KR920019415A - 배기가스 정화용 촉매 - Google Patents
배기가스 정화용 촉매 Download PDFInfo
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- KR920019415A KR920019415A KR1019920005664A KR920005664A KR920019415A KR 920019415 A KR920019415 A KR 920019415A KR 1019920005664 A KR1019920005664 A KR 1019920005664A KR 920005664 A KR920005664 A KR 920005664A KR 920019415 A KR920019415 A KR 920019415A
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- KR
- South Korea
- Prior art keywords
- exhaust gas
- oxide
- catalyst
- range
- cerium
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/92—Chemical or biological purification of waste gases of engine exhaust gases
- B01D53/94—Chemical or biological purification of waste gases of engine exhaust gases by catalytic processes
- B01D53/9445—Simultaneously removing carbon monoxide, hydrocarbons or nitrogen oxides making use of three-way catalysts [TWC] or four-way-catalysts [FWC]
- B01D53/945—Simultaneously removing carbon monoxide, hydrocarbons or nitrogen oxides making use of three-way catalysts [TWC] or four-way-catalysts [FWC] characterised by a specific catalyst
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/56—Platinum group metals
- B01J23/58—Platinum group metals with alkali- or alkaline earth metals
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/02—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the alkali- or alkaline earth metals or beryllium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/56—Platinum group metals
- B01J23/63—Platinum group metals with rare earths or actinides
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/78—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with alkali- or alkaline earth metals
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2255/00—Catalysts
- B01D2255/20—Metals or compounds thereof
- B01D2255/206—Rare earth metals
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2255/00—Catalysts
- B01D2255/20—Metals or compounds thereof
- B01D2255/207—Transition metals
- B01D2255/20715—Zirconium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2255/00—Catalysts
- B01D2255/40—Mixed oxides
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2255/00—Catalysts
- B01D2255/90—Physical characteristics of catalysts
- B01D2255/902—Multilayered catalyst
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02T—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO TRANSPORTATION
- Y02T10/00—Road transport of goods or passengers
- Y02T10/10—Internal combustion engine [ICE] based vehicles
- Y02T10/12—Improving ICE efficiencies
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Combustion & Propulsion (AREA)
- Biomedical Technology (AREA)
- Environmental & Geological Engineering (AREA)
- Analytical Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Catalysts (AREA)
- Exhaust Gas Treatment By Means Of Catalyst (AREA)
- Exhaust Gas After Treatment (AREA)
Abstract
내용 없음
Description
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
Claims (16)
- 촉매 1리터당 팔라듐 0.5 내지 30g, 알칼리토류금속 산화물 0.1 내지 50g, 산화세륨 10 내지 150g 및 산화지르코늄 0.1 내지 50g을 포함하는 촉매활성성분과 활성 알루미나 10 내지 300g을 포함하는 혼합물을 모노리드 담체에 갖추고 있는 내연기관의 배기가스로부터 일산화탄소, 탄화수소 및 질소산화물을 동시에 제거하는 배기가스정화 촉매.
- 제1항에 있어서, 상기 산화세륨과 상기 산화지르코늄의 적어도 한쪽이 복합체 또는 고용체의 형태로 존재하는 배기가스 정화촉매.
- 제1항에 있어서, 상기 산화세륨과 상기 산화지르코늄의 비율(산화물로서의 중량비)이 100 : 2 내지 100 : 60의 범위에 있는 배기가스 정화촉매.
- 제2항에 있어서, 상기 산화세륨과 상기 산화지르코늄의 적어도 한쪽에 형성된 상기 복합체 또는 고용체가 공기중 900℃에서 10시간 소성후 250Å보다 크지 않은 범위의 직경을 갖는 결정을 형성하는 배기가스 정화촉매.
- 제2항에 있어서, 상기 산화세륨과 상기 산화지르코늄의 적어도 한쪽에 형성된 상기 복합체 또는 고용체가, 공기중 900℃에서 10시간 소성시 수소중 500℃에서 30분 환원후 400℃에서의 산소소모를 산화세륨 9당 5×10-5를(0₂로서)보다 적지 않은 범위로 나타내는 배기가스 정화촉매.
- 제1항에 있어서, 상기 알칼리토류금속이 베릴륨, 마그네슘, 칼슘, 스트론튬, 및 바륨으로 구성되는 그룹으로부터 선택된 적어도 하나인 배기가스 정화촉매.
- 제1항에 있어서, 상기 알칼리토류금속의 칼슘, 스트론튬, 및 바륨으로 구성되는 그룹으로부터 선택된 적어도 하나인 배기가스 정화촉매.
- 제1항에 있어서, 상기 활성 알루미나가 10 내지 400㎡/g의 범위에 있는 비표면적을 갖는 배기가스 정화촉매.
- 제2항에 있어서, 촉매 1리터당 팔라듐의 양이 0.2 내지 25g의 범위에 있고, 상기 알칼리토류금속 산화물의 양이 0.5 내지 50g의 범위에 있고, 상기 산화세륨의 양이 20 내지 140g의 범위에 있고, 상기 산화지르코늄의 양이 1 내지 40g의 범위에 있고, 상기 활성 알루미나의 양이 10 내지 250g의 범위에 있으며, 또한 상기 산화세륨과 상기 산화지르코늄의 비율(산화물로서의 중량비)이 100 : 4 내지 100 : 40의 범위에 있는 배기가스정화 촉매.
- 제1항내지 제9항의 어느 한 항에 있어서, 산화란탄이 촉매활성 성분으로서 촉매 1리터당 1 내지 50g 범위의 양으로 더욱 도입되는 배기가스 정화촉매.
