物を用いたパターン形成方法
GB2274336B (en) * 1993-01-13 1997-04-30 British Gas Plc Gas sensors
BE1006245A3 (fr) * 1993-05-03 1994-06-14 Ape Associates As Reactifs pour la detection ou le dosage d'un analyte dans un echantillon, trousses les contenant, et procede de detection ou de dosage utilisant ces reactifs.
US5532025A (en) * 1993-07-23 1996-07-02 Kinlen; Patrick J. Corrosion inhibiting compositions
FR2710648B1 (fr) * 1993-09-28 1995-11-10 Alsthom Cge Alcatel Copolymère à propriétés magnétiques, son procédé de fabrication et ses applications.
US5382491A (en) * 1993-12-21 1995-01-17 International Business Machines Corporation Toner composition
US5589108A (en) * 1993-12-29 1996-12-31 Nitto Chemical Industry Co., Ltd. Soluble alkoxy-group substituted aminobenzenesulfonic acid aniline conducting polymers
US6024895A (en) * 1995-08-11 2000-02-15 Mitsubishi Rayon Co., Ltd. Cross-linkable, electrically conductive composition, electric conductor and process for forming the same
TW390895B (en) 1995-11-15 2000-05-21 Ibm Cross-linked electrically conductive polymers, precursors thereof, methods of fabrication thereof and applications thereof
US6030550A (en) * 1995-11-15 2000-02-29 International Business Machines Corporation Methods of fabrication of cross-linked electrically conductive polymers and precursors thereof
TW464661B (en) * 1996-06-10 2001-11-21 Nippon Catalytic Chem Ind Water-soluble electrically-conductive polyaniline and method for production thereof and antistatic agent using water-soluble electrically-conductive polymer
US5980784A (en) * 1996-10-02 1999-11-09 Mitsubishi Rayon Co., Ltd. Method for producing soluble conductive polymer having acidic group
US5968417A (en) * 1997-03-03 1999-10-19 The United States Of America As Represented By The Administrator Of The National Aeronautics And Space Administration Conducting compositions of matter
US5980723A (en) * 1997-08-27 1999-11-09 Jude Runge-Marchese Electrochemical deposition of a composite polymer metal oxide
US5995273A (en) * 1998-02-25 1999-11-30 Ashwin-Ushas Corporation Electrochromic display device
US5891970A (en) * 1998-07-02 1999-04-06 National Science Council Of Republic Of China Water-soluble self-acid-doped polyaniline derivatives and process for preparing the same
AU2880100A (en) 1999-02-12 2000-08-29 General Electric Company Data storage media
US6326441B1 (en) * 2000-01-18 2001-12-04 Council Of Scientific And Industrial Research Compensated sulphonated polyaniline and a process for the preparation thereof
KR20010109812A (ko) * 2000-06-02 2001-12-12 오권오 다양한 유기 극성용매에 용해성을 갖는 폴리아닐린 염의제조방법
US6406669B1 (en) * 2001-01-12 2002-06-18 The Regents Of The University Of California Polyaniline-based optical ammonia detector
US7071289B2 (en) 2002-07-11 2006-07-04 The University Of Connecticut Polymers comprising thieno [3,4-b]thiophene and methods of making and using the same
US7125479B2 (en) 2002-07-11 2006-10-24 The University Of Connecticut Polymeric compositions comprising thieno[3,4-b]thiophene, method of making, and use thereof
KR100704795B1 (ko) 2002-11-01 2007-04-09 미츠비시 레이온 가부시키가이샤 탄소 나노튜브 함유 조성물, 이를 포함하는 도막을 갖는복합체, 및 이들의 제조 방법
US7105237B2 (en) 2003-10-01 2006-09-12 The University Of Connecticut Substituted thieno[3,4-B]thiophene polymers, method of making, and use thereof
US7746533B2 (en) 2005-07-11 2010-06-29 The University Of Connecticut Electrochromic devices utilizing very low band gap conjugated counter electrodes: preparation and use
US7737247B2 (en) 2005-07-11 2010-06-15 The University Of Connecticut Polymers of thieno[3,4-b]furan, method of making, and use thereof
WO2007098203A2 (en) 2006-02-16 2007-08-30 University Of Connecticut Conductive polymers from precursor polymers, method of making, and use thereof
WO2008143651A2 (en) * 2006-12-07 2008-11-27 The Ohio State University Research Foundation A system for in vivo biosensing based on the optical response of electronic polymers
US7740942B2 (en) * 2006-12-13 2010-06-22 General Electric Company Opto-electronic devices containing sulfonated copolymers
US8168671B2 (en) 2008-06-26 2012-05-01 The University Of Connecticut Synthesis of thieno[3,4-b]thiophene, thieno[3,4-b]furan, related compounds and their derivatives and use thereof
WO2011014887A1 (en) * 2009-07-31 2011-02-03 The Ohio State University Electrically conducting polymer and copolymer compositions, methods for making same and applications therefor
KR101813316B1 (ko) 2011-08-17 2017-12-28 미쯔비시 케미컬 주식회사 고체 전해 콘덴서 및 그의 제조 방법
