KR890011922A - 대전 방지성 발포성 스티렌중합체 입자 및 그의 제조방법 - Google Patents

대전 방지성 발포성 스티렌중합체 입자 및 그의 제조방법 Download PDF

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KR890011922A
KR890011922A KR1019880004651A KR880004651A KR890011922A KR 890011922 A KR890011922 A KR 890011922A KR 1019880004651 A KR1019880004651 A KR 1019880004651A KR 880004651 A KR880004651 A KR 880004651A KR 890011922 A KR890011922 A KR 890011922A
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South Korea
Prior art keywords
ammonium salt
quaternary ammonium
styrene polymer
polymer particles
organosol
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KR1019880004651A
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KR960004144B1 (ko
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글레스너 스티클리 수전
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원본미기재
알코 케미칼 캄파니
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/22—After-treatment of expandable particles; Forming foamed products
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/22—After-treatment of expandable particles; Forming foamed products
    • C08J9/224—Surface treatment
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F12/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
    • C08F12/02—Monomers containing only one unsaturated aliphatic radical
    • C08F12/04—Monomers containing only one unsaturated aliphatic radical containing one ring
    • C08F12/06—Hydrocarbons
    • C08F12/08—Styrene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/16—Nitrogen-containing compounds
    • C08K5/17—Amines; Quaternary ammonium compounds
    • C08K5/19—Quaternary ammonium compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2325/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Derivatives of such polymers
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
    • Y10T428/2982—Particulate matter [e.g., sphere, flake, etc.]
    • Y10T428/2991—Coated
    • Y10T428/2998—Coated including synthetic resin or polymer

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Processes Of Treating Macromolecular Substances (AREA)

Abstract

내용 없음

Description

대전 방지성 발포성 스티렌중합체 입자 및 그의 제조방법
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (10)

  1. 하기 단계(a)-(e)포함하는, 사차 암모늄염의 접착코우팅을 갖는 발포성 스티렌 중합체 입자의 제조방법. (a) 상기 발포상 스티렌 중합체 입자를 밀폐된 혼합기내에 도입하고; (b) 방향족 성분이 있거나 없는 정상 또는 환상 지족 탄소수소 또는 이들의 혼합물내에 긴 사슬 지방산의 글리세릴 에스테르와 상기 사차 암모늄의 오르가노졸을 제조하고, (c) 상기 오르가노졸을 상기 발포성 스티렌 중합체 입자에 혼합하면서 첨가하고; (d) 상기 혼합기 내의 압력을 감소시킴으로써 상기 지방족 탄화수소를 제거하고; (e) 상기 사차 암모늄염으로 코우팅된 상기 발포성 스티렌 중합체 입자를 분리한다.
  2. 제1항에 있어서, 오르가노졸을 기준으로 2내지 40중량%의 사차 암모늄과 약 10 내지 약 20중량%의 글리세린의 모노-디-및 트리-지방산에스테르의 혼합물을 함유하고, 나머지는 방향족 성분이 있거나 없는 정상 또는 환상 지방족 탄화수소 또는 이들의 혼합물인 방법.
  3. 제2항에 있어서, 오르가노졸이 추가로 1000내지 4000ppm의 유동체를 함유하는 방법.
  4. 제3항에 있어서, 유동체가 스테아르산 아연인 방법.
  5. 제3항에 있어서, 유동체가 미세 실리카인 방법.
  6. 제1항 내지 제5항중 어느 한 항에 있어서, 오르가노졸이 총오르가노졸을 기준으로 2 내지 40중량%의 사차 암모늄염과 10% 내지 약 20중량%의 글리세린의 모노-, 디-및 트리-스테아레이트의 혼합물을 함유하고 그의 나모지는 n-펜탄, 이소펜탄, 시클로펜탄 또는 이들의 혼합물인 방법.
  7. 제1항 내지 제6항중 어느 한 항에 있어서, 사차 암모늄염이 메틸 트리카프릴릴 암모늄 클로라이드, 디코코 알킬 디메일 암모늄 클로라이드, 소야 디메틸 에틸 암모늄 에틸 술페이트, 코코 알킬 에틸 디메틸 암모늄 에틸 술페이트, 이소스테아르 아미도프로필 에틸 디메틸 암모늄 에틸 술페이트, 트리알킬알콕실화 암모늄염 및 디 알킬 비스알콕실화 암모늄염으로 구성된 군으로부터선택되는 방법.
  8. 하나 이상의 사차 암모늄염과 하나이상의 긴 사슬 지방산 글리세리드이 접착코오팅을 갖는 발포성 스티렌 중합체 입자.
  9. 제8항에 있어서, 상기 지방산 에스테르가 글리세린의 모노-, 디-, 및 트리 스테아레이트의 혼합물인 입자.
  10. 제8항 또는 제9항에 있어서, 상기 사차 암모늄염이 제7항에서 기술한 바와 같은 입자.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019880004651A 1987-04-30 1988-04-23 대전 방지성 발포성 스티렌 중합체 입자 및 그의 제조 방법 KR960004144B1 (ko)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
US4486287A 1987-04-30 1987-04-30
US044,862 1987-04-30
US07/144,906 US4781983A (en) 1987-04-30 1988-01-19 Method for preparing antistatic expandable polystyrene
US144906 1988-01-19
US144,906 1993-10-28

