KR910004677A - 올레핀 중합용으로 적절한 바나듐-기재 촉매의 제조방법 - Google Patents
올레핀 중합용으로 적절한 바나듐-기재 촉매의 제조방법 Download PDFInfo
- Publication number
- KR910004677A KR910004677A KR1019900012157A KR900012157A KR910004677A KR 910004677 A KR910004677 A KR 910004677A KR 1019900012157 A KR1019900012157 A KR 1019900012157A KR 900012157 A KR900012157 A KR 900012157A KR 910004677 A KR910004677 A KR 910004677A
- Authority
- KR
- South Korea
- Prior art keywords
- vanadium
- support
- liquid hydrocarbon
- vanadium compound
- compound
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/68—Vanadium, niobium, tantalum or compounds thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/904—Monomer polymerized in presence of transition metal containing catalyst at least part of which is supported on a polymer, e.g. prepolymerized catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Catalysts (AREA)
- Laminated Bodies (AREA)
- Chemical Or Physical Treatment Of Fibers (AREA)
- Steroid Compounds (AREA)
- Physical Or Chemical Processes And Apparatus (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
내용 없음.
Description
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
Claims (10)
- 염화 마그네슘의 구형 지지체상에서의 바나듐의 환원반응에 의하여 액체 탄화수소내에 침전된 바나듐 화합물을 기재로 하는 지글러-낫타형(Ziegler-Netta type)의 촉매를 제조하는 방법에 있어서, a)유기금속 화합물 중에서 선택된 바나듐-환원제를 b)하나 이상의 할로겐 및 하나의 알콕시기를 포함하는 액체 탄화수소에 가용성인 바나듐 화합물, 및 c) (i) Mg-C결합을 포함하는 특정 생성물이 실질적으로 없는 2염화 마그네슘 80 내지 99.5몰%, 및 (ii) 불안정한 수소가 없는 하나 이상의 유기전자 공여 화합물 D 0.5 내지 20몰%를 포함하는 고체 지지체를 액체 탄화수소내에서 접촉시켜 침전을 수행하며, 여기에서 상기 고체 생성물이 입자의 수평균 직경 Dn에 대한 질량 평균 직경 Dm의 비가 2미만이 되는 좁은 입자크기 분포 및 Dm이 10내지 100미크론인 구형 입자로 이루어짐을 특징으로 하는 방법.
- 제1항에 있어서, 지지체가 유기 전자 공여 화합물 D 5 내지 20몰% 및 2염화 마그네슘 80 내지 95몰%를 포함함을 특징으로 하는 방법.
- 제1항에 있어서, 유기 전자 공여 화합물 D가 에테르류, 티오에테르류, 술폰류, 술폭사이드류, 포스핀류, 아민류 및 아미드류 중에서 선택됨을 특징으로 하는 방법.
- 제1항에 있어서, 바나듐 화합물이 하나 이상의 할로겐 X 및 알콕시기 OR 올 X/OR의 몰비가 0.05 내지 20으로 포함함을 특징으로 하는 방법.
- 제1항에 있어서, 바나듐 화합물이 하기한 두가지 일반식중의 하나에 상응함을 특징으로 하는 방법.V(OR)4-mXm또는 VO(OR)3-nXn상기식에서, R은 탄소수 1 내지 12의 알킬라디칼을 나타내고, X는 할로겐 원자를 나타내고, m은 0.2 내지 3.8의 정수 또는 분수이며 n은 0.14 내지 2.85의 정수 또는 분수이다.
- 제1항에 있어서, 바나듐-환원제가 유기알루미늄, 유기마그네슘 및 유기아연 화합물중에서 선택됨을 특징으로 하는 방법.
- 제1항에 있어서, 지지체의 2염화 마그네슘 1몰당 환원제 0.05 내지 1.5몰을 접촉시킴을 특징으로 하는 방법.
- 제1항에 있어서, 지지체의 2염화 마그네슘 1몰당 바나듐 화합물 0.05 내지 2몰을 접촉시킴을 특징으로 하는 방법.
- 제1항에 있어서, 0℃ 내지 120℃에서 0.5 내지 15시간동안 접촉을 수행함을 특징으로 하는 방법.
