KR900014438A - 고경도투명수지 및 신규 중합성단량체 - Google Patents

고경도투명수지 및 신규 중합성단량체

Info

Publication number
KR900014438A
KR900014438A KR1019900002864A KR900002864A KR900014438A KR 900014438 A KR900014438 A KR 900014438A KR 1019900002864 A KR1019900002864 A KR 1019900002864A KR 900002864 A KR900002864 A KR 900002864A KR 900014438 A KR900014438 A KR 900014438A
Authority
KR
South Korea
Prior art keywords
group
atom
transparent resin
oxygen
residue
Prior art date
Application number
KR1019900002864A
Other languages
English (en)
Other versions
KR930005030B1 (ko
Inventor
도시유끼 스즈끼
가쯔요시 사사가와
마사오 이마이
요시노브 가네무라
Original Assignee
사와무라 하루오
미쯔이도오아쯔가가꾸 가부시끼가이샤
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 사와무라 하루오, 미쯔이도오아쯔가가꾸 가부시끼가이샤 filed Critical 사와무라 하루오
Publication of KR900014438A publication Critical patent/KR900014438A/ko
Application granted granted Critical
Publication of KR930005030B1 publication Critical patent/KR930005030B1/ko

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F36/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D493/00—Heterocyclic compounds containing oxygen atoms as the only ring hetero atoms in the condensed system
    • C07D493/02—Heterocyclic compounds containing oxygen atoms as the only ring hetero atoms in the condensed system in which the condensed system contains two hetero rings
    • C07D493/10—Spiro-condensed systems
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C333/00—Derivatives of thiocarbamic acids, i.e. compounds containing any of the groups, the nitrogen atom not being part of nitro or nitroso groups
    • C07C333/02—Monothiocarbamic acids; Derivatives thereof
    • C07C333/04—Monothiocarbamic acids; Derivatives thereof having nitrogen atoms of thiocarbamic groups bound to hydrogen atoms or to acyclic carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D251/00—Heterocyclic compounds containing 1,3,5-triazine rings
    • C07D251/02—Heterocyclic compounds containing 1,3,5-triazine rings not condensed with other rings
    • C07D251/12—Heterocyclic compounds containing 1,3,5-triazine rings not condensed with other rings having three double bonds between ring members or between ring members and non-ring members
    • C07D251/26—Heterocyclic compounds containing 1,3,5-triazine rings not condensed with other rings having three double bonds between ring members or between ring members and non-ring members with only hetero atoms directly attached to ring carbon atoms
    • C07D251/30—Only oxygen atoms
    • C07D251/34—Cyanuric or isocyanuric esters
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F212/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
    • C08F212/02—Monomers containing only one unsaturated aliphatic radical
    • C08F212/04—Monomers containing only one unsaturated aliphatic radical containing one ring
    • C08F212/14—Monomers containing only one unsaturated aliphatic radical containing one ring substituted by heteroatoms or groups containing heteroatoms
    • C08F212/22—Oxygen
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F212/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
    • C08F212/02—Monomers containing only one unsaturated aliphatic radical
    • C08F212/04—Monomers containing only one unsaturated aliphatic radical containing one ring
    • C08F212/14—Monomers containing only one unsaturated aliphatic radical containing one ring substituted by heteroatoms or groups containing heteroatoms
    • C08F212/26—Nitrogen
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F212/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
    • C08F212/02—Monomers containing only one unsaturated aliphatic radical
    • C08F212/32—Monomers containing only one unsaturated aliphatic radical containing two or more rings
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F212/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
    • C08F212/34—Monomers containing two or more unsaturated aliphatic radicals
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F299/00—Macromolecular compounds obtained by interreacting polymers involving only carbon-to-carbon unsaturated bond reactions, in the absence of non-macromolecular monomers
    • G—PHYSICS
    • G02—OPTICS
    • G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B1/00—Optical elements characterised by the material of which they are made; Optical coatings for optical elements
    • G02B1/04—Optical elements characterised by the material of which they are made; Optical coatings for optical elements made of organic materials, e.g. plastics
    • G02B1/041—Lenses
    • G—PHYSICS
    • G11—INFORMATION STORAGE
    • G11B—INFORMATION STORAGE BASED ON RELATIVE MOVEMENT BETWEEN RECORD CARRIER AND TRANSDUCER
    • G11B7/00—Recording or reproducing by optical means, e.g. recording using a thermal beam of optical radiation by modifying optical properties or the physical structure, reproducing using an optical beam at lower power by sensing optical properties; Record carriers therefor
    • G11B7/24—Record carriers characterised by shape, structure or physical properties, or by the selection of the material
    • G11B7/241—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material
    • G11B7/252—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of layers other than recording layers
    • G11B7/253—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of layers other than recording layers of substrates

