KR880011066A - (페닐에테닐) 페닐프로피온산과 그 에스테르 및 (벤조일페닐) 프로피온산 또는 그 에스테르의 제조방법 - Google Patents
(페닐에테닐) 페닐프로피온산과 그 에스테르 및 (벤조일페닐) 프로피온산 또는 그 에스테르의 제조방법 Download PDFInfo
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- KR880011066A KR880011066A KR1019880002452A KR880002452A KR880011066A KR 880011066 A KR880011066 A KR 880011066A KR 1019880002452 A KR1019880002452 A KR 1019880002452A KR 880002452 A KR880002452 A KR 880002452A KR 880011066 A KR880011066 A KR 880011066A
- Authority
- KR
- South Korea
- Prior art keywords
- propionic acid
- phenylethenyl
- residue
- phenyl
- alkyl ester
- Prior art date
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C57/00—Unsaturated compounds having carboxyl groups bound to acyclic carbon atoms
- C07C57/46—Unsaturated compounds having carboxyl groups bound to acyclic carbon atoms containing six-membered aromatic rings and other rings, e.g. cyclohexylphenylacetic acid
- C07C57/48—Unsaturated compounds having carboxyl groups bound to acyclic carbon atoms containing six-membered aromatic rings and other rings, e.g. cyclohexylphenylacetic acid having unsaturation outside the aromatic rings
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
- C07C1/20—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms
- C07C1/24—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms by elimination of water
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
- C07C1/32—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from compounds containing hetero-atoms other than or in addition to oxygen or halogen
- C07C1/325—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from compounds containing hetero-atoms other than or in addition to oxygen or halogen the hetero-atom being a metal atom
- C07C1/326—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from compounds containing hetero-atoms other than or in addition to oxygen or halogen the hetero-atom being a metal atom the hetero-atom being a magnesium atom
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C15/00—Cyclic hydrocarbons containing only six-membered aromatic rings as cyclic parts
- C07C15/40—Cyclic hydrocarbons containing only six-membered aromatic rings as cyclic parts substituted by unsaturated carbon radicals
- C07C15/50—Cyclic hydrocarbons containing only six-membered aromatic rings as cyclic parts substituted by unsaturated carbon radicals polycyclic non-condensed
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
- C07C5/32—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen
- C07C5/327—Formation of non-aromatic carbon-to-carbon double bonds only
- C07C5/333—Catalytic processes
- C07C5/3332—Catalytic processes with metal oxides or metal sulfides
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/10—Preparation of carboxylic acids or their salts, halides or anhydrides by reaction with carbon monoxide
- C07C51/14—Preparation of carboxylic acids or their salts, halides or anhydrides by reaction with carbon monoxide on a carbon-to-carbon unsaturated bond in organic compounds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C57/00—Unsaturated compounds having carboxyl groups bound to acyclic carbon atoms
- C07C57/30—Unsaturated compounds having carboxyl groups bound to acyclic carbon atoms containing six-membered aromatic rings
- C07C57/42—Unsaturated compounds having carboxyl groups bound to acyclic carbon atoms containing six-membered aromatic rings having unsaturation outside the rings
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
- C07C69/612—Esters of carboxylic acids having a carboxyl group bound to an acyclic carbon atom and having a six-membered aromatic ring in the acid moiety
- C07C69/618—Esters of carboxylic acids having a carboxyl group bound to an acyclic carbon atom and having a six-membered aromatic ring in the acid moiety having unsaturation outside the six-membered aromatic ring
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper
- C07C2523/74—Iron group metals
- C07C2523/745—Iron
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
내용 없음
Description
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
Claims (8)
- 하기 구조식으로 표시되는 ??-(3-1-페닐에테닐)페닐)프로피온산 및 그 알킬 에스테르(여기서, R은 H 또는 탄소수 1 내지 4개의 저급알킬기).
- 제1항에 있어서, 상기 저급알킬기가 메틸기인 것을 특징으로 하는 알킬에스테르.
- 상기식 (Ⅱ)로 표시되는 ??-(3-(1-페닐에테닐)페닐-프로피온산 또는 그 알킬에스테르를 산화시키는 것을 특징으로 하는 식 (I)의 ??-(3-(1-벤조닐페닐)프로피온산 또는 그 알킬에스테르의 제조방법.(여기서, R은 H 또는 탄소 1 내지 4개의 저급알킬기이다).(여기서, R은 H 또는 탄소수 1 내지 4개의 저급알킬기이다).
- 제3항에 있어서, 상기 산화가 산화촉매의 존재하의 분자상 산소에 의한 산화 또는 산화제에 의한 산화인 것을 특징으로 하는 제조방법.