- 프로필렌, 에틸렌 및/또는 1-부텐, 및 임의로는 비공액 디엔의 탄성 공중합체의 가스상 제조를 위한, 제1항에 따라 제조된 촉매의 용도.※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR8910856 | 1989-08-08 | ||
FR8910856A FR2650827B1 (fr) | 1989-08-08 | 1989-08-08 | Procede de preparation d'un catalyseur de type ziegler - natta a base de vanadium |
Publications (2)
Publication Number | Publication Date |
---|---|
KR910004677A true KR910004677A (ko) | 1991-03-29 |
KR0172119B1 KR0172119B1 (ko) | 1999-03-30 |
Family
ID=9384684
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
KR1019900012157A KR0172119B1 (ko) | 1989-08-08 | 1990-08-08 | 올레핀 중합용으로 적절한 바나듐-기재촉매의 제조방법 |
Country Status (19)
Country | Link |
---|---|
US (1) | US5070054A (ko) |
EP (1) | EP0412729B1 (ko) |
JP (1) | JPH0381303A (ko) |
KR (1) | KR0172119B1 (ko) |
CN (1) | CN1025339C (ko) |
AT (1) | ATE113614T1 (ko) |
AU (2) | AU639248B2 (ko) |
BR (1) | BR9003878A (ko) |
CA (1) | CA2022815C (ko) |
DD (1) | DD299652A5 (ko) |
DE (1) | DE69013798T2 (ko) |
ES (1) | ES2063281T3 (ko) |
FI (1) | FI903887A0 (ko) |
FR (1) | FR2650827B1 (ko) |
HU (1) | HUT59701A (ko) |
MY (1) | MY108533A (ko) |
NO (2) | NO175061B (ko) |
NZ (1) | NZ234816A (ko) |
RU (1) | RU2033257C1 (ko) |
Families Citing this family (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2656614B1 (fr) * | 1990-01-03 | 1993-05-07 | Bp Chemicals Snc | Procede de preparation d'un catalyseur de type ziegler-natta a base de vanadium, supporte sur un chlorure de magnesium. |
US5252688A (en) * | 1990-01-03 | 1993-10-12 | Bp Chemicals Limited | Process for preparing a Ziegler-Natta type catalyst |
IT1254474B (it) * | 1992-02-28 | 1995-09-25 | Montecatini Tecnologie Srl | Processo per la preparazione di copolimeri elastomerici dell'etilene |
US5585184A (en) * | 1994-09-29 | 1996-12-17 | Union Carbide Chemicals & Plastics Technology Corporation | Colorable non-sticky resin core-shell particles |
EP0712871A1 (en) * | 1994-11-02 | 1996-05-22 | Union Carbide Chemicals & Plastics Technology Corporation | Process for the production of homogeneous ethylene propylene rubbers using a vanadium catalyst supported on magnesium chloride |
US6391816B1 (en) * | 1999-10-27 | 2002-05-21 | Phillips Petroleum | Organometal compound catalyst |
KR20010076328A (ko) * | 2000-01-19 | 2001-08-11 | 이정태 | 티씨피/아이피를 하드웨어적으로 처리하는 장치 및 그동작방법 |
CN100460423C (zh) * | 2005-06-30 | 2009-02-11 | 中国石油化工股份有限公司 | 原位合成的负载型钒系非茂聚烯烃催化剂及制备与应用 |
CN105732699B (zh) * | 2014-12-10 | 2018-07-13 | 中国石油天然气股份有限公司 | 烷氧基钒化合物及其制备方法和应用 |
RU2682163C1 (ru) * | 2018-10-31 | 2019-03-15 | Федеральное государственное бюджетное учреждение науки Институт катализа им. Г.К. Борескова Сибирского отделения Российской академии наук (ИК СО РАН) | Способ приготовления ванадиймагниевого катализатора полимеризации этилена и сополимеризации этилена с альфа-олефинами |
Family Cites Families (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2529206A1 (fr) * | 1982-06-24 | 1983-12-30 | Bp Chimie Sa | Procede de preparation de supports a base de chlorure de magnesium pour la preparation de catalyseurs de polymerisation des alpha-olefines et supports obtenus |
EP0099772B2 (fr) * | 1982-06-24 | 1991-11-13 | BP Chimie Société Anonyme | Catalyseurs pour la polymérisation et la copolymérisation de l'éthylène et procédés de polymérisation utilisant ces catalyseurs |
FR2529207A1 (fr) * | 1982-06-24 | 1983-12-30 | Bp Chimie Sa | Procede pour la preparation de supports de catalyseurs pour la polymerisation des alpha-olefines et supports obtenus |