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Physics & Mathematics (AREA)
  • Emergency Medicine (AREA)
  • General Physics & Mathematics (AREA)
  • Optics & Photonics (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Paints Or Removers (AREA)
  • Polyurethanes Or Polyureas (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

내용 없음

Description

고경도투명수지 및 신규 중합성단량체
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (13)

  1. 하기일반식(Ⅰ)로 표시되는 단량체(A)와,
    (식중 C는 산소 또는 유황원자를, R는 잔기속에 할로겐원자, 산소원자, 치환족고리, 복소고리 또는 방향고리를 가지고 있거나 가지지 않는 지방족잔기, 지환족잔기 또는 복소고리잔기를 n은 1~4의 정수를 표시하고 n=1일 때, x는 산소원자 또는 유황원자, n2일 때 x는 모두가 산소 원자이거나 모두가 유황원자 혹은 1개 또는 2개가 산소 원자이고 나머지가 유환원자 또는 1개가 유환원자이고 나머지가 산소원자이다)1분자 속에기 또는기에서 선택된 적어도 1종의 관능기를 m개 가진 단량체(B)를 (n+m>)이 3이상의 정수가 되도록 조합해서 공중합시켜 이루어진 가교고분자로 부터 이루어진 고경도 투명수지.
  2. 제1항에 있어서, 청구범의 제1항의 단량체(A) 및 단량체(B)로 이루어진 하기 일반식 (Ⅱ) 및 /또는 (Ⅲ)으로 표시되는 구조단위를 함유하는 가교고분자로부터 이루어진 고경도투명수지.
    (식중 X는 산소 또는 유황원자, R는 잔기속에 할로겐원자, 산소원자, 치환족고리, 복소고리 또는 방향고리를 가지고 있거나 가지지 않는 지방족잔기, 지환족잔기 또는 복소고리잔기를, R'는 수소 또는 메틸기를, Y는…기,…기,기를, n은 1∼4의 정수를 표시하고, n=1일 때, x는 산소원자 또는 유황원자, n2일 때, x는 모두가 산소 원자이거나 모두가 유황원자 혹은 1개 또는 2개가 산소 원자이고 나머지가 유환원자 또는 1개가 유환원자이고 나머지가 산소원자, (n+m)이 3이상의 정수를 표시함.)
  3. 청구범위 제1항 기재의 고경도 투명수지로 이루어진 글레이징재인 고경도 투명수지.
  4. 청구범위 제1항 기재의 고경도 투명수지로 이루어진 디스플레이 장치용 부호커버인 고경도 투명수지.
  5. 청구범위 제1항 기재의 고경도 투명수지로 이루어진 광학렌지인 고경도 투명수지.
  6. 청구범위 제1항 기재의 고경도 투명수지로 이루어진 하아드코우재인 고경도 투명수지.
  7. 제1항에 있어서, 단량체(A)가 하기 일반식(Ⅳ)(Ⅴ)(Ⅵ)로 표시되는 당량체로 이루어진 군에서 선택된 적어도 1종인 단량체(A)와 1분자속에기,기 또는 CH2기에서 선택된 적어도 1종의 관능기를 m개 가진 당랸체(B)를 (n+m)이 3이상의 정수가 되도록 조합해서 공중합시켜 이루어진 가교고분자로 부터 이루어진 고경도 투명수지.
    (식중 n=1, R는 -CH3, -C2H5, -C3H7, -C4H|7, -C5H11, -C6H13, -CH2ccl3, -CH2CF3--CH2-,를 표시함. 또 방향고리의 치환기의 위치는 m-, 또는 p-위를 표시함).