- 제3항에 있어서, ??-(3-(1-페닐에테닐)페닐)프로피온산 또는 그 알킬에스테르가 1- (3-비닐페닐)-1-페닐에틸렌을 함유한 잔류분을 귀금속 착체 촉매의 존재하에 일산화탄소와 물 또는 저급알코올을 반응시킴으로써 얻어지는 것을 특징으로 하는 ??-(3-(1-페닐에테닐)페닐)프로피온산 또는 그 알킬에스테르의 제조방법.
- 제5항에 있어서, 상기 1-(3-비닐페닐)-1-페닐에틸렌을 함유한 잔류분이 1-(3-에틸페닐)-1-페닐에탄을 함유한 잔류분을 탈수소함으로써 제조되는 것을 특징으로 하는 제조방법.
- 제6항에 있어서, 상기 1-(3-에틸페닐)-1-페닐에탄을 함유한 잔류분이 벤젠을 에틸렌으로 알킬화촉매의 의하여 알킬화할 때에 비점 285℃ 내지 290℃ (상압환산)의 범위에 있는 잔류분으로서 회수되는 것을 특징으로 하는 제조방법.
- 제8항에 있어서, 상기 알킬화촉매가 루이스산 또는 프로톤산인 것을 특징으로 하는 제조방법.※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP62-57099 | 1987-03-12 | ||
JP62057099A JPH07100679B2 (ja) | 1987-03-12 | 1987-03-12 | α−(3−ベンゾイルフエニル)プロピオン酸またはそのエステルの製造方法 |
Publications (2)
Publication Number | Publication Date |
---|---|
KR880011066A true KR880011066A (ko) | 1988-10-26 |
KR950014219B1 KR950014219B1 (ko) | 1995-11-23 |
Family
ID=13046057
Family Applications (3)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
KR1019880002348A KR930006077B1 (ko) | 1987-03-12 | 1988-03-07 | 1-(3-비닐페닐)-1-페닐에틸렌류 및 그의 제조방법 |
KR1019880002452A KR950014219B1 (ko) | 1987-03-12 | 1988-03-09 | (페닐에테닐)페닐프로피온산과 그 에스테르 및 (벤조일페닐)프로피온산 또는 그 에스테르의 제조방법 |
KR1019880701415A KR950014220B1 (ko) | 1987-03-12 | 1988-03-12 | 디올레핀의 선택적 히드로에스테르화 방법 |
Family Applications Before (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
KR1019880002348A KR930006077B1 (ko) | 1987-03-12 | 1988-03-07 | 1-(3-비닐페닐)-1-페닐에틸렌류 및 그의 제조방법 |
Family Applications After (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
KR1019880701415A KR950014220B1 (ko) | 1987-03-12 | 1988-03-12 | 디올레핀의 선택적 히드로에스테르화 방법 |
Country Status (7)
Country | Link |
---|---|
US (3) | US4822934A (ko) |
EP (3) | EP0282065B1 (ko) |
JP (1) | JPH07100679B2 (ko) |
KR (3) | KR930006077B1 (ko) |
CA (1) | CA1299189C (ko) |
DE (3) | DE3865464D1 (ko) |
WO (1) | WO1988007034A1 (ko) |
Families Citing this family (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH07100678B2 (ja) * | 1987-03-12 | 1995-11-01 | 日本石油化学株式会社 | α−(3−ベンゾイルフエニル)プロピオン酸の製造方法 |
JPS63233949A (ja) * | 1987-03-23 | 1988-09-29 | Nippon Petrochem Co Ltd | ジオレフインの選択的ヒドロエステル化方法 |
US5059572A (en) * | 1989-10-31 | 1991-10-22 | Shell Oil Company | Catalyst and process for coupling organometallic reagents with aryl or vinylic halides |
US5237116A (en) * | 1989-10-31 | 1993-08-17 | Shell Oil Company | Catalyst and process for coupling organometallic reagents with aryl or vinylic halides |
WO2008012605A1 (en) * | 2006-07-27 | 2008-01-31 | Techfields Biochem Co. Ltd | Positively charged water-soluble prodrugs of ketoprofen and related compounds with very fast skin penetration rate |
DE602007008452D1 (de) * | 2006-10-17 | 2010-09-23 | Ge Healthcare As | Verfahren zur herstellung von alpha-keto-säuren und estern davon |
Family Cites Families (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4257973A (en) * | 1971-11-05 | 1981-03-24 | E. I. Du Pont De Nemours And Company | Process of making acids or esters from unsaturated compounds |
DE2646792C2 (de) * | 1975-10-23 | 1985-05-09 | Mitsubishi Petrochemical Co., Ltd., Tokio/Tokyo | Verfahren zur Herstellung einer α-(arylsubstituierten)-Propionsäure und/oder eines Esters derselben |
US4172087A (en) * | 1978-02-13 | 1979-10-23 | Texaco Development Corporation | Process for preparing unsaturated aliphatic esters from aliphatic dienes |