WO2013074702A1 (en) 2011-11-15 2013-05-23 Ashwin-Ushas Corporation, Inc. Complimentary polymer electrochromic device
US10096395B2 (en) 2012-07-24 2018-10-09 Mitsubishi Chemical Corporation Conductor, conductive composition and laminate
US9207515B2 (en) 2013-03-15 2015-12-08 Ashwin-Ushas Corporation, Inc. Variable-emittance electrochromic devices and methods of preparing the same
US8902486B1 (en) 2013-11-20 2014-12-02 Ashwin-Ushas Corporation, Inc. Method and apparatus for control of electrochromic devices
US9632059B2 (en) 2015-09-03 2017-04-25 Ashwin-Ushas Corporation, Inc. Potentiostat/galvanostat with digital interface
US9482880B1 (en) 2015-09-15 2016-11-01 Ashwin-Ushas Corporation, Inc. Electrochromic eyewear
KR102211565B1 (ko) 2017-02-10 2021-02-03 미쯔비시 케미컬 주식회사 도전성 조성물, 도전성 조성물의 제조 방법 및 도전체의 제조 방법
EP3744794B1 (en) 2018-01-26 2024-04-17 Mitsubishi Chemical Corporation Electroconductive composition and production method therefor, and water-soluble polymer and production method therefor
TWI810256B (zh) 2018-03-15 2023-08-01 日商三菱化學股份有限公司 導電膜及其製造方法、導電體、抗蝕劑圖案的形成方法及積層體
TWI802677B (zh) 2018-04-10 2023-05-21 日商三菱化學股份有限公司 導電性組成物、導電膜及積層體
CN109134853A (zh) * 2018-07-07 2019-01-04 盐城师范学院 一种二维有机材料的制备方法
EP3882314A4 (en) 2018-11-15 2022-03-16 Mitsubishi Chemical Corporation CONDUCTIVE COMPOSITION AND METHOD OF PRODUCTION, CONDUCTORS AND METHOD OF PRODUCTION
WO2021153678A1 (ja) 2020-01-29 2021-08-05 三菱ケミカル株式会社 導電性組成物、レジスト被覆材料、レジスト、及びレジストパターンの形成方法

Family Cites Families (20)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1434019A (en) * 1972-10-30 1976-04-28 Koebner A Sulphonation of aromatic compounds
US4488943A (en) * 1980-11-18 1984-12-18 The United States Of America As Represented By The United States Department Of Energy Polymer blends for use in photoelectrochemical cells for conversion of solar energy to electricity and methods for manufacturing such blends
US4585581A (en) * 1981-10-19 1986-04-29 The United States Of America As Represented By The United States Department Of Energy Polymer blends for use in photoelectrochemical cells for conversion of solar energy to electricity
US4615829A (en) * 1983-11-10 1986-10-07 Nitto Electric Industrial Co., Ltd. Electroconductive organic polymer and method for producing the same
DE3480752D1 (de) * 1983-12-30 1990-01-18 Nitto Denko Corp Elektrisch leitender poroeser film und verfahren zu seiner herstellung.
DE3422316C2 (de) * 1984-06-15 1986-11-20 Zipperling Kessler & Co (Gmbh & Co), 2070 Ahrensburg Verfahren zur Herstellung von verformbaren Polymerblends aus elektrisch leitfähigen organischen Polymeren und/oder organischen Leitern, Vorrichtung zur Durchführung des Verfahrens sowie Verwendung der Polymerblends
US4586792A (en) * 1984-08-31 1986-05-06 Board Of Governors For Higher Education, State Of Rhode Island Electronic display element
US4749260A (en) * 1984-08-31 1988-06-07 The Board Of Governors For Higher Education, State Of Rhode Island And Providence Plantations Variable color transparent panels
US4604427A (en) * 1984-12-24 1986-08-05 W. R. Grace & Co. Method of forming electrically conductive polymer blends
JPH089662B2 (ja) * 1985-02-26 1996-01-31 日東電工株式会社 導電性材料
DE3510036A1 (de) * 1985-03-20 1986-09-25 Basf Ag, 6700 Ludwigshafen Verbundwerkstoff aus poroesen werkstoffen und elektrisch leitfaehigen polymeren
WO1987005914A1 (en) * 1986-03-24 1987-10-08 The Regents Of The University Of California Self-doped polymers
US4742867A (en) * 1986-12-01 1988-05-10 Cape Cod Research, Inc. Method and apparatuses for heat transfer
US4822638A (en) * 1987-02-11 1989-04-18 Lockheed Corporation Electronic device fabrication on non-conductive polymer substrate
JPS6426637A (en) * 1987-07-23 1989-01-27 Tetsuya Aisaka Electrochemical polymerization of aniline and aniline derivative
US5069820A (en) * 1987-08-07 1991-12-03 Allied-Signal Inc. Thermally stable forms of electrically conductive polyaniline
US4851487A (en) * 1988-02-22 1989-07-25 Lockheed Corporation Conductive polymer materials and method of producing same
US4855361A (en) * 1988-02-22 1989-08-08 Lockheed Corporation Conductive polymer-polyimide blends and method for producing same
GB8813196D0 (en) * 1988-06-03 1988-07-06 Gbe International Plc Cutting machine
US4973391A (en) * 1988-08-30 1990-11-27 Osaka Gas Company, Ltd. Composite polymers of polyaniline with metal phthalocyanine and polyaniline with organic sulfonic acid and nafion

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