    또 방향고리의 치환기의 위치는 각각 위, 또는 p-위를 표시함.
    를 표시함.
    또 방향고리의 치환기의 위치는 각각 -위, 또는 p-위를 표시함).
  8. 제1항 또는 제2항 또는 제7항에 있어서, 이소프로펜일-α,α-디메틸벤질이소시아네이트와, 잔기속에 할로겐원자, 산소원자, 지방족고리, 복소고리 또는 방향고리를 가지고 있거나, 가지지 않는 지방족 잔기, 지환족 잔기 또는 복소고리 잔기 및 -OH기 및/또는 -SH기를 1~4개 가진 화합물을 이소프로펜일 -α, α-디메틸벤질이소시아네이트가 가진 이소시아네이트기 -OH기 및/또는 -SH기를 반응시켜 얻게되는 카르바민산 에스테르 또는 티오카르바민산에스테르화합물을 단량체(A)로 하는 고경도 투명수지.
  9. 제1항 제2항에 있어서 잔기부분 -R의 분자량이 15~500인 고경도투명수지.
  10. 제1항 또는 제2항 또는 제7항에 있어서, 단량체의 혼합물속에서의 이소프로펜일기와, CH2=기,기기와의 비율이, 이소프로펜일기/당량에 대해서,기,기,기의 총화가 0.5∼10 당량의 범위에서 공중합시킨 고경도 투명수지.
  11. 하기 일반식(Ⅰ)로 표시되는 신규중합성단량체,
    (식중 X는 산소 또는 유황원자를, R는 잔기속에 할로겐원자, 산소원자, 지환족고리, 복소고리 또는 방향고리를 가지고 있거나 나가지지 않는 지방족잔기, 지환족잔기 또는 복소고리 잔기를, n은 1~4의 정수를 표시하고 n=1일때, x는 산소원자 또는 유황원자, n2일때 x는 모두가 산소 원자이거나 모두가 유환원자 혹은 1개 또는 2개가 산소 원자이고 나머지가 유환원자 또는 1개가 유환원자이고 나머지가 산소원자이다)
  12. 제11항에 있어서, x가 산소원자인 신규중합성 단량체.
  13. 하기 일반식(Ⅶ)로 표시되는 신규중합성 단량체.
    (식중 n은 2 또는 3을 표시하고, R는
    를 표시함.
    또, 방향고리의 치환기의 위치는 각각 -위 는 p-위를 표시함.)
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019900002864A 1989-03-01 1990-02-28 고경도 투명수지 및 신규 중합성 단량체 KR930005030B1 (ko)

Applications Claiming Priority (9)

Application Number Priority Date Filing Date Title
JP126629 1986-05-31
JP48919 1989-03-01
JP4891989 1989-03-01
JP1-48919 1989-03-01
JP12662989 1989-05-22
JP1-126629 1989-05-22
JP1-241759 1989-09-20
JP241759 1989-09-20
JP24175989 1989-09-20

Publications (2)

Publication Number Publication Date
KR900014438A true KR900014438A (ko) 1990-10-24
KR930005030B1 KR930005030B1 (ko) 1993-06-12

Family

ID=27293462

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1019900002864A KR930005030B1 (ko) 1989-03-01 1990-02-28 고경도 투명수지 및 신규 중합성 단량체

Country Status (8)

