KR920000718A - β-피콜린의 유도체 및 이들을 함유하는 농작물 보호제 - Google Patents

β-피콜린의 유도체 및 이들을 함유하는 농작물 보호제 Download PDF

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KR920000718A
KR920000718A KR1019910009386A KR910009386A KR920000718A KR 920000718 A KR920000718 A KR 920000718A KR 1019910009386 A KR1019910009386 A KR 1019910009386A KR 910009386 A KR910009386 A KR 910009386A KR 920000718 A KR920000718 A KR 920000718A
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alkyl
haloalkyl
unsubstituted
alkenyl
phenyl
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바그너 올리버
찌페러 베른하르트
괴츠 노르베르트
카일 미하엘
암머만 에버하르트
로렌츠 기젤라
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바르츠, 비텐베르크
바스프 악티엔게젤샤프트
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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D213/00—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
    • C07D213/02—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
    • C07D213/04—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
    • C07D213/24—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom with substituted hydrocarbon radicals attached to ring carbon atoms
    • C07D213/28—Radicals substituted by singly-bound oxygen or sulphur atoms
    • C07D213/30—Oxygen atoms
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/34—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
    • A01N43/40—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom six-membered rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D213/00—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
    • C07D213/02—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
    • C07D213/04—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
    • C07D213/24—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom with substituted hydrocarbon radicals attached to ring carbon atoms
    • C07D213/26—Radicals substituted by halogen atoms or nitro radicals
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D213/00—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
    • C07D213/02—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
    • C07D213/04—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
    • C07D213/24—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom with substituted hydrocarbon radicals attached to ring carbon atoms
    • C07D213/44—Radicals substituted by doubly-bound oxygen, sulfur, or nitrogen atoms, or by two such atoms singly-bound to the same carbon atom
    • C07D213/46—Oxygen atoms
    • C07D213/50—Ketonic radicals
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D213/00—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
    • C07D213/02—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
    • C07D213/04—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
    • C07D213/24—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom with substituted hydrocarbon radicals attached to ring carbon atoms
    • C07D213/44—Radicals substituted by doubly-bound oxygen, sulfur, or nitrogen atoms, or by two such atoms singly-bound to the same carbon atom
    • C07D213/53—Nitrogen atoms

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  • Organic Chemistry (AREA)
  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Plant Pathology (AREA)
  • Engineering & Computer Science (AREA)
  • Dentistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Pest Control & Pesticides (AREA)
  • Agronomy & Crop Science (AREA)
  • Pyridine Compounds (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

내용 없음

Description

β-피콜린의 유도체 및 이들을 함유하는 농작물 보호제
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (6)