FR2529209A1 (fr) * | 1982-06-24 | 1983-12-30 | Bp Chimie Sa | Catalyseurs pour la polymerisation et la copolymerisation du propylene et procedes de polymerisation utilisant ces catalyseurs |
FR2560200B1 (fr) * | 1984-02-23 | 1986-06-27 | Bp Chimie Sa | Procede de preparation de catalyseurs supportes a base de composes de vanadium pour la polymerisation et la copolymerisation de l'ethylene |
FR2649708B1 (fr) * | 1989-07-17 | 1991-10-25 | Bp Chem Int Ltd | Procede de fabrication en phase gazeuse de copolymeres du propylene a l'aide d'un systeme catalytique de haute activite |
FR2651234B1 (fr) * | 1989-08-29 | 1993-03-12 | Bp Chem Int Ltd | Procede de fabrication en phase gazeuse de copolymeres du propylene a l'aide d'un systeme catalytique de haute activite. |
-
1989
- 1989-08-08 FR FR8910856A patent/FR2650827B1/fr not_active Expired - Fee Related
-
1990
- 1990-08-02 US US07/561,786 patent/US5070054A/en not_active Expired - Lifetime
- 1990-08-02 EP EP90308541A patent/EP0412729B1/en not_active Expired - Lifetime
- 1990-08-02 AT AT90308541T patent/ATE113614T1/de not_active IP Right Cessation
- 1990-08-02 DE DE69013798T patent/DE69013798T2/de not_active Expired - Fee Related
- 1990-08-02 ES ES90308541T patent/ES2063281T3/es not_active Expired - Lifetime
- 1990-08-06 FI FI903887A patent/FI903887A0/fi not_active Application Discontinuation
- 1990-08-07 MY MYPI90001314A patent/MY108533A/en unknown
- 1990-08-07 NO NO903462A patent/NO175061B/no unknown
- 1990-08-07 HU HU904927A patent/HUT59701A/hu unknown
- 1990-08-07 CA CA002022815A patent/CA2022815C/en not_active Expired - Fee Related
- 1990-08-08 JP JP2208320A patent/JPH0381303A/ja active Pending
- 1990-08-08 DD DD90343336A patent/DD299652A5/de not_active IP Right Cessation
- 1990-08-08 AU AU60827/90A patent/AU639248B2/en not_active Ceased
- 1990-08-08 BR BR909003878A patent/BR9003878A/pt unknown
- 1990-08-08 KR KR1019900012157A patent/KR0172119B1/ko not_active IP Right Cessation
- 1990-08-08 CN CN90107787A patent/CN1025339C/zh not_active Expired - Fee Related
- 1990-08-08 RU SU904830915A patent/RU2033257C1/ru active
- 1990-08-08 NZ NZ234816A patent/NZ234816A/en unknown
-
1993
- 1993-04-21 AU AU37077/93A patent/AU650814B2/en not_active Ceased
- 1993-12-08 NO NO934478A patent/NO300926B1/no unknown
Also Published As
Publication number | Publication date |
---|---|
FI903887A0 (fi) | 1990-08-06 |
DE69013798T2 (de) | 1995-03-16 |
NO934478D0 (no) | 1993-12-08 |
HU904927D0 (en) | 1991-01-28 |
DE69013798D1 (de) | 1994-12-08 |
CA2022815A1 (en) | 1991-02-09 |
AU650814B2 (en) | 1994-06-30 |
US5070054A (en) | 1991-12-03 |
FR2650827A1 (fr) | 1991-02-15 |
CN1049850A (zh) | 1991-03-13 |
NO934478L (no) | 1991-02-11 |
AU3707793A (en) | 1993-07-15 |
ES2063281T3 (es) | 1995-01-01 |
NO903462L (no) | 1991-02-11 |
KR0172119B1 (ko) | 1999-03-30 |
EP0412729A1 (en) | 1991-02-13 |
CA2022815C (en) | 2000-12-12 |
DD299652A5 (de) | 1992-04-30 |
JPH0381303A (ja) | 1991-04-05 |
MY108533A (en) | 1996-10-31 |
BR9003878A (pt) | 1991-09-03 |
NO175061B (no) | 1994-05-16 |
HUT59701A (en) | 1992-06-29 |
ATE113614T1 (de) | 1994-11-15 |
NO300926B1 (no) | 1997-08-18 |
AU639248B2 (en) | 1993-07-22 |
NO175061C (ko) | 1994-08-24 |
NZ234816A (en) | 1991-09-25 |
FR2650827B1 (fr) | 1993-03-05 |
NO903462D0 (no) | 1990-08-07 |
RU2033257C1 (ru) | 1995-04-20 |
EP0412729B1 (en) | 1994-11-02 |
AU6082790A (en) | 1991-02-14 |
CN1025339C (zh) | 1994-07-06 |
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