Country Link
US (1) US5084538A (ko)
EP (1) EP0385456B1 (ko)
KR (1) KR930005030B1 (ko)
CN (5) CN1051982C (ko)
AU (1) AU619956B2 (ko)
BR (1) BR9000916A (ko)
CA (1) CA2011075A1 (ko)
DE (1) DE69028329T2 (ko)

Families Citing this family (19)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BR9000917A (pt) * 1989-03-01 1991-02-13 Mitsui Toatsu Chemicals Processo para preparar uma resina transparente de elevada dureza,processo para preparar um monomero,material de envidracamento,cobertura protetora,lente otica,material de revestimento duro e processo para preparar uma camada de revestimento duro
US5393607A (en) * 1992-01-13 1995-02-28 Mitsui Toatsu Chemiclas, Inc. Laminated transparent plastic material and polymerizable monomer
IT1256020B (it) * 1992-05-26 1995-11-20 Enichem Sintesi Vetri organici ad alto indice di rifrazione
US5426164A (en) * 1992-12-24 1995-06-20 The Dow Chemical Company Photodefinable polymers containing perfluorocyclobutane groups
EP0608021B1 (en) * 1993-01-21 1997-05-07 Akzo Nobel N.V. Water-dispersible hybrid polymer
JP2695599B2 (ja) * 1993-09-29 1997-12-24 ホーヤ株式会社 ポリウレタンレンズの製造方法
US6274694B1 (en) 1995-11-20 2001-08-14 Hoya Corporation Process for the production of polyurethane lens
FR2762845B1 (fr) * 1997-05-02 1999-07-16 Corning Sa Compositions polymerisables a base de monomeres difonctionnels differents, resine et articles ophtalmiques les incorporant
US6329482B1 (en) 1997-05-02 2001-12-11 Corning, S.A. Polymerizable compositions based on difunctional monomers, resins and ophthalmic articles containing same
EP0977788B1 (en) * 1997-05-02 2003-07-09 Corning S.A. Polymerizable compositions based on difunctional monomers, resins and ophthalmic articles containing same
KR100872476B1 (ko) * 2002-07-10 2008-12-05 삼성전자주식회사 평판 표시 장치
US20040023122A1 (en) * 2002-08-01 2004-02-05 Felder Thomas C. Optical element resistant to pressure-induced defects
FR2925912B1 (fr) * 2007-12-26 2010-01-22 Toray Plastics Europ Film polyester enroulable comprenant sur au moins l'une de ses faces, un revetement reticule resistant aux rayures, procede d'obtention de ce film polyester
IL214883A (en) * 2011-08-29 2017-11-30 Alon Shimshon Protective layer for optical devices
TWI475321B (zh) * 2013-03-06 2015-03-01 Chi Mei Corp 感光性樹脂組成物及其應用
EP3197927A1 (en) 2014-09-26 2017-08-02 The Chemours Company FC, LLC Polyurethanes derived from non-fluorinated or partially fluorinated polymers
KR20220160123A (ko) 2014-09-26 2022-12-05 더 케무어스 컴퍼니 에프씨, 엘엘씨 표면 효과 조성물을 위한 비-플루오르화 단량체 및 중합체
EP3610845A1 (en) * 2018-08-13 2020-02-19 Stick Tech OY A dental composition
CN113956184B (zh) * 2021-11-05 2023-05-02 中石化石油工程技术服务有限公司 疏水交联单体、超支化堵漏凝胶及其制备方法

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2363546A1 (fr) * 1976-09-07 1978-03-31 Poudres & Explosifs Ste Nale Monomeres mixtes allyliques-acryliques, leur preparation et polymeres en derivant
EP0149038A3 (en) * 1983-12-29 1985-08-21 American Cyanamid Company Cationic copolymerization of meta- or paraisopropenyl-alpha,alpha-dimethylbenzylisocyanate
JPS60233114A (ja) * 1984-05-07 1985-11-19 Mitsui Toatsu Chem Inc 架橋性重合体
US4604439A (en) * 1985-05-28 1986-08-05 The Goodyear Tire & Rubber Company Functionalized monomers from 1-(1-isocyanato-1-methylethyl)-3- or 4-(1-methylethenyl) benzene
JP2628040B2 (ja) * 1987-01-28 1997-07-09 武田薬品工業株式会社 自己架橋性樹脂組成物
JP2641763B2 (ja) * 1988-06-09 1997-08-20 三井東圧化学株式会社 高硬度透明樹脂
DE4006097A1 (de) * 1990-02-27 1991-08-29 Hoechst Ag Ethylenisch ungesaettigte, fluorhaltige urethanderivate und verfahren zu ihrer herstellung