  1. 하기 일반식 ( I )의 β-피콜린 유도테 및 이것의 N-산화물 및 식물에 허용되는 산부가염 (단. A가 CH2이고.B는 C=0 이고 Ar은 페닐인 화합물은 제외) :
    상기식에서, A는 CR1R2이며, 여기에서 R1및 R2는 서로 독립적으로 각기 수소, C2-C6-알킬, C2-C6-알켄일 또는 C2-C5-알킬일이거나, 또는 R1및 R2는 함께 2내지 6개의 메 틸렌그룹을 갖는 메틸렌사슬을 형성하고;B는CH2, CHOR3. CHR4, C=0또는C=N-0-R5중의 하나이며. 여기에서 R2는 수소, C1-C22-알킬,C1-C6-할로알킬, C3-C6-시클로알킬, C3-C6-알켄일, C2-C6-아실, 페닐, 벤질 또는 벤조일이며, 이중에서 페닐고리는 비치환되거나또는Cl-C4-알킬, Cl-C4-알콕시, Cl-C4-할로알킬, Cl-C4-할로알콕시, 할로겐, 시아노 및 니트로로 이루어진 그룹중 1내지 3개의 치환기들에 의해 치환될 수 있고 R4는 수소, 불소, 염소, 브롬 또는 요오드이고, R5는'수소, Cl-C5-알킬, Cl-C6-할로알킬, C3-C7-시클로알킬, C3-C6-알켄일 또는 아르알킬이며, 이중에서 알킬기는 1내지 4개의 탄소원자를 가지며 아릴기는 비치환될 수 있거나또는 Cl-C4-알킬, Cl-C4-알콕시, Cl-C4-할로알킬, 할로겐, 시아노 및 니트로로 이루어진그룹중 1내지 3개의 치환기들에 외해 치환될 수 있고; Ar은 비치환되거나또는할로겐, C1-C6-알킬. Cl-C6-알록시, Cl-C4-할로알킬, C1-C4-할로알콕시, 패닐, 페녹시, 할로패닐, 할로패녹시 또는 벤질옥시에 의해 1내지 3치환된 단핵 또는 이핵아릴기 이다.
  2. 살균량의 하기 일반식 ( I )의 β-피콜린 유도체 또는 이들의 N-산화물 또는 식물에 허용되는 산부가염 (단,A가 CH2이고, B가 C=0이며 Ar은 페닐인 화합물은 제외)및 비활성 담체를 함휴하는 살균제 ;
    상기식에서. A는CR1R2이며, 여기에서 R1및 R2는서로 독립적으로 각기 수소, Cl-C6-알킬, C2-C5-알켄일또는 C1-C6-알킬일 이거나, 또는 R1및 R2는 함께 2내지 6개의 메틸렌그룹을 갖는 메틸텐사슬을 형성하고; B는 CH3, CHOR3, CHR4, C=0또는 C=N-0-R5중의 하나이며, 여기에서 R3는 수소, C1-C2-알킬, Cl-C4할로알킬, C3-C6-시클로알킬. C3-C6-알켄일, C2-C6-아실, 페닐, 벤질 또는 벤조일이며, 이중에서 패닐고리는 비치환되거나 또는 Cl-C4-알킬, C1-C6-할로알킬. C3-C7-시클로알킬, C3-C6--알켄일 또는 아르알킬이며, 이중에서 알킬기는 1내 지 4개의 탄소원자틀 가지며 아릴기는 비치환될 수 있거나 또는 Cl-C4,-알킬, Cl-C4-알록시, Cl-C4-할로알킬. Cl-C4-할로알콕시, 할로겐, 시아노 및 니트로로 이루어진 그룹중 1내지 3개의 치환기들에 의해 치환될 수 있고, Ar은 비치환되거나또는 할로겐. C1-C6-알킬, C1,-C4-알콕시,C1-할로알킬, Cl-C4-할로알콕시, 페닐, 패녹시, 할로패닐, 할로패녹시 또는 벤질옥시에 의해 1내지 3치환된 단핵또는 이핵아릴기 이다.
  3. 균 또는 균에 의해 공격받는 재료, 식물, 토양, 또는 종자들을 살균량 하기 일반식(I)의 β-피콜린체 또는 이들의 N-산화물 또는 식물에 허용되는 산부가염으로 처리하는 균억제방법 :
    상기식에서. A는CR1R2이며, 여기에서 R1및 R2는서로 독립적으로 각기 수소, Cl-C6-알킬, C2-C5-알켄일또는 C2-C6-알킬일이거나, 또는 R1및 R2는 함께 2내지 6개의 메틸렌그룹을 갖는 메틸텐사슬을 형성하고; B는 CH3, CHOR3, CHR4, C=0또는 C=N-0-R5중의 하나이며, 여기에서 R3는 수소, C1-C2-알킬, Cl-C4할로알킬, C3-C6-시클로알킬. C3-C6-알켄일, C3-C6-아실, 페닐, 벤질 또는 벤조일이며, 이중에서 패닐고리는 비치환되 거나 또는 Cl-C4-알킬, C1-C6-할로알킬. C2-C4-시클로알킬, C3-C6--알켄일 또는 아르알킬이며, 이중에서 알킬기는 1내 지 4개의 탄소훤자틀 가지며 아릴기는 비치환될 수 있거나 또는 Cl-C4,-알킬, Cl-C4-알록시, Cl-C4-할로알킬. Cl-C4-할로알록시, 할로겐, 시아노 및 니트로로 이루어진 그룹중 1내지 3개의치환기들에 의해 치환될 수 있고, Ar은 비치환되거나또는 할로겐. C1-C6-알킬, C1,-C6-알콕시, C1-C4-할로알킬, Cl-C4-할로알콕시, 페닐, 패녹시, 할로패닐, 할로패녹시 또는 벤질옥시에 의해 1내지 3치환된 단핵또는 이핵아릴기 이다.
  4. 제1항에 있어서, A는 C(C2H5)2이고, B는 CHOH 이고 Ar은 4-플루오로페닐임을 특징으로 하는 화합물.
  5. 제1항에 있어서, A는 C(C2H5)2이고, B는 C=O이고 Ar은 4-플루오로페닐임을 특징으로 하는 화합물.
  6. 제1항에 있어서, A는 C(C2H5)2이고, B는 CHCI 이고 Ar은 4-플루오로페닐임을 특징으로 하는 화합물
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019910009386A 1990-06-07 1991-06-07 β-피콜린의 유도체 및 이들을 함유하는 농작물 보호제 KR920000718A (ko)