Publications (2)

Publication Number Publication Date
KR890011922A true KR890011922A (ko) 1989-08-23
KR960004144B1 KR960004144B1 (ko) 1996-03-27

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Family Applications (1)

Application Number Title Priority Date Filing Date
KR1019880004651A KR960004144B1 (ko) 1987-04-30 1988-04-23 대전 방지성 발포성 스티렌 중합체 입자 및 그의 제조 방법

Country Status (7)

Country Link
US (1) US4781983A (ko)
EP (1) EP0289321B1 (ko)
JP (1) JP2750324B2 (ko)
KR (1) KR960004144B1 (ko)
CA (1) CA1286166C (ko)
DE (1) DE3875784T2 (ko)
MX (1) MX166551B (ko)

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KR20010109514A (ko) * 2001-11-19 2001-12-10 손진기 영구적인 대전방지성을 갖는 아크릴 패널의 제조방법
KR20070060454A (ko) * 2005-12-08 2007-06-13 주식회사 레오 케미칼 발포폴리스티렌 코팅제의 제조방법

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US5352390A (en) * 1989-07-25 1994-10-04 W. R. Grace & Co.-Conn. Cementitious compositions containing shredded polystyrene aggregate
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US5110841A (en) * 1990-06-25 1992-05-05 The Dow Chemical Company Antistatic polyolefin foams and films and method of making the foam and antistatic composition
US5112528A (en) * 1990-06-25 1992-05-12 The Dow Chemical Company Antistatic polyolefin foams and films and method of making the foam and antistatic composition
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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20010109514A (ko) * 2001-11-19 2001-12-10 손진기 영구적인 대전방지성을 갖는 아크릴 패널의 제조방법
KR20070060454A (ko) * 2005-12-08 2007-06-13 주식회사 레오 케미칼 발포폴리스티렌 코팅제의 제조방법

Also Published As

Publication number Publication date
CA1286166C (en) 1991-07-16
DE3875784D1 (de) 1992-12-17
JPS63286407A (ja) 1988-11-24
JP2750324B2 (ja) 1998-05-13
MX166551B (es) 1993-01-18
AU1524488A (en) 1988-11-03
EP0289321A2 (en) 1988-11-02
AU603658B2 (en) 1990-11-22
EP0289321B1 (en) 1992-11-11
DE3875784T2 (de) 1993-03-25
KR960004144B1 (ko) 1996-03-27
US4781983A (en) 1988-11-01
EP0289321A3 (en) 1990-01-24

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