Also Published As

Publication number Publication date
BR9000916A (pt) 1991-02-13
EP0385456A3 (en) 1991-08-21
CN1105662A (zh) 1995-07-26
DE69028329D1 (de) 1996-10-10
DE69028329T2 (de) 1997-03-20
US5084538A (en) 1992-01-28
CN1104652A (zh) 1995-07-05
AU5056590A (en) 1990-09-06
EP0385456A2 (en) 1990-09-05
CN1104208A (zh) 1995-06-28
KR930005030B1 (ko) 1993-06-12
CN1042234C (zh) 1999-02-24
CN1051982C (zh) 2000-05-03
CN1052075C (zh) 2000-05-03
CN1051995C (zh) 2000-05-03
CN1059501C (zh) 2000-12-13
CA2011075A1 (en) 1990-09-01
AU619956B2 (en) 1992-02-06
CN1106794A (zh) 1995-08-16
EP0385456B1 (en) 1996-09-04
CN1131748A (zh) 1996-09-25

Similar Documents

Publication Publication Date Title
KR900014438A (ko) 고경도투명수지 및 신규 중합성단량체
US4810812A (en) Thiolcarboxylic acid esters
KR900007907A (ko) 폴리테트라히드로푸란-디티올 및 그의 제법
KR870008928A (ko) 고 굴절률 플라스틱 렌즈용 수지
KR910011993A (ko) 폴리티올 화합물 및 그로부터 수득한 광학재료 및 광학제품
ATE4547T1 (de) Verfahren zur herstellung von polymerisaten.
IE791292L (en) Poly-(carbonate-urethanes).
KR860001143A (ko) 광경화 수지조성물
KR910000834A (ko) 고경도 투명수지 및 그것으로 이루어진 수지제품
KR970706246A (ko) 신규 황 함유 화합물 및 그의 제조방법(novel sulfur compounds and process for producing the same)
KR900014446A (ko) 고경도 투명수지 및 신규중합성단량체
KR880701258A (ko) 균질환 열경화성 공중합체
JPS5699246A (en) Stabilized synthetic resin composition
EP0376590A3 (en) Monomer or polymer composition derived from acryloxy alkyl cyanoacetamides
FI851531A0 (fi) Hydrofoba och/eller abhesiva massor, reaktiva foertunningsmedel, mjukgoerare och deras anvaendning.
EP0372299A3 (en) Polycarbonate cross-linker resin and fire resistant compositions made therefrom
KR920701387A (ko) 액정 매질
KR900014301A (ko) 네개고리 에스테르 및 에테르
GB1530830A (en) Sulphur-containing polymers and modification of sulphur therewith
KR900016289A (ko) 고굴절율의 유기 유리
KR910014457A (ko) 내후성 중합체 합금
DK335089A (da) Flammebestandige polycarbonater
JPS6426611A (en) Halogen-containing polymer
KR930013027A (ko) 광경화형 도막 조성물 및 이를 이용한 바닥재
EP0299565A3 (en) Optical products made from a thermosetting copolymer having an index of refraction nd20 - 1,52

Legal Events

Date Code Title Description
A201 Request for examination
E902 Notification of reason for refusal
G160 Decision to publish patent application
E701 Decision to grant or registration of patent right
GRNT Written decision to grant
FPAY Annual fee payment

Payment date: 19980526

Year of fee payment: 6

LAPS Lapse due to unpaid annual fee