- 제10항에 있어서, (a) 팔라듐 및 알칼리토류금속 산화물, (b) 그위에 지르코늄 및 란탄을 갖추고 있는 산화세륨, 및 (c) 그 위에 세륨 및 지르코늄을 갖추고 있는 활성 알루미나를 포함하는 촉매성분이 모노리드 담체에 침적되는 배기가스 정화촉매.
- 제11항에 있어서, 그 위에 지르코늄 및 란탄을 갖추고 있는 산화세륨중에 함유된 세륨과 그 위에 세륨 및 지르코늄을 갖추고 있는 내화성 무기산화물중에 함유된 세륨의 비율(산화물로서의 중량비)이 100 : 1 내지 10 : 100의 범위에 있는 배기가스 정화촉매.
- 제1항 내지 제9항의 어느 한 항에 있어서, 촉매 1리터당 산화티타늄이 1 내지 150g 범위의 양으로, 그리고/또는 산화실리콘이 0.05 내지 50g 범위의 양으로 더욱 함유되는 배기가스 정화촉매.
- 제1항 내지 제9항의 어느 한 항에 있어서, 철, 코발트 및 니켈로 구성되는 그룹으로부터 선택되는 적어도 하나의 금속의 산화물이 촉매 1리터당 0.1 내지 20g 범위의 양으로 더욱 함유되는 배기가스 정화촉매.
- 제1항 내지 제14항의 어느 한 항의 촉매를 배기가스 입구쪽의 촉매로서, (a) 로듐 및 백금 또는 (b) 로듐, 백금, 및 팔라듐으로 구성되는 촉매성분과 내화성 무기산화물을 포함하는 혼합물을 모노리드 담체에 갖추고 있는 촉매를 배기가스 출구쪽의 촉매로서 갖는 배기가스 정화시스템.
- (a) 로듐 및 백금 또는 (b) 로듐, 백금, 및 팔라듐으로 구성되는 촉매성분과 내화성 무기산화물을 포함하는 혼합물을 모노리드 담체에 갖추고 있는 촉매를 배기가스 입구쪽의 촉매로서, 제1항 내지 제14항의 어느 한 항의 촉매를 배기가스 출구쪽의 촉매로서 갖는 배기가스 정화시스템.※ 참고사항 : 최초출원 내용에 의하여 공개되는 것임.
Applications Claiming Priority (23)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP91-72978 | 1991-04-05 | ||
JP7297891 | 1991-04-05 | ||
JP91-072978 | 1991-04-05 | ||
JP91-138043 | 1991-06-10 | ||
JP13804391 | 1991-06-10 | ||
JP3180861A JPH0523593A (ja) | 1991-07-22 | 1991-07-22 | 排気ガス浄化システム |
JP91-180861 | 1991-07-22 | ||
JP91-202751 | 1991-08-13 | ||
JP91-202752 | 1991-08-13 | ||
JP20275191 | 1991-08-13 | ||
JP3202752A JPH0549940A (ja) | 1991-08-13 | 1991-08-13 | 排気ガス浄化システム |
JP23027091 | 1991-09-10 | ||
JP91-230270 | 1991-09-10 | ||
JP23472491 | 1991-09-13 | ||
JP91-234724 | 1991-09-13 | ||
JP91-312266 | 1991-11-27 | ||
JP31226691 | 1991-11-27 | ||
JP92-18754 | 1992-02-04 | ||
JP1875492 | 1992-02-04 | ||
JP92-018754 | 1992-02-04 | ||
JP92-22792 | 1992-02-07 | ||
JP92-022792 | 1992-02-07 | ||
JP02279292A JP3272015B2 (ja) | 1992-02-07 | 1992-02-07 | 排気ガス浄化用触媒 |
Publications (2)
Publication Number | Publication Date |
---|---|
KR920019415A true KR920019415A (ko) | 1992-11-19 |
KR960006924B1 KR960006924B1 (ko) | 1996-05-25 |
Family
ID=27579699
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
KR1019920005664A KR960006924B1 (ko) | 1991-04-05 | 1992-04-04 | 배기가스 정화용 촉매 |
Country Status (7)
Country | Link |
---|---|
US (1) | US5260249A (ko) |
EP (1) | EP0507590B1 (ko) |
KR (1) | KR960006924B1 (ko) |
AT (1) | ATE149870T1 (ko) |
BR (1) | BR9201213A (ko) |
CA (1) | CA2064977C (ko) |
DE (1) | DE69218017T2 (ko) |
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-
1992
- 1992-04-02 CA CA002064977A patent/CA2064977C/en not_active Expired - Lifetime
- 1992-04-03 US US07/862,967 patent/US5260249A/en not_active Expired - Lifetime
- 1992-04-03 DE DE69218017T patent/DE69218017T2/de not_active Expired - Lifetime
- 1992-04-03 AT AT92302928T patent/ATE149870T1/de not_active IP Right Cessation
- 1992-04-03 EP EP92302928A patent/EP0507590B1/en not_active Expired - Lifetime
- 1992-04-04 KR KR1019920005664A patent/KR960006924B1/ko not_active IP Right Cessation
- 1992-04-06 BR BR929201213A patent/BR9201213A/pt unknown
Also Published As
Publication number | Publication date |
---|---|
KR960006924B1 (ko) | 1996-05-25 |
EP0507590B1 (en) | 1997-03-12 |
CA2064977C (en) | 1998-09-22 |
CA2064977A1 (en) | 1992-10-06 |
DE69218017T2 (de) | 1997-06-19 |
ATE149870T1 (de) | 1997-03-15 |
EP0507590A1 (en) | 1992-10-07 |
DE69218017D1 (de) | 1997-04-17 |
BR9201213A (pt) | 1992-12-01 |
US5260249A (en) | 1993-11-09 |
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