IT8123391A0 (it) * | 1981-08-08 | 1981-08-08 | Montedison Spa | Processo per la preparazione di esteri di acidi arilpropionici otticamente attivi. |
CA1194284A (en) * | 1982-09-16 | 1985-10-01 | Atsushi Sato | Electrical insulating oil and oil-filled electrical appliances |
CA1211761A (en) * | 1982-12-25 | 1986-09-23 | Atsushi Sato | Electrical insulating substance and oil-filled electrical appliances containing the same |
JPS59216849A (ja) * | 1983-05-24 | 1984-12-06 | Nissan Chem Ind Ltd | α−フエニルプロピオン酸エステルの製造方法 |
JPS60189108A (ja) * | 1984-03-08 | 1985-09-26 | 日本石油化学株式会社 | 電気絶縁油 |
US4694100A (en) * | 1984-07-14 | 1987-09-15 | Nippon Petrochemicals Company, Ltd. | Method for producing α-(p-isobutylphenyl)propionic acid or its alkyl esters |
JPS6222732A (ja) * | 1985-07-24 | 1987-01-30 | Nippon Petrochem Co Ltd | 1,1−(3−エチルフエニル)フエニルエチレン |
GB8705699D0 (en) * | 1987-03-11 | 1987-04-15 | Shell Int Research | Carbonylation of olefinically unsaturated compounds |
JPH05170745A (ja) * | 1991-12-25 | 1993-07-09 | Kanebo Ltd | ベンズイミダゾール誘導体、その製造法、それを有効成分とする制吐剤およびその製造用中間体 |
-
1987
- 1987-03-12 JP JP62057099A patent/JPH07100679B2/ja not_active Expired - Lifetime
-
1988
- 1988-03-07 KR KR1019880002348A patent/KR930006077B1/ko not_active IP Right Cessation
- 1988-03-09 KR KR1019880002452A patent/KR950014219B1/ko not_active IP Right Cessation
- 1988-03-09 US US07/165,727 patent/US4822934A/en not_active Expired - Lifetime
- 1988-03-09 CA CA000560950A patent/CA1299189C/en not_active Expired - Lifetime
- 1988-03-09 US US07/165,729 patent/US4937375A/en not_active Expired - Fee Related
- 1988-03-10 EP EP88103827A patent/EP0282065B1/en not_active Expired - Lifetime
- 1988-03-10 DE DE8888103825T patent/DE3865464D1/de not_active Expired - Lifetime
- 1988-03-10 EP EP88103825A patent/EP0282063B1/en not_active Expired - Lifetime
- 1988-03-10 DE DE8888103827T patent/DE3871409D1/de not_active Expired - Lifetime
- 1988-03-12 EP EP88902549A patent/EP0304495B1/en not_active Expired - Lifetime
- 1988-03-12 US US07/275,081 patent/US4908473A/en not_active Expired - Fee Related
- 1988-03-12 WO PCT/JP1988/000264 patent/WO1988007034A1/ja active IP Right Grant
- 1988-03-12 KR KR1019880701415A patent/KR950014220B1/ko not_active IP Right Cessation
- 1988-03-12 DE DE8888902549T patent/DE3871461D1/de not_active Expired - Lifetime
Also Published As
Publication number | Publication date |
---|---|
EP0282063A1 (en) | 1988-09-14 |
US4908473A (en) | 1990-03-13 |
DE3871461D1 (de) | 1992-07-02 |
KR890700566A (ko) | 1989-04-25 |
US4937375A (en) | 1990-06-26 |
US4822934A (en) | 1989-04-18 |
DE3865464D1 (de) | 1991-11-21 |
JPS63225335A (ja) | 1988-09-20 |
CA1299189C (en) | 1992-04-21 |
EP0304495B1 (en) | 1992-05-27 |
EP0282063B1 (en) | 1991-10-16 |
WO1988007034A1 (en) | 1988-09-22 |
KR930006077B1 (ko) | 1993-07-07 |
JPH07100679B2 (ja) | 1995-11-01 |
EP0304495A1 (en) | 1989-03-01 |
EP0282065A2 (en) | 1988-09-14 |
KR950014219B1 (ko) | 1995-11-23 |
EP0282065A3 (en) | 1990-03-28 |
KR880011055A (ko) | 1988-10-26 |
EP0282065B1 (en) | 1992-05-27 |
KR950014220B1 (ko) | 1995-11-23 |
EP0304495A4 (en) | 1989-12-19 |
DE3871409D1 (de) | 1992-07-02 |
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