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DE24018260.6 1990-06-07
DE4018260A DE4018260A1 (de) 1990-06-07 1990-06-07 Derivate des (beta)-picolins und diese enthaltende pflanzenschutzmittel

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US (1) US5162329A (ko)
EP (1) EP0461487A3 (ko)
JP (1) JPH04235966A (ko)
KR (1) KR920000718A (ko)
AU (1) AU636229B2 (ko)
CA (1) CA2043091A1 (ko)
DE (1) DE4018260A1 (ko)
HU (1) HU209236B (ko)
IL (1) IL98291A0 (ko)
NZ (1) NZ238398A (ko)
ZA (1) ZA914318B (ko)

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Publication number Priority date Publication date Assignee Title
US5036074A (en) * 1989-03-01 1991-07-30 Ciba-Geigy Corporation Certain 2,4-dichloro-phenyl(loweralkylidene) pyridines having fungicidal activity
KR100235976B1 (ko) * 1992-05-15 1999-12-15 말콤 카터, 리차드 케이쓰 퍼시 치환된 피리딘 화합물,이것들의 제조방법 및 약제학적 사용방법
EP2603490A4 (en) * 2010-08-10 2014-01-01 Abbvie Inc NEW TRPV3 MODULATORS

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FR2387956A1 (fr) * 1977-04-20 1978-11-17 Unicler Derives de la pyridine et leur preparation
CA1225092A (en) * 1980-10-10 1987-08-04 Franz Dorn Pyridine and pyrazine derivatives
AU554104B2 (en) * 1981-09-01 1986-08-07 F. Hoffmann-La Roche Ag Heterocyclic compounds and fungicides containing same
DE3210725A1 (de) * 1982-03-24 1983-10-06 Bayer Ag Verfahren zur herstellung von methylketonen
EP0117485A3 (de) * 1983-02-28 1985-01-23 F. HOFFMANN-LA ROCHE & CO. Aktiengesellschaft Pyridin-, Pyrazin- und Pyrimidinderivate und deren Verwendung als fungizide Wirkstoffe
GB8504871D0 (en) * 1985-02-26 1985-03-27 Ici Plc Heterocyclic compounds
DE3506633A1 (de) * 1985-02-26 1986-08-28 Basf Ag, 6700 Ludwigshafen Pyridinderivate und diese enthaltende fungizide
US4933339A (en) * 1985-08-21 1990-06-12 Rohm And Haas Company (2-cyano-2-arylethyl)pyridine compounds useful in controlling fungicidal activity
GB8709794D0 (en) * 1987-04-24 1987-05-28 Ici Plc Heterocyclic acids
FR2629455B1 (fr) * 1988-03-29 1991-09-27 Rhone Poulenc Agrochimie Derives de 2-(3-pyridinyl)3-(phenoxy) propanenitrile
WO1990012006A1 (en) * 1989-04-07 1990-10-18 Pfizer Inc. Substituted 1-[3-(heteroarylmethoxy)phenyl]alkanols and related compounds in the treatment of asthma, arthritis and related diseases

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ZA914318B (en) 1993-02-24
DE4018260A1 (de) 1991-12-12
CA2043091A1 (en) 1991-12-08
EP0461487A3 (en) 1992-01-02
HU911896D0 (en) 1991-12-30
IL98291A0 (en) 1992-06-21
AU636229B2 (en) 1993-04-22
AU7820991A (en) 1991-12-12
HU209236B (en) 1994-04-28
HUT58184A (en) 1992-02-28
EP0461487A2 (de) 1991-12-18
NZ238398A (en) 1993-06-25
US5162329A (en) 1992-11-10

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