KR910019675A - 수소화처리용 촉매 및 그의 제조방법 - Google Patents

수소화처리용 촉매 및 그의 제조방법 Download PDF

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Publication number
KR910019675A
KR910019675A KR1019910008258A KR910008258A KR910019675A KR 910019675 A KR910019675 A KR 910019675A KR 1019910008258 A KR1019910008258 A KR 1019910008258A KR 910008258 A KR910008258 A KR 910008258A KR 910019675 A KR910019675 A KR 910019675A
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KR
South Korea
Prior art keywords
alumina
group
catalyst
aluminate
hydrotreating
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Application number
KR1019910008258A
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English (en)
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KR0175301B1 (ko
Inventor
히데후미 야마구치
히로유키 키요후지
카츠히로 시로노
린페이 토쿠오오
준 후치가미
Original Assignee
츠나시마 켄키치
쇼쿠바이 가세이 고오교오 가부시키가이샤
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Publication of KR910019675A publication Critical patent/KR910019675A/ko
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Publication of KR0175301B1 publication Critical patent/KR0175301B1/ko

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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J35/58—
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
    • C10G45/02—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing
    • C10G45/04—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
    • C10G45/02—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing
    • C10G45/04—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used
    • C10G45/06—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used containing nickel or cobalt metal, or compounds thereof
    • C10G45/08—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used containing nickel or cobalt metal, or compounds thereof in combination with chromium, molybdenum, or tungsten metals, or compounds thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/02—Boron or aluminium; Oxides or hydroxides thereof
    • B01J21/04—Alumina
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • B01J37/0018—Addition of a binding agent or of material, later completely removed among others as result of heat treatment, leaching or washing,(e.g. forming of pores; protective layer, desintegrating by heat)

Abstract

내용 없음

Description

수소화처리용 촉매 및 그의 제조방법
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
제1도는 가로좌표상 섬유 알루미나 입자들의 길이(Nm)에 대해 세로좌표상에 플롯팅된, 섬유 알루미나 입자들의 그들의 응집체내 총 수 당 개별적인 길이의 섬유 알루미나 입자들의 수에 의한 빈도(%)를 묘사하는 그래프이다, 제2도는 가로좌표상 반응시간에 대해 플롯팅된 세로좌표상 촉매 활성의 저하를 보상하기 위해 요구되는 온도 상승(T)℃를 보여주는, 촉매유효 수명의 시험 결과를 설명하는 그래프이다.

Claims (4)

  1. 알루미나 캐리어가 평균 입자 길이(L) 10-20Nm를 갖는 섬유 알루미나 입자들의 응집체로 구성되고, 상기 섬유 알루미나 입자들의 적어도 35%부분이 상기 평균 입자 길이(L)±5Nm범위내 길이를 갖음을 특징으로 하는, 주기율표의 Ⅵa족 및 Ⅷ족 금속으로 부터 선택된 촉매성분으로 지지된 알루미나 캐리어로 구성되는 수소화 처리용 촉매.
  2. 카르복실산 기 또는 그의 유도체의 기를 갖는 불포화 탄화수소 증합체 존재하에 알루미나 수화물을 침전시키고; 결과되는 알루미나 수화물 침전물을 세척하여 부산된 염을 제거하고; 침전물을 50℃이상의 온도 및 pH8-12에서 열 숙성에 적용시키고; 결과되는 알루미나 캐리어를 주기율표의 Ⅵa족 및 Ⅷ족 금속으로 부터 선택된 금속 성분으로 지지시키는 것으로 구성되는, 수소화처리용 촉매의 제조 방법.
  3. 제2항에 있어서, 산성 알루미나 염 및 알칼리 금속 알루미네이트의 반응으로 상기 알루미나 수화물을 침전시키는 방법.
  4. 제3항에 있어서, 상기 알칼리 금속 알루미네이트가 알루미늄산 칼륨 및 알루미늄산 나트륨으로 구성되는 군으로부터 선택되는 방법.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019910008258A 1990-05-22 1991-05-22 수소화처리용 촉매 및 그의 제조방법 KR0175301B1 (ko)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2132389A JP2757289B2 (ja) 1990-05-22 1990-05-22 水素化処理触媒およびその製造方法
JP2-132389 1990-05-22

Publications (2)

Publication Number Publication Date
KR910019675A true KR910019675A (ko) 1991-12-19
KR0175301B1 KR0175301B1 (ko) 1999-02-18

Family

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Application Number Title Priority Date Filing Date
KR1019910008258A KR0175301B1 (ko) 1990-05-22 1991-05-22 수소화처리용 촉매 및 그의 제조방법

Country Status (3)

Country Link
US (1) US5110783A (ko)
JP (1) JP2757289B2 (ko)
KR (1) KR0175301B1 (ko)

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5322616A (en) * 1992-03-30 1994-06-21 Texaco Inc. Mild hydrocracking of heavy hydrocarbon feedstocks employing lithia promoted catalysts
JPH08503651A (ja) * 1992-11-18 1996-04-23 アクゾ ノーベル ナムローゼ フェンノートシャップ 二酸化硫黄含有ガス流から二酸化硫黄を除去する方法
US5925592A (en) * 1995-10-04 1999-07-20 Katoh; Akira Process for preparing alumina carrier
EP1200349B2 (en) † 1999-08-11 2008-08-27 Albemarle Netherlands B.V. Process for the preparation of quasi-crystalline boehmites from inexpensive precursors
US8518242B2 (en) 2011-05-26 2013-08-27 Uop Llc Fibrous substrate-based hydroprocessing catalysts and associated methods
CN104549537B (zh) * 2013-10-23 2017-01-18 中国石油化工股份有限公司 一种重质油加氢催化剂载体的制备方法
WO2022209410A1 (ja) * 2021-03-31 2022-10-06 日揮触媒化成株式会社 炭化水素油の水素化処理触媒、およびその製造方法

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3417028A (en) * 1961-07-03 1968-12-17 Montgomery Douglas Sargent Process for the preparation of an inorganic gel having a predetermined pore structure
LU69410A1 (ko) * 1974-02-18 1975-12-09
CA1069486A (en) * 1975-11-10 1980-01-08 Nalco Chemical Company Method of preparing a controlled pore volume alumina with citric acid
US4048060A (en) * 1975-12-29 1977-09-13 Exxon Research And Engineering Company Two-stage hydrodesulfurization of oil utilizing a narrow pore size distribution catalyst
US4145316A (en) * 1977-12-27 1979-03-20 Exxon Research & Engineering Co. Preparation of catalysts of predetermined pore size distribution and pore volume
JPS56105754A (en) * 1980-01-25 1981-08-22 Mitsubishi Chem Ind Ltd Production of carrier for hydro-desulfurization catalyst
JPS5814957B2 (ja) * 1980-07-19 1983-03-23 住友電気工業株式会社 防蝕鋼管の接続部分の防蝕方法

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Publication number Publication date
KR0175301B1 (ko) 1999-02-18
JPH0427436A (ja) 1992-01-30
US5110783A (en) 1992-05-05
JP2757289B2 (ja) 1998-05-25

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